DE60235165D1 - Thermisch expandierbare mikrokugel und verfahren zu deren herstellung - Google Patents
Thermisch expandierbare mikrokugel und verfahren zu deren herstellungInfo
- Publication number
- DE60235165D1 DE60235165D1 DE60235165T DE60235165T DE60235165D1 DE 60235165 D1 DE60235165 D1 DE 60235165D1 DE 60235165 T DE60235165 T DE 60235165T DE 60235165 T DE60235165 T DE 60235165T DE 60235165 D1 DE60235165 D1 DE 60235165D1
- Authority
- DE
- Germany
- Prior art keywords
- producing
- thermally expandable
- expandable microbeads
- microbeads
- shell
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000004519 manufacturing process Methods 0.000 title 1
- 239000011325 microbead Substances 0.000 title 1
- 239000004604 Blowing Agent Substances 0.000 abstract 1
- 229920000103 Expandable microsphere Polymers 0.000 abstract 1
- 150000003961 organosilicon compounds Chemical class 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
- B01J13/06—Making microcapsules or microballoons by phase separation
- B01J13/14—Polymerisation; cross-linking
- B01J13/18—In situ polymerisation with all reactants being present in the same phase
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
- B01J13/06—Making microcapsules or microballoons by phase separation
- B01J13/14—Polymerisation; cross-linking
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/50—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by form
- D21H21/52—Additives of definite length or shape
- D21H21/54—Additives of definite length or shape being spherical, e.g. microcapsules, beads
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/59—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2984—Microcapsule with fluid core [includes liposome]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2984—Microcapsule with fluid core [includes liposome]
- Y10T428/2985—Solid-walled microcapsule from synthetic polymer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2991—Coated
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2991—Coated
- Y10T428/2993—Silicic or refractory material containing [e.g., tungsten oxide, glass, cement, etc.]
- Y10T428/2995—Silane, siloxane or silicone coating
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Manufacturing Of Micro-Capsules (AREA)
- Polymerisation Methods In General (AREA)
- Fertilizers (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001174946A JP5044074B2 (ja) | 2001-06-11 | 2001-06-11 | 熱発泡性マイクロスフェアー及びその製造方法 |
| PCT/JP2002/005737 WO2002100971A1 (fr) | 2001-06-11 | 2002-06-10 | Microspheres expansibles a la chaleur et leur procede d'obtention |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE60235165D1 true DE60235165D1 (de) | 2010-03-11 |
Family
ID=19016159
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE60235165T Expired - Lifetime DE60235165D1 (de) | 2001-06-11 | 2002-06-10 | Thermisch expandierbare mikrokugel und verfahren zu deren herstellung |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US7931967B2 (cg-RX-API-DMAC7.html) |
| EP (1) | EP1408097B2 (cg-RX-API-DMAC7.html) |
| JP (1) | JP5044074B2 (cg-RX-API-DMAC7.html) |
| CN (1) | CN100436562C (cg-RX-API-DMAC7.html) |
| AT (1) | ATE455593T1 (cg-RX-API-DMAC7.html) |
| DE (1) | DE60235165D1 (cg-RX-API-DMAC7.html) |
| TW (1) | TWI302567B (cg-RX-API-DMAC7.html) |
