JP4559004B2 - ジルコニアゾル及びその製造方法 - Google Patents
ジルコニアゾル及びその製造方法 Download PDFInfo
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- JP4559004B2 JP4559004B2 JP2001533062A JP2001533062A JP4559004B2 JP 4559004 B2 JP4559004 B2 JP 4559004B2 JP 2001533062 A JP2001533062 A JP 2001533062A JP 2001533062 A JP2001533062 A JP 2001533062A JP 4559004 B2 JP4559004 B2 JP 4559004B2
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- Prior art keywords
- zirconia
- sol
- acid
- polyether
- zro
- Prior art date
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- UJVRJBAUJYZFIX-UHFFFAOYSA-N nitric acid;oxozirconium Chemical compound [Zr]=O.O[N+]([O-])=O.O[N+]([O-])=O UJVRJBAUJYZFIX-UHFFFAOYSA-N 0.000 description 1
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- FZUGPQWGEGAKET-UHFFFAOYSA-N parbenate Chemical compound CCOC(=O)C1=CC=C(N(C)C)C=C1 FZUGPQWGEGAKET-UHFFFAOYSA-N 0.000 description 1
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- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/0004—Preparation of sols
- B01J13/0008—Sols of inorganic materials in water
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G25/00—Compounds of zirconium
- C01G25/02—Oxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2244—Oxides; Hydroxides of metals of zirconium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Nanotechnology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Composite Materials (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Dispersion Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/428,374 | 1999-10-28 | ||
| US09/428,374 US6376590B2 (en) | 1999-10-28 | 1999-10-28 | Zirconia sol, process of making and composite material |
| PCT/US2000/008796 WO2001030702A1 (en) | 1999-10-28 | 2000-04-03 | Zirconia sol and process of making same |
Publications (3)
| Publication Number | Publication Date |
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| JP2003512287A JP2003512287A (ja) | 2003-04-02 |
| JP2003512287A5 JP2003512287A5 (cg-RX-API-DMAC7.html) | 2007-04-12 |
| JP4559004B2 true JP4559004B2 (ja) | 2010-10-06 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2001533062A Expired - Fee Related JP4559004B2 (ja) | 1999-10-28 | 2000-04-03 | ジルコニアゾル及びその製造方法 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US6376590B2 (cg-RX-API-DMAC7.html) |
| EP (1) | EP1232118B1 (cg-RX-API-DMAC7.html) |
| JP (1) | JP4559004B2 (cg-RX-API-DMAC7.html) |
| AU (1) | AU4065200A (cg-RX-API-DMAC7.html) |
| CA (1) | CA2388876C (cg-RX-API-DMAC7.html) |
| DE (1) | DE60023023T2 (cg-RX-API-DMAC7.html) |
| WO (1) | WO2001030702A1 (cg-RX-API-DMAC7.html) |
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| CN113165900A (zh) * | 2018-11-30 | 2021-07-23 | 马蒂姆有限公司 | 一种在氨基酸存在下制备二氧化锆纳米颗粒的方法 |
| CN114656818A (zh) * | 2020-12-03 | 2022-06-24 | 凯斯科技股份有限公司 | 金属氧化物分散液 |
| CN115124074A (zh) * | 2022-07-26 | 2022-09-30 | 宣城市晶纳环保科技有限公司 | 一种高分散复合纳米二氧化锆的制备方法 |
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| KR101432853B1 (ko) | 2006-12-21 | 2014-08-26 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 나노입자의 제조 방법 |
| JP4315195B2 (ja) * | 2006-12-21 | 2009-08-19 | ソニー株式会社 | 硬化性樹脂材料−微粒子複合材料及びその製造方法、光学材料、並びに発光装置 |
