ES2674334T3 - Materiales de electrodo positivo: métodos para su preparación y su uso en baterías de litio secundarias - Google Patents
Materiales de electrodo positivo: métodos para su preparación y su uso en baterías de litio secundarias Download PDFInfo
- Publication number
- ES2674334T3 ES2674334T3 ES12839054.9T ES12839054T ES2674334T3 ES 2674334 T3 ES2674334 T3 ES 2674334T3 ES 12839054 T ES12839054 T ES 12839054T ES 2674334 T3 ES2674334 T3 ES 2674334T3
- Authority
- ES
- Spain
- Prior art keywords
- positive electrode
- carbon material
- mixture
- carbon
- electrode material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000007774 positive electrode material Substances 0.000 title claims abstract description 40
- 229910052744 lithium Inorganic materials 0.000 title claims abstract description 28
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical group [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title claims abstract description 27
- 238000000034 method Methods 0.000 title claims description 28
- 238000002360 preparation method Methods 0.000 title description 2
- 239000003575 carbonaceous material Substances 0.000 claims abstract description 72
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 51
- 239000000835 fiber Substances 0.000 claims abstract description 46
- 239000000203 mixture Substances 0.000 claims abstract description 45
- 239000002245 particle Substances 0.000 claims abstract description 37
- 239000000126 substance Substances 0.000 claims abstract description 20
- 239000006229 carbon black Substances 0.000 claims abstract description 17
- 229910052723 transition metal Inorganic materials 0.000 claims abstract description 14
- 150000003624 transition metals Chemical class 0.000 claims abstract description 14
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 10
- 150000001875 compounds Chemical class 0.000 claims abstract description 9
- 229910052751 metal Inorganic materials 0.000 claims abstract description 9
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 7
- 239000011248 coating agent Substances 0.000 claims abstract description 7
- 238000000576 coating method Methods 0.000 claims abstract description 7
- 229910052731 fluorine Inorganic materials 0.000 claims abstract description 6
- 229910052742 iron Inorganic materials 0.000 claims abstract description 6
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 6
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 6
- 229910052758 niobium Inorganic materials 0.000 claims abstract description 6
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 6
- 229910052721 tungsten Inorganic materials 0.000 claims abstract description 6
- 229910052720 vanadium Inorganic materials 0.000 claims abstract description 6
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 6
- 125000001153 fluoro group Chemical group F* 0.000 claims abstract description 5
- 229910021389 graphene Inorganic materials 0.000 claims abstract description 5
- 229910052783 alkali metal Inorganic materials 0.000 claims abstract description 4
- 150000001340 alkali metals Chemical class 0.000 claims abstract description 4
- 229910052785 arsenic Inorganic materials 0.000 claims abstract description 4
- 229910052796 boron Inorganic materials 0.000 claims abstract description 4
