JP2005507012A5 - - Google Patents
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- Publication number
- JP2005507012A5 JP2005507012A5 JP2003537146A JP2003537146A JP2005507012A5 JP 2005507012 A5 JP2005507012 A5 JP 2005507012A5 JP 2003537146 A JP2003537146 A JP 2003537146A JP 2003537146 A JP2003537146 A JP 2003537146A JP 2005507012 A5 JP2005507012 A5 JP 2005507012A5
- Authority
- JP
- Japan
- Prior art keywords
- fluorinated
- ionomer
- electrolyte membrane
- polymer electrolyte
- solid polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000012528 membrane Substances 0.000 claims description 88
- 239000005518 polymer electrolyte Substances 0.000 claims description 60
- 239000007787 solid Substances 0.000 claims description 60
- 229920000554 ionomer Polymers 0.000 claims description 57
- 229920000642 polymer Polymers 0.000 claims description 46
- 239000000446 fuel Substances 0.000 claims description 35
- 239000003054 catalyst Substances 0.000 claims description 31
- QLOAVXSYZAJECW-UHFFFAOYSA-N methane;molecular fluorine Chemical group C.FF QLOAVXSYZAJECW-UHFFFAOYSA-N 0.000 claims description 18
- 239000000178 monomer Substances 0.000 claims description 18
- 238000000034 method Methods 0.000 claims description 16
- 125000003010 ionic group Chemical group 0.000 claims description 13
- 229920000768 polyamine Polymers 0.000 claims description 11
- 239000003795 chemical substances by application Substances 0.000 claims description 9
- 230000008961 swelling Effects 0.000 claims description 9
- 239000002904 solvent Substances 0.000 claims description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 23
- 229910052799 carbon Inorganic materials 0.000 description 15
- 125000006575 electron-withdrawing group Chemical group 0.000 description 8
- 125000001033 ether group Chemical group 0.000 description 8
- 229910052760 oxygen Inorganic materials 0.000 description 7
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 125000005010 perfluoroalkyl group Chemical group 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- 125000003118 aryl group Chemical group 0.000 description 4
- 239000011230 binding agent Substances 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 125000000392 cycloalkenyl group Chemical group 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 4
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 4
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 229920002873 Polyethylenimine Polymers 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 238000007639 printing Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229920000557 Nafion® Polymers 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 229920002313 fluoropolymer Polymers 0.000 description 1
- 229920001002 functional polymer Polymers 0.000 description 1
- 238000009396 hybridization Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 238000007649 pad printing Methods 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US32936101P | 2001-10-15 | 2001-10-15 | |
