JP5044074B2 - 熱発泡性マイクロスフェアー及びその製造方法 - Google Patents
熱発泡性マイクロスフェアー及びその製造方法 Download PDFInfo
- Publication number
- JP5044074B2 JP5044074B2 JP2001174946A JP2001174946A JP5044074B2 JP 5044074 B2 JP5044074 B2 JP 5044074B2 JP 2001174946 A JP2001174946 A JP 2001174946A JP 2001174946 A JP2001174946 A JP 2001174946A JP 5044074 B2 JP5044074 B2 JP 5044074B2
- Authority
- JP
- Japan
- Prior art keywords
- polymerization
- thermally foamable
- organosilicon compound
- polymerizable
- foaming
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000004005 microsphere Substances 0.000 title claims description 222
- 238000004519 manufacturing process Methods 0.000 title claims description 24
- 150000003961 organosilicon compounds Chemical class 0.000 claims abstract description 65
- 229920000642 polymer Polymers 0.000 claims abstract description 34
- 238000006116 polymerization reaction Methods 0.000 claims description 111
- 239000002245 particle Substances 0.000 claims description 88
- 239000000178 monomer Substances 0.000 claims description 72
- 239000000203 mixture Substances 0.000 claims description 71
- 238000010557 suspension polymerization reaction Methods 0.000 claims description 65
- 239000002612 dispersion medium Substances 0.000 claims description 60
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 41
- 239000010419 fine particle Substances 0.000 claims description 39
- 238000000034 method Methods 0.000 claims description 37
- 239000000126 substance Substances 0.000 claims description 35
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 34
- 229920001577 copolymer Polymers 0.000 claims description 33
- 239000003381 stabilizer Substances 0.000 claims description 30
- 239000006185 dispersion Substances 0.000 claims description 28
- 239000004088 foaming agent Substances 0.000 claims description 28
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 claims description 25
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 13
- 229920002554 vinyl polymer Polymers 0.000 claims description 9
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 5
- 230000002378 acidificating effect Effects 0.000 claims description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 4
- 125000005641 methacryl group Chemical group 0.000 claims description 4
- 238000004581 coalescence Methods 0.000 claims description 2
- 239000011859 microparticle Substances 0.000 claims 1
- 239000004604 Blowing Agent Substances 0.000 abstract description 2
- 229920000103 Expandable microsphere Polymers 0.000 abstract 1
- 238000005187 foaming Methods 0.000 description 97
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 90
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 52
- 230000006399 behavior Effects 0.000 description 51
- 239000006260 foam Substances 0.000 description 51
- 230000000052 comparative effect Effects 0.000 description 41
- 239000000377 silicon dioxide Substances 0.000 description 35
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 34
- 239000011541 reaction mixture Substances 0.000 description 33
- 239000000706 filtrate Substances 0.000 description 26
- 230000004927 fusion Effects 0.000 description 24
- 239000002002 slurry Substances 0.000 description 24
- 238000001035 drying Methods 0.000 description 23
- -1 acrylate ester Chemical class 0.000 description 20
- 238000010438 heat treatment Methods 0.000 description 20
- 239000003973 paint Substances 0.000 description 20
- 238000006243 chemical reaction Methods 0.000 description 18
- 239000008119 colloidal silica Substances 0.000 description 18
- 239000011230 binding agent Substances 0.000 description 17
- 239000000976 ink Substances 0.000 description 17
- 239000000463 material Substances 0.000 description 17
- 238000002360 preparation method Methods 0.000 description 17
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 16
- 230000002776 aggregation Effects 0.000 description 14
- 238000004220 aggregation Methods 0.000 description 14
