ES2140684T3 - Metodo para la fabricacion de metacroleina. - Google Patents

Metodo para la fabricacion de metacroleina.

Info

Publication number
ES2140684T3
ES2140684T3 ES95922726T ES95922726T ES2140684T3 ES 2140684 T3 ES2140684 T3 ES 2140684T3 ES 95922726 T ES95922726 T ES 95922726T ES 95922726 T ES95922726 T ES 95922726T ES 2140684 T3 ES2140684 T3 ES 2140684T3
Authority
ES
Spain
Prior art keywords
sub
metacrolein
compositions
mixture
produce
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES95922726T
Other languages
English (en)
Inventor
Osamu Nagano
Toru Watanabe
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Asahi Kasei Corp
Asahi Chemical Industry Co Ltd
Original Assignee
Asahi Chemical Industry Co Ltd
Asahi Kasei Kogyo KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Asahi Chemical Industry Co Ltd, Asahi Kasei Kogyo KK filed Critical Asahi Chemical Industry Co Ltd
Application granted granted Critical
Publication of ES2140684T3 publication Critical patent/ES2140684T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/20—Unsaturated compounds having —CHO groups bound to acyclic carbon atoms
    • C07C47/21—Unsaturated compounds having —CHO groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C07C47/22—Acryaldehyde; Methacryaldehyde
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8876—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/51—Spheres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/651—50-500 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/653—500-1000 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0045—Drying a slurry, e.g. spray drying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/036—Precipitation; Co-precipitation to form a gel or a cogel
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

LO DESCRITO ES UN METODO PARA PRODUCIR METACROLEINA, EL CUAL CONSISTE EN SOMETER AL MENOS UN ELEMENTO SELECCIONADO DEL GRUPO QUE CONSTA DE ISOBUTILENO Y TERC-BUTANOL A OXIDACION CATALITICA EN FASE GASEOSA CON UN GAS QUE CONTIENE OXIGENO MOLECULAR EN PRESENCIA DE UNA COMPOSICION CATALIZADORA DE OXIDO REPRESENTADA POR LA FORMULA MO{SUB,12}BI{SUB,A}CE{SUB,B}K{SUB,C}FE{SUB,D}A{SUB,E}B{SUB,F}O{SUB,G}, EN DONDE A ES UNICAMENTE CO, O UNA MEZCLA DE CO Y MG EN DONDE LA PROPORCION ATOMICA DE MG PARA CO NO ES MAS DE 0,7, B ES RB, CS O UNA MEZCLA DE LOS MISMOS, Y A, B, C, D, E, F Y G SON, RESPECTIVAMENTE, LAS PROPORCIONES ATOMICAS ESPECIFICAS DE BI, CE, K, FE, A, B Y O, RELATIVAS A DOCE ATOMOS DE MO. MEDIANTE EL METODO DE LA PRESENTE INVENCION, ES POSIBLE PRODUCIR DE FORMA ESTABLE METACROLEINA EN ALTO RENDIMIENTO, UTILIZANDO UNA COMPOSICION CATALIZADORA DE OXIDO QUE TIENE UNA COMPOSICION ESTRUCTURAL RELATIVAMENTE SENCILLA Y POR ELLO PUEDE PREPARARSE FACILMENTE, Y LA CUAL TIENE NO SOLO UNA VIDA DE CATALIZADOR PROLONGADA DEBIDA A LA EXCELENTE ESTABILIDAD TERMICA Y RESISTENCIA A LA REDUCCION, SINO TAMBIEN EXCELENTE SELECTIVIDAD PARA METACROLEINA, EN DONDE LA COMPOSICION CATALIZADORA CONTIENE BI, CE, K Y FE EN CANTIDADES ESPECIFICAS Y EN UNA PROPORCION DE CANTIDAD RELATIVA ESPECIFICA, Y NO CONTIENE DICHOS ELEMENTOS QUE CAUSAN CONTAMINACION AMBIENTAL Y PROBLEMAS DE TOXICIDAD, Y ADEMAS NO REQUIERE EL USO, COMO MATERIAS PRIMAS PARA LA PREPARACION DEL MISMO, COMPOSICIONES QUE TIENEN BAJA SOLUBILIDAD EN AGUA, COMO COMPOSICIONES DE W, SB Y NB, LAS CUALES SE HAN UTILIZADO FRECUENTEMENTE CON EL FIN DE LOGRAR RENDIMIENTOS CATALITICOS DESEADOS, AUNQUE LA UTILIZACION DE LAS CUALES TIENE DESVENTAJAS DEBIDO A LAS DIFICULTADES EN LA OBTENCION DE COMPOSICIONES CATALIZADORAS UNIFORMES.
ES95922726T 1994-06-22 1995-06-21 Metodo para la fabricacion de metacroleina. Expired - Lifetime ES2140684T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP14015194 1994-06-22