| PCT/US2002/032840 WO2003034529A1 (en) | 2001-10-15 | 2002-10-15 | Solid polymer membrane for fuel cell with polyamine imbibed therein for reducing methanol permeability |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2005507012A JP2005507012A (ja) | 2005-03-10 |
| JP2005507012A5 true JP2005507012A5 (https=) | 2006-01-05 |
Family
ID=23285030
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2003537146A Pending JP2005507012A (ja) | 2001-10-15 | 2002-10-15 | メタノール透過度を減少させるためにその中にポリアミンが吸収された燃料電池用固体ポリマー膜 |
| JP2003536310A Pending JP2005506406A (ja) | 2001-10-15 | 2002-10-15 | その場重合によって調製された燃料電池用固体ポリマー膜 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2003536310A Pending JP2005506406A (ja) | 2001-10-15 | 2002-10-15 | その場重合によって調製された燃料電池用固体ポリマー膜 |
Country Status (9)
| Country | Link |
|---|---|
| US (2) | US20040241518A1 (https=) |
| EP (2) | EP1444292A1 (https=) |
| JP (2) | JP2005507012A (https=) |
| KR (2) | KR20040041695A (https=) |
| CN (2) | CN1572040A (https=) |
| CA (2) | CA2462814A1 (https=) |
| DE (1) | DE60228303D1 (https=) |
| TW (2) | TW589759B (https=) |
| WO (2) | WO2003033576A1 (https=) |
Families Citing this family (58)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1444292A1 (en) * | 2001-10-15 | 2004-08-11 | E.I. Du Pont De Nemours And Company | Solid polymer membrane for fuel cell prepared by in situ polymerization |
| CA2462566A1 (en) * | 2001-10-24 | 2003-05-01 | E. I. Du Pont De Nemours And Company | Continuous production of catalyst coated membranes |
| CA2483015A1 (en) * | 2002-04-25 | 2003-11-06 | Pemeas Gmbh | Multilayer electrolyte membrane |
| US7569302B2 (en) * | 2002-11-05 | 2009-08-04 | Panasonic Corporation | Fuel cell for generating electric power |
| US7659026B2 (en) | 2003-06-27 | 2010-02-09 | E.I. Du Pont De Nemours And Company | Fluorinated sulfonamide compounds and polymer electrolyte membranes prepared therefrom for use in electrochemical cells |
| US7071271B2 (en) * | 2003-10-30 | 2006-07-04 | 3M Innovative Properties Company | Aqueous emulsion polymerization of functionalized fluoromonomers |
| US7259208B2 (en) * | 2003-11-13 | 2007-08-21 | 3M Innovative Properties Company | Reinforced polymer electrolyte membrane |
| US7074841B2 (en) * | 2003-11-13 | 2006-07-11 | Yandrasits Michael A | Polymer electrolyte membranes crosslinked by nitrile trimerization |
| US7179847B2 (en) * | 2003-11-13 | 2007-02-20 | 3M Innovative Properties Company | Polymer electrolytes crosslinked by e-beam |
| US7265162B2 (en) * | 2003-11-13 | 2007-09-04 | 3M Innovative Properties Company | Bromine, chlorine or iodine functional polymer electrolytes crosslinked by e-beam |
| US7060756B2 (en) | 2003-11-24 | 2006-06-13 | 3M Innovative Properties Company | Polymer electrolyte with aromatic sulfone crosslinking |
| US7112614B2 (en) * | 2003-12-08 | 2006-09-26 | 3M Innovative Properties Company | Crosslinked polymer |
| US7060738B2 (en) * | 2003-12-11 | 2006-06-13 | 3M Innovative Properties Company | Polymer electrolytes crosslinked by ultraviolet radiation |
