JP2001525461A - ビニル含有立体特異性ポリプロピレンマクロマー - Google Patents
ビニル含有立体特異性ポリプロピレンマクロマーInfo
- Publication number
- JP2001525461A JP2001525461A JP2000524331A JP2000524331A JP2001525461A JP 2001525461 A JP2001525461 A JP 2001525461A JP 2000524331 A JP2000524331 A JP 2000524331A JP 2000524331 A JP2000524331 A JP 2000524331A JP 2001525461 A JP2001525461 A JP 2001525461A
- Authority
- JP
- Japan
- Prior art keywords
- daltons
- vinyl
- molecular weight
- compound
- polypropylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- -1 polypropylene Polymers 0.000 title claims abstract description 92
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 title claims abstract description 58
- 229920001155 polypropylene Polymers 0.000 title claims abstract description 53
- 239000004743 Polypropylene Substances 0.000 title claims abstract description 52
- 230000000707 stereoselective effect Effects 0.000 title claims abstract description 37
- 229920002554 vinyl polymer Polymers 0.000 title abstract description 36
- 239000003054 catalyst Substances 0.000 claims abstract description 57
- 238000000034 method Methods 0.000 claims abstract description 47
- 150000001875 compounds Chemical class 0.000 claims abstract description 42
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims abstract description 25
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims abstract description 23
- 239000000178 monomer Substances 0.000 claims abstract description 17
- 229910052723 transition metal Inorganic materials 0.000 claims abstract description 16
- 150000003624 transition metals Chemical class 0.000 claims abstract description 16
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 10
- 239000000203 mixture Substances 0.000 claims abstract description 8
- 150000001450 anions Chemical class 0.000 claims description 20
- ZHFFGBNOSGNGDM-UHFFFAOYSA-N carbanide hafnium(4+) inden-3a-id-1-yl-inden-1-id-1-yl-dimethylsilane Chemical group [CH3-].[CH3-].[Hf+4].C[Si](C)([c-]1ccc2ccccc12)[c-]1ccc2ccccc12 ZHFFGBNOSGNGDM-UHFFFAOYSA-N 0.000 claims description 17
- 150000001336 alkenes Chemical group 0.000 claims description 11
- NDJMNNSJDIFFTH-UHFFFAOYSA-L [Cl-].[Cl-].CC1=CC(C(=CC=C2)C=3C=CC=CC=3)=C2C1[Zr+2]([SiH](C)C)C1C(C)=CC2=C1C=CC=C2C1=CC=CC=C1 Chemical compound [Cl-].[Cl-].CC1=CC(C(=CC=C2)C=3C=CC=CC=3)=C2C1[Zr+2]([SiH](C)C)C1C(C)=CC2=C1C=CC=C2C1=CC=CC=C1 NDJMNNSJDIFFTH-UHFFFAOYSA-L 0.000 claims description 9
- 239000002243 precursor Substances 0.000 claims description 6
- UAGSWZGMVQXQKB-UHFFFAOYSA-N 1-cyclopenta-2,4-dien-1-yl-1H-indene zirconium(2+) Chemical compound [Zr++].C1=Cc2ccccc2C1[c-]1cccc1.C1=Cc2ccccc2C1[c-]1cccc1 UAGSWZGMVQXQKB-UHFFFAOYSA-N 0.000 claims description 3
- 230000008569 process Effects 0.000 abstract description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 116
- 229920000642 polymer Polymers 0.000 description 55
- 239000000243 solution Substances 0.000 description 29
- 239000012190 activator Substances 0.000 description 24
- 238000006243 chemical reaction Methods 0.000 description 22
- 238000006116 polymerization reaction Methods 0.000 description 21
- 239000000047 product Substances 0.000 description 19
- 239000002904 solvent Substances 0.000 description 19
- 238000012937 correction Methods 0.000 description 15
- AQZWEFBJYQSQEH-UHFFFAOYSA-N 2-methyloxaluminane Chemical compound C[Al]1CCCCO1 AQZWEFBJYQSQEH-UHFFFAOYSA-N 0.000 description 14
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 12
- 125000000217 alkyl group Chemical group 0.000 description 12
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 10
- 239000000463 material Substances 0.000 description 10
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 10
- 230000015572 biosynthetic process Effects 0.000 description 9
