HRP20210214T1 - Sustavi i postupci za obnovu olova iz baterija s olovnom kiselinom - Google Patents
Sustavi i postupci za obnovu olova iz baterija s olovnom kiselinom Download PDFInfo
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- HRP20210214T1 HRP20210214T1 HRP20210214TT HRP20210214T HRP20210214T1 HR P20210214 T1 HRP20210214 T1 HR P20210214T1 HR P20210214T T HRP20210214T T HR P20210214TT HR P20210214 T HRP20210214 T HR P20210214T HR P20210214 T1 HRP20210214 T1 HR P20210214T1
- Authority
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- Prior art keywords
- lead
- cathode
- base
- ion solution
- acid
- Prior art date
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- 238000000034 method Methods 0.000 title claims 17
- 239000002253 acid Substances 0.000 title claims 8
- 238000011084 recovery Methods 0.000 title 1
- 239000002585 base Substances 0.000 claims 13
- RVPVRDXYQKGNMQ-UHFFFAOYSA-N lead(2+) Chemical compound [Pb+2] RVPVRDXYQKGNMQ-UHFFFAOYSA-N 0.000 claims 11
- YADSGOSSYOOKMP-UHFFFAOYSA-N dioxolead Chemical compound O=[Pb]=O YADSGOSSYOOKMP-UHFFFAOYSA-N 0.000 claims 10
- 229910000464 lead oxide Inorganic materials 0.000 claims 9
- HTUMBQDCCIXGCV-UHFFFAOYSA-N lead oxide Chemical compound [O-2].[Pb+2] HTUMBQDCCIXGCV-UHFFFAOYSA-N 0.000 claims 9
- 239000006228 supernatant Substances 0.000 claims 9
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims 7
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims 6
- 239000002244 precipitate Substances 0.000 claims 5
- 150000003839 salts Chemical class 0.000 claims 5
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims 4
- 239000003638 chemical reducing agent Substances 0.000 claims 4
- 150000002500 ions Chemical class 0.000 claims 4
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims 3
- 150000001335 aliphatic alkanes Chemical class 0.000 claims 3
- MFEVGQHCNVXMER-UHFFFAOYSA-L 1,3,2$l^{2}-dioxaplumbetan-4-one Chemical compound [Pb+2].[O-]C([O-])=O MFEVGQHCNVXMER-UHFFFAOYSA-L 0.000 claims 2
- FUSNOPLQVRUIIM-UHFFFAOYSA-N 4-amino-2-(4,4-dimethyl-2-oxoimidazolidin-1-yl)-n-[3-(trifluoromethyl)phenyl]pyrimidine-5-carboxamide Chemical compound O=C1NC(C)(C)CN1C(N=C1N)=NC=C1C(=O)NC1=CC=CC(C(F)(F)F)=C1 FUSNOPLQVRUIIM-UHFFFAOYSA-N 0.000 claims 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims 2
- 229910000003 Lead carbonate Inorganic materials 0.000 claims 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims 2
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 claims 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 claims 2
- 239000003513 alkali Substances 0.000 claims 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 2
- 238000005868 electrolysis reaction Methods 0.000 claims 2
- 229910000377 hydrazine sulfate Inorganic materials 0.000 claims 2
- 239000012493 hydrazine sulfate Substances 0.000 claims 2
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 claims 2
- RYZCLUQMCYZBJQ-UHFFFAOYSA-H lead(2+);dicarbonate;dihydroxide Chemical compound [OH-].[OH-].[Pb+2].[Pb+2].[Pb+2].[O-]C([O-])=O.[O-]C([O-])=O RYZCLUQMCYZBJQ-UHFFFAOYSA-H 0.000 claims 2
- 229910021514 lead(II) hydroxide Inorganic materials 0.000 claims 2
- CSMWJXBSXGUPGY-UHFFFAOYSA-L sodium dithionate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)S([O-])(=O)=O CSMWJXBSXGUPGY-UHFFFAOYSA-L 0.000 claims 2
- 229940075931 sodium dithionate Drugs 0.000 claims 2
- 229910000838 Al alloy Inorganic materials 0.000 claims 1
- 229910001854 alkali hydroxide Inorganic materials 0.000 claims 1
- 229910001860 alkaline earth metal hydroxide Inorganic materials 0.000 claims 1
- -1 alkaline-earth metals hydroxide Chemical class 0.000 claims 1
- 229910052782 aluminium Inorganic materials 0.000 claims 1
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 238000006073 displacement reaction Methods 0.000 claims 1
