CZ309596A3 - Metallocene compounds, process of their preparation and their use in catalysts for olefin polymerization - Google Patents
Metallocene compounds, process of their preparation and their use in catalysts for olefin polymerization Download PDFInfo
- Publication number
- CZ309596A3 CZ309596A3 CZ963095A CZ309596A CZ309596A3 CZ 309596 A3 CZ309596 A3 CZ 309596A3 CZ 963095 A CZ963095 A CZ 963095A CZ 309596 A CZ309596 A CZ 309596A CZ 309596 A3 CZ309596 A3 CZ 309596A3
- Authority
- CZ
- Czechia
- Prior art keywords
- substituents
- metallocene compound
- bis
- formula
- aryl
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITMI950099A IT1272923B (it) | 1995-01-23 | 1995-01-23 | Composti metallocenici,procedimento per la loro preparazione,e loro utilizzo in catalizzatori per la polimerizzazione delle olefine |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CZ309596A3 true CZ309596A3 (en) | 1997-04-16 |
Family
ID=11370281
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CZ963095A CZ309596A3 (en) | 1995-01-23 | 1996-01-17 | Metallocene compounds, process of their preparation and their use in catalysts for olefin polymerization |
Country Status (24)
| Country | Link |
|---|---|
| US (3) | US6051728A (OSRAM) |
| EP (1) | EP0751946B2 (OSRAM) |
| JP (1) | JP3838662B2 (OSRAM) |
| KR (2) | KR100414759B1 (OSRAM) |
| CN (2) | CN1075076C (OSRAM) |
| AR (1) | AR000776A1 (OSRAM) |
| AU (1) | AU700256B2 (OSRAM) |
| BG (1) | BG100904A (OSRAM) |
| BR (1) | BR9606373A (OSRAM) |
| CA (1) | CA2186232A1 (OSRAM) |
| CZ (1) | CZ309596A3 (OSRAM) |
| DE (1) | DE69617543T3 (OSRAM) |
| ES (1) | ES2167539T5 (OSRAM) |
| FI (1) | FI963759A0 (OSRAM) |
| HU (1) | HUP9602907A3 (OSRAM) |
| IL (1) | IL116853A (OSRAM) |
| IT (1) | IT1272923B (OSRAM) |
| MX (1) | MX9604229A (OSRAM) |
| PL (1) | PL185055B1 (OSRAM) |
| RU (1) | RU2177948C2 (OSRAM) |
| TR (1) | TR199600720T1 (OSRAM) |
| TW (1) | TW319777B (OSRAM) |
| WO (1) | WO1996022995A1 (OSRAM) |
| ZA (1) | ZA96485B (OSRAM) |
Families Citing this family (61)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19533336A1 (de) * | 1995-09-11 | 1997-03-13 | Basf Ag | Verfahren zur Herstellung von Propen/But-1-en-Copolymeren |
| DE19533337A1 (de) * | 1995-09-11 | 1997-03-13 | Basf Ag | Propen/But-1-en-Copolymere |
| JP3566819B2 (ja) * | 1996-10-04 | 2004-09-15 | 関東化学株式会社 | 新規な有機遷移金属化合物 |
| DE19644039A1 (de) * | 1996-10-31 | 1998-05-07 | Hoechst Ag | Metallocene |
| KR100536794B1 (ko) * | 1996-11-15 | 2005-12-14 | 바셀 테크놀로지 캄파니 비이브이 | 복소환 메탈로센 및 중합 촉매 |
| US5900497A (en) * | 1996-12-20 | 1999-05-04 | Union Carbide Chemicals & Plsatics Technology Corporation | Process for preparing metallocene procatalysts |
| IL127229A0 (en) | 1997-03-29 | 1999-09-22 | Montell Technology Company Bv | Metallocenes and catalysts for polymerization of olefins |
| AT405834B (de) | 1997-10-09 | 1999-11-25 | Borealis Ag | Metallocene mit ferrocenyl-substituierten brücken und deren einsatz für die olefinpolymerisation |