| WO2008083275A2 (en) * | 2006-12-28 | 2008-07-10 | 3M Innovative Properties Company | Dental filler and methods |
| CN101573308B (zh) | 2006-12-29 | 2016-11-09 | 3M创新有限公司 | 氧化锆主体以及方法 |
| US7709092B2 (en) * | 2007-01-19 | 2010-05-04 | 3M Innovative Properties Company | Solar control multilayer film |
| JP2008201634A (ja) * | 2007-02-21 | 2008-09-04 | Fujifilm Corp | ジルコニア微粒子分散液、該分散剤から製造される有機無機複合材料および光学部品 |
| US7939578B2 (en) * | 2007-02-23 | 2011-05-10 | 3M Innovative Properties Company | Polymeric fibers and methods of making |
| KR20090125786A (ko) | 2007-02-27 | 2009-12-07 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 개선된 내균열성을 갖는 나노복합 구조체를 포함하는 휘도 향상 필름 |
| EP2142478B1 (fr) * | 2007-04-04 | 2011-05-25 | Essilor International (Compagnie Générale D'Optique) | Procede de preparation d'une solution colloïdale de zircone |
| US20080254258A1 (en) * | 2007-04-12 | 2008-10-16 | Altairnano, Inc. | Teflon® replacements and related production methods |
| US8513322B2 (en) * | 2007-05-31 | 2013-08-20 | 3M Innovative Properties Company | Polymeric beads and methods of making polymeric beads |
| DE102007036998A1 (de) | 2007-08-06 | 2009-02-19 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Verfahren zur Herstellung von amorphen metallorganischen Makromolekülen, mit diesem Verfahren erhaltenes Material und seine Verwendung |
| JP2009137774A (ja) * | 2007-12-03 | 2009-06-25 | Sumitomo Osaka Cement Co Ltd | ジルコニア粒子とその製造方法及びジルコニア透明分散液、並びに透明複合体及びその製造方法 |
| BRPI0820705A2 (pt) * | 2007-12-12 | 2014-10-07 | 3M Innovative Properties Co | Filme antimicrobiano microestruturado |
| WO2009076572A2 (en) | 2007-12-12 | 2009-06-18 | 3M Innovative Properties Company | Methods of making an article and articles |
| JP2011508019A (ja) * | 2007-12-21 | 2011-03-10 | スリーエム イノベイティブ プロパティズ カンパニー | 混合型配位子表面改質ナノ粒子 |
| WO2009085926A2 (en) * | 2007-12-28 | 2009-07-09 | 3M Innovative Properties Company | Method of making zirconia-containing nanoparticles |
| WO2009088043A1 (ja) * | 2008-01-09 | 2009-07-16 | Asahi Glass Company, Limited | 表面修飾ジルコニア粒子、その製造方法及び樹脂組成物 |
| FR2927005B1 (fr) * | 2008-02-05 | 2011-12-23 | Commissariat Energie Atomique | Materiau hybride organique-inorganique, couche mince optique de ce materiau, materiau optique les comprenant, et leur procede de fabrication |
| JP5037393B2 (ja) * | 2008-03-12 | 2012-09-26 | 富士フイルム株式会社 | 金属酸化物微粒子分散液及び成形体 |
| US7981986B2 (en) * | 2008-04-29 | 2011-07-19 | 3M Innovative Properties Company | Optical films comprising fluorenol (meth)acrylate monomer |
| US20090275720A1 (en) * | 2008-04-30 | 2009-11-05 | 3M Innovative Properties Company | Ortho-benzylphenol mono(meth)acrylate monomers suitable for microstructured optical films |
| JP5701474B2 (ja) * | 2008-06-13 | 2015-04-15 | 富士フイルム株式会社 | 無機微粒子分散液、有機無機複合組成物、成形体および光学部品 |
| US8343622B2 (en) * | 2008-07-01 | 2013-01-01 | 3M Innovative Properties Company | Flexible high refractive index hardcoat |
| US8611010B2 (en) * | 2008-09-30 | 2013-12-17 | 3M Innovative Properties Company | Substrate comprising unmatched refractive index primer at optically significant thickness |