Publications (1)

Publication Number Publication Date
ES2140684T3 true ES2140684T3 (es) 2000-03-01

Family

ID=15262061

Family Applications (1)

Application Number Title Priority Date Filing Date
ES95922726T Expired - Lifetime ES2140684T3 (es) 1994-06-22 1995-06-21 Metodo para la fabricacion de metacroleina.

Country Status (9)

Country Link
US (1) US5728894A (es)
EP (1) EP0767161B1 (es)
KR (1) KR100186659B1 (es)
CN (1) CN1046499C (es)
DE (1) DE69513172T2 (es)
ES (1) ES2140684T3 (es)
MY (1) MY117568A (es)
TW (1) TW299316B (es)
WO (1) WO1995035273A1 (es)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI257925B (en) * 2001-12-21 2006-07-11 Asahi Kasei Corp Oxide catalyst composition
KR100513664B1 (ko) * 2002-05-16 2005-09-07 주식회사 엘지화학 프로필렌의 부분 산화 반응용 촉매의 제조 방법
KR100497175B1 (ko) * 2003-03-26 2005-06-23 주식회사 엘지화학 프로필렌 및 이소부틸렌 부분산화 반응용 촉매의 제조방법
US20040192973A1 (en) * 2003-03-31 2004-09-30 Saudi Basic Industries Corporation Mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins
US7361791B2 (en) * 2003-03-31 2008-04-22 Saudi Basic Industries Corporation Mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins
US7232788B2 (en) * 2003-03-31 2007-06-19 Saudi Basic Industries Corporation Mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins
US7229945B2 (en) * 2003-12-19 2007-06-12 Saudi Basic Industrics Corporation Process of making mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins
US7732367B2 (en) 2005-07-25 2010-06-08 Saudi Basic Industries Corporation Catalyst for methacrolein oxidation and method for making and using same
US7851397B2 (en) * 2005-07-25 2010-12-14 Saudi Basic Industries Corporation Catalyst for methacrolein oxidation and method for making and using same
US7649112B2 (en) 2005-07-25 2010-01-19 Saudi Basic Industries Corporation Integrated plant for producing 2-ethyl-hexanol and methacrylic acid and a method based thereon
US7649111B2 (en) * 2005-07-25 2010-01-19 Saudi Basic Industries Corporation Catalyst for the oxidation of a mixed aldehyde feedstock to methacrylic acid and methods for making and using same
US7799946B2 (en) * 2007-02-14 2010-09-21 Saudi Basic Industries Corporation Process for separating methacrolein from methacrylic acid in a gas phase product from the partial oxidation of isobutene
CN101385978B (zh) * 2007-09-12 2011-04-20 上海华谊丙烯酸有限公司 一种合成甲基丙烯醛的催化剂及其制备方法
US9346036B2 (en) 2011-06-28 2016-05-24 Asahi Kasei Chemicals Corporation Oxide catalyst
US8921257B2 (en) 2011-12-02 2014-12-30 Saudi Basic Industries Corporation Dual function partial oxidation catalyst for propane to acrylic acid conversion
US8722940B2 (en) 2012-03-01 2014-05-13 Saudi Basic Industries Corporation High molybdenum mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins
WO2014051090A1 (ja) 2012-09-28 2014-04-03 旭化成ケミカルズ株式会社 酸化物触媒及びその製造方法、並びに、不飽和アルデヒド、ジオレフィン及び不飽和ニトリルの製造方法
CN103721722B (zh) * 2012-10-10 2017-03-08 上海华谊丙烯酸有限公司 复合氧化物催化剂及其制备方法
CN110420643A (zh) * 2019-08-16 2019-11-08 中国科学院过程工程研究所 一种蛋壳型复合金属催化剂的制备方法及其应用
CN113164928B (zh) 2019-09-30 2024-09-17 株式会社Lg化学 用于丙烯的氨氧化催化剂、该催化剂的制造方法、使用所述催化剂的氨氧化方法
KR102519507B1 (ko) 2019-09-30 2023-04-07 주식회사 엘지화학 프로필렌의 암모산화용 촉매, 이의 제조 방법, 및 이를 이용한 프로필렌의 암모산화 방법
CN113164929B (zh) * 2019-09-30 2024-07-12 株式会社Lg化学 用于丙烯的氨氧化催化剂、该催化剂的制备方法、使用该催化剂的氨氧化方法

