BR9503975A - Catalisador de cianeto de duplo metal processos para preparação de tal catalisador e para polimerização de um epóxido bem como poliéster poliol - Google Patents

Catalisador de cianeto de duplo metal processos para preparação de tal catalisador e para polimerização de um epóxido bem como poliéster poliol

Info

Publication number
BR9503975A
BR9503975A BR9503975A BR9503975A BR9503975A BR 9503975 A BR9503975 A BR 9503975A BR 9503975 A BR9503975 A BR 9503975A BR 9503975 A BR9503975 A BR 9503975A BR 9503975 A BR9503975 A BR 9503975A
Authority
BR
Brazil
Prior art keywords
catalyst
preparing
metal cyanide
epoxide
double metal
Prior art date
Application number
BR9503975A
Other languages
English (en)
Inventor
Bi Le-Khac
Original Assignee
Arco Chem Tech
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Arco Chem Tech filed Critical Arco Chem Tech
Publication of BR9503975A publication Critical patent/BR9503975A/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/04—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
    • C08G65/06—Cyclic ethers having no atoms other than carbon and hydrogen outside the ring
    • C08G65/08—Saturated oxiranes
    • C08G65/10—Saturated oxiranes characterised by the catalysts used
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2213—At least two complexing oxygen atoms present in an at least bidentate or bridging ligand
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/24—Nitrogen compounds
    • B01J27/26—Cyanides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0202—Alcohols or phenols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • B01J31/068—Polyalkylene glycols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/165—Polymer immobilised coordination complexes, e.g. organometallic complexes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2645—Metals or compounds thereof, e.g. salts
    • C08G65/2663—Metal cyanide catalysts, i.e. DMC's
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/30—Post-polymerisation treatment, e.g. recovery, purification, drying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0202—Polynuclearity
    • B01J2531/0205—Bi- or polynuclear complexes, i.e. comprising two or more metal coordination centres, without metal-metal bonds, e.g. Cp(Lx)Zr-imidazole-Zr(Lx)Cp
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/90—Catalytic systems characterized by the solvent or solvent system used
    • B01J2531/96—Water

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Toxicology (AREA)
  • General Health & Medical Sciences (AREA)
  • Polyethers (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Epoxy Resins (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Polyesters Or Polycarbonates (AREA)
BR9503975A 1994-09-08 1995-09-08 Catalisador de cianeto de duplo metal processos para preparação de tal catalisador e para polimerização de um epóxido bem como poliéster poliol BR9503975A (pt)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/302,296 US5482908A (en) 1994-09-08 1994-09-08 Highly active double metal cyanide catalysts

Publications (1)

Publication Number Publication Date
BR9503975A true BR9503975A (pt) 1996-09-24

Family

ID=23167137

Family Applications (1)

Application Number Title Priority Date Filing Date
BR9503975A BR9503975A (pt) 1994-09-08 1995-09-08 Catalisador de cianeto de duplo metal processos para preparação de tal catalisador e para polimerização de um epóxido bem como poliéster poliol

Country Status (16)

Country Link
US (2) US5482908A (pt)
EP (1) EP0700949B1 (pt)
JP (1) JP3479175B2 (pt)
KR (1) KR100355336B1 (pt)
CN (1) CN1072687C (pt)
AT (1) ATE177123T1 (pt)
AU (1) AU688548B2 (pt)
BR (1) BR9503975A (pt)
CA (1) CA2157312C (pt)
DE (1) DE69508009T2 (pt)
DK (1) DK0700949T3 (pt)
ES (1) ES2127997T3 (pt)
HU (1) HU215551B (pt)
RO (1) RO111742B1 (pt)
TW (1) TW401429B (pt)
ZA (1) ZA957474B (pt)

