KR20150041755A - Method for forming ti-containing film by peald using tdmat or tdeat - Google Patents
Method for forming ti-containing film by peald using tdmat or tdeat Download PDFInfo
- Publication number
- KR20150041755A KR20150041755A KR20140136089A KR20140136089A KR20150041755A KR 20150041755 A KR20150041755 A KR 20150041755A KR 20140136089 A KR20140136089 A KR 20140136089A KR 20140136089 A KR20140136089 A KR 20140136089A KR 20150041755 A KR20150041755 A KR 20150041755A
- Authority
- KR
- South Korea
- Prior art keywords
- film
- gas
- oxygen
- films
- power
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 73
- 239000010936 titanium Substances 0.000 claims abstract description 50
- 239000000758 substrate Substances 0.000 claims abstract description 24
- 238000006243 chemical reaction Methods 0.000 claims abstract description 23
- 230000008021 deposition Effects 0.000 claims abstract description 4
- 239000012495 reaction gas Substances 0.000 claims abstract 5
- 239000007789 gas Substances 0.000 claims description 86
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 70
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 49
- 239000000376 reactant Substances 0.000 claims description 41
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 39
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 37
- 229910052799 carbon Inorganic materials 0.000 claims description 37
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 35
- 229910052760 oxygen Inorganic materials 0.000 claims description 29
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 28
- 239000001301 oxygen Substances 0.000 claims description 28
- 239000013078 crystal Substances 0.000 claims description 27
- MNWRORMXBIWXCI-UHFFFAOYSA-N tetrakis(dimethylamido)titanium Chemical compound CN(C)[Ti](N(C)C)(N(C)C)N(C)C MNWRORMXBIWXCI-UHFFFAOYSA-N 0.000 claims description 27
- 229910052757 nitrogen Inorganic materials 0.000 claims description 22
- 229910010282 TiON Inorganic materials 0.000 claims description 19
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 19
- VJDVOZLYDLHLSM-UHFFFAOYSA-N diethylazanide;titanium(4+) Chemical compound [Ti+4].CC[N-]CC.CC[N-]CC.CC[N-]CC.CC[N-]CC VJDVOZLYDLHLSM-UHFFFAOYSA-N 0.000 claims description 19
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 claims description 17
- 238000000137 annealing Methods 0.000 claims description 8
- 238000000231 atomic layer deposition Methods 0.000 claims description 7
- 238000000151 deposition Methods 0.000 claims description 7
- 239000003153 chemical reaction reagent Substances 0.000 claims description 6
- 229910001873 dinitrogen Inorganic materials 0.000 claims description 6
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 4
- 229910001882 dioxygen Inorganic materials 0.000 claims description 4
- PWVDYRRUAODGNC-UHFFFAOYSA-N CCN([Ti])CC Chemical compound CCN([Ti])CC PWVDYRRUAODGNC-UHFFFAOYSA-N 0.000 abstract 1
- 125000002147 dimethylamino group Chemical group [H]C([H])([H])N(*)C([H])([H])[H] 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 description 32
- 239000001257 hydrogen Substances 0.000 description 30
- 239000010410 layer Substances 0.000 description 27
- 239000012528 membrane Substances 0.000 description 27
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 26
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 22
- 239000002243 precursor Substances 0.000 description 19
- 229910021529 ammonia Inorganic materials 0.000 description 13
- 238000002441 X-ray diffraction Methods 0.000 description 10
- 125000004429 atom Chemical group 0.000 description 10
- 239000011159 matrix material Substances 0.000 description 10
- 230000008569 process Effects 0.000 description 10
- 238000001228 spectrum Methods 0.000 description 10
- 230000015572 biosynthetic process Effects 0.000 description 8
- 238000001039 wet etching Methods 0.000 description 8
- 230000008901 benefit Effects 0.000 description 7
- 230000002829 reductive effect Effects 0.000 description 7
- 238000001312 dry etching Methods 0.000 description 6
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 5
- 229910000040 hydrogen fluoride Inorganic materials 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 4
- 238000004458 analytical method Methods 0.000 description 3
- 239000012159 carrier gas Substances 0.000 description 3
- 230000003247 decreasing effect Effects 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 239000002356 single layer Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 229910011208 Ti—N Inorganic materials 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 238000005229 chemical vapour deposition Methods 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000002050 diffraction method Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
- 230000001699 photocatalysis Effects 0.000 description 2
- 238000005240 physical vapour deposition Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000010926 purge Methods 0.000 description 2
- 230000000717 retained effect Effects 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 238000004544 sputter deposition Methods 0.000 description 2
- 229910052718 tin Inorganic materials 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 125000001664 diethylamino group Chemical group [H]C([H])([H])C([H])([H])N(*)C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000010574 gas phase reaction Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 239000003446 ligand Substances 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 1
- 238000000059 patterning Methods 0.000 description 1
- 239000011941 photocatalyst Substances 0.000 description 1
- 238000009832 plasma treatment Methods 0.000 description 1
- 238000000623 plasma-assisted chemical vapour deposition Methods 0.000 description 1
- 230000006798 recombination Effects 0.000 description 1
- 238000005215 recombination Methods 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02365—Forming inorganic semiconducting materials on a substrate
- H01L21/02612—Formation types
- H01L21/02617—Deposition types
- H01L21/0262—Reduction or decomposition of gaseous compounds, e.g. CVD
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
- C23C16/30—Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
- C23C16/40—Oxides
- C23C16/405—Oxides of refractory metals or yttrium
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
- C23C16/30—Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
- C23C16/308—Oxynitrides
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
- C23C16/30—Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
- C23C16/34—Nitrides
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
- C23C16/30—Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
- C23C16/36—Carbonitrides
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
- C23C16/455—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for introducing gases into reaction chamber or for modifying gas flows in reaction chamber
- C23C16/45523—Pulsed gas flow or change of composition over time
- C23C16/45525—Atomic layer deposition [ALD]
- C23C16/45527—Atomic layer deposition [ALD] characterized by the ALD cycle, e.g. different flows or temperatures during half-reactions, unusual pulsing sequence, use of precursor mixtures or auxiliary reactants or activations
- C23C16/45536—Use of plasma, radiation or electromagnetic fields
- C23C16/4554—Plasma being used non-continuously in between ALD reactions
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
- C23C16/455—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for introducing gases into reaction chamber or for modifying gas flows in reaction chamber
- C23C16/45523—Pulsed gas flow or change of composition over time
- C23C16/45525—Atomic layer deposition [ALD]
- C23C16/45553—Atomic layer deposition [ALD] characterized by the use of precursors specially adapted for ALD
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
- C23C16/52—Controlling or regulating the coating process
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Electromagnetism (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Chemical Vapour Deposition (AREA)
- Electrodes Of Semiconductors (AREA)
Abstract
Description
본 발명은 일반적으로, 테트라키스(디메틸아미노)티타늄 (TDMAT) 및/또는 테트라키스(디에틸아미노)티타늄 (TDEAT) 을 사용하여 플라즈마 강화 원자 층 증착 (PEALD) 에 의해 Ti 함유 막을 형성하는 방법에 관한 것이다.The present invention generally relates to a method for forming a Ti containing film by plasma enhanced atomic layer deposition (PEALD) using tetrakis (dimethylamino) titanium (TDMAT) and / or tetrakis (diethylamino) titanium .
Ti 계 막들은 스퍼터링 방법, PVD 방법, 및 CVD 방법에 의해 오랫 동안 형성되어 왔고, 예를 들어, 낮은 시트 저항을 갖는 TiN 막들은 구리 확산 차단 막들로서 상업적으로 사용되어왔다. 또한, 최근의 디바이스 노드들의 축소에 따라, SDDP (spacer-defined double patterning) 는 점차적으로 소형화를 위한 기술로서 사용되기 시작했고, TiO 및 TiN 은 SDDP 용 하드 마스크들을 위한 양호한 후보들로 고려된다. SDDP 하드 마스크들을 위하여, 양호한 스텝 커버리지를 갖는 컨포멀 막 (conformal film) 들이 하드 마스크들의 성질의 관점에서 필요하고, 따라서 당업자들은, 일반적으로 양호한 스텝 커버리지를 제공하는 ALD 방법에 의해 형성된 TiO 및 TiN 계 컨포멀 막들을 사용 및 평가했다. 특히, TiN 은 일반적으로 응력을 제어하기 어렵고 그것은 강하게 압축성이 되기 쉽고, 따라서 응력을 제어하는 것은 난제들 중 하나이다. 게다가, 디바이스 노드들의 소형화에 기인하여, 스퍼터링 방법, PVD 방법, 및 CVD 방법과 같은 종래 방법들에 의해 양호한 스텝 커버리지를 갖는 컨포멀 막들을 형성하는 것은 어려웠고, 따라서, 대안의 방법으로서, 양호한 스텝 커버리지 및 낮은 시트 저항을 갖는 막들을 형성하는 방법이 요망된다.Ti based films have been formed for a long time by a sputtering method, a PVD method, and a CVD method. For example, TiN films having low sheet resistance have been used commercially as copper diffusion barrier films. Also, with the recent shrinkage of device nodes, spacer-defined double patterning (SDDP) has gradually begun to be used as a technology for miniaturization, and TiO and TiN are considered good candidates for hard masks for SDDP. For SDDP hard masks, conformal films with good step coverage are needed in terms of the nature of the hard masks, and therefore those skilled in the art will appreciate that TiO2 and TiN < RTI ID = 0.0 > Conformal membranes were used and evaluated. In particular, TiN is generally difficult to control stresses and it is likely to be strongly compressible, and thus controlling stress is one of the challenges. In addition, due to the miniaturization of device nodes, it has been difficult to form conformal films with good step coverage by conventional methods such as sputtering methods, PVD methods, and CVD methods, and therefore, as an alternative method, And a method of forming films having low sheet resistance are desired.
본 발명의 개요Summary of the Invention
본 발명의 일부의 실시형태들에 따르면, 테트라키스(디메틸아미노)티타늄 (TDMAT) 또는 테트라키스(디에틸아미노)티타늄 (TDEAT) 을 플라즈마 강화 원자층 증착 (PEALD) 을 위한 전구체로서 사용함에 있어서, 단순히 반응물 가스를 변경함으로써, TiN, TiCN, TiO, TiON, 및 TiOCN 막들과 같은 다양한 타입의 막이 형성될 수 있고, 또한, 막에 통상적인 각 막의 막 품질이 제어될 수 있다. 일부 실시형태들에서, TDMAT 또는 TDEAT 와 동시에 암모니아가 사용되지 않아서, TDMAT 또는 TDEAT 가 암모니아에 매우 반응성일지라도, 전구체와 그 전구체와 함께 사용된 암모니아 사이의 반응이 회피될 수 있다.According to some embodiments of the present invention, in using tetrakis (dimethylamino) titanium (TDMAT) or tetrakis (diethylamino) titanium (TDEAT) as a precursor for plasma enhanced atomic layer deposition (PEALD) By simply changing the reagent gas, various types of films can be formed, such as TiN, TiCN, TiO, TiON, and TiOCN films, and also the film quality of each film typical of the film can be controlled. In some embodiments, the reaction between the precursor and the ammonia used with the precursor may be avoided, although ammonia is not used at the same time as TDMAT or TDEAT, so that TDMAT or TDEAT is highly reactive with ammonia.
다양한 타입의 막 중에서, TiN 막들 및 열적으로 어닐링된 TiO 막들이 결정질 성분들에 의해 구성될 수도 있다. TiCN 막들은 결정질 및 비정질 성분들의 혼합물에 의해 구성될 수도 있고, TiCN 막들의 탄소 함량이 높으면, 막들은 전체적으로 비정질 성분들에 의해 구성된다. 다른 타입의 막들이 비정질 성분들에 의해 구성된다. TiN 및 TiCN 막들을 형성함에 있어서, 질소 공급 가스가 종종 질화에 사용된다. 하지만, 일부 실시형태들에서, TiN 막들을 형성함에 있어서, 질소 공급 가스인 암모니아가 사용되는 것이 아니라, 수소가 반응물 가스로서 사용되며, 그에 의해 전구체 자체에 포함된 질소를 사용하여 TiN 막들을 형성한다. 일부 실시형태들에서, 수소 가스만이 TiN 막들을 형성하기 위한 반응물 가스로서 사용된다. 일부 실시형태들에서, 질소 가스가 사용될 수도 있지만; 질소 가스가 본질적으로 질소 공급 가스로서 사용되는 것이 아니라, 탄소 농도, 막 응력 및/또는 시트 저항을 제어하는데 사용된다. 따라서, 일부 실시형태들은, TiN 막들이 질소 티타늄 결합들을 갖는 메틸아민 종인 전구체를 사용하여 형성될 수 있고, 수소 흐름, 질소 흐름, 및/또는 RF 전력을 파라미터들로서 다른 막 형성 조건들과 조합함으로써, 막 품질이 효과적으로 제어될 수 있는 것을 특징으로 한다.Among the various types of films, TiN films and thermally annealed TiO films may be constituted by crystalline components. The TiCN films may be composed of a mixture of crystalline and amorphous components, and if the carbon content of the TiCN films is high, the films are generally constituted by amorphous components. Other types of membranes are composed of amorphous components. In forming TiN and TiCN films, a nitrogen feed gas is often used for nitridation. However, in some embodiments, in forming TiN films, ammonia, which is a nitrogen feed gas, is not used but hydrogen is used as a reactant gas, thereby forming TiN films using nitrogen contained in the precursor itself . In some embodiments, only hydrogen gas is used as the reactant gas to form TiN films. In some embodiments, nitrogen gas may be used; Nitrogen gas is not used essentially as a nitrogen feed gas, but is used to control carbon concentration, film stress, and / or sheet resistance. Thus, some embodiments can be formed using TiN films using precursors that are methylamine species with nitrogen-titanium bonds, and by combining hydrogen flow, nitrogen flow, and / or RF power with other film- And the film quality can be effectively controlled.
관련 기술에 수반된 문제 및 해법들에 대한 임의의 논의는 오로지 본 발명을 위한 맥락을 제공하는 목적을 위해서만 포함되고, 그 논의의 일부 또는 전부가 본 발명이 이루어진 당시에 알려져 있었다라는 것을 인정하는 것으로 받아들여져서는 안된다. Any discussion of the problems and solutions associated with the related art is only included for purposes of providing a context for the present invention and acknowledged that some or all of the discussion was known at the time the invention was made It should not be imported.
본 발명의 양태들 및 관련 기술에 비해 달성되는 이점들을 요약하는 목적으로, 본 발명의 특정 목적들 및 이점들이 본 개시에서 설명된다. 물론, 모든 그러한 목적들 또는 이점들이 반드시 본 발명의 임의의 특정 실시형태에 따라 달성되는 것은 아닐 수도 있다는 것이 이해되야 한다. 따라서, 예를 들어, 당업자는, 본 발명이 여기에 교시되거나 또는 시사될 수도 있는 바처럼 반드시 다른 목적들 또는 이점들을 달성하는 것은 아닌 여기에 교시된 바처럼 하나의 이점 또는 이점들의 군을 달성하거나 또는 최적화하는 방식으로 구체화되거나 또는 수행될 수도 있다는 것을 인식할 것이다.For purposes of summarizing the aspects of the invention and the advantages achieved relative to the related art, certain objects and advantages of the invention are set forth in the present disclosure. Of course, it should be understood that not all such objects or advantages may be achieved in accordance with any particular embodiment of the invention. Thus, for example, those skilled in the art will readily appreciate that the present invention is not limited to achieving other objects or advantages, such as may be taught or suggested herein, but rather achieves one or a group of benefits or advantages as taught herein Or may be embodied or performed in a manner that is optimized.
본 발명의 추가 양태들, 특징들 및 이점들은 다음의 상세한 설명으로부터 분명해질 것이다. Further aspects, features and advantages of the present invention will become apparent from the following detailed description.
본 발명의 이들 및 다른 특징들이 이제 본 발명을 제한하는 것이 아닌 본 발명을 예시하도록 의도된 바람직한 실시형태들의 도면들을 참조하여 설명될 것이다. 그 도면들은 예시적인 목적들로 대폭 단순화되고 반드시 스케일대로인 것은 아니다.
도 1은 본 발명의 실시형태에서 사용가능한, 유전체 막을 성막하기 위한 PEALD 장치의 개략도이다.
도 2(a)는 테트라키스(디메틸아미노)티타늄 (TDMAT) 의 화학식을 나타낸다.
도 2(b)는 본 발명의 실시형태에 따라 수소 플라즈마를 이용하여 형성된 결정질 TiN 막의 매트릭스 구조를 나타내는 개략적인 예시이고, 여기서 N-C 결합들이 끊어지고, 탄소들이 매트릭스에 들어가지 않는다.
도 2(c)는 수소 플라즈마를 사용하지 않고서 형성된 비정질 TiCN 막의 매트릭스 구조를 나타내는 개략적인 예시이고, 여기서 N-C 결합들이 유지되고, 탄소들이 매트릭스내에 들어가고 결정질 구조의 형성을 방해한다.
도 3은, 본 발명의 실시형태에 따른, 막이 아나타제 타입 결정들을 형성한다는 것을 나타내는, 어닐링된 막의 X-선 회절 분석의 결과를 나타낸다.
도 4는 본 발명의 실시형태에 따른 컨포멀 TiCN 막의 단면도의 투과 전자 현미경 (TEM) 사진이다.
도 5는 본 발명의 실시형태에 따른 반응물 가스로서 암모니아를 사용하여 유전체 막을 성막하기 위한 PEALD 방법의 프로세스 단계들을 나타낸다.
도 6은 본 발명의 일부 실시형태에 따른 유전체 막을 성막하기 위한 PEALD 방법의 프로세스 단계들을 나타낸다.
도 7은 본 발명의 실시형태에 따른 TiN 및 TiO 막들 또는 TiCN 및 TiO 막들로 이루어지는 TiON 또는 TiOCN 막의 라미네이트 구조를 나타내는 개략도이다.
도 8은 본 발명의 일부 실시형태들에 따른 TiN 막, TiO 막, 및 TiON 막의 건식 식각 레이트들을 나타내는 그래프이다.
도 9는 본 발명의 일부 실시형태들에 따른 TiN 막, TiO 막, 및 TiON 막의 습식 식각 레이트들을 나타내는 그래프이다.
도 10은 본 발명의 일부 실시형태들에 따른 TiCN 막들의 푸리에 변환 적외 (FT-IR) 스펙트럼들을 나타낸다.
도 11은 본 발명의 일부 실시형태들에 따른 TiCN 막들의 푸리에 변환 적외 (FT-IR) 스펙트럼들을 나타낸다.
도 12는 본 발명의 일부 실시형태들에 따른 TiN/TiCN 막의 결정질에 관한 막 응력의 범위를 나타내는 그래프이다.
도 13은 본 발명의 일부 실시형태들에 따른 TiCN 막들의 푸리에 변환 적외 (FT-IR) 스펙트럼들을 나타낸다.
도 14는: 본 발명의 일부 실시형태들에 따른 (a) TiCN 막 (탄소 함량: 6%) 의 X-선 회절 분석의 결과, 그리고 (b) TiCN 막 (탄소 함량: 16%) 의 X-선 회절 분석의 결과를 나타낸다.
도 15는: 본 발명의 일부 실시형태들에 따른 (a) TiCN 막들의 푸리에 변환 적외 (FT-IR) 스펙트럼들, 그리고 (b) TiCN 막들의 X-선 회절 분석의 결과들을 나타낸다.
도 16은: 본 발명의 일부 실시형태들에 따른 (a) TiCN 막들의 푸리에 변환 적외 (FT-IR) 스펙트럼들, 그리고 (b) TiCN 막들의 X-선 회절 (XRD) 분석의 결과들을 나타낸다.
도 17 은 본 발명의 일부 실시형태들에 따른, 막 응력과 수소 흐름 사이의 관계를 나타내는 그래프와, 막 응력과 RF 전력 사이의 관계를 나타내는 그래프를 도시한다.These and other aspects of the present invention will now be described with reference to the drawings of preferred embodiments, which are intended to illustrate the invention without limiting the invention. The figures are greatly simplified for illustrative purposes and are not necessarily to scale.
1 is a schematic view of a PEALD device for forming a dielectric film usable in an embodiment of the present invention.
Figure 2 (a) shows the chemical formula of tetrakis (dimethylamino) titanium (TDMAT).
Fig. 2 (b) is a schematic illustration showing a matrix structure of a crystalline TiN film formed using a hydrogen plasma according to an embodiment of the present invention, where the NC bonds are broken, and the carbons do not enter the matrix.
Figure 2 (c) is a schematic illustration showing a matrix structure of an amorphous TiCN film formed without the use of a hydrogen plasma, where the NC bonds are retained and the carbons enter the matrix and interfere with the formation of a crystalline structure.
Figure 3 shows the results of an X-ray diffraction analysis of an annealed film, showing that the film forms anatase type crystals, in accordance with an embodiment of the present invention.
4 is a transmission electron microscope (TEM) photograph of a cross-sectional view of a conformal TiCN film according to an embodiment of the present invention.
Figure 5 depicts the process steps of the PEALD method for depositing a dielectric film using ammonia as a reactant gas in accordance with an embodiment of the present invention.
Figure 6 depicts the process steps of the PEALD method for depositing a dielectric film in accordance with some embodiments of the present invention.
7 is a schematic view showing a laminate structure of a TiON or TiOCN film composed of TiN and TiO films or TiCN and TiO films according to an embodiment of the present invention.
8 is a graph showing dry etch rates of a TiN film, a TiO film, and a TiON film in accordance with some embodiments of the present invention.
9 is a graph showing wet etch rates of a TiN film, a
Figure 10 shows Fourier Transform Infrared (FT-IR) spectra of TiCN films according to some embodiments of the present invention.
Figure 11 shows Fourier Transform Infrared (FT-IR) spectra of TiCN films according to some embodiments of the present invention.
Figure 12 is a graph showing the range of film stresses related to the crystallinity of a TiN / TiCN film in accordance with some embodiments of the present invention.
Figure 13 shows Fourier Transform Infrared (FT-IR) spectra of TiCN films according to some embodiments of the present invention.
Figure 14 shows the results of X-ray diffraction analysis of (a) a TiCN film (carbon content: 6%) according to some embodiments of the present invention and (b) Ray diffraction analysis.
Figure 15 shows the results of (a) Fourier transform infrared (FT-IR) spectra of TiCN films and (b) X-ray diffraction analysis of TiCN films according to some embodiments of the present invention.
Figure 16 shows the results of (a) Fourier transform infrared (FT-IR) spectra of TiCN films and (b) X-ray diffraction (XRD) analysis of TiCN films according to some embodiments of the present invention.
Figure 17 shows a graph showing the relationship between membrane stress and hydrogen flow and a graph showing the relationship between membrane stress and RF power, in accordance with some embodiments of the present invention.