- 238000004519 manufacturing process Methods 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 150000001768 cations Chemical class 0.000 description 8
- 238000003780 insertion Methods 0.000 description 8
- 230000037431 insertion Effects 0.000 description 8
- 230000007935 neutral effect Effects 0.000 description 8
- 239000007795 chemical reaction product Substances 0.000 description 7
- 238000001914 filtration Methods 0.000 description 7
- 239000003446 ligand Substances 0.000 description 7
- 229910052751 metal Inorganic materials 0.000 description 7
- 238000003786 synthesis reaction Methods 0.000 description 7
- 150000003623 transition metal compounds Chemical class 0.000 description 7
- 229910052726 zirconium Inorganic materials 0.000 description 7
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 6
- 238000004458 analytical method Methods 0.000 description 6
- 229910052801 chlorine Inorganic materials 0.000 description 6
- 229910052735 hafnium Inorganic materials 0.000 description 6
- 238000002844 melting Methods 0.000 description 6
- 230000008018 melting Effects 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 6
- 239000000377 silicon dioxide Substances 0.000 description 6
- 239000005977 Ethylene Substances 0.000 description 5
- 239000002841 Lewis acid Substances 0.000 description 5
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 5
- 230000008859 change Effects 0.000 description 5
- 239000000460 chlorine Substances 0.000 description 5
- 230000008030 elimination Effects 0.000 description 5
- 238000003379 elimination reaction Methods 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 description 4
- 238000007259 addition reaction Methods 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- 238000009826 distribution Methods 0.000 description 4
- 125000005843 halogen group Chemical group 0.000 description 4
- 150000002367 halogens Chemical group 0.000 description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 4
- 229910052809 inorganic oxide Inorganic materials 0.000 description 4
- 150000007517 lewis acids Chemical class 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 239000011148 porous material Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- PBKONEOXTCPAFI-UHFFFAOYSA-N 1,2,4-trichlorobenzene Chemical compound ClC1=CC=C(Cl)C(Cl)=C1 PBKONEOXTCPAFI-UHFFFAOYSA-N 0.000 description 3
- 238000005160 1H NMR spectroscopy Methods 0.000 description 3
- 125000000041 C6-C10 aryl group Chemical group 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- 125000003545 alkoxy group Chemical group 0.000 description 3
- 125000002877 alkyl aryl group Chemical group 0.000 description 3
- 125000005018 aryl alkenyl group Chemical group 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- IDASTKMEQGPVRR-UHFFFAOYSA-N cyclopenta-1,3-diene;zirconium(2+) Chemical compound [Zr+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 IDASTKMEQGPVRR-UHFFFAOYSA-N 0.000 description 3
- 229910052731 fluorine Inorganic materials 0.000 description 3
- 239000011737 fluorine Substances 0.000 description 3
- 238000007306 functionalization reaction Methods 0.000 description 3
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 3
- 229910052736 halogen Inorganic materials 0.000 description 3
- 238000010348 incorporation Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000002808 molecular sieve Substances 0.000 description 3
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 3
- 230000000737 periodic effect Effects 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 229920006395 saturated elastomer Polymers 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 3
- 229910052719 titanium Inorganic materials 0.000 description 3
- 239000010936 titanium Substances 0.000 description 3
- 238000012546 transfer Methods 0.000 description 3
