SK282300B6 - Iónová zlúčenina katalytických zložiek a kompozícia s jej obsahom - Google Patents
Iónová zlúčenina katalytických zložiek a kompozícia s jej obsahom Download PDFInfo
- Publication number
- SK282300B6 SK282300B6 SK792-99A SK79299A SK282300B6 SK 282300 B6 SK282300 B6 SK 282300B6 SK 79299 A SK79299 A SK 79299A SK 282300 B6 SK282300 B6 SK 282300B6
- Authority
- SK
- Slovakia
- Prior art keywords
- hydrocarbyl
- catalyst
- groups
- group
- compound
- Prior art date
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- 150000008040 ionic compounds Chemical class 0.000 title claims abstract description 67
- 239000000203 mixture Substances 0.000 title claims description 90
- 239000003054 catalyst Substances 0.000 title abstract description 184
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract description 74
- 150000001450 anions Chemical class 0.000 claims abstract description 61
- 229910052751 metal Inorganic materials 0.000 claims abstract description 58
- 239000002184 metal Substances 0.000 claims abstract description 58
- 239000003085 diluting agent Substances 0.000 claims abstract description 53
- 239000007787 solid Substances 0.000 claims abstract description 51
- 125000001424 substituent group Chemical group 0.000 claims abstract description 32
- 230000000737 periodic effect Effects 0.000 claims abstract description 29
- 150000003623 transition metal compounds Chemical class 0.000 claims abstract description 29
- 125000002524 organometallic group Chemical group 0.000 claims abstract description 16
- 239000007795 chemical reaction product Substances 0.000 claims abstract description 11
- 125000002091 cationic group Chemical group 0.000 claims abstract description 10
- -1 dihydrocarbylamide Chemical class 0.000 claims description 157
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 110
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 76
- 239000000463 material Substances 0.000 claims description 67
- 229910052739 hydrogen Inorganic materials 0.000 claims description 51
- 239000001257 hydrogen Substances 0.000 claims description 50
- 239000006185 dispersion Substances 0.000 claims description 42
- 150000001875 compounds Chemical class 0.000 claims description 40
- 229910052757 nitrogen Inorganic materials 0.000 claims description 39
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 38
- 150000001768 cations Chemical class 0.000 claims description 37
- 239000012876 carrier material Substances 0.000 claims description 31
- 229910052760 oxygen Inorganic materials 0.000 claims description 29
- 239000001301 oxygen Substances 0.000 claims description 29
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 25
- 229910052717 sulfur Inorganic materials 0.000 claims description 25
- 239000011593 sulfur Substances 0.000 claims description 25
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 24
- 125000000217 alkyl group Chemical group 0.000 claims description 23
- 229910052698 phosphorus Inorganic materials 0.000 claims description 22
- 229930195733 hydrocarbon Natural products 0.000 claims description 18
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 16
- 150000004820 halides Chemical class 0.000 claims description 16
- 239000011574 phosphorus Substances 0.000 claims description 16
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 16
- 239000004215 Carbon black (E152) Substances 0.000 claims description 15
- 230000003197 catalytic effect Effects 0.000 claims description 14
- 239000002879 Lewis base Substances 0.000 claims description 13
- 150000004678 hydrides Chemical class 0.000 claims description 10
- 150000007527 lewis bases Chemical class 0.000 claims description 10
- 125000000538 pentafluorophenyl group Chemical group FC1=C(F)C(F)=C(*)C(F)=C1F 0.000 claims description 10
- 229910000765 intermetallic Inorganic materials 0.000 claims description 8
