GB1492618A - Process for preparing highly stereoregular polyolefins and catalyst used therefor - Google Patents
Process for preparing highly stereoregular polyolefins and catalyst used thereforInfo
- Publication number
- GB1492618A GB1492618A GB345975A GB345975A GB1492618A GB 1492618 A GB1492618 A GB 1492618A GB 345975 A GB345975 A GB 345975A GB 345975 A GB345975 A GB 345975A GB 1492618 A GB1492618 A GB 1492618A
- Authority
- GB
- United Kingdom
- Prior art keywords
- iii
- carboxylic ester
- catalyst
- halo
- linear
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/02—Carriers therefor
- C08F4/022—Magnesium halide as support anhydrous or hydrated or complexed by means of a Lewis base for Ziegler-type catalysts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
1492618 Ziegler polymerization catalyst for olefins MITSUI PETROCHEMICAL INDUSTRIES Ltd 27 Jan 1975 [1 Feb 1974 10 Aug 1974] 3459/75 Heading C3P Alphaolefins are polymerized in the presence of a catalyst comprising (A) a trialkyl aluminium or alkyl alkoxyaluminium compound or a complex thereof with a carboxylic ester, and (B) a solid titanium component which is a complex obtained by contacting, in any order, (i) a magnesium dihalide; (ii) a silicon compound which is a tetrahydrocarbylsilane, a halo and/or hydrocarbyl di- or polysilane, or a linear or cyclic siloxane which may be substituted by hydrocarbyl groups or in which the linear polysiloxanes are terminated by halo radicals; (iii) an organic carboxylic ester, and (iv) a tetravalent titanium halide, alkoxide or haloalkoxide. The various compounds (i) to (iv) may be pulverized together. Typical examples refer to the solution polymerization of propylene, in the presence of (A) Et 3 , Al or Bu 3 Al, and (B) (i) MgCl 2 (ii) methyl polysiloxane, hexamethyldisiloxane, 1,3-dichlorotetramethyldisiloxane, dimethyl diallyl silane, methyl pentachlorodisilane or octa phenylcyclotetrasiloxane; (iii) ethyl benzoate or ethyl chloroacetate and (iv) T : Cl 4 .
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP49012860A JPS5236786B2 (en) | 1974-02-01 | 1974-02-01 | |
JP49091181A JPS5120297A (en) | 1974-08-10 | 1974-08-10 | Arufua orefuinno koritsutaikisokuseijugohoho |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1492618A true GB1492618A (en) | 1977-11-23 |
Family
ID=26348543
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB345975A Expired GB1492618A (en) | 1974-02-01 | 1975-01-27 | Process for preparing highly stereoregular polyolefins and catalyst used therefor |
Country Status (7)
Country | Link |
---|---|
DE (1) | DE2504036C3 (en) |
FR (1) | FR2259842B1 (en) |
GB (1) | GB1492618A (en) |
HU (1) | HU172049B (en) |
IT (1) | IT1031397B (en) |
NL (1) | NL163226C (en) |
RO (1) | RO67837A (en) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0015099A1 (en) * | 1979-02-06 | 1980-09-03 | Mitsui Petrochemical Industries, Ltd. | Catalyst and process for producing olefin polymers or copolymers |
US4314046A (en) | 1978-04-12 | 1982-02-02 | Toa Nenryo Kogyo Kabushiki Kaisha | Process for the stereoregular polymerization of α-olefins in the presence of a supported titanium catalyst |
US4316966A (en) | 1979-10-16 | 1982-02-23 | Mitsui Petrochemical Industries Ltd. | Process for producing chemically blended propylene resin composition |
