BR9813496A - MacrÈmeros estereoespecìficos de polipropileno contendo vinila - Google Patents

MacrÈmeros estereoespecìficos de polipropileno contendo vinila

Info

Publication number
BR9813496A
BR9813496A BR9813496-5A BR9813496A BR9813496A BR 9813496 A BR9813496 A BR 9813496A BR 9813496 A BR9813496 A BR 9813496A BR 9813496 A BR9813496 A BR 9813496A
Authority
BR
Brazil
Prior art keywords
daltons
stereospecific
vinyl
macromers
polypropylene
Prior art date
Application number
BR9813496-5A
Other languages
English (en)
Inventor
Weiquing Weng
Armenag H Dekmezian
Eric J Markel
David L Peters
Original Assignee
Exxon Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Chemical Patents Inc filed Critical Exxon Chemical Patents Inc
Publication of BR9813496A publication Critical patent/BR9813496A/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound

Abstract

Patente de Invenção: <B>''MACRÈMEROS ESTEREOESPECìFICOS DE POLIPROPILENO CONTENDO VINILA''<D>. Macrómeros de polipropileno estereoespecíficos tendo uma alta porcentagem de ligações terminais de vinila e um método para preparação dos mesmos são providos. Os macrómeros de polipropileno estereoespecíficos apresentam pesos moleculares médios numéricos (M~ n~) de cerca de 2.000 dáltons a cerca de 50.000 dáltons e o número total de grupos vinílicos por 1000 átomos de carbono é maior do que ou igual a 7.000 ¸ M~ n~. O método para preparação dos macrómeros envolve: a) contatar, em solução, a uma temperatura de cerca de 90°C a cerca de 120°C, dois ou mais monómeros de propileno com uma composição de catalisador contendo um composto de catalisador metálico de transição quiral, estereorrígido; e b) recuperar as cadeias de polipropileno estereoespecíficas que apresentam pesos moleculares médios numéricos de cerca de 2.000 dáltons a cerca de 50.000 dáltons e de significativa insaturação vinílica.
BR9813496-5A 1997-12-10 1998-11-12 MacrÈmeros estereoespecìficos de polipropileno contendo vinila BR9813496A (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US6778397P 1997-12-10 1997-12-10
PCT/US1998/024078 WO1999029743A1 (en) 1997-12-10 1998-11-12 Vinyl-containing stereospecific polypropylene macromers

Publications (1)

Publication Number Publication Date
BR9813496A true BR9813496A (pt) 2000-10-10

Family

ID=22078390

Family Applications (1)

Application Number Title Priority Date Filing Date
BR9813496-5A BR9813496A (pt) 1997-12-10 1998-11-12 MacrÈmeros estereoespecìficos de polipropileno contendo vinila

Country Status (10)

Country Link
US (1) US6117962A (pt)
EP (1) EP1040140B1 (pt)
JP (1) JP2001525461A (pt)
KR (1) KR20010031058A (pt)
CN (1) CN1106407C (pt)
BR (1) BR9813496A (pt)
CA (1) CA2304288A1 (pt)
DE (1) DE69825316T2 (pt)
ES (1) ES2224453T3 (pt)
WO (1) WO1999029743A1 (pt)