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 13
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical class OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 12
- 125000005396 acrylic acid ester group Chemical group 0.000 description 12
- 239000007859 condensation product Substances 0.000 description 11
- 230000001747 exhibiting effect Effects 0.000 description 11
- 125000000524 functional group Chemical group 0.000 description 11
- 239000007788 liquid Substances 0.000 description 11
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 description 10
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 10
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 10
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 9
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 9
- 239000003505 polymerization initiator Substances 0.000 description 9
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 8
- 239000000084 colloidal system Substances 0.000 description 8
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 7
- 239000002253 acid Substances 0.000 description 7
- 235000010323 ascorbic acid Nutrition 0.000 description 7
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 7
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 6
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- 239000007789 gas Substances 0.000 description 6
- 230000001771 impaired effect Effects 0.000 description 6
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- 229920003023 plastic Polymers 0.000 description 6
- 239000004033 plastic Substances 0.000 description 6
- 229960005070 ascorbic acid Drugs 0.000 description 5
- 230000004888 barrier function Effects 0.000 description 5
- 239000002585 base Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 239000011147 inorganic material Substances 0.000 description 5
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 5
- 239000000347 magnesium hydroxide Substances 0.000 description 5
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 235000010288 sodium nitrite Nutrition 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 4
- 230000002159 abnormal effect Effects 0.000 description 4
- 239000011668 ascorbic acid Substances 0.000 description 4
- 239000001506 calcium phosphate Substances 0.000 description 4
- 229910000389 calcium phosphate Inorganic materials 0.000 description 4
- 235000011010 calcium phosphates Nutrition 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- 239000013538 functional additive Substances 0.000 description 4
- MEFJMBSAHDEPGF-UHFFFAOYSA-N hexanedioic acid;2-(2-hydroxyethylamino)ethanol Chemical compound OCCNCCO.OC(=O)CCCCC(O)=O MEFJMBSAHDEPGF-UHFFFAOYSA-N 0.000 description 4
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 4
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 150000000996 L-ascorbic acids Chemical class 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 239000008346 aqueous phase Substances 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 238000005119 centrifugation Methods 0.000 description 3
- 238000007334 copolymerization reaction Methods 0.000 description 3
- 230000003247 decreasing effect Effects 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 239000003995 emulsifying agent Substances 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 229910017053 inorganic salt Inorganic materials 0.000 description 3
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 3
- 239000011368 organic material Substances 0.000 description 3
- 239000005416 organic matter Substances 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 239000003208 petroleum Substances 0.000 description 3
- 239000011780 sodium chloride Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 3
- 239000002699 waste material Substances 0.000 description 3
- 239000002351 wastewater Substances 0.000 description 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- WYGWHHGCAGTUCH-UHFFFAOYSA-N 2-[(2-cyano-4-methylpentan-2-yl)diazenyl]-2,4-dimethylpentanenitrile Chemical compound CC(C)CC(C)(C#N)N=NC(C)(C#N)CC(C)C WYGWHHGCAGTUCH-UHFFFAOYSA-N 0.000 description 2