- OBAJXDYVZBHCGT-UHFFFAOYSA-N tris(pentafluorophenyl)borane Chemical compound FC1=C(F)C(F)=C(F)C(F)=C1B(C=1C(=C(F)C(F)=C(F)C=1F)F)C1=C(F)C(F)=C(F)C(F)=C1F OBAJXDYVZBHCGT-UHFFFAOYSA-N 0.000 description 3
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 description 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- 241000870566 Astronium fraxinifolium Species 0.000 description 2
- 125000006374 C2-C10 alkenyl group Chemical group 0.000 description 2
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- JLTDJTHDQAWBAV-UHFFFAOYSA-N N,N-dimethylaniline Chemical compound CN(C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 230000003213 activating effect Effects 0.000 description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- 125000003342 alkenyl group Chemical group 0.000 description 2
- 238000005804 alkylation reaction Methods 0.000 description 2
- 150000001491 aromatic compounds Chemical class 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical compound BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 238000010924 continuous production Methods 0.000 description 2
- 238000012718 coordination polymerization Methods 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 125000004407 fluoroaryl group Chemical group 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 229910052732 germanium Inorganic materials 0.000 description 2
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 150000004678 hydrides Chemical group 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 150000004706 metal oxides Chemical group 0.000 description 2
- 239000012968 metallocene catalyst Substances 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 239000011733 molybdenum Substances 0.000 description 2
- 229910052758 niobium Inorganic materials 0.000 description 2
- 239000010955 niobium Substances 0.000 description 2
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 2
- 238000006384 oligomerization reaction Methods 0.000 description 2
- 125000002524 organometallic group Chemical group 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 125000002097 pentamethylcyclopentadienyl group Chemical group 0.000 description 2
- 239000002685 polymerization catalyst Substances 0.000 description 2
- 239000002954 polymerization reaction product Substances 0.000 description 2
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- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 229910052715 tantalum Inorganic materials 0.000 description 2
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 2
- 229910052720 vanadium Inorganic materials 0.000 description 2
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000003643 water by type Substances 0.000 description 2
- 239000004711 α-olefin Substances 0.000 description 2
- ZOICEQJZAWJHSI-UHFFFAOYSA-N (2,3,4,5,6-pentafluorophenyl)boron Chemical compound [B]C1=C(F)C(F)=C(F)C(F)=C1F ZOICEQJZAWJHSI-UHFFFAOYSA-N 0.000 description 1
- GGQQNYXPYWCUHG-RMTFUQJTSA-N (3e,6e)-deca-3,6-diene Chemical compound CCC\C=C\C\C=C\CC GGQQNYXPYWCUHG-RMTFUQJTSA-N 0.000 description 1
- 125000000027 (C1-C10) alkoxy group Chemical group 0.000 description 1
- 125000003837 (C1-C20) alkyl group Chemical group 0.000 description 1
- 125000006736 (C6-C20) aryl group Chemical group 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical group [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- 125000003358 C2-C20 alkenyl group Chemical group 0.000 description 1
- 102100033040 Carbonic anhydrase 12 Human genes 0.000 description 1
- 102100033029 Carbonic anhydrase-related protein 11 Human genes 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 239000007818 Grignard reagent Substances 0.000 description 1
- 101000867855 Homo sapiens Carbonic anhydrase 12 Proteins 0.000 description 1
- 101000867841 Homo sapiens Carbonic anhydrase-related protein 11 Proteins 0.000 description 1