US4412049A (en) | 1980-09-29 | 1983-10-25 | Sumitomo Chemical Company, Limited | Process for producing highly stereoregular α-olefin polymers |
GB2130225A (en) * | 1982-09-24 | 1984-05-31 | Nippon Oil Co Ltd | Ziegler catalysed olefin polymerization |
US6800580B1 (en) | 1999-10-23 | 2004-10-05 | Samsung General Chemicals Co., Ltd. | Method for producing an improved catalyst for homo-and co-polymerization of olefin |
US6831033B2 (en) | 2001-06-21 | 2004-12-14 | Samsung General Chemicals Co., Ltd. | Method of preparing a catalyst for polymerization and copolymerization of ethylene |
Families Citing this family (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4105847A (en) | 1974-11-26 | 1978-08-08 | Mitsui Toatsu Chemicals Inc. | Method for polymerization of ethylene |
NL7509736A (en) * | 1975-08-15 | 1977-02-17 | Stamicarbon | PROCESS FOR POLYMERIZING ALKINES-1. |
NL7509735A (en) * | 1975-08-15 | 1977-02-17 | Stamicarbon | PROCESS FOR POLYMERIZING ALKINES-1. |
IT1042180B (en) * | 1975-08-29 | 1980-01-30 | Montedison Spa | PROPOLENE CRYSTAL POLYMERS AND COPOLYMERS AND PROCEDURE FOR THEIR PREPARATION |
IT1054410B (en) * | 1975-11-21 | 1981-11-10 | Mitsui Petrochemical Ind | CATALYSTS FOR THE POLYMERIZATION OF ALPHA OLEFINS |
SE7613662L (en) * | 1975-12-10 | 1977-06-11 | Mitsui Petrochemical Ind | POLYMERIZATION OF ALFA-OLEFINES |
JPS5287489A (en) * | 1976-01-19 | 1977-07-21 | Mitsui Petrochem Ind Ltd | Polymerization of olefins |
JPS52104593A (en) | 1976-03-01 | 1977-09-02 | Mitsui Petrochem Ind Ltd | Polymerization of olefins |
CA1087596A (en) * | 1976-05-14 | 1980-10-14 | Battelle Memorial Institute | Process for the preparation of olefine polymerization catalysts |
US4180636A (en) * | 1976-06-24 | 1979-12-25 | Showa Denko Kabushiki Kaisha | Process for polymerizing or co-polymerizing propylene |
JPS5952166B2 (en) * | 1976-06-29 | 1984-12-18 | 三井化学株式会社 | Method for manufacturing polyolefin |
US4507450A (en) * | 1976-08-18 | 1985-03-26 | Mitsubishi Chemical Industries Limited | Process for preparing polyolefin |
JPS5812888B2 (en) * | 1976-08-27 | 1983-03-10 | 三井化学株式会社 | Method for manufacturing polyolefin |
JPS58448B2 (en) * | 1976-09-27 | 1983-01-06 | 三井化学株式会社 | Method for manufacturing polyolefin |
DE2742586A1 (en) * | 1976-09-28 | 1978-03-30 | Asahi Chemical Ind | NEW POLYMERIZATION CATALYSTS AND THEIR USE (II) |
US4242479A (en) * | 1976-12-23 | 1980-12-30 | Showa Yuka Kabushiki Kaisha | Process for producing an improved ethylenic polymer |
JPS591407B2 (en) * | 1977-03-04 | 1984-01-12 | 三井化学株式会社 | Method for producing titanium catalyst component |
US4237254A (en) * | 1977-04-30 | 1980-12-02 | Mitsubishi Petrochemical Company Limited | Process for producing olefin polymers |
JPS595202B2 (en) * | 1978-04-12 | 1984-02-03 | 東亜燃料工業株式会社 | Method for producing a catalyst component for α-olefin polymerization |
IT1127222B (en) * | 1979-11-14 | 1986-05-21 | Montedison Spa | CATALYST COMPONENTS FOR OLEFINE POLYMERIZATION |
CA1144698A (en) * | 1980-01-09 | 1983-04-12 | Albert S. Matlack | 1-olefin polymerization catalyst |
KR100334165B1 (en) | 1998-04-17 | 2002-11-27 | 삼성종합화학주식회사 | A PRODUCTION METHOD OF A SUPPORTED CATALYST FOR ETHYLENE POLYMERIZATION AND ETHYLENE/α-OLEFIN COPOLYMERIZATION |
KR100334163B1 (en) | 1998-12-04 | 2002-10-25 | 삼성종합화학주식회사 | Olefin Polymerization or Copolymerization Method |