- SJECZPVISLOESU-UHFFFAOYSA-N 3-trimethoxysilylpropan-1-amine Chemical compound CO[Si](OC)(OC)CCCN SJECZPVISLOESU-UHFFFAOYSA-N 0.000 description 2
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 2
- NHTMVDHEPJAVLT-UHFFFAOYSA-N Isooctane Chemical compound CC(C)CC(C)(C)C NHTMVDHEPJAVLT-UHFFFAOYSA-N 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 125000001309 chloro group Chemical group Cl* 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- WOXXJEVNDJOOLV-UHFFFAOYSA-N ethenyl-tris(2-methoxyethoxy)silane Chemical compound COCCO[Si](OCCOC)(OCCOC)C=C WOXXJEVNDJOOLV-UHFFFAOYSA-N 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 2
- 230000006870 function Effects 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 230000000977 initiatory effect Effects 0.000 description 2
- 229910010272 inorganic material Inorganic materials 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 239000001282 iso-butane Substances 0.000 description 2
- 239000002609 medium Substances 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- CRSOQBOWXPBRES-UHFFFAOYSA-N neopentane Chemical compound CC(C)(C)C CRSOQBOWXPBRES-UHFFFAOYSA-N 0.000 description 2
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 2
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 2
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 125000005372 silanol group Chemical group 0.000 description 2
- 150000003377 silicon compounds Chemical class 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- TXUICONDJPYNPY-UHFFFAOYSA-N (1,10,13-trimethyl-3-oxo-4,5,6,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-17-yl) heptanoate Chemical compound C1CC2CC(=O)C=C(C)C2(C)C2C1C1CCC(OC(=O)CCCCCC)C1(C)CC2 TXUICONDJPYNPY-UHFFFAOYSA-N 0.000 description 1
- BEQKKZICTDFVMG-UHFFFAOYSA-N 1,2,3,4,6-pentaoxepane-5,7-dione Chemical compound O=C1OOOOC(=O)O1 BEQKKZICTDFVMG-UHFFFAOYSA-N 0.000 description 1
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- BYDSZOIVRARBOU-UHFFFAOYSA-N 2-(4-bicyclo[2.2.1]heptanyl)ethenyl-trimethoxysilane Chemical compound C1CC2CCC1(C=C[Si](OC)(OC)OC)C2 BYDSZOIVRARBOU-UHFFFAOYSA-N 0.000 description 1
- 125000000022 2-aminoethyl group Chemical group [H]C([*])([H])C([H])([H])N([H])[H] 0.000 description 1
- VGNMBOBKLDHWRC-UHFFFAOYSA-N 2-methyl-n,n-bis(3-trimethoxysilylpropyl)prop-2-enamide Chemical compound CO[Si](OC)(OC)CCCN(C(=O)C(C)=C)CCC[Si](OC)(OC)OC VGNMBOBKLDHWRC-UHFFFAOYSA-N 0.000 description 1
- LZMNXXQIQIHFGC-UHFFFAOYSA-N 3-[dimethoxy(methyl)silyl]propyl 2-methylprop-2-enoate Chemical compound CO[Si](C)(OC)CCCOC(=O)C(C)=C LZMNXXQIQIHFGC-UHFFFAOYSA-N 0.000 description 1
- NWBTXZPDTSKZJU-UHFFFAOYSA-N 3-[dimethyl(trimethylsilyloxy)silyl]propyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCC[Si](C)(C)O[Si](C)(C)C NWBTXZPDTSKZJU-UHFFFAOYSA-N 0.000 description 1
- BESKSSIEODQWBP-UHFFFAOYSA-N 3-tris(trimethylsilyloxy)silylpropyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCC[Si](O[Si](C)(C)C)(O[Si](C)(C)C)O[Si](C)(C)C BESKSSIEODQWBP-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- 229940126062 Compound A Drugs 0.000 description 1
- ZZZCUOFIHGPKAK-UHFFFAOYSA-N D-erythro-ascorbic acid Natural products OCC1OC(=O)C(O)=C1O ZZZCUOFIHGPKAK-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- 239000002211 L-ascorbic acid Substances 0.000 description 1
- 235000000069 L-ascorbic acid Nutrition 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000004260 Potassium ascorbate Substances 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- 229910021626 Tin(II) chloride Inorganic materials 0.000 description 1
- 229910021627 Tin(IV) chloride Inorganic materials 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 description 1
- 229930003268 Vitamin C Natural products 0.000 description 1
