KR930004373A - 올레핀 중합체 조성물 - Google Patents

올레핀 중합체 조성물 Download PDF

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KR930004373A
KR930004373A KR1019920014679A KR920014679A KR930004373A KR 930004373 A KR930004373 A KR 930004373A KR 1019920014679 A KR1019920014679 A KR 1019920014679A KR 920014679 A KR920014679 A KR 920014679A KR 930004373 A KR930004373 A KR 930004373A
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olefin
polyene
olefin polymer
polymer composition
composition according
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KR960016863B1 (ko
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데쓰노리 시노자끼
마모루 기오까
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다께바야시 쇼오고
미쓰이세끼유 가가꾸고오교오 가부시끼가이샤
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2308/00—Chemical blending or stepwise polymerisation process with the same catalyst

Abstract

내용 없음.

Description

올레핀 중합체 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 본 발명에서 사용되는 α-올레핀/폴리엔 공중합체 함유 중합체[Ⅰ]의 제조방법의 공정 설명도.

Claims (17)

  1. (ⅰ)α-올레핀/폴리엔 공중합체와, (ⅱ) 올레핀 중합체를 함유한, α-올레핀/폴리엔 공중합체 함유 공중합체(Ⅰ) 0.005∼99중량％와, 올레핀 중합체[Ⅱ]1∼99.995중량％로 구성됨을 특징으로 하는 올레핀 중합체 조성물.
  2. 제1항에 있어서, 상기 α-올레핀/폴리엔 중합체 함유 중합체[Ⅰ]가, 상기α-올레핀/폴리엔 공중합체(ⅰ)0.001∼15중량％와, 상기 올레핀 중합체(ⅱ)99.999∼85중량％로 구성된 α-올레핀/폴리엔 공중합체 함유 중합체인 것이 특징인 올레핀 중합체 조성물.
  3. 제1항 또는 제2항에있어서, 상기 α-올레핀/폴리엔 공중합체 함유 중합체[Ⅰ]가, [A]천이금속 화합물 촉매성분과 [B]주기표 Ⅰ∼Ⅲ족의 금속들로부터 선택한 금속을 함유한 유기금속 화합물 촉매성분을 함유한 촉매에, α-올레핀/폴리엔을 , 상기 천이금속 화합물 촉매성분 [A]1g당, 합계량으로 0.01∼2.000g을 공중합시켜 얻어진 α-올레핀/폴리엔 공중합체(ⅰ)로 구성된 예비중합된 촉매에,올레핀을 중합 또는 공중합시켜 올레핀중합체(ⅱ)를 제조함으로써 얻어진 α-올레핀/폴리엔 공중합체 함유 중합체인 것이 특징인 올레핀 중합체 조성물.
  4. 제1항 또는 제2항에 있어서, 상기 폴리엔 화합물이, 양말단에 올레핀성 2중 결합을 갖는 폴리엔 화합물인 것이 특징인 올레핀 중합체 조성물.
  5. 제1항 또는 제2항에 있어서, 상기 폴리엔 화합물이, 양 말단에 올레핀성 2중 결합을 갖는 탄소수 7이상의 지방족 폴리엔 화합물 및/또는 지환식 폴리엔 화합물인 것이 특징인 올레핀 중합체 조성물.
  6. 제3항에 있어서, 상기 천이금속 화합물 촉매성분[A], Ti, Zr, Hf, Nb, Ta,Cr 및 V 중에서 선택한 적어도 하나의 천이금속을 함유하는 것이 특징인 올레핀 중합체 조성물.
  7. 제3항에 있어서, 상기 천이금속 화합물 촉매성분[A]이, 티탄과 할로겐을 함유한 고체티타촉매성분인 것이 특징인 올레핀 중합체 조성물.
  8. 제3항에 있어서, 상기 천이금속 화합물 촉매성분[A]이, 시클로펜타디에닐 골격을 갖는 리간드를 함유한 메틸로센 화합물인 것이 특징인 올레핀 중합체 조성물.
  9. (ⅰ)α-올레핀/폴리엔 공중합체 15∼99중량％와, (ⅱ)올레핀 중합체 85∼1중량％를 함유한, α-올레핀/폴리엔 공중합체 함유 공중합체[Ⅰ]0.005∼99중량％, 올레핀 중합체 [Ⅱ]99.995∼1∼중량％로 구성됨을 특징으로 하는 올레핀 중합체 조성물.
  10. 제9항에 있어서, 상기 α-올레핀/폴리엔 공중합체 함유 중합체[Ⅰ]가, [A]천이금속 화합물 촉매성분과, [B]주기표 Ⅰ∼Ⅲ족의 금속들로부터 선택한 금속을 함유한 유기금속 화합물 촉매성분을 함유한 촉매에, α-올레핀/폴리엔을, 상기 천이금속 화합물 촉매성분[A]1g당, 합계량으로 0.01∼2.000g을 공중합시켜 얻어진 α-올레핀/폴리엔 공중합체(ⅰ)로 구성된 예비중합된 촉매에, 올레핀을 중합또는 공중합시켜 올레핀 중합체(ⅱ)를 제조함으로써 얻은 α-올레핀/폴리엔 공중합체 함유 중합체인 것이 특징인 올레핀 중합체 제조물.
  11. 제1항 기재의 올레핀 중합체 조성물로된 것이 특징인 진공성형품 또는 공기압 성형품.
  12. 제1항 기재의 올레핀 중합체 조성물로된 것이 특징인 블로우 성형품.
  13. 제1항 기재의 올레핀 중합체 조성물로된 것이 특징인 발포품.
  14. 제1항 기재의 올레핀 중합체 조성물로된 것이 특징인 캘린더 성형품.
  15. 제1항 기재의 올레핀 중합체 조성물로된 것이 특징인 팽창필름.
  16. 제1항 기재의 올레핀 중합체 조성물로된 것이 특징인 압출성형품.
  17. 제1항 기재의 올레핀 중합체 조성물로된 것이 특징인 연신 성형품.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019920014679A 1991-08-14 1992-08-14 올레핀 중합체 조성물 KR960016863B1 (ko)