본 개시에서, “가스” 는 증기화된 고체 및/또는 액체를 포함할 수도 있고 단일 가스 또는 가스들의 혼합물에 의해 구성될 수도 있다. 마찬가지로, 관사 "a" 또는 "an" 는 하나의 종을 지칭하거나 또는 다수의 종들을 포함하는 속 (genus) 을 지칭한다. 본 개시에서, 전구체 가스 및 반응물 가스 등의 프로세스 가스는 샤워헤드를 통해 반응 챔버에 도입되고 활성 가스 및 비활성 가스로 구성되거나, 본질적으로 이루어지거나, 또는 이루어질 수도 있다. 즉, 본 개시에서, "전구체 가스" 는 희가스 등의 캐리어 가스와 도입될 수도 있고, 마찬가지로 "반응물 가스" 는 희가스 등의 캐리어 가스와 도입될 수도 있다. 대안적으로, 전구체 또는 반응물 가스는 활성 가스로 이루어질 수도 있다. 희가스는 퍼지 가스로서 샤워헤드를 통해 간헐적으로 또는 연속적으로 도입될 수 있다. 프로세스 가스외의 가스, 즉 샤워헤드를 통과하지 않고서 도입된 가스는, 예를 들어 ,반응 공간을 실링하는데 사용될 수도 있고, 이는 희가스와 같은 시일 가스를 포함한다. 일부 실시형태들에서, "막" 은 실질적으로 핀홀들 없이 두께 방향에 수직한 방향으로 연속적으로 연장되어 전체 타겟 또는 관련 표면 (concerned surface) 을 커버하는 층, 또는 간단히 타겟 또는 관련 표면을 커버하는 층을 지칭한다. 일부 실시형태들에서, "층" 은, 표면 상에 형성된 특정 두께를 갖는 구조물 또는 막의 동의어를 지칭한다. 막 또는 층은, 특정 특성들을 갖는 별개 (discrete) 단일 막 또는 층, 또는 다수의 막들 또는 층들에 의해 구성될 수도 있고, 인접하는 막들 또는 층들 사이의 경계 (boundary) 는 명확 (clear) 하거나 또는 그렇지 않을 수도 있고, 물리적, 화학적 및/또는 임의의 다른 특성들, 형성 프로세스들 또는 시퀀스, 및/또는 인접하는 막들 또는 층들의 기능들 또는 목적들에 기초하여 확립될 수도 있다. 또한, 본 개시에서, 변수의 임의의 2개 수들은 변수의 작업가능한 범위를 구성할 수 있는데, 그 작업가능한 범위는 일상적인 작업 (routine work) 에 기초하여 결정될 수 있기 때문이고, 나타낸 임의의 범위들은 종점 (endpoint) 들을 포함하거나 또는 제외할 수도 있다. 또한, 표시된 변수들의 임의의 값들은 ("약" 으로 표시되든지 또는 그렇지 않든지에 상관 없이) 정확한 값들 또는 근사 값들을 지칭할 수도 있고 등가물 (equivalent) 들을 포함할 수도 있고, 일부의 실시형태들에서는, 평균, 중간 (median), 대표, 다수 (majority) 등을 지칭할 수도 있다.In the present disclosure, " gas " may comprise vaporized solids and / or liquid and may be constituted by a single gas or a mixture of gases. Similarly, the articles "a" or "an" refer to a species or to a genus comprising a plurality of species. In the present disclosure, the process gas, such as precursor gas and reactant gas, is introduced into the reaction chamber through the showerhead and may consist, consist essentially of, or consist of an active gas and an inert gas. That is, in the present disclosure, the "precursor gas" may be introduced with a carrier gas such as rare gas, and similarly, the "reactant gas" may be introduced with a carrier gas such as rare gas. Alternatively, the precursor or reagent gas may consist of an active gas. The rare gas may be introduced intermittently or continuously through the showerhead as purge gas. A gas other than the process gas, that is, the gas introduced without passing through the showerhead, may be used, for example, to seal the reaction space, which includes a seal gas such as rare gas. In some embodiments, a "film" is a layer that extends continuously in a direction perpendicular to the direction of thickness without substantially pinholes to form a layer covering the entire target or an associated surface, or simply a layer covering the target or associated surface Quot; In some embodiments, a "layer" refers to a structure or film synonym having a specific thickness formed on a surface. The film or layer may be composed of a discrete single film or layer with a specific property or multiple films or layers and the boundary between adjacent films or layers may be clear or otherwise And may be established based on physical, chemical and / or any other characteristics, forming processes or sequences, and / or functions or purposes of adjacent layers or layers. Also, in this disclosure, any two numbers of variables can constitute a workable range of a variable, since its operable range can be determined based on routine work, May include or exclude endpoints. In addition, any values of the indicated variables (whether indicated as "about" or not) may refer to exact or approximate values and may include equivalents, and in some embodiments , Mean, median, representative, majority, and the like.
본 개시에서 조건들 및/또는 구조들이 명시되지 않는 경우에, 당업자는, 일상적인 실험의 문제로서, 본 개시를 고려하여, 그러한 조건들 및/또는 구조들을 손쉽게 제공할 수 있다.Where conditions and / or structures are not specified in the present disclosure, those skilled in the art can readily provide such conditions and / or structures in view of this disclosure, as a matter of routine experimentation.
모든 개시된 실시형태들에서, 실시형태에 사용된 임의의 요소는 그와 동등한 임의의 요소에 의해 치환될 수 있고, 의도된 목적들을 위해 여기에서 명시적으로, 필요적으로, 또는 내재적으로 개시된 것들을 포함한다. 또한, 본 발명은 장치 및 방법들에 동일하게 적용될 수 있다.In any of the disclosed embodiments, any element used in the embodiments may be replaced by any element equivalent thereto and includes those explicitly, necessarily, or implicitly disclosed herein for intended purposes . Furthermore, the present invention is equally applicable to apparatus and methods.
본 개시에서, 임의의 정의된 의미들은 일부 실시형태들에서 보통 및 관습적인 의미들을 반드시 제외하는 것은 아니다.In this disclosure, any defined meanings are not necessarily excluded from the ordinary and customary meanings in some embodiments.
일부 실시형태들에서, 테트라키스(디메틸아미노)티타늄 (TDMAT) 또는 테트라키스(디에틸아미노)티타늄 (TDEAT) 을 사용하여 플라즈마 강화 원자층 증착 (PEALD) 에 의해 기판 상에 Ti 함유 막을 형성하는 방법은 : (i) 기판이 배치되는 반응 공간에 펄스로 TDMAT 및/또는 TDEAT 를 도입하는 단계; (ii) 반응 공간에 NH3 무함유 반응물 가스를 연속적으로 도입하는 단계; (iii) 반응 공간에 펄스로 RF 전력을 인가하는 단계로서, TDMAT 및/또는 TDEAT 의 펄스 그리고 RF 전력의 펄스는 오버랩되지 않는, 상기 인가하는 단계; 및 (iv) 기판 상에 Ti 함유 막을 성막하기 위하여 (i) 내지 (iii) 단계들을 반복하는 단계를 포함한다.In some embodiments, a method of forming a Ti-containing film on a substrate by plasma enhanced atomic layer deposition (PEALD) using tetrakis (dimethylamino) titanium (TDMAT) or tetrakis (diethylamino) (I) introducing TDMAT and / or TDEAT into the reaction space in which the substrate is placed in a pulse; (ii) continuously introducing an NH 3 -containing reactant gas into the reaction space; (iii) applying RF power in pulses to the reaction space, wherein pulses of TDMAT and / or TDEAT and pulses of RF power do not overlap; And (iv) repeating steps (i) to (iii) to form a Ti-containing film on the substrate.
일부 실시형태들에서, TDMAT 및 TDEAT 는 이들에 동등한 유도체들을 포함할 수도 있고, 여기에서 메틸 기들 및 에틸 기들은 교환가능하게 사용될 수 있다.In some embodiments, TDMAT and TDEAT may include equivalent derivatives to these, where methyl groups and ethyl groups may be used interchangeably.
위에서, "연속적으로" 는, 진공 파괴 없이, 타임라인으로서 중단 없이, 처리 조건들을 변경함이 없이, 또는 일부의 실시형태들에서는 그 직후에를 지칭한다.Above, "continuously" refers to without vacuum break, without interruption as a timeline, without changing processing conditions, or in some embodiments immediately thereafter.
일부 실시형태들에서, NH3 무함유 반응물 가스는 H2 및/또는 N2이다. 일부 실시형태들에서, NH3 무함유 반응물 가스는, 질소, 산소 및 탄소 중 어느 것도 함유하지 않는다. 일부 실시형태들에서, NH3 무함유 반응물 가스는 H2 및 희가스 (예를 들어, He, Ar) 로 이루어지고, 이에 의해 (iv) 단계에서 Ti 함유 막으로서 TiN 결정질 막을 성막한다. 대안적으로, 일부 실시형태들에서, NH3 무함유 반응물 가스는 H2, N2, 및 희가스 (예를 들어, He, Ar) 로 이루어지고, 이에 의해 (iv) 단계에서 Ti 함유 막으로서 TiCN 비정질 막을 성막한다. 대안적으로, 일부 실시형태들에서, NH3 무함유 반응물 가스는 산소를 포함하고, 이에 의해 (iv) 단계에서 Ti 함유 막으로서 TiO 막을 형성한다. 일부 실시형태들에서, 그 방법은, (iv) 단계에서 Ti 함유 막으로서 아나타제 결정을 갖는 TiO 막을 형성하기 위하여, (iv) 단계 후에 산소의 분위기에서 기판 상에 Ti 함유 막을 어닐링하는 단계를 더 포함하고, 여기서 비정질 TiO 는 아나타제 결정들로 변화된다. 아나타제 결정을 갖는 TiO 막은 광촉매 활성을 나타낸다. 어닐링 후에, TiO 막의 표면은 친수성을 획득하고, 이는 TiO 광촉매에 고유한 초친수성이다.In some embodiments, the NH 3 -containing reactant gas is H 2 and / or N 2 . In some embodiments, the NH 3 -containing reactant gas does not contain any of nitrogen, oxygen, and carbon. In some embodiments, the NH 3 -containing reactant gas comprises H 2 and rare gases (eg, He, Ar), thereby forming a TiN crystalline film as the Ti containing film in step (iv). Alternatively, in some embodiments, the NH 3 -containing reactant gas comprises H 2 , N 2 , and rare gases (eg, He, Ar), thereby forming TiCN An amorphous film is formed. Alternatively, in some embodiments, the NH 3 -containing reactant gas comprises oxygen, thereby forming a
일부 실시형태들에서, NH3 무함유 반응물 가스는 산소를 함유하지 않는 반응물 가스 그리고 산소를 함유하는 반응물 가스로 구성되고, (iv) 단계에서, (i) 내지 (iii) 단계들이 반복될 때, NH3 무함유 산소 무함유 반응물 가스 및 NH3 무함유 산소 함유 가스가 설정된 인터벌에서 교번하여 사용된다. 예를 들어, NH3 무함유 산소 무함유 반응물 가스는 질소 가스 없이 수소 가스이고, NH3 무함유 산소 함유 가스는 산소 가스이고, 이에 의해 설정된 인터벌에서 교번하여 성막된 TiO 막들과 TiN 막들로 이루어지는 TiON 막을 형성한다. 대안적으로, 일부 실시형태들에서, NH3 무함유 산소 무함유 반응물 가스는 수소 가스 및 질소 가스이고, NH3 무함유 산소 함유 가스는 산소 가스이고, 이에 의해 설정된 인터벌에서 교번하여 성막된 TiO 막들과 TiCN 막들로 이루어지는 TiOCN 막을 형성한다. 도 7은 본 발명의 실시형태에 따른 기판 (71) 상에 형성된 TiN 및 TiCN 막들 (72, 74, 76, 78) 및 TiO 막들 (73, 75, 77) 로 이루어지는 TiON 또는 TiOCN 막 (79) 의 라미네이트 구조를 나타내는 개략도이다. 본 실시형태에서, 먼저, TiN 또는 TiCN 서브 층을 형성하는 사이클은 5 내지 100번 수행되어 기판 (71) 상에 TiN 또는 TiCN 막 (72) 을 형성하고, 다음으로, TiO 서브 층을 형성하는 사이클은 한번 수행되어 TiN 또는 TiCN 막 (72) 상부에 TiO 막 (73) 을 형성한다. 마찬가지로, TiN 또는 TiCN 막 (74), TiO 막 (75), TiN 또는 TiCN 막 (76), TiO 막 (77), 및 TiN 또는 TiCN 막 (78) 이 이 순서대로 성막되어 라미네이트 (79) 를 형성한다. 일부 실시형태들에서, TiO 막을 형성하는 사이클의 수는 TiN 또는 TiCN 막을 형성하는 사이클들의 수보다 현저히 더 적다, 즉 TiO 막의 두께는 TiN 또는 TiCN 막의 두께보다 현저히 더 작다. 일부 실시형태들에서, 라미네이트들 (각 라미네이트는, 하나 이상의 TiN/TiCN 서브 층들로 구성될 수도 있는 단일 TiN/TiCN 막, 및 하나 이상의 TiO 서브 층들로 구성될 수도 있는 단일 TiO 막에 의해 구성됨) 의 수는 약 3 내지 200, 통상적으로 5 내지 100이다. 일부 실시형태들에서, 하나의 라미네이트에서 TiO 막을 형성하는 사이클들의 수 대 TiN/TiCN 막을 형성하는 사이클들의 수의 비는 1:1 내지 1:200, 통상적으로 1:3 내지 1:100, 보다 통상적으로는 1:5 내지 1:25 일 수도 있다. 또한, 도 5는 반응물 가스로서 암모니아를 사용하여 유전체 막을 성막하기 위한 PEALD 방법의 프로세스 단계들을 나타낸다. 도 6은 본 발명의 일부 실시형태에 따른 유전체 막을 성막하기 위한 PEALD 방법의 프로세스 단계들을 나타낸다. 도 6에 예시된 실시형태들에서, 암모니아가 반응물 가스로서 사용되지 않았기 때문에, 반응물 가스 (질소, 수소, 및/또는 산소) 가 연속적으로 공급될 수 있고, 또한 전구체 피드의 펄스와 RF 전력 인가의 펄스 사이의 퍼지 가스로서 기능할 수 있다. 위에서, 반응물 가스는 캐리어 가스로서 사용되는 희가스 (미도시) 와 함께 공급된다. 대조적으로, 도 5에서, 암모니아가 반응물 가스로서 사용되었기 때문에, 반응물 가스는 전구체 피드의 펄스와는 상이한 펄스로 공급되야 하고, 이는 서로 오버랩되지 않아야 하며, 더 복잡한 제어 시스템을 필요로 한다.In some embodiments, the NH 3 -containing reactant gas is comprised of a reactant gas that does not contain oxygen and a reactant gas that contains oxygen, and in step (iv), when steps (i) to (iii) The NH 3 -free oxygen-free reagent gas and the NH 3 -free oxygen-containing gas are alternately used at the set intervals. For example, the NH 3 -free oxygen-free reactant gas is hydrogen gas without nitrogen gas, and the NH 3 -free oxygen-containing gas is oxygen gas, whereby
본 개시에서, TiN, TiON, TiCN, TiOCN, TiO 막들, 및 다른 Ti 함유 막은, 매트릭스들이 실질적으로 또는 대부분 위에 나타낸 원소들로 구성되지만, 불순물, 비실질적인 원소들 이를테면 수소, 그리고 비실질적인 양의 재료 원소들을 제외하지 않은 막들을 지칭하거나, 또는 주로 그 나타낸 원소들에 의해 특성화되는 막들, 그 나타낸 원소들에 의해 표현되는 막들, 또는 당업자가 그렇게 인식하는 막들을 지칭한다.In the present disclosure, the TiN, TiON, TiCN, TiOCN, TiO2 films, and other Ti containing films are formed from a mixture of impurities, non-substantial elements such as hydrogen, Refers to films that do not exclude elements, or to films that are characterized primarily by the elements they represent, to films that are represented by the elements shown, or to those skilled in the art.
일부 실시형태들에서, TiN 막은 아래의 표 1에 나타낸 조건들하에서 형성될 수 있다. ALD 는 자기 제한 흡착 반응 프로세스이므로, 성막되는 전구체 분자들의 양은 반응 표면 사이트들의 수에 의해 결정되고, 포화 후의 전구체 노출과 관계 없고, 전구체의 공급은, 그에 의해 반응 표면 사이트들이 사이클마다 포화되도록 한다.In some embodiments, a TiN film can be formed under the conditions shown in Table 1 below. Since ALD is a self-limiting adsorption reaction process, the amount of precursor molecules deposited is determined by the number of reactive surface sites, independent of the precursor exposure after saturation, and the supply of precursors thereby causing the reaction surface sites to saturate per cycle.
일부 실시형태들에서, TiCN 막은 아래의 표 2에 나타낸 조건들하에서 형성될 수 있다.In some embodiments, a TiCN film can be formed under the conditions shown in Table 2 below.
일부 실시형태들에서, TiON 막은 아래의 표 4에 나타낸 조건들하에서 형성될 수 있다.In some embodiments, the TiON film may be formed under the conditions shown in Table 4 below.
일부 실시형태들에서, TiOCN 막은 아래의 표 5에 나타낸 조건들하에서 형성될 수 있다.In some embodiments, a TiOCN film can be formed under the conditions shown in Table 5 below.
일부 실시형태들에서, Ti 함유 막의 두께는, 막의 조성, 막의 의도된 용도 등에 따라, 약 0.3nm 내지 약 60nm, 통상적으로 약 0.06nm 내지 약 300nm 의 범위에 있을 수도 있다.In some embodiments, the thickness of the Ti containing film may range from about 0.3 nm to about 60 nm, typically from about 0.06 nm to about 300 nm, depending on the composition of the film, the intended use of the film, and the like.
일부 실시형태들에서, TiO 막은 아나타제 결정들을 형성하기 위하여 아래 표 6에 나타낸 조건들하에서 어닐링을 받는다.In some embodiments, the
어닐링을 수행하는 것에 의해, 아나타제 타입 결정들, 루틸 타입 (rutile-type) 결정들, 또는 브루카이트 (brookite-type) 타입 결정들이, 어닐링 온도에 따라, 형성될 수 있다. 예를 들어, 막이 약 600℃에서 어닐링될 때, 아나타제 타입 결정들이 형성된다. 어닐링을 위해, 산화 분위기를 제공하는 한, 임의의 가스가 사용될 수 있다.By performing the annealing, anatase type crystals, rutile-type crystals, or brookite-type type crystals can be formed, depending on the annealing temperature. For example, when the film is annealed at about 600 < 0 > C, anatase type crystals are formed. For annealing, any gas may be used as long as it provides an oxidizing atmosphere.
일부 실시형태들에서, Ti 함유 막은 막 응력이 -2,500 MPa 내지 800 MPa 이다. 도 12는 본 발명의 일부 실시형태들에 따른 TiN/TiCN 막의 결정질에 관한 막 응력의 범위를 나타내는 그래프이다. 도 12에 나타낸 바처럼, 막이 매우 결정질일 때, 즉 낮은 탄소 함량을 가질 때, 막은 높은 압축 응력을 갖고, 막이 전체적으로 비정질일 때, 막은 압축 응력이 약 -400 MPa이다. 막의 탄소 함량이 약 4% 와 약 9% 사이일 때, 막은 막에 포함된 결정 구조의 타입들에 따라, 인장 응력을 가질 수 있다. 즉, 막 응력은 2개 이상의 타입의 결정 구조에 관련되는 것으로 보이고, 결정 구조들의 비율에 따라, 막은 높은 막 응력 내지 낮은 막 응력을 나타낸다. 하지만, 막의 탄소 함량이 약 4% 보다 적거나 또는 약 9% 보다 많을 때, 인장 응력을 나타내는 결정 구조들을 형성하기 어려운 것으로 보인다. 일부 실시형태들에서, 막의 탄소 함량이 약 6% 일 때, 막은 최고 인장 응력, 약 800 MPa 를 갖는다. 막의 최저 압축 응력은 약 -2,500 MPa 이하일 수도 있고, 막의 탄소 함량이 검출가능하지 않을 때 (ND), 막은 최저 압축 응력을 나타낼 수도 있다. 막의 탄소 함량이 약 6% 보다 많을 때, 막은 최저 압축 응력을 나타내지 않을 수도 있다.In some embodiments, the Ti containing film has a film stress of -2,500 MPa to 800 MPa. Figure 12 is a graph showing the range of film stresses related to the crystallinity of a TiN / TiCN film in accordance with some embodiments of the present invention. As shown in FIG. 12, when the film is very crystalline, that is, when it has a low carbon content, the film has a high compressive stress, and when the film is amorphous as a whole, the film has a compressive stress of about -400 MPa. When the carbon content of the film is between about 4% and about 9%, the film may have tensile stress, depending on the types of crystal structure contained in the film. That is, the film stress appears to be related to two or more types of crystal structures, and depending on the proportion of the crystal structures, the film exhibits high to low film stresses. However, when the carbon content of the film is less than about 4% or greater than about 9%, it appears that it is difficult to form crystalline structures exhibiting tensile stress. In some embodiments, when the carbon content of the film is about 6%, the film has a peak tensile stress, about 800 MPa. The minimum compressive stress of the film may be about -2,500 MPa or less, and when the carbon content of the film is not detectable (ND), the film may exhibit the lowest compressive stress. When the carbon content of the film is greater than about 6%, the film may not exhibit the lowest compressive stress.
막의 결정질은 막 형성 파라미터들을 변경하는 것에 의해 조정될 수 있다. 몇몇 실시형태들에서, 그 방법은 : (a) (ii) 단계에서 반응물 가스로서 사용된 H2 의 참조 유량 (reference flow rate), (iii) 단계에서 사용된 참조 RF 전력, 및 (i) 내지 (iii) 전체에 걸친 참조 성막 온도를 포함하는 성막 조건들하에서 (i) 내지 (iv) 단계들에 의해 성막되는 TiN 결정질 막의 막 응력보다 더 큰, Ti 함유 막을 위한 타겟 막 응력을 설정하는 단계; 및 (b) (ii) 단계에서 반응물 가스로서 사용되는 H2 의 유량, (iii) 단계에서 사용되는 RF 전력, 및 (i) 내지 (iii) 단계 전체에 걸친 성막 온도를 설정하는 단계로서, H2 의 유량, RF 전력 및 성막 온도 중 하나 이상만이 막 응력을 변경하기 위한 제어 파라미터로서 사용되고, H2 의 참조 유량, 참조 RF 전력, 및 참조 성막 온도와는 상이한, 상기 설정하는 단계, 다음으로 Ti 함유 막을 성막하기 위해 (i) 내지 (iv) 단계들을 수행하는 단계를 더 포함한다. 일반적으로, RF 전력이 더 높아질 수록, 막 응력이 더 낮아지고, 온도가 더 높아질 수록, 막 응력이 더 높아지며, 수소 함량이 더 높아질 수록, 막 응력이 더 높아진다. 제어 파라미터들의 참조 값들을 참조하여, 제어 파라미터들을 조정함으로써, Ti 함유 막이 인장 막 응력을 갖도록 구성될 수 있다. 예를 들어, 인장 막 응력을 제공하기 위하여, H2 의 유량은 TiN 결정질 막에 사용되는 H2 의 참조 유량보다 더 낮게 설정될 수 있거나, RF 전력은 TiN 결정질 막에 사용되는 참조 RF 전력보다 더 낮게 설정될 수 있거나, 및/또는 성막 온도는 TiN 결정질 막에 사용되는 참조 성막 온도보다 더 높게 설정될 수 있다. 일부 실시형태들에서, Ti 함유 막이 약 4% 내지 약 9% 탄소를 함유할 때, 막은 인장 막 응력을 갖는다.The crystalline quality of the film can be adjusted by changing film formation parameters. In some embodiments, the method comprises: (a) determining a reference flow rate of H 2 used as the reactant gas in step (ii), a reference RF power used in step (iii), and (i) (iii) setting a target film stress for the Ti-containing film that is greater than the film stress of the TiN crystalline film deposited by the steps (i) to (iv) under film-forming conditions comprising the reference film-forming temperature throughout; And (b) setting a film forming temperature throughout the steps (i) to (iii), wherein the flow rate of H 2 used as the reactant gas in step (ii), the RF power used in step (iii) 2 is used as a control parameter for changing the film stress and only one of at least one of the flow rate, the RF power and the film forming temperature is different from the reference flow rate of H 2 , the reference RF power, and the reference film forming temperature, (I) to (iv) in order to form a film containing a silicon-containing film. In general, the higher the RF power, the lower the membrane stress, the higher the temperature, the higher the membrane stress, the higher the hydrogen content, the higher the membrane stress. By referring to the reference values of the control parameters and adjusting the control parameters, the Ti containing film can be configured to have tensile film stress. For example, in order to provide a tensile film stress, the flow rate of H 2 is may be set lower than the reference flow rate of the H 2 being used for the TiN crystalline film, the RF power is more than the reference RF power used for TiN crystalline film And / or the film formation temperature may be set to be higher than the reference film formation temperature used in the TiN crystalline film. In some embodiments, when the Ti containing film contains about 4% to about 9% carbon, the film has tensile film stress.