Families Citing this family (87)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7919561B2 (en) * 1996-09-04 2011-04-05 Exxonmobil Chemical Patents Inc. Process of producing thermoplastic polymer blends
EP1361232B1 (en) * 1997-12-10 2010-02-24 ExxonMobil Chemical Patents Inc. Polypropylene polymers incorporating macromers
US6197910B1 (en) * 1997-12-10 2001-03-06 Exxon Chemical Patents, Inc. Propylene polymers incorporating macromers
EP1522553B1 (en) 1998-07-01 2007-04-11 ExxonMobil Chemical Patents Inc. Elastic blends comprising crystalline polymer and crystallizable polymers of propylene
US6884562B1 (en) * 1998-10-27 2005-04-26 E. I. Du Pont De Nemours And Company Photoresists and processes for microlithography
WO2002060965A2 (en) * 2000-12-12 2002-08-08 Baker Hughes Incorporated Low molecular weight isotactic polypropylene polymers, copolymers and derivatives and materials prepared therewith
DE60238049D1 (de) 2001-04-12 2010-12-02 Exxonmobil Chem Patents Inc Verfahren zur Polymerisation von Propylen und Ethylen in Lösung
US6960635B2 (en) * 2001-11-06 2005-11-01 Dow Global Technologies Inc. Isotactic propylene copolymers, their preparation and use
US7524910B2 (en) 2002-10-15 2009-04-28 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
US7223822B2 (en) 2002-10-15 2007-05-29 Exxonmobil Chemical Patents Inc. Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom
AU2003277350A1 (en) * 2002-10-24 2004-05-13 Exxonmobil Chemical Patents Inc. Branched crystalline polypropylene
US20040132935A1 (en) * 2002-10-24 2004-07-08 Palanisamy Arjunan Branched crystalline polypropylene
JP4834965B2 (ja) * 2004-05-26 2011-12-14 三菱化学株式会社 新規遷移金属化合物、該遷移金属化合物を用いたプロピレン系重合体の製造方法
JP4834964B2 (ja) * 2004-05-26 2011-12-14 三菱化学株式会社 新規遷移金属化合物、該遷移金属化合物を用いたプロピレン系重合体の製造方法、および末端にビニル基を有するプロピレン系重合体
US7928164B2 (en) * 2005-06-22 2011-04-19 Exxonmobil Chemical Patents Inc. Homogeneous polymer blend and process of making the same
US9644092B2 (en) 2005-06-22 2017-05-09 Exxonmobil Chemical Patents Inc. Heterogeneous in-situ polymer blend
US20060293462A1 (en) * 2005-06-22 2006-12-28 Sunny Jacob Heterogeneous polymer blend and process of making the same
US9745461B2 (en) 2005-06-22 2017-08-29 Exxonmobil Chemical Patents Inc. Vulcanized polymer blends
US8022142B2 (en) * 2008-12-15 2011-09-20 Exxonmobil Chemical Patents Inc. Thermoplastic olefin compositions
US7951872B2 (en) * 2005-06-22 2011-05-31 Exxonmobil Chemical Patents Inc. Heterogeneous polymer blend with continuous elastomeric phase and process of making the same
JP5023522B2 (ja) * 2006-03-15 2012-09-12 東ソー株式会社 有機遷移金属化合物、それを用いたオレフィン重合用触媒およびポリオレフィンの製造方法
JP4637157B2 (ja) 2006-11-17 2011-02-23 日本ポリプロ株式会社 プロピレン系重合体及びその製造方法
WO2009114661A1 (en) 2008-03-13 2009-09-17 Dow Global Technologies Inc. Long chain branched (lcb), block or interconnected copolymers of ethylene in combination with one other polymer
JP5286154B2 (ja) * 2008-05-13 2013-09-11 日本ポリプロ株式会社 プロピレン系重合体
JP5256115B2 (ja) * 2008-05-13 2013-08-07 日本ポリプロ株式会社 メタロセン化合物を用いたプロピレン系重合体の製造方法
US8283400B2 (en) * 2008-06-09 2012-10-09 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions
US8242198B2 (en) 2008-06-09 2012-08-14 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions
US8431642B2 (en) * 2008-06-09 2013-04-30 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
US8802797B2 (en) 2008-06-20 2014-08-12 Exxonmobil Chemical Patents Inc. Vinyl-terminated macromonomer oligomerization
US8283428B2 (en) * 2008-06-20 2012-10-09 Exxonmobil Chemical Patents Inc. Polymacromonomer and process for production thereof