- 101001075218 Homo sapiens Gastrokine-1 Proteins 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 241000257303 Hymenoptera Species 0.000 description 1
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 1
- 239000002879 Lewis base Substances 0.000 description 1
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- 238000005481 NMR spectroscopy Methods 0.000 description 1
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical compound ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 1
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- RLEZACANRPOGPQ-UHFFFAOYSA-L [Cl-].[Cl-].C1CC2CC=CC=C2C1[Zr+2]([SiH](C)C)C1C2=CC=CCC2CC1 Chemical compound [Cl-].[Cl-].C1CC2CC=CC=C2C1[Zr+2]([SiH](C)C)C1C2=CC=CCC2CC1 RLEZACANRPOGPQ-UHFFFAOYSA-L 0.000 description 1
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- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical compound [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
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- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
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- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
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- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
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- 230000000717 retained effect Effects 0.000 description 1
- 239000000523 sample Substances 0.000 description 1
- 239000012488 sample solution Substances 0.000 description 1
- 125000003808 silyl group Chemical group [H][Si]([H])([H])[*] 0.000 description 1
- 238000010530 solution phase reaction Methods 0.000 description 1
- 239000012453 solvate Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229950011008 tetrachloroethylene Drugs 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 238000013519 translation Methods 0.000 description 1
- IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- VPGLGRNSAYHXPY-UHFFFAOYSA-L zirconium(2+);dichloride Chemical compound Cl[Zr]Cl VPGLGRNSAYHXPY-UHFFFAOYSA-L 0.000 description 1
- QMBQEXOLIRBNPN-UHFFFAOYSA-L zirconocene dichloride Chemical compound [Cl-].[Cl-].[Zr+4].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 QMBQEXOLIRBNPN-UHFFFAOYSA-L 0.000 description 1
- 238000010507 β-hydride elimination reaction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US6778397P | 1997-12-10 | 1997-12-10 | |
| US60/067,783 | 1997-12-10 | ||
| PCT/US1998/024078 WO1999029743A1 (en) | 1997-12-10 | 1998-11-12 | Vinyl-containing stereospecific polypropylene macromers |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2001525461A true JP2001525461A (ja) | 2001-12-11 |
| JP2001525461A5 JP2001525461A5 (https=) | 2006-01-19 |
Family
ID=22078390
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2000524331A Pending JP2001525461A (ja) | 1997-12-10 | 1998-11-12 | ビニル含有立体特異性ポリプロピレンマクロマー |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US6117962A (https=) |
| EP (1) | EP1040140B1 (https=) |
| JP (1) | JP2001525461A (https=) |
| KR (1) | KR20010031058A (https=) |
| CN (1) | CN1106407C (https=) |
| BR (1) | BR9813496A (https=) |
| CA (1) | CA2304288A1 (https=) |
| DE (1) | DE69825316T2 (https=) |
| ES (1) | ES2224453T3 (https=) |
| WO (1) | WO1999029743A1 (https=) |
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| JP2005336091A (ja) * | 2004-05-26 | 2005-12-08 | Mitsubishi Chemicals Corp | 新規遷移金属化合物、該遷移金属化合物を用いたプロピレン系重合体の製造方法、および末端にビニル基を有するプロピレン系重合体 |
| JP2005336092A (ja) * | 2004-05-26 | 2005-12-08 | Mitsubishi Chemicals Corp | 新規遷移金属化合物、該遷移金属化合物を用いたプロピレン系重合体の製造方法 |
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| JP2011524460A (ja) * | 2008-06-20 | 2011-09-01 | エクソンモービル・ケミカル・パテンツ・インク | 高割合のビニル末端基を有するプロピレンベースオリゴマー |
| JP2011525212A (ja) * | 2008-06-20 | 2011-09-15 | エクソンモービル・ケミカル・パテンツ・インク | ポリマクロモノマーとこれを製造する方法 |