Families Citing this family (478)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5712216A (en) * 1995-05-15 1998-01-27 Arco Chemical Technology, L.P. Highly active double metal cyanide complex catalysts
US5677413A (en) * 1995-06-15 1997-10-14 Arco Chemical Technology, L.P. Polyurethane elastomers exhibiting improved demold green strength and water absorption and haze-free polyols suitable for their preparation
US5670601A (en) * 1995-06-15 1997-09-23 Arco Chemical Technology, L.P. Polyurethane elastomers having improved green strength and demold time and polyoxyalkylene polyols suitable for their preparation
US5627122A (en) * 1995-07-24 1997-05-06 Arco Chemical Technology, L.P. Highly active double metal cyanide complex catalysts
US5811829A (en) 1995-08-10 1998-09-22 Arco Chemical Technology, L.P. Viscosity stable isocyanate-terminated prepolymers and polyoxyalkylene polyether polyols having improved storage stability
US5545601A (en) * 1995-08-22 1996-08-13 Arco Chemical Technology, L.P. Polyether-containing double metal cyanide catalysts
US5650452A (en) * 1995-10-18 1997-07-22 Arco Chemical Technology, L.P. Very low density molded polyurethane foams via isocyanate-terminated prepolymers
US5688861A (en) * 1995-11-30 1997-11-18 Arco Chemical Technology, L.P. Process for the preparation of polyol polymer dispersions
US5700847A (en) * 1995-12-04 1997-12-23 Arco Chemical Technology, L.P. Molded polyurethane foam with enhanced physical properties
US5767323A (en) * 1995-12-22 1998-06-16 Arco Chemical Technology, L.P. Process for preparing polyoxyalkylene polyether polyols having low levels of transition metals through double metal cyanide complex polyoxyalkylation
US5777177A (en) * 1996-02-07 1998-07-07 Arco Chemical Technology, L.P. Preparation of double metal cyanide-catalyzed polyols by continuous addition of starter
US5627120A (en) * 1996-04-19 1997-05-06 Arco Chemical Technology, L.P. Highly active double metal cyanide catalysts
FI111765B (fi) * 1996-06-26 2003-09-15 Fortum Nuclear Services Oy Menetelmä cesiumin erottamiseksi ydinjäteliuoksista sekä menetelmä heksasyanoferraattien valmistamiseksi
US5689012A (en) * 1996-07-18 1997-11-18 Arco Chemical Technology, L.P. Continuous preparation of low unsaturation polyoxyalkylene polyether polyols with continuous additon of starter
US5900384A (en) * 1996-07-18 1999-05-04 Arco Chemical Technology L.P. Double metal cyanide catalysts
US5693584A (en) * 1996-08-09 1997-12-02 Arco Chemical Technology, L.P. Highly active double metal cyanide catalysts
US5723563A (en) * 1996-10-11 1998-03-03 Arco Chemical Technology, L.P. Spandex elastomers
US5708118A (en) * 1996-10-11 1998-01-13 Arco Chemical Technology, L.P. Spandex elastomers
US5691441A (en) * 1996-10-11 1997-11-25 Arco Chemical Technology, L.P. Spandex elastomers
US5714428A (en) * 1996-10-16 1998-02-03 Arco Chemical Technology, L.P. Double metal cyanide catalysts containing functionalized polymers
US5786514A (en) * 1996-12-18 1998-07-28 Arco Chemical Technology, L.P. Process for alkoxylating carbonyl-functionalized phenols using double metal cyanide catalysts
US5958994A (en) * 1997-02-25 1999-09-28 Arco Chemical Technology, L.P. Method for decreasing the propensity for phase-out of the high molecular weight component of double metal cyanide-catalyzed high secondary hydroxyl polyoxypropylene polyols
DE19709031A1 (de) 1997-03-06 1998-09-10 Basf Ag Verfahren zur Herstellung von Doppelmetallcyanidkatalysatoren
US5783513A (en) * 1997-03-13 1998-07-21 Arco Chemical Technology, L.P. Process for making double metal cyanide catalysts
US6821308B2 (en) * 1997-04-02 2004-11-23 Bayer Antwerp N.V. Polyoxyalkylene monoethers with reduced water affinity
US5844070A (en) * 1997-05-16 1998-12-01 Arco Chemical Technology, L.P. Process for rapid activation of double metal cyanide catalysts
US5763642A (en) * 1997-06-19 1998-06-09 Arco Chemical Technology, L.P. Low monol polyoxy (higher) alkylene polyols with primary hydroxyl content
DE19730467A1 (de) * 1997-07-16 1999-01-21 Bayer Ag Neue Zink/Metall-Hexacyanocobaltat-Katalysatoren für die Herstellung von Polyetherpolyolen
US5891818A (en) * 1997-07-31 1999-04-06 Arco Chemical Technology, L.P. Cyanide complex catalyst manufacturing process
US5854386A (en) * 1997-08-25 1998-12-29 Arco Chemical Technology, L.P. Stabilizers for polymer polyols
DE19834573A1 (de) 1998-07-31 2000-02-03 Bayer Ag Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen
DE19842382A1 (de) 1998-09-16 2000-03-23 Bayer Ag Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen
DE19810269A1 (de) * 1998-03-10 2000-05-11 Bayer Ag Verbesserte Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen
US6624286B2 (en) 1997-10-13 2003-09-23 Bayer Aktiengesellschaft Double-metal cyanide catalysts containing polyester for preparing polyether polyols
AU9542598A (en) * 1997-10-13 1999-05-03 Bayer Aktiengesellschaft Crystalline double metal cyanide catalysts for producing polyether polyols
DE19745120A1 (de) * 1997-10-13 1999-04-15 Bayer Ag Verbesserte Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen
US5962619A (en) * 1998-03-16 1999-10-05 Arco Chemical Technology, L.P. Process for making clear polyurethane/urea elastomers
US5952261A (en) * 1998-03-20 1999-09-14 Arco Chemical Technology, L.P. Double metal cyanide complex catalysts modified with Group IIA compounds
US6066683A (en) * 1998-04-03 2000-05-23 Lyondell Chemical Worldwide, Inc. Molded and slab polyurethane foam prepared from double metal cyanide complex-catalyzed polyoxyalkylene polyols and polyols suitable for the preparation thereof
US6008263A (en) * 1998-04-03 1999-12-28 Lyondell Chemical Worldwide, Inc. Molded and slab polyurethane foam prepared from double metal cyanide complex-catalyzed polyoxyalkylene polyols and polyols suitable for the preparation thereof
DE19817676A1 (de) * 1998-04-21 1999-10-28 Bayer Ag Verfahren zur aufarbeitungsfreien Herstellung langkettiger Polyetherpolyole
AR019107A1 (es) 1998-04-27 2001-12-26 Dow Global Technologies Inc Polioles de alto peso molecular, proceso para su preparacion y uso de los mismos.
US6063897A (en) * 1998-05-05 2000-05-16 Arco Chemical Technology, L.P. Acid-treated double metal cyanide complex catalysts
US6013596A (en) * 1998-05-18 2000-01-11 Arco Chemical Technology, L.P. Double metal cyanide catalysts containing cyclic, bidentate complexing agents
US6028230A (en) * 1998-06-05 2000-02-22 Arco Chemical Technology, L.P. Epoxide polymerization process
US6051680A (en) * 1998-06-08 2000-04-18 Arco Chemical Technology, L.P. Silylated double metal cyanide complex catalysts
US6022903A (en) * 1998-07-09 2000-02-08 Arco Chemical Technology L.P. Permanent gas blown microcellular polyurethane elastomers
US6299715B1 (en) 1998-07-14 2001-10-09 Bayer Antwerp N.V. Urethane adhesive-laminated carpeting
US6171678B1 (en) * 1998-07-14 2001-01-09 Bayer Antwerp N.V. Polyurethane carpet backings with improved tuft bind
DE19834572A1 (de) 1998-07-31 2000-02-03 Bayer Ag Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen
DE19842383A1 (de) * 1998-09-16 2000-03-23 Bayer Ag Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen
US6051622A (en) * 1998-09-17 2000-04-18 Arco Chemical Technology, L.P. Low resilience, low frequency molded polyurethane foam
US6100310A (en) * 1998-09-25 2000-08-08 Bayer Antwerp N.V. Process for making microcellular polyurethane elastomers
US6264775B1 (en) 1998-12-22 2001-07-24 Bayer Antwerp N.V. Face-up coating of carpet backs with polyurethane
DE19903274A1 (de) 1999-01-28 2000-08-03 Basf Ag Verfahren zur Herstellung von Polyetherpolyolen
DE19905611A1 (de) 1999-02-11 2000-08-17 Bayer Ag Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen
DE19913260C2 (de) 1999-03-24 2001-07-05 Bayer Ag Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen
AU2294400A (en) 1999-02-11 2000-08-29 Bayer Aktiengesellschaft Double metal cyanide catalysts for producing polyether polyols
DE19906985A1 (de) 1999-02-19 2000-08-31 Bayer Ag Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen
DE19918727A1 (de) 1999-04-24 2000-10-26 Bayer Ag Langkettige Polyetherpolyole mit hohem Anteil primärer OH-Gruppen
US6528616B1 (en) 1999-05-05 2003-03-04 Bayer Aktiengesellschaft Double metal cyanide catalysts for the production of polyther polyols
US6800583B2 (en) 1999-06-02 2004-10-05 Basf Aktiengesellschaft Suspension of multimetal cyanide compounds, their preparation and their use
US6613714B2 (en) * 1999-06-02 2003-09-02 Basf Aktiengesellschaft Multimetal cyanide compounds, their preparation and their use
DE19928156A1 (de) 1999-06-19 2000-12-28 Bayer Ag Aus Polyetherpolyolen hergestellte Polyurethan-Weichschäume
US6384183B1 (en) 1999-07-09 2002-05-07 The Dow Chemical Company Metal hexacyanocobaltate nitroferricyanide complexes
US6376645B1 (en) 1999-07-09 2002-04-23 The Dow Chemical Company Complexing agent-modified hexacyanometallate hexanitrometallate catalysts
US20040266982A1 (en) * 1999-07-09 2004-12-30 Clement Katherine S Polymerization of alkylene oxides onto functionalized initiators
US6423662B1 (en) 1999-07-09 2002-07-23 Dow Global Technologies Inc. Incipient wetness method for making metal-containing cyanide catalysts
DE19937114C2 (de) 1999-08-06 2003-06-18 Bayer Ag Verfahren zur Herstellung von Polyetherpolyolen
US6358877B1 (en) 1999-09-10 2002-03-19 The Dow Chemical Company Metal catalysts complexed with sulfone or sulfoxide compounds
DE19953546A1 (de) 1999-11-08 2001-05-10 Bayer Ag Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen
DE19958355A1 (de) 1999-12-03 2001-06-07 Bayer Ag Verfahren zur Herstellung von DMC-Katalysatoren
US6359101B1 (en) 1999-12-15 2002-03-19 Synuthane International, Inc. Preparing polyether polyols with DMC catalysts
WO2001057106A1 (en) * 2000-02-04 2001-08-09 Ppg Industries Ohio, Inc. Photochromic coated articles
DE10008635A1 (de) † 2000-02-24 2001-09-06 Basf Ag Verfahren zur Herstellung von Polyetherpolyolen
DE60100807T2 (de) 2000-03-30 2004-08-05 Shell Internationale Research Maatschappij B.V. Dmc komplexkatalysator und verfahren zu seiner herstellung
EP1276563B1 (de) * 2000-04-20 2004-06-30 Bayer MaterialScience AG Verfahren zur herstellung von dmc-katalysatoren
AU2001255735A1 (en) 2000-04-28 2001-11-12 Synuthane International, Inc. Double metal cyanide catalysts containing polyglycol ether complexing agents
US6429166B1 (en) 2000-05-19 2002-08-06 Dow Global Technologies Inc. Method for preparing metal cyanide catalyst/polyol initiator slurries
US6388048B1 (en) * 2000-05-19 2002-05-14 The Dow Chemical Company Complexing agent-modified trimetal cyanide catalyst
