CN103930511A - 光学透明的双固化粘合剂组合物 - Google Patents
光学透明的双固化粘合剂组合物 Download PDFInfo
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- CN103930511A CN103930511A CN201280039230.8A CN201280039230A CN103930511A CN 103930511 A CN103930511 A CN 103930511A CN 201280039230 A CN201280039230 A CN 201280039230A CN 103930511 A CN103930511 A CN 103930511A
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- Prior art keywords
- methyl
- weight
- acrylate
- composition
- acryloxy
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- 239000003999 initiator Substances 0.000 claims description 75
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 63
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- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 12
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- LDHQCZJRKDOVOX-UHFFFAOYSA-N 2-butenoic acid Chemical compound CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 claims description 8
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 claims description 8
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- 239000012965 benzophenone Substances 0.000 claims description 6
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- PSGCQDPCAWOCSH-UHFFFAOYSA-N (4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl) prop-2-enoate Chemical compound C1CC2(C)C(OC(=O)C=C)CC1C2(C)C PSGCQDPCAWOCSH-UHFFFAOYSA-N 0.000 claims description 4
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- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims description 3
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- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 3
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- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 claims description 2
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- BQZJOQXSCSZQPS-UHFFFAOYSA-N 2-methoxy-1,2-diphenylethanone Chemical compound C=1C=CC=CC=1C(OC)C(=O)C1=CC=CC=C1 BQZJOQXSCSZQPS-UHFFFAOYSA-N 0.000 claims description 2
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- CRVGTESFCCXCTH-UHFFFAOYSA-N methyl diethanolamine Chemical compound OCCN(C)CCO CRVGTESFCCXCTH-UHFFFAOYSA-N 0.000 claims description 2
- HUTCEBBVAOYBMW-UHFFFAOYSA-N methyl prop-2-enoate;morpholine Chemical compound COC(=O)C=C.C1COCCN1 HUTCEBBVAOYBMW-UHFFFAOYSA-N 0.000 claims description 2
- 229910052757 nitrogen Inorganic materials 0.000 claims description 2
- RZFODFPMOHAYIR-UHFFFAOYSA-N oxepan-2-one;prop-2-enoic acid Chemical compound OC(=O)C=C.O=C1CCCCCO1 RZFODFPMOHAYIR-UHFFFAOYSA-N 0.000 claims description 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims description 2
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- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims 2
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- AUONHKJOIZSQGR-UHFFFAOYSA-N oxophosphane Chemical compound P=O AUONHKJOIZSQGR-UHFFFAOYSA-N 0.000 claims 1
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- ZMARGGQEAJXRFP-UHFFFAOYSA-N 1-hydroxypropan-2-yl 2-methylprop-2-enoate Chemical compound OCC(C)OC(=O)C(C)=C ZMARGGQEAJXRFP-UHFFFAOYSA-N 0.000 description 1
