KR830010000A - 헤테로 다중산의 제조방법 - Google Patents

헤테로 다중산의 제조방법 Download PDF

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Publication number
KR830010000A
KR830010000A KR1019820001795A KR820001795A KR830010000A KR 830010000 A KR830010000 A KR 830010000A KR 1019820001795 A KR1019820001795 A KR 1019820001795A KR 820001795 A KR820001795 A KR 820001795A KR 830010000 A KR830010000 A KR 830010000A
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KR
South Korea
Prior art keywords
heteropolyacid
phosphoric acid
molybdenum
molybdovanado
heteropolyacids
Prior art date
Application number
KR1019820001795A
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English (en)
Inventor
신끼찌 시미즈
히로시 이찌하시
고오이찌 나가이
Original Assignee
히지가다 다께시
스미도모 가가구 고오교오 가부시기 가이샤
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by 히지가다 다께시, 스미도모 가가구 고오교오 가부시기 가이샤 filed Critical 히지가다 다께시
Publication of KR830010000A publication Critical patent/KR830010000A/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B01J27/19—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
    • B01J27/198—Vanadium
    • B01J27/199—Vanadium with chromium, molybdenum, tungsten or polonium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00—Phosphorus; Compounds thereof
    • C01B25/16—Oxyacids of phosphorus; Salts thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

내용 없음

Description

헤테로 다중산의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 KBr정제법에 의하여 결정된 적외선 흡수 스펙트럼을 표시한 그림.
제2도는 시판되는 암모늄.12-몰리브도 인산염의 적외선 흡수 스택트럼을 표시하는 그림.

Claims (3)

  1. 일반식H3+X(PMO12-XVXO40).NH2O의 헤테로 다중산 또는 그 환원형 생성물로서 위의 일반식에서 x및 n은및의 등식을 민족시키고 인을 중심원자로서 몰리브덴 또는 몰리브덴과 바나듐을 배위원자로서 포함하는 수를 표시하며 이러한 헤테로 다중산 등은X-선분말회절에 있어서 적어도 격자간 거리 8.4,6.8,5.9,4.8,4.2 및 3.4에 회절선이 있는 등방결정 구조를 가진다.
  2. 청구의 범위 1항에 있어서 12-몰리브도 인산 또는 12-몰리브도바나도 인산의 암모늄염을 비활성가스 속에서 400℃이상의 온도로 하소하는 것이 특징은 청구의 범위 1에 의한 헤테로 다중산의 제조방법.
  3. 청구의 범위1항에 있어서 메타크롤레인을 기체상촉매산화시켜서 메타크릴산을 제조함에 있어서 청구의 범위 1에 의한 헤테로 다중산의 촉매로서의 이용.
    ※ 참고사항 : 최초출원내용에 의하여 공개하는 것임.
KR1019820001795A 1981-04-24 1982-04-23 헤테로 다중산의 제조방법 KR830010000A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP56062710A JPS57179007A (en) 1981-04-24 1981-04-24 Novel heteropolyacid, its manufacture and its using method
JP62710 1981-04-24

Publications (1)

Publication Number Publication Date
KR830010000A true KR830010000A (ko) 1983-12-24

Family

ID=13208143

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019820001795A KR830010000A (ko) 1981-04-24 1982-04-23 헤테로 다중산의 제조방법

Country Status (8)