| EP2370362B1 (en) | 2008-10-15 | 2013-11-27 | 3M Innovative Properties Company | Fillers and composite materials with zirconia and silica nanoparticles |
| JP5397829B2 (ja) * | 2008-12-04 | 2014-01-22 | 堺化学工業株式会社 | 酸化ジルコニウム分散液の製造方法 |
| JP5407324B2 (ja) * | 2008-12-24 | 2014-02-05 | 堺化学工業株式会社 | 酸化ジルコニウム分散液の製造方法 |
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| CN106185793A (zh) | 2008-12-30 | 2016-12-07 | 3M创新有限公司 | 纳米结构化制品和制备纳米结构化制品的方法 |
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| CN102686517B (zh) * | 2009-12-29 | 2015-01-07 | 3M创新有限公司 | 掺杂镧系元素的氧化锆基粒子 |
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| SG185417A1 (en) | 2010-05-07 | 2012-12-28 | 3M Innovative Properties Co | Antireflective films comprising microstructured surface |
| KR101639082B1 (ko) * | 2010-10-20 | 2016-07-13 | 코오롱인더스트리 주식회사 | 광중합성 조성물 및 이로부터 형성된 수지 경화층을 포함하는 광학시트 |
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| JP2014509291A (ja) * | 2010-12-22 | 2014-04-17 | スリーエム イノベイティブ プロパティズ カンパニー | 表面修飾ジルコニアナノ粒子 |
| KR101862899B1 (ko) | 2011-02-04 | 2018-05-30 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 산화지르코늄 나노입자를 포함하는 비결정성 퍼플루오로중합체 |
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| JP6014057B2 (ja) | 2011-03-14 | 2016-10-25 | スリーエム イノベイティブ プロパティズ カンパニー | 多層のナノ構造化物品 |
| WO2012125324A1 (en) | 2011-03-14 | 2012-09-20 | 3M Innovative Properties Company | Nanostructured articles |
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| EP2958858B1 (en) * | 2012-12-26 | 2020-11-25 | Essilor International | Method for producing zirconia colloids |
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| GB201518996D0 (en) * | 2015-10-27 | 2015-12-09 | Magnesium Elektron Ltd | Zirconia-based compositions for use as three-way catalysts |
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| JP7898379B2 (ja) * | 2020-02-26 | 2026-07-31 | ケアフュージョン・コーポレイション | ヨードフォア組成物を滅菌するためのシステム及び方法 |
| WO2021217044A1 (en) | 2020-04-23 | 2021-10-28 | Saint-Gobain Abrasives, Inc. | System and method for conducting an abrasive operation |
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| US12064850B2 (en) | 2021-12-30 | 2024-08-20 | Saint-Gobain Abrasives, Inc. | Abrasive articles and methods for forming same |
| WO2024121658A1 (en) | 2022-12-06 | 2024-06-13 | Solventum Intellectual Properties Company | Surface-treated filler, dental composition containing such a filler, process of production and use thereof |
| CN116102060A (zh) * | 2023-02-10 | 2023-05-12 | 广州市汉宵科研技术有限公司 | 一种纳米级氧化锆颗粒材料及其制备方法 |
Family Cites Families (100)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2984628A (en) | 1956-11-29 | 1961-05-16 | Du Pont | Concentrated zirconia and hafnia aquasols and their preparation |
| US3018262A (en) | 1957-05-01 | 1962-01-23 | Shell Oil Co | Curing polyepoxides with certain metal salts of inorganic acids |
| US3066112A (en) | 1959-01-30 | 1962-11-27 | Rafael L Bowen | Dental filling material comprising vinyl silane treated fused silica and a binder consisting of the reaction product of bis phenol and glycidyl acrylate |
| NL298323A (cg-RX-API-DMAC7.html) | 1959-12-24 | |||
| US3442817A (en) | 1966-04-15 | 1969-05-06 | Du Pont | Preparation of zirconia and hafnia sols |