ES2420117T3 (es) * 2008-06-20 2013-08-22 Exxonmobil Chemical Patents Inc. Oligómeros basados en propileno terminado en vinilo superior
US8283419B2 (en) 2008-06-20 2012-10-09 Exxonmobil Chemical Patents Inc. Olefin functionalization by metathesis reaction
US8372930B2 (en) * 2008-06-20 2013-02-12 Exxonmobil Chemical Patents Inc. High vinyl terminated propylene based oligomers
US8399725B2 (en) * 2008-06-20 2013-03-19 Exxonmobil Chemical Patents Inc. Functionalized high vinyl terminated propylene based oligomers
EP2307466B1 (en) 2008-08-01 2015-05-20 ExxonMobil Chemical Patents Inc. Catalyst system and process for olefin polymerization
US8580902B2 (en) 2008-08-01 2013-11-12 Exxonmobil Chemical Patents Inc. Catalyst system, process for olefin polymerization, and polymer compositions produced therefrom
US8022154B2 (en) * 2008-11-06 2011-09-20 Exxonmobil Chemical Patents Inc. Ethylene polymers, their production and use
US8106127B2 (en) * 2008-12-15 2012-01-31 Exxonmobil Chemical Patents Inc. Heterogeneous in-reactor polymer blends
US8093335B2 (en) * 2008-12-15 2012-01-10 Exxonmobil Chemical Patents Inc. Thermoplastic polyolefin in-reactor blends and molded articles therefrom
US8378042B2 (en) 2009-04-28 2013-02-19 Exxonmobil Chemical Patents Inc. Finishing process for amorphous polymers
US20120028865A1 (en) 2010-07-28 2012-02-02 Sudhin Datta Viscosity Modifiers Comprising Blends of Ethylene-Based Copolymers
US8618033B2 (en) 2010-01-22 2013-12-31 Exxonmobil Chemical Patents Inc. Ethylene copolymers, methods for their production, and use
EP2435526A4 (en) * 2009-05-29 2012-10-31 Exxonmobil Chem Patents Inc POLYOLEFINIC ADHESIVE COMPOSITIONS AND PROCESS FOR PRODUCING THE SAME
US8318648B2 (en) 2009-12-15 2012-11-27 Exxonmobil Research And Engineering Company Polyether-containing lubricant base stocks and process for making
JP5471629B2 (ja) * 2010-03-10 2014-04-16 株式会社島津製作所 液体クロマトグラフ用分析システム及び該分析システムの制御プログラム
US8703683B2 (en) 2010-04-23 2014-04-22 Exxonmobil Research And Engineering Company Poly (alkyl epdxides), process for making, and lubricant compositions having same
US8318998B2 (en) 2011-03-25 2012-11-27 Exxonmobil Chemical Patents Inc. Enhanced catalyst performance for production of vinyl terminated propylene and ethylene/propylene macromers
US8835563B2 (en) 2011-03-25 2014-09-16 Exxonmobil Chemical Patents Inc. Block copolymers from silylated vinyl terminated macromers
US9643900B2 (en) 2011-03-25 2017-05-09 Dow Global Technologies Llc Hyperbranched ethylene-based oils and greases
US8669326B2 (en) 2011-03-25 2014-03-11 Exxonmobil Chemical Patents Inc. Amine functionalized polyolefin and methods for preparation thereof
EP2688918B1 (en) * 2011-03-25 2016-12-07 ExxonMobil Chemical Patents Inc. Enhanced catalyst performance for production of vinyl terminated propylene and ethylene/propylene macromers
US8399724B2 (en) 2011-03-25 2013-03-19 Exxonmobil Chemical Patents Inc. Vinyl terminated higher olefin copolymers and methods to produce thereof
US8455597B2 (en) 2011-03-25 2013-06-04 Exxonmobil Chemical Patents Inc. Catalysts and methods of use thereof to produce vinyl terminated polymers
US8426659B2 (en) 2011-03-25 2013-04-23 Exxonmobil Chemical Patents Inc. Vinyl terminated higher olefin polymers and methods to produce thereof
US8841397B2 (en) 2011-03-25 2014-09-23 Exxonmobil Chemical Patents Inc. Vinyl terminated higher olefin polymers and methods to produce thereof
US8623974B2 (en) 2011-03-25 2014-01-07 Exxonmobil Chemical Patents Inc. Branched vinyl terminated polymers and methods for production thereof