| DE19748388A1 (de) * | 1997-11-03 | 1999-05-06 | Borealis Polymere Holding Gmbh | Metallocene mit ferrocenyl-substituierten Brücken und deren Einsatz für die Olefinpolymerisation |
| JP2002505713A (ja) * | 1998-04-21 | 2002-02-19 | モンテル テクノロジー カンパニー ビーブイ | α−オレフィンとのエチレンコポリマーの製造方法 |
| JP2002519484A (ja) | 1998-07-02 | 2002-07-02 | モンテル テクノロジー カンパニー ビーブイ | 実質的非晶質α−オレフィンポリマーの製造法とそれを含有する組成物および橋状リガンドの製造法 |
| DE19922020A1 (de) * | 1999-05-12 | 2000-11-16 | Targor Gmbh | Übergangsmetallverbindung, Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen |
| JP2003524013A (ja) | 2000-02-24 | 2003-08-12 | バセル テクノロジー カンパニー ビー.ブイ. | オレフィン重合用助触媒として有用な有機金属化合物 |
| KR20020007419A (ko) | 2000-03-22 | 2002-01-26 | 간디 지오프레이 에이치. | 이소택틱 프로필렌 중합체 및 감소된 이소택틱성을 갖는유연성 프로필렌 중합체의 열가소성 조성물 및 그 제조방법 |
| JP2003534415A (ja) * | 2000-05-24 | 2003-11-18 | バセル テクノロジー カンパニー ビー.ブイ. | プロピレンポリマーとその製造法 |
| US6673869B2 (en) | 2000-07-27 | 2004-01-06 | Basell Poliolefine Italia S.P.A. | Transparent elastomeric thermoplastic polyolefin compositions |
| WO2002051887A2 (en) | 2000-12-22 | 2002-07-04 | Basell Poliolefine Italia S.P.A. | Process for the preparation of porous polymers and polymers obtainable thereof |
| WO2002051877A2 (en) | 2000-12-22 | 2002-07-04 | Basell Polyolefine Gmbh | Catalyst components for the polymerization of olefins |
| DE60202524T2 (de) | 2001-05-21 | 2005-06-30 | Basell Polyolefine Gmbh | Katalysatorsystem für die polymerisierung von olefinen |
| ATE503792T1 (de) * | 2001-07-19 | 2011-04-15 | Univation Tech Llc | Polyethylenfilme mit verbesserten physikalischen eigenschaften |
| BR0211290A (pt) | 2001-07-19 | 2004-09-14 | Univation Tech Llc | Compostos de catalisador de metaloceno de baixa incorporação de comonÈmero |
| BR0211288A (pt) * | 2001-07-19 | 2004-08-10 | Univation Tech Llc | Sistemas catalisadores de metaloceno mistos contendo um incorporador de comonÈmero fraco e um incorporador de comonÈmero bom |
| US6936675B2 (en) * | 2001-07-19 | 2005-08-30 | Univation Technologies, Llc | High tear films from hafnocene catalyzed polyethylenes |
| US7022793B2 (en) | 2001-11-27 | 2006-04-04 | Basell Polyolefine Gmbh | Process for the treatment of polymer compositions |
| RU2214415C1 (ru) * | 2002-05-13 | 2003-10-20 | Общество с ограниченной ответственностью "Научно-исследовательская лаборатория "Синор" | Способ получения галогенидов металлоценов (варианты) |
| CA2487512A1 (en) | 2002-06-26 | 2004-01-08 | Basell Poliolefine Italia S.P.A. | Impact-resistant polyolefin compositions |
| CA2487517A1 (en) * | 2002-06-26 | 2004-01-08 | Basell Poliolefine Italia S.P.A. | Impact-resistant polyolefin compositions |
| US7449246B2 (en) * | 2004-06-30 | 2008-11-11 | General Electric Company | Barrier coatings |
| EP1549688A2 (en) * | 2002-10-10 | 2005-07-06 | Basell Polyolefine GmbH | Process for the copolymerization of ethylene |