- AZFNGPAYDKGCRB-XCPIVNJJSA-M [(1s,2s)-2-amino-1,2-diphenylethyl]-(4-methylphenyl)sulfonylazanide;chlororuthenium(1+);1-methyl-4-propan-2-ylbenzene Chemical compound [Ru+]Cl.CC(C)C1=CC=C(C)C=C1.C1=CC(C)=CC=C1S(=O)(=O)[N-][C@@H](C=1C=CC=CC=1)[C@@H](N)C1=CC=CC=C1 AZFNGPAYDKGCRB-XCPIVNJJSA-M 0.000 description 1
- IAXXETNIOYFMLW-COPLHBTASA-N [(1s,3s,4s)-4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl] 2-methylprop-2-enoate Chemical compound C1C[C@]2(C)[C@@H](OC(=O)C(=C)C)C[C@H]1C2(C)C IAXXETNIOYFMLW-COPLHBTASA-N 0.000 description 1
- NOZAQBYNLKNDRT-UHFFFAOYSA-N [diacetyloxy(ethenyl)silyl] acetate Chemical compound CC(=O)O[Si](OC(C)=O)(OC(C)=O)C=C NOZAQBYNLKNDRT-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
- 238000007385 chemical modification Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 239000012933 diacyl peroxide Substances 0.000 description 1
- WHGNXNCOTZPEEK-UHFFFAOYSA-N dimethoxy-methyl-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](C)(OC)CCCOCC1CO1 WHGNXNCOTZPEEK-UHFFFAOYSA-N 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 1
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 229940119545 isobornyl methacrylate Drugs 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Chemical class 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 150000004692 metal hydroxides Chemical class 0.000 description 1
- LUCXVPAZUDVVBT-UHFFFAOYSA-N methyl-[3-(2-methylphenoxy)-3-phenylpropyl]azanium;chloride Chemical compound Cl.C=1C=CC=CC=1C(CCNC)OC1=CC=CC=C1C LUCXVPAZUDVVBT-UHFFFAOYSA-N 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000003094 microcapsule Substances 0.000 description 1
- AIRYAPRCQFBWIL-UHFFFAOYSA-N n,n-bis[3-[dimethoxy(methyl)silyl]propyl]-2-methylprop-2-enamide Chemical compound CO[Si](C)(OC)CCCN(C(=O)C(C)=C)CCC[Si](C)(OC)OC AIRYAPRCQFBWIL-UHFFFAOYSA-N 0.000 description 1
- 239000010434 nepheline Substances 0.000 description 1
- 229910052664 nepheline Inorganic materials 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920001084 poly(chloroprene) Polymers 0.000 description 1
- 235000019275 potassium ascorbate Nutrition 0.000 description 1
- 229940017794 potassium ascorbate Drugs 0.000 description 1
- 235000010289 potassium nitrite Nutrition 0.000 description 1
- 239000004304 potassium nitrite Substances 0.000 description 1
- CONVKSGEGAVTMB-RXSVEWSESA-M potassium-L-ascorbate Chemical compound [K+].OC[C@H](O)[C@H]1OC(=O)C(O)=C1[O-] CONVKSGEGAVTMB-RXSVEWSESA-M 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 239000008262 pumice Substances 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 239000011044 quartzite Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- PPASLZSBLFJQEF-RKJRWTFHSA-M sodium ascorbate Substances [Na+].OC[C@@H](O)[C@H]1OC(=O)C(O)=C1[O-] PPASLZSBLFJQEF-RKJRWTFHSA-M 0.000 description 1
- 235000010378 sodium ascorbate Nutrition 0.000 description 1
- 229960005055 sodium ascorbate Drugs 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- PPASLZSBLFJQEF-RXSVEWSESA-M sodium-L-ascorbate Chemical compound [Na+].OC[C@H](O)[C@H]1OC(=O)C(O)=C1[O-] PPASLZSBLFJQEF-RXSVEWSESA-M 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000001119 stannous chloride Substances 0.000 description 1
- 235000011150 stannous chloride Nutrition 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 238000010558 suspension polymerization method Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- CZDYPVPMEAXLPK-UHFFFAOYSA-N tetramethylsilane Chemical compound C[Si](C)(C)C CZDYPVPMEAXLPK-UHFFFAOYSA-N 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 125000003396 thiol group Chemical group [H]S* 0.000 description 1
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- GQIUQDDJKHLHTB-UHFFFAOYSA-N trichloro(ethenyl)silane Chemical compound Cl[Si](Cl)(Cl)C=C GQIUQDDJKHLHTB-UHFFFAOYSA-N 0.000 description 1
- FLTJDUOFAQWHDF-UHFFFAOYSA-N trimethyl pentane Natural products CCCCC(C)(C)C FLTJDUOFAQWHDF-UHFFFAOYSA-N 0.000 description 1