| US7173067B2 (en) * | 2003-12-17 | 2007-02-06 | 3M Innovative Properties Company | Polymer electrolyte membranes crosslinked by direct fluorination |
| US7041191B2 (en) * | 2004-05-27 | 2006-05-09 | Institute Of Nuclear Energy Research | Method for manufacturing membrane electrode assembly of fuel cell by printing processes |
| US20060014887A1 (en) * | 2004-07-19 | 2006-01-19 | 3M Innovative Properties Company | Method of hydrolyzing a dispersion of ionic fluoropolymer |
| US7304101B2 (en) * | 2004-07-19 | 2007-12-04 | 3M Innovative Properties Company | Method of purifying a dispersion of ionic fluoropolymer |
| JP4573023B2 (ja) | 2004-07-23 | 2010-11-04 | 信越化学工業株式会社 | 燃料電池電解質膜用硬化性樹脂組成物並びに電解質膜、その製造方法及び電解質膜・電極接合体、その製造方法 |
| JP4429851B2 (ja) | 2004-09-08 | 2010-03-10 | 日東電工株式会社 | 耐久性に優れた電解質膜 |
| JP4946009B2 (ja) * | 2004-11-19 | 2012-06-06 | 旭硝子株式会社 | 固体高分子型燃料電池用電解質材料、固体高分子型燃料電池用膜・電極接合体の製造方法 |
| KR100661698B1 (ko) * | 2004-12-21 | 2006-12-26 | 마쯔시다덴기산교 가부시키가이샤 | 직접 메탄올형 연료전지 |
| US8232324B2 (en) * | 2005-02-28 | 2012-07-31 | Shin-Etsu Chemical Co., Ltd. | Electrolyte membrane-forming curable resin composition, and preparation of electrolyte membrane and electrolyte membrane/electrode assembly |
| GB0506866D0 (en) * | 2005-04-05 | 2005-05-11 | Rolls Royce Plc | A fuel cell arrangement |
| KR20080015020A (ko) * | 2005-06-01 | 2008-02-15 | 폴리퓨얼, 인코포레이티드 | 이온-전도성 코폴리머 및 비-이온성 폴리머를 포함하는폴리머 블랜드 |
| US20070031716A1 (en) * | 2005-08-05 | 2007-02-08 | Rajendran Raj G | Process for making cation exchange membranes with reduced methanol permeability |
| JP2007056155A (ja) * | 2005-08-25 | 2007-03-08 | Toyota Motor Corp | イオン伝導性材料、固体高分子電解質膜、及び燃料電池 |
| US20070218334A1 (en) * | 2006-03-16 | 2007-09-20 | Bonorand Lukas M | Methods for making sulfonated non-aromatic polymer electrolyte membranes |
| US20070128425A1 (en) * | 2005-12-07 | 2007-06-07 | 3M Innovative Properties Company | Reinforced ion-conductive membranes |
| KR100994124B1 (ko) * | 2006-01-19 | 2010-11-15 | 삼성에스디아이 주식회사 | 고분자막, 그 제조방법 및 이를 채용한 연료전지 |
| EP1873860A1 (en) * | 2006-06-28 | 2008-01-02 | Solvay Solexis S.p.A. | Catalyst-Polymer Liquid Dispersion for Fuel Cell Applications |
| US9187339B2 (en) * | 2007-09-07 | 2015-11-17 | Ishihara Sangyo Kaisha, Ltd. | Organic solvent dispersion containing flaky titanium oxide, method for production of the dispersion, titanium oxide film using the dispersion, and method for production of the titanium oxide film |
| JP5310334B2 (ja) * | 2008-07-15 | 2013-10-09 | トヨタ自動車株式会社 | アニオン伝導性電解質樹脂 |
| CN102317324B (zh) * | 2008-12-11 | 2014-12-24 | 索尔维索莱克西斯公司 | 氟代离聚物组合物的纯化 |
| SG169305A1 (en) * | 2009-08-26 | 2011-03-30 | Siemens Pte Ltd | Ion exchange membranes |
| CN102711966A (zh) * | 2009-11-02 | 2012-10-03 | Itm动力（研究）有限公司 | 离子型膜的制备 |
| CN102110822B (zh) * | 2009-12-25 | 2015-05-06 | 南京大学 | 一种气体扩散层及其制备方法和用途 |
| CN103237600B (zh) | 2010-10-15 | 2016-07-13 | 伊沃夸水处理技术有限责任公司 | 阴离子交换膜及制造方法 |
| JP5889907B2 (ja) | 2010-10-15 | 2016-03-22 | エヴォクア ウォーター テクノロジーズ エルエルシーＥｖｏｑｕａ Ｗａｔｅｒ Ｔｅｃｈｎｏｌｏｇｉｅｓｌｌｃ | カチオン交換膜を製造するためのモノマー溶液の製造方法 |