Family Cites Families (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3699099A (en) * 1969-08-07 1972-10-17 Colgate Palmolive Co 11-aminoalkylidenemorphanthridines
US4025565A (en) * 1972-02-22 1977-05-24 Asahi Glass Co., Ltd. Process for preparing unsaturated aldehyde having three to four carbon atoms
DE2308782C2 (de) * 1972-02-22 1982-11-11 Asahi Glass Co. Ltd., Tokyo Verfahren zur Herstellung von Acrolein oder Methacrolein
GB1523772A (en) * 1974-07-22 1978-09-06 Standard Oil Co Oxidation catalysts
US4162234A (en) * 1974-07-22 1979-07-24 The Standard Oil Company Oxidation catalysts
US4778930A (en) * 1974-08-05 1988-10-18 The Standard Oil Company Process for the oxidation of olefins using catalysts contaning antimony
JPS52111506A (en) * 1976-03-15 1977-09-19 Nippon Zeon Co Ltd Simultaneous preparation of 1,3-butadiene and methacrolein
JPS52111505A (en) * 1976-03-15 1977-09-19 Nippon Zeon Co Ltd Simultaneous preparation of 1,3-butadiene and methacrolein
JPS5945415B2 (ja) * 1976-12-13 1984-11-06 日本ゼオン株式会社 オレフイン酸化用触媒
JPS5319188A (en) * 1976-08-06 1978-02-22 Nippon Zeon Co Ltd Olefin oxidation catalyst
JPS5544730A (en) * 1978-09-27 1980-03-29 Toshiba Corp Electric machine transducer
JPS5867349A (ja) * 1981-10-20 1983-04-21 Asahi Chem Ind Co Ltd 触媒組成物
JPS5946132A (ja) * 1982-09-06 1984-03-15 Nippon Shokubai Kagaku Kogyo Co Ltd メタクロレイン合成用触媒
JPS6028824A (ja) * 1983-07-27 1985-02-14 Nippon Shokubai Kagaku Kogyo Co Ltd メタクロレイン製造用触媒の調製方法
US4537874A (en) * 1982-10-22 1985-08-27 Nippon Shokubai Kagaku Kogyo Co Ltd Catalyst for production of unsaturated aldehydes
JPH0699335B2 (ja) * 1984-02-01 1994-12-07 三菱レイヨン株式会社 メタクロレイン及びメタクリル酸の製造法
JPH0662463B2 (ja) * 1984-02-03 1994-08-17 三菱レイヨン株式会社 メタクロレイン及びメタクリル酸の製造法
JPS6133234A (ja) * 1984-07-23 1986-02-17 Mitsubishi Petrochem Co Ltd 触媒の再生法
JPS6236740A (ja) * 1985-08-09 1987-02-17 Pioneer Electronic Corp 光学式ピツクアツプ装置
JPH0811187B2 (ja) * 1986-10-27 1996-02-07 三菱レイヨン株式会社 メタクロレイン及びメタクリル酸の製造用触媒の調製法
JPS63122641A (ja) * 1986-11-11 1988-05-26 Mitsubishi Rayon Co Ltd メタクロレイン及びメタクリル酸の製造法
JPS63122642A (ja) * 1986-11-11 1988-05-26 Mitsubishi Rayon Co Ltd メタクロレイン及びメタクリル酸の製造法
JP2742413B2 (ja) * 1987-06-18 1998-04-22 株式会社日本触媒 メタクロレイン合成用触媒および再現性に優れたその製造方法
DE3867249D1 (de) * 1987-02-17 1992-02-13 Nippon Catalytic Chem Ind Katalysator zur oxydation von olefin oder tertiaerem alkohol und verfahren zu seiner herstellung.
GB8813766D0 (en) * 1988-06-10 1988-07-13 Efamol Holdings Essential fatty acid compositions
JP2657693B2 (ja) * 1989-03-01 1997-09-24 三菱レイヨン株式会社 メタクロレイン及びメタクリル酸の製造用触媒の調製法
JPH0813332B2 (ja) * 1989-09-25 1996-02-14 三菱レイヨン株式会社 メタクロレイン及びメタクリル酸の製造用触媒の調製法
ES2130297T3 (es) * 1989-12-06 1999-07-01 Nippon Catalytic Chem Ind Procedimiento para producir metacroleina y acido metacrilico.
JP2934267B2 (ja) * 1989-12-06 1999-08-16 株式会社日本触媒 メタクロレインおよびメタクリル酸の製造方法
EP0460932B1 (en) * 1990-06-06 1995-05-17 MITSUI TOATSU CHEMICALS, Inc. Method for preparing acrolein or methacrolein
JP2841324B2 (ja) * 1990-06-06 1998-12-24 三井化学株式会社 メタクロレインの製造方法
JP2974826B2 (ja) * 1991-07-17 1999-11-10 三菱レイヨン株式会社 メタクロレイン及びメタクリル酸製造用触媒の調製法