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KR96045841A KR960016864B1 (en) 1991-08-14 1996-10-15 Olefin polymer composition

Applications Claiming Priority (8)

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JP20446691 1991-08-14
JP20446791 1991-08-14
JP20446491 1991-08-14
JP91-204467 1991-08-14
JP91-204464 1991-08-14
JP91-204465 1991-08-14
JP91-204466 1991-08-14
JP20446591 1991-08-14

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KR930004373A true KR930004373A (ko) 1993-03-22
KR960016863B1 KR960016863B1 (ko) 1996-12-23

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KR1019920014679A KR960016863B1 (ko) 1991-08-14 1992-08-14 올레핀 중합체 조성물
KR1019920014678A KR960011548B1 (ko) 1991-08-14 1992-08-14 올레핀 중합용 촉매, 올레핀 중합방법 및 올레핀 중합체

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EP (4) EP0611780B1 (ko)
KR (2) KR960016863B1 (ko)
CN (3) CN1063763C (ko)
CA (2) CA2076065C (ko)
DE (4) DE69225414T2 (ko)
RU (2) RU2092501C1 (ko)
TW (2) TW248565B (ko)

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CN1069279A (zh) 1993-02-24
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KR960011548B1 (ko) 1996-08-23
DE69216347T3 (de) 2000-10-19
DE69225414T2 (de) 1998-11-19
CN1043144C (zh) 1999-04-28
DE69229351T2 (de) 1999-11-04
CA2076065C (en) 1998-04-21
DE69208006D1 (de) 1996-03-14
KR960016863B1 (ko) 1996-12-23
EP0534119A2 (en) 1993-03-31
CN1048733C (zh) 2000-01-26
EP0534119B1 (en) 1996-01-31
EP0611780A2 (en) 1994-08-24
EP0679661A1 (en) 1995-11-02
CN1063763C (zh) 2001-03-28
EP0611780B1 (en) 1999-06-02
DE69229351D1 (de) 1999-07-08
RU2091391C1 (ru) 1997-09-27
DE69216347D1 (de) 1997-02-13
EP0536503A3 (en) 1993-08-11
EP0534119A3 (en) 1993-08-11
CA2076065A1 (en) 1993-02-15
CA2076059A1 (en) 1993-02-15
DE69225414D1 (de) 1998-06-10
CN1113494A (zh) 1995-12-20
DE69216347T2 (de) 1997-05-28
RU2092501C1 (ru) 1997-10-10
TW248565B (ko) 1995-06-01
EP0611780A3 (en) 1995-10-25
EP0536503A2 (en) 1993-04-14
CN1070651A (zh) 1993-04-07
EP0536503B2 (en) 2000-04-12
KR930004337A (ko) 1993-03-22

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