US8785562B2 (en) 2011-03-25 2014-07-22 Exxonmobil Chemical Patents Inc. Amphiphilic block polymers prepared by alkene metathesis
US8501894B2 (en) 2011-03-25 2013-08-06 Exxonmobil Chemical Patents Inc. Hydrosilyation of vinyl macromers with metallocenes
US8940839B2 (en) 2011-03-25 2015-01-27 Exxonmobil Chemical Patents Inc. Diblock copolymers prepared by cross metathesis
JP5793820B2 (ja) * 2011-03-25 2015-10-14 エクソンモービル ケミカル パテンツ インコーポレイテッド 分枝ビニル末端ポリマー及びその製造方法
US8669330B2 (en) 2011-03-25 2014-03-11 Exxonmobil Chemical Patents Inc. Olefin triblock polymers via ring-opening metathesis polymerization
JP5600219B2 (ja) 2011-10-24 2014-10-01 三菱化学株式会社 熱可塑性エラストマー組成物及びその製造方法
US8604148B2 (en) 2011-11-29 2013-12-10 Exxonmobil Chemical Patents Inc. Functionalization of vinyl terminated polymers by ring opening cross metathesis
CN104169312A (zh) * 2012-02-22 2014-11-26 埃克森美孚化学专利公司 乙烯基封端的大分子单体低聚
US8796376B2 (en) 2012-03-26 2014-08-05 Exxonmobil Chemical Patents Inc. Functionalized polymers and oligomers
WO2013158253A1 (en) 2012-04-19 2013-10-24 Exxonmobil Chemical Patents Inc. Lubricant compositions comprising ethylene propylene copolymers and methods for making them
US9422385B2 (en) 2013-01-30 2016-08-23 Exxonmobil Chemical Patents Inc. Polyethylene copolymers with vinyl terminated macromonomers as comonomers
JP2014189776A (ja) * 2013-03-28 2014-10-06 Mitsubishi Chemicals Corp 変性プロピレン系重合体組成物
JP6525981B2 (ja) 2013-06-28 2019-06-05 ダウ グローバル テクノロジーズ エルエルシー 軽分岐疎水性物質ならびに対応する界面活性剤の調製のための方法、及びその適用
JP6516737B2 (ja) 2013-06-28 2019-05-22 ダウ グローバル テクノロジーズ エルエルシー 超分岐エチレン含有オリゴマー
US9963648B2 (en) 2013-06-28 2018-05-08 Dow Global Technologies Llc Process for the preparation of branched polyolefins for lubricant applications
WO2015023380A1 (en) 2013-08-16 2015-02-19 Exxonmobil Chemical Patents Inc. Polyamide-polyolefin copolymers and methods of making them
US9376559B2 (en) * 2013-11-22 2016-06-28 Exxonmobil Chemical Patents Inc. Reverse staged impact copolymers
US9695288B2 (en) 2013-11-22 2017-07-04 Exxonmobil Chemical Patents Inc. Graft engineering thermoplastics with polyolefins
US9771448B2 (en) 2014-03-28 2017-09-26 Mitsui Chemicals, Inc. Olefin-based resin, method for producing same and propylene-based resin composition
WO2015166666A2 (en) 2015-08-24 2015-11-05 Sumitomo Chemical Company, Limited Injection-molded article for packaging material, injection-molded article for automotive part, industrial film, and food packaging film
WO2015166665A2 (en) 2015-08-24 2015-11-05 Sumitomo Chemical Company, Limited Injection-molded article for packaging material, injection-molded article for automotive part, industrial film, and food packaging film
EP3375849A4 (en) 2015-11-09 2019-06-26 Mitsui Chemicals, Inc. VISCOSITY MODIFIER FOR LUBRICATING OILS, ADDITIVE COMPOSITION FOR LUBRICATING OILS, AND LUBRICATING OIL COMPOSITIONS
US10882932B2 (en) 2016-10-05 2021-01-05 Exxonmobil Chemical Patents Inc. Sterically hindered metallocenes, synthesis and use
JP7027988B2 (ja) 2017-04-27 2022-03-02 住友化学株式会社 プロピレン重合体組成物
JPWO2020009090A1 (ja) 2018-07-05 2021-07-08 住友化学株式会社 プロピレン重合体組成物
US11377560B2 (en) 2018-12-18 2022-07-05 ExxonMobil Technology and Engineering Company Modified asphalts and methods for producing the same
EP3940009A4 (en) 2019-03-12 2023-03-15 Mitsui Chemicals, Inc. OLEFIN-BASED RESIN, CROSSLINKER THEREOF, AND METHODS OF PRODUCTION THEREOF
KR102488629B1 (ko) * 2019-06-13 2023-01-13 주식회사 엘지화학 혼성 담지 메탈로센 촉매 및 이를 이용한 폴리프로필렌의 제조 방법
WO2020251247A1 (ko) * 2019-06-13 2020-12-17 주식회사 엘지화학 신규 전이금속 화합물 및 이를 이용한 폴리프로필렌의 제조방법
KR102524952B1 (ko) * 2019-06-13 2023-04-24 주식회사 엘지화학 신규 전이금속 화합물 및 이를 이용한 폴리프로필렌의 제조방법