| WO (1) | WO2002100971A1 (cg-RX-API-DMAC7.html) |
Families Citing this family (53)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7838037B2 (en) * | 1999-11-17 | 2010-11-23 | Tagra Biotechnologies Ltd. | Method of microencapsulation |
| US6866906B2 (en) | 2000-01-26 | 2005-03-15 | International Paper Company | Cut resistant paper and paper articles and method for making same |
| JP4721596B2 (ja) * | 2001-09-28 | 2011-07-13 | 株式会社クレハ | 低密度発泡紙及びその製造方法 |
| ES2347993T3 (es) | 2002-09-13 | 2010-11-26 | International Paper Company | Papel con rigidez y cuerpo mejorados y método para fabricarlo campo de aplicación de la invención. |
| EP1598405B1 (en) * | 2003-02-24 | 2014-10-01 | Matsumoto Yushi-Seiyaku Co., Ltd. | Thermoexpansible microsphere, process for producing the same and method of use thereof |
| US7828935B2 (en) * | 2003-04-07 | 2010-11-09 | International Paper Company | Papers for liquid electrophotographic printing and method for making same |
| JP4738746B2 (ja) * | 2004-01-20 | 2011-08-03 | セメダイン株式会社 | 耐火構造体用硬化性組成物、シーリング材及びそれを用いた耐火工法 |
| JP4567980B2 (ja) * | 2004-01-26 | 2010-10-27 | 三洋化成工業株式会社 | 熱膨張性マイクロカプセルおよび中空樹脂粒子 |
| US7361399B2 (en) * | 2004-05-24 | 2008-04-22 | International Paper Company | Gloss coated multifunctional printing paper |
| JP2006035092A (ja) * | 2004-07-27 | 2006-02-09 | Sanyo Chem Ind Ltd | 中空樹脂粒子と無機微粒子との混合物の製造方法 |
| JP4217200B2 (ja) * | 2004-09-24 | 2009-01-28 | 積水化学工業株式会社 | 中空樹脂微粒子の製造方法、中空樹脂微粒子、反射防止フィルム用コーティング剤及び反射防止フィルム |
| KR101192031B1 (ko) | 2005-03-11 | 2012-10-16 | 인터내셔널 페이퍼 컴퍼니 | 팽창성 미소구체 및 이온성 화합물을 함유하는 조성물, 및이의 제조 및 사용 방법 |
| JP2006326501A (ja) * | 2005-05-26 | 2006-12-07 | Casio Electronics Co Ltd | 中空マイクロカプセル及びその製造方法 |
| WO2007036981A1 (ja) | 2005-09-27 | 2007-04-05 | Cemedine Co., Ltd. | 硬化性組成物 |
| JP5484673B2 (ja) * | 2005-12-19 | 2014-05-07 | 株式会社クレハ | 熱発泡性マイクロスフェアー、並びにその製造方法と用途 |
| EP1974097B1 (en) | 2006-01-17 | 2017-12-13 | International Paper Company | Paper substrates containing high surface sizing and low internal sizing and having high dimensional stability |
| US8388809B2 (en) | 2006-02-10 | 2013-03-05 | Akzo Nobel N.V. | Microspheres |
| EP1981631B1 (en) * | 2006-02-10 | 2015-09-30 | Akzo Nobel N.V. | Microspheres |
| US7956096B2 (en) | 2006-02-10 | 2011-06-07 | Akzo Nobel N.V. | Microspheres |
| JP5448459B2 (ja) * | 2006-02-10 | 2014-03-19 | アクゾ ノーベル ナムローゼ フェンノートシャップ | 微小球 |
| US7943011B2 (en) * | 2006-05-05 | 2011-05-17 | International Paper Company | Paperboard material with expanded polymeric microspheres |
| PT2274478E (pt) | 2008-03-31 | 2012-10-02 | Int Paper Co | Folha de registo com qualidade de impressão melhorada a baixos niveis de aditivos |
| EP2787120B1 (en) | 2008-06-20 | 2024-10-16 | Global Holdings II, Inc. | Recording sheet with improved optical properties |
| WO2010025383A1 (en) * | 2008-08-28 | 2010-03-04 | International Paper Company | Expandable microspheres and methods of making and using the same |
| US9296244B2 (en) | 2008-09-26 | 2016-03-29 | International Paper Company | Composition suitable for multifunctional printing and recording sheet containing same |
| JP5202284B2 (ja) * | 2008-12-22 | 2013-06-05 | 株式会社日立産機システム | 熱硬化性樹脂組成物 |
| JP2010202805A (ja) * | 2009-03-04 | 2010-09-16 | Sekisui Chem Co Ltd | 熱膨張性マイクロカプセル及び熱膨張性マイクロカプセルの製造方法 |
