MX2014004782A - Monomeros de beta-dicetona de metileno, metodos para obtener los monomeros de beta-dicetona de metileno; composiciones polimerizables y productos obtenidos a partir de los mismos. - Google Patents

Monomeros de beta-dicetona de metileno, metodos para obtener los monomeros de beta-dicetona de metileno; composiciones polimerizables y productos obtenidos a partir de los mismos.

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Publication number
MX2014004782A
MX2014004782A MX2014004782A MX2014004782A MX2014004782A MX 2014004782 A MX2014004782 A MX 2014004782A MX 2014004782 A MX2014004782 A MX 2014004782A MX 2014004782 A MX2014004782 A MX 2014004782A MX 2014004782 A MX2014004782 A MX 2014004782A
Authority
MX
Mexico
Prior art keywords
diketone
beta
methylene beta
monomers
products formed
Prior art date
Application number
MX2014004782A
Other languages
English (en)
Other versions
MX360462B (es
Inventor
Jeffrey M Sullivan
Bernard Miles Malofsky
Adam Gregg Malofsky
Tanmoy Dey
Original Assignee
Sirrus Inc
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Filing date
Publication date
Application filed by Sirrus Inc filed Critical Sirrus Inc
Publication of MX2014004782A publication Critical patent/MX2014004782A/es
Publication of MX360462B publication Critical patent/MX360462B/es

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    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
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    • C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04—Homopolymers or copolymers of esters
    • C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
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    • C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04—Homopolymers or copolymers of esters
    • C09J133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
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    • C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04—Homopolymers or copolymers of esters
    • C09J133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
    • C09J133/16—Homopolymers or copolymers of esters containing halogen atoms
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    • C09J135/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least another carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J135/02—Homopolymers or copolymers of esters
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    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
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    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency

Abstract

La presente invención proporciona monómeros de beta-dicetona de metileno, métodos para producir los mismos, y composiciones y productos formados a partir de los mismos. En el método para producir las beta-dicetonas de metileno de la invención, una beta-dicetona se hace reaccionar con una fuente de formaldehido en un reacción modificada de Knoevenagel opcionalmente en presencia de un catalizador ácido o básico, y opcionalmente en presencia de un disolvente acido o no ácido, para formar un complejo de reacción. El complejo de reacción puede ser un complejo oligomérico. El complejo de reacción es sometido a procesamiento adicional, que puede ser vaporización por contacto con medios de transferencia de energía con el objeto de aislar el monómero de beta-dicetona. Los productos y composiciones adicionales de la presente invención formados a partir de monómeros de beta-dicetona de metileno, incluyen productos basados en monómeros (por ejemplo tintas, adhesivos, recubrimientos, selladores o productos de moldeo reactivos) y productos con base en polímeros (por ejemplo fibras, películas, hojas, polímeros médicos, polímeros compuestos y agentes tensoactivos).
MX2014004782A 2011-10-19 2012-10-18 Monomeros de metileno beta-dicetona, procedimientos de preparacion de monomeros de metileno beta-dicetona, composiciones polimerizables y productos formados a partir de ellos. MX360462B (es)

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MX2014004781A MX360463B (es) 2011-10-19 2012-10-18 Monomeros de beta-cetoester de metileno, procedimientos de fabricación de monomeros de beta-cetoester de metileno, composiciones polimerizables y productos formados a partir de las mismas.
MX2014004782A MX360462B (es) 2011-10-19 2012-10-18 Monomeros de metileno beta-dicetona, procedimientos de preparacion de monomeros de metileno beta-dicetona, composiciones polimerizables y productos formados a partir de ellos.

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