Family Cites Families (75)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3127133A1 (de) * 1981-07-09 1983-01-27 Hoechst Ag, 6000 Frankfurt Verfahren zur herstellung von polyolefinen und deren copolymerisaten
US5324800A (en) * 1983-06-06 1994-06-28 Exxon Chemical Patents Inc. Process and catalyst for polyolefin density and molecular weight control
US4530914A (en) * 1983-06-06 1985-07-23 Exxon Research & Engineering Co. Process and catalyst for producing polyethylene having a broad molecular weight distribution
US4937299A (en) * 1983-06-06 1990-06-26 Exxon Research & Engineering Company Process and catalyst for producing reactor blend polyolefins
DE3508887A1 (de) * 1985-03-13 1986-09-25 Hoechst Ag, 6230 Frankfurt Verfahren zur herstellung von optisch aktiven polyolefinen
US4808561A (en) * 1985-06-21 1989-02-28 Exxon Chemical Patents Inc. Supported polymerization catalyst
US4665208A (en) * 1985-07-11 1987-05-12 Exxon Chemical Patents Inc. Process for the preparation of alumoxanes
US4701432A (en) * 1985-11-15 1987-10-20 Exxon Chemical Patents Inc. Supported polymerization catalyst
DE3782243T2 (de) * 1986-08-26 1993-03-04 Mitsui Petrochemical Ind Katalysator zur polymerisierung von alpha-olefin und verfahren.
WO1988002378A1 (en) * 1986-09-24 1988-04-07 Mitsui Petrochemical Industries, Ltd. Process for polymerizing olefin
JPH0780933B2 (ja) * 1986-11-20 1995-08-30 三井石油化学工業株式会社 オレフインの重合方法
JP2618384B2 (ja) * 1986-12-27 1997-06-11 三井石油化学工業株式会社 オレフイン重合用固体触媒およびその製法
DE3789666T2 (de) * 1986-12-30 1994-08-04 Mitsui Petrochemical Ind Fester katalysator für die olefinpolymerisation und verfahren zu dessen herstellung.
PL276385A1 (en) * 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
IL85097A (en) * 1987-01-30 1992-02-16 Exxon Chemical Patents Inc Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes
JPH0742301B2 (ja) * 1987-02-14 1995-05-10 三井石油化学工業株式会社 微粒子状アルミノオキサン、その製法およびその用途
US4769910A (en) * 1987-03-30 1988-09-13 Northern Telecom Limited Cutting tool for cylindrical articles
JP2538588B2 (ja) * 1987-04-03 1996-09-25 三井石油化学工業株式会社 オレフイン重合用固体触媒の製法
US5206199A (en) * 1987-04-20 1993-04-27 Mitsui Petrochemical Industries, Ltd. Catalyst for polymerizing an olefin and process for polymerizing an olefin
US5017714A (en) * 1988-03-21 1991-05-21 Exxon Chemical Patents Inc. Silicon-bridged transition metal compounds
US5120867A (en) * 1988-03-21 1992-06-09 Welborn Jr Howard C Silicon-bridged transition metal compounds
US4871705A (en) * 1988-06-16 1989-10-03 Exxon Chemical Patents Inc. Process for production of a high molecular weight ethylene a-olefin elastomer with a metallocene alumoxane catalyst
US5155080A (en) * 1988-07-15 1992-10-13 Fina Technology, Inc. Process and catalyst for producing syndiotactic polyolefins
US4892851A (en) * 1988-07-15 1990-01-09 Fina Technology, Inc. Process and catalyst for producing syndiotactic polyolefins
DE68919156T3 (de) * 1988-08-05 2002-08-14 Fina Technology Verfahren zur Herstellung grosser symmetrischer Polymerteilchen.