| US3514252A (en) | 1967-07-07 | 1970-05-26 | Grace W R & Co | Process for the preparation of stabilized zirconia powders |
| US3860556A (en) | 1968-03-15 | 1975-01-14 | Minnesota Mining & Mfg | Low water absorption dental restorative |
| US3539533A (en) | 1968-06-14 | 1970-11-10 | Johnson & Johnson | Dental filling material |
| US3708296A (en) | 1968-08-20 | 1973-01-02 | American Can Co | Photopolymerization of epoxy monomers |
| US3709706A (en) | 1969-05-16 | 1973-01-09 | Minnesota Mining & Mfg | Refractory fibers and other articles of zirconia and silica mixtures |
| US3629187A (en) | 1969-06-25 | 1971-12-21 | Dentsply Int Inc | Dental compositions containing adduct of 2 2' - propane bis 3-(4-phenoxy)-1 2-hydroxy propane - 1 - methacrylate and isocyanate |
| US3709866A (en) | 1970-06-01 | 1973-01-09 | Dentsply Int Inc | Photopolymerizable dental products |
| US3766132A (en) | 1971-02-12 | 1973-10-16 | Lee Pharmaceuticals | Diacrylate esters of low viscosity and the use thereof as binders in dental restorative compositions |
| US3751399A (en) | 1971-05-24 | 1973-08-07 | Lee Pharmaceuticals | Polyacrylate resin compositions |
| US3729113A (en) | 1971-07-08 | 1973-04-24 | Reflector Hardware Corp | Modular cabinet assembly, and components and subassemblies therefor |
| GB1408265A (en) | 1971-10-18 | 1975-10-01 | Ici Ltd | Photopolymerisable composition |
| US3808006A (en) | 1971-12-06 | 1974-04-30 | Minnesota Mining & Mfg | Photosensitive material containing a diaryliodium compound, a sensitizer and a color former |
| US3741769A (en) | 1972-10-24 | 1973-06-26 | Minnesota Mining & Mfg | Novel photosensitive polymerizable systems and their use |
| DE2406557C3 (de) | 1974-02-12 | 1981-02-19 | Kulzer & Co Gmbh, 6380 Bad Homburg | Hydroxyl-Gruppen enthaltende Diester von Acrylsäuren und diese enthaltendes Zahnfüllungsmaterial |
| US4115346A (en) | 1974-02-12 | 1978-09-19 | Kulzer & Co. Gmbh | Hydroxy group containing diesters of acrylic acids and their use in dental material |
| AU497960B2 (en) | 1974-04-11 | 1979-01-25 | Minnesota Mining And Manufacturing Company | Photopolymerizable compositions |
| GB1512981A (en) | 1974-05-02 | 1978-06-01 | Gen Electric | Curable epoxide compositions |
| US4250311A (en) | 1974-05-02 | 1981-02-10 | General Electric Company | P, As, and Sb hexafluoride onium salts as photoinitiators |
| GB1569021A (en) | 1976-03-17 | 1980-06-11 | Kuraray Co | Adhesive cementing agents containing partial phosphonic orphosphonic acid esters |
| JPS5940953B2 (ja) * | 1977-11-30 | 1984-10-03 | 東邦化学工業株式会社 | ポリエステル系合成繊維の染色法 |
| US4292029A (en) | 1978-05-15 | 1981-09-29 | University Of Michigan | Hydrophobic composite restorative materials and their use in tooth treatment |
| US4387240A (en) | 1978-06-02 | 1983-06-07 | Minnesota Mining And Manufacturing Company | Oligomeric methacryl substituted alkylsiloxanes |
| US4216288A (en) | 1978-09-08 | 1980-08-05 | General Electric Company | Heat curable cationically polymerizable compositions and method of curing same with onium salts and reducing agents |
