CH616861A5 - Oxidation catalyst. - Google Patents
Oxidation catalyst. Download PDFInfo
- Publication number
- CH616861A5 CH616861A5 CH952175A CH952175A CH616861A5 CH 616861 A5 CH616861 A5 CH 616861A5 CH 952175 A CH952175 A CH 952175A CH 952175 A CH952175 A CH 952175A CH 616861 A5 CH616861 A5 CH 616861A5
- Authority
- CH
- Switzerland
- Prior art keywords
- mixture
- catalyst
- catalysts
- represent
- oxidation catalyst
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title claims description 113
- 238000007254 oxidation reaction Methods 0.000 title claims description 21
- 230000003647 oxidation Effects 0.000 title claims description 19
- 239000000203 mixture Substances 0.000 claims description 42
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 18
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 11
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 11
- 229910052721 tungsten Inorganic materials 0.000 claims description 10
- 239000010937 tungsten Substances 0.000 claims description 10
- 229910052698 phosphorus Inorganic materials 0.000 claims description 9
- 239000011574 phosphorus Substances 0.000 claims description 9
- 229910017052 cobalt Inorganic materials 0.000 claims description 8
- 239000010941 cobalt Substances 0.000 claims description 8
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 8
- 239000011777 magnesium Substances 0.000 claims description 8
- 229910052759 nickel Inorganic materials 0.000 claims description 8
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 7
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 7
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 7
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 7
- 229910052793 cadmium Inorganic materials 0.000 claims description 7
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims description 7
- 239000011575 calcium Substances 0.000 claims description 7
- 229910052791 calcium Inorganic materials 0.000 claims description 7
- 229910052749 magnesium Inorganic materials 0.000 claims description 7
- 229910052712 strontium Inorganic materials 0.000 claims description 7
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims description 7
- 229910052717 sulfur Inorganic materials 0.000 claims description 7
- 239000011593 sulfur Substances 0.000 claims description 7
- 229910052725 zinc Inorganic materials 0.000 claims description 7
- 239000011701 zinc Substances 0.000 claims description 7
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 6
- 229910052783 alkali metal Inorganic materials 0.000 claims description 6
- 150000001340 alkali metals Chemical class 0.000 claims description 6
- 229910052787 antimony Inorganic materials 0.000 claims description 6
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 6
- 229910052785 arsenic Inorganic materials 0.000 claims description 6
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims description 6
- 229910052796 boron Inorganic materials 0.000 claims description 6
- 239000011651 chromium Substances 0.000 claims description 6
- 229910052732 germanium Inorganic materials 0.000 claims description 6
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims description 6
- 239000010955 niobium Substances 0.000 claims description 6
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 6
- 239000011135 tin Substances 0.000 claims description 6
- 239000011572 manganese Substances 0.000 claims description 5
- 229910052718 tin Inorganic materials 0.000 claims description 5