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- 125000004437 phosphorous atom Chemical group 0.000 claims description 6
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- 239000004480 active ingredient Substances 0.000 claims description 3
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- 239000000243 solution Substances 0.000 description 126
- 238000000034 method Methods 0.000 description 96
- 238000006116 polymerization reaction Methods 0.000 description 86
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- 239000011949 solid catalyst Substances 0.000 description 60
- 230000008569 process Effects 0.000 description 59
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- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 46
- 239000002245 particle Substances 0.000 description 42
- 150000001993 dienes Chemical class 0.000 description 41
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- 239000010936 titanium Substances 0.000 description 33
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- 238000012644 addition polymerization Methods 0.000 description 20
- 150000001336 alkenes Chemical class 0.000 description 18
- 125000004432 carbon atom Chemical group C* 0.000 description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 18
- 238000004519 manufacturing process Methods 0.000 description 17
- 150000002902 organometallic compounds Chemical class 0.000 description 17
- 125000000129 anionic group Chemical group 0.000 description 16
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- 229910052782 aluminium Inorganic materials 0.000 description 14
- 238000009826 distribution Methods 0.000 description 14
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- 239000002002 slurry Substances 0.000 description 14
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- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 12
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 12
- 239000003795 chemical substances by application Substances 0.000 description 12
- 230000007935 neutral effect Effects 0.000 description 12
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 11
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 11
- 229910052796 boron Inorganic materials 0.000 description 11
- 238000001816 cooling Methods 0.000 description 11
- 230000000694 effects Effects 0.000 description 11
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- 229910052723 transition metal Inorganic materials 0.000 description 10
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 9
- 230000015572 biosynthetic process Effects 0.000 description 9
- 229920001577 copolymer Polymers 0.000 description 9
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 9
- 150000003624 transition metals Chemical class 0.000 description 9
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 8
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 8
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 8
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 8
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- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 8
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- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 7
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- 125000003118 aryl group Chemical group 0.000 description 6
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- 125000005842 heteroatom Chemical group 0.000 description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 5
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 5
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 5
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- YWWNNLPSZSEZNZ-UHFFFAOYSA-N n,n-dimethyldecan-1-amine Chemical compound CCCCCCCCCCN(C)C YWWNNLPSZSEZNZ-UHFFFAOYSA-N 0.000 description 1