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| KR102488629B1 (ko) * | 2019-06-13 | 2023-01-13 | 주식회사 엘지화학 | 혼성 담지 메탈로센 촉매 및 이를 이용한 폴리프로필렌의 제조 방법 |
| WO2020251247A1 (ko) * | 2019-06-13 | 2020-12-17 | 주식회사 엘지화학 | 신규 전이금속 화합물 및 이를 이용한 폴리프로필렌의 제조방법 |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03100004A (ja) * | 1989-09-07 | 1991-04-25 | Hoechst Ag | ポリオレフィンワックスの製法 |
| JPH05214027A (ja) * | 1991-10-28 | 1993-08-24 | Shell Internatl Res Maatschappij Bv | 触媒組成物 |
| JPH05320260A (ja) * | 1992-05-20 | 1993-12-03 | Idemitsu Kosan Co Ltd | 末端ビニルエチレン−プロピレン共重合体およびその製造方法 |
| JPH06501047A (ja) * | 1990-09-14 | 1994-01-27 | エクソン・ケミカル・パテンツ・インク | 制御されたタクチシティーのポリ−α−オレフィンを製造するためのイオン触媒 |
| JPH06505033A (ja) * | 1990-09-13 | 1994-06-09 | エクソン・ケミカル・パテンツ・インク | モノシクロペンタジエニル遷移金属触媒系による結晶性ポリ−α−オレフィンの製造方法 |
| JPH072941A (ja) * | 1993-06-18 | 1995-01-06 | Idemitsu Kosan Co Ltd | エチレン系共重合体の製造方法 |
| JPH07188318A (ja) * | 1991-08-26 | 1995-07-25 | Hoechst Ag | オレフィンポリマーの製造方法 |
Family Cites Families (68)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3127133A1 (de) * | 1981-07-09 | 1983-01-27 | Hoechst Ag, 6000 Frankfurt | Verfahren zur herstellung von polyolefinen und deren copolymerisaten |
| US4530914A (en) * | 1983-06-06 | 1985-07-23 | Exxon Research & Engineering Co. | Process and catalyst for producing polyethylene having a broad molecular weight distribution |
| US5324800A (en) * | 1983-06-06 | 1994-06-28 | Exxon Chemical Patents Inc. | Process and catalyst for polyolefin density and molecular weight control |
| US4937299A (en) * | 1983-06-06 | 1990-06-26 | Exxon Research & Engineering Company | Process and catalyst for producing reactor blend polyolefins |
| DE3508887A1 (de) * | 1985-03-13 | 1986-09-25 | Hoechst Ag, 6230 Frankfurt | Verfahren zur herstellung von optisch aktiven polyolefinen |
| US4808561A (en) * | 1985-06-21 | 1989-02-28 | Exxon Chemical Patents Inc. | Supported polymerization catalyst |
| US4665208A (en) * | 1985-07-11 | 1987-05-12 | Exxon Chemical Patents Inc. | Process for the preparation of alumoxanes |
| US4701432A (en) * | 1985-11-15 | 1987-10-20 | Exxon Chemical Patents Inc. | Supported polymerization catalyst |
| WO1988001626A1 (fr) * | 1986-08-26 | 1988-03-10 | Mitsui Petrochemical Industries, Ltd. | CATALYSEUR DE POLYMERISATION D'alpha-OLEFINE ET PROCEDE DE POLYMERISATION |
| ATE177759T1 (de) * | 1986-09-24 | 1999-04-15 | Mitsui Chemicals Inc | Verfahren zur olefinpolymerisation |
| JPH0780933B2 (ja) * | 1986-11-20 | 1995-08-30 | 三井石油化学工業株式会社 | オレフインの重合方法 |
| JP2618384B2 (ja) * | 1986-12-27 | 1997-06-11 | 三井石油化学工業株式会社 | オレフイン重合用固体触媒およびその製法 |
| US4921825A (en) * | 1986-12-30 | 1990-05-01 | Mitsui Petrochemical Industries, Ltd. | Solid catalyst for olefin polymerization and processes for its production |
| IL85097A (en) * | 1987-01-30 | 1992-02-16 | Exxon Chemical Patents Inc | Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes |
| PL276385A1 (en) * | 1987-01-30 | 1989-07-24 | Exxon Chemical Patents Inc | Method for polymerization of olefines,diolefins and acetylene unsaturated compounds |
| JPH0742301B2 (ja) * | 1987-02-14 | 1995-05-10 | 三井石油化学工業株式会社 | 微粒子状アルミノオキサン、その製法およびその用途 |
| US4769910A (en) * | 1987-03-30 | 1988-09-13 | Northern Telecom Limited | Cutting tool for cylindrical articles |
| JP2538588B2 (ja) * | 1987-04-03 | 1996-09-25 | 三井石油化学工業株式会社 | オレフイン重合用固体触媒の製法 |
| US5206199A (en) * | 1987-04-20 | 1993-04-27 | Mitsui Petrochemical Industries, Ltd. | Catalyst for polymerizing an olefin and process for polymerizing an olefin |
| US5017714A (en) * | 1988-03-21 | 1991-05-21 | Exxon Chemical Patents Inc. | Silicon-bridged transition metal compounds |
| US5120867A (en) * | 1988-03-21 | 1992-06-09 | Welborn Jr Howard C | Silicon-bridged transition metal compounds |