- 229910052684 Cerium Inorganic materials 0.000 claims description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 4
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 4
- 229910052776 Thorium Inorganic materials 0.000 claims description 4
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 4
- 229910052802 copper Inorganic materials 0.000 claims description 4
- 239000010949 copper Substances 0.000 claims description 4
- 229910052738 indium Inorganic materials 0.000 claims description 4
- 229910052746 lanthanum Inorganic materials 0.000 claims description 4
- 229910052758 niobium Inorganic materials 0.000 claims description 4
- 229910052707 ruthenium Inorganic materials 0.000 claims description 4
- 229910052709 silver Inorganic materials 0.000 claims description 4
- 239000004332 silver Substances 0.000 claims description 4
- 229910052716 thallium Inorganic materials 0.000 claims description 4
- BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 claims description 4
- 229910052727 yttrium Inorganic materials 0.000 claims description 4
- 229910052726 zirconium Inorganic materials 0.000 claims description 4
- ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 claims description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 3
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims description 3
- 229910052777 Praseodymium Inorganic materials 0.000 claims description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 3
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 3
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims description 3
- 229910052804 chromium Inorganic materials 0.000 claims description 3
- 229910052733 gallium Inorganic materials 0.000 claims description 3
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims description 3
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims description 3
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 3
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 3
- PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 claims description 3
- 229910052715 tantalum Inorganic materials 0.000 claims description 3
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims description 3
- 229910052714 tellurium Inorganic materials 0.000 claims description 3
- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 claims description 3
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 claims 2
- 239000002184 metal Substances 0.000 claims 2
- 229910052748 manganese Inorganic materials 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 description 51
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 25
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 25
- 239000000243 solution Substances 0.000 description 21
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 18
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 16
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 16
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 11
- 239000002002 slurry Substances 0.000 description 11
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 10
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 10
- 150000001336 alkenes Chemical class 0.000 description 10
- IAQRGUVFOMOMEM-ONEGZZNKSA-N trans-but-2-ene Chemical compound C\C=C\C IAQRGUVFOMOMEM-ONEGZZNKSA-N 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 8
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 8
- 238000002474 experimental method Methods 0.000 description 7