- 229910052732 germanium Inorganic materials 0.000 claims abstract description 4
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 4
- 125000004433 nitrogen atom Chemical group N* 0.000 claims abstract description 4
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 4
- 229910052711 selenium Inorganic materials 0.000 claims abstract description 4
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 4
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 4
- -1 lithium oxide compound Chemical class 0.000 claims description 22
- 229910021393 carbon nanotube Inorganic materials 0.000 claims description 20
- 239000002041 carbon nanotube Substances 0.000 claims description 20
- 239000000463 material Substances 0.000 claims description 15
- 229910001947 lithium oxide Inorganic materials 0.000 claims description 14
- 238000002156 mixing Methods 0.000 claims description 13
- 239000011247 coating layer Substances 0.000 claims description 11
- 229910052493 LiFePO4 Inorganic materials 0.000 claims description 10
- 239000006230 acetylene black Substances 0.000 claims description 8
- 230000006835 compression Effects 0.000 claims description 7
- 238000007906 compression Methods 0.000 claims description 7
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical group C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 7
- 239000012298 atmosphere Substances 0.000 claims description 6
- 239000003273 ketjen black Substances 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- 229920005989 resin Polymers 0.000 claims description 5
- 239000011347 resin Substances 0.000 claims description 5
- 229910000668 LiMnPO4 Inorganic materials 0.000 claims description 4
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 3
- 229910019142 PO4 Inorganic materials 0.000 claims description 3
- 239000004698 Polyethylene Substances 0.000 claims description 3
- 239000004743 Polypropylene Substances 0.000 claims description 3
- 239000002134 carbon nanofiber Substances 0.000 claims description 3
- 239000006185 dispersion Substances 0.000 claims description 3
- 125000002573 ethenylidene group Chemical group [*]=C=C([H])[H] 0.000 claims description 3
- DWYMPOCYEZONEA-UHFFFAOYSA-L fluoridophosphate Chemical compound [O-]P([O-])(F)=O DWYMPOCYEZONEA-UHFFFAOYSA-L 0.000 claims description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 3
- 239000010452 phosphate Substances 0.000 claims description 3
- 229920000573 polyethylene Polymers 0.000 claims description 3
- 229920001155 polypropylene Polymers 0.000 claims description 3
- 229920002125 Sokalan® Polymers 0.000 claims description 2
- 239000012300 argon atmosphere Substances 0.000 claims description 2
- 239000011737 fluorine Substances 0.000 claims description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 2
- 229920005992 thermoplastic resin Polymers 0.000 claims description 2
- FUJCRWPEOMXPAD-UHFFFAOYSA-N lithium oxide Chemical compound [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 claims 4
- 229910010740 LiFeSiO4 Inorganic materials 0.000 claims 2
- 239000002194 amorphous carbon material Substances 0.000 claims 2
- 238000001354 calcination Methods 0.000 claims 1
- 239000002657 fibrous material Substances 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 description 15