US6955772B2 (en) * 2001-03-29 2005-10-18 Agfa-Gevaert Aqueous composition containing a polymer or copolymer of a 3,4-dialkoxythiophene and a non-newtonian binder
US6890584B2 (en) * 2000-06-28 2005-05-10 Agfa-Gevaert Flexographic ink containing a polymer or copolymer of a 3,4-dialkoxythiophene
DE10108485A1 (de) 2001-02-22 2002-09-05 Bayer Ag Verbessertes Verfahren zur Herstellung von Polyetherpolyolen
DE10108484A1 (de) 2001-02-22 2002-09-05 Bayer Ag Verbessertes Verfahren zur Herstelung von Polyetherpolyolen
DE10117273A1 (de) * 2001-04-06 2002-10-17 Basf Ag Verfahren zur Herstellung von Hydroxyalkylcarbonsäureestern
KR100418058B1 (ko) * 2001-04-18 2004-02-14 에스케이씨 주식회사 폴리올 제조용 복금속 시안계 착화합물 촉매
DE10122020A1 (de) 2001-05-07 2002-11-14 Bayer Ag Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen
US6833431B2 (en) * 2001-05-02 2004-12-21 Bayer Aktiengesellschaft Double-metal cyanide catalysts for preparing polyether polyols
DE10122019A1 (de) * 2001-05-07 2002-11-14 Bayer Ag Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen
US6596842B2 (en) 2001-07-16 2003-07-22 Shell Oil Company Polymerizing alkylene oxide with sound or radiation treated DMC
DE10137628A1 (de) * 2001-08-03 2003-02-27 Basf Ag Verfahren zur Herstellung von Polyurethan-Weichschaumstoffen
DE10138216A1 (de) 2001-08-03 2003-02-20 Bayer Ag Aliphatische Polycarbonathomo- und -copolymere durch DMC-Katalyse
DE10142746A1 (de) * 2001-08-31 2003-03-20 Bayer Ag Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen
DE10142747A1 (de) 2001-08-31 2003-03-20 Bayer Ag Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen
US20070142604A1 (en) * 2005-12-16 2007-06-21 Nina Bojkova Polyurethanes and sulfur-containing polyurethanes and methods of preparation
US20030096935A1 (en) * 2001-11-16 2003-05-22 Nagpal Vidhu J. Impact resistant polyureaurethane and method of preparation
US8017720B2 (en) * 2005-12-16 2011-09-13 Ppg Industries Ohio, Inc. Sulfur-containing oligomers and high index polyurethanes prepared therefrom
US20060241273A1 (en) * 2001-11-16 2006-10-26 Bojkova Nina V High impact poly (urethane urea) polysulfides
US6541673B1 (en) * 2001-11-30 2003-04-01 Arco Chemical Technology, L.P. Process for oxyalkylating phenolic compounds
ES2199666B1 (es) 2002-02-25 2005-06-01 Repsol Quimica, S.A. Procedimiento de produccion de polioleteres.
CA2479809A1 (en) * 2002-03-21 2003-10-02 Dow Global Technologies Inc. Method for preparing metal cyanide catalyst complexes using partially miscible complexing agents
US6797665B2 (en) 2002-05-10 2004-09-28 Bayer Antwerpen Double-metal cyanide catalysts for preparing polyether polyols
CN1325165C (zh) * 2002-05-17 2007-07-11 中国石化集团金陵石油化工有限责任公司 连续法制备双金属氰化物络合催化剂工艺
US6835801B2 (en) * 2002-07-19 2004-12-28 Bayer Antwerp, N.V. Activated starter mixtures and the processes related thereto
US20040021133A1 (en) * 2002-07-31 2004-02-05 Nagpal Vidhu J. High refractive index polymerizable composition
DE10235130A1 (de) * 2002-08-01 2004-02-19 Bayer Ag Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen
US6696383B1 (en) 2002-09-20 2004-02-24 Bayer Polymers Llc Double-metal cyanide catalysts which can be used to prepare polyols and the processes related thereto
DE10246707A1 (de) * 2002-10-07 2004-04-15 Bayer Ag Zweikomponenten-Systeme für die Herstellung elastischer Beschichtungen
DE10246708A1 (de) * 2002-10-07 2004-04-15 Bayer Ag Zweikomponenten-Systeme für die Herstellung elastischer Beschichtungen
US7001634B2 (en) * 2002-11-07 2006-02-21 Bayer Materialscience Llc Process for suppressing the foaming of an aqueous system
US7009032B2 (en) * 2002-12-20 2006-03-07 Ppg Industries Ohio, Inc. Sulfide-containing polythiols
US6806348B2 (en) * 2003-02-11 2004-10-19 Basf Corporation Process for removing and regenerating a double metal cyanide (DMC) catalyst from a polymer polyol
WO2004081082A1 (en) * 2003-03-07 2004-09-23 Dow Global Technologies Inc. Continuous process and system of producing polyether polyols
US6713599B1 (en) 2003-03-31 2004-03-30 Basf Corporation Formation of polymer polyols with a narrow polydispersity using double metal cyanide (DMC) catalysts
US20040197570A1 (en) * 2003-04-02 2004-10-07 Slack William E. Prepolymers of allophanate-modified MDI and polyoxypropylene polyol
US20050014637A1 (en) * 2003-06-04 2005-01-20 Duijghuisen Henricus Petrus Bernardus Polyether polyol composition
US6884826B2 (en) * 2003-06-09 2005-04-26 Bayer Antwerp, N.V. Process for preparing double metal cyanide catalyzed polyols
US20050070682A1 (en) * 2003-09-30 2005-03-31 Lawrey Bruce D. Polyetherurethaneurea elastomers and thin-walled articles prepared therefrom
US7368518B2 (en) 2003-10-06 2008-05-06 Kaneka Corporation Pressure-sensitive adhesive composition
US7223890B2 (en) * 2003-10-10 2007-05-29 Bayer Materialscience Llc Isocyanate reactive mixture and process for preparing same
US7005552B2 (en) * 2003-11-03 2006-02-28 Bayer Materialscience Llc Single reactor synthesis of KOH-capped polyols based on DMC-synthesized intermediates
US20050101477A1 (en) * 2003-11-07 2005-05-12 George Combs Unsaturated tertiary alcohols as ligands for active dmc catalysts
US20050107486A1 (en) * 2003-11-17 2005-05-19 Bi Le-Khac UV-curable polyols
US20050281977A1 (en) * 2004-01-23 2005-12-22 Mashburn Larry E Method of carpet construction
US8470927B2 (en) 2004-02-26 2013-06-25 Bayer Materialscience Llc Process for production of polymer polyols
ES2298705T3 (es) * 2004-02-27 2008-05-16 Repsol Quimica S.A. Catalizadores de cianuros dobles metalicos (dmc) con esteres-corona, procedimiento para su obtencion y aplicaciones.
US20050209438A1 (en) * 2004-03-19 2005-09-22 Browne Edward P Starter feed stream acidification in DMC-catalyzed process
US7060750B2 (en) * 2004-04-28 2006-06-13 Bayer Materialscience Llc Moisture-curable, polyether urethanes and their use in sealant, adhesive and coating compositions
US11149107B2 (en) 2004-09-01 2021-10-19 Ppg Industries Ohio, Inc. Polyurethanes, articles and coatings prepared therefrom and methods of making the same
US20090280709A1 (en) 2004-09-01 2009-11-12 Ppg Industries Ohio, Inc. Polyurethanes, Articles and Coatings Prepared Therefrom and Methods of Making the Same
US11591436B2 (en) 2004-09-01 2023-02-28 Ppg Industries Ohio, Inc. Polyurethane article and methods of making the same
US9464169B2 (en) 2004-09-01 2016-10-11 Ppg Industries Ohio, Inc. Polyurethanes, articles and coatings prepared therefrom and methods of making the same
US9598527B2 (en) 2004-09-01 2017-03-21 Ppg Industries Ohio, Inc. Polyurethanes, articles and coatings prepared therefrom and methods of making the same
US20090280329A1 (en) 2004-09-01 2009-11-12 Ppg Industries Ohio, Inc. Polyurethanes, Articles and Coatings Prepared Therefrom and Methods of Making the Same
US11008418B2 (en) 2004-09-01 2021-05-18 Ppg Industries Ohio, Inc. Polyurethanes, articles and coatings prepared therefrom and methods of making the same
US20060058182A1 (en) * 2004-09-13 2006-03-16 Combs George G Processes for the preparation of double metal cyanide (DMC) catalysts
JP2008518088A (ja) * 2004-10-26 2008-05-29 ダウ グローバル テクノロジーズ インコーポレイティド 活性水素含有化合物をアルコキシル化する改良方法及びそれから調製したアルコキシル化化合物
CN1308079C (zh) * 2004-11-29 2007-04-04 黎明化工研究院 一种氰化物络合物催化剂及其制备方法和用途
US20060229375A1 (en) * 2005-04-06 2006-10-12 Yu-Ling Hsiao Polyurethane foams made with alkoxylated vegetable oil hydroxylate
US7609773B2 (en) * 2005-04-18 2009-10-27 Qualcomm Incorporated Method of determining the location of the FFT window and the delay spread for the platinum broadcast channel estimator
US7842653B2 (en) * 2005-06-16 2010-11-30 Council Of Scientific & Industrial Research Process for the preparation of lubricants
US7754643B2 (en) * 2005-10-07 2010-07-13 Council Of Scientific & Industrial Research Transesterification catalyst and a process for the preparation thereof
US7323605B2 (en) * 2005-11-09 2008-01-29 Bayer Materialscience Llc Double metal cyanide-catalyzed, low unsaturation polyethers from boron-containing starters
US7482495B2 (en) * 2005-12-22 2009-01-27 Lyondell Chemical Technology, L.P. Process for making alkylene glycol ether compositions useful for metal recovery
DE102006006696A1 (de) * 2006-02-14 2007-08-23 Clariant International Limited Polyalkylenglykol-Schmiermittelbasisöle mit enger Molmassenverteilung
CN101437875B (zh) * 2006-05-05 2011-05-11 Ppg工业俄亥俄公司 硫醚官能的低聚多硫醇以及由其制备的制品
DE102006024025A1 (de) * 2006-05-23 2007-11-29 Bayer Materialscience Ag Verfahren zur Herstellung von Polyetherpolyolen
US20070299242A1 (en) * 2006-06-21 2007-12-27 Bayer Materialscience Llc Pendant acrylate and/or methacrylate-containing polyether monols and polyols
US20080021191A1 (en) * 2006-07-20 2008-01-24 Reese Jack R High water content tolerant process for the production of polyethers
US7977501B2 (en) * 2006-07-24 2011-07-12 Bayer Materialscience Llc Polyether carbonate polyols made via double metal cyanide (DMC) catalysis
US8093351B2 (en) * 2006-08-24 2012-01-10 Cornell Research Foundation, Inc. Copolymerization of propylene oxide and carbon dioxide and homopolymerization of propylene oxide
US20080132729A1 (en) 2006-12-01 2008-06-05 Mcdaniel Kenneth G Continuous process for the production of ethoxylates
US20080132728A1 (en) * 2006-12-01 2008-06-05 Mcdaniel Kenneth G Continuous processes for the production of alkylphenol ethoxylates
CN100415800C (zh) * 2007-01-05 2008-09-03 南通汇科聚氨酯研发有限公司 环氧化物开环聚合用双金属氰化物催化剂
US20080167501A1 (en) 2007-01-08 2008-07-10 Bayer Materialscience Llc. High productivity alkoxylation processes
US7834082B2 (en) 2007-01-17 2010-11-16 Bayer Materialscience Llc Polyether-polysiloxane polyols
DE102007002555A1 (de) 2007-01-17 2008-07-24 Bayer Materialscience Ag Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen
CA2675599C (en) 2007-01-29 2015-06-16 The Lubrizol Corporation Lubricant compositions comprising an ester and a polyol
CA2674549A1 (en) 2007-01-29 2008-08-07 The Lubrizol Corporation Lubricating compositions
DE102007005960A1 (de) 2007-02-07 2008-08-14 Bayer Materialscience Ag Ruß-gefüllte Polyurethane mit hoher Dielektrizitätskonstante und Durchschlagsfestigkeit
US20080255378A1 (en) 2007-04-16 2008-10-16 Bayer Materialscience Llc High productivity process for non-phenolic ethoxylates
US7473677B2 (en) 2007-04-16 2009-01-06 Bayer Materialscience Llc High productivity process for alkylphenol ethoxylates
DE102007038436A1 (de) 2007-08-16 2009-02-19 Bayer Materialscience Ag Verfahren zur Herstellung von Polyolen
DE102007057145A1 (de) 2007-11-28 2009-06-04 Evonik Goldschmidt Gmbh Verfahren zur Herstellung von Polyetheralkoholen mit DMC-Katalysatoren unter Verwendung von SiH-Gruppen tragenden Verbindungen als Additive