| US7550528B2 (en) | 2002-10-15 | 2009-06-23 | Exxonmobil Chemical Patents Inc. | Functionalized olefin polymers |
| US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
| EP2261292B1 (en) * | 2002-10-15 | 2014-07-23 | ExxonMobil Chemical Patents Inc. | Polyolefin adhesive compositions |
| US7541402B2 (en) | 2002-10-15 | 2009-06-02 | Exxonmobil Chemical Patents Inc. | Blend functionalized polyolefin adhesive |
| BRPI0409738B1 (pt) | 2003-04-17 | 2014-01-21 | Processo contínuo para a polimerização de olefinas em um reator de leito fluidizado | |
| WO2005005495A2 (en) | 2003-07-04 | 2005-01-20 | Basell Polyolefine Gmbh | Olefin polymerization process |
| EP1564226A1 (en) | 2004-02-16 | 2005-08-17 | Stichting Dutch Polymer Institute | Titanocene-based catalyst system |
| EP1727836A2 (en) | 2004-03-12 | 2006-12-06 | Basell Polyolefine GmbH | Catalyst system for the polymerization of olefin |
| WO2005095474A1 (en) | 2004-03-12 | 2005-10-13 | Basell Polyolefine Gmbh | Process for polymerizing 1-hexene or higher alpha-olefins |
| WO2005095473A1 (en) | 2004-03-12 | 2005-10-13 | Basell Polyolefine Gmbh | Process for polymerizing 1-hexene or higher alpha-olefins |
| EP1655314A1 (en) | 2004-11-09 | 2006-05-10 | Basell Polyolefine GmbH | Process for the preparation of 1-butene/propylene copolymers |
| US7300994B2 (en) * | 2004-11-22 | 2007-11-27 | Cornell Research Foundation, Inc. | Isotactic polypropylene containing polymers |
| JP2008520793A (ja) | 2004-11-22 | 2008-06-19 | バーゼル・ポリオレフィン・ゲーエムベーハー | プロピレンベースのターポリマー |
| EP1825036A1 (en) * | 2004-12-13 | 2007-08-29 | Basell Poliolefine Italia S.r.l. | Polyolefin composition, fibres and nonwoven fabrics |
| DE602005011181D1 (de) * | 2004-12-23 | 2009-01-02 | Basell Poliolefine Srl | Fasern mit elastischen eigenschaften |
| US7026494B1 (en) | 2005-01-10 | 2006-04-11 | Chevron Phillips Chemical Company, Lp | Polymerization catalysts for producing high melt index polymers without the use of hydrogen |
| WO2009077185A1 (en) | 2007-12-18 | 2009-06-25 | Basell Polyolefine Gmbh | Gas-phase process for the polymerization of alpha-olefins |
| US20100280153A1 (en) * | 2008-01-11 | 2010-11-04 | Keita Itakura | Modified propylene resin |
| KR101580849B1 (ko) * | 2008-02-29 | 2015-12-30 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 폴리올레핀 조성물 |
| US8637625B2 (en) | 2008-11-18 | 2014-01-28 | Borealis Ag | Propylene-butene random copolymer produced in the presence of a metallocene catalyst |
| EP2341086A1 (en) † | 2009-12-30 | 2011-07-06 | Borealis AG | Bopp-film |
| WO2015009480A1 (en) * | 2013-07-17 | 2015-01-22 | Exxonmobil Chemical Patents Inc. | Process using substituted metallocene catalysts and products therefrom |
| CN105358589B (zh) | 2013-07-17 | 2018-07-03 | 埃克森美孚化学专利公司 | 金属茂和由其衍生的催化剂组合物 |
| US9938364B2 (en) | 2013-07-17 | 2018-04-10 | Exxonmobil Chemical Patents Inc. | Substituted metallocene catalysts |