Country Link
US (1) US4565801A (ko)
EP (1) EP0064371B1 (ko)
JP (1) JPS57179007A (ko)
KR (1) KR830010000A (ko)
CA (1) CA1197066A (ko)
DE (1) DE3261040D1 (ko)
ES (1) ES511663A0 (ko)
MX (1) MX160826A (ko)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3508649A1 (de) * 1985-03-12 1986-09-18 Röhm GmbH, 6100 Darmstadt Heteropolysaeure h(pfeil abwaerts)8(pfeil abwaerts)pmo(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)vo(pfeil abwaerts)3(pfeil abwaerts)(pfeil abwaerts)9(pfeil abwaerts), deren anhydrid pmo(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)vo(pfeil abwaerts)3(pfeil abwaerts)(pfeil abwaerts)5(pfeil abwaerts)und ihre verwendung
IN164212B (ko) * 1985-06-10 1989-02-04 Iel Ltd
CA1291983C (en) * 1986-09-29 1991-11-12 Keisuke Kinomura Glycosidation catalyst and process for preparing glycoside derivatives
US4916101A (en) * 1988-12-05 1990-04-10 Sun Refining And Marketing Company Method of preparing heteropolyacid catalysts
CA2077551A1 (en) * 1990-03-05 1991-09-06 John H. Grate Catalytic system for olefin oxidation to carbonyl products
US5792721A (en) * 1990-03-05 1998-08-11 Catalytica, Inc. Preparation of phosphomolybdovanadate polyoxoanions
US5107027A (en) * 1990-08-01 1992-04-21 Texaco Chemical Company Tert-butylamine synthesis over montmorillonite clays
GB9023257D0 (en) * 1990-10-25 1990-12-05 British Petroleum Co Plc Desulphurisation of oil
FR2680702B1 (fr) * 1991-09-03 1994-11-04 Atochem Nouveau systeme catalytique et son application a l'oxydeshydrogenation d'acides carboxyliques satures et l'oxydation d'aldehydes en acides.
US5919725A (en) * 1993-11-19 1999-07-06 Exxon Research And Engineering Co. Heteropoly salts or acid salts deposited in the interior of porous supports
WO1995013869A1 (en) * 1993-11-19 1995-05-26 Exxon Research & Engineering Company Heteropoly compounds and use in aromatic alkylation
JP3767309B2 (ja) 2000-03-07 2006-04-19 住友化学株式会社 ヘテロポリ酸系触媒の製造方法およびメタクリル酸の製造方法
KR100790215B1 (ko) 2006-08-29 2008-01-02 주식회사 효성 고순도 헤테로폴리산 촉매의 정제 방법
JP4895303B2 (ja) * 2007-08-24 2012-03-14 三菱レイヨン株式会社 メタクリル酸製造用触媒の製造方法、メタクリル酸製造用触媒およびメタクリル酸の製造方法
CN111682203B (zh) * 2020-06-17 2022-04-05 宁波大学 一种钒钼磷杂多酸钴钠的制备方法及其作为锂离子电池负极材料的用途

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2900235A (en) * 1955-08-19 1959-08-18 Du Pont Reduced phosphomolybdic acids wherein the average valence of the molybdenum is not more than 4
GB822140A (en) * 1957-03-18 1959-10-21 Standard Oil Co Process for the production of unsaturated carboxylic acids
NL225963A (ko) * 1957-03-18
FR1372476A (fr) * 1963-05-27 1964-09-18 Pechiney Saint Gobain Nouveau catalyseur d'oxydation d'hydrocarbures en anhydride maléique et son procédé de préparation
US3446575A (en) * 1966-12-28 1969-05-27 Sylvania Electric Prod Preparation of heteropolymolybdic acids
US3379652A (en) * 1967-04-28 1968-04-23 Eastman Kodak Co Arsenophosphomolybdic acid catalyst compositions and process for their preparation
FR1533971A (fr) * 1967-06-05 1968-07-26 Aquitaine Petrole Catalyseur perfectionné pour l'oxydation d'hydrocarbures insaturés en les acides monocarboxyliques insaturés correspondants
JPS5232444B2 (ko) * 1973-07-04 1977-08-22
DE2460541C3 (de) * 1973-12-29 1979-10-18 Nippon Shokubai Kagaku Kogyo Co. Ltd., Osaka (Japan) Phosphor, Molybdän und Vanadium sowie gegebenenfalls Kupfer, Kobalt, Zirkon, Wismut, Antimon und/oder Arsen enthaltender Oxydkatalysator und dessen Verwendung zur Herstellung von Methacrylsäure
US4192951A (en) * 1975-08-11 1980-03-11 Celanese Corporation Hydrocarbon oxidation process
JPS52138499A (en) * 1976-05-17 1977-11-18 Mitsubishi Chem Ind Ltd Production of heteropolyacid
JPS5390214A (en) * 1977-01-14 1978-08-08 Asahi Glass Co Ltd Preparation of methacrylic acid
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US4321160A (en) * 1979-12-27 1982-03-23 Standard Oil Company Method for the activation of phosphomolybdic acid based catalysts

Also Published As

Publication number Publication date
ES8307261A1 (es) 1983-07-01
DE3261040D1 (en) 1984-11-29
US4565801A (en) 1986-01-21
EP0064371A1 (en) 1982-11-10
JPS57179007A (en) 1982-11-04
MX160826A (es) 1990-05-30
CA1197066A (en) 1985-11-26
EP0064371B1 (en) 1984-10-24
ES511663A0 (es) 1983-07-01

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