DE102007057146A1 (de) 2007-11-28 2009-06-04 Evonik Goldschmidt Gmbh Verfahren zur Herstellung von Polyetheralkoholen mit DMC-Katalysatoren unter Verwendung von speziellen Additiven mit aromatischer Hydroxy-Funktionalisierung
DE102008000360A1 (de) 2008-02-21 2009-08-27 Evonik Goldschmidt Gmbh Neue Alkoxysilylgruppen tragende Polyetheralkohole durch Alkoxylierung epoxidfunktioneller Alkoxysilane an Doppelmetallcyanid (DMC)-Katalysatoren, sowie Verfahren zu deren Herstellung
DE102008011683A1 (de) 2008-02-28 2009-09-03 Bayer Materialscience Ag Verfahren zur Herstellung von Polyolen
DE102008000903A1 (de) 2008-04-01 2009-10-08 Evonik Goldschmidt Gmbh Neue Organosiloxangruppen tragende Polyetheralkohole durch Alkoxylierung epoxidfunktioneller (Poly)Organosiloxane an Doppelmetallcyanid (DMC)-Katalysatoren, sowie Verfahren zu deren Herstellung
KR100941637B1 (ko) 2008-05-21 2010-02-11 에스케이씨 주식회사 반응성이 제어된, 폴리올 제조용 복금속 시안계 촉매 및이의 제조방법
DE102008028555A1 (de) 2008-06-16 2009-12-17 Bayer Materialscience Ag Verfahren zur Herstellung von Polyolen
CA2729116C (en) * 2008-06-25 2017-01-24 Benefuel Inc. Process of manufacturing of fatty acid alkyl esters
DE102008002713A1 (de) 2008-06-27 2009-12-31 Evonik Goldschmidt Gmbh Neue Polyethersiloxane enthaltende Alkoxylierungsprodukte durch direkte Alkoxylierung organomodifizierter alpha, omega-Dihydroxysiloxane an Doppelmetallcyanid (DMC)-Katalysatoren, sowie Verfahren zu deren Herstellung
IL200996A0 (en) 2008-10-01 2010-06-30 Bayer Materialscience Ag Photopolymer formulations having a low crosslinking density
IL200995A0 (en) 2008-10-01 2010-06-30 Bayer Materialscience Ag Polyether-based polyurethane formulations for the production of holographic media
IL200997A0 (en) 2008-10-01 2010-06-30 Bayer Materialscience Ag Special polyether-based polyurethane formulations for the production of holographic media
DE102008051882A1 (de) 2008-10-16 2010-04-29 Bayer Materialscience Ag Verfahren zur Herstellung von Polyetheresterpolyolen
DE102008043245A1 (de) 2008-10-29 2010-05-06 Evonik Goldschmidt Gmbh Siliconpolyether-Copolymersysteme sowie Verfahren zu deren Herstellung durch Alkoxylierungsreaktion
DE102008043343A1 (de) 2008-10-31 2010-05-06 Evonik Goldschmidt Gmbh Silikonpolyetherblock-Copolymere mit definierter Polydispersität im Polyoxyalkylenteil und deren Verwendung als Stabilisatoren zur Herstellung von Polyurethanschäumen
US20110218264A1 (en) * 2008-11-14 2011-09-08 Dow Global Technologies Llc Modified natural oils and products made therefrom
US10239985B2 (en) 2008-12-23 2019-03-26 Covestro Llc Polymer polyols comprising a natural oil base polyol, polyurethane foams comprising these polymer polyols and processes for their preparation
DE102009002371A1 (de) 2009-04-15 2010-10-21 Evonik Goldschmidt Gmbh Verfahren zur Herstellung von geruchlosen Polyetheralkoholen mittels DMC-Katalysatoren und deren Verwendung in kosmetischen und/oder dermatologischen Zubereitungen
US20100324340A1 (en) 2009-06-23 2010-12-23 Bayer Materialscience Llc Short chain polyether polyols prepared from ultra-low water-content starters via dmc catalysis
DE102009031584A1 (de) 2009-07-03 2011-01-05 Bayer Materialscience Ag Verfahren zur Herstellung von Polyetherpolyolen mit primären Hydroxyl-Endgruppen
US8580984B2 (en) 2009-07-10 2013-11-12 Dow Global Technologies Llc Esters of secondary hydroxy fatty acid oligomers and preparation thereof
US8362304B2 (en) * 2009-07-15 2013-01-29 Lyondell Chemical Technology, L.P. Process for making glycol ether compositions useful for metal recovery
DE102009042190A1 (de) 2009-09-18 2011-03-24 Bayer Materialscience Ag Silangruppenhaltige Reaktivverdünner
DE102009042201A1 (de) 2009-09-18 2011-04-14 Bayer Materialscience Ag Silangruppenhaltige Polyether
DE102009043616A1 (de) 2009-09-29 2011-03-31 Bayer Materialscience Ag Verfahren zur Herstellung von aminogruppenhaltigen Polyolen
HUE044164T2 (hu) 2009-10-19 2019-10-28 Basf Se Kettõs fém-cianid katalizátorok kondicionálása
CA2780919A1 (en) 2009-10-21 2011-04-28 Bayer Materialscience Ag Biodegradable hydrogel
CN102667936B (zh) 2009-11-03 2016-03-30 拜尔材料科学股份公司 生产全息介质的方法
EP2317511B1 (de) 2009-11-03 2012-03-07 Bayer MaterialScience AG Photopolymerformulierungen mit einstellbarem mechanischem Modul Guv
WO2011067057A1 (de) 2009-11-03 2011-06-09 Bayer Materialscience Ag Verfahren zur herstellung eines holographischen films
JP5638085B2 (ja) 2009-11-03 2014-12-10 バイエル・マテリアルサイエンス・アクチェンゲゼルシャフトＢａｙｅｒ ＭａｔｅｒｉａｌＳｃｉｅｎｃｅ ＡＧ 異なった書込コモノマーを含有する感光性ポリマー組成物
TWI488908B (zh) 2009-11-03 2015-06-21 Bayer Materialscience Ag 製造全像膜的方法
CN102656209A (zh) 2009-12-09 2012-09-05 陶氏环球技术有限责任公司 仲羟基脂肪酸及其衍生物的聚醚衍生物
WO2011075343A1 (en) 2009-12-17 2011-06-23 Dow Global Technologies Inc. Ethylene oxide capping of secondary hydroxyl polyols
KR20120128130A (ko) 2010-01-20 2012-11-26 바이엘 인텔렉쳐 프로퍼티 게엠베하 폴리에테르 카르보네이트 폴리올의 제조를 위한 이중 금속 시아나이드 촉매의 활성화 방법
DE102010008410A1 (de) 2010-02-18 2011-08-18 Bayer MaterialScience AG, 51373 Verfahren zur Herstellung von Polyethercarbonatpolyolen
US20110213170A1 (en) * 2010-02-26 2011-09-01 Daniele Vinci Estolide derivatives useful as biolubricants
EP2365019A1 (de) 2010-03-13 2011-09-14 Bayer MaterialScience AG Verfahren zur Herstellung von Polyetherpolyolen
US20110230581A1 (en) 2010-03-17 2011-09-22 Bayer Materialscience Llc Process for the production of polyether polyols with a high ethylene oxide content
ES2587257T3 (es) 2010-03-24 2016-10-21 Covestro Deutschland Ag Procedimiento para la preparación de polioletercarbonatos
EP2372454A1 (de) 2010-03-29 2011-10-05 Bayer MaterialScience AG Photopolymer-Formulierung zur Herstellung sichtbarer Hologramme
MX2012012617A (es) 2010-04-29 2012-12-17 Dow Global Technologies Llc Polioles de poliester-polieter hibridos.
WO2011136906A1 (en) 2010-04-29 2011-11-03 Dow Global Technologies Llc Oligomerized ester alkoxylate compositions
KR20130060213A (ko) 2010-04-30 2013-06-07 바스프 에스이 폴리에테르 폴리올, 폴리에테르 폴리올의 제조 방법, 및 폴리우레탄 제조를 위한 그의 용도
US9115246B2 (en) 2010-04-30 2015-08-25 Basf Se Polyether polyols, process for preparing polyether polyols and their use for producing polyurethanes
DE102010019504A1 (de) 2010-05-06 2011-11-10 Bayer Materialscience Ag Polyisocyanatprepolymere und deren Verwendung
PL2571922T3 (pl) 2010-05-18 2014-11-28 Bayer Ip Gmbh Sposób wytwarzania polioli polieterowęglanowych
EP2576657B1 (en) * 2010-05-27 2017-01-18 Dow Global Technologies LLC Methods for producing crosslinkable silyl group-containing polyoxyalkylene polymers
SA111320500B1 (ar) 2010-06-04 2015-06-17 داو جلوبال تكنولوجيز ال ال سي معلقات لاستعادة محسنة للزيت
WO2011160296A1 (en) 2010-06-23 2011-12-29 Basf Se Modified double metal cyanide catalyst
ES2534519T5 (es) 2010-06-30 2020-12-29 Dow Global Technologies Llc Polímeros terminados en sililo
MX2013000190A (es) 2010-07-05 2013-01-28 Bayer Ip Gmbh Procedimiento para la preparacion de mezclas de polioles.
DE102010038768A1 (de) 2010-08-02 2012-02-02 Evonik Goldschmidt Gmbh Modifizierte Alkoxylierungsprodukte mit mindestens einer nicht-terminalen Alkoxysilylgruppe mit erhöhter Lagerstabilität und erhöhter Dehnbarkeit der unter deren Verwendung hergestellten Polymere
DE102010038774A1 (de) 2010-08-02 2012-02-02 Evonik Goldschmidt Gmbh Modifizierte Alkoxylierungsprodukte, die zumindest eine nicht-terminale Alkoxysilylgruppe aufweisen, mit erhöhter Lagerstabilität und erhöhter Dehnbarkeit der unter deren Verwendung hergestellten Polymere
DE102010039090A1 (de) 2010-08-09 2012-02-09 Basf Se Verfahren zur Herstellung von Polyetheralkoholen
DE102010039140A1 (de) 2010-08-10 2012-02-16 Evonik Goldschmidt Gmbh Dispergiermittel und Verfahren zu deren Herstellung
JP5731651B2 (ja) 2010-08-20 2015-06-10 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ ポリエーテルエステルポリオールの製造方法
DE102010040517A1 (de) 2010-09-09 2012-03-15 Bayer Materialscience Aktiengesellschaft Verfahren zur Herstellung von Polyetherpolyolen
EP2441788A1 (de) 2010-10-14 2012-04-18 Bayer MaterialScience AG Verfahren zur Herstellung von Polyetherpolyolen
EA023366B1 (ru) 2010-10-25 2016-05-31 Стипэн Компани Сложные эфирамины и производные, получаемые посредством метатезиса натуральных масел
AP3677A (en) 2010-10-25 2016-04-16 Stepan Co Fatty amines, amidoamines, and their derivatives from natural oil metathesis
US9006144B2 (en) 2010-10-25 2015-04-14 Stepan Company Glyphosate formulations based on compositions derived from natural oil metathesis
EP2633018B1 (en) 2010-10-25 2021-07-28 Stepan Company Sulfonates from natural oil metathesis
EA023401B1 (ru) 2010-10-25 2016-05-31 Стипэн Компани Амиды жирных кислот и их производные, полученные посредством метатезиса натурального масла
SG189991A1 (en) 2010-10-25 2013-06-28 Stepan Co Hard surface cleaners based on compositions derived from natural oil metathesis
CA2815645C (en) 2010-10-25 2017-08-15 Stepan Company Alkoxylated fatty esters and derivatives from natural oil metathesis
BR112013009946B1 (pt) 2010-10-25 2019-04-30 Stepan Company Composição de sulfobetaina, betaina ou amônio quaternário, derivado; formulação de glifosato, composição de herbicida solúvel em água ou composição antimicrobiana, limpador de superfície áspera, formulação de detergente para vestuário sujo, xampu ou condicionador de cabelo ou produto de limpeza pessoal ou sabonete, inibidor de corrosão, dispersante de parafina, espumante de poço de gás, espumante, aditivo de espuma ou dispersante e emulsificante aniônico para composições agrícolas
WO2012061110A1 (en) 2010-10-25 2012-05-10 Stepan Company Light-duty liquid detergents based on compositions derived from natural oil metathesis
PL2633020T3 (pl) 2010-10-25 2019-10-31 Stepan Co Detergenty do prania na bazie kompozycji pochodzących z metatezy naturalnego oleju
DE102010043409A1 (de) 2010-11-04 2012-05-10 Bayer Materialscience Aktiengesellschaft Verfahren zur Herstellung von Polycarbonatpolyolen durch immortale Polymerisation von cyclischen Carbonaten
EP2450387A1 (de) 2010-11-08 2012-05-09 Bayer MaterialScience AG Photopolymer-Formulierung für die Herstellung holographischer Medien
ES2501515T3 (es) 2010-11-09 2014-10-02 Basf Se Polieterester-polioles
EP2465890A1 (de) 2010-12-17 2012-06-20 Bayer MaterialScience AG Verfahren zur Herstellung von Polyethercarbonatpolyolen mit primären Hydroxyl-Endgruppen und daraus hergestellte Polyurethanpolymere
KR20140007822A (ko) 2010-12-20 2014-01-20 바이엘 인텔렉쳐 프로퍼티 게엠베하 폴리에테르 에스테르 폴리올의 제조 방법
ES2525022T3 (es) 2010-12-20 2014-12-16 Bayer Intellectual Property Gmbh Procedimiento para la preparación de polioléteres