| CN105377904B (zh) | 2013-07-17 | 2018-07-10 | 埃克森美孚化学专利公司 | 金属茂和由其衍生的催化剂组合物 |
| EP3022233B1 (en) | 2013-07-17 | 2019-05-01 | ExxonMobil Chemical Patents Inc. | Cyclopropyl substituted metallocene catalysts |
| JP2016531978A (ja) | 2013-07-17 | 2016-10-13 | エクソンモービル ケミカル パテンツ インコーポレイテッド | 置換メタロセン触媒 |
| US9587053B2 (en) * | 2013-09-30 | 2017-03-07 | Lg Chem, Ltd. | Preparation method of a propylene-1-butene copolymer and a propylene-1-butene copolymer obtained therefrom |
| WO2016099117A1 (ko) | 2014-12-15 | 2016-06-23 | 주식회사 엘지화학 | 메탈로센 화합물, 메탈로센 담지 촉매 및 이를 이용하는 폴리올레핀의 제조 방법 |
| KR101826253B1 (ko) * | 2015-07-15 | 2018-02-06 | 한화케미칼 주식회사 | 메탈로센 화합물 및 이의 제조방법 |
| KR102212822B1 (ko) * | 2016-12-05 | 2021-02-08 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 필름용의 브로드 오쏘고날 분포 메탈로센 폴리에틸렌 |
| US11518824B2 (en) | 2017-10-11 | 2022-12-06 | Basell Polyolefine Gmbh | Supported catalyst system |
Family Cites Families (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ZA844157B (en) * | 1983-06-06 | 1986-01-29 | Exxon Research Engineering Co | Process and catalyst for polyolefin density and molecular weight control |
| DE3443087A1 (de) * | 1984-11-27 | 1986-05-28 | Hoechst Ag, 6230 Frankfurt | Verfahren zur herstellung von polyolefinen |
| US4668773A (en) * | 1985-03-25 | 1987-05-26 | Northwestern University | Organolanthanide catalysts |
| ES2082745T3 (es) * | 1987-04-03 | 1996-04-01 | Fina Technology | Sistemas cataliticos metalocenos para la polimerizacion de las olefinas presentando un puente de hidrocarburo de silicio. |
| US4892851A (en) * | 1988-07-15 | 1990-01-09 | Fina Technology, Inc. | Process and catalyst for producing syndiotactic polyolefins |
| DE68928696T2 (de) * | 1988-12-26 | 1998-12-03 | Mitsui Chemicals, Inc., Tokio/Tokyo | Olefin-kopolymer und verfahren zur herstellung |
| DE3929693A1 (de) * | 1989-09-07 | 1991-03-14 | Hoechst Ag | Verfahren zur herstellung eines polyolefinwachses |
| US5026798A (en) * | 1989-09-13 | 1991-06-25 | Exxon Chemical Patents Inc. | Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system |
| IT1249008B (it) * | 1990-06-27 | 1995-02-11 | Himont Inc | Copolimeri cristallini sindiotattici del propilene |
| ES2090209T3 (es) * | 1990-11-12 | 1996-10-16 | Hoechst Ag | Metalocenos con ligandos basados en derivados de indenilo sustituidos en posicion 2, procedimiento para su preparacion y su empleo como catalizadores. |
| EP0485823B1 (de) * | 1990-11-12 | 1995-03-08 | Hoechst Aktiengesellschaft | 2-Substituierte Bisindenylmetallocene, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren bei der Olefinpolymerisation |
| WO1992012184A1 (en) * | 1990-12-28 | 1992-07-23 | Exxon Chemical Patents Inc. | Syndiotactic polypropylene |
| ES2155492T3 (es) * | 1991-05-27 | 2001-05-16 | Basell Polyolefine Gmbh | Procedimiento para la obtencion de poliolefinas con una amplia distribucion de pesos moleculares. |