| EP2529830A3 (en) * | 2009-06-09 | 2014-10-29 | Matsumoto Yushi-Seiyaku Co., Ltd. | Heat-expandable microspheres and a method of making heat-expandable microspheres and application thereof |
| JP5731110B2 (ja) * | 2009-09-18 | 2015-06-10 | 積水化学工業株式会社 | 発泡粒子、発泡性組成物、及び、発泡成形体の製造方法 |
| JP5427529B2 (ja) * | 2009-09-28 | 2014-02-26 | 積水化学工業株式会社 | 発泡粒子及び発泡成形体の製造方法 |
| CN102725689B (zh) | 2010-01-22 | 2014-10-08 | 帝斯曼知识产权资产管理有限公司 | 能固化成具有选择性视觉效果的层的液体可辐射固化树脂及其使用方法 |
| JP5898954B2 (ja) * | 2010-03-31 | 2016-04-06 | 積水化学工業株式会社 | 熱膨張性マイクロカプセル、熱膨張性マイクロカプセルの製造方法、発泡性マスターバッチ及び発泡成形体 |
| JP5825506B2 (ja) * | 2011-02-25 | 2015-12-02 | 横浜ゴム株式会社 | タイヤトレッド用ゴム組成物 |
| JP2013053275A (ja) * | 2011-09-06 | 2013-03-21 | Sekisui Chem Co Ltd | 熱膨張性マイクロカプセルの製造方法 |
| US9206552B2 (en) | 2012-02-17 | 2015-12-08 | International Paper Company | Absorbent plastic pigment with improved print density containing and recording sheet containing same |
| JP5604472B2 (ja) * | 2012-05-17 | 2014-10-08 | 株式会社クレハ | 熱発泡性マイクロスフェアー及びその製造方法 |
| TW201422405A (zh) * | 2012-12-10 | 2014-06-16 | zhi-peng Chen | 球體之一體成型製造方法 |
| ES2581583T3 (es) | 2013-07-29 | 2016-09-06 | Takasago International Corporation | Microcápsulas |
| JP6438214B2 (ja) * | 2014-05-21 | 2018-12-12 | 株式会社クレハ | 熱膨張性マイクロスフェアーの製造方法、該製造方法で製造された熱膨張性マイクロスフェアー、及び該製造方法に用いるコロイダルシリカの判別方法 |
| CN104532475A (zh) * | 2014-12-15 | 2015-04-22 | 梁晋煜 | 一种制作球形立体棉的方法 |
| EP3162434B1 (en) * | 2015-01-08 | 2020-02-26 | Sekisui Plastics Co., Ltd. | Hollow particles |
| CN104788797B (zh) * | 2015-04-03 | 2017-05-03 | 上海杰上杰化学有限公司 | 可发泡树脂粒子及用其制备发泡材料的方法 |
| WO2017002659A1 (ja) | 2015-06-29 | 2017-01-05 | 松本油脂製薬株式会社 | 熱膨張性微小球の製造方法及びその利用 |
| JP6610174B2 (ja) * | 2015-11-06 | 2019-11-27 | コニカミノルタ株式会社 | 中空粒子の製造方法 |
| CN105384958A (zh) * | 2015-12-19 | 2016-03-09 | 仇颖超 | 一种二氧化硅溶胶改性偶氮二甲酰胺发泡剂的制备方法 |
| CN108697595B (zh) * | 2016-02-29 | 2022-01-14 | 积水化成品工业株式会社 | 内含二氧化硅的微胶囊树脂颗粒、其生产方法及其用途 |
| CN111315790B (zh) * | 2017-09-29 | 2024-01-30 | 罗门哈斯公司 | 具有径向变化的颗粒 |
| CN111278874B (zh) * | 2017-09-29 | 2023-12-22 | 罗门哈斯公司 | 制备具有径向变化的颗粒 |
| MX2020009799A (es) * | 2018-03-21 | 2020-10-12 | Nouryon Chemicals Int Bv | Recubrimientos con propiedades reflectantes solares. |
| KR102202059B1 (ko) * | 2018-05-11 | 2021-01-12 | 주식회사 엘지화학 | 고흡수성 수지 시트의 제조 방법 |
| US20220033608A1 (en) | 2018-12-05 | 2022-02-03 | Sabic Global Technologies B.V. | Expandable, shelf stable polymer bead |
| EP3816143B1 (en) | 2019-10-30 | 2023-07-26 | Alloy Surfaces Company, Inc. | Pyrophoric pellets that emit infrared radiation |
| KR20240130713A (ko) * | 2022-01-21 | 2024-08-29 | 마쓰모토유시세이야쿠 가부시키가이샤 | 열팽창성 미소구, 중공 입자 및 이들의 용도 |
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|---|---|---|---|---|
| US3142583A (en) * | 1960-04-05 | 1964-07-28 | Walter M Mcmahon | Inorganic coating composition |
| NL302030A (cg-RX-API-DMAC7.html) * | 1962-12-21 | 1900-01-01 | ||
| US3615972A (en) † | 1967-04-28 | 1971-10-26 | Dow Chemical Co | Expansible thermoplastic polymer particles containing volatile fluid foaming agent and method of foaming the same |
| US3740359A (en) * | 1972-07-10 | 1973-06-19 | Dow Chemical Co | Vinylidene chloride expandable microspheres |
| JPS5846251B2 (ja) * | 1980-07-29 | 1983-10-15 | 日立化成工業株式会社 | 発泡性ビニル系重合体粒子の製造法 |