- 238000012360 testing method Methods 0.000 description 15
- 230000000052 comparative effect Effects 0.000 description 14
- 235000019241 carbon black Nutrition 0.000 description 11
- GELKBWJHTRAYNV-UHFFFAOYSA-K lithium iron phosphate Chemical compound [Li+].[Fe+2].[O-]P([O-])([O-])=O GELKBWJHTRAYNV-UHFFFAOYSA-K 0.000 description 10
- 229910001386 lithium phosphate Inorganic materials 0.000 description 8
- 239000010450 olivine Substances 0.000 description 8
- 229910052609 olivine Inorganic materials 0.000 description 8
- 239000000725 suspension Substances 0.000 description 8
- TWQULNDIKKJZPH-UHFFFAOYSA-K trilithium;phosphate Chemical group [Li+].[Li+].[Li+].[O-]P([O-])([O-])=O TWQULNDIKKJZPH-UHFFFAOYSA-K 0.000 description 8
- 229940125782 compound 2 Drugs 0.000 description 7
- 238000011156 evaluation Methods 0.000 description 7
- 125000005647 linker group Chemical group 0.000 description 7
- 239000004480 active ingredient Substances 0.000 description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 6
- 239000004020 conductor Substances 0.000 description 6
- 238000007599 discharging Methods 0.000 description 6
- 239000003792 electrolyte Substances 0.000 description 6
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 5
- 229910001416 lithium ion Inorganic materials 0.000 description 5
- 229910003002 lithium salt Inorganic materials 0.000 description 5
- 159000000002 lithium salts Chemical class 0.000 description 5
- 239000007773 negative electrode material Substances 0.000 description 5
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 4
- 238000001704 evaporation Methods 0.000 description 4
- 239000010408 film Substances 0.000 description 4
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 description 3
- 239000013543 active substance Substances 0.000 description 3
- 229910002804 graphite Inorganic materials 0.000 description 3
- 239000010439 graphite Substances 0.000 description 3
- 238000007689 inspection Methods 0.000 description 3
- 239000011255 nonaqueous electrolyte Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 229910021450 lithium metal oxide Inorganic materials 0.000 description 2
- 238000011068 loading method Methods 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- 239000002071 nanotube Substances 0.000 description 2
- 229920000620 organic polymer Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 239000002759 woven fabric Substances 0.000 description 2
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 229910011279 LiCoPO4 Inorganic materials 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
- 229920002544 Olefin fiber Polymers 0.000 description 1
- DJBQSLSCMPHXBH-UHFFFAOYSA-K P(=O)([O-])([O-])[O-].[Fe+2].[Li+].[Fe+2] Chemical compound P(=O)([O-])([O-])[O-].[Fe+2].[Li+].[Fe+2] DJBQSLSCMPHXBH-UHFFFAOYSA-K 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 229910021386 carbon form Inorganic materials 0.000 description 1
- 239000002322 conducting polymer Substances 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 210000001787 dendrite Anatomy 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 239000007770 graphite material Substances 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000012784 inorganic fiber Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- MCVFFRWZNYZUIJ-UHFFFAOYSA-M lithium;trifluoromethanesulfonate Chemical compound [Li+].[O-]S(=O)(=O)C(F)(F)F MCVFFRWZNYZUIJ-UHFFFAOYSA-M 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- CXHHBNMLPJOKQD-UHFFFAOYSA-M methyl carbonate Chemical compound COC([O-])=O CXHHBNMLPJOKQD-UHFFFAOYSA-M 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 239000004767 olefin fiber Substances 0.000 description 1