- PIJPYDMVFNTHIP-UHFFFAOYSA-L lead sulfate Chemical compound [PbH4+2].[O-]S([O-])(=O)=O PIJPYDMVFNTHIP-UHFFFAOYSA-L 0.000 claims 1
- 229940098779 methanesulfonic acid Drugs 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 238000004064 recycling Methods 0.000 claims 1
- 230000001172 regenerating effect Effects 0.000 claims 1
- 238000000926 separation method Methods 0.000 claims 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
- C22B7/006—Wet processes
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B13/00—Obtaining lead
- C22B13/04—Obtaining lead by wet processes
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B13/00—Obtaining lead
- C22B13/04—Obtaining lead by wet processes
- C22B13/045—Recovery from waste materials
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/205—Treatment or purification of solutions, e.g. obtained by leaching using adducts or inclusion complexes
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/22—Treatment or purification of solutions, e.g. obtained by leaching by physical processes, e.g. by filtration, by magnetic means, or by thermal decomposition
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/44—Treatment or purification of solutions, e.g. obtained by leaching by chemical processes
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B5/00—General methods of reducing to metals
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/22—Inorganic acids
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B15/00—Operating or servicing cells
- C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
- C25C1/18—Electrolytic production, recovery or refining of metals by electrolysis of solutions of lead
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/06—Lead-acid accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/54—Reclaiming serviceable parts of waste accumulators
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/84—Recycling of batteries or fuel cells
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Mechanical Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- Geochemistry & Mineralogy (AREA)
- Secondary Cells (AREA)
- Electrolytic Production Of Metals (AREA)
- Processing Of Solid Wastes (AREA)
- Manufacture And Refinement Of Metals (AREA)
Claims (15)
1. Postupak recikliranja olova iz olovne paste baterije s olovnom kiselinom, koji obuhvaća:
dovođenje u kontakt olovne paste s bazom da bi se time stvorio supernatant koji obuhvaća topljivu sulfatnu sol i talog koji obuhvaća netopivu olovnu sol;
odvajanje supernatanta od taloga;
regenerirajući najmanje dio baze iz supernatanta pomoću prve elektrokemijske stanice;
dovođenje u kontakt taloga s regeneriranom alkanskom sulfonskom kiselinom da bi se generirala mješavina koja obuhvaća otopinu iona olova i netopljivi dioksid olova;
dovođenje u dodir netopljivog dioksida olova s redukcijskim agensom da bi se time pretvorio dioksid olova u oksid olova;
kombiniranje oksida olova s otopinom iona olova da bi se formirala kombinirana otopina iona olova;
podvrgavanje kombinirane otopine ion olova električnom potencijalu u drugoj elektrokemijskoj stanici da bi se time kontinuirano stvorilo olovo na prvom dijelu pokretne katode i da bi se generirala regenerirana alkanska sulfonska kiselina; i
prikupljanje olova iz drugog dijela katode dok se kontinuirano stvara olovo na prvom dijelu katode za proizvodnju nove baterije s olovnom kiselinom.
2. Postupak sukladno patentnom zahtjevu 1, pri čemu baza obuhvaća najmanje jedan od alkalnog ili alkalin-zemnog metala hidroksida i karbonat, i netopljiva olovna sol obuhvaća najmanje jedan od oksida olova, hidroksida olova, i karbonata olova ili pri čemu je baza dodana u količini dovoljnoj da proizvede supernatant koji obuhvaća topljivu sol sulfata i talog obuhvaća netopljivu sol sulfata bez značajnije proizvodnje plumbata.