| DE3129515C2 (de) * | 1980-07-29 | 1986-07-24 | Hitachi Chemical Co., Ltd., Tokio/Tokyo | Schäumbare Styrolharzmasse und Verfahren zu ihrer Herstellung |
| JPS5938241A (ja) * | 1982-08-26 | 1984-03-02 | Sekisui Plastics Co Ltd | 発泡性粒子の製造法 |
| JPS6019033A (ja) | 1983-07-12 | 1985-01-31 | Matsumoto Yushi Seiyaku Kk | 中空マイクロバル−ンおよびその製法 |
| JPS62286534A (ja) | 1986-06-04 | 1987-12-12 | Matsumoto Yushi Seiyaku Kk | 熱膨張性マイクロカプセルの製造法 |
| JPH04202443A (ja) * | 1990-11-30 | 1992-07-23 | Dainippon Ink & Chem Inc | 発泡性ビニル系樹脂粒子の製造方法 |
| JP3012950B2 (ja) * | 1991-04-19 | 2000-02-28 | 永和化成工業株式会社 | 発泡剤組成物 |
| JP3110526B2 (ja) * | 1991-11-08 | 2000-11-20 | 水澤化学工業株式会社 | ハイドロタルサイト被覆粒子、その製法及び樹脂用配合剤 |
| JPH06240040A (ja) | 1993-02-16 | 1994-08-30 | Dainichiseika Color & Chem Mfg Co Ltd | 複合マイクロバルーン及びその製造方法 |
| US5461125A (en) * | 1993-04-30 | 1995-10-24 | Minnesota Mining And Manufacturing Company | Waterborne core-shell latex polymers |
| JPH10176078A (ja) * | 1996-12-20 | 1998-06-30 | Hitachi Chem Co Ltd | 発泡性樹脂粒子およびその製造法 |
| US5834526A (en) | 1997-07-11 | 1998-11-10 | Wu; Huey S. | Expandable hollow particles |
| JPH11181210A (ja) * | 1997-12-17 | 1999-07-06 | Toagosei Co Ltd | 安定化された水性硬化性組成物 |
| JP4620812B2 (ja) | 1998-01-26 | 2011-01-26 | 株式会社クレハ | 発泡性マイクロスフェアーの製造方法 |
| DE69920664T3 (de) | 1998-01-26 | 2008-09-25 | Kureha Corp. | Expandierbare mikrokugeln und herstellungsverfahren dafür |
| DE19810803A1 (de) * | 1998-03-12 | 1999-09-16 | Wacker Chemie Gmbh | Verfahren zur Herstellung mikroverkapselter Produkte mit Organopolysiloxanwänden |
| JPH11335509A (ja) | 1998-05-22 | 1999-12-07 | Toagosei Co Ltd | 水性組成物 |
| JP2000086937A (ja) * | 1998-09-11 | 2000-03-28 | Matsushita Electric Ind Co Ltd | 耐熱性断熱材料と耐熱性断熱材料の製造方法 |
| US7232607B2 (en) | 2000-04-28 | 2007-06-19 | Kureha Corporation | Thermally foamable microsphere and production process thereof |
| US7252882B2 (en) | 2000-04-28 | 2007-08-07 | Kureha Corporation | Thermally foamable microsphere and production process thereof |
| US8088482B2 (en) * | 2001-05-25 | 2012-01-03 | Ip Rights, Llc | Expandable microspheres for foam insulation and methods |
-
2001
- 2001-06-11 JP JP2001174946A patent/JP5044074B2/ja not_active Expired - Fee Related
-
2002
- 2002-06-10 DE DE60235165T patent/DE60235165D1/de not_active Expired - Lifetime
- 2002-06-10 CN CNB028117336A patent/CN100436562C/zh not_active Expired - Fee Related
- 2002-06-10 AT AT02733441T patent/ATE455593T1/de not_active IP Right Cessation
- 2002-06-10 US US10/480,207 patent/US7931967B2/en not_active Expired - Fee Related
- 2002-06-10 WO PCT/JP2002/005737 patent/WO2002100971A1/ja not_active Ceased
- 2002-06-10 EP EP02733441A patent/EP1408097B2/en not_active Expired - Lifetime
- 2002-06-11 TW TW091112607A patent/TWI302567B/zh not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| TWI302567B (cg-RX-API-DMAC7.html) | 2008-11-01 |
| US20040157057A1 (en) | 2004-08-12 |
| JP5044074B2 (ja) | 2012-10-10 |
| EP1408097B2 (en) | 2012-10-10 |
| JP2002363537A (ja) | 2002-12-18 |
| EP1408097A1 (en) | 2004-04-14 |
| CN100436562C (zh) | 2008-11-26 |
| US7931967B2 (en) | 2011-04-26 |
| WO2002100971A1 (fr) | 2002-12-19 |
| ATE455593T1 (de) | 2010-02-15 |
| EP1408097B1 (en) | 2010-01-20 |
| EP1408097A4 (en) | 2006-10-18 |
| CN1514865A (zh) | 2004-07-21 |
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