| US4871705A (en) * | 1988-06-16 | 1989-10-03 | Exxon Chemical Patents Inc. | Process for production of a high molecular weight ethylene a-olefin elastomer with a metallocene alumoxane catalyst |
| US4892851A (en) * | 1988-07-15 | 1990-01-09 | Fina Technology, Inc. | Process and catalyst for producing syndiotactic polyolefins |
| US5155080A (en) * | 1988-07-15 | 1992-10-13 | Fina Technology, Inc. | Process and catalyst for producing syndiotactic polyolefins |
| EP0354893B2 (en) * | 1988-08-05 | 2002-03-13 | Fina Technology, Inc. | Process for producing large symmetrical polymer particles |
| US5091352A (en) * | 1988-09-14 | 1992-02-25 | Mitsui Petrochemical Industries, Ltd. | Olefin polymerization catalyst component, olefin polymerization catalyst and process for the polymerization of olefins |
| US4908463A (en) * | 1988-12-05 | 1990-03-13 | Ethyl Corporation | Aluminoxane process |
| US5103031A (en) * | 1989-02-21 | 1992-04-07 | Ethyl Corporation | Falling film aluminoxane process |
| DE3907964A1 (de) * | 1989-03-11 | 1990-09-13 | Hoechst Ag | Verfahren zur herstellung eines syndiotaktischen polyolefins |
| US4968827A (en) * | 1989-06-06 | 1990-11-06 | Ethyl Corporation | Alkylaluminoxane process |
| US4924018A (en) * | 1989-06-26 | 1990-05-08 | Ethyl Corporation | Alkylaluminoxane process |
| US5057475A (en) * | 1989-09-13 | 1991-10-15 | Exxon Chemical Patents Inc. | Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization |
| US5763549A (en) * | 1989-10-10 | 1998-06-09 | Fina Technology, Inc. | Cationic metallocene catalysts based on organoaluminum anions |
| DK0426637T4 (da) * | 1989-10-30 | 2002-01-14 | Fina Technology | Fremgangsmåde til fremstilling af metallocenkatalysatorer til polymerisation af olefiner |
| US5087809A (en) * | 1990-11-26 | 1992-02-11 | Eastman Kodak Company | Spectrally selective dithering and color filter mask for increased image sensor blue sensitivity |
| ATE186918T1 (de) * | 1990-01-02 | 1999-12-15 | Exxon Chemical Patents Inc | Ionische metallocenkatalysatoren auf träger für olefinpolymerisation |
| CA2057892C (en) * | 1990-04-09 | 1995-08-08 | Tetsunosuke Shiomura | Propylene copolymer |
| RU2118203C1 (ru) * | 1990-06-22 | 1998-08-27 | Экксон Кэмикал Пейтентс Инк. | Каталитическая система для получения полиолефинов и композиция, используемая для полимеризации олефинов |
| EP0500944B1 (en) * | 1990-07-24 | 1998-10-07 | Mitsui Chemicals, Inc. | Catalyst for alpha-olefin polymerization and production of poly-alpha-olefin therewith |
| US5189192A (en) * | 1991-01-16 | 1993-02-23 | The Dow Chemical Company | Process for preparing addition polymerization catalysts via metal center oxidation |
| DE4120009A1 (de) * | 1991-06-18 | 1992-12-24 | Basf Ag | Loesliche katalysatorsysteme zur herstellung von polyalk-1-enen mit hohen molmassen |
| US5721185A (en) * | 1991-06-24 | 1998-02-24 | The Dow Chemical Company | Homogeneous olefin polymerization catalyst by abstraction with lewis acids |
| US5157137A (en) * | 1991-07-26 | 1992-10-20 | Ethyl Corporation | Method of making gel free alkylaluminoxane solutions |
| US5235081A (en) * | 1992-03-18 | 1993-08-10 | Ethyl Corporation | Method of removing gel forming materials from methylaluminoxanes |
| US5308815A (en) * | 1991-07-26 | 1994-05-03 | Ethyl Corporation | Heterogeneous methylaluminoxane catalyst system |
| DE4130299A1 (de) * | 1991-09-12 | 1993-03-18 | Basf Ag | Verfahren zur herstellung von polypropylen unter hochdruck |
| ATE286918T1 (de) * | 1991-10-15 | 2005-01-15 | Basell Polyolefine Gmbh | Verfahren zur herstellung eines olefinpolymers unter verwendung von metallocenen mit speziell substituierten indenylliganden |
| EP0631589A1 (en) * | 1992-03-16 | 1995-01-04 | Exxon Chemical Patents Inc. | IONIC CATALYST FOR THE PRODUCTION OF POLY-$g(a)-OLEFINS OF CONTROLLED TACTICITY |