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 7
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 6
- 229910021529 ammonia Inorganic materials 0.000 description 6
- QGAVSDVURUSLQK-UHFFFAOYSA-N ammonium heptamolybdate Chemical compound N.N.N.N.N.N.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.[Mo].[Mo].[Mo].[Mo].[Mo].[Mo].[Mo] QGAVSDVURUSLQK-UHFFFAOYSA-N 0.000 description 6
- VCJMYUPGQJHHFU-UHFFFAOYSA-N iron(3+);trinitrate Chemical compound [Fe+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O VCJMYUPGQJHHFU-UHFFFAOYSA-N 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Inorganic materials [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 6
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 5
- 229910001981 cobalt nitrate Inorganic materials 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- RXPAJWPEYBDXOG-UHFFFAOYSA-N hydron;methyl 4-methoxypyridine-2-carboxylate;chloride Chemical compound Cl.COC(=O)C1=CC(OC)=CC=N1 RXPAJWPEYBDXOG-UHFFFAOYSA-N 0.000 description 4
- 229910052750 molybdenum Inorganic materials 0.000 description 4
- 239000011733 molybdenum Substances 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 239000011591 potassium Substances 0.000 description 4
- 229910052700 potassium Inorganic materials 0.000 description 4
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 4
- 229910001220 stainless steel Inorganic materials 0.000 description 4
- 239000010935 stainless steel Substances 0.000 description 4
- BKOOMYPCSUNDGP-UHFFFAOYSA-N 2-methylbut-2-ene Chemical group CC=C(C)C BKOOMYPCSUNDGP-UHFFFAOYSA-N 0.000 description 3
- STNJBCKSHOAVAJ-UHFFFAOYSA-N Methacrolein Chemical compound CC(=C)C=O STNJBCKSHOAVAJ-UHFFFAOYSA-N 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 3
- 229910002651 NO3 Inorganic materials 0.000 description 3
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 3
- NLSCHDZTHVNDCP-UHFFFAOYSA-N caesium nitrate Chemical compound [Cs+].[O-][N+]([O-])=O NLSCHDZTHVNDCP-UHFFFAOYSA-N 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 229910001960 metal nitrate Inorganic materials 0.000 description 3
- 238000005839 oxidative dehydrogenation reaction Methods 0.000 description 3
- 239000000376 reactant Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- MHNNAWXXUZQSNM-UHFFFAOYSA-N 2-methylbut-1-ene Chemical compound CCC(C)=C MHNNAWXXUZQSNM-UHFFFAOYSA-N 0.000 description 2
- 239000012190 activator Substances 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 description 2
- 235000010333 potassium nitrate Nutrition 0.000 description 2
- 239000004323 potassium nitrate Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 229910000667 (NH4)2Ce(NO3)6 Inorganic materials 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 229910006113 GeCl4 Inorganic materials 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 229910006213 ZrOCl2 Inorganic materials 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 229910052792 caesium Inorganic materials 0.000 description 1
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 238000006317 isomerization reaction Methods 0.000 description 1
- MIVBAHRSNUNMPP-UHFFFAOYSA-N manganese(2+);dinitrate Chemical compound [Mn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MIVBAHRSNUNMPP-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 150000003112 potassium compounds Chemical class 0.000 description 1
- SWLJJEFSPJCUBD-UHFFFAOYSA-N tellurium tetrachloride Chemical compound Cl[Te](Cl)(Cl)Cl SWLJJEFSPJCUBD-UHFFFAOYSA-N 0.000 description 1