막 응력은 막에서 결합 상태에 따라 달라진다. 일부 실시형태들에서, Ti 함유 막은 푸리에 변환 적외 분광 (FT-IR) 그래프에서 2,000 cm-1 및 1,400 cm-1 에서 피크들을 나타낸다. 일반적으로 2,000 cm-1 에서의 피크는 인장 응력을 나타내는 반면, 1,400 cm-1 에서의 피크는 압축 응력을 나타낸다. 이들 응력들의 합이 막의 응력을 나타낸다. 2,000 cm-1 및 1,400 cm-1 에서 피크가 없으면, 막은 강한 압축 응력을 나타내며, 이는 막이 TiN 결정들에 의해 구성됨을 나타낸다. 반응물 가스로서 사용된 수소 가스의 흐름이 증가될 때, 먼저, 1,400 cm-1에서의 피크가 사라지고, 막은 인장 응력을 갖는 막이 된다. 이 상태에서, RF 전력이 증가될 때, 2,000 cm-1에서의 피크가 사라지고, 이는 막의 결정질이 증가하고 막은 강한 압축 응력을 갖는 막이 됨을 나타낸다. 따라서, 2개 파라미터들 (수소 가스 흐름 및 RF 전력) 을 조정함으로써, FT-IR 그래프에서 피크들이 조절될 수 있다; 즉 막 응력이 제어될 수 있다. 어떤 결합이 각 피크에 대응하는지는 알려져 있지 않지만, 2,000 cm-1 및 1,400 cm-1 에서의 피크들 중 어느 하나가 감소될 때, 막에서 탄소 함량이 감소되기 때문에 그 피크들은 탄소에 관련되는 것으로 예상된다. 일부 실시형태들에서, FT-IR 그래프에서 1,400 cm-1 에서의 피크의 높이에 기초하여, 수소 흐름과 막 응력 사이의 관계가 결정될 수 있다. 수소 흐름 및 RF 전력을 조작함으로써 1,400 cm-1 에서의 피크가 2,000 cm-1 에서의 피크보다 더 용이하게 사라질 수 있다. 일부 실시형태들에서, 2,000 cm-1에서의 피크는 막 형성을 위한 온도에 의해 제어될 수 있다. 온도가 높을 때, 2,000 cm-1에서의 피크가 높아진다.The film stress depends on the bonding state in the film. In some embodiments, the Ti containing film exhibits peaks at 2,000 cm -1 and 1,400 cm -1 in a Fourier transform infrared spectroscopy (FT-IR) graph. Generally, peaks at 2,000 cm -1 exhibit tensile stresses, while peaks at 1,400 cm -1 exhibit compressive stresses. The sum of these stresses represents the stress of the film. Without peaks at 2,000 cm -1 and 1,400 cm -1 , the film exhibits strong compressive stresses, indicating that the film is constituted by TiN crystals. When the flow of the hydrogen gas used as the reactant gas is increased, first, the peak at 1,400 cm -1 disappears, and the film becomes a film having a tensile stress. In this state, when the RF power is increased, the peak at 2,000 cm <" 1 > disappears indicating that the crystalline quality of the film increases and the film becomes a film with strong compressive stress. Thus, by adjusting the two parameters (hydrogen gas flow and RF power), the peaks in the FT-IR graph can be adjusted; That is, the film stress can be controlled. It is not known which bond corresponds to each peak, but when one of the peaks at 2,000 cm -1 and 1,400 cm -1 is reduced, the peaks are related to carbon because the carbon content in the film is reduced It is expected. In some embodiments, based on the height of the peak at 1400 cm < -1 > in the FT-IR graph, the relationship between hydrogen flow and membrane stress can be determined. The peak at 1,400 cm -1 by manipulating the hydrogen flow, and RF power can be lost more readily than the peak at 2,000 cm -1. In some embodiments, the peak at 2,000 cm -1 may be controlled by the temperature for film formation. When the temperature is high, the peak at 2,000 cm -1 becomes high.
일부 실시형태들에서, 반응물 가스로서 수소를 증가하게 도입함으로써, 1,400 cm-1 에서의 피크가 낮아지고, 2,000 cm-1 에서의 피크만이 유지되고, 이에 의해 결과적인 막을 인장성으로 만든다. 이 상황에서, RF 전력을 증가시킴으로써, 2,000 cm-1 에서의 피크가 또한 사라지고, 이에 의해 결과적인 막을 압축성으로 만들고, 그 막은 TiN 결정들에 의해 구성된다. 수소 가스 흐름을 사용하지 않고서 RF 전력이 증가될 때, 1,400 cm-1 에서의 피크는 더 높아지고, 막 응력은 매우 압축성이 된다. 일부 실시형태들에서, 1,400 cm-1 에서의 피크는 다수의 결합들에 대응한다, 즉 압축 응력 및 인장 응력을 나타내는 다수의 피크들이 집합적으로 1,400 cm-1에서의 피크를 구성하고, 수소 가스 흐름이 증가될 때, 먼저 인장 응력을 나타내는 피크가 사라지고, 다음으로 압축 응력을 나타내는 피크가 사라지며, 이로써, 1,400 cm-1에서의 피크가 존재하지 않게 하고 인장 응력을 나타내는 2,000 cm-1 에서의 피크만을 남긴다. 결과적으로, 인장 응력을 갖는 막이 획득된다. 일부 실시형태들에서, RF 전력을 증가시키는 것은, RF 전력 인가의 지속시간을 늘리는 것과 대등하고, 그것들은 교환가능하게 사용될 수 있다.In some embodiments, by increasing the hydrogen as the reactant gas, the peak at 1400 cm <" 1 > is lowered and only the peak at 2000 cm < -1 > is maintained, thereby rendering the resulting film tensile. In this situation, by increasing the RF power, the peak at 2,000 cm <" 1 > also disappeared, thereby making the resulting film compressible, and the film constituted by TiN crystals. When RF power is increased without using a hydrogen gas flow, the peak at 1,400 cm <" 1 > is higher and the membrane stress becomes very compressive. In some embodiments, the peak at 1,400 cm -1 corresponds to the number of coupling, that is configured for a plurality of peaks at 1,400 cm -1 peak to collectively represent the compression stress and tensile stress, and hydrogen gas when the flow is increased, the first peak represents the tensile stress disappears, the peaks representing the following compression stress to fall off, and thereby, a peak at 1,400 cm -1 no longer exists, and at 2,000 cm -1 indicates a tensile stress Leaving only the peak. As a result, a film having tensile stress is obtained. In some embodiments, increasing the RF power is equivalent to increasing the duration of the RF power application, and they can be used interchangeably.
TDMAT 및 TDEAT의 구조적으로 중요한 피쳐는, 티타늄 상의 Ti-C 및 Ti-H 와 같은 결합들이 있는 것이 아니라, Ti의 모든 4개 핸드 (hand) 들이 Ti-N 결합이라는 것이다. 도 2(a)는 테트라키스(디메틸아미노)티타늄 (TDMAT) 의 화학식을 나타낸다. 이 피쳐에 기인하여, 분자 구조에 포함된 질소들은 효율적으로 막에 포함될 수 있고, 디메틸아민의 형태로 존재하는 탄소들이 용이하게 수소 플라즈마에 의해 제거될 수 있고, 이에 의해 불순물인 탄소를 제거하고 TiN의 결정화를 증진시킨다. 도 2(b)는 본 발명의 실시형태에 따라 수소 플라즈마를 이용하여 형성된 결정질 TiN 막의 매트릭스 구조를 나타내는 개략적인 예시이고, 여기서 N-C 결합들은 끊어지고, 탄소들이 매트릭스내에 들어가지 않는다. 수소 플라즈마에 의한 탄소들의 감소 (reduction) 는 막의 매트릭스 구조를 결정질로 만들고, 매트릭스 구조를 형성하기 위한 질소들이, 반응물 가스로부터가 아니라, 전구체로부터 제공된다. 도 2(c) 는 수소 플라즈마를 사용하지 않고서 형성된 비정질 TiCN 막의 매트릭스 구조를 나타내는 개략적인 예시이고, 여기서 N-C 결합들이 유지되고, 탄소들이 매트릭스내에 들어가고 결정질 구조의 형성을 방해한다. 다른 한편, 수소 플라즈마의 효과를 약화시키고 반응물 가스로서 질소를 사용함으로써, 탄소들은 막에 존재할 수 있고, 이에 의해 막에서 불순물인 탄소를 남기고 따라서 TiCN 에 의해 구성되는 비정질 막을 형성한다.A structurally important feature of TDMAT and TDEAT is not that there are bonds such as Ti-C and Ti-H on titanium, but all four hands of Ti are Ti-N bonds. Figure 2 (a) shows the chemical formula of tetrakis (dimethylamino) titanium (TDMAT). Due to this feature, the nitrogen contained in the molecular structure can be efficiently included in the film, and the carbons present in the form of dimethylamine can be easily removed by the hydrogen plasma, thereby removing the impurity carbon and forming TiN Lt; / RTI > FIG. 2 (b) is a schematic illustration showing a matrix structure of a crystalline TiN film formed using a hydrogen plasma according to an embodiment of the present invention, wherein the N-C bonds are broken and the carbons do not enter the matrix. The reduction of carbons by the hydrogen plasma makes the matrix structure of the film crystalline and the nitrogen for forming the matrix structure is provided from the precursor, not from the reactant gas. Figure 2 (c) is a schematic illustration showing a matrix structure of an amorphous TiCN film formed without the use of a hydrogen plasma, where the N-C bonds are retained and the carbons enter the matrix and interfere with the formation of a crystalline structure. On the other hand, by weakening the effect of the hydrogen plasma and using nitrogen as the reactant gas, the carbons can be present in the film, thereby leaving an impurity carbon in the film and thus forming an amorphous film constituted by TiCN.
또한, TDMAT 및/또는 TDEAT의 사용과 조합하여, 기판의 표면 상에 흡착된 재료가 처리되는 표면 플라즈마 처리 방법인 PEALD에 의해, 가스 상 (gas phase) 에서 Ti 와 디메틸아민 등의 해리된 리간드들의 재결합에 기인하여 Ti-C 및 Ti-H 결합들을 형성하는 것에 의해 막 품질을 열화시킬 위험성이 기상 반응 방법인 PECVD 와 비교하여 감소될 수 있고, 분자 구조에서 Ti-N 결합들을 자르지 않고서 탄소들이 효율적으로 제거될 수 있다. 상기한 바는 전구체로서 TDMAT 및 TDEAT 의 우월한 특징들이고, 다양한 타입의 막의 성막이 보다 용이해지는 이유이다.It is also possible, in combination with the use of TDMAT and / or TDEAT, for the removal of dissociated ligands, such as Ti and dimethylamine, in the gas phase, by means of PEALD, a surface plasma treatment process in which the adsorbed material is treated on the surface of the substrate. The risk of deteriorating the film quality by forming Ti-C and Ti-H bonds due to recombination can be reduced as compared with the gas phase reaction PECVD, and the carbon can be efficiently removed without cutting Ti-N bonds in the molecular structure As shown in FIG. These are the superior features of TDMAT and TDEAT as precursors and are the reason why the deposition of various types of films is easier.
또한, Ti의 특징으로서, 그것은 산소에 타이트하게 결합될 수 있고, 따라서, Ti 의 산화는 매우 용이하고, 이에 의해 TiO 막을 용이하게 형성한다. 하지만, Ti 와 산소 사이의 타이트한 결합은 탄소 및 질소 등의 다른 원소들의 제거에 기여하고, 따라서, 산소가 TiO 막을 형성하는데 사용될 때, 탄소 및 질소는 산소에 의해 제거되고 막 내에 존재하지 않는다. 따라서, 일부 실시형태들에서, 산소 그리고 질소 및/또는 탄소를 막에서 동시에 남길 때, 즉, TiON 또는 TiOCN 막을 형성할 때, 그것은, TiO 막들 및 TiN 또는 TiCN 막들이 교번하여 라미네이트되는 라미네이션 방법을 사용하는 것에 의해 형성될 수 있다.Further, as a characteristic of Ti, it can be tightly bound to oxygen, and therefore oxidation of Ti is very easy, thereby easily forming a TiO film. However, the tight bond between Ti and oxygen contributes to the removal of other elements such as carbon and nitrogen, and thus, when oxygen is used to form the
일반적으로, TiN의 결정이 전도성일 때, 그리고 TiN의 결정질이 향상될 때, 시트 저항은 낮아진다. 탄소 또는 산소가 막에 포함될 때, 결정질이 열화되고, 그 구조를 비정질로 만든다. 일부 실시형태들에서, 수소 가스 흐름 및 RF 전력을 제어함으로써, 막 응력 및 탄소 농도가 제어될 수 있고, 그에 의해 막의 결정질을 제어하고 시트 저항을 제어한다. 탄소 농도와 막 응력 사이에 관찰되는 강한 상관이 없지만, 탄소 농도가 극히 낮고 결정질이 높을 때, 막은 압축성으로 특성화된다. 이것은, 탄소 농도의 감소에 기인하여 결정질이 향상되고, 그에 의해 막을 압축성으로 만들기 때문일 수도 있다.Generally, when the crystal of TiN is conductive and when the crystalline of TiN is improved, the sheet resistance is lowered. When carbon or oxygen is included in the film, the crystalline is deteriorated and makes its structure amorphous. In some embodiments, by controlling hydrogen gas flow and RF power, the film stress and carbon concentration can be controlled, thereby controlling the crystalline quality of the film and controlling the sheet resistance. There is no strong correlation observed between the carbon concentration and the film stress, but when the carbon concentration is extremely low and the crystalline is high, the film is characterized by compressibility. This may be because the crystallinity is improved due to the decrease of the carbon concentration, thereby making the film compressible.
막 응력을 제어함에 있어서, 인장 응력을 갖는 막을 획득하기 위하여, 수소 공급 및 RF 전력을 조합하여 제어하는 것이 극히 중요하다. 인장 응력을 갖는 막을 형성하기 위해 설정된 것과 비교하여 수소 흐름이 너무 낮거나 RF 전력이 너무 높을 때, 막 응력은 압축 응력으로 변화하고, 따라서, 수소 흐름 및 RF 전력 양자 모두를 제어하는 것이 매우 중요하다.In controlling membrane stress, it is extremely important to control the hydrogen supply and RF power in combination in order to obtain a membrane with tensile stress. When the hydrogen flow is too low or the RF power is too high as compared to that set to form a film with tensile stress, the film stress will change to compressive stress and therefore it is very important to control both hydrogen flow and RF power .
TDMAT 는 암모니아와 동시에 공급될 수 없기 때문에, 암모니아가 막을 성막하는데 사용될 때, 전구체를 공급한 후에, 전구체로부터 암모니아로 가스를 전환시키는 단계가 필요하다. 하지만, 일부 실시형태들에서, 암모니아가 사용되지 않고, 따라서, 전구체를 공급한 후에 전환 단계는 필요하지 않고, 그에 의해 막 성장 레이트를 향상시킨다.Since TDMAT can not be supplied simultaneously with ammonia, when ammonia is used to form a film, it is necessary to convert the gas from the precursor to ammonia after supplying the precursor. However, in some embodiments, ammonia is not used, and therefore, no conversion step is required after supplying the precursor, thereby improving the film growth rate.
TiON 막들을 평가하는 동안에, NF3 에 의한 건조 식각 레이트 및 불화 수소에 의한 습식 식각 레이트가, 교번하여 라미네이트된 TiO 층들과 TiN 층들 사이의 경계에서 변화되는 것이 발견되었다. 즉, 라미네이트가 TiO 층들과 TiN 층들 사이에 경계를 가질 때, TiO 또는 TiN 단일 층과 비교하여, 라미네이트의 NF3 에 의한 건식 식각에 대한 저항이 높고, 라미네이트의 불화 수소에 의한 습식 식각 레이트에 대한 저항이 저하된다. 위의 상관은 TiO 층들과 TiN 층들 사이의 경계의 수가 증가할 때 향상된다. 즉, 경계의 수가 더 높아질 때, 건식 식각에 대한 저항이 더 높아지고 습식 식각에 대한 저항이 더 낮아진다.During the evaluation of the TiON films, it has been found that the dry etch rate by NF 3 and the wet etch rate by hydrogen fluoride alternate at the interface between the
일부 실시형태들에서, 막의 스텝 커버리지는 약 90% 내지 약 105%, 통상적으로 약 95% 이상이다.In some embodiments, the step coverage of the film is from about 90% to about 105%, typically about 95% or more.
그 실시형태들은 바람직한 실시형태들을 참조하여 설명될 것이다. 하지만, 본 발명은 그 바람직한 실시형태들에 한정되지 않는다.The embodiments will be described with reference to the preferred embodiments. However, the present invention is not limited to the preferred embodiments thereof.
도 1은, 바람직하게는 이하의 시퀀스들을 수행하도록 프로그램된 제어들과 함께, 본 발명의 일부 실시형태들에서 사용가능한, PEALD 장치의 개략도이다. 동 도에서, 반응 챔버 (3) 의 내부 (11) 에서 서로 대향하고 평행한 한 쌍의 도전성 평판 전극들 (4, 2) 을 제공하고, HRF 전력 (13.56 MHz 또는 27 MHz) (5) 및 5MHz 이하의 LRF 전력 (400 kHz~500 kHz) (50) 을 일측에 인가하고, 타측에 대해 전기 접지 (12) 하는 것에 의해, 플라즈마가 전극들 사이에서 여기된다. 온도 조절기가 하부 스테이지 (2) (하부 전극) 에 제공되고, 그 위에 놓여진 기판 (1) 의 온도는 주어진 온도로 일정하게 유지된다. 상부 전극 (4) 은 또한 샤워 플레이트의 역할을 하고, 반응 가스 및 희가스가 가스 흐름 제어기 (23), 펄스 흐름 제어 밸브 (31) 및 샤워 플레이트를 통해 반응 챔버 (3) 내에 도입된다. 추가적으로, 반응 챔버 (3) 에서, 배기 파이프 (6) 가 제공되고, 이를 통해 반응 챔버 (3) 의 내부 (11) 에 있는 가스가 배기된다. 추가적으로, 반응 챔버에는 반응 챔버 (3) 의 내부 (11) 로 시일 가스를 도입하기 위하여 시일 가스 흐름 제어기 (24) 가 제공된다 (반응 챔버의 내부에서 반응 구역 및 이송 구역을 분리시키기 위한 분리 플레이트가 동 도로부터 생략되어 있다).Figure 1 is a schematic diagram of a PEALD device, which may be used in some embodiments of the invention, preferably with controls programmed to perform the following sequences. In the figure, a pair of conductive
당업자는, 그 장치가, 본원의 다른 곳에 기재된 성막 및 반응기 세정 프로세스들로 하여금 수행되게 하도록 프로그램되거나 또는 다른 방법으로 구성된 하나 이상의 제어기(들) (미도시) 를 포함한다는 것을 인식할 것이다. 제어기(들) 은 다양한 전력 소스들, 가열 시스템들, 펌프들, 로보틱스 및 가스 흐름 제어기들 또는 반응기의 밸브들과 연통되는데, 이는 당업자에 의해 인식될 것이다.Those skilled in the art will recognize that the apparatus includes one or more controller (s) (not shown) that are programmed or otherwise configured to cause the deposition and reactor cleaning processes described elsewhere herein to be performed. The controller (s) are in communication with the various power sources, heating systems, pumps, robotics and gas flow controllers or valves of the reactor, which will be appreciated by those skilled in the art.
실시예Example
예 1 내지 6Examples 1 to 6
Ti 함유 막들이, 도 6에 예시된 시퀀스 및 도 1에 예시된 장치를 사용하여 이하의 표 7 및 8에 나타낸 조건들하에서 패턴들 (종횡비: 2:1) 을 갖는 기판들 상에 성막되었다.Ti containing films were deposited on substrates having patterns (aspect ratio: 2: 1) under the conditions shown in Tables 7 and 8 below using the sequence illustrated in FIG. 6 and the apparatus illustrated in FIG.
이렇게 획득된 막들이 평가되었고, 그 결과들은 표 9에 나타나 있다.The membranes thus obtained were evaluated, and the results are shown in Table 9.
표 9에 나타낸 바처럼, TiN 막들이, 질소 흐름 없이 상대적으로 높은 흐름의 수소를 사용하여 (예 5), 그리고 상대적으로 높은 RF 전력으로 상대적으로 높은 흐름의 수소를 사용하여 (예 4) 형성되었다. 수소 흐름에 상대적으로 질소 흐름이 증가되었을 때, 막에서 탄소 함량이 증가되었고, 그에 의해 TiCN 막들 (예 1 내지 3) 을 형성한다. 예 1 내지 5에서, 각 막의 스텝 커버리지는 95% 이상이었고, 막 응력은 -3,800 MPa 과 +620 MPa 사이에서 변화되었고, 또한, 각 막은 습식 식각에 대해 높은 저항을 나타냈다. 예 6에서, 높은 품질의 TiO 막이 형성되었다. 도 4는, 예 3에서 형성된 컨포멀 TiCN 막의 단면도의 투과 전자 현미경 (TEM) 사진이다.As shown in Table 9, TiN films were formed (Example 4) using a relatively high flow of hydrogen without nitrogen flow (Example 5) and a relatively high flow of hydrogen with a relatively high RF power (Example 4) . When the nitrogen flow is increased relative to the hydrogen flow, the carbon content in the film is increased, thereby forming TiCN films (Examples 1 to 3). In Examples 1 to 5, the step coverage of each film was greater than 95%, the film stress varied between -3,800 MPa and +620 MPa, and each film exhibited a high resistance to wet etching. In Example 6, a
예 7-10Example 7-10
Ti 함유 막들이, 도 6에 예시된 시퀀스 및 도 1에 예시된 장치를 사용하여 표 8 및 이하의 표 10에 나타낸 조건들하에서 패턴들 (종횡비: 2:1) 을 갖는 기판들 상에 성막되었다.Ti containing films were deposited on substrates having patterns (aspect ratio: 2: 1) under the conditions shown in Table 8 and Table 10 below using the sequence illustrated in FIG. 6 and the apparatus illustrated in FIG. 1 .
