CN100400683C - 一种用含铅锌废渣或氧化铅锌矿生产金属铅和锌的方法 - Google Patents
一种用含铅锌废渣或氧化铅锌矿生产金属铅和锌的方法 Download PDFInfo
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- CN100400683C CN100400683C CNB2006101483669A CN200610148366A CN100400683C CN 100400683 C CN100400683 C CN 100400683C CN B2006101483669 A CNB2006101483669 A CN B2006101483669A CN 200610148366 A CN200610148366 A CN 200610148366A CN 100400683 C CN100400683 C CN 100400683C
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- zinc
- lead
- electrolysis
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- leaded
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- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 title claims abstract description 85
- 239000011701 zinc Substances 0.000 title claims abstract description 81
- 229910052725 zinc Inorganic materials 0.000 title claims abstract description 77
- JQJCSZOEVBFDKO-UHFFFAOYSA-N lead zinc Chemical compound [Zn].[Pb] JQJCSZOEVBFDKO-UHFFFAOYSA-N 0.000 title claims abstract description 18
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 18
- 239000002699 waste material Substances 0.000 title claims abstract description 12
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 title claims description 5
- 239000002893 slag Substances 0.000 title abstract 3
- 239000000243 solution Substances 0.000 claims abstract description 18
- 238000002386 leaching Methods 0.000 claims abstract description 15
- 229910052751 metal Inorganic materials 0.000 claims abstract description 14
- 239000002184 metal Substances 0.000 claims abstract description 14
- 239000000706 filtrate Substances 0.000 claims abstract description 11
- 239000008151 electrolyte solution Substances 0.000 claims abstract description 8
- 238000000034 method Methods 0.000 claims description 40
- 238000005868 electrolysis reaction Methods 0.000 claims description 23
- 239000002994 raw material Substances 0.000 claims description 13
- 239000003513 alkali Substances 0.000 claims description 7
- 238000005406 washing Methods 0.000 claims description 6
- 239000002585 base Substances 0.000 claims description 4
- 238000000605 extraction Methods 0.000 claims description 4
- 239000010935 stainless steel Substances 0.000 claims description 4
- 229910001069 Ti alloy Inorganic materials 0.000 claims description 3
- 239000003792 electrolyte Substances 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 238000000280 densification Methods 0.000 claims description 2
- 230000005611 electricity Effects 0.000 claims description 2
- 229910001256 stainless steel alloy Inorganic materials 0.000 claims 1
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 abstract description 7
- 239000011787 zinc oxide Substances 0.000 abstract description 4
- 238000003756 stirring Methods 0.000 abstract description 3
- 238000001035 drying Methods 0.000 abstract description 2
- 238000001914 filtration Methods 0.000 abstract description 2
- 238000000227 grinding Methods 0.000 abstract 1
- 239000011261 inert gas Substances 0.000 abstract 1
- 229910000464 lead oxide Inorganic materials 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 abstract 1
- 238000003825 pressing Methods 0.000 abstract 1
- 239000011133 lead Substances 0.000 description 27
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- 238000005265 energy consumption Methods 0.000 description 8
- 239000000203 mixture Substances 0.000 description 8
- 238000005516 engineering process Methods 0.000 description 5
- 238000003723 Smelting Methods 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 239000000428 dust Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 230000008901 benefit Effects 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
- 239000005083 Zinc sulfide Substances 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- 239000002910 solid waste Substances 0.000 description 2
- 229910052984 zinc sulfide Inorganic materials 0.000 description 2
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000010405 anode material Substances 0.000 description 1
- 239000010406 cathode material Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000003500 flue dust Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000002920 hazardous waste Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 231100000956 nontoxicity Toxicity 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000001698 pyrogenic effect Effects 0.000 description 1
- 230000002000 scavenging effect Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 230000026676 system process Effects 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 238000009858 zinc metallurgy Methods 0.000 description 1
Images
Classifications
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Abstract