- HYWCXWRMUZYRPH-UHFFFAOYSA-N trimethyl(prop-2-enyl)silane Chemical compound C[Si](C)(C)CC=C HYWCXWRMUZYRPH-UHFFFAOYSA-N 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 239000005050 vinyl trichlorosilane Substances 0.000 description 1
- 235000019154 vitamin C Nutrition 0.000 description 1
- 239000011718 vitamin C Substances 0.000 description 1
- 239000013585 weight reducing agent Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
- B01J13/06—Making microcapsules or microballoons by phase separation
- B01J13/14—Polymerisation; cross-linking
- B01J13/18—In situ polymerisation with all reactants being present in the same phase
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
- B01J13/06—Making microcapsules or microballoons by phase separation
- B01J13/14—Polymerisation; cross-linking
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/50—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by form
- D21H21/52—Additives of definite length or shape
- D21H21/54—Additives of definite length or shape being spherical, e.g. microcapsules, beads
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/59—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2984—Microcapsule with fluid core [includes liposome]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2984—Microcapsule with fluid core [includes liposome]
- Y10T428/2985—Solid-walled microcapsule from synthetic polymer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2991—Coated
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2991—Coated
- Y10T428/2993—Silicic or refractory material containing [e.g., tungsten oxide, glass, cement, etc.]
- Y10T428/2995—Silane, siloxane or silicone coating
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Manufacturing Of Micro-Capsules (AREA)
- Polymerisation Methods In General (AREA)
- Fertilizers (AREA)
Priority Applications (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001174946A JP5044074B2 (ja) | 2001-06-11 | 2001-06-11 | 熱発泡性マイクロスフェアー及びその製造方法 |
| EP02733441A EP1408097B2 (en) | 2001-06-11 | 2002-06-10 | Heat-expandable microsphere and process for producing the same |
| AT02733441T ATE455593T1 (de) | 2001-06-11 | 2002-06-10 | Thermisch expandierbare mikrokugel und verfahren zu deren herstellung |
| CNB028117336A CN100436562C (zh) | 2001-06-11 | 2002-06-10 | 热发泡性微球体及其制造方法 |
| US10/480,207 US7931967B2 (en) | 2001-06-11 | 2002-06-10 | Thermally foamable microsphere and production process thereof |
| PCT/JP2002/005737 WO2002100971A1 (fr) | 2001-06-11 | 2002-06-10 | Microspheres expansibles a la chaleur et leur procede d'obtention |
| DE60235165T DE60235165D1 (de) | 2001-06-11 | 2002-06-10 | Thermisch expandierbare mikrokugel und verfahren zu deren herstellung |
| TW091112607A TWI302567B (cg-RX-API-DMAC7.html) | 2001-06-11 | 2002-06-11 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001174946A JP5044074B2 (ja) | 2001-06-11 | 2001-06-11 | 熱発泡性マイクロスフェアー及びその製造方法 |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2012113529A Division JP5604472B2 (ja) | 2012-05-17 | 2012-05-17 | 熱発泡性マイクロスフェアー及びその製造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2002363537A JP2002363537A (ja) | 2002-12-18 |
| JP5044074B2 true JP5044074B2 (ja) | 2012-10-10 |
Family
ID=19016159
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2001174946A Expired - Fee Related JP5044074B2 (ja) | 2001-06-11 | 2001-06-11 | 熱発泡性マイクロスフェアー及びその製造方法 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US7931967B2 (cg-RX-API-DMAC7.html) |
| EP (1) | EP1408097B2 (cg-RX-API-DMAC7.html) |
| JP (1) | JP5044074B2 (cg-RX-API-DMAC7.html) |
| CN (1) | CN100436562C (cg-RX-API-DMAC7.html) |
| AT (1) | ATE455593T1 (cg-RX-API-DMAC7.html) |
| DE (1) | DE60235165D1 (cg-RX-API-DMAC7.html) |
| TW (1) | TWI302567B (cg-RX-API-DMAC7.html) |
| WO (1) | WO2002100971A1 (cg-RX-API-DMAC7.html) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2012167286A (ja) * | 2012-05-17 | 2012-09-06 | Kureha Corp | 熱発泡性マイクロスフェアー及びその製造方法 |
Families Citing this family (52)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7838037B2 (en) * | 1999-11-17 | 2010-11-23 | Tagra Biotechnologies Ltd. | Method of microencapsulation |