이렇게 획득된 막들이 평가되었고, 그 결과들은 표 11 내지 13에 나타나 있다.The membranes thus obtained were evaluated, and the results are shown in Tables 11-13.
예 7 내지 9 에서, 경향으로서, RF 전력이 더 낮을 때, 그리고 온도가 더 높을 때, 탄소 함량이 더 높아졌다. 표 11 내지 13에 나타낸 바처럼, RF 전력을 감소시키고 온도를 증가시킴으로써, 막의 탄소 함량이 감소되었고, 막 응력이 압축성이 되었다 (예 7 내지 9). 예 7 내지 9에서, 각 막의 스텝 커버리지는 약 100% 였고, 막 응력은 약 -4,500 MPa 과 +2,000 MPa 사이에서 변화되었고, 또한, 각 막은 습식 식각에 대해 높은 저항을 나타냈다. 예 10에서, 높은 품질의 TiO 막이 형성되었고, 이는 RF 전력 및 온도의 변화에 의해 현저히 영향받지 않았다.In Examples 7 to 9, as a trend, the carbon content was higher when the RF power was lower and when the temperature was higher. By reducing the RF power and increasing the temperature, as shown in Tables 11-13, the carbon content of the membrane was reduced and the membrane stress became compressible (Examples 7 to 9). In Examples 7 to 9, the step coverage of each film was about 100%, the film stress was varied between about -4,500 MPa and +2,000 MPa, and each film exhibited a high resistance to wet etching. In Example 10, a
예 11-16Example 11-16
라미네이트들에 의해 구성된 Ti 함유 막들이, 도 6에 예시된 시퀀스 및 도 1에 예시된 장치를 사용하여 이하의 표 14 및 15에 나타낸 조건들하에서 패턴들 (종횡비: 2:1) 을 갖는 기판들 상에 성막되었다.The Ti-containing films constituted by the laminates were laminated to the substrates having patterns (aspect ratio: 2: 1) under the conditions shown in Tables 14 and 15 below using the sequence illustrated in Fig. 6 and the apparatus illustrated in Fig. It was settled on.
예 16에서, 각 TiCN 층이 예 1에 있는 것과 같은 조건하에서 형성되었다.In Example 16, each TiCN layer was formed under the same conditions as in Example 1.
이렇게 획득된 막들이 평가되었고, 그 결과들은 표 16에 나타나 있다.The membranes thus obtained were evaluated, and the results are shown in Table 16.
표 16에 나타낸 바처럼, 예 13-16 에서 라미네이트들의 습식 및 건식 식각 레이트 성질들은 예 11 및 12에 있는 2개의 베이스 막들의 그러한 것들간의 범위내에 속하는 것이 아니라 그들의 양자 모두와는 상이했다. TiN 막과 TiO 막 사이의 경계의 수가 증가될 때, 건식 식각 레이트가 감소되는 반면에, 습식 식각 레이트는 증가되었다 (예 13-15).As shown in Table 16, the wet and dry etch rate properties of the laminates in Examples 13-16 were not within the range between those of the two base films in Examples 11 and 12, but were different from both of them. As the number of boundaries between the TiN film and the
예 17-19Example 17-19
막들은 예 11, 12, 및 14 에서와 동일한 조건들하에서 형성되었고, 건식 식각 레이트 및 습식 식각 레이트가 각 막에 대해 측정되었다. 도 8은 예 18에서 형성된 TiN 막, 예 17에서 형성된 TiO 막, 그리고 예 19에서 형성된 TiON 막의 건식 식각 레이트들을 나타내는 그래프이다. TiON 막의 건식 식각 레이트는 TiN 막의 그것 및 TiO 막의 그것보다 두드러지게 낮았다. 도 9는 예 18에서 형성된 TiN 막, 예 17에서 형성된 TiO 막, 그리고 예 19에서 형성된 TiON 막의 습식 식각 레이트들을 나타내는 그래프이다. TiON 막의 습식 식각 레이트는 TiN 막의 그것 및 TiO 막의 그것보다 두드러지게 더 높았다.The films were formed under the same conditions as in Examples 11, 12, and 14, and the dry etch rate and wet etch rate were measured for each film. 8 is a graph showing the dry etch rates of the TiN film formed in Example 18, the TiO film formed in Example 17, and the TiON film formed in Example 19; The dry etch rate of the TiON film was significantly lower than that of the TiN film and that of the TiO film. 9 is a graph showing the wet etch rates of the TiN film formed in Example 18, the TiO film formed in Example 17, and the TiON film formed in Example 19; The wet etch rate of the TiON film was significantly higher than that of the TiN film and that of the TiO film.
예 20Example 20
막 형성 프로세스 후에, 막이 약 2시간 동안 약 600℃ 에서 어닐링된 것을 제외하고는, 예 6에서와 동일한 조건하에서 형성되었다. 도 3은, 막이 아나타제 타입 결정들을 형성한다는 것을 나타내는, 어닐링된 막의 X-선 회절 분석의 결과를 나타낸다.After the film forming process, the film was formed under the same conditions as in Example 6, except that the film was annealed at about 600 캜 for about 2 hours. Figure 3 shows the results of an X-ray diffraction analysis of an annealed film, indicating that the film forms anatase type crystals.
예 21-32Example 21-32
Ti 함유 막들이, 도 6에 예시된 시퀀스 및 도 1에 예시된 장치를 사용하여 표 8 및 이하의 표 17에 나타낸 조건들하에서 패턴들 (종횡비: 2:1) 을 갖는 기판들 상에 성막되었다.Ti containing films were deposited on substrates having patterns (aspect ratio: 2: 1) under the conditions shown in Table 8 and Table 17 below using the sequence illustrated in FIG. 6 and the apparatus illustrated in FIG. 1 .
이렇게 획득된 막들이 평가되었고, 그 결과들은 표 18에 나타나 있다.The membranes thus obtained were evaluated, and the results are shown in Table 18.
도 10은 예 21 내지 25에서 형성된 TiCN 막들의 푸리에 변환 적외 (FT-IR) 스펙트럼들을 나타내고, 여기서, 예 21 은 참조예 (“POR”, process of record) 이다. 막 응력은 막에서 결합 상태에 따라 달라졌다. 일반적으로 2,000 cm-1 에서의 피크는 인장 응력을 나타내는 반면, 1,400 cm-1 에서의 피크는 압축 응력을 나타낸다. 이들 응력들의 합이 막의 응력을 나타낸다. 반응물 가스로서 사용된 수소 가스의 흐름이 예 21 내지 23에서 감소되었을 때, 1,400 cm-1에서의 피크는 증가되었고, 막은 압축성이 되었다. 예 21에서, RF 전력이 예 24에서 증가되었을 때, 2,000 cm-1 에서의 피크는 감소되었고, 이는 막의 결정질이 증가되었고, 막이 매우 압축성이 되었음을 나타낸다.10 shows the Fourier Transform Infrared (FT-IR) spectra of the TiCN films formed in Examples 21 to 25, wherein Example 21 is a reference ("POR", process of record). The film stresses varied depending on the bonding state in the film. Generally, peaks at 2,000 cm -1 exhibit tensile stresses, while peaks at 1,400 cm -1 exhibit compressive stresses. The sum of these stresses represents the stress of the film. When the flow of hydrogen gas used as the reactant gas was reduced in Examples 21 to 23, the peak at 1,400 cm <" 1 > was increased and the membrane became compressive. In Example 21, when the RF power was increased in Example 24, the peak at 2,000 cm <" 1 > decreased, indicating that the crystalline quality of the film was increased and the film was very compressive.
도 11은 예 26 내지 29에서 형성된 TiCN 막들의 푸리에 변환 적외 (FT-IR) 스펙트럼들을 나타낸다. 온도가 예 26 내지 29에서 더 높았을 때, 2,000 cm-1에서의 피크가 더 높았다. 2,000 cm-1에서의 피크는 막 형성을 위한 온도에 의해 제어될 수 있다.11 shows Fourier Transform Infrared (FT-IR) spectra of TiCN films formed in Examples 26-29. When the temperature was higher in Examples 26 to 29, the peak at 2,000 cm -1 was higher. The peak at 2,000 cm -1 may be controlled by the temperature for film formation.
도 13은 예 30 내지 32에서 형성된 TiCN 막들의 푸리에 변환 적외 (FT-IR) 스펙트럼들을 나타낸다. RF 전력이 예 30 내지 32에서 수소 가스 흐름을 사용하지 않고서 증가되었을 때, 1,400 cm-1에서의 피크는 더 높아졌고, 2,000 cm-1에서의 피크는 더 낮아졌고, 막 응력이 매우 압축성이 되었다.13 shows Fourier Transform Infrared (FT-IR) spectra of TiCN films formed in Examples 30-32. When the RF power was increased without using a hydrogen gas flow in Examples 30 to 32, the peak at 1,400 cm -1 became higher, the peak at 2,000 cm -1 became lower, and the membrane stress became very compressive .
도 14는 : (a) 예 21에서 획득된 TiCN 막 (탄소 함량: 6%) 의 X-선 회절 분석의 결과, 그리고 (b) 예 23에서 획득된 TiCN 막 (탄소 함량: 16%) 의 X-선 회절 분석의 결과를 나타낸다. 도 14에서 (a) 에 나타낸 바처럼, 낮은 탄소 함량 (6%) 을 갖는 막은 결정질 (예 21) 인 반면에, 도 14에서 (b) 에 나타낸 바처럼, 높은 탄소 함량 (16%) 을 갖는 막은 비정질이었다 (예 23). 막을 구성하는 결정들은, 실질적으로 NaCl 과 동일한 fcc (면심 입방) 구조를 갖는 오스보나이트 TiN 이었다. 막은 다수의 결정들을 포함하지만, 그것들은 주로 (111) 면에서 성장했다.Fig. 14 shows the results of X-ray diffraction analysis of (a) the TiCN film (carbon content: 6%) obtained in Example 21 and (b) the X of the TiCN film (carbon content: 16% Ray diffraction analysis. As shown in Fig. 14 (a), a film having a low carbon content (6%) is crystalline (Example 21), while a film having a high carbon content (16% The membrane was amorphous (Example 23). The crystals constituting the film were os- bonite TiN having a fcc (face-centered cubic) structure substantially the same as NaCl. The film contains a large number of crystals, but they have grown mainly on the (111) plane.
도 15는 : (a) 예 21 내지 23에서 형성된 TiCN 막들의 푸리에 변환 적외 (FT-IR) 스펙트럼들, 및 (b) 예 21 내지 23에서 형성된 TiCN 막들의 X-선 회절 (XRD) 분석의 결과들을 나타낸다. 도 15에 있는 (a) 및 (b) 에 나타낸 바처럼, 1,400 cm-1에서의 피크가 감소되었을 때, XRD 에서 (111) 의 피크는 증가되었고, 이는 1,400 cm-1 에서의 피크가 (111) 결정면 상의 원자 배열과 연관되었다는 것을 나타낸다.Figure 15 shows the results of X-ray diffraction (XRD) analysis of (a) Fourier transform infrared (FT-IR) spectra of TiCN films formed in Examples 21-23 and (b) TiCN films formed in Examples 21-23 . Like a bar in Fig. (A) and (b) in 15, when the reduction in the peak at 1,400 cm -1, the peak in the XRD (111) was increased, which is a peak at 1,400 cm -1 (111 ) ≪ / RTI > crystal plane.
도 16은 : (a) 예 21 및 24에서 형성된 TiCN 막들의 푸리에 변환 적외 (FT-IR) 스펙트럼들, 및 (b) 예 21 및 24에서 형성된 TiCN 막들의 X-선 회절 (XRD) 분석의 결과들을 나타낸다. 도 16에 있는 (a) 및 (b) 에 나타낸 바처럼, 2,000 cm-1에서의 피크가 감소되었을 때, XRD 에서 (200) 의 피크는 증가되었고, 이는 2,000 cm-1 에서의 피크가 (200) 결정면 상의 원자 배열과 연관되었다는 것을 나타낸다. 일반적으로, (1,400 cm-1 및 2,000 cm-1 에서의) FT-IR 피크들이 감소되고, 막의 결정질은 향상된다.Figure 16 shows the results of X-ray diffraction (XRD) analysis of (a) Fourier transform infrared (FT-IR) spectra of TiCN films formed in Examples 21 and 24 and (b) TiCN films formed in Examples 21 and 24 . Like a bar in Fig. (A) and (b) in 16, when the reduction in the peak at 2,000 cm -1, the peak in the XRD (200) was increased, which is a peak at 2,000 cm -1 (200 ) ≪ / RTI > crystal plane. In general, the FT-IR peaks (at 1,400 cm -1 and 2,000 cm -1 ) are reduced and the crystalline quality of the film is improved.
예 33-40Example 33-40
Ti 함유 막들이, 도 6에 예시된 시퀀스 및 도 1에 예시된 장치를 사용하여 표 8 및 이하의 표 19에 나타낸 조건들하에서 패턴들 (종횡비: 2:1) 을 갖는 기판들 상에 성막되었다.Ti containing films were deposited on substrates having patterns (aspect ratio: 2: 1) under the conditions shown in Table 8 and Table 19 below using the sequence illustrated in FIG. 6 and the apparatus illustrated in FIG. 1 .
이렇게 획득된 막들이 평가되었고, 그 결과들은 도 17에 나타나 있다. 도 17 은 예 33 내지 36에서 막 응력과 수소 흐름 사이의 관계를 나타내는 그래프와, 예 37 내지 40에서 막 응력과 RF 전력 사이의 관계를 나타내는 그래프를 도시한다. 도 17에 나타낸 바처럼, 막 응력은 수소 흐름에 의해 제어되었고, 수소 흐름이 증가되었을 때, 막 응력은 인장성이 되었다 (예 35 및 36). 또한, RF 전력이 증가되었을 때, 막 응력이 압축성이 되었다 (예 40). 제어 파라미터들과 조합하여 수소 흐름 및 RF 전력을 사용함으로써, 막 응력이 약 -2,500 MPa 과 약 +1,000 MPa 사이에서 조정될 수 있다.The thus obtained films were evaluated, and the results are shown in Fig. Figure 17 shows a graph showing the relationship between membrane stress and hydrogen flow in Examples 33-36 and a graph showing the relationship between membrane stress and RF power in Examples 37-40. As shown in Fig. 17, the membrane stress was controlled by the hydrogen flow, and when the hydrogen flow was increased, the membrane stress became tensile (Examples 35 and 36). Also, when the RF power was increased, the membrane stress became compressive (Example 40). By using hydrogen flow and RF power in combination with control parameters, the membrane stress can be adjusted between about -2,500 MPa and about +1,000 MPa.
예 41-44Example 41-44
Ti 함유 막들이, 도 6에 예시된 시퀀스 및 도 1에 예시된 장치를 사용하여 표 8 및 이하의 표 20에 나타낸 조건들하에서 패턴들 (종횡비: 2:1) 을 갖는 기판들 상에 성막되었다.Ti containing films were deposited on substrates having patterns (aspect ratio: 2: 1) under the conditions shown in Table 8 and Table 20 below using the sequence illustrated in FIG. 6 and the apparatus illustrated in FIG. 1 .
이렇게 획득된 막들이 평가되었고, 그 결과들은 표 21에 나타나 있다.The membranes thus obtained were evaluated, and the results are shown in Table 21.
예 41 내지 44에서, TDEAT 가 TDMAT 대신에 사용되었다. 표 21에 나타낸 바처럼, TDEAT 으로부터 도출된 막들에 대한 RF 전력의 효과는 TDMAT 으로부터 도출된 막들에 대한 그것과는 현저히 상이했다. 질소가 사용되었을 때 (예 41), RF 전력이 더 낮았을 때, 탄소 함량이 더 낮은 반면, 수소가 사용되거나 포함되었을 때 (예 42 및 43), RF 전력이 더 낮았을 때, 탄소 함량이 더 높았다. 산소가 사용되었을 때 (예 44), RF 전력은 탄소 함량에 영향을 미치지 않았다. 예 41 내지 44에서, 각 막의 스텝 커버리지는 약 100% 였고, 막 응력은 약 -5,000 MPa 과 +2,000 MPa 사이에서 변화되었고, 또한, 각 막은 습식 식각에 대해 높은 저항을 나타냈다. 예 41 내지 44에서, 막 응력은 400 W 과 600 W 사이의 RF 전력에서 극적으로 변화했고, 이는 결정질 상태가 RF 전력의 함수로서 변화했음을 나타낸다.In Examples 41 to 44, TDEAT was used instead of TDMAT. As shown in Table 21, the effect of RF power on the films derived from TDEAT was significantly different from that for films derived from TDMAT. When nitrogen is used (Example 41), when the RF power is lower, the carbon content is lower, while when the hydrogen is used or included (Examples 42 and 43), when the RF power is lower, Higher. When oxygen was used (Example 44), RF power did not affect the carbon content. In Examples 41 to 44, the step coverage of each film was about 100%, the film stress was changed between about -5,000 MPa and +2,000 MPa, and each film exhibited a high resistance to wet etching. In Examples 41 to 44, the film stress varied dramatically at RF power between 400 W and 600 W, indicating that the crystalline state changed as a function of RF power.
본 발명은 위의 언급된 실시형태들 및 다음을 포함하는 다른 다양한 실시형태들을 포함한다: The present invention includes other various embodiments including the above-mentioned embodiments and the following:
1) TDMAT 또는 TDEAT 를 사용하여 ALD 에 의해 Ti 함유 막을 형성하는 방법에 있어서, 그 방법은, 성막 온도가 50℃ 내지 250℃ (예를 들어, 150℃ 미만) 의 범위에 있고, 오로지 반응물 가스를 변경하는 것에 의해서, 95% 이상의 스텝 커버리지를 갖는 TiO, TiON, TiN, TiCN, 및 TiOCN 막들로부터 선택된 다양한 막들이 기판 상에 성막될 수 있는 것을 특징으로 한다. 특히, 그 방법은, TiN 막이 수소 함유 반응물 그리고 전구체 자체에 포함된 질소를 사용하여, 암모니아 및 질소 등의 질소 함유 반응물 없이, 성막될 수 있는 것을 특징으로 한다. 그 방법은 또한, 인장 응력을 갖는 TiN 막이, 막 응력을 제어하는 목적을 위해 RF 전력 제어 및 시트 저항 제어와 조합하여 반응물 가스로서 수소를 사용하여 성막될 수 있는 것을 특징으로 한다.1) A method of forming a Ti-containing film by ALD using TDMAT or TDEAT, the method being characterized in that the film formation temperature is in the range of 50 to 250 캜 (e.g., less than 150 캜) The various films selected from TiO2, TiON, TiN, TiCN, and TiOCN films having a step coverage of 95% or more can be deposited on the substrate. In particular, the method is characterized in that the TiN film can be deposited without nitrogen-containing reactants such as ammonia and nitrogen, using the hydrogen-containing reactant and the nitrogen contained in the precursor itself. The method is also characterized in that a TiN film with tensile stress can be deposited using hydrogen as the reactant gas in combination with RF power control and sheet resistance control for the purpose of controlling the film stress.
2) 1) 에 따른 방법은, TiCN 막이 반응물로서 질소 또는 수소와 조합한 질소일 때 성막되는 것을 특징으로 한다.2) The method according to 1) is characterized in that a film is formed when the TiCN film is nitrogen combined with nitrogen or hydrogen as a reactant.
3) 1) 에 따른 방법에서, TiON 막 및 TiOCN 막이 각각 TiN 및 TiCN 에 의해 주로 구성되는 막들에 산소를 첨가하는 것에 의해 성막될 수 있고, 여기서 라미네이트 구조는 TiO 층 및 TiN 또는 TiCN 층을 교번하여 성막하는 것에 의해 형성된다. 특히, 그 방법은, TiON 막이 형성될 때, NF3를 사용한 건식 식각 레이트, 불화 수소를 사용한 습식 식각 레이트, 및 시트 저항이 제어될 수 있는 것을 특징으로 한다.3) In the process according to 1), the TiON film and the TiOCN film can be deposited by adding oxygen to the films consisting mainly of TiN and TiCN, respectively, wherein the laminate structure alternates the
4) 1) 에 따른 방법은 TiO 막이 산소 뿐만 아니라 TDMAT 또는 TDEAT 를 사용하여 성막될 수 있는 것을 특징으로 한다.4) The method according to 1) is characterized in that the
5) 1)에 따른 방법에서, 반응물 가스는 TiO, TiON, TiN, TiCN, 또는 TiOCN 막을 형성하기 위하여 He, Ar, H2, N2, O2, N2O, 및 H2O 로 이루어지는 군으로부터 선택된 하나의 가스 또는 혼합된 가스이고, 여기에서 He의 유량은 0 내지 8000 sccm이고, Ar의 유량은 0 내지 8000 sccm이고, H2 의 유량은 0 내지 5000 sccm이고, N2 의 유량은 0 내지 500 sccm이고, O2 의 유량은 0 내지 5000 sccm이고, N2O 의 유량은 0 내지 5000 sccm이고, H2O 의 유량은 0 내지 5000 sccm이다.5) In the process according to 1), the reactant gas is selected from the group consisting of He, Ar, H 2 , N 2 , O 2 , N 2 O and H 2 O to form
6) 1)에 따른 방법에서, 성막되는 막의 조성들이 다음과 같이 제어될 수 있다: C: 0 원자% 내지 25 원자%; Ti: 10 원자% 내지 40 원자%; N: 0 원자% 내지 50 원자%; O: 0 원자% 내지 70 원자%; H: 3 원자% 내지 25 원자%.6) In the method according to 1), the compositions of the film to be deposited can be controlled as follows: C: 0 atom% to 25 atom%; Ti: 10 atom% to 40 atom%; N: 0 atom% to 50 atom%; O: 0 atom% to 70 atom%; H: 3 atom% to 25 atom%.
7) 1) 에 따른 방법은, 막 응력이 다음 중 적어도 어느 하나를 변경함으로써 제어될 수 있다: 처리 온도, 반응물 가스로서 사용되는 H2 의 유량, 및 RF 전력.7) The method according to 1) can be controlled by changing at least one of the following: the processing temperature, the flow rate of H 2 used as the reactant gas, and the RF power.
8) 7) 에 따른 방법에서, 막 응력이 -5,000 MPa 내지 +1,500 MPa의 범위에서 제어될 수 있다.8) In the method according to 7), the film stress can be controlled in the range of -5,000 MPa to +1,500 MPa.
9) 7)에 따른 방법에서, 기판 온도가 70℃ 내지 250℃ 이고, H2 의 유량이 50 sccm 내지 2,000 sccm이고, RF 전력이 150 W 내지 500 W인 조건들하에서 인장 응력이 획득될 수 있다.9) In the method according to 7), tensile stress can be obtained under the conditions that the substrate temperature is 70 ° C. to 250 ° C., the flow rate of H 2 is 50 sccm to 2,000 sccm, and the RF power is 150 W to 500 W .