Description
成分 | Zn | Pb | Cu | Fe | Al | Ca | As | Sb |
含量(%) | 37.53 | 13.69 | 2.33 | 1.13 | 0.76 | 1.31 | 0.026 | 0.017 |
成分 | Zn | Pb | Cu | Fe | Al | Ca | As | Sb |
浓度(g/L) | 35.23 | 12.87 | 0.005 | 0.05 | 0.59 | 0.17 | 0.02 | 0.01 |
成分 | Zn | Pb | Cu | Si | Al | Ca | As | Sb |
含量(%) | 14.30 | 51.61 | 0.88 | 0.25 | 0.46 | 2.21 | 0.33 | 2.06 |
成分 | Zn | Pb | Cu | Si | Al | Ca | As | Sb |
浓度(g/L) | 4.77 | 19.84 | 0.20 | 0.06 | 0.18 | 0.4 | 0.10 | 0.13 |
Claims (1)
Priority Applications (1)
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CNB2006101483669A CN100400683C (zh) | 2006-12-30 | 2006-12-30 | 一种用含铅锌废渣或氧化铅锌矿生产金属铅和锌的方法 |
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CNB2006101483669A CN100400683C (zh) | 2006-12-30 | 2006-12-30 | 一种用含铅锌废渣或氧化铅锌矿生产金属铅和锌的方法 |
Publications (2)
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CN101012514A CN101012514A (zh) | 2007-08-08 |
CN100400683C true CN100400683C (zh) | 2008-07-09 |
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CNB2006101483669A Expired - Fee Related CN100400683C (zh) | 2006-12-30 | 2006-12-30 | 一种用含铅锌废渣或氧化铅锌矿生产金属铅和锌的方法 |
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Families Citing this family (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100586617C (zh) * | 2007-05-29 | 2010-02-03 | 于军 | 从含锌粉料中回收并制取超细锌粉的方法 |
CN101698952B (zh) * | 2009-10-30 | 2012-02-15 | 施熊飞 | 湿法制取锌粉的工艺 |
CN101760757B (zh) * | 2009-12-09 | 2012-05-23 | 王树楷 | 硫酸铅物料电解碱浸生产铅的方法 |
CN102787239A (zh) * | 2011-05-20 | 2012-11-21 | 鹰潭市精鹰铜业有限公司 | 碱法分离含铜铅锌烟灰工艺 |
US8524177B2 (en) * | 2011-09-09 | 2013-09-03 | Canadus Chemical LLC | Process for purifying zinc oxide |
CN102329963A (zh) * | 2011-09-28 | 2012-01-25 | 界首市骏马工贸有限公司 | 含铅烟道灰中铅的高效节能分离提取制备装置 |
CN103255442B (zh) * | 2012-02-16 | 2015-07-29 | 同济大学 | 一种添加含铅化合物碱液电解制备超细锌粉的方法 |
AU2013302212B2 (en) * | 2012-08-07 | 2017-08-03 | Glencore Queensland Limited | Recovery of zinc from lead slag |
CN102888624A (zh) * | 2012-11-06 | 2013-01-23 | 江西自立资源再生有限公司 | 一种含锌碱液旋流电解生产超细锌粉的方法 |
WO2015003537A1 (zh) * | 2013-07-12 | 2015-01-15 | Zhang Chao | 一种碱性溶液中的金属电解方法 |
PL3072180T3 (pl) | 2013-11-19 | 2019-09-30 | Aqua Metals Inc. | Urządzenia i sposób recyklingu bez wytapiania akumulatorów kwasowo-ołowiowych |
CN104195559A (zh) * | 2014-08-22 | 2014-12-10 | 南开大学 | 一种钢管表面锌层退镀及回收锌的方法 |
CN104593602A (zh) * | 2014-12-31 | 2015-05-06 | 上海第二工业大学 | 一种从废旧含铅玻璃碱性浸出液中提取金属铅的方法 |
ES2880798T3 (es) | 2015-05-13 | 2021-11-25 | Aqua Metals Inc | Sistemas y métodos de ciclo cerrado para reciclar baterías de plomo-ácido |
CN107923057B (zh) | 2015-05-13 | 2020-07-14 | 艾库伊金属有限公司 | 电沉积铅组合物、生产方法和用途 |
DK3294916T3 (da) | 2015-05-13 | 2021-02-15 | Aqua Metals Inc | Systemer og fremgangsmåder til genindvinding af bly fra blysyrebatterier |
CN105039691A (zh) * | 2015-08-25 | 2015-11-11 | 四川华富宇科技有限责任公司 | 一种电氧化浸出低品位氧化铅锌矿石的方法及其浸出设备 |
US10316420B2 (en) * | 2015-12-02 | 2019-06-11 | Aqua Metals Inc. | Systems and methods for continuous alkaline lead acid battery recycling |
CN107385472B (zh) * | 2017-06-29 | 2019-03-19 | 泸溪蓝天高科有限责任公司 | 一种电解锌的生产方法 |
CN107460500A (zh) * | 2017-08-15 | 2017-12-12 | 江西金铂铼资源循环新技术有限公司 | 含铅次氧化锌铵浸液旋流电积生产电铅的方法 |
CN111455183B (zh) * | 2020-05-14 | 2022-03-01 | 沈阳鑫迪环境技术有限公司 | 一种废轮胎裂解炭黑净化协同回收铅、锌的方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1450182A (zh) * | 2003-05-07 | 2003-10-22 | 同济大学 | 一种用氧化锌矿生产高纯度金属锌的方法 |
WO2005007904A1 (en) * | 2003-07-18 | 2005-01-27 | Kandy S. A. | Process for the high yield recovery of lead from spent lead-acid batteries with reduced associated production of slag and gaseous emissions |
CN1804060A (zh) * | 2006-01-13 | 2006-07-19 | 北京科技大学 | 一种对铅锌尾矿进行铅锌复合提纯的湿化学方法 |
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2006
- 2006-12-30 CN CNB2006101483669A patent/CN100400683C/zh not_active Expired - Fee Related
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1450182A (zh) * | 2003-05-07 | 2003-10-22 | 同济大学 | 一种用氧化锌矿生产高纯度金属锌的方法 |
WO2005007904A1 (en) * | 2003-07-18 | 2005-01-27 | Kandy S. A. | Process for the high yield recovery of lead from spent lead-acid batteries with reduced associated production of slag and gaseous emissions |
CN1804060A (zh) * | 2006-01-13 | 2006-07-19 | 北京科技大学 | 一种对铅锌尾矿进行铅锌复合提纯的湿化学方法 |
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CN101012514A (zh) | 2007-08-08 |
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Effective date of registration: 20110809 Address after: Baiyun road 650224 Yunnan city of Kunming province No. 548 Dan Tong modern city 18 building B8 room Patentee after: KUNMING TONGYUE TECHNOLOGY DEVELOPMENT CO.,LTD. Address before: 1239 Siping Road, Shanghai, No. 200092 Patentee before: Tongji University |
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