| JPH04351638A (ja) * | 1991-05-29 | 1992-12-07 | Toray Dow Corning Silicone Co Ltd | ヘキセニル基含有シリコーンレジンおよびその製造方法 |
| TW300901B (OSRAM) * | 1991-08-26 | 1997-03-21 | Hoechst Ag | |
| US5330948A (en) * | 1992-03-31 | 1994-07-19 | Northwestern University | Homogeneous catalysts for stereoregular olefin polymerization |
| FI112233B (fi) * | 1992-04-01 | 2003-11-14 | Basell Polyolefine Gmbh | Katalyytti olefiinipolymerointia varten, menetelmä sen valmistamiseksi ja sen käyttö |
| EP0584609B1 (de) * | 1992-08-15 | 1999-03-10 | TARGOR GmbH | Verfahren zur Herstellung von Polyolefinen |
| TW272985B (OSRAM) * | 1992-09-11 | 1996-03-21 | Hoechst Ag | |
| EP0588208A3 (en) * | 1992-09-12 | 1994-07-06 | Hoechst Ag | Polyolefin moulding composition with broad melt range, process and use therefore |
| JP3307704B2 (ja) * | 1993-02-19 | 2002-07-24 | 三菱化学株式会社 | α‐オレフィン重合体の製造法 |
| EP1070729B1 (en) * | 1993-06-07 | 2011-09-28 | Mitsui Chemicals, Inc. | Transition metal compound, olefin polymerization catalyst component comprising said compound, olefin polymerization catalyst containing said component, process for olefin polymerization using said catalyst, propylene homopolymer, propylene copolymer and propylene elastomer |
| EP1209165B1 (en) * | 1993-06-07 | 2006-04-19 | Mitsui Chemicals, Inc. | Propylene elastomer |
| US5459117A (en) * | 1993-08-27 | 1995-10-17 | Ewen; John A. | Doubly-conformationally locked, stereorigid catalysts for the preparation of tactiospecific polymers |
| DE4333128A1 (de) * | 1993-09-29 | 1995-03-30 | Hoechst Ag | Verfahren zur Herstellung von Polyolefinen |
| DE4344689A1 (de) * | 1993-12-27 | 1995-06-29 | Hoechst Ag | Metallocenverbindung |
| US5504223A (en) * | 1994-01-25 | 1996-04-02 | The Dow Chemical Company | Synthesis of cyclopentadienyl metal coordination complexes from metal hydrocarbyloxides |
-
1995
- 1995-01-23 IT ITMI950099A patent/IT1272923B/it active IP Right Grant
-
1996
- 1996-01-17 CZ CZ963095A patent/CZ309596A3/cs unknown
- 1996-01-17 WO PCT/EP1996/000171 patent/WO1996022995A1/en not_active Ceased
- 1996-01-17 RU RU96121252/04A patent/RU2177948C2/ru not_active IP Right Cessation
- 1996-01-17 MX MX9604229A patent/MX9604229A/es unknown
- 1996-01-17 EP EP96901285A patent/EP0751946B2/en not_active Expired - Lifetime
- 1996-01-17 DE DE69617543T patent/DE69617543T3/de not_active Expired - Lifetime
- 1996-01-17 FI FI963759A patent/FI963759A0/fi unknown
- 1996-01-17 ES ES96901285T patent/ES2167539T5/es not_active Expired - Lifetime
- 1996-01-17 KR KR10-2003-7010028A patent/KR100414759B1/ko not_active Expired - Fee Related
- 1996-01-17 CN CN96190226A patent/CN1075076C/zh not_active Expired - Fee Related
- 1996-01-17 AU AU45366/96A patent/AU700256B2/en not_active Ceased
- 1996-01-17 BR BR9606373-4A patent/BR9606373A/pt not_active IP Right Cessation
- 1996-01-17 JP JP52259496A patent/JP3838662B2/ja not_active Expired - Lifetime
- 1996-01-17 HU HU9602907A patent/HUP9602907A3/hu unknown