BR112013016657B1 (pt) 2010-12-27 2021-11-03 Dow Global Technologies Llc Método para produzir um produto de poliéter monol ou poliéter poliol
WO2012121997A1 (en) 2011-03-04 2012-09-13 Ppg Industries Ohio, Inc. Polythiourethan based composite articles
KR101404702B1 (ko) 2011-03-08 2014-06-17 에스케이이노베이션 주식회사 에테르 결합 단위체를 함유한 이산화탄소/에폭사이드 공중합체의 제조 방법
WO2012122197A2 (en) 2011-03-09 2012-09-13 Benefuel Inc. Systems and methods for making bioproducts
ES2653151T3 (es) 2011-03-28 2018-02-06 Covestro Deutschland Ag Procedimiento para la preparación de espumas flexibles de poliuretano
JP6208655B2 (ja) 2011-04-04 2017-10-04 ヘンケル・アクチェンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフト・アウフ・アクチェンＨｅｎｋｅｌ ＡＧ ＆ Ｃｏ． ＫＧａＡ エポキシドを重合するためおよびエポキシドと二酸化炭素を共重合するための触媒
EP2511314A1 (de) 2011-04-12 2012-10-17 Bayer MaterialScience AG Polyurethanpolymer und dessen Verwendung in elektromechanischen Wandlern
BR112013029462B1 (pt) 2011-05-16 2021-02-23 Stepan Company Composição de surfactante e concentrado aquoso úteis pararecuperação de petróleo, produto injetável feito para diluir o concentrado e acomposição de surfactante, microemulsão de petróleo em água de baixaviscosidade, estável e método
SA112330512B1 (ar) 2011-05-17 2016-11-17 ريبسول، اس. ايه. عملية لتحضير مُحفِّز من مُعقَّد سيانيدي مزدوج المعدن
DE102011076019A1 (de) 2011-05-18 2012-11-22 Evonik Goldschmidt Gmbh Alkoxylierungsprodukte und Verfahren zu ihrer Herstellung mittels DMC-Katalysatoren
EP2530101A1 (de) 2011-06-01 2012-12-05 Bayer MaterialScience AG Verfahren zur Herstellung von Polyetherpolyolen
ES2537891T3 (es) 2011-06-30 2015-06-15 Bayer Intellectual Property Gmbh Procedimiento para la preparación de polieterpolioles de peso molecular alto
PT2543689T (pt) 2011-07-04 2016-09-22 Repsol Sa Método contínuo para a síntese de polióis
EP2548905A1 (de) 2011-07-18 2013-01-23 Bayer MaterialScience AG Verfahren zur Aktivierung von Doppelmetallcyanidkatalysatoren zur Herstellung von Polyetherpolyolen
EP2548906A1 (de) 2011-07-18 2013-01-23 Bayer MaterialScience AG Verfahren zur Aktivierung von Doppelmetallcyanidkatalysatoren zur Herstellung von Polyetherpolyolen
EP2548908A1 (de) 2011-07-18 2013-01-23 Bayer MaterialScience AG Verfahren zur Herstellung von Polyetherpolyolen
EP2548907A1 (de) 2011-07-18 2013-01-23 Bayer MaterialScience AG Verfahren zur Herstellung von Polyetherpolyolen
CA2843048A1 (en) 2011-07-26 2013-01-31 Bayer Intellectual Property Gmbh Etherified lactate esters, method for the production thereof and use thereof for enhancing the effect of plant protecting agents
DE102011109541A1 (de) 2011-08-03 2013-02-07 Evonik Goldschmidt Gmbh Verwendung von Polysiloxanen enthaltend verzweigte Polyetherreste zur Herstellung von Polyurethanschäumen
DE102011109545A1 (de) 2011-08-03 2013-02-07 Evonik Goldschmidt Gmbh Verfahren zur Herstellung von Polyethersiloxanen enthaltend Polyethercarbonatgrundstrukturen
EP2748226B1 (en) 2011-08-25 2015-09-16 Dow Global Technologies LLC Process for making polyether alcohols having oxyethylene units by polymerization of ethylene carbonate in the presence of double metal cyanide catalysts
US20140255824A1 (en) 2011-10-12 2014-09-11 Bayer Intellectual Property Gmbh Sulphur-containing chain transfer reagents in polyurethane-based photopolymer formulations
JP2014535072A (ja) 2011-10-12 2014-12-25 バイエル・インテレクチュアル・プロパティ・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツングＢａｙｅｒ Ｉｎｔｅｌｌｅｃｔｕａｌ Ｐｒｏｐｅｒｔｙ ＧｍｂＨ ポリウレタン系フォトポリマー処方物における連鎖移動剤
BR112014009157B1 (pt) 2011-10-28 2020-11-10 Dow Global Technologies Llc composição lubrificante e método para preparar uma composição lubrificante
EP2604642A1 (de) 2011-12-16 2013-06-19 Bayer Intellectual Property GmbH Verfahren zur Herstellung von Polyethercarbonatpolyolen
EP2604641A1 (de) 2011-12-16 2013-06-19 Bayer Intellectual Property GmbH Verfahren zur Herstellung von Polyetherestercarbonatpolyolen
ES2560031T3 (es) 2011-12-20 2016-02-17 Medical Adhesive Revolution Gmbh Polímero de hidroxi-amino y su uso en adhesivos para tejido de poliurea-poliuretano
CN108570140A (zh) 2011-12-20 2018-09-25 阿德希西斯医疗有限公司 用于生物可降解组织粘合剂的异氰酸酯官能的预聚物
SG10201604976RA (en) 2011-12-20 2016-08-30 Bayer Ip Gmbh Hydroxy-aminopolymers and method for producing same
EP2802612B1 (de) 2012-01-09 2016-04-06 Medical Adhesive Revolution GmbH Beta-aminosäureester modifizierte (aspartat-)härter und dessen verwendung in polyharnstoff-gewebeklebstoffen
DE102012203737A1 (de) 2012-03-09 2013-09-12 Evonik Goldschmidt Gmbh Modifizierte Alkoxylierungsprodukte, die zumindest eine nicht-terminale Alkoxysilylgruppe aufweisen und mehrere Urethangruppen enthalten und deren Verwendung
ES2833282T3 (es) 2012-04-24 2021-06-14 Stepan Co Derivados de alcohol graso no saturado a partir de metátesis del aceite natural
NZ701296A (en) 2012-04-24 2016-02-26 Stepan Co Unsaturated fatty alcohol alkoxylates from natural oil metathesis
ES2644129T3 (es) * 2012-05-10 2017-11-27 Basf Se Alcoholes alcoxilados y su uso en formulaciones para la limpieza de superficies duras
EP2671893A1 (de) 2012-06-06 2013-12-11 Bayer MaterialScience AG Verfahren zur Herstellung von Omega-Hydroxy-Aminopolymeren
US9035105B2 (en) 2012-07-20 2015-05-19 Bayer Materialscience Llc Process for the in situ production of polyether polyols based on renewable materials and their use in the production of flexible polyurethane foams
EP2703426A1 (de) 2012-08-27 2014-03-05 Bayer MaterialScience AG Verfahren zur Herstellung von Polyethercarbonatpolyolen
EP2703425A1 (de) 2012-08-27 2014-03-05 Bayer MaterialScience AG Verfahren zur Herstellung von Polyethercarbonatpolyolen
CN102875796B (zh) * 2012-10-16 2015-03-04 山东蓝星东大化工有限责任公司 一种提高聚醚多元醇生产用dmc催化剂活性的方法
DE102012218846A1 (de) 2012-10-16 2014-04-17 Bayer Materialscience Ag Herstellung und Verwendung neuer thermoplastischer Polyurethan-Elastomere auf Basis von Polyethercarbonatpolyolen
DE102012218848A1 (de) 2012-10-16 2014-04-17 Bayer Materialscience Ag Herstellung und Verwendung neuer thermoplastischer Polyurethan-Elastomere auf Basis von Polyethercarbonatpolyolen
EP2725044B1 (de) 2012-10-24 2017-06-21 Covestro Deutschland AG Alkoxysilanterminiertes Präpolymer auf Basis von Polyethercarbonatpolyolen für Sprühschäume
EP2730602A1 (de) 2012-11-09 2014-05-14 Bayer MaterialScience AG Verfahren zur Herstellung von Polyethercarbonatpolyolen
BR112015010448A2 (pt) 2012-11-09 2018-05-15 Bayer Materialscience Ag Método para a produção de poliéter-carbonato- polióis.
US9568643B2 (en) 2012-12-13 2017-02-14 Ppg Industries Ohio, Inc. Polyurethane urea-containing compositions and optical articles and methods for preparing them
US9562134B2 (en) 2013-03-12 2017-02-07 Covestro Llc Catalyst for the production of polyols having lower amounts of high molecular weight tail
SG11201507218QA (en) 2013-03-13 2015-10-29 Stepan Co Surfactants based on monounsaturated fatty alcohol derivatives
US9890100B2 (en) 2013-03-14 2018-02-13 Covestro Llc Continuous process for the production of low molecular weight polyethers with a DMC catalyst
US9051412B2 (en) 2013-03-14 2015-06-09 Bayer Materialscience Llc Base-catalyzed, long chain, active polyethers from short chain DMC-catalyzed starters
US8987396B2 (en) 2013-03-15 2015-03-24 Bayer Materialscience Llc Active polymer polyols and a process for their production
US10669368B2 (en) 2013-03-15 2020-06-02 Covestro Llc Method to increase the resistance of double metal cyanide catalysts to deactivation
DE102013206175A1 (de) 2013-04-09 2014-10-09 Evonik Industries Ag Polysiloxan-Polyether-Copolymere mit Amino- und/oder quaternären Ammoniumgruppen im Polyetherteil und Verfahren zu deren Herstellung
DK2986694T3 (da) 2013-04-17 2020-03-30 Lubrizol Corp Fremgangsmåde til smøring af cylinder og stempel i en intern to-taktsforbrændingsmotor
DE102013208328A1 (de) 2013-05-07 2014-11-13 Evonik Industries Ag Polyoxyalkylene mit seitenständigen langkettigen Acyloxyresten und Verfahren zu ihrer Herstellung mittels DMC-Katalysatoren
WO2014198689A1 (de) 2013-06-13 2014-12-18 Bayer Materialscience Ag Polyethercarbonat-polyoxymethylen-block-copolymere
JP2016525619A (ja) 2013-08-02 2016-08-25 コベストロ、ドイチュラント、アクチエンゲゼルシャフトＣｏｖｅｓｔｒｏ Ｄｅｕｔｓｃｈｌａｎｄ Ａｇ ポリエーテルカーボネートポリオールの製造方法
DE102013216751A1 (de) 2013-08-23 2015-02-26 Evonik Industries Ag Modifizierte Alkoxylierungsprodukte, die Alkoxysilylgruppen aufweisen und Urethangruppen enthalten und deren Verwendung
EP2845871A1 (de) 2013-09-05 2015-03-11 Bayer MaterialScience AG Vernetzung von Doppelbindungen enthaltenden Polyethercarbonatpolyolen durch Addition von Mercaptanen
EP2845873A1 (de) 2013-09-05 2015-03-11 Bayer MaterialScience AG Radikalische Vernetzung von Polyethercarbonatpolyolen enthaltend elektronenarme und elektronenreiche Doppelbindungen
WO2015032720A1 (de) 2013-09-05 2015-03-12 Bayer Materialscience Ag Höherfunktionelle polyethercarbonatpolyole erhalten unter einsatz von verzweigermolekülen
EP2845872A1 (de) 2013-09-05 2015-03-11 Bayer MaterialScience AG Niederviskose Polyethercarbonatpolyole mit Seitenketten
EP2851384A1 (de) 2013-09-20 2015-03-25 Bayer MaterialScience AG Verzweigte Polyethercarbonatpolyole und Verfahren zu deren Herstellung
EP2865700A1 (de) 2013-10-23 2015-04-29 Bayer MaterialScience AG Verfahren zur Herstellung von Polyethercarbonatpolyolen
CN105683341A (zh) 2013-10-29 2016-06-15 陶氏巴西东南工业有限公司 一种润滑剂组合物以及润滑机械装置的方法
EP2876121A1 (de) 2013-11-22 2015-05-27 Bayer MaterialScience AG Einsatz von Urethan-Alkoholen zur Herstellung von Polyetherpolyolen
EP3077437A1 (de) 2013-11-27 2016-10-12 Covestro Deutschland AG Mischungen von polyethercarbonatpolyolen und polyetherpolyolen zur herstellung von polyurethanweichschaumstoffen
EP2886572A1 (de) 2013-12-17 2015-06-24 Bayer MaterialScience AG Einsatz von Urethan-Alkoholen zur Herstellung von Polyethercarbonatpolyolen
CN105814113B (zh) 2013-12-18 2018-11-23 科思创德国股份有限公司 后处理碱性聚醚多元醇的方法
EP2894180A1 (en) 2014-01-08 2015-07-15 Bayer MaterialScience AG Polymer Polyols comprising a Polyether Carbonate Polyol as the Base Polyol
EP2910585B1 (de) 2014-02-21 2018-07-04 Covestro Deutschland AG Schotterkörper sowie Verfahren zur Herstellung von Schotterkörpern
CN106414532B (zh) 2014-04-07 2019-11-01 科思创德国股份有限公司 制造聚甲醛嵌段共聚物的方法
EP3134449A1 (de) 2014-04-24 2017-03-01 Covestro Deutschland AG Polyurethanschaumstoffe basierend auf polyethercarbonatpolyolen
US9527958B2 (en) 2014-05-02 2016-12-27 Covestro Llc Process for purification of polyether carbonate polyols
DE102014209355A1 (de) 2014-05-16 2015-11-19 Evonik Degussa Gmbh Guanidinhaltige Polyoxyalkylene und Verfahren zur Herstellung
DE102014209408A1 (de) 2014-05-19 2015-11-19 Evonik Degussa Gmbh Ethoxylatherstellung unter Verwendung hoch aktiver Doppelmetallcyanid-Katalysatoren