10) 1) 에 따른 방법에서, 시트 저항이 10Ω/sq. 내지 5,000Ω/sq.의 범위에서 제어될 수 있다.10) The method according to 1), wherein the sheet resistance is 10? / Sq. To 5,000 OMEGA / sq. ≪ / RTI >
11) 3) 에 따른 방법에서, TiO 및 TiN 또는 TiCN 의 각 층의 두께는 0.06 nm 내지 10 nm의 범위에 있다.11) In the method according to 3), the thickness of each layer of
12) 3) 에 따른 방법에서, TiO 층들의 수 대 TiN 또는 TiCN 층들의 수의 비는 예를 들어 두께가 20 nm 인 라미네이트에 대해 1:333 내지 333:1의 범위에 있다.12) In the method according to 3), the ratio of the number of
13) 3) 에 따른 방법은 전체 산소 농도가 TiO 층들의 두께를 감소 또는 증가시키는 것에 의해, 즉, TiN 또는 TiCN 층들의 두께를 상대적으로 증가 또는 감소시키는 것에 의해 제어될 수 있는 것을 특징으로 한다. 위의 방법은 또한, 탄소 농도 및 질소 농도를 제어하는데 사용될 수 있다.13) The method according to 3) is characterized in that the total oxygen concentration can be controlled by reducing or increasing the thickness of the
14) 3) 에 따른 방법에서, TiON 막이 형성되고, NF3 를 사용한 그의 건식 식각 레이트 및 불화 수소를 사용한 습식 식각 레이트는, 라미네이트될 TiO 층들 및 TiN 층들의 수를 변경함으로써 제어될 수 있다.14) In the method according to 3), a TiON film is formed, and its dry etching rate using NF 3 and the wet etching rate using hydrogen fluoride can be controlled by changing the number of
15) 14) 에 따른 방법에서, NF3를 사용한 건식 식각 레이트는 TiO 단일 막의 그것의 0.03 배 내지 1 배로 제어될 수 있고, 라미네이트를 구성하는 층들의 수가 증가할 때, 건식 식각에 대한 저항이 향상, 즉, 증가된다.15) In the method according to 14), the dry etching rate using NF 3 can be controlled to 0.03 to 1 times that of the
16) 14) 에 따른 방법에서, 불화 수소를 사용한 습식 식각 레이트는 TiO 단일 막의 그것의 1 배 내지 10 배로 제어될 수 있고, 라미네이트를 구성하는 층들의 수가 증가할 때, 습식 식각에 대한 저항이 저하, 즉, 감소된다.16) In the method according to 14), the wet etch rate using hydrogen fluoride can be controlled to be 1 to 10 times that of the
17) 1) 에 따른 방법은, 비정질 TiO 막이, 용이하게 산화되는 Ti의 특성에 기인하여 PEALD 에 의해서 뿐만 아니라 열적 ALD 에 의해서도 형성될 수 있는 것을 특징으로 한다.17) The method according to 1) is characterized in that the
18) 1)에 따른 방법은 TiO 막을 형성한 후에 400℃내지 1,000℃의 온도에서 열적 어닐링을 수행하는 것에 의해, 아나타제 타입 TiO2 결정들, 루틸 타입 TiO2 결정들, 또는 브루카이트 타입 TiO2 결정들이 어닐링 온도에 따라 형성될 수 있는 것을 특징으로 한다.18) 1) a method of the by performing a thermal annealing at a temperature of 400 ℃ to 1,000 ℃ after forming film TiO, the anatase type TiO 2 crystal, rutile-type TiO 2 crystal according, or brookite-type TiO 2 crystals Can be formed according to the annealing temperature.
19) 18) 에 따른 방법은 아나타제 타입 TiO2 결정들 또는 루틸 타입 TiO2 결정들이 광촉매 활성을 나타내고, 또한 아나타제 타입 TiO2 결정들이 초친수성을 나타내는 것을 특징으로 한다.19) The method according to 18) is characterized in that anatase type TiO 2 crystals or rutile type TiO 2 crystals exhibit photocatalytic activity, and anatase type TiO 2 crystals exhibit superhydrophilic properties.
20) 1) 에 따른 방법에서, RF 전력이 10 W 내지 2,000 W의 범위에 있다.20) In the method according to 1), the RF power is in the range of 10 W to 2,000 W.
21) 1) 에 따른 방법은 막의 스텝 커버리지가 95% 이상인 것을 특징으로 한다.21) The method according to 1) is characterized in that the step coverage of the film is 95% or more.
22) 1) 에 따른 방법은 실리콘 기판을 유지하는 서셉터의 온도가 0℃ 내지 600℃의 범위에 있고, 장치에 설치된 플라즈마 생성기는 1 MHz 과 60 MHz 사이의 임의의 주파수를 갖는 것을 특징으로 한다.22) The method according to 1), characterized in that the temperature of the susceptor holding the silicon substrate is in the range of 0 ° C. to 600 ° C., and the plasma generator installed in the apparatus has an arbitrary frequency between 1 MHz and 60 MHz .
당업자는, 본 발명의 사상으로부터 이탈함이 없이 수많은 그리고 다양한 변경들이 이루어질 수 있다는 것을 이해할 것이다. 그러므로, 본 발명의 형태들은 단지 예시적이고 본 발명의 범위를 제한하도록 의도된 것이 아니라는 것이 분명히 이해되야 한다. It will be understood by those skilled in the art that numerous and various modifications may be made without departing from the spirit of the invention. It is therefore to be clearly understood that the forms of the invention are illustrative only and are not intended to limit the scope of the invention.
Claims (18)
(i) 기판이 배치되는 반응 공간에 펄스로 TDMAT 및/또는 TDEAT 를 도입하는 단계;
(ii) 상기 반응 공간에 NH3 무함유 반응물 가스를 연속적으로 도입하는 단계;
(iii) 상기 반응 공간에 펄스로 RF 전력을 인가하는 단계로서, TDMAT 및/또는 TDEAT 의 펄스 그리고 RF 전력의 펄스는 오버랩되지 않는, 상기 인가하는 단계; 및
(iv) 상기 기판 상에 Ti 함유 막을 성막하기 위하여 (i) 내지 (iii) 단계들을 반복하는 단계를 포함하는, Ti 함유 막을 형성하는 방법.A method of forming a Ti-containing film on a substrate by plasma enhanced atomic layer deposition (PEALD) using tetrakis (dimethylamino) titanium (TDMAT) or tetrakis (diethylamino) titanium (TDEAT)
(i) introducing TDMAT and / or TDEAT into the reaction space in which the substrate is placed in a pulse;
(ii) continuously introducing an NH 3 -containing reactant gas into the reaction space;
(iii) applying RF power in pulses to the reaction space, wherein pulses of TDMAT and / or TDEAT and pulses of RF power do not overlap; And
(iv) repeating steps (i) to (iii) to form a Ti-containing film on the substrate.
상기 NH3 무함유 반응물 가스는 H2 및/또는 N2인, Ti 함유 막을 형성하는 방법.The method according to claim 1,
Wherein the NH 3 -free reactant gas is H 2 and / or N 2 .
상기 NH3 무함유 반응물 가스는 질소를 함유하지 않거나 또는 산소를 함유하지 않는, Ti 함유 막을 형성하는 방법.The method according to claim 1,
The NH 3 reagent gas-free or containing no oxygen or not contain nitrogen, a method of forming a film containing Ti.
상기 NH3 무함유 반응물 가스는 산소를 포함하는, Ti 함유 막을 형성하는 방법.The method according to claim 1,
Wherein the NH 3 -containing reactant gas comprises oxygen.
상기 NH3 무함유 반응물 가스가 H2 및 희가스로 이루어짐으로써, (iv) 단계에서 상기 Ti 함유 막으로서 TiN 결정질 막을 성막하는, Ti 함유 막을 형성하는 방법.3. The method of claim 2,
Wherein the NH 3 -containing reactant gas is composed of H 2 and a rare gas, thereby forming a Ti-containing crystalline film as the Ti-containing film in the step (iv).
상기 NH3 무함유 반응물 가스가 H2, N2 및 희가스로 이루어짐으로써, (iv) 단계에서 상기 Ti 함유 막으로서 TiCN 비정질 막을 성막하는, Ti 함유 막을 형성하는 방법.3. The method of claim 2,
Wherein the Ti-containing amorphous film is formed as the Ti-containing film in the step (iv), wherein the NH 3 -containing reactant gas is composed of H 2 , N 2 and a rare gas.
상기 Ti 함유 막은 막 응력이 -2,500 MPa 내지 800 MPa 인, Ti 함유 막을 형성하는 방법.The method according to claim 1,
Wherein the Ti-containing film has a film stress of -2,500 MPa to 800 MPa.
(ii) 단계에서 상기 반응물 가스로서 사용된 H2 의 참조 유량 (reference flow rate), (iii) 단계에서 사용된 참조 RF 전력, 및 (i) 내지 (iii) 전체에 걸친 참조 성막 온도를 포함하는 성막 조건들하에서 (i) 내지 (iv) 단계들에 의해 성막되는 TiN 결정질 막의 막 응력보다 더 큰, 상기 Ti 함유 막을 위한 타겟 막 응력을 설정하는 단계; 및
(ii) 단계에서 상기 반응물 가스로서 사용되는 H2 의 유량, (iii) 단계에서 사용되는 RF 전력, 및 (i) 내지 (iii) 단계 전체에 걸친 성막 온도를 설정하는 단계로서, 상기 H2 의 유량, 상기 RF 전력 및 상기 성막 온도 중 하나 이상만이 상기 막 응력을 변경하기 위한 제어 파라미터로서 사용되고, 상기 H2 의 참조 유량, 상기 참조 RF 전력, 및 상기 참조 성막 온도와는 상이한, 상기 설정하는 단계,
다음으로 상기 Ti 함유 막을 성막하기 위해 (i) 내지 (iv) 단계들을 수행하는 단계를 더 포함하는, Ti 함유 막을 형성하는 방법.The method according to claim 1,
the reference flow rate of H 2 used as the reactant gas in step (ii), the reference RF power used in step (iii), and the reference deposition temperature throughout (i) to (iii) Setting a target film stress for the Ti-containing film that is greater than the film stress of the TiN crystalline film deposited by the steps (i) to (iv) under film-forming conditions; And
(ii) a step of setting the film forming temperature throughout the RF power, and (i) - (iii) steps used in the flow rate, (iii) Step of H 2 is used as the reagent gas in the step of the H 2 Wherein at least one of the flow rate, the RF power, and the film forming temperature is used as a control parameter for changing the film stress, and the reference flow rate of H 2 , the reference RF power, and the reference film forming temperature are different from each other ,
And then performing steps (i) to (iv) to form the Ti-containing film.
상기 Ti 함유 막은 인장 막 응력을 갖는, Ti 함유 막을 형성하는 방법.9. The method of claim 8,
Wherein the Ti-containing film has tensile film stress.
설정된 상기 H2 의 유량은 상기 TiN 결정질 막에 사용된 상기 H2 의 참조 유량보다 더 작은, Ti 함유 막을 형성하는 방법.10. The method of claim 9,
The flow rate of the H 2 is set how smaller, a film containing Ti than the reference flow rate of the H 2 used in the TiN crystalline film.
설정된 상기 RF 전력은 상기 TiN 결정질 막에 사용된 상기 참조 RF 전력보다 더 작은, Ti 함유 막을 형성하는 방법.10. The method of claim 9,
Wherein the set RF power is less than the reference RF power used in the TiN crystalline film.
설정된 상기 성막 온도는 상기 TiN 결정질 막에 사용된 상기 참조 성막 온도보다 더 높은, Ti 함유 막을 형성하는 방법.10. The method of claim 9,
Wherein the set film forming temperature is higher than the reference film forming temperature used in the TiN crystalline film.
상기 Ti 함유 막은 약 4% 내지 약 9% 탄소를 함유하는, Ti 함유 막을 형성하는 방법.10. The method of claim 9,
Wherein the Ti containing film contains about 4% to about 9% carbon.
상기 Ti 함유 막은 푸리에 변환 적외 분광 (FT-IR) 그래프에서 2,000 cm-1 에서 피크를 나타내고 1,400 cm-1 에서 실질적으로 피크들을 나타내지 않는, Ti 함유 막을 형성하는 방법.10. The method of claim 9,
Wherein the Ti-containing film exhibits a peak at 2,000 cm < -1 > in a Fourier Transform Infrared Spectroscopy (FT-IR) graph and does not substantially exhibit peaks at 1,400 cm <" 1 & gt ;.
상기 NH3 무함유 반응물 가스는 산소를 함유하지 않는 반응물 가스 그리고 산소를 함유하는 반응물 가스로 구성되고, (iv) 단계에서, (i) 내지 (iii) 단계들이 반복될 때, NH3 무함유 산소 무함유 반응물 가스 및 NH3 무함유 산소 함유 가스가 설정된 인터벌에서 교번하여 사용되는, Ti 함유 막을 형성하는 방법.The method according to claim 1,
In the NH 3-free reaction gas is made up of a reaction gas containing a reaction gas and oxygen that does not contain oxygen, (iv) step, (i) - (iii) when the steps are repeated, NH 3-free oxygen Containing gas and NH 3 -free oxygen containing gas are used alternately at set intervals.
상기 NH3 무함유 산소 무함유 반응물 가스가 질소 가스 없이 수소 가스이고, 상기 NH3 무함유 산소 함유 가스가 산소 가스임으로써, 설정된 인터벌에서 교번하여 성막된 TiO 막들과 TiN 막들로 이루어지는 TiON 막을 형성하는, Ti 함유 막을 형성하는 방법.16. The method of claim 15,
And it said NH 3-free oxygen-free reaction gas is hydrogen gas without nitrogen gas, the NH 3-free oxygen-containing gas is oxygen gas being as, alternately at predetermined intervals to form a film TiON made of a film-forming TiO films and TiN films , A Ti-containing film is formed.
상기 NH3 무함유 산소 무함유 반응물 가스가 수소 가스 및 질소 가스이고, 상기 NH3 무함유 산소 함유 가스가 산소 가스임으로써, 설정된 인터벌에서 교번하여 성막된 TiO 막들과 TiCN 막들로 이루어지는 TiOCN 막을 형성하는, Ti 함유 막을 형성하는 방법.16. The method of claim 15,
Wherein the NH 3 -free oxygen-free reactant gas is a hydrogen gas and a nitrogen gas, and the NH 3 -free oxygen containing gas is oxygen gas, thereby forming a TiOCN film composed of TiO 2 films and TiCN films alternately formed at a predetermined interval , A Ti-containing film is formed.
(iv) 단계에서 상기 Ti 함유 막으로서 아나타제 결정을 갖는 TiO 막을 형성하기 위하여 (iv) 단계 후에 산소의 분위기에서 상기 기판 상에 상기 Ti 함유 막을 어닐링하는 단계를 더 포함하는, Ti 함유 막을 형성하는 방법.The method according to claim 1,
further comprising the step of: (iv) annealing the Ti-containing film on the substrate in an atmosphere of oxygen after the step (iv) so as to form a TiO film having anatase crystal as the Ti-containing film in the step (iv) .
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US14/050,150 US9556516B2 (en) | 2013-10-09 | 2013-10-09 | Method for forming Ti-containing film by PEALD using TDMAT or TDEAT |
US14/050,150 | 2013-10-09 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR20150041755A true KR20150041755A (en) | 2015-04-17 |
KR102332870B1 KR102332870B1 (en) | 2021-11-29 |
Family
ID=52777161
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1020140136089A KR102332870B1 (en) | 2013-10-09 | 2014-10-08 | Method for forming ti-containing film by peald using tdmat or tdeat |
Country Status (4)
Country | Link |
---|---|
US (1) | US9556516B2 (en) |
JP (1) | JP6472203B2 (en) |
KR (1) | KR102332870B1 (en) |
TW (1) | TWI625414B (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20180010323A (en) * | 2015-06-18 | 2018-01-30 | 어플라이드 머티어리얼스, 인코포레이티드 | Deposition methods for uniform and conformal hybrid titanium oxide films |
WO2021030332A1 (en) * | 2019-08-13 | 2021-02-18 | Applied Materials, Inc. | Peald titanium nitride with direct microwave plasma |
Families Citing this family (354)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10378106B2 (en) | 2008-11-14 | 2019-08-13 | Asm Ip Holding B.V. | Method of forming insulation film by modified PEALD |
US9394608B2 (en) | 2009-04-06 | 2016-07-19 | Asm America, Inc. | Semiconductor processing reactor and components thereof |
US8802201B2 (en) | 2009-08-14 | 2014-08-12 | Asm America, Inc. | Systems and methods for thin-film deposition of metal oxides using excited nitrogen-oxygen species |
US9312155B2 (en) | 2011-06-06 | 2016-04-12 | Asm Japan K.K. | High-throughput semiconductor-processing apparatus equipped with multiple dual-chamber modules |
US9793148B2 (en) | 2011-06-22 | 2017-10-17 | Asm Japan K.K. | Method for positioning wafers in multiple wafer transport |
US10364496B2 (en) | 2011-06-27 | 2019-07-30 | Asm Ip Holding B.V. | Dual section module having shared and unshared mass flow controllers |
US10854498B2 (en) | 2011-07-15 | 2020-12-01 | Asm Ip Holding B.V. | Wafer-supporting device and method for producing same |
US20130023129A1 (en) | 2011-07-20 | 2013-01-24 | Asm America, Inc. | Pressure transmitter for a semiconductor processing environment |
US9017481B1 (en) | 2011-10-28 | 2015-04-28 | Asm America, Inc. | Process feed management for semiconductor substrate processing |
KR20130107001A (en) * | 2012-03-21 | 2013-10-01 | 엘지이노텍 주식회사 | Apparatus for deposition |
US8946830B2 (en) | 2012-04-04 | 2015-02-03 | Asm Ip Holdings B.V. | Metal oxide protective layer for a semiconductor device |
US9558931B2 (en) | 2012-07-27 | 2017-01-31 | Asm Ip Holding B.V. | System and method for gas-phase sulfur passivation of a semiconductor surface |
US9659799B2 (en) | 2012-08-28 | 2017-05-23 | Asm Ip Holding B.V. | Systems and methods for dynamic semiconductor process scheduling |
US9021985B2 (en) | 2012-09-12 | 2015-05-05 | Asm Ip Holdings B.V. | Process gas management for an inductively-coupled plasma deposition reactor |
US9324811B2 (en) | 2012-09-26 | 2016-04-26 | Asm Ip Holding B.V. | Structures and devices including a tensile-stressed silicon arsenic layer and methods of forming same |
US10714315B2 (en) | 2012-10-12 | 2020-07-14 | Asm Ip Holdings B.V. | Semiconductor reaction chamber showerhead |
US9640416B2 (en) | 2012-12-26 | 2017-05-02 | Asm Ip Holding B.V. | Single-and dual-chamber module-attachable wafer-handling chamber |
US20160376700A1 (en) | 2013-02-01 | 2016-12-29 | Asm Ip Holding B.V. | System for treatment of deposition reactor |
US9589770B2 (en) | 2013-03-08 | 2017-03-07 | Asm Ip Holding B.V. | Method and systems for in-situ formation of intermediate reactive species |
US9484191B2 (en) | 2013-03-08 | 2016-11-01 | Asm Ip Holding B.V. | Pulsed remote plasma method and system |
US8993054B2 (en) | 2013-07-12 | 2015-03-31 | Asm Ip Holding B.V. | Method and system to reduce outgassing in a reaction chamber |
US9018111B2 (en) | 2013-07-22 | 2015-04-28 | Asm Ip Holding B.V. | Semiconductor reaction chamber with plasma capabilities |
US9793115B2 (en) | 2013-08-14 | 2017-10-17 | Asm Ip Holding B.V. | Structures and devices including germanium-tin films and methods of forming same |
US9240412B2 (en) | 2013-09-27 | 2016-01-19 | Asm Ip Holding B.V. | Semiconductor structure and device and methods of forming same using selective epitaxial process |
US9556516B2 (en) | 2013-10-09 | 2017-01-31 | ASM IP Holding B.V | Method for forming Ti-containing film by PEALD using TDMAT or TDEAT |
US10179947B2 (en) | 2013-11-26 | 2019-01-15 | Asm Ip Holding B.V. | Method for forming conformal nitrided, oxidized, or carbonized dielectric film by atomic layer deposition |
US20150175467A1 (en) * | 2013-12-23 | 2015-06-25 | Infineon Technologies Austria Ag | Mold, method for producing a mold, and method for forming a mold article |
US10683571B2 (en) | 2014-02-25 | 2020-06-16 | Asm Ip Holding B.V. | Gas supply manifold and method of supplying gases to chamber using same |
US10167557B2 (en) | 2014-03-18 | 2019-01-01 | Asm Ip Holding B.V. | Gas distribution system, reactor including the system, and methods of using the same |
US9447498B2 (en) | 2014-03-18 | 2016-09-20 | Asm Ip Holding B.V. | Method for performing uniform processing in gas system-sharing multiple reaction chambers |
US11015245B2 (en) | 2014-03-19 | 2021-05-25 | Asm Ip Holding B.V. | Gas-phase reactor and system having exhaust plenum and components thereof |
US9404587B2 (en) | 2014-04-24 | 2016-08-02 | ASM IP Holding B.V | Lockout tagout for semiconductor vacuum valve |
US10858737B2 (en) | 2014-07-28 | 2020-12-08 | Asm Ip Holding B.V. | Showerhead assembly and components thereof |
US9543180B2 (en) | 2014-08-01 | 2017-01-10 | Asm Ip Holding B.V. | Apparatus and method for transporting wafers between wafer carrier and process tool under vacuum |
US9890456B2 (en) | 2014-08-21 | 2018-02-13 | Asm Ip Holding B.V. | Method and system for in situ formation of gas-phase compounds |
US10941490B2 (en) | 2014-10-07 | 2021-03-09 | Asm Ip Holding B.V. | Multiple temperature range susceptor, assembly, reactor and system including the susceptor, and methods of using the same |
US9657845B2 (en) | 2014-10-07 | 2017-05-23 | Asm Ip Holding B.V. | Variable conductance gas distribution apparatus and method |
KR102300403B1 (en) | 2014-11-19 | 2021-09-09 | 에이에스엠 아이피 홀딩 비.브이. | Method of depositing thin film |
KR102263121B1 (en) | 2014-12-22 | 2021-06-09 | 에이에스엠 아이피 홀딩 비.브이. | Semiconductor device and manufacuring method thereof |
US9478415B2 (en) | 2015-02-13 | 2016-10-25 | Asm Ip Holding B.V. | Method for forming film having low resistance and shallow junction depth |
US10529542B2 (en) | 2015-03-11 | 2020-01-07 | Asm Ip Holdings B.V. | Cross-flow reactor and method |
US10276355B2 (en) | 2015-03-12 | 2019-04-30 | Asm Ip Holding B.V. | Multi-zone reactor, system including the reactor, and method of using the same |
JP6416031B2 (en) * | 2015-03-30 | 2018-10-31 | 株式会社Kokusai Electric | Semiconductor device manufacturing method, substrate processing apparatus, and program |
US10458018B2 (en) | 2015-06-26 | 2019-10-29 | Asm Ip Holding B.V. | Structures including metal carbide material, devices including the structures, and methods of forming same |
US10600673B2 (en) | 2015-07-07 | 2020-03-24 | Asm Ip Holding B.V. | Magnetic susceptor to baseplate seal |
US9899291B2 (en) | 2015-07-13 | 2018-02-20 | Asm Ip Holding B.V. | Method for protecting layer by forming hydrocarbon-based extremely thin film |
US10043661B2 (en) | 2015-07-13 | 2018-08-07 | Asm Ip Holding B.V. | Method for protecting layer by forming hydrocarbon-based extremely thin film |
US10083836B2 (en) | 2015-07-24 | 2018-09-25 | Asm Ip Holding B.V. | Formation of boron-doped titanium metal films with high work function |
US10087525B2 (en) | 2015-08-04 | 2018-10-02 | Asm Ip Holding B.V. | Variable gap hard stop design |
US9647114B2 (en) | 2015-08-14 | 2017-05-09 | Asm Ip Holding B.V. | Methods of forming highly p-type doped germanium tin films and structures and devices including the films |
US9711345B2 (en) | 2015-08-25 | 2017-07-18 | Asm Ip Holding B.V. | Method for forming aluminum nitride-based film by PEALD |
SG10201607880PA (en) * | 2015-09-25 | 2017-04-27 | Tokyo Electron Ltd | METHOD FOR FORMING TiON FILM |
US9960072B2 (en) | 2015-09-29 | 2018-05-01 | Asm Ip Holding B.V. | Variable adjustment for precise matching of multiple chamber cavity housings |
US9909214B2 (en) | 2015-10-15 | 2018-03-06 | Asm Ip Holding B.V. | Method for depositing dielectric film in trenches by PEALD |