| US6866906B2 (en) | 2000-01-26 | 2005-03-15 | International Paper Company | Cut resistant paper and paper articles and method for making same |
| JP4721596B2 (ja) * | 2001-09-28 | 2011-07-13 | 株式会社クレハ | 低密度発泡紙及びその製造方法 |
| ES2347993T3 (es) | 2002-09-13 | 2010-11-26 | International Paper Company | Papel con rigidez y cuerpo mejorados y método para fabricarlo campo de aplicación de la invención. |
| EP1598405B1 (en) * | 2003-02-24 | 2014-10-01 | Matsumoto Yushi-Seiyaku Co., Ltd. | Thermoexpansible microsphere, process for producing the same and method of use thereof |
| US7828935B2 (en) * | 2003-04-07 | 2010-11-09 | International Paper Company | Papers for liquid electrophotographic printing and method for making same |
| JP4738746B2 (ja) * | 2004-01-20 | 2011-08-03 | セメダイン株式会社 | 耐火構造体用硬化性組成物、シーリング材及びそれを用いた耐火工法 |
| JP4567980B2 (ja) * | 2004-01-26 | 2010-10-27 | 三洋化成工業株式会社 | 熱膨張性マイクロカプセルおよび中空樹脂粒子 |
| US7361399B2 (en) * | 2004-05-24 | 2008-04-22 | International Paper Company | Gloss coated multifunctional printing paper |
| JP2006035092A (ja) * | 2004-07-27 | 2006-02-09 | Sanyo Chem Ind Ltd | 中空樹脂粒子と無機微粒子との混合物の製造方法 |
| JP4217200B2 (ja) * | 2004-09-24 | 2009-01-28 | 積水化学工業株式会社 | 中空樹脂微粒子の製造方法、中空樹脂微粒子、反射防止フィルム用コーティング剤及び反射防止フィルム |
| KR101192031B1 (ko) | 2005-03-11 | 2012-10-16 | 인터내셔널 페이퍼 컴퍼니 | 팽창성 미소구체 및 이온성 화합물을 함유하는 조성물, 및이의 제조 및 사용 방법 |
| JP2006326501A (ja) * | 2005-05-26 | 2006-12-07 | Casio Electronics Co Ltd | 中空マイクロカプセル及びその製造方法 |
| WO2007036981A1 (ja) | 2005-09-27 | 2007-04-05 | Cemedine Co., Ltd. | 硬化性組成物 |
| JP5484673B2 (ja) * | 2005-12-19 | 2014-05-07 | 株式会社クレハ | 熱発泡性マイクロスフェアー、並びにその製造方法と用途 |
| EP1974097B1 (en) | 2006-01-17 | 2017-12-13 | International Paper Company | Paper substrates containing high surface sizing and low internal sizing and having high dimensional stability |
| US8388809B2 (en) | 2006-02-10 | 2013-03-05 | Akzo Nobel N.V. | Microspheres |
| EP1981631B1 (en) * | 2006-02-10 | 2015-09-30 | Akzo Nobel N.V. | Microspheres |
| US7956096B2 (en) | 2006-02-10 | 2011-06-07 | Akzo Nobel N.V. | Microspheres |
| JP5448459B2 (ja) * | 2006-02-10 | 2014-03-19 | アクゾ ノーベル ナムローゼ フェンノートシャップ | 微小球 |
| US7943011B2 (en) * | 2006-05-05 | 2011-05-17 | International Paper Company | Paperboard material with expanded polymeric microspheres |
| PT2274478E (pt) | 2008-03-31 | 2012-10-02 | Int Paper Co | Folha de registo com qualidade de impressão melhorada a baixos niveis de aditivos |
| EP2787120B1 (en) | 2008-06-20 | 2024-10-16 | Global Holdings II, Inc. | Recording sheet with improved optical properties |
| WO2010025383A1 (en) * | 2008-08-28 | 2010-03-04 | International Paper Company | Expandable microspheres and methods of making and using the same |
| US9296244B2 (en) | 2008-09-26 | 2016-03-29 | International Paper Company | Composition suitable for multifunctional printing and recording sheet containing same |
| JP5202284B2 (ja) * | 2008-12-22 | 2013-06-05 | 株式会社日立産機システム | 熱硬化性樹脂組成物 |
| JP2010202805A (ja) * | 2009-03-04 | 2010-09-16 | Sekisui Chem Co Ltd | 熱膨張性マイクロカプセル及び熱膨張性マイクロカプセルの製造方法 |
| EP2529830A3 (en) * | 2009-06-09 | 2014-10-29 | Matsumoto Yushi-Seiyaku Co., Ltd. | Heat-expandable microspheres and a method of making heat-expandable microspheres and application thereof |
| JP5731110B2 (ja) * | 2009-09-18 | 2015-06-10 | 積水化学工業株式会社 | 発泡粒子、発泡性組成物、及び、発泡成形体の製造方法 |
| JP5427529B2 (ja) * | 2009-09-28 | 2014-02-26 | 積水化学工業株式会社 | 発泡粒子及び発泡成形体の製造方法 |
| CN102725689B (zh) | 2010-01-22 | 2014-10-08 | 帝斯曼知识产权资产管理有限公司 | 能固化成具有选择性视觉效果的层的液体可辐射固化树脂及其使用方法 |
| JP5898954B2 (ja) * | 2010-03-31 | 2016-04-06 | 積水化学工業株式会社 | 熱膨張性マイクロカプセル、熱膨張性マイクロカプセルの製造方法、発泡性マスターバッチ及び発泡成形体 |
| JP5825506B2 (ja) * | 2011-02-25 | 2015-12-02 | 横浜ゴム株式会社 | タイヤトレッド用ゴム組成物 |
| JP2013053275A (ja) * | 2011-09-06 | 2013-03-21 | Sekisui Chem Co Ltd | 熱膨張性マイクロカプセルの製造方法 |
| US9206552B2 (en) | 2012-02-17 | 2015-12-08 | International Paper Company | Absorbent plastic pigment with improved print density containing and recording sheet containing same |