| US5329032A (en) * | 1992-03-18 | 1994-07-12 | Akzo Chemicals Inc. | Polymethylaluminoxane of enhanced solution stability |
| EP0578838A1 (en) * | 1992-04-29 | 1994-01-19 | Hoechst Aktiengesellschaft | Olefin polymerization catalyst, process for its preparation, and its use |
| US5350723A (en) * | 1992-05-15 | 1994-09-27 | The Dow Chemical Company | Process for preparation of monocyclopentadienyl metal complex compounds and method of use |
| US5240894A (en) * | 1992-05-18 | 1993-08-31 | Exxon Chemical Patents Inc. | Method for making and using a supported metallocene catalyst system |
| US5434115A (en) * | 1992-05-22 | 1995-07-18 | Tosoh Corporation | Process for producing olefin polymer |
| EP0574597B2 (en) * | 1992-06-13 | 2002-06-26 | Basell Polyolefine GmbH | Process for the preparation of bridged, chiral metallocene catalysts of the bisindenyl type |
| US5710222A (en) * | 1992-06-22 | 1998-01-20 | Fina Technology, Inc. | Method for controlling the melting points and molecular weights of syndiotactic polyolefins using metallocene catalyst systems |
| JPH07509752A (ja) * | 1992-08-05 | 1995-10-26 | エクソン・ケミカル・パテンツ・インク | オレフィン重合用の担持されたイオン遷移金属触媒 |
| US5248801A (en) * | 1992-08-27 | 1993-09-28 | Ethyl Corporation | Preparation of methylaluminoxanes |
| DE69312306T2 (de) * | 1992-10-02 | 1997-11-13 | Dow Chemical Co | Aufträger homogener komplexkatalysator für olefinpolymerisation |
| DE69333470T2 (de) * | 1992-10-28 | 2004-08-19 | Idemitsu Kosan Co. Ltd. | Olefincopolymere und verfahren zu ihrer herstellung |
| US5939346A (en) * | 1992-11-02 | 1999-08-17 | Akzo Nobel N.V. | Catalyst system comprising an aryloxyaluminoxane containing an electron withdrawing group |
| JP3626186B2 (ja) * | 1993-05-25 | 2005-03-02 | エクソンモービル・ケミカル・パテンツ・インク | オレフィンの重合用の担持されたメタロセン触媒系、その製造法及び使用 |
| EP0764175B1 (en) * | 1994-06-09 | 1999-12-08 | Infineum USA L.P. | Dilute process for the polymerization of non-ethylene alpha-olefin homopolymers and copolymers using metallocene catalyst systems |
| ES2165425T3 (es) * | 1994-06-24 | 2002-03-16 | Exxonmobil Chem Patents Inc | Sistemas cataliticos de polimerizacion, su produccion y uso. |
| KR100378973B1 (ko) * | 1994-06-24 | 2003-08-19 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 중합촉매시스템, 이의 제조방법 및 용도 |
| BR9508487A (pt) * | 1994-08-03 | 1997-12-30 | Exxon Chemical Patents Inc | Composição de catalisador iônico suportado |
| US5696213A (en) * | 1995-04-21 | 1997-12-09 | Exxon Chemical Patents Inc. | Ethylene-α-olefin-diolefin elastomers solution polymerization process |
| CA2223258A1 (en) * | 1995-07-06 | 1997-01-23 | Exxon Chemical Patents, Inc. | Method for producing prepolymerized, supported metallocene catalyst systems |
| DE69808243T2 (de) * | 1997-02-07 | 2003-05-08 | Exxonmobil Chemical Patents Inc., Baytown | Thermoplastische,elastomere zusammensetzungen aus verzweigten olefincopolymeren |
-
1998
- 1998-02-06 US US09/020,101 patent/US6117962A/en not_active Expired - Lifetime
- 1998-11-12 WO PCT/US1998/024078 patent/WO1999029743A1/en not_active Ceased
- 1998-11-12 CA CA002304288A patent/CA2304288A1/en not_active Abandoned
- 1998-11-12 DE DE69825316T patent/DE69825316T2/de not_active Expired - Lifetime
- 1998-11-12 JP JP2000524331A patent/JP2001525461A/ja active Pending
- 1998-11-12 KR KR1020007003891A patent/KR20010031058A/ko not_active Abandoned
- 1998-11-12 ES ES98959421T patent/ES2224453T3/es not_active Expired - Lifetime
- 1998-11-12 BR BR9813496-5A patent/BR9813496A/pt not_active Application Discontinuation
- 1998-11-12 EP EP98959421A patent/EP1040140B1/en not_active Expired - Lifetime
- 1998-11-12 CN CN98809979A patent/CN1106407C/zh not_active Expired - Fee Related
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03100004A (ja) * | 1989-09-07 | 1991-04-25 | Hoechst Ag | ポリオレフィンワックスの製法 |