- 230000037361 pathway Effects 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000011163 secondary particle Substances 0.000 description 1
- 238000013517 stratification Methods 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/0402—Methods of deposition of the material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/0402—Methods of deposition of the material
- H01M4/0421—Methods of deposition of the material involving vapour deposition
- H01M4/0428—Chemical vapour deposition
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/043—Processes of manufacture in general involving compressing or compaction
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/0471—Processes of manufacture in general involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/136—Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/139—Processes of manufacture
- H01M4/1391—Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/139—Processes of manufacture
- H01M4/1393—Processes of manufacture of electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/139—Processes of manufacture
- H01M4/1397—Processes of manufacture of electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/362—Composites
- H01M4/366—Composites as layered products
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
- H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
- H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
- H01M4/587—Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/621—Binders
- H01M4/622—Binders being polymers
- H01M4/623—Binders being polymers fluorinated polymers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/624—Electric conductive fillers
- H01M4/625—Carbon or graphite
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/66—Selection of materials
- H01M4/661—Metal or alloys, e.g. alloy coatings
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
- H01M2004/028—Positive electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2220/00—Batteries for particular applications
- H01M2220/20—Batteries in motive systems, e.g. vehicle, ship, plane
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Composite Materials (AREA)
- Crystallography & Structural Chemistry (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Carbon And Carbon Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA2754372A CA2754372A1 (en) | 2011-10-04 | 2011-10-04 | Positive-electrode material for lithium-ion secondary battery and method of producing same |
| CA2754372 | 2011-10-04 | ||
| PCT/CA2012/050702 WO2013049939A1 (en) | 2011-10-04 | 2012-10-04 | Positive-electrode materials: methods for their preparation and use in lithium secondary batteries |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2674334T3 true ES2674334T3 (es) | 2018-06-28 |
Family
ID=48040601
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES12839054.9T Active ES2674334T3 (es) | 2011-10-04 | 2012-10-04 | Materiales de electrodo positivo: métodos para su preparación y su uso en baterías de litio secundarias |