- IEXRMSFAVATTJX-UHFFFAOYSA-N tetrachlorogermane Chemical compound Cl[Ge](Cl)(Cl)Cl IEXRMSFAVATTJX-UHFFFAOYSA-N 0.000 description 1
- IPCAPQRVQMIMAN-UHFFFAOYSA-L zirconyl chloride Chemical compound Cl[Zr](Cl)=O IPCAPQRVQMIMAN-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8876—Arsenic, antimony or bismuth
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
- B01J27/057—Selenium or tellurium; Compounds thereof
- B01J27/0576—Tellurium; Compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
- B01J27/19—Molybdenum
- B01J27/192—Molybdenum with bismuth
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
- C07C253/26—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons containing carbon-to-carbon multiple bonds, e.g. unsaturated aldehydes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
- C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
- C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
- C07C5/48—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with oxygen as an acceptor
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
- C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US49053274A | 1974-07-22 | 1974-07-22 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH616861A5 true CH616861A5 (en) | 1980-04-30 |
Family
ID=23948462
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH952175A CH616861A5 (en) | 1974-07-22 | 1975-07-21 | Oxidation catalyst. |
Country Status (19)
| Country | Link |
|---|---|
| JP (2) | JPS6036812B2 (no) |
| AT (1) | AT354408B (no) |
| BE (1) | BE831530A (no) |
| BR (1) | BR7504680A (no) |
| CA (1) | CA1075672A (no) |
| CH (1) | CH616861A5 (no) |
| CS (1) | CS195708B2 (no) |
| DD (1) | DD122065A5 (no) |
| DE (1) | DE2530959C2 (no) |
| EG (1) | EG12556A (no) |
| ES (1) | ES439592A1 (no) |
| FR (1) | FR2279465A1 (no) |
| GB (1) | GB1523772A (no) |
| IN (1) | IN144016B (no) |
| IT (1) | IT1039883B (no) |
| NL (1) | NL188016B (no) |
| NO (1) | NO145184C (no) |
| RO (1) | RO70128A (no) |
| YU (1) | YU37273B (no) |
Families Citing this family (59)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL175175C (nl) * | 1970-10-30 | 1984-10-01 | Standard Oil Co Ohio | Werkwijze voor de omzetting van propeen en/of isobuteen met een moleculaire zuurstof bevattend gas en ammoniak in aanwezigheid van een katalysator. |
| GB1523772A (en) * | 1974-07-22 | 1978-09-06 | Standard Oil Co | Oxidation catalysts |
| JPS527904A (en) * | 1975-07-04 | 1977-01-21 | Mitsubishi Rayon Co Ltd | Process for preparation of methacrolein, methacrylic acid or 1,3-butad iene |
| JPS51113807A (en) * | 1975-03-31 | 1976-10-07 | Mitsubishi Rayon Co Ltd | Process for preparation of methacrolein and methacrylic acid and or 1, 3-butadiene |
| US4118419A (en) * | 1975-12-03 | 1978-10-03 | Mitsubishi Rayon Company, Ltd. | Catalytic process for the preparation of an unsaturated carboxylic acid |
| JPS5353613A (en) * | 1976-10-26 | 1978-05-16 | Nippon Zeon Co Ltd | Preparation of methacrylic acid |
| IL55073A (en) * | 1977-07-28 | 1982-01-31 | Standard Oil Co | Catalysts for the oxidation and ammoxidation of olefins |
| CA1133505A (en) * | 1977-07-28 | 1982-10-12 | Andrew T. Guttmann | Process for the oxidation of olefins |
| CA1127137A (en) * | 1977-12-20 | 1982-07-06 | Dev D. Suresh | Ammoxidation of olefins with novel antimonate catalysts |
| JPS5416409A (en) * | 1978-06-26 | 1979-02-07 | Mitsubishi Rayon Co Ltd | Preparation of 1,3-futadiene |