| JPH06505033A (ja) * | 1990-09-13 | 1994-06-09 | エクソン・ケミカル・パテンツ・インク | モノシクロペンタジエニル遷移金属触媒系による結晶性ポリ−α−オレフィンの製造方法 |
| JPH06501047A (ja) * | 1990-09-14 | 1994-01-27 | エクソン・ケミカル・パテンツ・インク | 制御されたタクチシティーのポリ−α−オレフィンを製造するためのイオン触媒 |
| JPH07188318A (ja) * | 1991-08-26 | 1995-07-25 | Hoechst Ag | オレフィンポリマーの製造方法 |
| JPH05214027A (ja) * | 1991-10-28 | 1993-08-24 | Shell Internatl Res Maatschappij Bv | 触媒組成物 |
| JPH05320260A (ja) * | 1992-05-20 | 1993-12-03 | Idemitsu Kosan Co Ltd | 末端ビニルエチレン−プロピレン共重合体およびその製造方法 |
| JPH072941A (ja) * | 1993-06-18 | 1995-01-06 | Idemitsu Kosan Co Ltd | エチレン系共重合体の製造方法 |
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|---|---|---|---|---|
| JP2005336092A (ja) * | 2004-05-26 | 2005-12-08 | Mitsubishi Chemicals Corp | 新規遷移金属化合物、該遷移金属化合物を用いたプロピレン系重合体の製造方法 |
| JP2005336091A (ja) * | 2004-05-26 | 2005-12-08 | Mitsubishi Chemicals Corp | 新規遷移金属化合物、該遷移金属化合物を用いたプロピレン系重合体の製造方法、および末端にビニル基を有するプロピレン系重合体 |
| JP2007246433A (ja) * | 2006-03-15 | 2007-09-27 | Tosoh Corp | 有機遷移金属化合物、それを用いたオレフィン重合用触媒およびポリオレフィンの製造方法 |
| US8324335B2 (en) | 2006-11-17 | 2012-12-04 | Japan Polypropylene Corporation | Propylene-based polymer and method for producing the same, and propylene-based resin composition |
| WO2008059969A1 (en) | 2006-11-17 | 2008-05-22 | Japan Polypropylene Corporation | Propylene polymer, process for production of the propylene polymer, and propylene resin composition |
| JP2013100558A (ja) * | 2008-05-13 | 2013-05-23 | Japan Polypropylene Corp | プロピレン系重合体 |
| JP2009299045A (ja) * | 2008-05-13 | 2009-12-24 | Japan Polypropylene Corp | プロピレン系重合体 |
| JP2009299046A (ja) * | 2008-05-13 | 2009-12-24 | Japan Polypropylene Corp | メタロセン化合物を用いたプロピレン系重合体の製造方法 |
| JP2011524460A (ja) * | 2008-06-20 | 2011-09-01 | エクソンモービル・ケミカル・パテンツ・インク | 高割合のビニル末端基を有するプロピレンベースオリゴマー |
| JP2011525212A (ja) * | 2008-06-20 | 2011-09-15 | エクソンモービル・ケミカル・パテンツ・インク | ポリマクロモノマーとこれを製造する方法 |
| JP2014511911A (ja) * | 2011-03-25 | 2014-05-19 | エクソンモービル ケミカル パテンツ インコーポレイテッド | ビニル末端プロピレンおよびエチレン／プロピレンマクロマーの生成のための触媒性能の向上 |
| WO2013061974A1 (ja) | 2011-10-24 | 2013-05-02 | 三菱化学株式会社 | 熱可塑性エラストマー組成物及びその製造方法 |
| JP2014189776A (ja) * | 2013-03-28 | 2014-10-06 | Mitsubishi Chemicals Corp | 変性プロピレン系重合体組成物 |
| US9771448B2 (en) | 2014-03-28 | 2017-09-26 | Mitsui Chemicals, Inc. | Olefin-based resin, method for producing same and propylene-based resin composition |
| WO2015166666A2 (en) | 2015-08-24 | 2015-11-05 | Sumitomo Chemical Company, Limited | Injection-molded article for packaging material, injection-molded article for automotive part, industrial film, and food packaging film |
| WO2015166665A2 (en) | 2015-08-24 | 2015-11-05 | Sumitomo Chemical Company, Limited | Injection-molded article for packaging material, injection-molded article for automotive part, industrial film, and food packaging film |
| WO2017082182A1 (ja) | 2015-11-09 | 2017-05-18 | 三井化学株式会社 | 潤滑油用粘度調整剤、潤滑油用添加剤組成物および潤滑油組成物 |
| EP3395885A1 (en) | 2017-04-27 | 2018-10-31 | Sumitomo Chemical Company, Ltd | Propylene polymer composition |
| WO2020009090A1 (ja) | 2018-07-05 | 2020-01-09 | 住友化学株式会社 | プロピレン重合体組成物 |
| WO2020184421A1 (ja) | 2019-03-12 | 2020-09-17 | 三井化学株式会社 | オレフィン系樹脂、その架橋物およびそれらの製造方法 |
| WO2024190872A1 (ja) * | 2023-03-15 | 2024-09-19 | デンカ株式会社 | 化合物、共重合体、組成物、ワニス、及びそれらの硬化体 |
Also Published As
| Publication number | Publication date |
|---|---|
| DE69825316T2 (de) | 2005-05-12 |
| ES2224453T3 (es) | 2005-03-01 |
| DE69825316D1 (de) | 2004-09-02 |
| CN1106407C (zh) | 2003-04-23 |
| EP1040140B1 (en) | 2004-07-28 |
| EP1040140A1 (en) | 2000-10-04 |
| US6117962A (en) | 2000-09-12 |
| CA2304288A1 (en) | 1999-06-17 |
| BR9813496A (pt) | 2000-10-10 |
| WO1999029743A1 (en) | 1999-06-17 |
| CN1274367A (zh) | 2000-11-22 |
| KR20010031058A (ko) | 2001-04-16 |
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