Country Status (8)
| Country | Link |
|---|---|
| US (4) | US9577253B2 (https=) |
| EP (1) | EP2764564B1 (https=) |
| JP (1) | JP6321541B2 (https=) |
| KR (1) | KR102000579B1 (https=) |
| CN (2) | CN108511674B (https=) |
| CA (2) | CA2754372A1 (https=) |
| ES (1) | ES2674334T3 (https=) |
| WO (1) | WO2013049939A1 (https=) |
Families Citing this family (51)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2492167C (en) | 2011-06-24 | 2018-12-05 | Nexeon Ltd | Structured particles |
| CA2754372A1 (en) * | 2011-10-04 | 2013-04-04 | Hydro-Quebec | Positive-electrode material for lithium-ion secondary battery and method of producing same |
| EP2810322A1 (en) | 2012-01-30 | 2014-12-10 | Nexeon Limited | Composition of si/c electro active material |
| JP6184056B2 (ja) * | 2012-04-09 | 2017-08-23 | リケンテクノス株式会社 | 樹脂組成物 |
| CA2776205A1 (en) | 2012-05-08 | 2013-11-08 | Hydro-Quebec | Lithium-ion secondary battery and method of producing same |
| JP5497109B2 (ja) | 2012-07-03 | 2014-05-21 | 昭和電工株式会社 | 複合炭素繊維 |
| JP5497110B2 (ja) | 2012-07-03 | 2014-05-21 | 昭和電工株式会社 | 複合炭素繊維の製造方法 |
| CA2794290A1 (en) | 2012-10-22 | 2014-04-22 | Hydro-Quebec | Method of producing electrode material for lithium-ion secondary battery and lithium-ion secondary battery using such electrode material |
| JP5949798B2 (ja) * | 2013-03-25 | 2016-07-13 | 住友大阪セメント株式会社 | 電極材料、電極材料の製造方法及び電極並びにリチウムイオン電池 |
| CA2820227C (en) * | 2013-07-10 | 2020-10-20 | Grafoid, Inc. | Novel composite conductive material |
| US11043680B2 (en) * | 2013-11-13 | 2021-06-22 | Showa Denko K.K. | Electrode material including small diameter, carbon nanotubes bridging large diameter carbon nanotubes, redox flow battery electrode, redox flow battery, and method for producing electrode material |
| JP2015185229A (ja) * | 2014-03-20 | 2015-10-22 | 三菱マテリアル株式会社 | リチウムイオン二次電池の電極 |
| WO2015150213A1 (de) * | 2014-04-04 | 2015-10-08 | Basf Se | Verfahren zur herstellung von formkörpern |
| KR101567203B1 (ko) | 2014-04-09 | 2015-11-09 | (주)오렌지파워 | 이차 전지용 음극 활물질 및 이의 방법 |
| US20170098817A1 (en) * | 2014-05-21 | 2017-04-06 | GM Global Technology Operations LLC | Distributing conductive carbon black on active material in lithium battery electrodes |
| KR102276423B1 (ko) * | 2014-06-10 | 2021-07-12 | 삼성전자주식회사 | 복합체, 이를 이용한 전기화학적 활물질 복합체, 이를 포함한 전극, 리튬 전지, 전계 방출 소자, 바이오센서, 반도체 소자 및 열전소자 |
| KR101550781B1 (ko) | 2014-07-23 | 2015-09-08 | (주)오렌지파워 | 2 차 전지용 실리콘계 활물질 입자의 제조 방법 |
| GB2533161C (en) | 2014-12-12 | 2019-07-24 | Nexeon Ltd | Electrodes for metal-ion batteries |
| JP6505464B2 (ja) * | 2015-02-20 | 2019-04-24 | 大阪瓦斯株式会社 | リチウム二次電池用負極材料、リチウム二次電池用の負極活物質層用組成物、リチウム二次電池用負極及びリチウム二次電池の製造方法 |
| JP6042513B2 (ja) * | 2015-03-24 | 2016-12-14 | 太平洋セメント株式会社 | 二次電池用正極活物質及びその製造方法 |
| KR102336781B1 (ko) * | 2015-03-24 | 2021-12-08 | 다이헤이요 세멘토 가부시키가이샤 | 이차전지용 양극 활물질 및 그 제조방법 |
| KR101726037B1 (ko) | 2015-03-26 | 2017-04-11 | (주)오렌지파워 | 실리콘계 음극 활물질 및 이의 제조 방법 |
| US10826068B2 (en) | 2015-06-30 | 2020-11-03 | Murata Manufacturing Co., Ltd. | Negative electrode, battery, battery pack, electronic apparatus, electrically driven vehicle, electrical storage device, and electric power system |