| JPS5416410A (en) * | 1978-06-26 | 1979-02-07 | Mitsubishi Rayon Co Ltd | Preparation of methacrolein, methacrylic acid and 1,3-butadiene |
| JPS5517306A (en) * | 1978-07-20 | 1980-02-06 | Standard Oil Co | Olefin oxidation using catalyst containing various promoter elements |
| JPS5538330A (en) * | 1978-09-13 | 1980-03-17 | Ube Ind Ltd | Preparation of acrylonitrile |
| DE2841712A1 (de) * | 1978-09-25 | 1980-04-10 | Basf Ag | Verfahren zur herstellung von p- substituierten benzaldehyden |
| JPS6122040A (ja) * | 1984-07-10 | 1986-01-30 | Mitsubishi Rayon Co Ltd | メタクロレイン及びメタクリル酸の製造法 |
| JPS6338417A (ja) * | 1986-08-01 | 1988-02-19 | 松下電器産業株式会社 | 炊飯器 |
| JPH04136537A (ja) * | 1990-09-26 | 1992-05-11 | Kobe Steel Ltd | 構造物の振動抑制装置 |
| JPH04140530A (ja) * | 1990-09-28 | 1992-05-14 | Kobe Steel Ltd | 構造物の振動抑制装置 |
| JPH04133043U (ja) * | 1991-06-03 | 1992-12-10 | 富士ポリマテツク株式会社 | バネ定数可変式動制振器 |
| DE4200248A1 (de) * | 1992-01-08 | 1993-07-15 | Basf Ag | Verfahren zur regenerierung von metalloxid-katalysatoren |
| JPH05302643A (ja) * | 1992-04-15 | 1993-11-16 | Kobe Steel Ltd | 住宅用床パネル |
| ES2140684T3 (es) * | 1994-06-22 | 2000-03-01 | Asahi Chemical Ind | Metodo para la fabricacion de metacroleina. |
| US6136998A (en) * | 1996-10-15 | 2000-10-24 | Mitsubishi Rayon Co., Ltd. | Retention of activity of molybdenum-containing metallic oxide catalyst |
| FR2756499B1 (fr) * | 1996-12-03 | 1999-01-22 | Atochem Elf Sa | Systeme catalytique notamment pour l'oxydation menagee et selective des alcanes en alcenes et aldehydes insatures |
| DE19957416A1 (de) * | 1999-11-29 | 2001-06-13 | Aventis Res & Tech Gmbh & Co | Verfahren zur katalytischen Herstellung von Halogenbenzaldehyden und Katalysatoren zur Durchführung des Verfahrens |
| DE10137534A1 (de) | 2001-08-01 | 2003-02-13 | Basf Ag | Verfahren zur Herstellung von Maleinsäureanhydrid |
| JP4030740B2 (ja) | 2001-10-11 | 2008-01-09 | ダイヤニトリックス株式会社 | アンモ酸化用触媒の製造方法 |
| JP4503444B2 (ja) * | 2004-02-05 | 2010-07-14 | ダイヤニトリックス株式会社 | アクリロニトリル製造用触媒、及びアクリロニトリルの製造方法 |
| DE102007003076A1 (de) * | 2007-01-16 | 2008-07-17 | Basf Se | Verfahren zur Herstellung einer das Element Eisen in oxidischer Form enthaltenden Multielementoxidmasse |
| JP2008267759A (ja) * | 2007-04-25 | 2008-11-06 | Dainichi Co Ltd | 加湿装置 |
| EP2152412A2 (en) * | 2007-05-03 | 2010-02-17 | Shell Internationale Research Maatschappij B.V. | A catalyst, its preparation and use |
| CN101679144A (zh) * | 2007-05-03 | 2010-03-24 | 国际壳牌研究有限公司 | 包含铟的脱氢催化剂及其制备和用途 |
| US9399606B2 (en) | 2012-12-06 | 2016-07-26 | Basf Se | Catalyst and process for the oxidative dehydrogenation of N-butenes to butadiene |
| KR20150094620A (ko) | 2012-12-06 | 2015-08-19 | 바스프 에스이 | n-부텐의 부타디엔으로의 산화성 탈수소화 방법 |
| JP2016503073A (ja) | 2013-01-15 | 2016-02-01 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | 酸化的脱水素化によるｎ−ブテン類からの１，３−ブタジエンの製造方法 |
| US10144681B2 (en) | 2013-01-15 | 2018-12-04 | Basf Se | Process for the oxidative dehydrogenation of N-butenes to butadiene |
| KR20150105455A (ko) | 2013-01-16 | 2015-09-16 | 바스프 에스이 | 생성물을 처리하는 동안에 과산화물 함량을 모니터링하는, n-부텐의 산화성 탈수소화에 의한 부타디엔의 제조 방법 |
| EA201690165A1 (ru) | 2013-07-10 | 2016-06-30 | Басф Се | Способ окислительного дегидрирования н-бутенов в бутадиен |
| JP6478996B2 (ja) | 2013-10-30 | 2019-03-06 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | 酸化的脱水素反応によりｎ−ブテンから１，３−ブタジエンを製造するための方法 |
| JP2017502988A (ja) | 2014-01-13 | 2017-01-26 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | ｎ−ブテンを酸化的脱水素するための反応器の起動法 |