- DMWVYCCGCQPJEA-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhexane Chemical compound CC(C)(C)OOC(C)(C)CCC(C)(C)OOC(C)(C)C DMWVYCCGCQPJEA-UHFFFAOYSA-N 0.000 description 1
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 description 1
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- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical group CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- WTBPWOVBWKJVPF-UHFFFAOYSA-N 3-(2-ethylhexylperoxymethyl)heptane Chemical compound CCCCC(CC)COOCC(CC)CCCC WTBPWOVBWKJVPF-UHFFFAOYSA-N 0.000 description 1
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- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
- C08F222/10—Esters
- C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
- C08F222/106—Esters of polycondensation macromers
- C08F222/1065—Esters of polycondensation macromers of alcohol terminated (poly)urethanes, e.g. urethane(meth)acrylates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J109/00—Adhesives based on homopolymers or copolymers of conjugated diene hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
- C09J175/04—Polyurethanes
- C09J175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
- C09J175/04—Polyurethanes
- C09J175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
- C09J175/16—Polyurethanes having carbon-to-carbon unsaturated bonds having terminal carbon-to-carbon unsaturated bonds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
- C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
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- Macromonomer-Based Addition Polymer (AREA)
Abstract
Description
组分 | 含量 |
含有(甲基)丙烯酰氧基团的氨基甲酸酯低聚物1-1 | 70重量份 |
(甲基)丙烯酸酯4-1 | 10重量份 |
(甲基)丙烯酸酯4-2 | 7重量份 |
(甲基)丙烯酸酯4-3 | 7重量份 |
紫外光引发剂5-1 | 2重量份 |
紫外光引发剂5-2 | 1重量份 |
热引发剂6-1 | 2重量份 |
热引发剂6-2 | 1重量份 |
组分 | 含量 |
含有(甲基)丙烯酰氧基团的氨基甲酸酯低聚物1-1 | 70重量份 |
(甲基)丙烯酸酯4-1 | 11重量份 |
(甲基)丙烯酸酯4-2 | 7重量份 |
(甲基)丙烯酸酯4-3 | 7重量份 |
紫外光引发剂5-1 | 2重量份 |
紫外光引发剂5-2 | 1重量份 |
热引发剂6-1 | 2重量份 |
组分 | 含量 |
含有(甲基)丙烯酰氧基团的氨基甲酸酯低聚物1-1 | 70重量份 |
(甲基)丙烯酸酯4-1 | 11重量份 |
(甲基)丙烯酸酯4-2 | 8重量份 |
(甲基)丙烯酸酯4-3 | 8重量份 |
紫外光引发剂5-1 | 1重量份 |
组分 | 含量 |
含有(甲基)丙烯酰氧基团的氨基甲酸酯低聚物1-2 | 65重量份 |
含有(甲基)丙烯酰氧基团的氨基甲酸酯低聚物1-3 | 20重量份 |
(甲基)丙烯酸酯4-1 | 10重量份 |
(甲基)丙烯酸酯4-2 | 7重量份 |
(甲基)丙烯酸酯4-3 | 7重量份 |
紫外光引发剂5-1 | 2重量份 |
热引发剂6-1 | 2重量份 |
热引发剂6-2 | 1重量份 |
组分 | 含量 |
含有(甲基)丙烯酰氧基团的氨基甲酸酯低聚物1-2 | 65重量份 |
含有(甲基)丙烯酰氧基团的氨基甲酸酯低聚物1-3 | 20重量份 |
(甲基)丙烯酸酯4-1 | 10重量份 |
(甲基)丙烯酸酯4-2 | 7重量份 |
(甲基)丙烯酸酯4-3 | 7重量份 |
紫外光引发剂5-1 | 2重量份 |
紫外光引发剂5-2 | 1重量份 |
热引发剂6-1 | 2重量份 |
组分 | 含量 |
具有甲基丙烯酰氧基的聚异戊二烯2-1 | 30重量份 |
液体聚丁二烯3-1 | 40重量份 |
(甲基)丙烯酸酯4-1 | 12重量份 |
(甲基)丙烯酸酯4-2 | 12重量份 |
紫外光引发剂5-1 | 2重量份 |
紫外光引发剂5-2 | 1重量份 |
热引发剂6-1 | 2重量份 |
热引发剂6-2 | 1重量份 |
组分 | 含量 |
具有甲基丙烯酰氧基的聚异戊二烯2-1 | 30重量份 |
液体聚丁二烯3-1 | 40重量份 |
(甲基)丙烯酸酯4-2 | 12重量份 |
(甲基)丙烯酸酯4-4 | 12重量份 |
紫外光引发剂5-1 | 2重量份 |
紫外光引发剂5-2 | 1重量份 |
热引发剂6-1 | 2重量份 |
热引发剂6-2 | 1重量份 |
组分 | 含量 |
具有甲基丙烯酰氧基的聚异戊二烯2-1 | 30重量份 |
具有甲基丙烯酰氧基的聚异戊二烯2-2 | 10重量份 |
液体聚丁二烯3-1 | 33重量份 |