3. Postupak sukladno patentnom zahtjevu 1, pri čemu ta regenerirana alkanska sulfonska kiselina obuhvaća metansulfonsku kiselinu.
4. Postupak sukladno patentnom zahtjevu 1, pri čemu redukcijski agens obuhvaća vodik peroksid, dikarboksilnu kiselinu, metalno olovo, sulfit, hidrazin sulfat, ili natrij ditionat.
5. Postupak sukladno patentnom zahtjevu 1, pri čemu katoda pokazuje rotacijsko kretanje dok se primjenjuje električni potencijal, tako da se olovo taloži na katodi uklonjeno sukladno kombiniranoj otopini iona olova.
6. Postupak sukladno patentnom zahtjevu 1, nadalje obuhvaća elektrolizu supernatanta koji obuhvaća topljivu sulfatnu sol da bi se proizvela regenerirana baza i sumporna kiselina i pri čemu najmanje dio količine baze u koraku dovođenja u kontakt olovne paste obuhvaća regeneriranu bazu ili nadalje obuhvaća prikupljanje sumporne kiseline za proizvodnju nove baterije s olovnom kiselinom.
7. Postupak sukladno patentnom zahtjevu 1, pri čemu kombiniranje oksida olova još obuhvaća dovođenje oksida olova do otopine za ion olova čime se stvara kombinirana otopina iona olova.
8. Postupak sukladno patentnom zahtjevu 1, pri čemu kombiniranje oksida olova nadalje obuhvaća dovođenje u dodir oksida olova s drugim dijelom alkanske sulfonske kiseline da bi se time generirala druga otopina iona olova, i kombiniranje otopine iona olova i druge otopine iona olova da bi se stvorila kombinirana otopina iona olova.
9. Postupak oporavka olova sukladno olovne paste baterije s olovnom kiselinom, pri čemu pasta olova obuhvaća sulfat olova i dioksid olova, taj postupak obuhvaća:
dovođenje u kontakt olovna paste s redukcijskim agensom da bi se reducirao dioksid olova u oksid olova i time formirala predobrađena pasta olova;
dovođenje u kontakt predobrađene olovne paste s bazom da bi se time generirao supernatant koji obuhvaća topljivu sol sulfata i istaloženi dio koji obuhvaća netopljivu olovnu sol;
odvajanje supernatanta sukladno istaloženog sadržaja;
dovođenje u kontakt s alkanskom sulfonskom kiselinom da bi se generirala otopina iona olova;
nanošenje električnog potencijala na katodu u dodiru s otopinom iona olova da bi se time neprekidno stvorilo ljepljivo olovo na prvi dio katode i da bi se regenerirala alkan sulfonska kiselina; i
uklanjanje ljepljivog olova sukladno drugog dijela katode dok se kontinuirano stvara ljepljivo olovo na prvom dijelu katode.
10. Postupak sukladno patentnom zahtjevu 9, pri čemu je baza dodana u količini dovoljnoj da proizvode supernatant koji obuhvaća topljivu sol sulfata i istaloženi sadržaj obuhvaća netopljivu sol olova bez značajnije proizvodnje plumbata, ili pri čemu baza obuhvaća najmanje jedno od alkalnog ili alkalin-zemnog metal hidroksida i karbonata, i topljiva sol olova obuhvaća najmanje oksid olova, hidroksid olova, i karbonat olova.
11. Postupak sukladno patentnom zahtjevu 9, pri čemu je taj istaloženi sadržaj pretežno bez sulfata.
12. Postupak sukladno patentnom zahtjevu 9, pri čemu redukcijski agens obuhvaća vodik peroksid, dikarboksilnu kiselinu, metalno olovo, sulfit, hidrazin sulfat, ili natrij ditionat.