| DE2850917A1 (de) | 1978-11-24 | 1980-06-04 | Bayer Ag | Dentalwerkstoffe auf basis von organischen kunststoffen in pastoeser form |
| US4327014A (en) | 1979-04-11 | 1982-04-27 | Kanebo Ltd. | Resin-forming material, implant material and compositions for restorative material suitable for medical or dental use |
| US4250053A (en) | 1979-05-21 | 1981-02-10 | Minnesota Mining And Manufacturing Company | Sensitized aromatic iodonium or aromatic sulfonium salt photoinitiator systems |
| US4379695A (en) | 1980-06-02 | 1983-04-12 | Scientific Pharmaceuticals, Inc. | Dental material comprising dimethyacrylate adducts of glycidyl methacrylate with diesters of bis(hydroxymethyl) tricyclo[5.2.1.02,6 ]decane and dicarboxylic acids |
| JPS5828878B2 (ja) | 1980-08-20 | 1983-06-18 | 三金工業株式会社 | 環状ピロ燐酸エステル誘導体 |
| EP0060911B1 (de) | 1981-03-24 | 1985-06-19 | Blendax-Werke R. Schneider GmbH & Co. | Dentales Füllungsmaterial |
| EP0094915B1 (de) | 1982-05-19 | 1987-01-21 | Ciba-Geigy Ag | Härtbare, Metallocenkomplexe enthaltende Zusammensetzungen, daraus erhältliche aktivierte Vorstufen und deren Verwendung |
| US5089536A (en) | 1982-11-22 | 1992-02-18 | Minnesota Mining And Manufacturing Company | Energy polmerizable compositions containing organometallic initiators |
| US5073476A (en) | 1983-05-18 | 1991-12-17 | Ciba-Geigy Corporation | Curable composition and the use thereof |
| US4545924A (en) | 1983-06-13 | 1985-10-08 | Owens-Corning Fiberglas Corporation | Production of a magnesium chloride gel system useful in ceramics and fiber production |
| US4612138A (en) * | 1983-08-04 | 1986-09-16 | Nalco Chemical Company | Stable acidic and alkaline metal oxide sols |
| DE3341888A1 (de) | 1983-11-19 | 1985-05-30 | Bayer Ag, 5090 Leverkusen | Anorganisch-organische fuellstoffe, verfahren zu deren herstellung sowie deren verwendung in polymerisierbaren massen |
| DE3342601C1 (de) | 1983-11-25 | 1985-03-14 | Blendax-Werke R. Schneider Gmbh & Co, 6500 Mainz | Verwendung von bromierten aromatischen Diacrylsaeure- bzw. Dimethacrylsaeureestern in dentalen Fuellungsmaterialien |
| US4544359A (en) | 1984-01-13 | 1985-10-01 | Pentron Corporation | Dental restorative material |
| DE3403040A1 (de) | 1984-01-30 | 1985-08-08 | Blendax-Werke R. Schneider Gmbh & Co, 6500 Mainz | Dentales fuellungsmaterial |
| US4503169A (en) | 1984-04-19 | 1985-03-05 | Minnesota Mining And Manufacturing Company | Radiopaque, low visual opacity dental composites containing non-vitreous microparticles |
| US4746685A (en) | 1984-08-31 | 1988-05-24 | Nippon Oil And Fats Co., Ltd. | Light curable dental composition |
| DE3443221A1 (de) | 1984-11-27 | 1986-06-05 | ESPE Fabrik pharmazeutischer Präparate GmbH, 8031 Seefeld | Bisacylphosphinoxide, ihre herstellung und verwendung |
| US4661540A (en) | 1984-12-06 | 1987-04-28 | Berger, Jenson & Nicholson Limited | Water reducible coating compositions |
| EP0184467A3 (en) | 1984-12-06 | 1988-06-08 | Berger, Jenson and Nicholson Limited | Water reducible coating compositions |
| US4642126A (en) | 1985-02-11 | 1987-02-10 | Norton Company | Coated abrasives with rapidly curable adhesives and controllable curvature |