| US10971717B2 (en) * | 2015-11-19 | 2021-04-06 | Tdk Corporation | Positive electrode active material, positive electrode, and lithium ion secondary battery |
| KR101918815B1 (ko) | 2016-08-23 | 2018-11-15 | 넥시온 엘티디. | 이차 전지용 음극 활물질 및 이의 제조 방법 |
| KR101773719B1 (ko) | 2016-08-23 | 2017-09-01 | (주)오렌지파워 | 2 차 전지용 실리콘계 활물질 입자 및 이의 제조 방법 |
| KR102268081B1 (ko) * | 2017-04-28 | 2021-06-23 | 주식회사 엘지에너지솔루션 | 양극, 이를 포함하는 이차 전지, 및 상기 양극의 제조 방법 |
| WO2019016925A1 (en) * | 2017-07-20 | 2019-01-24 | Nec Corporation | CARBON CONDUCTIVE ADDITIVES FOR LITHIUM ION BATTERY |
| CN107845796B (zh) * | 2017-10-27 | 2020-10-23 | 东北大学秦皇岛分校 | 一种碳掺杂磷酸钒钠正极材料及其制备方法和应用 |
| CN108123120B (zh) * | 2017-12-07 | 2020-07-21 | 成都新柯力化工科技有限公司 | 一种锂电池用纳米硅酸铁锂/石墨烯正极材料及其制备方法 |
| JP6927012B2 (ja) * | 2017-12-15 | 2021-08-25 | トヨタ自動車株式会社 | 蓄電デバイス用電極の製造方法、蓄電デバイス用電極および蓄電デバイス |
| TWI668902B (zh) * | 2018-04-03 | 2019-08-11 | 臺灣塑膠工業股份有限公司 | 電極片與電化學儲能元件 |
| CN110342493B (zh) * | 2018-04-03 | 2021-07-30 | 清华大学 | 过渡金属氧化物/碳纳米管复合材料及其制备方法 |
| CN110635116B (zh) * | 2018-06-22 | 2021-10-22 | 比亚迪股份有限公司 | 锂离子电池负极材料及其制备方法、负极和锂离子电池 |
| KR102276630B1 (ko) * | 2018-09-10 | 2021-07-13 | 도레이 카부시키가이샤 | 이차 전지용 전극 및 이차 전지 |
| WO2020105729A1 (ja) * | 2018-11-22 | 2020-05-28 | 国立大学法人信州大学 | リチウムイオン二次電池用正極、リチウムイオン二次電池およびリチウムイオン二次電池用正極の製造方法 |
| CN109659531A (zh) * | 2018-12-17 | 2019-04-19 | 中科廊坊过程工程研究院 | 一种镍钴铝酸锂复合正极材料及其制备方法和应用 |
| JP7524892B2 (ja) * | 2019-03-11 | 2024-07-30 | 日本ケミコン株式会社 | 電極及び電極の製造方法 |
| CN111081980B (zh) * | 2019-12-24 | 2020-11-27 | 苏州睿梵工业设计有限公司 | 一种电动工具用锂离子电池的石墨负极的制备方法 |
| CN111403732B (zh) * | 2020-03-30 | 2021-07-02 | 江西安驰新能源科技有限公司 | 一种高能量密度磷酸铁锂电池 |
| JP7362585B2 (ja) * | 2020-09-29 | 2023-10-17 | プライムアースEvエナジー株式会社 | リチウムイオン二次電池用正極、リチウムイオン二次電池、及びリチウムイオン二次電池用正極の製造方法 |
| JP7362586B2 (ja) * | 2020-09-29 | 2023-10-17 | プライムアースEvエナジー株式会社 | リチウムイオン二次電池用正極、リチウムイオン二次電池、及びリチウムイオン二次電池用正極の製造方法 |
| WO2023090453A1 (ja) * | 2021-11-22 | 2023-05-25 | 株式会社レゾナック | 正極合剤層、導電助剤、正極合剤およびリチウムイオン二次電池 |
| KR102873758B1 (ko) * | 2021-11-26 | 2025-10-17 | 삼성에스디아이 주식회사 | 복합양극활물질, 이를 채용한 양극과 리튬전지 및 이의 제조방법 |
| CN116565107A (zh) * | 2022-01-27 | 2023-08-08 | 宁德时代新能源科技股份有限公司 | 负极极片、二次电池、电池模块、电池包及用电装置 |
| CN114975973A (zh) * | 2022-07-05 | 2022-08-30 | 北京理工大学 | 一种改性的高性能焦磷酸铁钠钠离子电池正极材料、其制备及应用 |
| US20240154127A1 (en) * | 2022-11-03 | 2024-05-09 | Lg Energy Solution, Ltd. | Positive Electrode and Lithium Secondary Battery Manufactured Using the Same |
| CN116544381B (zh) * | 2023-05-30 | 2024-04-05 | 广东凯金新能源科技股份有限公司 | 预镁硅氧负极材料及其制备方法、及二次电池 |
| WO2025095771A1 (en) * | 2023-10-31 | 2025-05-08 | Petroliam Nasional Berhad (Petronas) | Electrode formulations |
| JP2025185839A (ja) * | 2024-06-11 | 2025-12-23 | 三菱鉛筆株式会社 | カーボンナノチューブ分散液、電極膜および電池用セパレーター |
| CN120674480B (zh) * | 2025-08-19 | 2026-01-09 | 湖北万润新能源科技股份有限公司 | 一种复合磷酸铁锂材料及其制备方法、正极极片和二次电池 |
Family Cites Families (35)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0603397B2 (en) | 1991-09-13 | 2002-12-18 | Asahi Kasei Kogyo Kabushiki Kaisha | Secondary cell |
| JP3523397B2 (ja) | 1995-11-07 | 2004-04-26 | 日本電信電話株式会社 | 非水電解質二次電池 |
| US5910382A (en) | 1996-04-23 | 1999-06-08 | Board Of Regents, University Of Texas Systems | Cathode materials for secondary (rechargeable) lithium batteries |
| CA2270771A1 (fr) * | 1999-04-30 | 2000-10-30 | Hydro-Quebec | Nouveaux materiaux d'electrode presentant une conductivite de surface elevee |