US5091352A (en) * 1988-09-14 1992-02-25 Mitsui Petrochemical Industries, Ltd. Olefin polymerization catalyst component, olefin polymerization catalyst and process for the polymerization of olefins
US4908463A (en) * 1988-12-05 1990-03-13 Ethyl Corporation Aluminoxane process
US5103031A (en) * 1989-02-21 1992-04-07 Ethyl Corporation Falling film aluminoxane process
DE3907964A1 (de) * 1989-03-11 1990-09-13 Hoechst Ag Verfahren zur herstellung eines syndiotaktischen polyolefins
US4968827A (en) * 1989-06-06 1990-11-06 Ethyl Corporation Alkylaluminoxane process
US4924018A (en) * 1989-06-26 1990-05-08 Ethyl Corporation Alkylaluminoxane process
DE3929693A1 (de) * 1989-09-07 1991-03-14 Hoechst Ag Verfahren zur herstellung eines polyolefinwachses
US5057475A (en) * 1989-09-13 1991-10-15 Exxon Chemical Patents Inc. Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization
US5026798A (en) * 1989-09-13 1991-06-25 Exxon Chemical Patents Inc. Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system
US5763549A (en) * 1989-10-10 1998-06-09 Fina Technology, Inc. Cationic metallocene catalysts based on organoaluminum anions
DE69018376T3 (de) * 1989-10-30 2002-05-16 Fina Technology Herstellung von Metallocenkatalysatoren für Olefinpolymerisation.
JP3131218B2 (ja) * 1989-12-06 2001-01-31 トランスウィッチ・コーポレーション 波形整形トランスバーサルフィルタ
EP0627448B2 (en) * 1990-01-02 2008-03-19 ExxonMobil Chemical Patents Inc. Supported ionic metallocene catalysts for olefin polymerization
EP0476148B1 (en) * 1990-04-09 1995-08-23 MITSUI TOATSU CHEMICALS, Inc. Propylene copolymer
CA2085581C (en) * 1990-06-22 2002-07-30 Joann Marie Canich Aluminum-free monocyclopentadienyl metallocene catalysts for olefin polymerization
EP0500944B1 (en) * 1990-07-24 1998-10-07 Mitsui Chemicals, Inc. Catalyst for alpha-olefin polymerization and production of poly-alpha-olefin therewith
CA2090962A1 (en) * 1990-09-14 1992-03-15 Howard W. Turner Ionic catalyst for the production of poly-.alpha.-olefins of controlled tacticity
US5189192A (en) * 1991-01-16 1993-02-23 The Dow Chemical Company Process for preparing addition polymerization catalysts via metal center oxidation
DE4120009A1 (de) * 1991-06-18 1992-12-24 Basf Ag Loesliche katalysatorsysteme zur herstellung von polyalk-1-enen mit hohen molmassen
US5721185A (en) * 1991-06-24 1998-02-24 The Dow Chemical Company Homogeneous olefin polymerization catalyst by abstraction with lewis acids
US5308815A (en) * 1991-07-26 1994-05-03 Ethyl Corporation Heterogeneous methylaluminoxane catalyst system
US5157137A (en) * 1991-07-26 1992-10-20 Ethyl Corporation Method of making gel free alkylaluminoxane solutions
US5235081A (en) * 1992-03-18 1993-08-10 Ethyl Corporation Method of removing gel forming materials from methylaluminoxanes
TW300901B (pt) * 1991-08-26 1997-03-21 Hoechst Ag
DE4130299A1 (de) * 1991-09-12 1993-03-18 Basf Ag Verfahren zur herstellung von polypropylen unter hochdruck
JP3394997B2 (ja) * 1991-10-15 2003-04-07 バーゼル・ポリオレフィン・ゲゼルシャフト・ミト・ベシュレンクテル・ハフツング 特異的に置換されたインデニル配位子を持つメタロセンを用いてオレフィンポリマーを製造する方法
DE69207348T2 (de) * 1991-10-28 1996-06-27 Shell Int Research Katalisatorzusammensetzung