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- VFLWKHBYVIUAMP-UHFFFAOYSA-N n-methyl-n-octadecyloctadecan-1-amine Chemical compound CCCCCCCCCCCCCCCCCCN(C)CCCCCCCCCCCCCCCCCC VFLWKHBYVIUAMP-UHFFFAOYSA-N 0.000 description 1
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- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- 125000002097 pentamethylcyclopentadienyl group Chemical group 0.000 description 1
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 1
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
- 229930015698 phenylpropene Natural products 0.000 description 1
- FVZVCSNXTFCBQU-UHFFFAOYSA-N phosphanyl Chemical group [PH2] FVZVCSNXTFCBQU-UHFFFAOYSA-N 0.000 description 1
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- 230000000704 physical effect Effects 0.000 description 1
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- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
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- 238000000926 separation method Methods 0.000 description 1
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- SCABQASLNUQUKD-UHFFFAOYSA-N silylium Chemical class [SiH3+] SCABQASLNUQUKD-UHFFFAOYSA-N 0.000 description 1
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- 238000001179 sorption measurement Methods 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-O sulfonium Chemical class [SH3+] RWSOTUBLDIXVET-UHFFFAOYSA-O 0.000 description 1
- 230000008093 supporting effect Effects 0.000 description 1
- 238000001356 surgical procedure Methods 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical class FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- 125000000101 thioether group Chemical group 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- ZCUFMDLYAMJYST-UHFFFAOYSA-N thorium dioxide Chemical compound O=[Th]=O ZCUFMDLYAMJYST-UHFFFAOYSA-N 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- BNOPYGRAXZULSM-UHFFFAOYSA-N tri(tetradecyl)phosphane Chemical compound CCCCCCCCCCCCCCP(CCCCCCCCCCCCCC)CCCCCCCCCCCCCC BNOPYGRAXZULSM-UHFFFAOYSA-N 0.000 description 1
- IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 description 1
- MOSFSEPBWRXKJZ-UHFFFAOYSA-N tridecylphosphane Chemical compound CCCCCCCCCCCCCP MOSFSEPBWRXKJZ-UHFFFAOYSA-N 0.000 description 1
- CXKQHHJKHZXXPZ-UHFFFAOYSA-N triethylsilanylium Chemical compound CC[Si+](CC)CC CXKQHHJKHZXXPZ-UHFFFAOYSA-N 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 1
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 1
- VOYMPSZBODLRKS-UHFFFAOYSA-N trimethylsilanylium Chemical compound C[Si+](C)C VOYMPSZBODLRKS-UHFFFAOYSA-N 0.000 description 1
- 125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- RIOQSEWOXXDEQQ-UHFFFAOYSA-O triphenylphosphanium Chemical compound C1=CC=CC=C1[PH+](C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-O 0.000 description 1
- YFTHZRPMJXBUME-UHFFFAOYSA-N tripropylamine Chemical compound CCCN(CCC)CCC YFTHZRPMJXBUME-UHFFFAOYSA-N 0.000 description 1
- COIOYMYWGDAQPM-UHFFFAOYSA-N tris(2-methylphenyl)phosphane Chemical compound CC1=CC=CC=C1P(C=1C(=CC=CC=1)C)C1=CC=CC=C1C COIOYMYWGDAQPM-UHFFFAOYSA-N 0.000 description 1
- ZWNALNKUTLUDJH-UHFFFAOYSA-N tris(3,4-dimethylphenyl) borate Chemical compound B(OC1=CC(=C(C=C1)C)C)(OC1=CC(=C(C=C1)C)C)OC1=CC(=C(C=C1)C)C ZWNALNKUTLUDJH-UHFFFAOYSA-N 0.000 description 1
- 125000002221 trityl group Chemical group [H]C1=C([H])C([H])=C([H])C([H])=C1C([*])(C1=C(C(=C(C(=C1[H])[H])[H])[H])[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
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- 238000001291 vacuum drying Methods 0.000 description 1
- 238000004260 weight control Methods 0.000 description 1
- 125000005023 xylyl group Chemical group 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61908—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2420/00—Metallocene catalysts
- C08F2420/02—Cp or analog bridged to a non-Cp X anionic donor