| DE102014203725A1 (de) | 2014-02-28 | 2015-09-03 | Basf Se | Oxidationskatalysator mit sattelförmigem Trägerformkörper |
| WO2016023892A1 (de) | 2014-08-12 | 2016-02-18 | Basf Se | Verfahren zur herstellung von 1,3-butadien aus n-butenen durch oxidative dehydrierung |
| EA201790690A1 (ru) | 2014-09-26 | 2017-09-29 | Басф Се | Способ получения 1,3-бутадиена из n-бутенов путем окислительного дегидрирования |
| US10358399B2 (en) | 2014-11-03 | 2019-07-23 | Basf Se | Process for preparing 1,3-butadiene from n-butenes by oxidative dehydrogenation |
| EP3218334B1 (de) | 2014-11-14 | 2018-09-26 | Basf Se | Verfahren zur herstellung von 1,3-butadien durch dehydrierung von n-butenen unter bereitstellung eines butane und 2-butene enthaltenden stoffstromes |
| KR20170134522A (ko) | 2015-03-26 | 2017-12-06 | 바스프 에스이 | 산화성 탈수소화에 의한 n-부텐으로부터의 1,3-부타디엔의 제조 |
| WO2016151074A1 (de) | 2015-03-26 | 2016-09-29 | Basf Se | Verfahren zur herstellung von 1,3-butadien aus n-butenen durch oxidative dehydrierung |
| WO2016150940A1 (de) | 2015-03-26 | 2016-09-29 | Basf Se | Verfahren zur herstellung von 1,3-butadien aus n-butenen durch oxidative dehydrierung |
| CN107667084A (zh) | 2015-03-26 | 2018-02-06 | 巴斯夫欧洲公司 | 由正丁烯通过氧化脱氢生产1,3‑丁二烯 |
| WO2017093454A1 (de) | 2015-12-03 | 2017-06-08 | Basf Se | Verfahren zur herstellung von butadien durch oxidative dehydrierung von n-butenen |
| WO2017121739A1 (de) | 2016-01-13 | 2017-07-20 | Basf Se | Verfahren zur herstellung von 1,3-butadien aus n-butenen durch oxidative dehydrierung |
| WO2017133997A1 (de) | 2016-02-04 | 2017-08-10 | Basf Se | Verfahren zur herstellung von 1,3-butadien aus n-butenen durch oxidative dehydrierung |
| US20190337870A1 (en) | 2016-08-09 | 2019-11-07 | Basf Se | Method of starting up a reactor for the oxidative dehydrogenation of n-butenes |
| WO2018095840A1 (de) | 2016-11-22 | 2018-05-31 | Basf Se | Verfahren zur herstellung von 1,3-butadien aus n-butenen durch oxidative dehydrierung umfassend eine furan-abtrennung bei der aufarbeitung |
| EP3323797A1 (de) | 2016-11-22 | 2018-05-23 | Basf Se | Verfahren zur herstellung von 1,3-butadien aus n-butenen durch oxidative dehydrierung umfassend eine saure wäsche des c4-produktgasstroms |
| WO2018095776A1 (de) | 2016-11-22 | 2018-05-31 | Basf Se | Verfahren zur herstellung von 1,3-butadien aus n-butenen durch oxidative dehydrierung umfassend eine wässrige wäsche des c4-produktgasstroms |
| WO2018095856A1 (de) | 2016-11-22 | 2018-05-31 | Basf Se | Verfahren zur herstellung von 1,3-butadien aus n-butenen durch oxidative dehydrierung umfassend eine methacrolein-abtrennung bei der aufarbeitung |
| WO2018219996A1 (de) | 2017-06-02 | 2018-12-06 | Basf Se | Verfahren zur herstellung von 1,3-butadien aus n-butenen durch oxidative dehydrierung in kreisgasfahrweise mit co2-angereichertem kreisgas |
| WO2018234158A1 (de) | 2017-06-19 | 2018-12-27 | Basf Se | Verfahren zur herstellung von 1,3-butadien aus n-butenen durch oxidative dehydrierung umfassend eine wäsche des c4-produktgasstroms |
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| JPS481645Y1 (no) | 1968-07-25 | 1973-01-17 | ||
| US3761424A (en) * | 1968-08-31 | 1973-09-25 | Degussa | Catalysts for the oxidation of alkenes |
| US3642930A (en) * | 1968-12-30 | 1972-02-15 | Standard Oil Co Ohio | Process for the manufacture of isoprene from isoamylenes and methyl butanols and catalyst therefor |
