DE3069992D1 - Catalyst and process for producing olefin polymers or copolymers - Google Patents
Catalyst and process for producing olefin polymers or copolymersInfo
- Publication number
- DE3069992D1 DE3069992D1 DE8080300349T DE3069992T DE3069992D1 DE 3069992 D1 DE3069992 D1 DE 3069992D1 DE 8080300349 T DE8080300349 T DE 8080300349T DE 3069992 T DE3069992 T DE 3069992T DE 3069992 D1 DE3069992 D1 DE 3069992D1
- Authority
- DE
- Germany
- Prior art keywords
- catalyst
- olefin
- alpha
- copolymers
- phosphorus
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/905—Polymerization in presence of transition metal containing catalyst in presence of hydrogen
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/906—Comminution of transition metal containing catalyst
Abstract
A catalyst for use in producing olefin polymers or copolymers comprising (A) a solid titanium catalyst component having magnesium, halogen, titanium, phosphorus and a carboxylic acid ester and (B) an organometallic compound of a metal of Groups I to III of Mendelejeff's periodic table provides improved results, in that stereoregular products can be obtained over a wide range of melt flow indices, when the solid titanium catalyst component (A) is one in which the molar ratio of the phosphorus to the carboxylic acid ester is from 0.05:1 to 2:1 and which has a specific surface area of not less than 40 m<2>/g, and also contains (C) an electron donor.
<??>The catalyst can be used to produce an olefin polymer or copolymer by polymerizing an alpha-olefin having at least 3 carbon atoms or copolymerizing at least two such alpha-olefins or such an alpha-olefin with up to 20 mole% of ethylene and/or a diene.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP54011823A JPS5923561B2 (en) | 1979-02-06 | 1979-02-06 | Olefin polymerization method |
Publications (1)
Publication Number | Publication Date |
---|---|
DE3069992D1 true DE3069992D1 (en) | 1985-03-07 |
Family
ID=11788487
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE8080300349T Expired DE3069992D1 (en) | 1979-02-06 | 1980-02-06 | Catalyst and process for producing olefin polymers or copolymers |
Country Status (6)
Country | Link |
---|---|
US (1) | US4404341A (en) |
EP (1) | EP0015099B1 (en) |
JP (1) | JPS5923561B2 (en) |
AT (1) | ATE11418T1 (en) |
CA (1) | CA1139737A (en) |
DE (1) | DE3069992D1 (en) |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5819307A (en) * | 1981-07-27 | 1983-02-04 | Mitsubishi Petrochem Co Ltd | Production of olefin polymer |
DE3247919A1 (en) * | 1982-12-24 | 1984-06-28 | Basf Ag, 6700 Ludwigshafen | METHOD FOR PRODUCING HOMO AND COPOLYMERISATS FROM (ALPHA) MONOOLEFINES BY MEANS OF A ZIEGLER-NATTA CATALYST SYSTEM |
US4521541A (en) * | 1983-02-09 | 1985-06-04 | International Flavors & Fragrances Inc. | Process for forming functional fluid and solid-containing thermoplastic films, uses thereof and process for producing same |
JPH0723407B2 (en) * | 1986-04-08 | 1995-03-15 | 三菱油化株式会社 | Catalyst component for propylene polymerization |
JPS6383104A (en) * | 1986-09-26 | 1988-04-13 | Idemitsu Petrochem Co Ltd | Production of olefin polymer |
JPS63146905A (en) * | 1986-12-11 | 1988-06-18 | Idemitsu Petrochem Co Ltd | Production of olefinic polymer |
US4948770A (en) * | 1987-06-29 | 1990-08-14 | Shell Oil Company | Method for crystallizing magnesium chloride and method for using in a catalyst composition |