WO2015191434A2 (en) 2014-06-09 2015-12-17 Stepan Company Detergents for cold-water cleaning
WO2016016061A1 (en) 2014-07-30 2016-02-04 Basf Se Amphiphilic star-like polyether
DE102014217790A1 (de) 2014-09-05 2016-03-10 Evonik Degussa Gmbh Verfahren zur Herstellung von hydrosilylierbaren Eugenol-Polyethern und Eugenol-Polyethersiloxanen sowie deren Verwendung
WO2016046110A1 (de) 2014-09-23 2016-03-31 Covestro Deutschland Ag Feuchtigkeitshärtende polyethercarbonate enthaltend alkoxysilyl-gruppen
EP3023447A1 (de) 2014-11-18 2016-05-25 Covestro Deutschland AG Verfahren zur Herstellung von Polyethercarbonatpolyolen
JP2018506444A (ja) 2014-12-01 2018-03-08 ダウ グローバル テクノロジーズ エルエルシー 表面改質剤としてのポリオレフィンポリオール類
US10570352B2 (en) 2015-01-08 2020-02-25 Stepan Company Cold-water laundry detergents
EP3050907A1 (de) 2015-01-28 2016-08-03 Covestro Deutschland AG Verfahren zur Herstellung von Polyethercarbonatpolyolen
US20160244549A1 (en) 2015-02-25 2016-08-25 Bayer Materialscience Llc Alkoxysilane-group modified polyurethanes and low modulus sealants formed therefrom
US20180237577A1 (en) 2015-02-27 2018-08-23 Covestro Deutschland Ag Use of polyether carbonate polyols for producing polyurethane foams with stable colour
EP3067376A1 (de) 2015-03-11 2016-09-14 Evonik Degussa GmbH Herstellung von Polyurethansystemen unter Einsatz von Polyetherpolycarbonatpolyolen
US9951174B2 (en) 2015-05-20 2018-04-24 Covestro Llc Polyol compositions, a process for the production of these polyol compositions, and their use in the production of open celled polyurethane foams having high airflow
EP3098252A1 (de) 2015-05-26 2016-11-30 Covestro Deutschland AG Einsatz von alkoholen, die mindestens zwei urethangruppen enthalten, zur herstellung von polyethercarbonatpolyolen
DE102015108232A1 (de) 2015-05-26 2016-12-01 Franken Systems Gmbh Verfahren zur feuchtigkeitsbeständigen Grundierung von mineralischen Untergründen
EP3098251A1 (de) 2015-05-26 2016-11-30 Covestro Deutschland AG Einsatz von alkoholen, die mindestens zwei urethangruppen enthalten, zur herstellung von polyetherpolyolen
EP3098250A1 (de) 2015-05-26 2016-11-30 Covestro Deutschland AG Verfahren zur herstellung von polyethercarbonatpolyolen
DE102015110841A1 (de) 2015-07-06 2017-01-12 Franken Systems Gmbh Verwendung eines Reaktivsystems zur Bauwerksabdichtung und eine Bauwerksabdichtung
CN107922607B (zh) 2015-08-26 2020-05-19 科思创德国股份有限公司 制备高分子量聚氧化烯多元醇的方法
GB201515350D0 (en) 2015-08-28 2015-10-14 Econic Technologies Ltd Method for preparing polyols
EP3138867B1 (de) 2015-09-03 2019-10-02 Evonik Degussa GmbH Verwendung von eugenol-polyethern und eugenol-polyethersiloxanen als netzmittel
CA3004385A1 (en) 2015-11-19 2017-05-26 Covestro Deutschland Ag Polyurethane foams based on polyether carbonate polyols
US9745259B2 (en) 2015-12-04 2017-08-29 Chevron U.S.A. Inc. Process for preparing alcohol ether sulfates
WO2017097729A1 (de) 2015-12-09 2017-06-15 Covestro Deutschland Ag Polyurethanschaumstoffe basierend auf polyethercarbonatpolyolen
EP3178858A1 (de) 2015-12-09 2017-06-14 Covestro Deutschland AG Polyurethanschaumstoffe basierend auf polyethercarbonatpolyolen
US9562135B1 (en) 2015-12-21 2017-02-07 Covestro Llc Polyether carbonates by DMC catalysis
EP3219741A1 (de) 2016-03-18 2017-09-20 Covestro Deutschland AG Verfahren zur herstellung von polyethercarbonatpolyolen
US9994506B2 (en) 2016-04-20 2018-06-12 Covestro Llc Process for transitioning reactors from base-catalyzed polyol production to DMC-catalyzed polyol production
US11312811B2 (en) 2016-04-26 2022-04-26 Covestro Llc Flexible foam using polymer polyols produced via DMC catalyzed polyols
KR20190008212A (ko) 2016-05-13 2019-01-23 코베스트로 도이칠란트 아게 폴리옥시알킬렌 폴리올의 제조 방법
JP2019523311A (ja) 2016-05-20 2019-08-22 ステパン カンパニー 洗濯洗剤のためのポリエーテルアミン組成物
EP3260483A1 (de) 2016-06-22 2017-12-27 Covestro Deutschland AG Verfahren zur herstellung von polyethercarbonatpolyolen
CN106084197A (zh) * 2016-06-22 2016-11-09 青神鑫统领建材有限公司 一种窄分布聚醚的制备方法
US10119223B2 (en) 2016-07-15 2018-11-06 Covestro Llc Carpet and synthetic turf backings prepared from a polyether carbonate polyol
US10258953B2 (en) 2016-08-05 2019-04-16 Covestro Llc Systems and processes for producing polyether polyols
US11098153B2 (en) 2016-10-12 2021-08-24 Covestro Deutschland Ag Method for producing a multiple bond-containing prepolymer as elastomer precursor
CN109790276B (zh) 2016-10-12 2022-06-10 科思创德国股份有限公司 制备弹性体的方法
EP3330308A1 (de) 2016-12-05 2018-06-06 Covestro Deutschland AG Verfahren zur herstellung von tdi-basierten polyurethanweichschaumstoffen enthaltend organische säureanhydride und/oder organische säurechloride
EP3330307A1 (de) 2016-12-05 2018-06-06 Covestro Deutschland AG Verwendung von acrylsäureestern und amiden zur erniedrigung von emissionen eines polyurethanschaumstoffes
EP3336130A1 (de) 2016-12-19 2018-06-20 Covestro Deutschland AG Verfahren zur herstellung von polyetherthiocarbonatpolyolen
EP3336137A1 (de) 2016-12-19 2018-06-20 Covestro Deutschland AG Verwendung von physikalischen treibmitteln zur erzeugung von polyethercarbonatpolyol-basierten polyurethanschaumstoffen mit reduzierter emission von cyclischem propylencarbonat
EP3336115A1 (de) 2016-12-19 2018-06-20 Covestro Deutschland AG Verfahren zur erniedrigung von emissionen eines polyurethanschaumstoffes
GB201703324D0 (en) 2017-03-01 2017-04-12 Econic Tech Ltd Method for preparing polyether carbonates
WO2018169833A1 (en) 2017-03-15 2018-09-20 Covestro Llc Viscoelastic polyurethane foams with reduced temperature sensitivity
EP3385295A1 (de) 2017-04-05 2018-10-10 Covestro Deutschland AG Flammgeschützte phosphorfunktionelle polyethercarbonatpolyole und verfahren zu deren herstellung
EP3409704A1 (de) 2017-06-01 2018-12-05 Covestro Deutschland AG Polyurethanschaumstoffe basierend auf polyethercarbonatpolyolen
EP3424967A1 (de) 2017-07-07 2019-01-09 Covestro Deutschland AG Verfahren zur herstellung von funktionalisierten polyoxyalkylenpolyolen
JP6948057B2 (ja) * 2017-08-30 2021-10-13 公立大学法人大阪 有機リン化合物分解触媒
CN107474237A (zh) * 2017-09-05 2017-12-15 句容宁武新材料股份有限公司 一种通过三元复合催化剂合成聚醚多元醇的方法
EP3461852A1 (de) 2017-09-28 2019-04-03 Covestro Deutschland AG Verfahren zur herstellung eines mehrfachbindungen enthaltenden polymers als elastomer-vorstufe
AU2018346935A1 (en) 2017-10-10 2020-04-16 Stepan Company Polymeric dispersants from aralkylated phenols
KR20240137722A (ko) 2017-10-10 2024-09-20 스테판 컴파니 페닐 글리시딜 에테르로부터의 중합체 분산제
CN111201264A (zh) 2017-10-18 2020-05-26 科思创德国股份有限公司 二嵌段共聚物及其作为表面活性剂的用途
EP3473658A1 (de) 2017-10-18 2019-04-24 Covestro Deutschland AG Diblockcopolymere und deren verwendung als tenside
GB201717459D0 (en) 2017-10-24 2017-12-06 Econic Tech Limited Methods for forming polycarbonate ether polyols and high molecular weight polyether carbonates
GB201717441D0 (en) 2017-10-24 2017-12-06 Econic Tech Ltd A polymerisation process
US20190119444A1 (en) 2017-10-25 2019-04-25 Covestro Llc Process to remove dmc catalysts from polyether carbonate polyols
US10766998B2 (en) 2017-11-21 2020-09-08 Covestro Llc Flexible polyurethane foams
EP3489278A1 (de) 2017-11-23 2019-05-29 Covestro Deutschland AG Hochmolekulare polyoxyalkylene mit tiefer glastemperatur hergestellt nach der grafting-through-methode
EP3502162A1 (de) 2017-12-19 2019-06-26 Covestro Deutschland AG Verfahren zur herstellung von polyetheresterpolyolen
US11602740B2 (en) 2017-12-19 2023-03-14 Oriental Union Chemical Corp. High-activity double-metal-cyanide catalyst
US11919844B2 (en) 2017-12-19 2024-03-05 Oriental Union Chemical Corp. Method for fabricating polyols
US20190185399A1 (en) 2017-12-19 2019-06-20 Oriental Union Chemical Corp. High-activity double-metal-cyanide catalyst, method for fabricating the same, and applications of the same
EP3527606A1 (de) 2018-02-16 2019-08-21 Covestro Deutschland AG Verfahren zur herstellung von polyethercarbonatpolyolen
EP3533815A1 (de) 2018-02-28 2019-09-04 Covestro Deutschland AG Polyurethanweichschaumstoffe auf basis von polyoxymethylen-polyoxyalkylen-blockcopolymeren
EP3762441B1 (de) 2018-03-07 2022-04-13 Covestro Intellectual Property GmbH & Co. KG Polyurethanschaumstoffe basierend auf polyethercarbonatpolyolen
EP3536727A1 (de) 2018-03-07 2019-09-11 Covestro Deutschland AG Polyurethanschaumstoffe basierend auf polyethercarbonatpolyolen
EP3543268A1 (de) 2018-03-22 2019-09-25 Covestro Deutschland AG Verfahren zur herstellung von polyurethanweichschaumstoffen
CN111954689A (zh) 2018-03-22 2020-11-17 科思创知识产权两合公司 制备具有高的粗密度的聚氨酯软质泡沫材料的方法
EP3549969A1 (de) 2018-04-06 2019-10-09 Covestro Deutschland AG Polyurethanschaumstoffe basierend auf polyethercarbonatpolyolen
CN112004862A (zh) 2018-04-25 2020-11-27 汉高股份有限及两合公司 用于制备羟基官能化聚醚-聚硅氧烷嵌段共聚物的方法
EP3567067A1 (de) 2018-05-08 2019-11-13 Covestro Deutschland AG Abtrennung von doppelmetallcyanid-katalysator
KR20210020916A (ko) * 2018-06-19 2021-02-24 헨켈 아게 운트 코. 카게아아 고 활성 이중 금속 시아나이드 화합물
EP3587469A1 (de) 2018-06-22 2020-01-01 Covestro Deutschland AG Verfahren zur herstellung von polyol
EP3597690A1 (de) 2018-07-19 2020-01-22 Covestro Deutschland AG Heterocyclen-funktionelle polyether oder polyethercarbonate und verfahren zu deren herstellung
EP3604320A1 (de) 2018-08-01 2020-02-05 Covestro Deutschland AG Phosphorfunktionelle polyoxyalkylenpolyole und verfahren zu deren herstellung
EP3608348A1 (de) 2018-08-07 2020-02-12 Covestro Deutschland AG Verfahren zur herstellung eines organooxysilyl-vernetzten polymers
EP3608018A1 (de) 2018-08-08 2020-02-12 Covestro Deutschland AG Verfahren zur herstellung von doppelmetallcyanid-katalysatoren
EP3617248A1 (de) 2018-08-30 2020-03-04 Covestro Deutschland AG Verfahren zur abtrennung von gasförmigen bestandteilen
RU2677659C1 (ru) * 2018-09-03 2019-01-18 Публичное Акционерное Общество "Нижнекамскнефтехим" Способ получения твердого двойного кобальтцианидного катализатора полимеризации пропиленоксида
RU2687105C1 (ru) * 2018-09-03 2019-05-07 Публичное Акционерное Общество "Нижнекамскнефтехим" Способ получения простого полиэфира с высокой молекулярной массой на основе пропиленоксида на двойном кобальтцианидном катализаторе
GB201814526D0 (en) 2018-09-06 2018-10-24 Econic Tech Ltd Methods for forming polycarbonate ether polyols and high molecular weight polyether carbonates
US10793692B2 (en) 2018-10-24 2020-10-06 Covestro Llc Viscoelastic flexible foams comprising hydroxyl-terminated prepolymers
EP3643730A1 (de) 2018-10-26 2020-04-29 Covestro Deutschland AG Verfahren zur herstellung von polyoxymethylen-polyoxyalkylen-blockcopolymeren
EP3656797A1 (de) 2018-11-22 2020-05-27 Covestro Deutschland AG Verfahren zur herstellung von polyoxymethylen-polyalkylenoxid-blockcopolymeren