US10211308B2 (en) | 2015-10-21 | 2019-02-19 | Asm Ip Holding B.V. | NbMC layers |
US10322384B2 (en) | 2015-11-09 | 2019-06-18 | Asm Ip Holding B.V. | Counter flow mixer for process chamber |
US9455138B1 (en) | 2015-11-10 | 2016-09-27 | Asm Ip Holding B.V. | Method for forming dielectric film in trenches by PEALD using H-containing gas |
US9905420B2 (en) | 2015-12-01 | 2018-02-27 | Asm Ip Holding B.V. | Methods of forming silicon germanium tin films and structures and devices including the films |
US9607837B1 (en) | 2015-12-21 | 2017-03-28 | Asm Ip Holding B.V. | Method for forming silicon oxide cap layer for solid state diffusion process |
US9735024B2 (en) | 2015-12-28 | 2017-08-15 | Asm Ip Holding B.V. | Method of atomic layer etching using functional group-containing fluorocarbon |
US9627221B1 (en) | 2015-12-28 | 2017-04-18 | Asm Ip Holding B.V. | Continuous process incorporating atomic layer etching |
US11139308B2 (en) | 2015-12-29 | 2021-10-05 | Asm Ip Holding B.V. | Atomic layer deposition of III-V compounds to form V-NAND devices |
US10468251B2 (en) | 2016-02-19 | 2019-11-05 | Asm Ip Holding B.V. | Method for forming spacers using silicon nitride film for spacer-defined multiple patterning |
US9754779B1 (en) | 2016-02-19 | 2017-09-05 | Asm Ip Holding B.V. | Method for forming silicon nitride film selectively on sidewalls or flat surfaces of trenches |
US10529554B2 (en) | 2016-02-19 | 2020-01-07 | Asm Ip Holding B.V. | Method for forming silicon nitride film selectively on sidewalls or flat surfaces of trenches |
US10501866B2 (en) | 2016-03-09 | 2019-12-10 | Asm Ip Holding B.V. | Gas distribution apparatus for improved film uniformity in an epitaxial system |
US10343920B2 (en) | 2016-03-18 | 2019-07-09 | Asm Ip Holding B.V. | Aligned carbon nanotubes |
US9892913B2 (en) | 2016-03-24 | 2018-02-13 | Asm Ip Holding B.V. | Radial and thickness control via biased multi-port injection settings |
US10190213B2 (en) | 2016-04-21 | 2019-01-29 | Asm Ip Holding B.V. | Deposition of metal borides |
US10087522B2 (en) | 2016-04-21 | 2018-10-02 | Asm Ip Holding B.V. | Deposition of metal borides |
US10865475B2 (en) | 2016-04-21 | 2020-12-15 | Asm Ip Holding B.V. | Deposition of metal borides and silicides |
US10367080B2 (en) | 2016-05-02 | 2019-07-30 | Asm Ip Holding B.V. | Method of forming a germanium oxynitride film |
US10032628B2 (en) | 2016-05-02 | 2018-07-24 | Asm Ip Holding B.V. | Source/drain performance through conformal solid state doping |
KR102592471B1 (en) | 2016-05-17 | 2023-10-20 | 에이에스엠 아이피 홀딩 비.브이. | Method of forming metal interconnection and method of fabricating semiconductor device using the same |
US11453943B2 (en) | 2016-05-25 | 2022-09-27 | Asm Ip Holding B.V. | Method for forming carbon-containing silicon/metal oxide or nitride film by ALD using silicon precursor and hydrocarbon precursor |
US10388509B2 (en) | 2016-06-28 | 2019-08-20 | Asm Ip Holding B.V. | Formation of epitaxial layers via dislocation filtering |
US10612137B2 (en) | 2016-07-08 | 2020-04-07 | Asm Ip Holdings B.V. | Organic reactants for atomic layer deposition |
US9859151B1 (en) | 2016-07-08 | 2018-01-02 | Asm Ip Holding B.V. | Selective film deposition method to form air gaps |
US9793135B1 (en) | 2016-07-14 | 2017-10-17 | ASM IP Holding B.V | Method of cyclic dry etching using etchant film |
US10714385B2 (en) | 2016-07-19 | 2020-07-14 | Asm Ip Holding B.V. | Selective deposition of tungsten |
KR102354490B1 (en) | 2016-07-27 | 2022-01-21 | 에이에스엠 아이피 홀딩 비.브이. | Method of processing a substrate |
US9887082B1 (en) | 2016-07-28 | 2018-02-06 | Asm Ip Holding B.V. | Method and apparatus for filling a gap |
US9812320B1 (en) | 2016-07-28 | 2017-11-07 | Asm Ip Holding B.V. | Method and apparatus for filling a gap |
US10177025B2 (en) | 2016-07-28 | 2019-01-08 | Asm Ip Holding B.V. | Method and apparatus for filling a gap |
KR102532607B1 (en) | 2016-07-28 | 2023-05-15 | 에이에스엠 아이피 홀딩 비.브이. | Substrate processing apparatus and method of operating the same |
US10395919B2 (en) | 2016-07-28 | 2019-08-27 | Asm Ip Holding B.V. | Method and apparatus for filling a gap |
US10090316B2 (en) | 2016-09-01 | 2018-10-02 | Asm Ip Holding B.V. | 3D stacked multilayer semiconductor memory using doped select transistor channel |
US10410943B2 (en) | 2016-10-13 | 2019-09-10 | Asm Ip Holding B.V. | Method for passivating a surface of a semiconductor and related systems |
US10643826B2 (en) | 2016-10-26 | 2020-05-05 | Asm Ip Holdings B.V. | Methods for thermally calibrating reaction chambers |
US11532757B2 (en) | 2016-10-27 | 2022-12-20 | Asm Ip Holding B.V. | Deposition of charge trapping layers |
US10643904B2 (en) | 2016-11-01 | 2020-05-05 | Asm Ip Holdings B.V. | Methods for forming a semiconductor device and related semiconductor device structures |
US10229833B2 (en) | 2016-11-01 | 2019-03-12 | Asm Ip Holding B.V. | Methods for forming a transition metal nitride film on a substrate by atomic layer deposition and related semiconductor device structures |
US10435790B2 (en) | 2016-11-01 | 2019-10-08 | Asm Ip Holding B.V. | Method of subatmospheric plasma-enhanced ALD using capacitively coupled electrodes with narrow gap |
US10714350B2 (en) | 2016-11-01 | 2020-07-14 | ASM IP Holdings, B.V. | Methods for forming a transition metal niobium nitride film on a substrate by atomic layer deposition and related semiconductor device structures |
US10134757B2 (en) | 2016-11-07 | 2018-11-20 | Asm Ip Holding B.V. | Method of processing a substrate and a device manufactured by using the method |
KR102546317B1 (en) | 2016-11-15 | 2023-06-21 | 에이에스엠 아이피 홀딩 비.브이. | Gas supply unit and substrate processing apparatus including the same |
US10340135B2 (en) | 2016-11-28 | 2019-07-02 | Asm Ip Holding B.V. | Method of topologically restricted plasma-enhanced cyclic deposition of silicon or metal nitride |
KR20180068582A (en) | 2016-12-14 | 2018-06-22 | 에이에스엠 아이피 홀딩 비.브이. | Substrate processing apparatus |
US11447861B2 (en) | 2016-12-15 | 2022-09-20 | Asm Ip Holding B.V. | Sequential infiltration synthesis apparatus and a method of forming a patterned structure |
US9916980B1 (en) | 2016-12-15 | 2018-03-13 | Asm Ip Holding B.V. | Method of forming a structure on a substrate |
US11581186B2 (en) | 2016-12-15 | 2023-02-14 | Asm Ip Holding B.V. | Sequential infiltration synthesis apparatus |
KR20180070971A (en) | 2016-12-19 | 2018-06-27 | 에이에스엠 아이피 홀딩 비.브이. | Substrate processing apparatus |
US10269558B2 (en) | 2016-12-22 | 2019-04-23 | Asm Ip Holding B.V. | Method of forming a structure on a substrate |
US10867788B2 (en) | 2016-12-28 | 2020-12-15 | Asm Ip Holding B.V. | Method of forming a structure on a substrate |
US11390950B2 (en) | 2017-01-10 | 2022-07-19 | Asm Ip Holding B.V. | Reactor system and method to reduce residue buildup during a film deposition process |
US10655221B2 (en) | 2017-02-09 | 2020-05-19 | Asm Ip Holding B.V. | Method for depositing oxide film by thermal ALD and PEALD |
US10468261B2 (en) | 2017-02-15 | 2019-11-05 | Asm Ip Holding B.V. | Methods for forming a metallic film on a substrate by cyclical deposition and related semiconductor device structures |
US10529563B2 (en) | 2017-03-29 | 2020-01-07 | Asm Ip Holdings B.V. | Method for forming doped metal oxide films on a substrate by cyclical deposition and related semiconductor device structures |
US10283353B2 (en) | 2017-03-29 | 2019-05-07 | Asm Ip Holding B.V. | Method of reforming insulating film deposited on substrate with recess pattern |
US10103040B1 (en) | 2017-03-31 | 2018-10-16 | Asm Ip Holding B.V. | Apparatus and method for manufacturing a semiconductor device |
USD830981S1 (en) | 2017-04-07 | 2018-10-16 | Asm Ip Holding B.V. | Susceptor for semiconductor substrate processing apparatus |
KR102457289B1 (en) | 2017-04-25 | 2022-10-21 | 에이에스엠 아이피 홀딩 비.브이. | Method for depositing a thin film and manufacturing a semiconductor device |
US10892156B2 (en) | 2017-05-08 | 2021-01-12 | Asm Ip Holding B.V. | Methods for forming a silicon nitride film on a substrate and related semiconductor device structures |
US10446393B2 (en) | 2017-05-08 | 2019-10-15 | Asm Ip Holding B.V. | Methods for forming silicon-containing epitaxial layers and related semiconductor device structures |
US10770286B2 (en) | 2017-05-08 | 2020-09-08 | Asm Ip Holdings B.V. | Methods for selectively forming a silicon nitride film on a substrate and related semiconductor device structures |
US10504742B2 (en) | 2017-05-31 | 2019-12-10 | Asm Ip Holding B.V. | Method of atomic layer etching using hydrogen plasma |
US10886123B2 (en) | 2017-06-02 | 2021-01-05 | Asm Ip Holding B.V. | Methods for forming low temperature semiconductor layers and related semiconductor device structures |
US12040200B2 (en) | 2017-06-20 | 2024-07-16 | Asm Ip Holding B.V. | Semiconductor processing apparatus and methods for calibrating a semiconductor processing apparatus |
US11306395B2 (en) | 2017-06-28 | 2022-04-19 | Asm Ip Holding B.V. | Methods for depositing a transition metal nitride film on a substrate by atomic layer deposition and related deposition apparatus |
US10685834B2 (en) | 2017-07-05 | 2020-06-16 | Asm Ip Holdings B.V. | Methods for forming a silicon germanium tin layer and related semiconductor device structures |
KR20190009245A (en) | 2017-07-18 | 2019-01-28 | 에이에스엠 아이피 홀딩 비.브이. | Methods for forming a semiconductor device structure and related semiconductor device structures |
US10541333B2 (en) | 2017-07-19 | 2020-01-21 | Asm Ip Holding B.V. | Method for depositing a group IV semiconductor and related semiconductor device structures |
US11374112B2 (en) | 2017-07-19 | 2022-06-28 | Asm Ip Holding B.V. | Method for depositing a group IV semiconductor and related semiconductor device structures |
US11018002B2 (en) | 2017-07-19 | 2021-05-25 | Asm Ip Holding B.V. | Method for selectively depositing a Group IV semiconductor and related semiconductor device structures |
US10605530B2 (en) | 2017-07-26 | 2020-03-31 | Asm Ip Holding B.V. | Assembly of a liner and a flange for a vertical furnace as well as the liner and the vertical furnace |
US10312055B2 (en) | 2017-07-26 | 2019-06-04 | Asm Ip Holding B.V. | Method of depositing film by PEALD using negative bias |
US10590535B2 (en) | 2017-07-26 | 2020-03-17 | Asm Ip Holdings B.V. | Chemical treatment, deposition and/or infiltration apparatus and method for using the same |
US10692741B2 (en) | 2017-08-08 | 2020-06-23 | Asm Ip Holdings B.V. | Radiation shield |
US10770336B2 (en) | 2017-08-08 | 2020-09-08 | Asm Ip Holding B.V. | Substrate lift mechanism and reactor including same |
US11769682B2 (en) | 2017-08-09 | 2023-09-26 | Asm Ip Holding B.V. | Storage apparatus for storing cassettes for substrates and processing apparatus equipped therewith |
US10249524B2 (en) | 2017-08-09 | 2019-04-02 | Asm Ip Holding B.V. | Cassette holder assembly for a substrate cassette and holding member for use in such assembly |
US11139191B2 (en) | 2017-08-09 | 2021-10-05 | Asm Ip Holding B.V. | Storage apparatus for storing cassettes for substrates and processing apparatus equipped therewith |
US10236177B1 (en) | 2017-08-22 | 2019-03-19 | ASM IP Holding B.V.. | Methods for depositing a doped germanium tin semiconductor and related semiconductor device structures |
USD900036S1 (en) | 2017-08-24 | 2020-10-27 | Asm Ip Holding B.V. | Heater electrical connector and adapter |
US11830730B2 (en) | 2017-08-29 | 2023-11-28 | Asm Ip Holding B.V. | Layer forming method and apparatus |
US11295980B2 (en) | 2017-08-30 | 2022-04-05 | Asm Ip Holding B.V. | Methods for depositing a molybdenum metal film over a dielectric surface of a substrate by a cyclical deposition process and related semiconductor device structures |
US11056344B2 (en) | 2017-08-30 | 2021-07-06 | Asm Ip Holding B.V. | Layer forming method |
TWI784036B (en) * | 2017-08-30 | 2022-11-21 | 荷蘭商Asm智慧財產控股公司 | Layer forming method |
KR102491945B1 (en) | 2017-08-30 | 2023-01-26 | 에이에스엠 아이피 홀딩 비.브이. | Substrate processing apparatus |
KR102401446B1 (en) | 2017-08-31 | 2022-05-24 | 에이에스엠 아이피 홀딩 비.브이. | Substrate processing apparatus |
US10607895B2 (en) | 2017-09-18 | 2020-03-31 | Asm Ip Holdings B.V. | Method for forming a semiconductor device structure comprising a gate fill metal |
KR102630301B1 (en) | 2017-09-21 | 2024-01-29 | 에이에스엠 아이피 홀딩 비.브이. | Method of sequential infiltration synthesis treatment of infiltrateable material and structures and devices formed using same |
US10844484B2 (en) | 2017-09-22 | 2020-11-24 | Asm Ip Holding B.V. | Apparatus for dispensing a vapor phase reactant to a reaction chamber and related methods |
US10658205B2 (en) | 2017-09-28 | 2020-05-19 | Asm Ip Holdings B.V. | Chemical dispensing apparatus and methods for dispensing a chemical to a reaction chamber |
US10403504B2 (en) | 2017-10-05 | 2019-09-03 | Asm Ip Holding B.V. | Method for selectively depositing a metallic film on a substrate |
KR102394352B1 (en) | 2017-10-06 | 2022-05-06 | 어플라이드 머티어리얼스, 인코포레이티드 | Methods and Precursors for Selective Deposition of Metal Films |
US10319588B2 (en) | 2017-10-10 | 2019-06-11 | Asm Ip Holding B.V. | Method for depositing a metal chalcogenide on a substrate by cyclical deposition |
US10923344B2 (en) | 2017-10-30 | 2021-02-16 | Asm Ip Holding B.V. | Methods for forming a semiconductor structure and related semiconductor structures |
US10366879B2 (en) | 2017-11-14 | 2019-07-30 | International Business Machines Corporation | Dry and wet etch resistance for atomic layer deposited TiO2 for SIT spacer application |
US10910262B2 (en) | 2017-11-16 | 2021-02-02 | Asm Ip Holding B.V. | Method of selectively depositing a capping layer structure on a semiconductor device structure |
KR102443047B1 (en) | 2017-11-16 | 2022-09-14 | 에이에스엠 아이피 홀딩 비.브이. | Method of processing a substrate and a device manufactured by the same |
US11022879B2 (en) | 2017-11-24 | 2021-06-01 | Asm Ip Holding B.V. | Method of forming an enhanced unexposed photoresist layer |
WO2019103613A1 (en) | 2017-11-27 | 2019-05-31 | Asm Ip Holding B.V. | A storage device for storing wafer cassettes for use with a batch furnace |
KR102633318B1 (en) | 2017-11-27 | 2024-02-05 | 에이에스엠 아이피 홀딩 비.브이. | Devices with clean compact zones |
US10290508B1 (en) | 2017-12-05 | 2019-05-14 | Asm Ip Holding B.V. | Method for forming vertical spacers for spacer-defined patterning |
US10872771B2 (en) | 2018-01-16 | 2020-12-22 | Asm Ip Holding B. V. | Method for depositing a material film on a substrate within a reaction chamber by a cyclical deposition process and related device structures |
CN111630203A (en) | 2018-01-19 | 2020-09-04 | Asm Ip私人控股有限公司 | Method for depositing gap filling layer by plasma auxiliary deposition |
TWI799494B (en) | 2018-01-19 | 2023-04-21 | 荷蘭商Asm 智慧財產控股公司 | Deposition method |
USD903477S1 (en) | 2018-01-24 | 2020-12-01 | Asm Ip Holdings B.V. | Metal clamp |
US11018047B2 (en) | 2018-01-25 | 2021-05-25 | Asm Ip Holding B.V. | Hybrid lift pin |
US10535516B2 (en) | 2018-02-01 | 2020-01-14 | Asm Ip Holdings B.V. | Method for depositing a semiconductor structure on a surface of a substrate and related semiconductor structures |
USD880437S1 (en) | 2018-02-01 | 2020-04-07 | Asm Ip Holding B.V. | Gas supply plate for semiconductor manufacturing apparatus |
US11081345B2 (en) | 2018-02-06 | 2021-08-03 | Asm Ip Holding B.V. | Method of post-deposition treatment for silicon oxide film |
WO2019158960A1 (en) | 2018-02-14 | 2019-08-22 | Asm Ip Holding B.V. | A method for depositing a ruthenium-containing film on a substrate by a cyclical deposition process |
US10896820B2 (en) | 2018-02-14 | 2021-01-19 | Asm Ip Holding B.V. | Method for depositing a ruthenium-containing film on a substrate by a cyclical deposition process |
US10731249B2 (en) | 2018-02-15 | 2020-08-04 | Asm Ip Holding B.V. | Method of forming a transition metal containing film on a substrate by a cyclical deposition process, a method for supplying a transition metal halide compound to a reaction chamber, and related vapor deposition apparatus |
KR102636427B1 (en) | 2018-02-20 | 2024-02-13 | 에이에스엠 아이피 홀딩 비.브이. | Substrate processing method and apparatus |
US10658181B2 (en) | 2018-02-20 | 2020-05-19 | Asm Ip Holding B.V. | Method of spacer-defined direct patterning in semiconductor fabrication |
US10975470B2 (en) | 2018-02-23 | 2021-04-13 | Asm Ip Holding B.V. | Apparatus for detecting or monitoring for a chemical precursor in a high temperature environment |
US11473195B2 (en) | 2018-03-01 | 2022-10-18 | Asm Ip Holding B.V. | Semiconductor processing apparatus and a method for processing a substrate |
US11629406B2 (en) | 2018-03-09 | 2023-04-18 | Asm Ip Holding B.V. | Semiconductor processing apparatus comprising one or more pyrometers for measuring a temperature of a substrate during transfer of the substrate |
US11114283B2 (en) | 2018-03-16 | 2021-09-07 | Asm Ip Holding B.V. | Reactor, system including the reactor, and methods of manufacturing and using same |
KR102646467B1 (en) | 2018-03-27 | 2024-03-11 | 에이에스엠 아이피 홀딩 비.브이. | Method of forming an electrode on a substrate and a semiconductor device structure including an electrode |
US11088002B2 (en) | 2018-03-29 | 2021-08-10 | Asm Ip Holding B.V. | Substrate rack and a substrate processing system and method |
US11230766B2 (en) | 2018-03-29 | 2022-01-25 | Asm Ip Holding B.V. | Substrate processing apparatus and method |
US10510536B2 (en) | 2018-03-29 | 2019-12-17 | Asm Ip Holding B.V. | Method of depositing a co-doped polysilicon film on a surface of a substrate within a reaction chamber |
KR102501472B1 (en) | 2018-03-30 | 2023-02-20 | 에이에스엠 아이피 홀딩 비.브이. | Substrate processing method |
KR20190128558A (en) | 2018-05-08 | 2019-11-18 | 에이에스엠 아이피 홀딩 비.브이. | Methods for depositing an oxide film on a substrate by a cyclical deposition process and related device structures |
US12025484B2 (en) | 2018-05-08 | 2024-07-02 | Asm Ip Holding B.V. | Thin film forming method |
TW202349473A (en) | 2018-05-11 | 2023-12-16 | 荷蘭商Asm Ip私人控股有限公司 | Methods for forming a doped metal carbide film on a substrate and related semiconductor device structures |
KR102596988B1 (en) | 2018-05-28 | 2023-10-31 | 에이에스엠 아이피 홀딩 비.브이. | Method of processing a substrate and a device manufactured by the same |
US11270899B2 (en) | 2018-06-04 | 2022-03-08 | Asm Ip Holding B.V. | Wafer handling chamber with moisture reduction |
US11718913B2 (en) | 2018-06-04 | 2023-08-08 | Asm Ip Holding B.V. | Gas distribution system and reactor system including same |
US11286562B2 (en) | 2018-06-08 | 2022-03-29 | Asm Ip Holding B.V. | Gas-phase chemical reactor and method of using same |
JP7094154B2 (en) * | 2018-06-13 | 2022-07-01 | 東京エレクトロン株式会社 | Film forming equipment and film forming method |
KR102568797B1 (en) | 2018-06-21 | 2023-08-21 | 에이에스엠 아이피 홀딩 비.브이. | Substrate processing system |
US10797133B2 (en) | 2018-06-21 | 2020-10-06 | Asm Ip Holding B.V. | Method for depositing a phosphorus doped silicon arsenide film and related semiconductor device structures |
