JP4609319B2 - 光変換用セラミックス複合材料およびその用途 - Google Patents
光変換用セラミックス複合材料およびその用途 Download PDFInfo
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- JP4609319B2 JP4609319B2 JP2005508070A JP2005508070A JP4609319B2 JP 4609319 B2 JP4609319 B2 JP 4609319B2 JP 2005508070 A JP2005508070 A JP 2005508070A JP 2005508070 A JP2005508070 A JP 2005508070A JP 4609319 B2 JP4609319 B2 JP 4609319B2
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- 239000002131 composite material Substances 0.000 title claims description 67
- 239000000919 ceramic Substances 0.000 title claims description 43
- 238000006243 chemical reaction Methods 0.000 title claims description 43
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 62
- 239000011159 matrix material Substances 0.000 claims description 38
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 27
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 22
- 229910044991 metal oxide Inorganic materials 0.000 claims description 21
- 150000004706 metal oxides Chemical class 0.000 claims description 21
- 238000000034 method Methods 0.000 claims description 19
- 238000007711 solidification Methods 0.000 claims description 16
- 230000008023 solidification Effects 0.000 claims description 16
- 229910052684 Cerium Inorganic materials 0.000 claims description 9
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims description 9
- 229910021193 La 2 O 3 Inorganic materials 0.000 claims description 8
- 229910017493 Nd 2 O 3 Inorganic materials 0.000 claims description 8
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 8
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 7
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 5
- -1 MgCr 2 O 4 Inorganic materials 0.000 claims description 4
- 229910015372 FeAl Inorganic materials 0.000 claims description 3
- 229910005191 Ga 2 O 3 Inorganic materials 0.000 claims description 3
- 229910018068 Li 2 O Inorganic materials 0.000 claims description 3
- 229910016583 MnAl Inorganic materials 0.000 claims description 3
- 229910006404 SnO 2 Inorganic materials 0.000 claims description 3
- GEIAQOFPUVMAGM-UHFFFAOYSA-N ZrO Inorganic materials [Zr]=O GEIAQOFPUVMAGM-UHFFFAOYSA-N 0.000 claims description 3
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 claims description 3
- 230000005284 excitation Effects 0.000 claims description 3
- 229910052863 mullite Inorganic materials 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- 230000001590 oxidative effect Effects 0.000 claims 1
- 239000000463 material Substances 0.000 description 18
- 239000000843 powder Substances 0.000 description 12
- 238000002156 mixing Methods 0.000 description 10
- LTPBRCUWZOMYOC-UHFFFAOYSA-N Beryllium oxide Chemical compound O=[Be] LTPBRCUWZOMYOC-UHFFFAOYSA-N 0.000 description 9
- 239000013078 crystal Substances 0.000 description 9
- 239000002994 raw material Substances 0.000 description 8