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Catalysts (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/768,518 US5783512A (en) | 1996-12-18 | 1996-12-18 | Catalyst component dispersion comprising an ionic compound and solid addition polymerization catalysts containing the same |
| PCT/US1997/021875 WO1998027119A1 (en) | 1996-12-18 | 1997-12-01 | Catalyst component dispersion comprising an ionic compound and solid addition polymerization catalysts containing the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| SK79299A3 SK79299A3 (en) | 2000-01-18 |
| SK282300B6 true SK282300B6 (sk) | 2002-01-07 |
Family
ID=25082729
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SK792-99A SK282300B6 (sk) | 1996-12-18 | 1997-12-01 | Iónová zlúčenina katalytických zložiek a kompozícia s jej obsahom |
Country Status (28)
| Country | Link |
|---|---|
| US (2) | US5783512A (cs) |
| EP (1) | EP0946601B1 (cs) |
| JP (1) | JP2001506691A (cs) |
| KR (1) | KR100520586B1 (cs) |
| CN (1) | CN1283672C (cs) |
| AR (1) | AR010791A1 (cs) |
| AT (1) | ATE224921T1 (cs) |
| AU (1) | AU726483B2 (cs) |
| BR (1) | BR9713776A (cs) |
| CA (1) | CA2271380C (cs) |
| CZ (1) | CZ298647B6 (cs) |
| DE (1) | DE69715907T2 (cs) |
| DZ (1) | DZ2378A1 (cs) |
| EG (1) | EG21570A (cs) |
| ES (1) | ES2180075T3 (cs) |
| HU (1) | HUP0000290A3 (cs) |
| ID (1) | ID22284A (cs) |
| MY (1) | MY117875A (cs) |
| NO (1) | NO320275B1 (cs) |
| NZ (1) | NZ335444A (cs) |
| PL (1) | PL334023A1 (cs) |
| PT (1) | PT946601E (cs) |
| SA (1) | SA98181018B1 (cs) |
| SK (1) | SK282300B6 (cs) |
| TR (1) | TR199901319T2 (cs) |
| TW (1) | TW460493B (cs) |
| WO (1) | WO1998027119A1 (cs) |
| ZA (1) | ZA9711325B (cs) |
Families Citing this family (173)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5384299A (en) * | 1987-01-30 | 1995-01-24 | Exxon Chemical Patents Inc. | Ionic metallocene catalyst compositions |
| US6143686A (en) * | 1994-08-03 | 2000-11-07 | Exxon Chemical Patents, Inc. | Supported ionic catalyst compositions |
| WO1996004319A1 (en) * | 1994-08-03 | 1996-02-15 | Exxon Chemical Patents Inc. | Supported ionic catalyst composition |
| US6228795B1 (en) * | 1997-06-05 | 2001-05-08 | Exxon Chemical Patents, Inc. | Polymeric supported catalysts |
| EP1036097A1 (en) * | 1997-12-01 | 2000-09-20 | Asahi Kasei Kabushiki Kaisha | Olefin polymerization catalyst and method for polymerizing an olefin using the catalyst |
| DE69925114T2 (de) | 1998-03-04 | 2005-10-27 | Exxonmobil Chemical Patents Inc., Baytown | Verfahren zur polymerisation von olefinen bei hohen temperaturen |
| EP1124858A1 (en) * | 1998-09-16 | 2001-08-22 | The Dow Chemical Company | Slurry polymerization process and polymer compositions |
| US6818585B2 (en) * | 1998-12-30 | 2004-11-16 | Univation Technologies, Llc | Catalyst compounds, catalyst systems thereof and their use in a polymerization process |
| US6852811B1 (en) * | 1998-12-30 | 2005-02-08 | The Dow Chemical Company | Process for preparing a supported polymerization catalyst using reduced amounts of solvent and polymerization process |
| BR0010289B1 (pt) * | 1999-05-05 | 2011-01-25 | copolìmeros de etileno, processo para preparar os mesmos, e filmes destes. | |
| GB9918668D0 (en) * | 1999-08-06 | 1999-10-13 | Bp Chem Int Ltd | Polymerisation catalysts |
| BR0016495A (pt) | 1999-12-20 | 2002-09-17 | Exxon Chemical Patents Inc | Processos para a preparação de resinas poliolefìnicas usando catalisadores iÈnicos suportados |
| DE19962910A1 (de) * | 1999-12-23 | 2001-07-05 | Targor Gmbh | Chemische Verbindung, Verfahren zu deren Herstellung und deren Verwendung in Katalysatorsystemen zur Herstellung von Polyolefinen |
| US7041617B2 (en) * | 2004-01-09 | 2006-05-09 | Chevron Phillips Chemical Company, L.P. | Catalyst compositions and polyolefins for extrusion coating applications |
| US6444765B1 (en) * | 2000-06-14 | 2002-09-03 | Equistar Chemicals, Lp | Olefin polymerization process for producing broad MWD polymers |