PL3663372T3 (pl) 2018-12-06 2024-07-01 Henkel Ag & Co. Kgaa Utwardzalna kompozycja zawierająca kopolimery szczotkowe polisiloksan-poli(glikol alkilenowy)
EP3663371B1 (en) 2018-12-06 2024-03-13 Henkel AG & Co. KGaA Preparation of polysiloxane polyalkyleneglycol brush copolymers
US10723829B2 (en) 2018-12-19 2020-07-28 Covestro Llc Product-to-product process for preparation of low viscosity polyoxyalkylene polyols
US10738155B2 (en) 2018-12-19 2020-08-11 Covestro Llc Product-to-product process for preparation of low viscosity polyoxyalkylene polyols
US10961347B2 (en) 2018-12-19 2021-03-30 Covestro Llc Process for preparing polyoxyalkylene polyols by the continuous addition of starter
EP3670557A1 (de) 2018-12-21 2020-06-24 Covestro Deutschland AG Verfahren zur herstellung eines polyoxyalkylenpolyesterpolyols
EP3670571A1 (de) 2018-12-21 2020-06-24 Covestro Deutschland AG Verfahren zur herstellung eines polyester-polyetherpolyol-blockcopolymers
EP3670568A1 (de) 2018-12-21 2020-06-24 Covestro Deutschland AG Verfahren zur herstellung eines polyesters
EP3683251A1 (de) 2019-01-15 2020-07-22 Covestro Deutschland AG Verfahren zur herstellung von diol
WO2020173568A1 (de) 2019-02-28 2020-09-03 Covestro Intellectual Property Gmbh & Co. Kg Isocyanat-terminierte prepolymere für die herstellung von polyurethan-integral-schaumstoffen
US20220177403A1 (en) 2019-03-08 2022-06-09 Stepan Company Reactive surfactants
US10544158B1 (en) 2019-03-14 2020-01-28 Covestro Llc Process for producing polycyclic polyether polyols
US10723830B1 (en) 2019-03-28 2020-07-28 Covestro Llc Product-to-product process for preparation of low viscosity polyoxyalkylene polyether polyols
GB201906214D0 (en) 2019-05-02 2019-06-19 Econic Tech Ltd A polyol block copolymer, compositions and processes therefor
GB201906210D0 (en) 2019-05-02 2019-06-19 Econic Tech Limited A polyol block copolymer, compositions and processes therefor
EP3741788A1 (de) 2019-05-24 2020-11-25 Covestro Deutschland AG Verfahren zur herstellung von polyoxyalkylenpolyol-mischungen
EP3747927A1 (de) * 2019-06-05 2020-12-09 Covestro Deutschland AG Verfahren zur kontinuierlichen herstellung von polyoxyalkylenpolyolen
WO2020249433A1 (de) 2019-06-11 2020-12-17 Covestro Deutschland Ag Verfahren zur herstellung von polyethercarbonatpolyolen
EP3750940A1 (de) 2019-06-11 2020-12-16 Covestro Deutschland AG Verfahren zur herstellung von polyethercarbonatpolyolen
EP3760663A1 (de) 2019-07-05 2021-01-06 Covestro Deutschland AG Verfahren zur herstellung von polyetherestercarbonatpolyolen
EP3763768A1 (de) 2019-07-12 2021-01-13 Covestro Deutschland AG Polyethercarbonatpolyole mit enger segmentlängenverteilung
EP3771724A1 (de) 2019-07-31 2021-02-03 Covestro Deutschland AG Verfahren zur herstellung von polyethercarbonatpolyolen
US20220315698A1 (en) 2019-07-31 2022-10-06 Covestro Deutschland Ag Method for producing polyether carbonate polyols
US20240025094A1 (en) 2019-10-09 2024-01-25 Covestro Llc Methods, systems and computer program products for producing polyurethane foam products using optical and infrared imaging
CN114729114A (zh) 2019-12-04 2022-07-08 科思创知识产权两合公司 制备聚醚碳酸酯多元醇的方法
EP3831867A1 (de) 2019-12-04 2021-06-09 Covestro Deutschland AG Verfahren zur herstellung von polyethercarbonatpolyolen
EP3838963A1 (de) 2019-12-17 2021-06-23 Covestro Deutschland AG Verfahren zur herstellung von polyoxyalkylenpolyesterpolyolen
EP3838964A1 (de) 2019-12-18 2021-06-23 Covestro Deutschland AG Polyurethanschaumstoffe basierend auf polyethercarbonatpolyolen
EP3838938A1 (de) 2019-12-18 2021-06-23 Covestro Deutschland AG Verfahren zur herstellung von polyoxymethylen-polyoxyalkylen-copolymeren
KR102395484B1 (ko) * 2020-01-03 2022-05-06 부산대학교 산학협력단 이중금속시안염 촉매, 이의 제조방법 및 폴리올 제조 방법
WO2021148272A1 (de) 2020-01-21 2021-07-29 Covestro Deutschland Ag Verfahren zur herstellung von doppelmetallcyanid-katalysatoren
US20210238361A1 (en) 2020-01-30 2021-08-05 Evonik Operations Gmbh Process for producing high-purity hydrosilylation products
MX2022009296A (es) * 2020-01-31 2022-08-15 Dow Global Technologies Llc Proceso de separacion de catalizadores.
US20230046210A1 (en) 2020-02-22 2023-02-16 Covestro Deutschland Ag Process for preparing double metal cyanide catalysts
GB202003003D0 (en) 2020-03-02 2020-04-15 Econic Tech Ltd A polyol block copolymer
GB202003002D0 (en) 2020-03-02 2020-04-15 Crane Ltd Method of preparation of a polyol block copolymer
EP3878885A1 (de) 2020-03-10 2021-09-15 Covestro Deutschland AG Verfahren zur herstellung von polyethercarbonatpolyolen
EP3882297A1 (de) 2020-03-17 2021-09-22 Covestro Deutschland AG Verfahren zur herstellung von polyethercarbonatpolyolen
EP3885390A1 (de) 2020-03-25 2021-09-29 Covestro Deutschland AG Verfahren zur herstellung eines etheresterols
EP3889204A1 (de) 2020-04-02 2021-10-06 Covestro Deutschland AG Verfahren zur herstellung eines polyoxyalkylencarbonatpolyols
EP3892660A1 (de) 2020-04-08 2021-10-13 Covestro Deutschland AG Polyurethanschaumstoffe basierend auf polyethercarbonatpolyolen
EP3916055A1 (de) 2020-05-26 2021-12-01 Covestro Deutschland AG Polycarbonat-zusammensetzungen enthaltend polyethercarbonatpolyole
EP3922660A1 (de) 2020-06-08 2021-12-15 Covestro Deutschland AG Verfahren zur herstellung von polyethercarbonatpolyolen
EP3922659A1 (de) 2020-06-08 2021-12-15 Covestro Deutschland AG Verfahren zur herstellung von polyethercarbonatpolyolen
EP3922661A1 (de) 2020-06-12 2021-12-15 Covestro Deutschland AG Verfahren zur herstellung von polyoxymethylen-polyoxyalkylen-copolymeren
EP3932973A1 (en) 2020-07-01 2022-01-05 Henkel AG & Co. KGaA Bi-functionalized polysiloxane brush copolymers
EP3960783A1 (de) 2020-09-01 2022-03-02 Covestro Deutschland AG Isocyanat-terminierte prepolymere auf basis von polyoxymethylen-polyoxyalkylen-blockcopolymeren, verfahren zur deren herstellung und deren verwendung
EP3988600A1 (de) 2020-10-20 2022-04-27 Covestro Deutschland AG Verfahren zur herstellung von polyethercarbonatalkoholen
CN112321815B (zh) * 2020-10-28 2022-09-16 中国石油化工股份有限公司 一种低气味高活性聚醚多元醇的制备方法
GB202017531D0 (en) 2020-11-05 2020-12-23 Econic Tech Limited (poly)ol block copolymer
WO2022096390A1 (de) 2020-11-06 2022-05-12 Covestro Deutschland Ag Verfahren zur herstellung eines polyol-gemisches
US11898007B2 (en) 2021-02-12 2024-02-13 Council Of Scientific & Industrial Research Double metal cyanide catalyst for the production of polyether polyols and a process thereof
US11572433B2 (en) 2021-03-12 2023-02-07 Covestro Llc In-situ formed polyols, a process for their preparation, foams prepared from these in-situ formed polyols and a process for their preparation
WO2022189318A1 (de) 2021-03-12 2022-09-15 Covestro Deutschland Ag Verfahren zur aufreinigung von cyclischen carbonaten
US11866543B2 (en) 2021-05-06 2024-01-09 Covestro Llc Glycidyl (meth)acrylate polymer polyol stabilizers
EP4089127A1 (en) 2021-05-12 2022-11-16 Covestro Deutschland AG Cast polyurethane elastomers and production thereof
WO2022258570A1 (de) 2021-06-10 2022-12-15 Covestro Deutschland Ag Verfahren zur herstellung von polyoxymethylen-polyoxyalkylen-copolymeren
EP4101873A1 (de) 2021-06-11 2022-12-14 Covestro Deutschland AG Einsatz von bismut-katalysatoren zur verringerung von cyclischem propylencarbonat bei der herstellung von weichschaumstoffen basierend auf polyethercarbonatpolyolen
EP4112674A1 (de) 2021-06-30 2023-01-04 Evonik Operations GmbH Verfahren zur herstellung hochreiner hydrosilylierungsprodukte
US11718705B2 (en) 2021-07-28 2023-08-08 Covestro Llc In-situ formed polyether polyols, a process for their preparation, and a process for the preparation of polyurethane foams
US20230039276A1 (en) 2021-07-28 2023-02-09 Covestro Llc Novel polyether polyol blends, a process for their preparation, foams prepared from these polyether polyol blends and a process for their preparation
MX2024001871A (es) 2021-08-11 2024-03-04 Econic Tech Ltd Metodo para preparar tensoactivos mediante copolimerizacion de epoxidos y co2 utilizando una mezcla de un catalizador bimetalico macrociclico y un catalizador de cianuro bimetalico.
EP4151669A1 (de) 2021-09-15 2023-03-22 Covestro Deutschland AG Verfahren zur herstellung von polyethercarbonatpolyolen
CN118159578A (zh) 2021-10-07 2024-06-07 科思创德国股份有限公司 制备聚氧化烯聚酯多元醇的方法
US11952454B2 (en) 2021-10-18 2024-04-09 Covestro Llc Processes and production plants for producing polymer polyols
GB202115335D0 (en) 2021-10-25 2021-12-08 Econic Tech Ltd Surface-active agent
US20230147479A1 (en) 2021-11-05 2023-05-11 Covestro Llc Processes and production plants for producing polyols
EP4194476A1 (de) 2021-12-07 2023-06-14 Covestro Deutschland AG Polyurethanschaumstoffe basierend auf polyethercarbonatpolyolen
EP4444778A1 (en) 2021-12-08 2024-10-16 Covestro Deutschland AG Polyurethane elastomer with improved hydrolysis resistance
EP4219579A1 (de) 2022-01-28 2023-08-02 Covestro Deutschland AG Herstellung von aliphatischen polyurethan-weichschaumstoffe in einem präpolymerverfahren basierend auf aliphatischen oligomeren polyisocyanaten und monohydroxyfunktionellen verbindungen
WO2023144058A1 (de) 2022-01-28 2023-08-03 Covestro Deutschland Ag Herstellung von aliphatischen polyurethan-weichschaumstoffen mit verkürzten abbindezeiten (klebfreizeiten) und steigzeiten
EP4219578A1 (de) 2022-01-28 2023-08-02 Covestro Deutschland AG Herstellung von aliphatischen polyurethan-weichschaumstoffe in einem präpolymerverfahren basierend auf aliphatischen oligomeren polyisocyanaten und monohydroxyfunktionellen verbindungen
EP4219576A1 (de) 2022-01-28 2023-08-02 Covestro Deutschland AG Herstellung von aliphatischen polyurethan-polyisocyanuratschaumstoffen (pur-pir) unter verwendung eines katalysatorgemischs aus salzen organischer carbonsäuren und 1,1,3,3-tetraalkylguanidinen
EP4273185A1 (en) 2022-05-04 2023-11-08 PCC Rokita SA Method for the manufacture of a polyether diol product
EP4279534A1 (en) 2022-05-20 2023-11-22 PCC ROKITA Spolka Akcyjna A method for producing low unsaturation level oxyalkylates, an oxyalkylate, a use thereof and a polyurethane foam
EP4302874A1 (de) 2022-07-04 2024-01-10 Covestro Deutschland AG Verfahren zur herstellung von doppelmetallcyanid-katalysatoren
CN115710164B (zh) * 2022-12-26 2024-08-23 常州大学 一种异壬醇聚氧乙烯醚的制备方法及其应用方法
CN116217913A (zh) * 2022-12-29 2023-06-06 杭州普力材料科技有限公司 一种三配体双金属络合物催化剂及其制备方法
EP4397691A1 (de) 2023-01-06 2024-07-10 Covestro Deutschland AG Verfahren zur herstellung eines polyoxyalkylenpolyols
GB2626546A (en) 2023-01-25 2024-07-31 Econic Tech Ltd Surface-active agent
GB2626989A (en) 2023-02-10 2024-08-14 Econic Tech Ltd Surface-active agent