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 7
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 6
- 239000011247 coating layer Substances 0.000 description 6
- 238000010586 diagram Methods 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 6
- 239000000395 magnesium oxide Substances 0.000 description 6
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 6
- 239000012190 activator Substances 0.000 description 5
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000000155 melt Substances 0.000 description 5
- 238000002844 melting Methods 0.000 description 5
- 230000008018 melting Effects 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 230000006750 UV protection Effects 0.000 description 4
- 230000003213 activating effect Effects 0.000 description 4
- 239000000292 calcium oxide Substances 0.000 description 4
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 4
- 239000010410 layer Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 238000000635 electron micrograph Methods 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 239000011812 mixed powder Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 238000002441 X-ray diffraction Methods 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000000295 emission spectrum Methods 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- 230000005496 eutectics Effects 0.000 description 2
- 230000004907 flux Effects 0.000 description 2
- 239000002223 garnet Substances 0.000 description 2
- 238000005286 illumination Methods 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- 229910001404 rare earth metal oxide Inorganic materials 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- FRWYFWZENXDZMU-UHFFFAOYSA-N 2-iodoquinoline Chemical compound C1=CC=CC2=NC(I)=CC=C21 FRWYFWZENXDZMU-UHFFFAOYSA-N 0.000 description 1
- 229910016036 BaF 2 Inorganic materials 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 229910052691 Erbium Inorganic materials 0.000 description 1
- 229910052693 Europium Inorganic materials 0.000 description 1
- 229910052688 Gadolinium Inorganic materials 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 229910052779 Neodymium Inorganic materials 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229910052771 Terbium Inorganic materials 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 238000000149 argon plasma sintering Methods 0.000 description 1
- OYLGJCQECKOTOL-UHFFFAOYSA-L barium fluoride Chemical compound [F-].[F-].[Ba+2] OYLGJCQECKOTOL-UHFFFAOYSA-L 0.000 description 1
- 229910001632 barium fluoride Inorganic materials 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000002051 biphasic effect Effects 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 150000001785 cerium compounds Chemical class 0.000 description 1
- 229910000420 cerium oxide Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 230000001112 coagulating effect Effects 0.000 description 1