- 1996-01-17 CA CA002186232A patent/CA2186232A1/en not_active Abandoned
- 1996-01-17 PL PL96316387A patent/PL185055B1/pl not_active IP Right Cessation
- 1996-01-17 TR TR96/00720T patent/TR199600720T1/xx unknown
- 1996-01-17 KR KR1019960705230A patent/KR100418106B1/ko not_active Expired - Fee Related
- 1996-01-22 ZA ZA96485A patent/ZA96485B/xx unknown
- 1996-01-22 IL IL11685396A patent/IL116853A/xx not_active IP Right Cessation
- 1996-01-23 US US08/599,483 patent/US6051728A/en not_active Expired - Lifetime
- 1996-01-23 AR ARP960101110A patent/AR000776A1/es active IP Right Grant
- 1996-02-26 TW TW085102169A patent/TW319777B/zh active
- 1996-10-11 BG BG100904A patent/BG100904A/xx unknown
-
2000
- 2000-01-11 US US09/481,047 patent/US6518386B1/en not_active Expired - Lifetime
-
2001
- 2001-06-07 CN CNB011208953A patent/CN1196721C/zh not_active Expired - Fee Related
-
2002
- 2002-10-11 US US10/269,699 patent/US20030120015A1/en not_active Abandoned
Also Published As
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CZ309596A3 (en) | Metallocene compounds, process of their preparation and their use in catalysts for olefin polymerization | |
| RU2362779C2 (ru) | Металлоорганическое соединение переходного металла, бисциклопентадиенильная лигандная система, каталитическая система и получение полиолефинов | |
| US5459117A (en) | Doubly-conformationally locked, stereorigid catalysts for the preparation of tactiospecific polymers | |
| JP3946282B2 (ja) | プロピレンのエチレンとのアモルファスコポリマー | |
| JP5584639B2 (ja) | 1−ブテンの重合方法 | |
| Resconi et al. | Rac-[methylene (3-tert-butyl-1-indenyl) 2] ZrCl2: a simple, high-performance zirconocene catalyst for isotactic polypropene | |
| CA2257177A1 (en) | Metallocenes and catalysts for polymerization of olefins | |
| JP2000511156A (ja) | 開放ペンタジエニルメタロセン類、その前駆物質とそれからの重合触媒 | |
| WO2006117285A1 (en) | Process for the polymerization of alpha olefins | |
| KR20100024433A (ko) | 1-부텐 에틸렌 공중합체 | |
| EP0979247B1 (en) | Process for producing isotactic polypropylenes in condensed phase using titanocenes | |
| KR101139268B1 (ko) | 유기금속 전이 금속 화합물, 비스시클로펜타디에닐 리간드계, 촉매 계 및 폴리올레핀 제조 | |
| KR101665076B1 (ko) | 안사-메탈로센 화합물 및 이를 이용한 담지 촉매의 제조방법 | |
| JP2004534829A (ja) | メタロセン、オレフィンポリマー製造用の触媒系における使用 | |
| JP3095754B2 (ja) | プロピレン‐イソブロック共重合体、その製造方法およびそれに使用される触媒 | |
| JPH1180183A (ja) | 重合用金属化合物及びそれを用いた芳香族ビニル化合物−オレフィン共重合体の製造方法 | |
| JP3154511B2 (ja) | シンジオタクチックポリプロピレンの製造方法 | |
| WO2010077163A1 (en) | Synthesis of substituted tetrahydroindenyl complexes, metallocenes produced therefrom and use of the metallocenes in polymerisation processes | |
| JP2001288221A (ja) | プロピレン重合体 | |
| KR20230072858A (ko) | 폴리프로필렌 공중합체 제조방법 | |
| JP2002047313A (ja) | プロピレン重合体 | |
| US20020032342A1 (en) | Novel metallocene catalyst and process for preparing styrenic polymer using the same |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PD00 | Pending as of 2000-06-30 in czech republic |