WO1993019103A1 (en) * 1992-03-16 1993-09-30 Exxon Chemical Patents Inc. IONIC CATALYST FOR THE PRODUCTION OF POLY-α-OLEFINS OF CONTROLLED TACTICITY
US5329032A (en) * 1992-03-18 1994-07-12 Akzo Chemicals Inc. Polymethylaluminoxane of enhanced solution stability
EP0578838A1 (en) * 1992-04-29 1994-01-19 Hoechst Aktiengesellschaft Olefin polymerization catalyst, process for its preparation, and its use
US5350723A (en) * 1992-05-15 1994-09-27 The Dow Chemical Company Process for preparation of monocyclopentadienyl metal complex compounds and method of use
US5240894A (en) * 1992-05-18 1993-08-31 Exxon Chemical Patents Inc. Method for making and using a supported metallocene catalyst system
JP3186218B2 (ja) * 1992-05-20 2001-07-11 出光興産株式会社 末端ビニルエチレン−プロピレン共重合体およびその製造方法
US5434115A (en) * 1992-05-22 1995-07-18 Tosoh Corporation Process for producing olefin polymer
ES2113900T3 (es) * 1992-06-13 1998-05-16 Targor Gmbh Proceso para la preparacion de catalizadores de metalocenos quirales, puenteados del tipo bisindenilo.
US5710222A (en) * 1992-06-22 1998-01-20 Fina Technology, Inc. Method for controlling the melting points and molecular weights of syndiotactic polyolefins using metallocene catalyst systems
DE69331112T2 (de) * 1992-08-05 2002-06-20 Exxonmobil Chem Patents Inc Ionische übergangsmetallkatalysatoreren auf träger für olefinpolymerisation
US5248801A (en) * 1992-08-27 1993-09-28 Ethyl Corporation Preparation of methylaluminoxanes
KR100287389B1 (ko) * 1992-10-02 2001-04-16 그래햄 이. 테일러 올레핀 중합반응을 위한 지지된 균일한 촉매(supported homogeneous catalyst complexes for olefin polymerization)
WO1994010216A1 (en) * 1992-10-28 1994-05-11 Idemitsu Kosan Co., Ltd. Olefin copolymers and process for producing the same
US5939346A (en) * 1992-11-02 1999-08-17 Akzo Nobel N.V. Catalyst system comprising an aryloxyaluminoxane containing an electron withdrawing group
EP0705281B1 (en) * 1993-05-25 1998-03-11 Exxon Chemical Patents Inc. Supported metallocene catalyst systems for the polymerization of olefins, preparation and use thereof
JP3501408B2 (ja) * 1993-06-18 2004-03-02 出光興産株式会社 エチレン系共重合体の製造方法
JPH10501288A (ja) * 1994-06-09 1998-02-03 エクソン ケミカル パテンツ インコーポレイテッド メタロセン触媒系を用いる非エチレンα−オレフィンホモポリマー及びコポリマーの希釈重合方法
PL182074B1 (en) * 1994-06-24 2001-11-30 Exxon Chemical Patents Inc Catalytic systems for polymerisation processes, their production and application
EP0766702B1 (en) * 1994-06-24 2001-10-17 ExxonMobil Chemical Patents Inc. Polymerization catalyst systems, their production and use
US5972823A (en) * 1994-08-03 1999-10-26 Exxon Chemical Patents Inc Supported ionic catalyst composition
US5696213A (en) * 1995-04-21 1997-12-09 Exxon Chemical Patents Inc. Ethylene-α-olefin-diolefin elastomers solution polymerization process
ES2176466T3 (es) * 1995-07-06 2002-12-01 Exxonmobil Chem Patents Inc Metodo para producir sistemas cataliticos de metaloceno soportados y polimerizados previamente.
US6660809B1 (en) * 1997-02-07 2003-12-09 Exxonmobil Chemical Patents Inc. Propylene polymers incorporating polyethylene macromers