- 150000004696 coordination complex Chemical class 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 1
- 238000007580 dry-mixing Methods 0.000 description 1
- OGPBJKLSAFTDLK-UHFFFAOYSA-N europium atom Chemical compound [Eu] OGPBJKLSAFTDLK-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000007850 fluorescent dye Substances 0.000 description 1
- 230000017525 heat dissipation Effects 0.000 description 1
- 238000005338 heat storage Methods 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- GZCRRIHWUXGPOV-UHFFFAOYSA-N terbium atom Chemical compound [Tb] GZCRRIHWUXGPOV-UHFFFAOYSA-N 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
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Description
(1)金属の酸化物と二種以上の金属の酸化物から生成される複合酸化物とからなる群から選ばれる二種以上の酸化物を夫々成分とする二種以上のマトリックス相から形成されている凝固体であり、各マトリックス相が連続的にかつ三次元的に配列されて相互に絡み合って存在し、該マトリックス相の少なくとも一つが付活された酸化物からなる蛍光体相であることを特徴とする光変換用セラミック複合材料。
(2)凝固体が、一方向凝固法により得られたものであることを特徴とする上記(1)に記載の光変換用セラミック複合材料。
(3)金属酸化物が、Al2O3、MgO、SiO2、TiO2、ZrO2、CaO、Y2O3、BaO、BeO、FeO、Fe2O3、MnO、CoO、Nb2O5、Ta2O5、Cr2O3、SrO、ZnO、NiO、Li2O、Ga2O3、HfO2、ThO2、UO2、SnO2および希土類元素酸化物(La2O3、Y2O3、CeO2、Pr6O11、Nd2O3、Sm2O3、Gd2O3、Eu2O3、Tb4O7、Dy2O3、Ho2O3、Er2O3、Tm2O3、Yb2O3、Lu2O3)からなる群から選択される上記(1)又は(2)のいずれか1項に記載の光変換用セラミック複合材料。
(4)2種以上の金属酸化物の組み合わせで生成される複合酸化物が、3Al2O3・2SiO2(Mullite)、MgO・Al2O3、Al2O3・TiO2、BaO・6Al2O3、BaO・Al2O3、BeO・3Al2O3、BeO・Al2O3、3BeO・Al2O3、CaO・TiO2、CaO・Nb2O3、CaO・ZrO2、2CoO・TiO2、FeAl2O4、MnAl2O4、3MgO・Y2O3、2MgO・SiO2、MgCr2O4、MgO・TiO2、MgO・Ta2O5、MnO・TiO2、2MnO・TiO2、3SrO・Al2O3、SrO・Al2O3、SrO・2Al2O3SrO・6Al2O3、SrO・TiO3、TiO2・3Nb205、TiO2・Nb2O5、3Y2O3・5Al2O3、2Y2O3・Al2O3、2MgO・2Al2O3・5SiO2、LaAlO3、CeAlO3、PrAlO3、NdAlO3、SmAlO3、EuAlO3、GdAlO3、DyAlO3、Yb4Al2O9、Er3Al5O12、11Al2O3・La2O3、11Al2O3・Nd2O3、11Al2O3・Pr2O3、EuAl11O18、2Gd2O3・Al2O3、11Al2O3・Sm2O3、Yb3Al5O12、CeAl11O18、およびEr4Al2O9からなる群から選択される上記(1)又は(2)のいずれか1項に記載の光変換用セラミック複合材料。
(6)付活元素がセリウムであることを特徴とする、上記(1)〜(5)の何れか1項に記載の光変換用セラミック複合材料。
(7)上記(1)〜(7)のいずれか1項に記載の光変換用セラミック複合材料を使用して、発光ダイオードから発光された光の色を別の色に変えることを特徴とする光変換方法。
(8)マトリックスを構成する相がα−Al2O3相及びYAG相であり、YAG相がセリウムで付活された蛍光体である光変換用セラミック複合材料を使用し、青色光を白色光に変えることを特徴とする上記(7)に記載の光変換方法。
(9)発光ダイオードチップと、上記(1)〜(6)のいずれか1項に記載の光変換用セラミック複合材料とを有する発光ダイオード。
(10)光変換用セラミック複合材料が発光ダイオードチップから放出された可視光により励起されて励起波長よりも長波長の可視光の蛍光を出すマトリックス相を含む上記(9)に記載の発光ダイオード。
(11)光変換用セラミック複合材料が発光ダイオードチップから放出された青色光を白色光に変える上記(10)または(11)に記載の発光ダイオード。
以下では、具体的例を挙げ、本発明を更に詳しく説明する。
α−Al2O3粉末(純度99.99%)とY2O3粉末(純度99.999%)の混合比は、モル比で82:18とし、CeO2粉末(純度99.99%)は、仕込み酸化物の反応により生成するYAG1モル対し0.01モルとなるようにした。これらの粉末をエタノール中、ボールミルによって16時間湿式混合した後、エバポレーターを用いてエタノールを脱媒して原料粉末を得た。原料粉末は、真空炉中で予備溶解し一方向凝固の原料とした。
実施例1で作製した光変換用セラミック複合材料から、ダイヤモンドカッターを用いて薄板を切出した。この薄板を加工して図2に示す発光ダイオードに装着できる円盤状の試料を作製し発光ダイオードを作製した。用いた青発光ダイオードチップの波長は470nmである。このようにして得られた白色発光ダイオードの発光スペクトルを図10に示す。約470nmの青色と、光変換用セラミック複合材料から放出された530nmの光が観察された。