| US4619817A (en) | 1985-03-27 | 1986-10-28 | Battelle Memorial Institute | Hydrothermal method for producing stabilized zirconia |
| US4652274A (en) | 1985-08-07 | 1987-03-24 | Minnesota Mining And Manufacturing Company | Coated abrasive product having radiation curable binder |
| US4772530A (en) | 1986-05-06 | 1988-09-20 | The Mead Corporation | Photosensitive materials containing ionic dye compounds as initiators |
| US4772511A (en) | 1985-11-22 | 1988-09-20 | Minnesota Mining And Manufacturing Company | Transparent non-vitreous zirconia microspheres |
| JPH0729771B2 (ja) | 1986-01-14 | 1995-04-05 | 悦朗 加藤 | 単斜ジルコニア超微結晶の高分散ゾルまたはゲルおよび製造方法 |
| JPS62260718A (ja) | 1986-05-06 | 1987-11-13 | Shigeyuki Somiya | 水熱法による高純度ジルコニア−アルミナ系超微粉末の製造方法 |
| US4719091A (en) | 1986-07-01 | 1988-01-12 | Corning Glass Works | Preparation of mono-sized zirconia powders by forced hydrolysis |
| US4778671A (en) | 1986-07-14 | 1988-10-18 | Corning Glass Works | Preparation of unagglomerated metal oxide particles with uniform particle size |
| AU601491B2 (en) | 1986-09-27 | 1990-09-13 | Nissan Chemical Industries Ltd. | Process for manufacturing fine zirconium oxide powder |
| US4874450A (en) | 1987-01-29 | 1989-10-17 | The Mead Corporation | Laminating transparent or translucent materials using ionic dye-counter ion complexes |
| US4927560A (en) | 1987-02-25 | 1990-05-22 | Nippon Shokubai Kagaku Kogyo Co., Ltd. | Method for production of inorganic minute globular particles |
| CA1323949C (en) | 1987-04-02 | 1993-11-02 | Michael C. Palazzotto | Ternary photoinitiator system for addition polymerization |
| US4886624A (en) | 1987-08-19 | 1989-12-12 | Rhone-Poulenc, Inc. | Colloidal alcohol-dispersible association complexes of ceric dioxide and a hydroxyphenyl carboxylic acid |
| FR2629071B1 (fr) * | 1988-03-22 | 1991-03-15 | Produits Refractaires | Oxyde de zirconium reactif et sa preparation |
| US4985340A (en) | 1988-06-01 | 1991-01-15 | Minnesota Mining And Manufacturing Company | Energy curable compositions: two component curing agents |
| US5234870A (en) | 1988-07-21 | 1993-08-10 | Nippon Shokubai Kagaku Kogyo Co., Ltd. | Zirconia sol and method for production thereof |
| US4954414A (en) | 1988-11-08 | 1990-09-04 | The Mead Corporation | Photosensitive composition containing a transition metal coordination complex cation and a borate anion and photosensitive materials employing the same |
| US5275759A (en) | 1989-02-10 | 1994-01-04 | Nippon Shokubai Kagaku Kogyo Co., Ltd. | Zirconia sol, method for production thereof, porous ceramic-producing slurry, and porous ceramic product obtained by use thereof |
| US5057393A (en) | 1989-07-10 | 1991-10-15 | The Mead Corporation | Dye branched-alkyl borate photoinitiators |
| JPH077895B2 (ja) | 1989-07-14 | 1995-01-30 | 日本電気株式会社 | 可変利得増幅器 |
| US5190583A (en) * | 1989-12-04 | 1993-03-02 | Transfer-Electric Gesellschaft Fur | Aqueous coating composition and the use thereof for coating to be protected from light, especially ultraviolet radiation |
| US5124417A (en) | 1990-02-12 | 1992-06-23 | Minnesota Mining And Manufacturing Company | Initiators for cationic polymerization |
| US5037579A (en) | 1990-02-12 | 1991-08-06 | Nalco Chemical Company | Hydrothermal process for producing zirconia sol |