13. Postupak sukladno patentnom zahtjevu 9, pri čemu se katoda pomjera u odnosu na otopinu jona olova dok se nanosi električni potencijal, ili pri čemu ta katoda ispoljava rotacijsko pomjeranje dok se primjenjuje električni potencijal, tako da je olovo pohranjeno na katodi uklonjeno sukladno otopini iona olova.
14. Postupak sukladno patentnom zahtjevu 9, pri čemu ta katoda obuhvaća aluminij, leguru aluminij, ili prah aluminija umetnut u plastiku.
15. Postupak sukladno patentnom zahtjevu 9, još obuhvaća elektrolizu supernatanta koji obuhvaća topljivu sulfatnu sol da bi se proizvela regenerirana baza i sumporna kiselina, i pri čemu se najmanje neka količina baze dovodi u dodir olovne paste obuhvaća regeneriranom bazom.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201562160844P | 2015-05-13 | 2015-05-13 | |
| PCT/US2016/032332 WO2016183428A1 (en) | 2015-05-13 | 2016-05-13 | Systems and methods for recovery of lead from lead acid batteries |
| EP16793599.8A EP3294916B1 (en) | 2015-05-13 | 2016-05-13 | Systems and methods for recovery of lead from lead acid batteries |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| HRP20210214T1 true HRP20210214T1 (hr) | 2021-03-19 |
Family
ID=57248554
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| HRP20210214TT HRP20210214T1 (hr) | 2015-05-13 | 2021-02-08 | Sustavi i postupci za obnovu olova iz baterija s olovnom kiselinom |
Country Status (23)
| Country | Link |
|---|---|
| US (1) | US11028460B2 (hr) |
| EP (1) | EP3294916B1 (hr) |
| JP (1) | JP6805240B2 (hr) |
| KR (1) | KR102274210B1 (hr) |
| CN (2) | CN110343862A (hr) |
| AU (1) | AU2016260407B2 (hr) |
| BR (1) | BR112017024433B1 (hr) |
| CA (1) | CA2986022C (hr) |
| CL (1) | CL2017002874A1 (hr) |
| CY (1) | CY1123795T1 (hr) |
| DK (1) | DK3294916T3 (hr) |
| ES (1) | ES2848389T3 (hr) |
| HR (1) | HRP20210214T1 (hr) |
| HU (1) | HUE052705T2 (hr) |
| LT (1) | LT3294916T (hr) |
| MX (1) | MX2017014539A (hr) |
| PE (1) | PE20180144A1 (hr) |
| PL (1) | PL3294916T3 (hr) |
| PT (1) | PT3294916T (hr) |
| RS (1) | RS61647B1 (hr) |
| SI (1) | SI3294916T1 (hr) |
| UA (1) | UA124523C2 (hr) |
| WO (1) | WO2016183428A1 (hr) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AP2016009279A0 (en) | 2013-11-19 | 2016-06-30 | Aqua Metals Inc | Devices and method for smelterless recycling of lead acid batteries |
| PE20180144A1 (es) | 2015-05-13 | 2018-01-18 | Aqua Metals Inc | Sistemas y metodos para recuperacion de plomo de baterias de plomo acido |
| WO2016183429A1 (en) | 2015-05-13 | 2016-11-17 | Aqua Metals Inc. | Closed loop systems and methods for recycling lead acid batteries |
| US10689769B2 (en) | 2015-05-13 | 2020-06-23 | Aqua Metals Inc. | Electrodeposited lead composition, methods of production, and uses |