| WO2012096653A1 (en) * | 2011-01-11 | 2012-07-19 | Utc Power Corporation | Proton exchange material and method therefor |
| WO2012125138A1 (en) | 2011-03-11 | 2012-09-20 | Utc Power Corporation | Unitized electrode assembly with high equivalent weight ionomer |
| CN103947024B9 (zh) * | 2011-11-22 | 2017-06-20 | 住友电气工业株式会社 | 氧化还原液流电池隔膜 |
| DE112012005339B4 (de) | 2011-12-19 | 2019-02-14 | National Research Council Of Canada | Verfahren zur Herstellung coextrudierter Ionenaustauschvorläufer- Harzmembranen und deren Verwendung |
| KR101885246B1 (ko) * | 2012-04-06 | 2018-08-03 | 삼성전자주식회사 | 이온 교환체, 이의 제조방법 및 이를 포함하는 이온 교환 필터 장치와 전기 탈이온 장치 |
| WO2014055123A1 (en) | 2012-10-04 | 2014-04-10 | Evoqua Water Technologies Llc | High-performance anion exchange membranes and methods of making same |
| CA2887132C (en) | 2012-10-11 | 2020-07-21 | Evoqua Water Technologies Llc | Coated ion exchange membranes |
| KR101925670B1 (ko) | 2012-12-21 | 2018-12-05 | 아우디 아게 | 전해질 막, 분산액 및 그를 위한 방법 |
| EP2956979B1 (en) | 2012-12-21 | 2019-02-20 | Toyota Jidosha Kabushiki Kaisha | Proton exchange material and method therefor |
| CN105637690B (zh) | 2012-12-21 | 2018-06-22 | 奥迪股份公司 | 制备电解质材料的方法 |
| US20190202991A1 (en) * | 2016-05-02 | 2019-07-04 | Simon Fraser University | Energy conversion devices including stable ionenes |
| DE102016212056A1 (de) * | 2016-07-01 | 2018-01-04 | Mahle International Gmbh | Filtermedium und Verfahren zur Herstellung eines solchen Filtermediums |
| US10199667B2 (en) * | 2016-11-30 | 2019-02-05 | Nissan North America, Inc. | Segmented cation-anion exchange membrane for self-humidification of fuel cells and method of making |
| JP7404349B2 (ja) | 2018-09-25 | 2023-12-25 | エヴォクア ウォーター テクノロジーズ エルエルシー | 一価選択性カチオン交換膜 |
| US11289745B2 (en) * | 2019-01-09 | 2022-03-29 | GM Global Technology Operations LLC | Elimination of gaseous reactants in lithium ion batteries |
| CN110467703B (zh) * | 2019-09-06 | 2022-05-20 | 哈尔滨理工大学 | 一种基于原位聚合基体制备固态聚合物电解质薄膜的方法 |
| KR20220010948A (ko) * | 2020-07-20 | 2022-01-27 | 현대자동차주식회사 | 이온전도도 향상을 위한 충진제를 포함한 막-전극 접합체용 전해질막 |
| CN112054152B (zh) * | 2020-09-30 | 2023-04-28 | 中创新航技术研究院(江苏)有限公司 | 隔膜和电池 |
| CN113258132B (zh) * | 2021-05-11 | 2022-09-06 | 合肥工业大学 | 固态电解质及其制备方法以及固态电池 |
| CN120059001A (zh) * | 2025-02-26 | 2025-05-30 | 内蒙古大学 | 一种质子交换膜燃料电池催化剂层的离聚物及其制备方法 |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3282875A (en) * | 1964-07-22 | 1966-11-01 | Du Pont | Fluorocarbon vinyl ether polymers |
| JPS5858365B2 (ja) * | 1976-07-02 | 1983-12-24 | 東ソー株式会社 | 陽イオン交換膜の製法 |
| JPS5360388A (en) | 1976-11-11 | 1978-05-30 | Toyo Soda Mfg Co Ltd | Production of cation exchange membrane |
| US4358545A (en) * | 1980-06-11 | 1982-11-09 | The Dow Chemical Company | Sulfonic acid electrolytic cell having flourinated polymer membrane with hydration product less than 22,000 |
| US5672438A (en) * | 1995-10-10 | 1997-09-30 | E. I. Du Pont De Nemours And Company | Membrane and electrode assembly employing exclusion membrane for direct methanol fuel cell |