Also Published As

Publication number Publication date
EP1040140B1 (en) 2004-07-28
CA2304288A1 (en) 1999-06-17
JP2001525461A (ja) 2001-12-11
EP1040140A1 (en) 2000-10-04
DE69825316D1 (de) 2004-09-02
KR20010031058A (ko) 2001-04-16
US6117962A (en) 2000-09-12
WO1999029743A1 (en) 1999-06-17
DE69825316T2 (de) 2005-05-12
CN1274367A (zh) 2000-11-22
CN1106407C (zh) 2003-04-23
ES2224453T3 (es) 2005-03-01

Similar Documents

Publication Publication Date Title
BR9813496A (pt) MacrÈmeros estereoespecìficos de polipropileno contendo vinila
BR9806952A (pt) Preparação de macrÈmeros contendo vinila.
CA2226195A1 (en) Block copolymer, block copolymer composition and heat shrinkable films made thereof
BR9813031A (pt) Polìmeros de propileno incorporando macrÈmeros
HUP0202644A2 (hu) Fémorganikus katalizátorkompozíciók
BR9815112A (pt) Processo para a preparação de polìmeros sintéticos com teor de monÈmeros restantes muito baixo, produtos preparados a partir dos mesmos e seu emprego
BR9813438A (pt) Sistemas catalisadores de polimerização, seus usos, seus produtos e artigos do mesmo
EP2261266A3 (en) Process for the polymerization of a monomer with a catalyst composition containing an organometal compound, an organoaluminum compound and a treated solid oxide compound
BR8206546A (pt) Processo para produzir uma composicao de copolimero em bloco de propileno e composicao
NO934729L (no) Fremgangsmåte for fremstilling av en blanding som inneholder etylenpolymerer, blanding som inneholder etylenpolymerer, og anvendelse av blandingen
TR199800375A2 (xx) Selant kompozisyonları.
NO20005803D0 (no) Fremgangsmåte til fremstilling av amorf polyalfaolefiner med særlig höy molekylvekt
BR9813439A (pt) Polìmeros de propileno elastoméricos
WO2003091311A8 (en) Monomers containing polyoxyalkylenes and polymer supports therefrom
BR9913647A (pt) Composições de polipropileno ramificado
HK1033330A1 (en) Polymeric products containing modified carbon products and methods of making and using the same
DE60011897D1 (de) Verfahren zur herstellung von alpha-olefin polymeren
BR0214136A (pt) Polìmeros de enxerto, processo para a preparação e uso dos mesmos
SE9603683D0 (sv) A method of compounding a multimodal polymer composition
AU2240999A (en) Improved olefin polymerization process
EP0705849A4 (en) PROCESS FOR PRODUCING OLEFINIC POLYMER, AND CATALYST FOR POLYMERIZATION OF OLEFIN
WO2003018647A1 (fr) Polypropylene
BR8607057A (pt) Composicoes de polimeros de etileno,processo para a sua preparacao e sua aplicacao para a obtencao de artigos industriais
AU5388199A (en) Process for the hydrogenation of a polymer composed of diene monomer units and nitrile group containing monomer units and hydrogenated polymer
TW367335B (en) Cyclo-olefin polymers and preparation process thereof

Legal Events

Date Code Title Description
B06A Notification to applicant to reply to the report for non-patentability or inadequacy of the application [chapter 6.1 patent gazette]
B11B Dismissal acc. art. 36, par 1 of ipl - no reply within 90 days to fullfil the necessary requirements