| DE2000425A1 (de) * | 1969-01-11 | 1970-07-16 | Toa Gosei Chem Ind | Verfahren zur Oxydation von Olefinen |
| DE2125032C3 (de) * | 1970-05-26 | 1979-11-22 | Nippon Catalytic Chem Ind | Verfahren zur Herstellung von (Meth) Acrolein neben geringen Mengen (Meth) Acrylsäure |
| NL158483B (nl) * | 1970-05-29 | 1978-11-15 | Sumitomo Chemical Co | Werkwijze voor het bereiden van acrylonitrile uit propeen. |
| US3928462A (en) * | 1970-07-08 | 1975-12-23 | Sumitomo Chemical Co | Catalytic process for the preparation of methacrolein |
| NL175175C (nl) * | 1970-10-30 | 1984-10-01 | Standard Oil Co Ohio | Werkwijze voor de omzetting van propeen en/of isobuteen met een moleculaire zuurstof bevattend gas en ammoniak in aanwezigheid van een katalysator. |
| US3801670A (en) * | 1970-12-25 | 1974-04-02 | Sumitomo Chemical Co | Catalytic process for the production of diolefins |
| DE2161471C3 (de) * | 1970-12-26 | 1982-05-13 | Nippon Shokubai Kagaku Kogyo Co. Ltd., Osaka | Verfahren zur Herstellung von Acrolein und Acrylsäure |
| GB1373304A (en) * | 1970-12-29 | 1974-11-06 | Mitsubishi Petrochemical Co | Process for production of acrolein |
| JPS5112603B1 (no) * | 1971-05-26 | 1976-04-21 | ||
| US3839227A (en) * | 1971-06-02 | 1974-10-01 | Rohm & Haas | Novel catalyst for methacrolein production |
| JPS5111603B1 (no) * | 1971-06-14 | 1976-04-13 | ||
| US3786000A (en) * | 1972-01-06 | 1974-01-15 | Rohm & Haas | Catalyst for the production of acrolein and acrylic acid |
| JPS5310573B2 (no) * | 1972-02-15 | 1978-04-14 | ||
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| DE2249922C2 (de) * | 1972-10-12 | 1982-05-27 | Basf Ag, 6700 Ludwigshafen | Verfahren zur katalytischen Oxidation von Propylen oder Isobutylen zu Acrolein oder Methacrolein in der Gasphase mit molekularem Sauerstoff |
| FR2208399A5 (no) * | 1972-11-27 | 1974-06-21 | Ugine Kuhlmann | |
| CA1049553A (en) * | 1973-04-30 | 1979-02-27 | The Standard Oil Company | Preparation of acrylic acid and methacrylic acid from propylene or isobutylene in a one-reactor, fluid-bed system |
| NL171440C (nl) * | 1973-05-10 | 1983-04-05 | Japan Synthetic Rubber Co Ltd | Werkwijze voor het bereiden van methacroleien door katalytische oxydatie van isobuteen. |
| DE2424934A1 (de) * | 1973-06-04 | 1975-01-02 | Standard Oil Co Ohio | Verfahren zur katalytischen herstellung ungesaettigter nitrile |
| US3972920A (en) * | 1973-06-11 | 1976-08-03 | Mitsubishi Rayon Co., Ltd. | Process for producing unsaturated aldehydes, unsaturated fatty acids or conjugated dienes |
| DE2428218A1 (de) * | 1973-06-15 | 1975-01-09 | Forni Ed Impianti Ind Ingg De | Verfahren zur behandlung von abfaellen, insbesondere von muell |
| US3883573A (en) * | 1973-06-15 | 1975-05-13 | Standard Oil Co | Commercial fixed-bed acrylonitrile or methacrylonitrile |
| GB1467865A (en) * | 1973-07-27 | 1977-03-23 | Basf Ag | Catalytic oxidation or ammoxidation of a-olefins to alpha,beta- olefinically unsaturated aldehydes acids or nitriles |
| GB1483097A (en) * | 1973-08-29 | 1977-08-17 | Mitsubishi Rayon Co | Method for vapour-phase catalytic oxidation of tert-butyl alcohol |
| US3932551A (en) * | 1973-10-12 | 1976-01-13 | The Standard Oil Company | Process for the preparation of diolefins from olefins |
| JPS5245692B2 (no) * | 1973-10-16 | 1977-11-17 | ||
| DE2516966A1 (de) * | 1974-04-19 | 1975-10-30 | Mitsubishi Chem Ind | Katalysator und verfahren zur herstellung von maleinsaeureanhydrid |
| JPS5432766B2 (no) * | 1974-06-04 | 1979-10-16 | ||