Y3Al5O121モル対し、Ceの付活量を0.03モルになるように、Al2O3(99.99%)とY2O3(99.999%)を実施例1で示した方法によって混合、乾燥し原料を得た。この原料100重量部に対しフラックスとして5重量部の弗化バリウム(BaF2)を混合し、アルミナ坩堝にし込み、大気中1600℃1時間の焼成を行った。窒温に戻った坩堝から試料を取出し、これを硝酸溶液で洗浄しフラックスを除去した。このようにして得られたCeを付活したYAG粉末40重量部をエポキシ樹脂100重量部に混練し、120℃1時間、150℃4時間かけて、樹脂を硬化させ成形体を得た。これを円盤状に加工し図2に示す発光ダイオードを作製した。円盤の厚みは、発光ダイオードの発光色が実施例2と同じ色になるように調整した。このようにして決めた円盤の厚みは実施例2のセラミック複合材料の円盤の厚みとほぼ同じであった。発光ダイオードの色はCIE色度図における座標がx=0.27,y=0.36であった。このようにして作製した発光ダイオードの放射エネルギーを380nmから780nmの範囲で積分球を用いて測定した。同様に実施例2に述べた発光ダイオードの放射エネルギーも測定した。このようにして得られた白色発光ダイオードの発光スペクトルを図10に示す。その結果、比較例1を基準にした場合、実施例2の放射エネルギーは約1.5倍となった。このことから本発明における波長変換セラミック複合材料のほうがより光を透過でき、高輝度の発光ダイオードを作製できることが分かる。
Claims (16)
- ある波長の光を吸収してそれとは異なる波長の光である蛍光を発生する一体物の光変換部材であって、該光変換部材が、一方向凝固により得られたものであり、金属の酸化物と二種以上の金属の酸化物から生成される複合酸化物とからなる群から選ばれる二種以上の酸化物を夫々成分とする二種以上のマトリックス相から形成されている凝固体であり、各マトリックス相が連続的にかつ三次元的に配列されて相互に絡み合って存在し、該マトリックス相の少なくとも一つが付活された酸化物からなる蛍光体相であるセラミック複合材料からなることを特徴とする光変換部材。
- 前記セラミック複合材料が可視光により励起されて励起波長よりも長波長の可視光の蛍光を出すマトリックス相を含む請求項1に記載の光変換部材。
- 前記セラミック複合材料が青色光を白色光に変える請求項1に記載の光変換部材。
- 金属酸化物が、Al2O3、MgO、SiO2、TiO2、ZrO2、CaO、Y2O3、BaO、BeO、FeO、Fe2O3、MnO、CoO、Nb2O5、Ta2O5、Cr2O3、SrO、ZnO、NiO、Li2O、Ga2O3、HfO2、ThO2、UO2、SnO2および希土類元素酸化物(La2O3、Y2O3、CeO2、Pr6O11、Nd2O3、Sm2O3、Gd2O3、Eu2O3、Tb4O7、Dy2O3、Ho2O3、Er2O3、Tm2O3、Yb2O3、Lu2O3)からなる群から選択される請求項1〜3のいずれか1項に記載の光変換部材。
- 2種以上の金属酸化物の組み合わせで生成される複合酸化物が、3Al2O3・2SiO2(Mullite)、MgO・Al2O3、Al2O3・TiO2、BaO・6Al2O3、BaO・Al2O3、BeO・3Al2O3、BeO・Al2O3、3BeO・Al2O3、CaO・TiO2、CaO・Nb2O3、CaO・ZrO2、2CoO・TiO2、FeAl2O4、MnAl2O4、3MgO・Y2O3、2MgO・SiO2、MgCr2O4、MgO・TiO2、MgO・Ta2O5、MnO・TiO2、2MnO・TiO2、3SrO・Al2O3、SrO・Al2O3、SrO・2Al2O3SrO・6Al2O3、SrO・TiO3、TiO2・3Nb2O5、TiO2・Nb2O5、3Y2O3・5Al2O3、2Y2O3・Al2O3、2MgO・2Al2O3・5SiO2、LaAlO3、CeAlO3、PrAlO3、NdAlO3、SmAlO3、EuAlO3、GdAlO3、DyAlO3、Yb4Al2O9、Er3Al5O12、11Al2O3・La2O3、11Al2O3・Nd2O3、11Al2O3・Pr2O3、EuAl11O18、2Gd2O3・Al2O3、11Al2O3・Sm2O3、Yb3Al5O12、CeAl11O18、およびEr4Al2O9からなる群から選択される請求項1〜3のいずれか1項に記載の光変換部材。
- マトリックスを構成する相がα−Al2O3相及びY3Al5O12(YAG)相の2相であることを特徴とする、請求項1〜3のいずれか1項に記載の光変換部材。
- 前記光変換部材が板状である請求項1〜6のいずれか1項に記載の光変換部材。
- 発光ダイオードチップと、発光ダイオードチップへ電流を供給する電極と、発光ダイオードの光放出側に配置され発光ダイオードチップから発光された光の色を別の色に変える光変換部材とを有する発光ダイオードであって、前記光変換部材が、一方向凝固により得られたものであり、金属の酸化物と二種以上の金属の酸化物から生成される複合酸化物とからなる群から選ばれる二種以上の酸化物を夫々成分とする二種以上のマトリックス相から形成されている凝固体であり、各マトリックス相が連続的にかつ三次元的に配列されて相互に絡み合って存在し、該マトリックス相の少なくとも一つが付活された酸化物からなる蛍光体相である光変換用セラミック複合材料の本体(body)からなることを特徴とする発光ダイオード。
- 前記光変換用セラミック複合材料が発光ダイオードチップから放出された可視光により励起されて励起波長よりも長波長の可視光の蛍光を出すマトリックス相を含む請求項8に記載の発光ダイオード。
- 前記光変換用セラミック複合材料が発光ダイオードチップから放出された青色光を白色光に変える請求項8または9に記載の発光ダイオード。
- 金属酸化物が、Al2O3、MgO、SiO2、TiO2、ZrO2、CaO、Y2O3、BaO、BeO、FeO、Fe2O3、MnO、CoO、Nb2O5、Ta2O5、Cr2O3、SrO、ZnO、NiO、Li2O、Ga2O3、HfO2、ThO2、UO2、SnO2および希土類元素酸化物(La2O3、Y2O3、CeO2、Pr6O11、Nd2O3、Sm2O3、Gd2O3、Eu2O3、Tb4O7、Dy2O3、Ho2O3、Er2O3、Tm2O3、Yb2O3、Lu2O3)からなる群から選択される請求項8〜10のいずれか1項に記載の発光ダイオード。
- 2種以上の金属酸化物の組み合わせで生成される複合酸化物が、3Al2O3・2SiO2(Mullite)、MgO・Al2O3、Al2O3・TiO2、BaO・6Al2O3、BaO・Al2O3、BeO・3Al2O3、BeO・Al2O3、3BeO・Al2O3、CaO・TiO2、CaO・Nb2O3、CaO・ZrO2、2CoO・TiO2、FeAl2O4、MnAl2O4、3MgO・Y2O3、2MgO・SiO2、MgCr2O4、MgO・TiO2、MgO・Ta2O5、MnO・TiO2、2MnO・TiO2、3SrO・Al2O3、SrO・Al2O3、SrO・2Al2O3SrO・6Al2O3、SrO・TiO3、TiO2・3Nb2O5、TiO2・Nb2O5、3Y2O3・5Al2O3、2Y2O3・Al2O3、2MgO・2Al2O3・5SiO2、LaAlO3、CeAlO3、PrAlO3、NdAlO3、SmAlO3、EuAlO3、GdAlO3、DyAlO3、Yb4Al2O9、Er3Al5O12、11Al2O3・La2O3、11Al2O3・Nd2O3、11Al2O3・Pr2O3、EuAl11O18、2Gd2O3・Al2O3、11Al2O3・Sm2O3、Yb3Al5O12、CeAl11O18、およびEr4Al2O9からなる群から選択される請求項8〜11のいずれか1項に記載の発光ダイオード。