| US5084586A (en) | 1990-02-12 | 1992-01-28 | Minnesota Mining And Manufacturing Company | Novel initiators for cationic polymerization |
| US5055372A (en) | 1990-04-23 | 1991-10-08 | The Mead Corporation | Photohardenable composition containing borate salts and ketone initiators |
| JPH0472768A (ja) | 1990-07-13 | 1992-03-06 | Meidensha Corp | 自己消弧型半導体装置 |
| JPH0764564B2 (ja) * | 1991-02-20 | 1995-07-12 | 株式会社槌屋 | 酸化ジルコニウム系前駆体ゲル状物及びその製造方法 |
| US5332429A (en) | 1991-05-31 | 1994-07-26 | Minnesota Mining And Manufacturing Company | Method for treating fluoroaluminosilicate glass |
| FR2681534B1 (fr) | 1991-09-20 | 1995-01-27 | Rhone Poulenc Chimie | Solutions collouidales concentrees de particules monocristallines non agregees d'oxydes de metaux, leur procede de preparation et leur application a l'obtention de films. |
| DE4133621A1 (de) | 1991-10-10 | 1993-04-22 | Inst Neue Mat Gemein Gmbh | Nanoskalige teilchen enthaltende kompositmaterialien, verfahren zu deren herstellung und deren verwendung fuer optische elemente |
| DE4212633A1 (de) | 1992-04-15 | 1993-10-21 | Inst Neue Mat Gemein Gmbh | Verfahren zur Herstellung oberflächenmodifizierter nanoskaliger keramischer Pulver |
| WO1993023333A1 (en) * | 1992-05-20 | 1993-11-25 | E.I. Du Pont De Nemours And Company | Process for making inorganic gels |
| US5460701A (en) | 1993-07-27 | 1995-10-24 | Nanophase Technologies Corporation | Method of making nanostructured materials |
| TW343961B (en) | 1994-06-17 | 1998-11-01 | Nissan Chemical Ind Ltd | Aqueous zirconia sol and method of preparing same |
| JP3214982B2 (ja) | 1994-07-04 | 2001-10-02 | 株式会社トクヤマ | 無機組成物 |
| US5856373A (en) | 1994-10-31 | 1999-01-05 | Minnesota Mining And Manufacturing Company | Dental visible light curable epoxy system with enhanced depth of cure |
| JP3542425B2 (ja) | 1994-11-17 | 2004-07-14 | キヤノン株式会社 | インクジェット記録用水系分散インク、これを用いるインクジェット記録方法、インクカートリッジ、記録ユニットおよび記録装置 |
| CN1083400C (zh) | 1995-03-15 | 2002-04-24 | 霍亚株式会社 | 金属氧化物析出物的制造方法 |
| US5698483A (en) | 1995-03-17 | 1997-12-16 | Institute Of Gas Technology | Process for preparing nanosized powder |
| DE19515820A1 (de) * | 1995-04-29 | 1996-10-31 | Inst Neue Mat Gemein Gmbh | Verfahren zur Herstellung schwach agglomerierter nanoskaliger Teilchen |
| US5648407A (en) | 1995-05-16 | 1997-07-15 | Minnesota Mining And Manufacturing Company | Curable resin sols and fiber-reinforced composites derived therefrom |
| WO1997015526A1 (en) | 1995-10-27 | 1997-05-01 | E.I. Du Pont De Nemours And Company | Hydrothermal process for making ultrafine metal oxide powders |
| DE19540623A1 (de) | 1995-10-31 | 1997-05-07 | Inst Neue Mat Gemein Gmbh | Verfahren zur Herstellung von Kompositmaterialien mit hohem Grenzflächenanteil und dadurch erhältliche Kompositmaterialien |
| US5886069A (en) | 1995-11-13 | 1999-03-23 | E. I. Du Pont De Nemours And Company | Titanium dioxide particles having substantially discrete inorganic particles dispersed on their surfaces |
| DE19617931C5 (de) | 1996-04-26 | 2010-07-22 | Ivoclar Vivadent Ag | Verwendung eines gefüllten und polymerisierbaren Materials als Dentalmaterial |