| US4001317A (en) * | 1974-07-22 | 1977-01-04 | Standard Oil Company | Process for the oxidation of olefins using catalysts containing various promoter elements |
| GB1523772A (en) * | 1974-07-22 | 1978-09-06 | Standard Oil Co | Oxidation catalysts |
| GB1489559A (en) * | 1975-03-03 | 1977-10-19 | Mitsubishi Rayon Co | Catalytic process for the preparation of acrylic acid or methacrylic acid |
| US4075232A (en) * | 1975-03-06 | 1978-02-21 | The Standard Oil Company | Preparation of maleic anhydride from n-butene in a one-reactor, fluid-bed system using two different catalysts |
| GB1490683A (en) * | 1975-03-12 | 1977-11-02 | Mitsubishi Rayon Co | Process and a catalyst for producing unsaturated aldehydes unsaturated carboxylic acids or conjugated diene |
| GB1513335A (en) * | 1975-03-17 | 1978-06-07 | Mitsubishi Rayon Co | Process and a catalyst for the preparation of unsaturated carboxylic acid |
| IN142430B (no) * | 1975-04-21 | 1977-07-09 | Standard Oil Co | |
| DE3315745C2 (de) * | 1983-04-30 | 1986-11-27 | Schott Glaswerke, 6500 Mainz | Kochfeld mit gasbeheizten Brennern und einer durchgehenden Kochfläche aus Glaskeramik oder vergleichbarem Material |
-
1975
- 1975-07-08 GB GB28688/75A patent/GB1523772A/en not_active Expired
- 1975-07-11 IN IN1358/CAL/75A patent/IN144016B/en unknown
- 1975-07-11 DE DE2530959A patent/DE2530959C2/de not_active Expired
- 1975-07-15 AT AT544975A patent/AT354408B/de not_active IP Right Cessation
- 1975-07-15 DD DD187311A patent/DD122065A5/xx unknown
- 1975-07-16 CA CA231,620A patent/CA1075672A/en not_active Expired
- 1975-07-17 IT IT25502/75A patent/IT1039883B/it active
- 1975-07-18 BE BE158437A patent/BE831530A/xx not_active IP Right Cessation
- 1975-07-18 NL NLAANVRAGE7508637,A patent/NL188016B/xx active IP Right Review Request
- 1975-07-18 NO NO752572A patent/NO145184C/no unknown
- 1975-07-21 RO RO7582908A patent/RO70128A/ro unknown
- 1975-07-21 EG EG432/75A patent/EG12556A/xx active
- 1975-07-21 CH CH952175A patent/CH616861A5/de not_active IP Right Cessation
- 1975-07-21 ES ES439592A patent/ES439592A1/es not_active Expired
- 1975-07-21 FR FR7522659A patent/FR2279465A1/fr active Granted
- 1975-07-22 BR BR7504680*A patent/BR7504680A/pt unknown
- 1975-07-22 YU YU1863/75A patent/YU37273B/xx unknown
- 1975-07-22 JP JP50089599A patent/JPS6036812B2/ja not_active Expired
- 1975-07-22 CS CS755174A patent/CS195708B2/cs unknown
-
1985
- 1985-04-25 JP JP60089889A patent/JPS6118435A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| DE2530959A1 (de) | 1976-02-05 |
| GB1523772A (en) | 1978-09-06 |
| DE2530959C2 (de) | 1986-03-20 |
| FR2279465B1 (no) | 1981-08-28 |
| JPS6242654B2 (no) | 1987-09-09 |
| NO145184B (no) | 1981-10-26 |
| NL7508637A (nl) | 1976-01-26 |
| JPS6036812B2 (ja) | 1985-08-22 |
| EG12556A (en) | 1979-09-30 |
| ES439592A1 (es) | 1977-06-01 |
| BE831530A (fr) | 1975-11-17 |
| BR7504680A (pt) | 1976-07-06 |
| NO752572L (no) | 1976-01-23 |
| AT354408B (de) | 1979-01-10 |
| IN144016B (no) | 1978-03-11 |
| YU37273B (en) | 1984-08-31 |
| FR2279465A1 (fr) | 1976-02-20 |
| DD122065A5 (no) | 1976-09-12 |
| JPS5140391A (no) | 1976-04-05 |
| YU186375A (en) | 1983-04-27 |
| IT1039883B (it) | 1979-12-10 |
| CS195708B2 (en) | 1980-02-29 |
| CA1075672A (en) | 1980-04-15 |
| NO145184C (no) | 1982-02-03 |
| RO70128A (ro) | 1982-10-11 |
| NL188016B (nl) | 1991-10-16 |
| ATA544975A (de) | 1979-06-15 |
| JPS6118435A (ja) | 1986-01-27 |
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