- マトリックスを構成する相がα−Al2O3相及びY3Al5O12(YAG)相の2相であることを特徴とする、請求項8〜10のいずれか1項に記載の発光ダイオード。
- 前記光変換部材が板状である請求項8〜10のいずれか1項に記載の発光ダイオード。
- 請求項8〜14のいずれか1項に記載の発光ダイオードを使用して、発光ダイオードチップから発光された光の色を別の色に変えることを特徴とする光変換方法。
- 請求項15の光変換方法において、マトリックスを構成する相がα−Al2O3相及びYAG相であり、YAG相がセリウムで付活された蛍光体である光変換用セラミック複合材料を使用し、青色光を白色光に変えることを特徴とする光変換方法。
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JP2003010887 | 2003-01-20 | ||
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PCT/JP2004/000371 WO2004065324A1 (ja) | 2003-01-20 | 2004-01-19 | 光変換用セラミックス複合材料およびその用途 |
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EP (2) | EP1588991B1 (ja) |
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KR (1) | KR100639647B1 (ja) |
CN (2) | CN1738781A (ja) |
TW (1) | TWI314364B (ja) |
WO (1) | WO2004065324A1 (ja) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
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Families Citing this family (95)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
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JP2017202962A (ja) * | 2016-05-13 | 2017-11-16 | 宇部興産株式会社 | 光変換用セラミックス複合材料、その製造方法、およびそれを備えた発光装置 |
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DE102017101729A1 (de) * | 2017-01-30 | 2018-08-02 | Osram Opto Semiconductors Gmbh | Strahlungsemittierende Vorrichtung |
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2000272955A (ja) * | 1999-03-26 | 2000-10-03 | Ube Ind Ltd | 希土類選択エミッター材料 |
JP2001328871A (ja) * | 2000-05-17 | 2001-11-27 | Univ Osaka | 高融点材料からなる成形体の製造方法 |
JP2002252372A (ja) * | 2001-02-26 | 2002-09-06 | Nichia Chem Ind Ltd | 発光ダイオード |
JP2003521435A (ja) * | 2000-02-02 | 2003-07-15 | スリーエム イノベイティブ プロパティズ カンパニー | 溶融Al2O3−希土類酸化物共晶研磨粒子、研磨物品、ならびにそれらの製造方法および使用方法 |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3691482A (en) * | 1970-01-19 | 1972-09-12 | Bell Telephone Labor Inc | Display system |
HU200033B (en) * | 1988-03-28 | 1990-03-28 | Tungsram Reszvenytarsasag | Method for making luminous powder in yellow-green range and mercury vapour gas-discharge lamp containing the said powder |
JP3216683B2 (ja) | 1993-10-08 | 2001-10-09 | 宇部興産株式会社 | セラミックス複合材料 |
US5484752A (en) | 1993-11-12 | 1996-01-16 | Ube Industries, Ltd. | Ceramic composite material |
JP3264106B2 (ja) | 1993-11-12 | 2002-03-11 | 宇部興産株式会社 | セラミックス複合材料 |
JP3128044B2 (ja) | 1993-11-12 | 2001-01-29 | 宇部興産株式会社 | セラミックス複合材料 |
US5902763A (en) * | 1995-01-19 | 1999-05-11 | Ube Industries, Inc. | Fused ceramic composite |
JP3412379B2 (ja) | 1995-01-19 | 2003-06-03 | 宇部興産株式会社 | セラミックス複合材料 |
JP3412378B2 (ja) | 1995-01-19 | 2003-06-03 | 宇部興産株式会社 | セラミックス複合材料 |
