MX360463B - Monomeros de beta-cetoester de metileno, procedimientos de fabricación de monomeros de beta-cetoester de metileno, composiciones polimerizables y productos formados a partir de las mismas. - Google Patents

Monomeros de beta-cetoester de metileno, procedimientos de fabricación de monomeros de beta-cetoester de metileno, composiciones polimerizables y productos formados a partir de las mismas.

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Publication number
MX360463B
MX360463B MX2014004781A MX2014004781A MX360463B MX 360463 B MX360463 B MX 360463B MX 2014004781 A MX2014004781 A MX 2014004781A MX 2014004781 A MX2014004781 A MX 2014004781A MX 360463 B MX360463 B MX 360463B
Authority
MX
Mexico
Prior art keywords
ketoester
beta
methylene beta
ketoester monomers
products formed
Prior art date
Application number
MX2014004781A
Other languages
English (en)
Other versions
MX2014004781A (es
Inventor
Jeffrey M Sullivan
Bernard Miles Malofsky
Adam Gregg Malofsky
Tanmoy Dey
Original Assignee
Sirrus Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sirrus Inc filed Critical Sirrus Inc
Publication of MX2014004781A publication Critical patent/MX2014004781A/es
Publication of MX360463B publication Critical patent/MX360463B/es

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    • C09J133/04—Homopolymers or copolymers of esters
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Abstract

La presente invención proporciona monómeros de beta-cetoésteres de metileno, métodos para producir los mismos, y composiciones y productos formados a partir de los mismos. En el método para producir las beta-cetoésteres de metileno de la invención, un beta-cetoéster se hace reaccionar con una fuente de formaldehido en un reacción modificada de Knoevenagel opcionalmente en presencia de un catalizador ácido o básico, y opcionalmente en presencia de un disolvente acido o no ácido, para formar un complejo de reacción. El complejo de reacción puede ser un complejo oligomérico. El complejo de reacción es sometido a procesamiento adicional, que puede ser vaporización por contacto con medios de transferencia de energía con el objeto de aislar el monómero de beta-cetoéster. Los productos y composiciones adicionales de la presente invención formados a partir de monómeros de beta-cetoésteres de metileno, incluyen productos basados en monómeros (por ejemplo tintas, adhesivos, recubrimientos, selladores o productos de moldeo reactivos) y productos con base en polímeros (por ejemplo fibras, películas, hojas, polímeros médicos, polímeros compuestos y agentes tensoactivos).
MX2014004781A 2011-10-19 2012-10-18 Monomeros de beta-cetoester de metileno, procedimientos de fabricación de monomeros de beta-cetoester de metileno, composiciones polimerizables y productos formados a partir de las mismas. MX360463B (es)

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US201161549104P 2011-10-19 2011-10-19
US201161549152P 2011-10-19 2011-10-19
US201161549092P 2011-10-19 2011-10-19
PCT/US2012/060837 WO2013066629A1 (en) 2011-10-19 2012-10-18 Methylene beta-ketoester monomers, methods for making methylene beta-ketoester monomers, polymerizable compositions and products formed therefrom

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MX2014004780A MX370256B (es) 2011-10-19 2012-10-18 Monomeros multifuncionales, procedimientos para la preparación de monomeros multifuncionales, composiciones polimerizables y productos formados a partir de los mismos.
MX2014004782A MX360462B (es) 2011-10-19 2012-10-18 Monomeros de metileno beta-dicetona, procedimientos de preparacion de monomeros de metileno beta-dicetona, composiciones polimerizables y productos formados a partir de ellos.
MX2014004781A MX360463B (es) 2011-10-19 2012-10-18 Monomeros de beta-cetoester de metileno, procedimientos de fabricación de monomeros de beta-cetoester de metileno, composiciones polimerizables y productos formados a partir de las mismas.

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MX2014004782A MX360462B (es) 2011-10-19 2012-10-18 Monomeros de metileno beta-dicetona, procedimientos de preparacion de monomeros de metileno beta-dicetona, composiciones polimerizables y productos formados a partir de ellos.

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