| GB0017547D0 (en) * | 2000-07-17 | 2000-09-06 | Bp Chem Int Ltd | Supported polymerisation catalysts |
| AU2002211323A1 (en) * | 2000-10-04 | 2002-04-15 | Dow Global Technologies Inc. | Supported catalyst compositions |
| US6943133B2 (en) * | 2000-10-20 | 2005-09-13 | Univation Technologies, Llc | Diene functionalized catalyst supports and supported catalyst compositions |
| US6656866B2 (en) * | 2000-12-04 | 2003-12-02 | Univation Technologies, Llc | Catalyst preparation method |
| CN1518561A (zh) * | 2001-05-04 | 2004-08-04 | 通过使用金属络合物催化剂所制造的无规或嵌段共聚物或三元聚合物 | |
| ATE384086T1 (de) * | 2001-06-15 | 2008-02-15 | Dow Global Technologies Inc | Verzweigte polymere auf alpha-olefin basis |
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| CN114901627B (zh) | 2019-12-30 | 2024-07-02 | 陶氏环球技术有限责任公司 | 用于制备α-取代的丙烯酸酯的方法 |
| KR20220120655A (ko) | 2019-12-30 | 2022-08-30 | 다우 글로벌 테크놀로지스 엘엘씨 | 알파-치환된 아크릴레이트를 제조하는 방법 |
| WO2021242619A1 (en) | 2020-05-27 | 2021-12-02 | Dow Global Technologies Llc | Polymer formulations and irrigation tubing including polymer formulations |
| JP7726977B2 (ja) | 2020-07-17 | 2025-08-20 | ダウ グローバル テクノロジーズ エルエルシー | 拘束幾何プロ触媒のためのヒドロカルビル変性メチルアルミノキサン助触媒 |
| US20230382929A1 (en) | 2020-10-15 | 2023-11-30 | Dow Global Technologies Llc | Olefin polymerization catalysts bearing a 6-amino-n-aryl azaindole ligand |
| AR133003A1 (es) | 2023-06-28 | 2025-08-20 | Dow Global Technologies Llc | Artículos moldeados por soplado |
| WO2025072678A1 (en) | 2023-09-29 | 2025-04-03 | Dow Global Technologies Llc | Process for preparing an olefin-acrylate block copolymer |
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| JP2618384B2 (ja) | 1986-12-27 | 1997-06-11 | 三井石油化学工業株式会社 | オレフイン重合用固体触媒およびその製法 |
| US5064802A (en) * | 1989-09-14 | 1991-11-12 | The Dow Chemical Company | Metal complex compounds |
| DE69033368T3 (de) * | 1990-01-02 | 2008-07-03 | Exxon Chemical Patents, Inc. | Ionische Metallocenkatalysatoren auf Träger für Olefinpolymerisation |
| US5444134A (en) | 1991-07-11 | 1995-08-22 | Idemitsu Kosan Co., Ltd. | Process for producing olefin based polymers and olefin polymerization catalyst |
| DE69222317T2 (de) * | 1991-11-25 | 1998-02-12 | Exxon Chemical Patents, Inc., Baytown, Tex. | Polyionische, uebergangsmetall enthaltende katalysatorzusammensetzung |
| US5296433A (en) * | 1992-04-14 | 1994-03-22 | Minnesota Mining And Manufacturing Company | Tris(pentafluorophenyl)borane complexes and catalysts derived therefrom |
| EP0654050A1 (en) * | 1992-08-05 | 1995-05-24 | Exxon Chemical Patents Inc. | Gas phase polymerization of ethylene and c 7? to c 10? olefins |
| EP1110974B1 (en) * | 1992-08-05 | 2007-11-28 | ExxonMobil Chemical Patents Inc. | Method for preparing a supported activator component |
| ES2136132T3 (es) * | 1992-10-05 | 1999-11-16 | Exxon Chemical Patents Inc | Procedimiento de polimerizacion que emplea un sistema catalizador con productividad mejorada. |
| WO1996004319A1 (en) * | 1994-08-03 | 1996-02-15 | Exxon Chemical Patents Inc. | Supported ionic catalyst composition |
| IT1272939B (it) | 1995-02-01 | 1997-07-01 | Enichem Spa | Catalizzatore metallocenico supportato per la (co)polimerizzazione delle olefine |
| DE69611554T2 (de) * | 1995-02-20 | 2001-07-05 | Tosoh Corp., Shinnanyo | Katalysator für die Polymerisation von Olefinen und Verfahren zur Herstellung von Olefinpolymerisaten |
| TR199700932T1 (xx) * | 1995-03-10 | 1998-01-21 | The Dow Chemical Company | Desteklenmi� kataliz�r bile�eni, desteklenmi� kataliz�r, haz�rlama i�lemi, polimerizasyon i�lemi, kompleks bile�ikler ve bunlar�n haz�rlanmas�. |
| JPH09309926A (ja) * | 1996-05-17 | 1997-12-02 | Dow Chem Co:The | エチレン共重合体の製造方法 |
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| MM4A | Patent lapsed due to non-payment of maintenance fees |
Effective date: 20101201 |