| US5643689A (en) * | 1996-08-28 | 1997-07-01 | E.C.R.-Electro-Chemical Research Ltd. | Non-liquid proton conductors for use in electrochemical systems under ambient conditions |
| WO1998042037A1 (en) | 1997-03-17 | 1998-09-24 | Motorola Inc. | Electrochemical cell having a polymer blend electrolyte |
| US6025092A (en) | 1998-02-13 | 2000-02-15 | E. I. Du Pont De Nemours And Company | Fluorinated ionomers and their uses |
| US6100324A (en) | 1998-04-16 | 2000-08-08 | E. I. Du Pont De Nemours And Company | Ionomers and ionically conductive compositions |
| MY135964A (en) | 1998-10-26 | 2008-07-31 | Du Pont | Ionomers and polymers for electrochemical uses |
| US6287722B1 (en) * | 1999-03-02 | 2001-09-11 | E. I. Du Pont Nemours And Co. | Continuous melt process for fabricating ionically conductive articles |
| HK1047579A1 (zh) | 1999-06-16 | 2003-02-28 | 纳幕尔杜邦公司 | 氟化离子聚合物 |
| JP2001085038A (ja) | 1999-09-14 | 2001-03-30 | Daihatsu Motor Co Ltd | 燃料電池システム |
| JP2001081220A (ja) | 1999-09-20 | 2001-03-27 | Honda Motor Co Ltd | 高分子複合膜、その製造方法、ならびに高分子固体電解質膜 |
| JP4042285B2 (ja) * | 2000-02-23 | 2008-02-06 | トヨタ自動車株式会社 | 固体高分子電解質膜およびその製造方法 |
| EP1444292A1 (en) * | 2001-10-15 | 2004-08-11 | E.I. Du Pont De Nemours And Company | Solid polymer membrane for fuel cell prepared by in situ polymerization |
| JP2006508493A (ja) * | 2002-01-23 | 2006-03-09 | ポリフューエル・インコーポレイテッド | 酸−塩基プロトン伝導性ポリマーブレンド膜 |
| EP1527494B1 (de) * | 2002-08-02 | 2005-12-28 | Pemeas GmbH | Protonenleitende polymembran, welche sulfonsäuregruppen enthaltende polymere umfasst, und deren anwendung in brennstoffzellen |
-
2002
- 2002-10-15 EP EP02801714A patent/EP1444292A1/en not_active Withdrawn
- 2002-10-15 CA CA002462814A patent/CA2462814A1/en not_active Abandoned
- 2002-10-15 US US10/488,845 patent/US20040241518A1/en not_active Abandoned
- 2002-10-15 CN CNA028203801A patent/CN1572040A/zh active Pending
- 2002-10-15 WO PCT/US2002/032838 patent/WO2003033576A1/en not_active Ceased
- 2002-10-15 WO PCT/US2002/032840 patent/WO2003034529A1/en not_active Ceased
- 2002-10-15 JP JP2003537146A patent/JP2005507012A/ja active Pending
- 2002-10-15 JP JP2003536310A patent/JP2005506406A/ja active Pending
- 2002-10-15 CA CA002459357A patent/CA2459357A1/en not_active Abandoned
- 2002-10-15 DE DE60228303T patent/DE60228303D1/de not_active Expired - Fee Related
- 2002-10-15 EP EP02801716A patent/EP1444748B1/en not_active Expired - Lifetime
- 2002-10-15 US US10/488,910 patent/US7534516B2/en not_active Expired - Fee Related
- 2002-10-15 TW TW091123683A patent/TW589759B/zh not_active IP Right Cessation
- 2002-10-15 KR KR10-2004-7005472A patent/KR20040041695A/ko not_active Withdrawn
- 2002-10-15 CN CNA028204530A patent/CN1571808A/zh active Pending
- 2002-10-15 KR KR1020047005474A patent/KR20050036849A/ko not_active Withdrawn
- 2002-10-15 TW TW091123689A patent/TW587351B/zh not_active IP Right Cessation
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