CN1043144C - 预聚合的催化剂、用于烯烃聚合的催化剂和烯烃的聚合方法 - Google Patents

预聚合的催化剂、用于烯烃聚合的催化剂和烯烃的聚合方法 Download PDF

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Publication number
CN1043144C
CN1043144C CN92109484A CN92109484A CN1043144C CN 1043144 C CN1043144 C CN 1043144C CN 92109484 A CN92109484 A CN 92109484A CN 92109484 A CN92109484 A CN 92109484A CN 1043144 C CN1043144 C CN 1043144C
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Prior art keywords
compound
catalyst component
catalyst
olefin
transition metal
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Expired - Lifetime
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CN92109484A
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Chinese (zh)
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CN1070651A (zh
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筱崎哲德
木冈护
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Mitsui Chemical Industry Co Ltd
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Mitsui Chemicals Inc
Mitsui Petrochemical Industries Ltd
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16—Ethene-propene or ethene-propene-diene copolymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2308/00—Chemical blending or stepwise polymerisation process with the same catalyst

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
CN92109484A 1991-08-14 1992-08-14 预聚合的催化剂、用于烯烃聚合的催化剂和烯烃的聚合方法 Expired - Lifetime CN1043144C (zh)

Applications Claiming Priority (8)

Application Number Priority Date Filing Date Title
JP204465/91 1991-08-14
JP204467/91 1991-08-14
JP20446791 1991-08-14
JP20446491 1991-08-14
JP20446591 1991-08-14
JP204464/91 1991-08-14
JP204466/91 1991-08-14
JP20446691 1991-08-14

Related Child Applications (1)

Application Number Title Priority Date Filing Date
CN95105201A Division CN1048733C (zh) 1991-08-14 1995-05-02 含烯烃聚合物组合物的制品

Publications (2)

Publication Number Publication Date
CN1070651A CN1070651A (zh) 1993-04-07
CN1043144C true CN1043144C (zh) 1999-04-28

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CN92109484A Expired - Lifetime CN1043144C (zh) 1991-08-14 1992-08-14 预聚合的催化剂、用于烯烃聚合的催化剂和烯烃的聚合方法
CN92109483A Expired - Fee Related CN1063763C (zh) 1991-08-14 1992-08-14 烯烃聚合物组合物及其用途
CN95105201A Expired - Lifetime CN1048733C (zh) 1991-08-14 1995-05-02 含烯烃聚合物组合物的制品

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CN92109483A Expired - Fee Related CN1063763C (zh) 1991-08-14 1992-08-14 烯烃聚合物组合物及其用途
CN95105201A Expired - Lifetime CN1048733C (zh) 1991-08-14 1995-05-02 含烯烃聚合物组合物的制品

Country Status (7)

Country Link
EP (4) EP0679661B1 (en:Method)
KR (2) KR960016863B1 (en:Method)
CN (3) CN1043144C (en:Method)
CA (2) CA2076065C (en:Method)
DE (4) DE69225414T2 (en:Method)
RU (2) RU2092501C1 (en:Method)
TW (2) TW274087B (en:Method)

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Publication number Publication date
EP0679661B1 (en) 1998-05-06
EP0534119B1 (en) 1996-01-31
EP0534119A2 (en) 1993-03-31
CA2076059A1 (en) 1993-02-15
KR960011548B1 (ko) 1996-08-23
DE69229351D1 (de) 1999-07-08
CN1069279A (zh) 1993-02-24
EP0611780B1 (en) 1999-06-02
EP0679661A1 (en) 1995-11-02
DE69216347D1 (de) 1997-02-13
EP0536503B1 (en) 1997-01-02
RU2091391C1 (ru) 1997-09-27
DE69225414T2 (de) 1998-11-19
EP0536503A2 (en) 1993-04-14
CN1063763C (zh) 2001-03-28
EP0611780A3 (en) 1995-10-25
EP0611780A2 (en) 1994-08-24
EP0536503A3 (en) 1993-08-11
KR930004337A (ko) 1993-03-22
DE69216347T3 (de) 2000-10-19
KR960016863B1 (ko) 1996-12-23
KR930004373A (ko) 1993-03-22
CN1113494A (zh) 1995-12-20
EP0536503B2 (en) 2000-04-12
DE69225414D1 (de) 1998-06-10
TW248565B (en:Method) 1995-06-01
CA2076065C (en) 1998-04-21
EP0534119A3 (en) 1993-08-11
DE69216347T2 (de) 1997-05-28
TW274087B (en:Method) 1996-04-11
DE69208006D1 (de) 1996-03-14
CN1048733C (zh) 2000-01-26
CN1070651A (zh) 1993-04-07
CA2076065A1 (en) 1993-02-15
DE69229351T2 (de) 1999-11-04
DE69208006T2 (de) 1996-06-13
RU2092501C1 (ru) 1997-10-10

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