| JP4595145B2 (ja) | 1999-10-27 | 2010-12-08 | ソニー株式会社 | 非水電解質電池 |
| JP2003168429A (ja) | 2001-11-29 | 2003-06-13 | Sanyo Electric Co Ltd | 非水電解質二次電池 |
| JP2003272632A (ja) * | 2002-03-15 | 2003-09-26 | Mikuni Color Ltd | 炭素被覆リチウム遷移金属酸化物、2次電池正極材料及び2次電池 |
| US6913855B2 (en) | 2002-07-22 | 2005-07-05 | Valence Technology, Inc. | Method of synthesizing electrochemically active materials from a slurry of precursors |
| JP4040606B2 (ja) | 2003-06-06 | 2008-01-30 | Jfeケミカル株式会社 | リチウムイオン二次電池用負極材料およびその製造方法、ならびにリチウムイオン二次電池用負極およびリチウムイオン二次電池 |
| TW200508431A (en) * | 2003-08-26 | 2005-03-01 | Showa Denko Kk | Crimped carbon fiber and production method thereof |
| JP2007242386A (ja) | 2006-03-08 | 2007-09-20 | Matsushita Electric Ind Co Ltd | 電極およびそれを用いた蓄電素子 |
| JP5345300B2 (ja) | 2006-06-27 | 2013-11-20 | 花王株式会社 | リチウムイオン電池用複合正極材料およびこれを用いた電池 |
| KR101114122B1 (ko) | 2006-06-27 | 2012-03-13 | 닛산 지도우샤 가부시키가이샤 | 리튬이온 전지용 복합 양극재료 및 이것을 이용한 전지 |
| JP5118877B2 (ja) | 2007-04-27 | 2013-01-16 | トヨタ自動車株式会社 | 二次電池 |
| JP5352069B2 (ja) | 2007-08-08 | 2013-11-27 | トヨタ自動車株式会社 | 正極材料、正極板、二次電池、及び正極材料の製造方法 |
| CA2623407A1 (en) * | 2008-02-28 | 2009-08-28 | Hydro-Quebec | Composite electrode material |
| CA2638410A1 (en) | 2008-07-28 | 2010-01-28 | Hydro-Quebec | Composite electrode material |
| JP5794753B2 (ja) * | 2008-09-30 | 2015-10-14 | 電気化学工業株式会社 | 二次電池用正極 |
| EP2237346B1 (en) | 2009-04-01 | 2017-08-09 | The Swatch Group Research and Development Ltd. | Electrically conductive nanocomposite material comprising sacrificial nanoparticles and open porous nanocomposites produced thereof |
| JP5650418B2 (ja) | 2009-03-12 | 2015-01-07 | ザ・スウォッチ・グループ・リサーチ・アンド・ディベロップメント・リミテッド | 犠牲ナノ粒子を含む電気伝導性ナノ複合材料およびそれから生成される開放多孔質ナノ複合材 |
| US8877865B2 (en) * | 2009-03-30 | 2014-11-04 | Kuraray Co., Ltd. | Resin composition and multilayered structure |
| JP4835881B2 (ja) * | 2009-03-31 | 2011-12-14 | 宇部興産株式会社 | リチウムイオン電池用電極およびその製造方法 |
| CN101567441B (zh) * | 2009-06-09 | 2011-11-30 | 天津大学 | 一步法碳包覆的LiFePO4粉体的制备方法 |
| JP2011060432A (ja) * | 2009-09-04 | 2011-03-24 | Ube Industries Ltd | 微細な炭素繊維で覆われた粒子 |
| JP5486907B2 (ja) | 2009-11-18 | 2014-05-07 | 電気化学工業株式会社 | リチウムイオン二次電池用正極材及びその製造方法 |
| CN101752561B (zh) * | 2009-12-11 | 2012-08-22 | 宁波艾能锂电材料科技股份有限公司 | 石墨烯改性磷酸铁锂正极活性材料及其制备方法以及锂离子二次电池 |
| JP5799486B2 (ja) * | 2010-02-12 | 2015-10-28 | 東洋インキScホールディングス株式会社 | 炭素材料分散液 |
| CN101789502A (zh) * | 2010-03-12 | 2010-07-28 | 江苏工业学院 | 金属离子掺杂和碳包覆相结合改性锂离子电池正极材料 |
| CN101834288A (zh) * | 2010-03-23 | 2010-09-15 | 浙江大学 | 一种磷酸铁锂/纳米碳复合材料及其制备方法 |
| CN101800310B (zh) * | 2010-04-02 | 2013-02-13 | 中国科学院苏州纳米技术与纳米仿生研究所 | 一种掺入石墨烯的锂离子电池正极材料的制备方法 |
| CN101944601B (zh) * | 2010-09-27 | 2012-08-01 | 彩虹集团公司 | 一种纳米磷酸铁锂均匀碳包覆的方法 |
| US8753772B2 (en) * | 2010-10-07 | 2014-06-17 | Battelle Memorial Institute | Graphene-sulfur nanocomposites for rechargeable lithium-sulfur battery electrodes |
| CN102013477B (zh) * | 2010-11-10 | 2012-05-23 | 河北力滔电池材料有限公司 | 一种锂离子电池复合材料磷酸铁锂/碳的制备方法 |
| CN102104143A (zh) * | 2010-11-29 | 2011-06-22 | 唐品利 | 一种高性能动力电池用复合材料的水热合成法 |
| CA2754372A1 (en) * | 2011-10-04 | 2013-04-04 | Hydro-Quebec | Positive-electrode material for lithium-ion secondary battery and method of producing same |
-
2011
- 2011-10-04 CA CA2754372A patent/CA2754372A1/en not_active Abandoned
-
2012