JP3412381B2 (ja) | 1995-01-19 | 2003-06-03 | 宇部興産株式会社 | セラミックス複合材料 |
CN1211312C (zh) * | 1996-07-01 | 2005-07-20 | 宇部兴产株式会社 | 陶瓷复合材料和多孔陶瓷材料及其生产方法 |
TW383508B (en) | 1996-07-29 | 2000-03-01 | Nichia Kagaku Kogyo Kk | Light emitting device and display |
WO2001024284A1 (en) * | 1999-09-27 | 2001-04-05 | Lumileds Lighting, U.S., Llc | A light emitting diode device that produces white light by performing complete phosphor conversion |
JP4151284B2 (ja) | 2001-03-05 | 2008-09-17 | 日亜化学工業株式会社 | 窒化物半導体発光素子及び発光装置並びにそれらの製造方法 |
-
2004
- 2004-01-19 US US10/542,569 patent/US8900480B2/en active Active
- 2004-01-19 EP EP04703258.6A patent/EP1588991B1/en not_active Expired - Lifetime
- 2004-01-19 EP EP12169462.4A patent/EP2497758B1/en not_active Expired - Lifetime
- 2004-01-19 CN CNA2004800024937A patent/CN1738781A/zh active Pending
- 2004-01-19 KR KR1020057013293A patent/KR100639647B1/ko active IP Right Grant
- 2004-01-19 WO PCT/JP2004/000371 patent/WO2004065324A1/ja active Application Filing
- 2004-01-19 CN CNA2009101280225A patent/CN101555128A/zh active Pending
- 2004-01-19 JP JP2005508070A patent/JP4609319B2/ja not_active Expired - Lifetime
- 2004-01-20 TW TW093101621A patent/TWI314364B/zh active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2000272955A (ja) * | 1999-03-26 | 2000-10-03 | Ube Ind Ltd | 希土類選択エミッター材料 |
JP2003521435A (ja) * | 2000-02-02 | 2003-07-15 | スリーエム イノベイティブ プロパティズ カンパニー | 溶融Al2O3−希土類酸化物共晶研磨粒子、研磨物品、ならびにそれらの製造方法および使用方法 |
JP2001328871A (ja) * | 2000-05-17 | 2001-11-27 | Univ Osaka | 高融点材料からなる成形体の製造方法 |
JP2002252372A (ja) * | 2001-02-26 | 2002-09-06 | Nichia Chem Ind Ltd | 発光ダイオード |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2016503497A (ja) * | 2012-11-07 | 2016-02-04 | ロレックス・ソシエテ・アノニムRolex Sa | 時計構成要素 |
KR20190047078A (ko) | 2016-10-28 | 2019-05-07 | 니뽄 도쿠슈 도교 가부시키가이샤 | 광 파장 변환 부재의 제조 방법, 광 파장 변환 부재, 광 파장 변환 부품, 및 발광 장치 |
US10910524B2 (en) | 2016-10-28 | 2021-02-02 | Ngk Spark Plug Co.. Ltd. | Light wavelength conversion member and light emitting device |
US11063186B2 (en) | 2016-10-28 | 2021-07-13 | Ngk Spark Plug Co., Ltd. | Method for producing light wavelength conversion member, light wavelength conversion member, light wavelength conversion component and light emitting device |
Also Published As
Publication number | Publication date |
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CN101555128A (zh) | 2009-10-14 |
WO2004065324A1 (ja) | 2004-08-05 |
KR20050093839A (ko) | 2005-09-23 |
EP2497758B1 (en) | 2019-05-29 |
TWI314364B (en) | 2009-09-01 |
EP1588991A4 (en) | 2011-05-18 |
EP2497758A3 (en) | 2016-05-25 |
US8900480B2 (en) | 2014-12-02 |
EP1588991B1 (en) | 2019-04-17 |
KR100639647B1 (ko) | 2006-11-01 |
JPWO2004065324A1 (ja) | 2006-05-18 |
US20060124951A1 (en) | 2006-06-15 |
EP1588991A1 (en) | 2005-10-26 |
CN1738781A (zh) | 2006-02-22 |
EP2497758A2 (en) | 2012-09-12 |
TW200425540A (en) | 2004-11-16 |
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