| US10316420B2 (en) | 2015-12-02 | 2019-06-11 | Aqua Metals Inc. | Systems and methods for continuous alkaline lead acid battery recycling |
| CN106834679B (zh) * | 2017-02-22 | 2018-08-17 | 中南大学 | 磺酸溶液两段逆流加压氧化浸出硫化铅精矿中铅的方法 |
| GB201812664D0 (en) | 2018-08-03 | 2018-09-19 | Imperial Innovations Ltd | Recycling of lead-and tin-based materials |
| JP6550582B1 (ja) * | 2018-11-27 | 2019-07-31 | 株式会社ジェーエフシーテック | 鉛の製造方法および製造設備 |
| CN109763143B (zh) * | 2019-01-22 | 2020-01-21 | 华中科技大学 | 一种废铅酸电池的资源化回收处理方法 |
| CN111740183B (zh) * | 2020-07-06 | 2021-09-28 | 广西电网有限责任公司柳州供电局 | 一种基于水的重力可以高效回收蓄电池的设备 |
| CN112018467A (zh) * | 2020-09-08 | 2020-12-01 | 太和县大华能源科技有限公司 | 一种铅酸蓄电池铅膏回收装置与回收方法 |
| CN112366380B (zh) * | 2020-10-21 | 2021-09-28 | 骆驼集团(安徽)再生资源有限公司 | 一种铅酸蓄电池的废酸回收工艺 |
| CN112359210B (zh) * | 2020-11-09 | 2023-04-14 | 湖南省汨罗锦胜智造科技股份有限公司 | 一种从废旧铅酸蓄电池中回收铅的办法 |
| CN113136492B (zh) * | 2021-03-30 | 2023-03-10 | 广西大学 | 一种从废铅膏中回收铅的方法 |
| CN113740320A (zh) * | 2021-09-26 | 2021-12-03 | 北京化工大学 | 一种废旧铅酸蓄电池回收过程中的铜杂质含量分析方法 |
| KR102655724B1 (ko) * | 2023-10-12 | 2024-04-08 | 주식회사 원광에스앤티 | 태양광 폐모듈 습식 처리 공정 및 태양광 폐모듈 습식 처리 설비 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
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- 2016-05-13 JP JP2018511351A patent/JP6805240B2/ja active Active
- 2016-05-13 WO PCT/US2016/032332 patent/WO2016183428A1/en active Application Filing
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Also Published As
| Publication number | Publication date |
|---|---|
| CN107849634A (zh) | 2018-03-27 |
| US11028460B2 (en) | 2021-06-08 |
| DK3294916T3 (da) | 2021-02-15 |
| CL2017002874A1 (es) | 2018-02-16 |
| BR112017024433B1 (pt) | 2021-10-19 |
| CA2986022A1 (en) | 2016-11-17 |
| ES2848389T3 (es) | 2021-08-09 |
| CA2986022C (en) | 2022-06-21 |
| US20180127852A1 (en) | 2018-05-10 |
| BR112017024433A2 (pt) | 2018-11-27 |
| PE20180144A1 (es) | 2018-01-18 |
| JP6805240B2 (ja) | 2020-12-23 |
| LT3294916T (lt) | 2021-03-10 |
| KR102274210B1 (ko) | 2021-07-06 |
| KR20180012779A (ko) | 2018-02-06 |
| MX2017014539A (es) | 2018-03-12 |
| CY1123795T1 (el) | 2022-05-27 |
| RS61647B1 (sr) | 2021-04-29 |
| EP3294916A1 (en) | 2018-03-21 |
| SI3294916T1 (sl) | 2021-04-30 |
| HUE052705T2 (hu) | 2021-05-28 |
| EP3294916B1 (en) | 2020-11-18 |
| UA124523C2 (uk) | 2021-10-05 |
| AU2016260407A1 (en) | 2018-01-04 |
| PT3294916T (pt) | 2021-02-19 |
| PL3294916T3 (pl) | 2021-05-17 |
| AU2016260407B2 (en) | 2020-07-16 |
| JP2018517848A (ja) | 2018-07-05 |
| CN110343862A (zh) | 2019-10-18 |
| CN107849634B (zh) | 2019-07-30 |
| WO2016183428A1 (en) | 2016-11-17 |
| EP3294916A4 (en) | 2018-12-12 |
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