KR100361224B1 (en) | 1999-12-01 | 2002-11-29 | 삼성종합화학주식회사 | Method for preparing catalyst for ethylene homo- and co-polymerization |
KR100351386B1 (en) | 2000-04-24 | 2002-09-05 | 삼성종합화학주식회사 | Catalyst for preparation of ultra high molecular weight polyethylene and preparation method of ultra high molecular weight polyethylene using the same |
KR100353960B1 (en) | 2000-05-31 | 2002-09-27 | 삼성종합화학주식회사 | A method for producing ethylene homo- and co-polymer |
KR100359932B1 (en) | 2000-06-15 | 2002-11-07 | 삼성종합화학주식회사 | A catalyst for ethylene homo- and copolymerization |
KR100421553B1 (en) | 2000-12-27 | 2004-03-09 | 삼성아토피나주식회사 | A polymerization method of alpha-olefins |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1016512A (en) * | 1961-07-28 | 1966-01-12 | Kogyogijutsuin | Preparation of a new type polymer silicopolypropylene |
JPS4932195B1 (en) * | 1970-10-02 | 1974-08-28 | ||
NL7114641A (en) * | 1970-10-29 | 1972-05-03 | ||
NL160286C (en) * | 1971-06-25 | |||
GB1452314A (en) * | 1972-11-10 | 1976-10-13 | Mitsui Petrochemical Ind Ld | Catalyst compositions for use in the polymerziation of olefins |
-
1975
- 1975-01-27 GB GB345975A patent/GB1492618A/en not_active Expired
- 1975-01-29 HU HU75MI00000574A patent/HU172049B/en unknown
- 1975-01-31 NL NL7501176A patent/NL163226C/en not_active IP Right Cessation
- 1975-01-31 FR FR7503095A patent/FR2259842B1/fr not_active Expired
- 1975-01-31 DE DE19752504036 patent/DE2504036C3/en not_active Expired
- 1975-01-31 IT IT1987775A patent/IT1031397B/en active
- 1975-02-01 RO RO7581319A patent/RO67837A/en unknown
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4314046A (en) | 1978-04-12 | 1982-02-02 | Toa Nenryo Kogyo Kabushiki Kaisha | Process for the stereoregular polymerization of α-olefins in the presence of a supported titanium catalyst |
EP0015099A1 (en) * | 1979-02-06 | 1980-09-03 | Mitsui Petrochemical Industries, Ltd. | Catalyst and process for producing olefin polymers or copolymers |
US4316966A (en) | 1979-10-16 | 1982-02-23 | Mitsui Petrochemical Industries Ltd. | Process for producing chemically blended propylene resin composition |
US4412049A (en) | 1980-09-29 | 1983-10-25 | Sumitomo Chemical Company, Limited | Process for producing highly stereoregular α-olefin polymers |
GB2130225A (en) * | 1982-09-24 | 1984-05-31 | Nippon Oil Co Ltd | Ziegler catalysed olefin polymerization |
US6800580B1 (en) | 1999-10-23 | 2004-10-05 | Samsung General Chemicals Co., Ltd. | Method for producing an improved catalyst for homo-and co-polymerization of olefin |
US6831033B2 (en) | 2001-06-21 | 2004-12-14 | Samsung General Chemicals Co., Ltd. | Method of preparing a catalyst for polymerization and copolymerization of ethylene |
Also Published As
Publication number | Publication date |
---|---|
DE2504036C3 (en) | 1984-09-13 |
FR2259842A1 (en) | 1975-08-29 |
FR2259842B1 (en) | 1983-08-12 |
AU7764475A (en) | 1976-07-29 |
HU172049B (en) | 1978-05-28 |
NL7501176A (en) | 1975-08-05 |
DE2504036B2 (en) | 1981-01-15 |
DE2504036A1 (en) | 1975-08-07 |
NL163226C (en) | 1980-08-15 |
NL163226B (en) | 1980-03-17 |
IT1031397B (en) | 1979-04-30 |
RO67837A (en) | 1982-05-10 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PE20 | Patent expired after termination of 20 years |
Effective date: 19950126 |