| TW201422405A (zh) * | 2012-12-10 | 2014-06-16 | zhi-peng Chen | 球體之一體成型製造方法 |
| ES2581583T3 (es) | 2013-07-29 | 2016-09-06 | Takasago International Corporation | Microcápsulas |
| JP6438214B2 (ja) * | 2014-05-21 | 2018-12-12 | 株式会社クレハ | 熱膨張性マイクロスフェアーの製造方法、該製造方法で製造された熱膨張性マイクロスフェアー、及び該製造方法に用いるコロイダルシリカの判別方法 |
| CN104532475A (zh) * | 2014-12-15 | 2015-04-22 | 梁晋煜 | 一种制作球形立体棉的方法 |
| EP3162434B1 (en) * | 2015-01-08 | 2020-02-26 | Sekisui Plastics Co., Ltd. | Hollow particles |
| CN104788797B (zh) * | 2015-04-03 | 2017-05-03 | 上海杰上杰化学有限公司 | 可发泡树脂粒子及用其制备发泡材料的方法 |
| WO2017002659A1 (ja) | 2015-06-29 | 2017-01-05 | 松本油脂製薬株式会社 | 熱膨張性微小球の製造方法及びその利用 |
| JP6610174B2 (ja) * | 2015-11-06 | 2019-11-27 | コニカミノルタ株式会社 | 中空粒子の製造方法 |
| CN105384958A (zh) * | 2015-12-19 | 2016-03-09 | 仇颖超 | 一种二氧化硅溶胶改性偶氮二甲酰胺发泡剂的制备方法 |
| CN108697595B (zh) * | 2016-02-29 | 2022-01-14 | 积水化成品工业株式会社 | 内含二氧化硅的微胶囊树脂颗粒、其生产方法及其用途 |
| CN111315790B (zh) * | 2017-09-29 | 2024-01-30 | 罗门哈斯公司 | 具有径向变化的颗粒 |
| CN111278874B (zh) * | 2017-09-29 | 2023-12-22 | 罗门哈斯公司 | 制备具有径向变化的颗粒 |
| MX2020009799A (es) * | 2018-03-21 | 2020-10-12 | Nouryon Chemicals Int Bv | Recubrimientos con propiedades reflectantes solares. |
| KR102202059B1 (ko) * | 2018-05-11 | 2021-01-12 | 주식회사 엘지화학 | 고흡수성 수지 시트의 제조 방법 |
| US20220033608A1 (en) | 2018-12-05 | 2022-02-03 | Sabic Global Technologies B.V. | Expandable, shelf stable polymer bead |
| EP3816143B1 (en) | 2019-10-30 | 2023-07-26 | Alloy Surfaces Company, Inc. | Pyrophoric pellets that emit infrared radiation |
| KR20240130713A (ko) * | 2022-01-21 | 2024-08-29 | 마쓰모토유시세이야쿠 가부시키가이샤 | 열팽창성 미소구, 중공 입자 및 이들의 용도 |
Family Cites Families (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3142583A (en) * | 1960-04-05 | 1964-07-28 | Walter M Mcmahon | Inorganic coating composition |
| NL302030A (cg-RX-API-DMAC7.html) * | 1962-12-21 | 1900-01-01 | ||
| US3615972A (en) † | 1967-04-28 | 1971-10-26 | Dow Chemical Co | Expansible thermoplastic polymer particles containing volatile fluid foaming agent and method of foaming the same |
| US3740359A (en) * | 1972-07-10 | 1973-06-19 | Dow Chemical Co | Vinylidene chloride expandable microspheres |
| JPS5846251B2 (ja) * | 1980-07-29 | 1983-10-15 | 日立化成工業株式会社 | 発泡性ビニル系重合体粒子の製造法 |
| DE3129515C2 (de) * | 1980-07-29 | 1986-07-24 | Hitachi Chemical Co., Ltd., Tokio/Tokyo | Schäumbare Styrolharzmasse und Verfahren zu ihrer Herstellung |
| JPS5938241A (ja) * | 1982-08-26 | 1984-03-02 | Sekisui Plastics Co Ltd | 発泡性粒子の製造法 |
| JPS6019033A (ja) | 1983-07-12 | 1985-01-31 | Matsumoto Yushi Seiyaku Kk | 中空マイクロバル−ンおよびその製法 |
| JPS62286534A (ja) | 1986-06-04 | 1987-12-12 | Matsumoto Yushi Seiyaku Kk | 熱膨張性マイクロカプセルの製造法 |
| JPH04202443A (ja) * | 1990-11-30 | 1992-07-23 | Dainippon Ink & Chem Inc | 発泡性ビニル系樹脂粒子の製造方法 |
| JP3012950B2 (ja) * | 1991-04-19 | 2000-02-28 | 永和化成工業株式会社 | 発泡剤組成物 |
| JP3110526B2 (ja) * | 1991-11-08 | 2000-11-20 | 水澤化学工業株式会社 | ハイドロタルサイト被覆粒子、その製法及び樹脂用配合剤 |
| JPH06240040A (ja) | 1993-02-16 | 1994-08-30 | Dainichiseika Color & Chem Mfg Co Ltd | 複合マイクロバルーン及びその製造方法 |
| US5461125A (en) * | 1993-04-30 | 1995-10-24 | Minnesota Mining And Manufacturing Company | Waterborne core-shell latex polymers |
| JPH10176078A (ja) * | 1996-12-20 | 1998-06-30 | Hitachi Chem Co Ltd | 発泡性樹脂粒子およびその製造法 |
| US5834526A (en) | 1997-07-11 | 1998-11-10 | Wu; Huey S. | Expandable hollow particles |
| JPH11181210A (ja) * | 1997-12-17 | 1999-07-06 | Toagosei Co Ltd | 安定化された水性硬化性組成物 |
| JP4620812B2 (ja) | 1998-01-26 | 2011-01-26 | 株式会社クレハ | 発泡性マイクロスフェアーの製造方法 |
| DE69920664T3 (de) | 1998-01-26 | 2008-09-25 | Kureha Corp. | Expandierbare mikrokugeln und herstellungsverfahren dafür |
| DE19810803A1 (de) * | 1998-03-12 | 1999-09-16 | Wacker Chemie Gmbh | Verfahren zur Herstellung mikroverkapselter Produkte mit Organopolysiloxanwänden |
| JPH11335509A (ja) | 1998-05-22 | 1999-12-07 | Toagosei Co Ltd | 水性組成物 |
| JP2000086937A (ja) * | 1998-09-11 | 2000-03-28 | Matsushita Electric Ind Co Ltd | 耐熱性断熱材料と耐熱性断熱材料の製造方法 |