(甲基)丙烯酸酯4-1 | 12重量份 |
(甲基)丙烯酸酯4-2 | 12重量份 |
紫外光引发剂5-1 | 2重量份 |
紫外光引发剂5-2 | 1重量份 |
组分 | 含量 |
具有甲基丙烯酰氧基的聚异戊二烯2-1 | 50重量份 |
(甲基)丙烯酸酯4-1 | 12重量份 |
(甲基)丙烯酸酯4-2 | 12重量份 |
(甲基)丙烯酸酯4-4 | 20重量份 |
紫外光引发剂5-1 | 2重量份 |
紫外光引发剂5-2 | 1重量份 |
热引发剂6-1 | 2重量份 |
热引发剂6-2 | 1重量份 |
组分 | 含量 |
具有甲基丙烯酰氧基的聚异戊二烯2-1 | 45重量份 |
具有甲基丙烯酰氧基的聚异戊二烯2-2 | 15重量份 |
(甲基)丙烯酸酯4-1 | 17重量份 |
(甲基)丙烯酸酯4-4 | 17重量份 |
紫外光引发剂5-1 | 2重量份 |
紫外光引发剂5-2 | 1重量份 |
热引发剂6-1 | 2重量份 |
热引发剂6-2 | 1重量份 |
Claims (15)
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CN201280039230.8A CN103930511A (zh) | 2011-08-12 | 2012-08-09 | 光学透明的双固化粘合剂组合物 |
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CN2011102307241A CN102925062A (zh) | 2011-08-12 | 2011-08-12 | 光学透明的双固化粘合剂 |
PCT/CN2012/079869 WO2013023545A1 (en) | 2011-08-12 | 2012-08-09 | Optical transparent dual cure adhesives composition |
CN201280039230.8A CN103930511A (zh) | 2011-08-12 | 2012-08-09 | 光学透明的双固化粘合剂组合物 |
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CN201280039230.8A Pending CN103930511A (zh) | 2011-08-12 | 2012-08-09 | 光学透明的双固化粘合剂组合物 |
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US (3) | US20140163130A1 (zh) |
EP (1) | EP2742108B1 (zh) |
JP (1) | JP2014527106A (zh) |
KR (1) | KR101951974B1 (zh) |
CN (2) | CN102925062A (zh) |
ES (1) | ES2659559T3 (zh) |
TW (1) | TWI553082B (zh) |
WO (1) | WO2013023545A1 (zh) |
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CN104449542A (zh) * | 2014-12-11 | 2015-03-25 | 江南大学 | 一种新型双重固化的紫外光固化粘合剂的制备方法 |
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TWI762441B (zh) * | 2015-05-26 | 2022-05-01 | 德商漢高股份有限及兩合公司 | 光固化黏著劑組成物、其製備方法及其用途 |
CN109072021A (zh) * | 2016-04-26 | 2018-12-21 | 王子控股株式会社 | 双面粘着片及积层体 |
CN109072021B (zh) * | 2016-04-26 | 2021-05-28 | 王子控股株式会社 | 双面粘着片及积层体 |
CN106497438A (zh) * | 2016-11-10 | 2017-03-15 | 深圳飞世尔新材料股份有限公司 | 一种电容式触摸屏贴合用光热双重固化光学胶粘剂 |
CN106893501A (zh) * | 2017-01-20 | 2017-06-27 | 广东多正化工科技有限公司 | 单组份低温光固化丙烯酸酯胶粘剂及其制备方法 |
CN111133012A (zh) * | 2017-09-22 | 2020-05-08 | 株式会社Lg化学 | 用于偏光板保护层的无溶剂型可光固化树脂组合物、包含其固化产物的偏光板和图像显示装置 |
CN111133012B (zh) * | 2017-09-22 | 2022-01-28 | 杉金光电(苏州)有限公司 | 用于偏光板保护层的无溶剂型可光固化树脂组合物、包含其固化产物的偏光板和图像显示装置 |
CN109988513A (zh) * | 2018-01-03 | 2019-07-09 | 泰柏斯科技有限公司 | 紫外线可固化光学粘合剂以及包括其的堆叠结构 |
CN109988513B (zh) * | 2018-01-03 | 2022-05-24 | 泰柏斯科技有限公司 | 紫外线可固化光学粘合剂以及包括其的堆叠结构 |
CN110845679A (zh) * | 2019-11-19 | 2020-02-28 | 珠海格力绿色再生资源有限公司 | 改性端羟基聚丁二烯液体橡胶光热双重固化材料及制法 |
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US20160024357A1 (en) | 2016-01-28 |
ES2659559T3 (es) | 2018-03-16 |
KR101951974B1 (ko) | 2019-02-25 |
TW201307506A (zh) | 2013-02-16 |
KR20140065414A (ko) | 2014-05-29 |
TWI553082B (zh) | 2016-10-11 |
WO2013023545A1 (en) | 2013-02-21 |
EP2742108B1 (en) | 2018-01-24 |
US9708518B2 (en) | 2017-07-18 |
US20140163130A1 (en) | 2014-06-12 |
EP2742108A1 (en) | 2014-06-18 |
JP2014527106A (ja) | 2014-10-09 |
EP2742108A4 (en) | 2015-04-08 |
US20150159059A1 (en) | 2015-06-11 |
CN102925062A (zh) | 2013-02-13 |
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