DE3823934C2 (en) * | 1987-07-31 | 2002-01-03 | Petroleo Brasileiro Sa | Process for producing an ethylene polymerization catalyst and ethylene polymerization process |
US5288933A (en) * | 1992-04-16 | 1994-02-22 | Union Carbide Chemicals & Plastics Technology Corporation | Process for the production of polyethylene |
EP0952162A1 (en) * | 1998-04-24 | 1999-10-27 | Fina Research S.A. | Production of Ziegler-Natta catalysts |
US6767857B1 (en) * | 2003-05-29 | 2004-07-27 | Fina Technology, Inc. | Process for forming a Ziegler-Natta catalyst system having a controlled morphology |
KR100472771B1 (en) * | 2003-08-30 | 2005-03-14 | 주식회사 일렘테크놀러지홀딩스 | high stereospecific polybutene-1 polymer and the highly active preparation method thereof |
MX2018009997A (en) | 2016-02-18 | 2019-02-07 | Int Flavors & Fragrances Inc | Polyurea capsule compositions. |
MX2019003078A (en) | 2016-09-16 | 2019-07-08 | Int Flavors & Fragrances Inc | Microcapsule compositions stabilized with viscosity control agents. |
CN115010830B (en) * | 2021-03-03 | 2024-01-30 | 中国石油天然气股份有限公司 | Olefin polymerization catalyst carrier, preparation method thereof, olefin polymerization catalyst and system |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL162664B (en) * | 1969-06-20 | 1980-01-15 | Montedison Spa | PROCESS FOR PREPARING A CATALYST FOR THE POLYMERIZATION OF OLEFINS-1. |
US4187196A (en) * | 1971-06-25 | 1980-02-05 | Montedison S.P.A. | Process for the stereoregular polymerization of alpha-olefins |
IT956396B (en) * | 1972-06-09 | 1973-10-10 | Montedison Spa | PROCESS FOR THE PREPARATION OF ELASTOMERIC COPOLYMERS OF ETI LENE WITH ALPHA OLEFINS |
GB1492618A (en) * | 1974-02-01 | 1977-11-23 | Mitsui Petrochemical Ind | Process for preparing highly stereoregular polyolefins and catalyst used therefor |
US4069169A (en) * | 1975-11-24 | 1978-01-17 | Mitsui Petrochemical Industries Ltd. | Process for preparation of catalyst component supported on high performance carrier |
US4180636A (en) * | 1976-06-24 | 1979-12-25 | Showa Denko Kabushiki Kaisha | Process for polymerizing or co-polymerizing propylene |
JPS5373279A (en) * | 1976-12-13 | 1978-06-29 | Mitsubishi Chem Ind Ltd | Preparation of olefin polymer |
US4130503A (en) * | 1977-12-23 | 1978-12-19 | Phillips Petroleum Company | Phosphite in MgX2 supported TiX3 /AlCl3 catalyst system |
-
1979
- 1979-02-06 JP JP54011823A patent/JPS5923561B2/en not_active Expired
-
1980
- 1980-02-04 US US06/118,325 patent/US4404341A/en not_active Expired - Lifetime
- 1980-02-06 CA CA000345172A patent/CA1139737A/en not_active Expired
- 1980-02-06 EP EP80300349A patent/EP0015099B1/en not_active Expired
- 1980-02-06 DE DE8080300349T patent/DE3069992D1/en not_active Expired
- 1980-02-06 AT AT80300349T patent/ATE11418T1/en not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
EP0015099A1 (en) | 1980-09-03 |
US4404341A (en) | 1983-09-13 |
JPS55104303A (en) | 1980-08-09 |
CA1139737A (en) | 1983-01-18 |
EP0015099B1 (en) | 1985-01-23 |
JPS5923561B2 (en) | 1984-06-02 |
ATE11418T1 (en) | 1985-02-15 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
8363 | Opposition against the patent | ||
8365 | Fully valid after opposition proceedings | ||
8327 | Change in the person/name/address of the patent owner |
Owner name: MITSUI CHEMICALS, INC., TOKIO/TOKYO, JP |