TW202405221A (en) | 2018-06-27 | 2024-02-01 | 荷蘭商Asm Ip私人控股有限公司 | Cyclic deposition methods for forming metal-containing material and films and structures including the metal-containing material |
TW202409324A (en) | 2018-06-27 | 2024-03-01 | 荷蘭商Asm Ip私人控股有限公司 | Cyclic deposition processes for forming metal-containing material |
US10612136B2 (en) | 2018-06-29 | 2020-04-07 | ASM IP Holding, B.V. | Temperature-controlled flange and reactor system including same |
TWI751420B (en) | 2018-06-29 | 2022-01-01 | 荷蘭商Asm知識產權私人控股有限公司 | Thin-film deposition method |
US10755922B2 (en) * | 2018-07-03 | 2020-08-25 | Asm Ip Holding B.V. | Method for depositing silicon-free carbon-containing film as gap-fill layer by pulse plasma-assisted deposition |
US10388513B1 (en) * | 2018-07-03 | 2019-08-20 | Asm Ip Holding B.V. | Method for depositing silicon-free carbon-containing film as gap-fill layer by pulse plasma-assisted deposition |
US10767789B2 (en) | 2018-07-16 | 2020-09-08 | Asm Ip Holding B.V. | Diaphragm valves, valve components, and methods for forming valve components |
US11152207B2 (en) * | 2018-07-26 | 2021-10-19 | Tokyo Electron Limited | Method of forming titanium nitride films with (200) crystallographic texture |
US10483099B1 (en) | 2018-07-26 | 2019-11-19 | Asm Ip Holding B.V. | Method for forming thermally stable organosilicon polymer film |
US11053591B2 (en) | 2018-08-06 | 2021-07-06 | Asm Ip Holding B.V. | Multi-port gas injection system and reactor system including same |
US10883175B2 (en) | 2018-08-09 | 2021-01-05 | Asm Ip Holding B.V. | Vertical furnace for processing substrates and a liner for use therein |
US10829852B2 (en) | 2018-08-16 | 2020-11-10 | Asm Ip Holding B.V. | Gas distribution device for a wafer processing apparatus |
US11430674B2 (en) | 2018-08-22 | 2022-08-30 | Asm Ip Holding B.V. | Sensor array, apparatus for dispensing a vapor phase reactant to a reaction chamber and related methods |
US11024523B2 (en) | 2018-09-11 | 2021-06-01 | Asm Ip Holding B.V. | Substrate processing apparatus and method |
KR20200030162A (en) | 2018-09-11 | 2020-03-20 | 에이에스엠 아이피 홀딩 비.브이. | Method for deposition of a thin film |
US11049751B2 (en) | 2018-09-14 | 2021-06-29 | Asm Ip Holding B.V. | Cassette supply system to store and handle cassettes and processing apparatus equipped therewith |
US10734219B2 (en) * | 2018-09-26 | 2020-08-04 | Asm Ip Holdings B.V. | Plasma film forming method |
CN110970344A (en) | 2018-10-01 | 2020-04-07 | Asm Ip控股有限公司 | Substrate holding apparatus, system including the same, and method of using the same |
US11232963B2 (en) | 2018-10-03 | 2022-01-25 | Asm Ip Holding B.V. | Substrate processing apparatus and method |
KR102592699B1 (en) | 2018-10-08 | 2023-10-23 | 에이에스엠 아이피 홀딩 비.브이. | Substrate support unit and apparatuses for depositing thin film and processing the substrate including the same |
US10847365B2 (en) | 2018-10-11 | 2020-11-24 | Asm Ip Holding B.V. | Method of forming conformal silicon carbide film by cyclic CVD |
US10811256B2 (en) | 2018-10-16 | 2020-10-20 | Asm Ip Holding B.V. | Method for etching a carbon-containing feature |
KR102546322B1 (en) | 2018-10-19 | 2023-06-21 | 에이에스엠 아이피 홀딩 비.브이. | Substrate processing apparatus and substrate processing method |
KR102605121B1 (en) | 2018-10-19 | 2023-11-23 | 에이에스엠 아이피 홀딩 비.브이. | Substrate processing apparatus and substrate processing method |
JP2020066764A (en) * | 2018-10-23 | 2020-04-30 | 東京エレクトロン株式会社 | Film formation device and film formation method |
USD948463S1 (en) | 2018-10-24 | 2022-04-12 | Asm Ip Holding B.V. | Susceptor for semiconductor substrate supporting apparatus |
US10381219B1 (en) | 2018-10-25 | 2019-08-13 | Asm Ip Holding B.V. | Methods for forming a silicon nitride film |
US11087997B2 (en) | 2018-10-31 | 2021-08-10 | Asm Ip Holding B.V. | Substrate processing apparatus for processing substrates |
KR20200051105A (en) | 2018-11-02 | 2020-05-13 | 에이에스엠 아이피 홀딩 비.브이. | Substrate support unit and substrate processing apparatus including the same |
US11572620B2 (en) | 2018-11-06 | 2023-02-07 | Asm Ip Holding B.V. | Methods for selectively depositing an amorphous silicon film on a substrate |
US11031242B2 (en) | 2018-11-07 | 2021-06-08 | Asm Ip Holding B.V. | Methods for depositing a boron doped silicon germanium film |
US10847366B2 (en) | 2018-11-16 | 2020-11-24 | Asm Ip Holding B.V. | Methods for depositing a transition metal chalcogenide film on a substrate by a cyclical deposition process |
US10818758B2 (en) | 2018-11-16 | 2020-10-27 | Asm Ip Holding B.V. | Methods for forming a metal silicate film on a substrate in a reaction chamber and related semiconductor device structures |
US10559458B1 (en) | 2018-11-26 | 2020-02-11 | Asm Ip Holding B.V. | Method of forming oxynitride film |
US12040199B2 (en) | 2018-11-28 | 2024-07-16 | Asm Ip Holding B.V. | Substrate processing apparatus for processing substrates |
US11217444B2 (en) | 2018-11-30 | 2022-01-04 | Asm Ip Holding B.V. | Method for forming an ultraviolet radiation responsive metal oxide-containing film |
KR102636428B1 (en) | 2018-12-04 | 2024-02-13 | 에이에스엠 아이피 홀딩 비.브이. | A method for cleaning a substrate processing apparatus |
US11158513B2 (en) | 2018-12-13 | 2021-10-26 | Asm Ip Holding B.V. | Methods for forming a rhenium-containing film on a substrate by a cyclical deposition process and related semiconductor device structures |
JP7504584B2 (en) | 2018-12-14 | 2024-06-24 | エーエスエム・アイピー・ホールディング・ベー・フェー | Method and system for forming device structures using selective deposition of gallium nitride - Patents.com |
TWI819180B (en) | 2019-01-17 | 2023-10-21 | 荷蘭商Asm 智慧財產控股公司 | Methods of forming a transition metal containing film on a substrate by a cyclical deposition process |
KR20200091543A (en) | 2019-01-22 | 2020-07-31 | 에이에스엠 아이피 홀딩 비.브이. | Semiconductor processing device |
CN111524788B (en) | 2019-02-01 | 2023-11-24 | Asm Ip私人控股有限公司 | Method for topologically selective film formation of silicon oxide |
KR102626263B1 (en) | 2019-02-20 | 2024-01-16 | 에이에스엠 아이피 홀딩 비.브이. | Cyclical deposition method including treatment step and apparatus for same |
JP2020136678A (en) | 2019-02-20 | 2020-08-31 | エーエスエム・アイピー・ホールディング・ベー・フェー | Method for filing concave part formed inside front surface of base material, and device |
US11482533B2 (en) | 2019-02-20 | 2022-10-25 | Asm Ip Holding B.V. | Apparatus and methods for plug fill deposition in 3-D NAND applications |
JP7509548B2 (en) | 2019-02-20 | 2024-07-02 | エーエスエム・アイピー・ホールディング・ベー・フェー | Cyclic deposition method and apparatus for filling recesses formed in a substrate surface - Patents.com |
JP2020133004A (en) | 2019-02-22 | 2020-08-31 | エーエスエム・アイピー・ホールディング・ベー・フェー | Base material processing apparatus and method for processing base material |
KR20200108243A (en) | 2019-03-08 | 2020-09-17 | 에이에스엠 아이피 홀딩 비.브이. | Structure Including SiOC Layer and Method of Forming Same |
KR20200108248A (en) | 2019-03-08 | 2020-09-17 | 에이에스엠 아이피 홀딩 비.브이. | STRUCTURE INCLUDING SiOCN LAYER AND METHOD OF FORMING SAME |
KR20200108242A (en) | 2019-03-08 | 2020-09-17 | 에이에스엠 아이피 홀딩 비.브이. | Method for Selective Deposition of Silicon Nitride Layer and Structure Including Selectively-Deposited Silicon Nitride Layer |
KR20200116033A (en) | 2019-03-28 | 2020-10-08 | 에이에스엠 아이피 홀딩 비.브이. | Door opener and substrate processing apparatus provided therewith |
KR20200116855A (en) | 2019-04-01 | 2020-10-13 | 에이에스엠 아이피 홀딩 비.브이. | Method of manufacturing semiconductor device |
KR20200123380A (en) | 2019-04-19 | 2020-10-29 | 에이에스엠 아이피 홀딩 비.브이. | Layer forming method and apparatus |
KR20200125453A (en) | 2019-04-24 | 2020-11-04 | 에이에스엠 아이피 홀딩 비.브이. | Gas-phase reactor system and method of using same |
KR20200130121A (en) | 2019-05-07 | 2020-11-18 | 에이에스엠 아이피 홀딩 비.브이. | Chemical source vessel with dip tube |
KR20200130118A (en) | 2019-05-07 | 2020-11-18 | 에이에스엠 아이피 홀딩 비.브이. | Method for Reforming Amorphous Carbon Polymer Film |
KR20200130652A (en) | 2019-05-10 | 2020-11-19 | 에이에스엠 아이피 홀딩 비.브이. | Method of depositing material onto a surface and structure formed according to the method |
JP2020188254A (en) | 2019-05-16 | 2020-11-19 | エーエスエム アイピー ホールディング ビー.ブイ. | Wafer boat handling device, vertical batch furnace, and method |
JP2020188255A (en) | 2019-05-16 | 2020-11-19 | エーエスエム アイピー ホールディング ビー.ブイ. | Wafer boat handling device, vertical batch furnace, and method |
USD975665S1 (en) | 2019-05-17 | 2023-01-17 | Asm Ip Holding B.V. | Susceptor shaft |
USD947913S1 (en) | 2019-05-17 | 2022-04-05 | Asm Ip Holding B.V. | Susceptor shaft |
USD935572S1 (en) | 2019-05-24 | 2021-11-09 | Asm Ip Holding B.V. | Gas channel plate |
USD922229S1 (en) | 2019-06-05 | 2021-06-15 | Asm Ip Holding B.V. | Device for controlling a temperature of a gas supply unit |
KR20200141002A (en) | 2019-06-06 | 2020-12-17 | 에이에스엠 아이피 홀딩 비.브이. | Method of using a gas-phase reactor system including analyzing exhausted gas |
KR20200143254A (en) | 2019-06-11 | 2020-12-23 | 에이에스엠 아이피 홀딩 비.브이. | Method of forming an electronic structure using an reforming gas, system for performing the method, and structure formed using the method |
USD944946S1 (en) | 2019-06-14 | 2022-03-01 | Asm Ip Holding B.V. | Shower plate |
USD931978S1 (en) | 2019-06-27 | 2021-09-28 | Asm Ip Holding B.V. | Showerhead vacuum transport |
KR20210005515A (en) | 2019-07-03 | 2021-01-14 | 에이에스엠 아이피 홀딩 비.브이. | Temperature control assembly for substrate processing apparatus and method of using same |
JP7499079B2 (en) | 2019-07-09 | 2024-06-13 | エーエスエム・アイピー・ホールディング・ベー・フェー | Plasma device using coaxial waveguide and substrate processing method |
CN112216646A (en) | 2019-07-10 | 2021-01-12 | Asm Ip私人控股有限公司 | Substrate supporting assembly and substrate processing device comprising same |
KR20210010307A (en) | 2019-07-16 | 2021-01-27 | 에이에스엠 아이피 홀딩 비.브이. | Substrate processing apparatus |
KR20210010820A (en) | 2019-07-17 | 2021-01-28 | 에이에스엠 아이피 홀딩 비.브이. | Methods of forming silicon germanium structures |
KR20210010816A (en) | 2019-07-17 | 2021-01-28 | 에이에스엠 아이피 홀딩 비.브이. | Radical assist ignition plasma system and method |
US11643724B2 (en) | 2019-07-18 | 2023-05-09 | Asm Ip Holding B.V. | Method of forming structures using a neutral beam |
TWI839544B (en) | 2019-07-19 | 2024-04-21 | 荷蘭商Asm Ip私人控股有限公司 | Method of forming topology-controlled amorphous carbon polymer film |
TW202113936A (en) | 2019-07-29 | 2021-04-01 | 荷蘭商Asm Ip私人控股有限公司 | Methods for selective deposition utilizing n-type dopants and/or alternative dopants to achieve high dopant incorporation |
CN112309900A (en) | 2019-07-30 | 2021-02-02 | Asm Ip私人控股有限公司 | Substrate processing apparatus |
CN112309899A (en) | 2019-07-30 | 2021-02-02 | Asm Ip私人控股有限公司 | Substrate processing apparatus |
US11227782B2 (en) | 2019-07-31 | 2022-01-18 | Asm Ip Holding B.V. | Vertical batch furnace assembly |
US11587814B2 (en) | 2019-07-31 | 2023-02-21 | Asm Ip Holding B.V. | Vertical batch furnace assembly |
US11587815B2 (en) | 2019-07-31 | 2023-02-21 | Asm Ip Holding B.V. | Vertical batch furnace assembly |
CN112323048B (en) | 2019-08-05 | 2024-02-09 | Asm Ip私人控股有限公司 | Liquid level sensor for chemical source container |
USD965044S1 (en) | 2019-08-19 | 2022-09-27 | Asm Ip Holding B.V. | Susceptor shaft |
USD965524S1 (en) | 2019-08-19 | 2022-10-04 | Asm Ip Holding B.V. | Susceptor support |
JP2021031769A (en) | 2019-08-21 | 2021-03-01 | エーエスエム アイピー ホールディング ビー.ブイ. | Production apparatus of mixed gas of film deposition raw material and film deposition apparatus |
KR20210024423A (en) | 2019-08-22 | 2021-03-05 | 에이에스엠 아이피 홀딩 비.브이. | Method for forming a structure with a hole |
USD930782S1 (en) | 2019-08-22 | 2021-09-14 | Asm Ip Holding B.V. | Gas distributor |
USD949319S1 (en) | 2019-08-22 | 2022-04-19 | Asm Ip Holding B.V. | Exhaust duct |
USD979506S1 (en) | 2019-08-22 | 2023-02-28 | Asm Ip Holding B.V. | Insulator |
USD940837S1 (en) | 2019-08-22 | 2022-01-11 | Asm Ip Holding B.V. | Electrode |
KR20210024420A (en) | 2019-08-23 | 2021-03-05 | 에이에스엠 아이피 홀딩 비.브이. | Method for depositing silicon oxide film having improved quality by peald using bis(diethylamino)silane |
US11286558B2 (en) | 2019-08-23 | 2022-03-29 | Asm Ip Holding B.V. | Methods for depositing a molybdenum nitride film on a surface of a substrate by a cyclical deposition process and related semiconductor device structures including a molybdenum nitride film |
CN110459468A (en) * | 2019-08-29 | 2019-11-15 | 上海华力集成电路制造有限公司 | The lithographic method of TiAlN thin film |
KR20210029090A (en) | 2019-09-04 | 2021-03-15 | 에이에스엠 아이피 홀딩 비.브이. | Methods for selective deposition using a sacrificial capping layer |
KR20210029663A (en) | 2019-09-05 | 2021-03-16 | 에이에스엠 아이피 홀딩 비.브이. | Substrate processing apparatus |
US11562901B2 (en) | 2019-09-25 | 2023-01-24 | Asm Ip Holding B.V. | Substrate processing method |
CN112593212B (en) | 2019-10-02 | 2023-12-22 | Asm Ip私人控股有限公司 | Method for forming topologically selective silicon oxide film by cyclic plasma enhanced deposition process |
CN112635282A (en) | 2019-10-08 | 2021-04-09 | Asm Ip私人控股有限公司 | Substrate processing apparatus having connection plate and substrate processing method |
KR20210042810A (en) | 2019-10-08 | 2021-04-20 | 에이에스엠 아이피 홀딩 비.브이. | Reactor system including a gas distribution assembly for use with activated species and method of using same |
CN112626501A (en) * | 2019-10-09 | 2021-04-09 | 长鑫存储技术有限公司 | Method for improving impurity content of plasma deposition film and control device |
KR20210043460A (en) | 2019-10-10 | 2021-04-21 | 에이에스엠 아이피 홀딩 비.브이. | Method of forming a photoresist underlayer and structure including same |
US12009241B2 (en) | 2019-10-14 | 2024-06-11 | Asm Ip Holding B.V. | Vertical batch furnace assembly with detector to detect cassette |
TWI834919B (en) | 2019-10-16 | 2024-03-11 | 荷蘭商Asm Ip私人控股有限公司 | Method of topology-selective film formation of silicon oxide |
US11637014B2 (en) | 2019-10-17 | 2023-04-25 | Asm Ip Holding B.V. | Methods for selective deposition of doped semiconductor material |
KR20210047808A (en) | 2019-10-21 | 2021-04-30 | 에이에스엠 아이피 홀딩 비.브이. | Apparatus and methods for selectively etching films |
KR20210050453A (en) | 2019-10-25 | 2021-05-07 | 에이에스엠 아이피 홀딩 비.브이. | Methods for filling a gap feature on a substrate surface and related semiconductor structures |
US11646205B2 (en) | 2019-10-29 | 2023-05-09 | Asm Ip Holding B.V. | Methods of selectively forming n-type doped material on a surface, systems for selectively forming n-type doped material, and structures formed using same |
KR20210054983A (en) | 2019-11-05 | 2021-05-14 | 에이에스엠 아이피 홀딩 비.브이. | Structures with doped semiconductor layers and methods and systems for forming same |
US11501968B2 (en) | 2019-11-15 | 2022-11-15 | Asm Ip Holding B.V. | Method for providing a semiconductor device with silicon filled gaps |
KR20210062561A (en) | 2019-11-20 | 2021-05-31 | 에이에스엠 아이피 홀딩 비.브이. | Method of depositing carbon-containing material on a surface of a substrate, structure formed using the method, and system for forming the structure |
CN112951697A (en) | 2019-11-26 | 2021-06-11 | Asm Ip私人控股有限公司 | Substrate processing apparatus |
US11450529B2 (en) | 2019-11-26 | 2022-09-20 | Asm Ip Holding B.V. | Methods for selectively forming a target film on a substrate comprising a first dielectric surface and a second metallic surface |
CN112885693A (en) | 2019-11-29 | 2021-06-01 | Asm Ip私人控股有限公司 | Substrate processing apparatus |
CN112885692A (en) | 2019-11-29 | 2021-06-01 | Asm Ip私人控股有限公司 | Substrate processing apparatus |
JP2021090042A (en) | 2019-12-02 | 2021-06-10 | エーエスエム アイピー ホールディング ビー.ブイ. | Substrate processing apparatus and substrate processing method |
KR20210070898A (en) | 2019-12-04 | 2021-06-15 | 에이에스엠 아이피 홀딩 비.브이. | Substrate processing apparatus |
KR20210078405A (en) | 2019-12-17 | 2021-06-28 | 에이에스엠 아이피 홀딩 비.브이. | Method of forming vanadium nitride layer and structure including the vanadium nitride layer |
US11527403B2 (en) | 2019-12-19 | 2022-12-13 | Asm Ip Holding B.V. | Methods for filling a gap feature on a substrate surface and related semiconductor structures |
TW202140135A (en) | 2020-01-06 | 2021-11-01 | 荷蘭商Asm Ip私人控股有限公司 | Gas supply assembly and valve plate assembly |
KR20210089079A (en) | 2020-01-06 | 2021-07-15 | 에이에스엠 아이피 홀딩 비.브이. | Channeled lift pin |
US11993847B2 (en) | 2020-01-08 | 2024-05-28 | Asm Ip Holding B.V. | Injector |
KR102675856B1 (en) | 2020-01-20 | 2024-06-17 | 에이에스엠 아이피 홀딩 비.브이. | Method of forming thin film and method of modifying surface of thin film |
TW202130846A (en) | 2020-02-03 | 2021-08-16 | 荷蘭商Asm Ip私人控股有限公司 | Method of forming structures including a vanadium or indium layer |
KR20210100010A (en) | 2020-02-04 | 2021-08-13 | 에이에스엠 아이피 홀딩 비.브이. | Method and apparatus for transmittance measurements of large articles |
US11776846B2 (en) | 2020-02-07 | 2023-10-03 | Asm Ip Holding B.V. | Methods for depositing gap filling fluids and related systems and devices |
US11781243B2 (en) | 2020-02-17 | 2023-10-10 | Asm Ip Holding B.V. | Method for depositing low temperature phosphorous-doped silicon |
TW202203344A (en) | 2020-02-28 | 2022-01-16 | 荷蘭商Asm Ip控股公司 | System dedicated for parts cleaning |
KR20210116240A (en) | 2020-03-11 | 2021-09-27 | 에이에스엠 아이피 홀딩 비.브이. | Substrate handling device with adjustable joints |
US11876356B2 (en) | 2020-03-11 | 2024-01-16 | Asm Ip Holding B.V. | Lockout tagout assembly and system and method of using same |
CN113394086A (en) | 2020-03-12 | 2021-09-14 | Asm Ip私人控股有限公司 | Method for producing a layer structure having a target topological profile |
KR20210124042A (en) | 2020-04-02 | 2021-10-14 | 에이에스엠 아이피 홀딩 비.브이. | Thin film forming method |
TW202146689A (en) | 2020-04-03 | 2021-12-16 | 荷蘭商Asm Ip控股公司 | Method for forming barrier layer and method for manufacturing semiconductor device |
TW202145344A (en) | 2020-04-08 | 2021-12-01 | 荷蘭商Asm Ip私人控股有限公司 | Apparatus and methods for selectively etching silcon oxide films |
US11821078B2 (en) | 2020-04-15 | 2023-11-21 | Asm Ip Holding B.V. | Method for forming precoat film and method for forming silicon-containing film |
US11996289B2 (en) | 2020-04-16 | 2024-05-28 | Asm Ip Holding B.V. | Methods of forming structures including silicon germanium and silicon layers, devices formed using the methods, and systems for performing the methods |
KR20210132605A (en) | 2020-04-24 | 2021-11-04 | 에이에스엠 아이피 홀딩 비.브이. | Vertical batch furnace assembly comprising a cooling gas supply |
KR20210132600A (en) | 2020-04-24 | 2021-11-04 | 에이에스엠 아이피 홀딩 비.브이. | Methods and systems for depositing a layer comprising vanadium, nitrogen, and a further element |
CN113555279A (en) | 2020-04-24 | 2021-10-26 | Asm Ip私人控股有限公司 | Method of forming vanadium nitride-containing layers and structures including the same |
KR20210134226A (en) | 2020-04-29 | 2021-11-09 | 에이에스엠 아이피 홀딩 비.브이. | Solid source precursor vessel |
KR20210134869A (en) | 2020-05-01 | 2021-11-11 | 에이에스엠 아이피 홀딩 비.브이. | Fast FOUP swapping with a FOUP handler |