Also Published As

Publication number Publication date
US5728894A (en) 1998-03-17
DE69513172D1 (de) 1999-12-09
TW299316B (es) 1997-03-01
DE69513172T2 (de) 2000-08-24
CN1046499C (zh) 1999-11-17
EP0767161A4 (en) 1997-09-17
EP0767161B1 (en) 1999-11-03
KR100186659B1 (ko) 1999-05-15
CN1143946A (zh) 1997-02-26
MY117568A (en) 2004-07-31
EP0767161A1 (en) 1997-04-09
WO1995035273A1 (en) 1995-12-28
KR970701686A (ko) 1997-04-12

Similar Documents

Publication Publication Date Title
ES2140684T3 (es) Metodo para la fabricacion de metacroleina.
EP1459803A4 (en) oxide catalyst
Keston et al. Paper chromatography applied to the isotopic derivative method of analysis
BR0002501A (pt) Catalisador de óxido complexo, e, processo para produzir (met)acroleìna e ácido (met) acrìlico
ES474046A1 (es) Procedimiento para preparar pinturas intumescentes dotadas de propiedades de resistencia a la llama.
BR0002417A (pt) Catalisador e processo para a produção de aldeìdo insaturado e de acìdo carboxìlico insaturado
ES2133372T3 (es) Composicion a base de un oxido mixto de cerio y de circonio, preparacion y utilizacion.
KR860000233A (ko) 에탄올 에틸렌으로 옥시탈수소화시키는 방법
ES444223A1 (es) Un procedimiento mejorado de oxidacion amoniacal de propile-no o de isobutileno en fase de vapor.
KR870008617A (ko) 복합산화물 촉매의 제조방법
SE7408388L (es)
ES2034247T3 (es) Una composicion desodorante y su uso.
JPS55124734A (en) Preparation of methacrylic acid
ES2093007T3 (es) Uso de un catalizador para la preparacion de aldehido.
BRPI0406100A (pt) álcoois terciários insaturados como ligantes para catalisadores dmc
ES2044095T3 (es) Procedimiento para producir cianuro de hidrogeno por amoxidacion catalitica de metanol en fase vapor.
KR830010000A (ko) 헤테로 다중산의 제조방법
AR030849A1 (es) Composiciones catalizadoras soportadas
JPS5495513A (en) Preparation of acrylonitrile
ES385061A1 (es) Procedimiento para la preparacion de acido acetico.
IE37007L (en) Antiallergic tricyclic compounds
ES414126A1 (es) Procedimiento para obtener metacrilonitrilo.
BR0212483A (pt) Processo para a produção de ácido acrìlico a partir de propeno através de oxidação em fase gasosa, e, uso de um ácido acrìlico
SE387545B (sv) Forfarande for att framstella dispersa pulverformiga till korniga fasta emnen med hydrofoba och oleofila egenskaper genom inblandning av ett oorganiskt trevert kromsalt och 0,005 till 0,4 vikt % av ett organiskt ...
AR022470A1 (es) Uso de pirazol-carboxamidas

Legal Events

Date Code Title Description
FG2A Definitive protection

Ref document number: 767161

Country of ref document: ES