| US7232607B2 (en) | 2000-04-28 | 2007-06-19 | Kureha Corporation | Thermally foamable microsphere and production process thereof |
| US7252882B2 (en) | 2000-04-28 | 2007-08-07 | Kureha Corporation | Thermally foamable microsphere and production process thereof |
| US8088482B2 (en) * | 2001-05-25 | 2012-01-03 | Ip Rights, Llc | Expandable microspheres for foam insulation and methods |
-
2001
- 2001-06-11 JP JP2001174946A patent/JP5044074B2/ja not_active Expired - Fee Related
-
2002
- 2002-06-10 DE DE60235165T patent/DE60235165D1/de not_active Expired - Lifetime
- 2002-06-10 CN CNB028117336A patent/CN100436562C/zh not_active Expired - Fee Related
- 2002-06-10 AT AT02733441T patent/ATE455593T1/de not_active IP Right Cessation
- 2002-06-10 US US10/480,207 patent/US7931967B2/en not_active Expired - Fee Related
- 2002-06-10 WO PCT/JP2002/005737 patent/WO2002100971A1/ja not_active Ceased
- 2002-06-10 EP EP02733441A patent/EP1408097B2/en not_active Expired - Lifetime
- 2002-06-11 TW TW091112607A patent/TWI302567B/zh not_active IP Right Cessation
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2012167286A (ja) * | 2012-05-17 | 2012-09-06 | Kureha Corp | 熱発泡性マイクロスフェアー及びその製造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| TWI302567B (cg-RX-API-DMAC7.html) | 2008-11-01 |
| US20040157057A1 (en) | 2004-08-12 |
| EP1408097B2 (en) | 2012-10-10 |
| JP2002363537A (ja) | 2002-12-18 |
| EP1408097A1 (en) | 2004-04-14 |
| CN100436562C (zh) | 2008-11-26 |
| US7931967B2 (en) | 2011-04-26 |
| WO2002100971A1 (fr) | 2002-12-19 |
| ATE455593T1 (de) | 2010-02-15 |
| EP1408097B1 (en) | 2010-01-20 |
| EP1408097A4 (en) | 2006-10-18 |
| CN1514865A (zh) | 2004-07-21 |
| DE60235165D1 (de) | 2010-03-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP5044074B2 (ja) | 熱発泡性マイクロスフェアー及びその製造方法 | |
| JP5604472B2 (ja) | 熱発泡性マイクロスフェアー及びその製造方法 | |
| CN101341227B (zh) | 热发泡性微球及其制造方法和用途 | |
| KR100716484B1 (ko) | 열발포성 마이크로스페어 및 그의 제조 방법 | |
| CN100566811C (zh) | 热发泡性微球及其制造方法、其用途、含有其的组合物、和物品 | |
| JP3670980B2 (ja) | 熱発泡性マイクロスフェアー及びその製造方法 | |
| WO1999037706A1 (fr) | Microspheres expansibles et leur procede de production | |
| JP2019528158A (ja) | 熱膨張性熱可塑性マイクロスフェアおよびそれらの調製方法 | |
| JP4620812B2 (ja) | 発泡性マイクロスフェアーの製造方法 | |
| CN115175758A (zh) | 热膨胀性微球、其制造方法和用途 | |
| JP4903924B2 (ja) | 発泡性マイクロスフェアー及びその製造方法 | |
| JP6438214B2 (ja) | 熱膨張性マイクロスフェアーの製造方法、該製造方法で製造された熱膨張性マイクロスフェアー、及び該製造方法に用いるコロイダルシリカの判別方法 | |
| JP2017113654A (ja) | マイクロスフェアー、これを含む熱発泡性樹脂組成物、構造部材、および成形体 | |
| JP6276423B2 (ja) | 熱発泡性マイクロスフェアー、並びにそれを含む組成物及び成形体 | |
| JP5612245B2 (ja) | 熱発泡性マイクロスフェアー及びその製造方法並びに組成物 | |
| JP4721596B2 (ja) | 低密度発泡紙及びその製造方法 | |
| CN117715698A (zh) | 热膨胀性微球、组合物以及成型体 | |
| JP4945079B2 (ja) | 熱発泡性マイクロスフェアー及びその製造方法 | |
| CN118715302A (zh) | 热膨胀性微小球及其用途 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20080428 |
|
| RD03 | Notification of appointment of power of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7423 Effective date: 20100824 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20110913 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20111019 |
|
| A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20120228 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20120517 Free format text: JAPANESE INTERMEDIATE CODE: A821 Effective date: 20120517 |
|
| A911 | Transfer to examiner for re-examination before appeal (zenchi) |
Free format text: JAPANESE INTERMEDIATE CODE: A911 Effective date: 20120525 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20120710 |
|
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20120713 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 5044074 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20150720 Year of fee payment: 3 |
|
| RD04 | Notification of resignation of power of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: R3D04 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| LAPS | Cancellation because of no payment of annual fees |