- 2012-10-04 KR KR1020147010971A patent/KR102000579B1/ko active Active
- 2012-10-04 US US14/349,076 patent/US9577253B2/en active Active
- 2012-10-04 JP JP2014533746A patent/JP6321541B2/ja active Active
- 2012-10-04 CN CN201810283179.4A patent/CN108511674B/zh active Active
- 2012-10-04 CA CA2849008A patent/CA2849008C/en active Active
- 2012-10-04 CN CN201280048742.0A patent/CN103918109B/zh active Active
- 2012-10-04 EP EP12839054.9A patent/EP2764564B1/en active Active
- 2012-10-04 ES ES12839054.9T patent/ES2674334T3/es active Active
- 2012-10-04 WO PCT/CA2012/050702 patent/WO2013049939A1/en not_active Ceased
-
2017
- 2017-01-13 US US15/405,662 patent/US10090525B2/en active Active
-
2018
- 2018-06-05 US US15/997,910 patent/US10944107B2/en active Active
-
2020
- 2020-11-12 US US17/096,403 patent/US11715828B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| US20150037673A1 (en) | 2015-02-05 |
| CN108511674A (zh) | 2018-09-07 |
| CN108511674B (zh) | 2022-06-03 |
| CN103918109A (zh) | 2014-07-09 |
| US11715828B2 (en) | 2023-08-01 |
| EP2764564A4 (en) | 2015-07-01 |
| CN103918109B (zh) | 2018-05-01 |
| US9577253B2 (en) | 2017-02-21 |
| JP6321541B2 (ja) | 2018-05-09 |
| CA2849008A1 (en) | 2013-04-11 |
| CA2849008C (en) | 2021-01-12 |
| US10090525B2 (en) | 2018-10-02 |
| KR20140082988A (ko) | 2014-07-03 |
| WO2013049939A1 (en) | 2013-04-11 |
| JP2014532263A (ja) | 2014-12-04 |
| US20210066718A1 (en) | 2021-03-04 |
| KR102000579B1 (ko) | 2019-07-16 |
| EP2764564B1 (en) | 2018-04-25 |
| CA2754372A1 (en) | 2013-04-04 |
| US20180287155A1 (en) | 2018-10-04 |
| US20170125813A1 (en) | 2017-05-04 |
| US10944107B2 (en) | 2021-03-09 |
| EP2764564A1 (en) | 2014-08-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| ES2674334T3 (es) | Materiales de electrodo positivo: métodos para su preparación y su uso en baterías de litio secundarias | |
| JP5834273B2 (ja) | リチウム二次電池用電極材およびリチウム二次電池 | |
| US9203084B2 (en) | Cathode active material-coated discrete graphene sheets for lithium batteries and process for producing same | |
| ES2880601T3 (es) | Batería secundaria de iones de litio y procedimiento de producción de la misma | |
| JP6353329B2 (ja) | 非水電解質二次電池用負極及び非水電解質二次電池 | |
| TWI705606B (zh) | 負極活性物質、混合負極活性物質材料、非水電解質二次電池用負極、鋰離子二次電池、負極活性物質的製造方法、以及鋰離子二次電池的製造方法 | |
| ES2855168T3 (es) | Procedimiento de producción de material de electrodo para batería secundaria de iones de litio y batería de iones de litio que usa dicho material de electrodo | |
| US10608276B2 (en) | Carbon material, anode material and spacer additive for lithium ion battery | |
| CN104603992B (zh) | 锂离子二次电池用电极材料、其制造方法及锂离子二次电池 | |
| CN104916809A (zh) | 一种一体化柔性电极 | |
| CN103959520A (zh) | 锂二次电池及其制造方法 | |
| CN108718535A (zh) | 负极活性物质、混合负极活性物质材料、非水电解质二次电池用负极、锂离子二次电池、负极活性物质的制造方法、及锂离子二次电池的制造方法 | |
| CN114243023A (zh) | 正极浆料、制备正极极片的方法及正极极片、二次电池、电池模块、电池包和用电装置 | |
| JP6931491B2 (ja) | 電気化学蓄電装置用の電極を製造する方法 | |
| CN109494372A (zh) | 锂离子二次电池用的负极、锂离子二次电池和锂离子二次电池的制造方法 | |
| JP7597589B2 (ja) | 正極材料、非水電解質二次電池、および、正極材料の製造方法 | |
| CN103843187A (zh) | 非水电解质二次电池和非水电解质二次电池的制造方法 | |
| JP2021002448A (ja) | 負極材、負極、電池セル | |
| CN115485899A (zh) | 蓄电元件 | |
| JP7718167B2 (ja) | リチウムイオン電池 | |
| JP2015032383A (ja) | 非水電解質二次電池用正極および非水電解質二次電池 | |
| JP7547761B2 (ja) | 非水電解質蓄電素子 | |
| JP2023017587A (ja) | 非水電解質蓄電素子及びその製造方法 |