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3427256A (en) * 1963-02-14 1969-02-11 Gen Tire & Rubber Co Double metal cyanide complex compounds
US3278459A (en) * 1963-02-14 1966-10-11 Gen Tire & Rubber Co Method of making a polyether using a double metal cyanide complex compound
US3278458A (en) * 1963-02-14 1966-10-11 Gen Tire & Rubber Co Method of making a polyether using a double metal cyanide complex compound
US3427334A (en) * 1963-02-14 1969-02-11 Gen Tire & Rubber Co Double metal cyanides complexed with an alcohol aldehyde or ketone to increase catalytic activity
US3829505A (en) * 1970-02-24 1974-08-13 Gen Tire & Rubber Co Polyethers and method for making the same
CA1155871A (en) * 1980-10-16 1983-10-25 Gencorp Inc. Method for treating polypropylene ether and poly-1,2- butylene ether polyols
AU551979B2 (en) * 1982-03-31 1986-05-15 Shell Internationale Research Maatschappij B.V. Epoxy polymerisation catalysts
US4877906A (en) * 1988-11-25 1989-10-31 Arco Chemical Technology, Inc. Purification of polyols prepared using double metal cyanide complex catalysts
US5010047A (en) * 1989-02-27 1991-04-23 Arco Chemical Technology, Inc. Recovery of double metal cyanide complex catalyst from a polymer
JPH03149222A (ja) 1989-11-07 1991-06-25 Asahi Glass Co Ltd ポリエーテル化合物の製造方法
JP2960460B2 (ja) * 1990-03-06 1999-10-06 旭硝子株式会社 ポリエーテル類の製造方法
JPH03281529A (ja) 1990-03-29 1991-12-12 Asahi Glass Co Ltd ポリエーテル化合物の製造方法
JP2595766B2 (ja) * 1990-05-25 1997-04-02 旭硝子株式会社 ポリオキシアルキレンアルコールの製造方法
JP2653236B2 (ja) * 1990-10-05 1997-09-17 旭硝子株式会社 ポリエーテル化合物の製造方法
JPH04314728A (ja) * 1991-04-12 1992-11-05 Asahi Glass Co Ltd ポリエーテル類の製造方法
US5158922A (en) * 1992-02-04 1992-10-27 Arco Chemical Technology, L.P. Process for preparing metal cyanide complex catalyst
US5248833A (en) * 1992-09-22 1993-09-28 Arco Chemical Technology, L.P. Process for purifying polyols made with double metal cyanide catalysts
CA2138063C (en) * 1993-12-23 2007-02-20 Bi Le-Khac Polyurethane foam-supported double metal cyanide catalysts for polyol synthesis

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AU3048795A (en) 1996-03-21
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KR100355336B1 (ko) 2003-01-24
EP0700949B1 (en) 1999-03-03
HU215551B (hu) 1999-01-28
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US5536883A (en) 1996-07-16
TW401429B (en) 2000-08-11
CA2157312C (en) 2008-02-19
JPH08104741A (ja) 1996-04-23
KR960010719A (ko) 1996-04-20
CN1133300A (zh) 1996-10-16
DE69508009D1 (de) 1999-04-08
HU9502619D0 (en) 1995-10-30
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CA2157312A1 (en) 1996-03-09
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EP0700949A2 (en) 1996-03-13
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DE69508009T2 (de) 1999-08-12
HUT73052A (en) 1996-06-28

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