| US5942559A (en) | 1996-08-26 | 1999-08-24 | Ivoclar Ag | Dental light-curing opaquer |
| US6030914A (en) | 1996-11-12 | 2000-02-29 | Tosoh Corporation | Zirconia fine powder and method for its production |
| JP4086338B2 (ja) | 1996-12-06 | 2008-05-14 | 株式会社松風 | 歯科用弾性修復材料並びにそれを用いた歯科補綴材料の作製方法 |
| US5760126A (en) | 1996-12-20 | 1998-06-02 | Minnesota Mining And Manufacturing Company | Aqueous fluorochemical compositions and abrasion-resistant coatings therefrom |
| US6025406A (en) | 1997-04-11 | 2000-02-15 | 3M Innovative Properties Company | Ternary photoinitiator system for curing of epoxy resins |
| US5879715A (en) | 1997-09-02 | 1999-03-09 | Ceramem Corporation | Process and system for production of inorganic nanoparticles |
-
1999
- 1999-10-28 US US09/428,374 patent/US6376590B2/en not_active Expired - Lifetime
-
2000
- 2000-04-03 WO PCT/US2000/008796 patent/WO2001030702A1/en not_active Ceased
- 2000-04-03 DE DE60023023T patent/DE60023023T2/de not_active Expired - Lifetime
- 2000-04-03 CA CA002388876A patent/CA2388876C/en not_active Expired - Fee Related
- 2000-04-03 EP EP00920055A patent/EP1232118B1/en not_active Expired - Lifetime
- 2000-04-03 JP JP2001533062A patent/JP4559004B2/ja not_active Expired - Fee Related
- 2000-04-03 AU AU40652/00A patent/AU4065200A/en not_active Abandoned
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| US9202688B2 (en) | 2010-04-23 | 2015-12-01 | Pixelligent Technologies, Llc | Synthesis, capping and dispersion of nanocrystals |
| US9328432B2 (en) | 2010-04-23 | 2016-05-03 | Pixelligent Technologies, Llc | Synthesis, capping and dispersion of nanocrystals |
| US9617657B2 (en) | 2010-04-23 | 2017-04-11 | Pixelligent Technologies, Llc | Synthesis, capping and dispersion of nanocrystals |
| US9856581B2 (en) | 2010-04-23 | 2018-01-02 | Pixelligent Technologies, Llc | Synthesis, capping and dispersion of nanocrystals |
| US10753012B2 (en) | 2010-10-27 | 2020-08-25 | Pixelligent Technologies, Llc | Synthesis, capping and dispersion of nanocrystals |
| US9359689B2 (en) | 2011-10-26 | 2016-06-07 | Pixelligent Technologies, Llc | Synthesis, capping and dispersion of nanocrystals |
| CN113165900A (zh) * | 2018-11-30 | 2021-07-23 | 马蒂姆有限公司 | 一种在氨基酸存在下制备二氧化锆纳米颗粒的方法 |
| CN113165900B (zh) * | 2018-11-30 | 2023-07-18 | 马蒂姆有限公司 | 一种在氨基酸存在下制备二氧化锆纳米颗粒的方法 |
| CN114656818A (zh) * | 2020-12-03 | 2022-06-24 | 凯斯科技股份有限公司 | 金属氧化物分散液 |
| CN114656818B (zh) * | 2020-12-03 | 2023-11-17 | 凯斯科技股份有限公司 | 金属氧化物分散液 |
| CN115124074A (zh) * | 2022-07-26 | 2022-09-30 | 宣城市晶纳环保科技有限公司 | 一种高分散复合纳米二氧化锆的制备方法 |
| CN115124074B (zh) * | 2022-07-26 | 2024-02-06 | 宣城市晶纳环保科技有限公司 | 一种高分散复合纳米二氧化锆的制备方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| AU4065200A (en) | 2001-05-08 |
| WO2001030702A1 (en) | 2001-05-03 |
| DE60023023T2 (de) | 2006-06-14 |
| US20020004544A1 (en) | 2002-01-10 |
| EP1232118A1 (en) | 2002-08-21 |
| EP1232118B1 (en) | 2005-10-05 |
| JP2003512287A (ja) | 2003-04-02 |
| DE60023023D1 (de) | 2006-02-16 |
| US6376590B2 (en) | 2002-04-23 |
| CA2388876A1 (en) | 2001-05-03 |
| CA2388876C (en) | 2009-10-27 |
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