KR20210141379A (en) | 2020-05-13 | 2021-11-23 | 에이에스엠 아이피 홀딩 비.브이. | Laser alignment fixture for a reactor system |
KR20210143653A (en) | 2020-05-19 | 2021-11-29 | 에이에스엠 아이피 홀딩 비.브이. | Substrate processing apparatus |
KR20210145078A (en) | 2020-05-21 | 2021-12-01 | 에이에스엠 아이피 홀딩 비.브이. | Structures including multiple carbon layers and methods of forming and using same |
KR20210145080A (en) | 2020-05-22 | 2021-12-01 | 에이에스엠 아이피 홀딩 비.브이. | Apparatus for depositing thin films using hydrogen peroxide |
TW202201602A (en) | 2020-05-29 | 2022-01-01 | 荷蘭商Asm Ip私人控股有限公司 | Substrate processing device |
TW202218133A (en) | 2020-06-24 | 2022-05-01 | 荷蘭商Asm Ip私人控股有限公司 | Method for forming a layer provided with silicon |
TW202217953A (en) | 2020-06-30 | 2022-05-01 | 荷蘭商Asm Ip私人控股有限公司 | Substrate processing method |
TW202202649A (en) | 2020-07-08 | 2022-01-16 | 荷蘭商Asm Ip私人控股有限公司 | Substrate processing method |
KR20220010438A (en) | 2020-07-17 | 2022-01-25 | 에이에스엠 아이피 홀딩 비.브이. | Structures and methods for use in photolithography |
TW202204662A (en) | 2020-07-20 | 2022-02-01 | 荷蘭商Asm Ip私人控股有限公司 | Method and system for depositing molybdenum layers |
US12040177B2 (en) | 2020-08-18 | 2024-07-16 | Asm Ip Holding B.V. | Methods for forming a laminate film by cyclical plasma-enhanced deposition processes |
KR20220027026A (en) | 2020-08-26 | 2022-03-07 | 에이에스엠 아이피 홀딩 비.브이. | Method and system for forming metal silicon oxide and metal silicon oxynitride |
USD990534S1 (en) | 2020-09-11 | 2023-06-27 | Asm Ip Holding B.V. | Weighted lift pin |
USD1012873S1 (en) | 2020-09-24 | 2024-01-30 | Asm Ip Holding B.V. | Electrode for semiconductor processing apparatus |
US12009224B2 (en) | 2020-09-29 | 2024-06-11 | Asm Ip Holding B.V. | Apparatus and method for etching metal nitrides |
TW202229613A (en) | 2020-10-14 | 2022-08-01 | 荷蘭商Asm Ip私人控股有限公司 | Method of depositing material on stepped structure |
KR20220053482A (en) | 2020-10-22 | 2022-04-29 | 에이에스엠 아이피 홀딩 비.브이. | Method of depositing vanadium metal, structure, device and a deposition assembly |
TW202223136A (en) | 2020-10-28 | 2022-06-16 | 荷蘭商Asm Ip私人控股有限公司 | Method for forming layer on substrate, and semiconductor processing system |
TW202235649A (en) | 2020-11-24 | 2022-09-16 | 荷蘭商Asm Ip私人控股有限公司 | Methods for filling a gap and related systems and devices |
KR20220076343A (en) | 2020-11-30 | 2022-06-08 | 에이에스엠 아이피 홀딩 비.브이. | an injector configured for arrangement within a reaction chamber of a substrate processing apparatus |
CN114639631A (en) | 2020-12-16 | 2022-06-17 | Asm Ip私人控股有限公司 | Fixing device for measuring jumping and swinging |
TW202231903A (en) | 2020-12-22 | 2022-08-16 | 荷蘭商Asm Ip私人控股有限公司 | Transition metal deposition method, transition metal layer, and deposition assembly for depositing transition metal on substrate |
USD980813S1 (en) | 2021-05-11 | 2023-03-14 | Asm Ip Holding B.V. | Gas flow control plate for substrate processing apparatus |
USD981973S1 (en) | 2021-05-11 | 2023-03-28 | Asm Ip Holding B.V. | Reactor wall for substrate processing apparatus |
USD980814S1 (en) | 2021-05-11 | 2023-03-14 | Asm Ip Holding B.V. | Gas distributor for substrate processing apparatus |
USD1023959S1 (en) | 2021-05-11 | 2024-04-23 | Asm Ip Holding B.V. | Electrode for substrate processing apparatus |
USD990441S1 (en) | 2021-09-07 | 2023-06-27 | Asm Ip Holding B.V. | Gas flow control plate |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20020064598A1 (en) * | 1999-06-11 | 2002-05-30 | Shulin Wang | Method of depositing a thick titanium nitride film |
US20030143328A1 (en) * | 2002-01-26 | 2003-07-31 | Applied Materials, Inc. | Apparatus and method for plasma assisted deposition |
US20060032443A1 (en) * | 2004-07-28 | 2006-02-16 | Kazuhide Hasebe | Film formation method and apparatus for semiconductor process |
US20100032842A1 (en) * | 2008-08-07 | 2010-02-11 | Texas Instruments Incorporated | MODULATED DEPOSITION PROCESS FOR STRESS CONTROL IN THICK TiN FILMS |
KR20100015073A (en) * | 2008-08-04 | 2010-02-12 | 한국과학기술원 | Method for manufacturing thin film transistors based on titanium oxides as active layer and thin film transistors thereof |
JP2010258413A (en) * | 2009-04-01 | 2010-11-11 | Elpida Memory Inc | Method of manufacturing capacitive insulating film for capacitor |
Family Cites Families (1187)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3089507A (en) | 1963-05-14 | Air eject system control valve | ||
US2161626A (en) | 1937-09-25 | 1939-06-06 | Walworth Patents Inc | Locking device |
US2745640A (en) | 1953-09-24 | 1956-05-15 | American Viscose Corp | Heat exchanging apparatus |
US3094396A (en) | 1959-07-07 | 1963-06-18 | Continental Can Co | Method of and apparatus for curing internal coatings on can bodies |
US2990045A (en) | 1959-09-18 | 1961-06-27 | Lipe Rollway Corp | Thermally responsive transmission for automobile fan |
US6482262B1 (en) | 1959-10-10 | 2002-11-19 | Asm Microchemistry Oy | Deposition of transition metal carbides |
US3232437A (en) | 1963-03-13 | 1966-02-01 | Champlon Lab Inc | Spin-on filter cartridge |
US4393013A (en) | 1970-05-20 | 1983-07-12 | J. C. Schumacher Company | Vapor mass flow control system |
US3833492A (en) | 1971-09-22 | 1974-09-03 | Pollution Control Ind Inc | Method of producing ozone |
US3862397A (en) | 1972-03-24 | 1975-01-21 | Applied Materials Tech | Cool wall radiantly heated reactor |
US3854443A (en) | 1973-12-19 | 1974-12-17 | Intel Corp | Gas reactor for depositing thin films |
US3887790A (en) | 1974-10-07 | 1975-06-03 | Vernon H Ferguson | Wrap-around electric resistance heater |
SE393967B (en) | 1974-11-29 | 1977-05-31 | Sateko Oy | PROCEDURE AND PERFORMANCE OF LAYING BETWEEN THE STORAGE IN A LABOR PACKAGE |
US4054071A (en) | 1975-06-17 | 1977-10-18 | Aetna-Standard Engineering Company | Flying saw with movable work shifter |
DE2610556C2 (en) | 1976-03-12 | 1978-02-02 | Siemens AG, 1000 Berlin und 8000 München | Device for distributing flowing media over a flow cross-section |
US4194536A (en) | 1976-12-09 | 1980-03-25 | Eaton Corporation | Composite tubing product |
US4181330A (en) | 1977-03-22 | 1980-01-01 | Noriatsu Kojima | Horn shaped multi-inlet pipe fitting |
US4176630A (en) | 1977-06-01 | 1979-12-04 | Dynair Limited | Automatic control valves |
US4145699A (en) | 1977-12-07 | 1979-03-20 | Bell Telephone Laboratories, Incorporated | Superconducting junctions utilizing a binary semiconductor barrier |
US4389973A (en) | 1980-03-18 | 1983-06-28 | Oy Lohja Ab | Apparatus for performing growth of compound thin films |
US4322592A (en) | 1980-08-22 | 1982-03-30 | Rca Corporation | Susceptor for heating semiconductor substrates |
US4479831A (en) | 1980-09-15 | 1984-10-30 | Burroughs Corporation | Method of making low resistance polysilicon gate transistors and low resistance interconnections therefor via gas deposited in-situ doped amorphous layer and heat-treatment |
US4436674A (en) | 1981-07-30 | 1984-03-13 | J.C. Schumacher Co. | Vapor mass flow control system |
US4414492A (en) | 1982-02-02 | 1983-11-08 | Intent Patent A.G. | Electronic ballast system |
US4401507A (en) | 1982-07-14 | 1983-08-30 | Advanced Semiconductor Materials/Am. | Method and apparatus for achieving spatially uniform externally excited non-thermal chemical reactions |
US4512113A (en) | 1982-09-23 | 1985-04-23 | Budinger William D | Workpiece holder for polishing operation |
US4499354A (en) | 1982-10-06 | 1985-02-12 | General Instrument Corp. | Susceptor for radiant absorption heater system |
US4570328A (en) | 1983-03-07 | 1986-02-18 | Motorola, Inc. | Method of producing titanium nitride MOS device gate electrode |
JPS6050923A (en) | 1983-08-31 | 1985-03-22 | Hitachi Ltd | Method of plasma surface treatment and device therefor |
USD288556S (en) | 1984-02-21 | 1987-03-03 | Pace, Incorporated | Ornamental design for a frame of circuit elements utilized to replace damaged elements on printed circuit boards |
US4735259A (en) | 1984-02-21 | 1988-04-05 | Hewlett-Packard Company | Heated transfer line for capillary tubing |
US4811684A (en) | 1984-11-26 | 1989-03-14 | Semiconductor Energy Laboratory Co., Ltd. | Photo CVD apparatus, with deposition prevention in light source chamber |
JPH0752718B2 (en) | 1984-11-26 | 1995-06-05 | 株式会社半導体エネルギー研究所 | Thin film formation method |
US4653541A (en) | 1985-06-26 | 1987-03-31 | Parker Hannifin Corporation | Dual wall safety tube |
US4789294A (en) | 1985-08-30 | 1988-12-06 | Canon Kabushiki Kaisha | Wafer handling apparatus and method |
US4654226A (en) | 1986-03-03 | 1987-03-31 | The University Of Delaware | Apparatus and method for photochemical vapor deposition |
US4722298A (en) | 1986-05-19 | 1988-02-02 | Machine Technology, Inc. | Modular processing apparatus for processing semiconductor wafers |
US4718637A (en) | 1986-07-02 | 1988-01-12 | Mdc Vacuum Products Corporation | High vacuum gate valve having improved metal vacuum joint |
US4681134A (en) | 1986-07-23 | 1987-07-21 | Paris Sr Raymond L | Valve lock |
US5183511A (en) | 1986-07-23 | 1993-02-02 | Semiconductor Energy Laboratory Co., Ltd. | Photo CVD apparatus with a glow discharge system |
US4882199A (en) | 1986-08-15 | 1989-11-21 | Massachusetts Institute Of Technology | Method of forming a metal coating on a substrate |
US4753192A (en) | 1987-01-08 | 1988-06-28 | Btu Engineering Corporation | Movable core fast cool-down furnace |
JPH0344472Y2 (en) | 1987-02-10 | 1991-09-18 | ||
US4976996A (en) | 1987-02-17 | 1990-12-11 | Lam Research Corporation | Chemical vapor deposition reactor and method of use thereof |
US4821674A (en) | 1987-03-31 | 1989-04-18 | Deboer Wiebe B | Rotatable substrate supporting mechanism with temperature sensing device for use in chemical vapor deposition equipment |
US4780169A (en) | 1987-05-11 | 1988-10-25 | Tegal Corporation | Non-uniform gas inlet for dry etching apparatus |
US4827430A (en) | 1987-05-11 | 1989-05-02 | Baxter International Inc. | Flow measurement system |
US5221556A (en) | 1987-06-24 | 1993-06-22 | Epsilon Technology, Inc. | Gas injectors for reaction chambers in CVD systems |
NO161941C (en) | 1987-06-25 | 1991-04-30 | Kvaerner Eng | PROCEDURE AT THE PLANT FOR TRANSPORTING HYDROCARBONS OVER LONG DISTANCE FROM A HYDROCARBON SOURCE TO SEA. |
US5062386A (en) | 1987-07-27 | 1991-11-05 | Epitaxy Systems, Inc. | Induction heated pancake epitaxial reactor |
USD327534S (en) | 1987-07-30 | 1992-06-30 | CLM Investments, Inc. | Floor drain strainer |
US4854263B1 (en) | 1987-08-14 | 1997-06-17 | Applied Materials Inc | Inlet manifold and methods for increasing gas dissociation and for PECVD of dielectric films |
US4857504A (en) | 1987-08-25 | 1989-08-15 | University Of Arkansas | Melt-produced high temperature rare earth barium copper oxide superconductor and processes for making same |
US4756794A (en) | 1987-08-31 | 1988-07-12 | The United States Of America As Represented By The Secretary Of The Navy | Atomic layer etching |
JPH0648217B2 (en) | 1987-12-24 | 1994-06-22 | 川惣電機工業株式会社 | Continuous temperature measuring device for molten metal |
US5028366A (en) | 1988-01-12 | 1991-07-02 | Air Products And Chemicals, Inc. | Water based mold release compositions for making molded polyurethane foam |
FR2628985B1 (en) | 1988-03-22 | 1990-12-28 | Labo Electronique Physique | EPITAXY REACTOR WITH WALL PROTECTION |
US4978567A (en) | 1988-03-31 | 1990-12-18 | Materials Technology Corporation, Subsidiary Of The Carbon/Graphite Group, Inc. | Wafer holding fixture for chemical reaction processes in rapid thermal processing equipment and method for making same |
JP2859632B2 (en) | 1988-04-14 | 1999-02-17 | キヤノン株式会社 | Film forming apparatus and film forming method |
US5178682A (en) | 1988-06-21 | 1993-01-12 | Mitsubishi Denki Kabushiki Kaisha | Method for forming a thin layer on a semiconductor substrate and apparatus therefor |
US4986215A (en) | 1988-09-01 | 1991-01-22 | Kyushu Electronic Metal Co., Ltd. | Susceptor for vapor-phase growth system |
JP2918892B2 (en) | 1988-10-14 | 1999-07-12 | 株式会社日立製作所 | Plasma etching method |
US4837185A (en) | 1988-10-26 | 1989-06-06 | Intel Corporation | Pulsed dual radio frequency CVD process |
US5119760A (en) | 1988-12-27 | 1992-06-09 | Symetrix Corporation | Methods and apparatus for material deposition |
JPH0834187B2 (en) | 1989-01-13 | 1996-03-29 | 東芝セラミックス株式会社 | Susceptor |
US5194401A (en) | 1989-04-18 | 1993-03-16 | Applied Materials, Inc. | Thermally processing semiconductor wafers at non-ambient pressures |
EP0395358B1 (en) | 1989-04-25 | 2001-03-14 | Matsushita Electronics Corporation | Manufacturing method of a bipolar transistor |
US5192717A (en) | 1989-04-28 | 1993-03-09 | Canon Kabushiki Kaisha | Process for the formation of a polycrystalline semiconductor film by microwave plasma chemical vapor deposition method |
US5360269A (en) | 1989-05-10 | 1994-11-01 | Tokyo Kogyo Kabushiki Kaisha | Immersion-type temperature measuring apparatus using thermocouple |
US4987856A (en) | 1989-05-22 | 1991-01-29 | Advanced Semiconductor Materials America, Inc. | High throughput multi station processor for multiple single wafers |
US5060322A (en) | 1989-07-27 | 1991-10-29 | Delepine Jean C | Shower room and ceiling element, especially for a shower room |
US5013691A (en) | 1989-07-31 | 1991-05-07 | At&T Bell Laboratories | Anisotropic deposition of silicon dioxide |
JPH0734936Y2 (en) | 1990-01-16 | 1995-08-09 | 大日本スクリーン製造株式会社 | Treatment liquid vapor supply device |
JPH03277774A (en) | 1990-03-27 | 1991-12-09 | Semiconductor Energy Lab Co Ltd | Photo-vapor reaction device |
DE4011933C2 (en) | 1990-04-12 | 1996-11-21 | Balzers Hochvakuum | Process for the reactive surface treatment of a workpiece and treatment chamber therefor |
US5167716A (en) | 1990-09-28 | 1992-12-01 | Gasonics, Inc. | Method and apparatus for batch processing a semiconductor wafer |
JP2780866B2 (en) | 1990-10-11 | 1998-07-30 | 大日本スクリーン製造 株式会社 | Light irradiation heating substrate temperature measurement device |
TW214599B (en) | 1990-10-15 | 1993-10-11 | Seiko Epson Corp | |
JPH04115531U (en) | 1991-03-25 | 1992-10-14 | ノリタケダイヤ株式会社 | Joint pipe for wire saw |
JP3323530B2 (en) | 1991-04-04 | 2002-09-09 | 株式会社日立製作所 | Method for manufacturing semiconductor device |
US5116018A (en) | 1991-04-12 | 1992-05-26 | Automax, Inc. | Lockout modules |
US5243195A (en) | 1991-04-25 | 1993-09-07 | Nikon Corporation | Projection exposure apparatus having an off-axis alignment system and method of alignment therefor |
US5104514A (en) | 1991-05-16 | 1992-04-14 | The United States Of America As Represented By The Secretary Of The Navy | Protective coating system for aluminum |
JP3040212B2 (en) | 1991-09-05 | 2000-05-15 | 株式会社東芝 | Vapor phase growth equipment |
US5430011A (en) | 1991-09-17 | 1995-07-04 | Sumitomi Electric Industries, Ltd. | Crystal compensated superconducting thin film formed of oxide superconductor material |
JP3140111B2 (en) | 1991-11-19 | 2001-03-05 | オリンパス光学工業株式会社 | High magnification microscope objective |
US5199603A (en) | 1991-11-26 | 1993-04-06 | Prescott Norman F | Delivery system for organometallic compounds |
US5455069A (en) | 1992-06-01 | 1995-10-03 | Motorola, Inc. | Method of improving layer uniformity in a CVD reactor |
KR100293830B1 (en) | 1992-06-22 | 2001-09-17 | 리차드 에이치. 로브그렌 | Plasma Purification Method for Removing Residues in Plasma Treatment Chamber |
US5534072A (en) | 1992-06-24 | 1996-07-09 | Anelva Corporation | Integrated module multi-chamber CVD processing system and its method for processing subtrates |
JP3148004B2 (en) | 1992-07-06 | 2001-03-19 | 株式会社東芝 | Optical CVD apparatus and method for manufacturing semiconductor device using the same |
US5601641A (en) | 1992-07-21 | 1997-02-11 | Tse Industries, Inc. | Mold release composition with polybutadiene and method of coating a mold core |
KR100304127B1 (en) | 1992-07-29 | 2001-11-30 | 이노마다 시게오 | Electronic-substrate treatment system using portable sealed container and apparatus thereof |
US5271967A (en) | 1992-08-21 | 1993-12-21 | General Motors Corporation | Method and apparatus for application of thermal spray coatings to engine blocks |
US5326427A (en) | 1992-09-11 | 1994-07-05 | Lsi Logic Corporation | Method of selectively etching titanium-containing materials on a semiconductor wafer using remote plasma generation |
JPH06295862A (en) | 1992-11-20 | 1994-10-21 | Mitsubishi Electric Corp | Compound semiconductor fabrication system and organic metal material vessel |
IT1257434B (en) | 1992-12-04 | 1996-01-17 | Cselt Centro Studi Lab Telecom | STEAM GENERATOR FOR VAPOR PHASE CHEMICAL LAYING PLANTS |
US5382311A (en) | 1992-12-17 | 1995-01-17 | Tokyo Electron Limited | Stage having electrostatic chuck and plasma processing apparatus using same |
JPH0653210U (en) | 1992-12-28 | 1994-07-19 | 株式会社三田 | Escape wheel rescue plate |
US5421893A (en) | 1993-02-26 | 1995-06-06 | Applied Materials, Inc. | Susceptor drive and wafer displacement mechanism |
DE4311197A1 (en) | 1993-04-05 | 1994-10-06 | Patent Treuhand Ges Fuer Elektrische Gluehlampen Mbh | Method for operating an incoherently radiating light source |
US5404082A (en) | 1993-04-23 | 1995-04-04 | North American Philips Corporation | High frequency inverter with power-line-controlled frequency modulation |
US5354580A (en) | 1993-06-08 | 1994-10-11 | Cvd Incorporated | Triangular deposition chamber for a vapor deposition system |
JPH0799162A (en) | 1993-06-21 | 1995-04-11 | Hitachi Ltd | Cvd reactor apparatus |
EP0630749B1 (en) | 1993-06-28 | 1998-12-23 | Canon Kabushiki Kaisha | Heat generating resistor containing TaN0.8, substrate provided with said heat generating resistor for liquid jet head, liquid jet head provided with said substrate, and liquid jet apparatus provided with said liquid jet head |
US5997768A (en) | 1993-06-29 | 1999-12-07 | Ciba Specialty Chemicals Corporation | Pelletization of metal soap powders |
US5415753A (en) | 1993-07-22 | 1995-05-16 | Materials Research Corporation | Stationary aperture plate for reactive sputter deposition |
US6122036A (en) | 1993-10-21 | 2000-09-19 | Nikon Corporation | Projection exposure apparatus and method |
JP2682403B2 (en) | 1993-10-29 | 1997-11-26 | 日本電気株式会社 | Method for manufacturing semiconductor device |
US5413813A (en) | 1993-11-23 | 1995-05-09 | Enichem S.P.A. | CVD of silicon-based ceramic materials on internal surface of a reactor |
US5616947A (en) | 1994-02-01 | 1997-04-01 | Matsushita Electric Industrial Co., Ltd. | Semiconductor device having an MIS structure |
US5681779A (en) | 1994-02-04 | 1997-10-28 | Lsi Logic Corporation | Method of doping metal layers for electromigration resistance |
US5589002A (en) | 1994-03-24 | 1996-12-31 | Applied Materials, Inc. | Gas distribution plate for semiconductor wafer processing apparatus with means for inhibiting arcing |
JP3211548B2 (en) | 1994-03-30 | 2001-09-25 | ウシオ電機株式会社 | Dielectric barrier discharge fluorescent lamp |
JPH07283149A (en) | 1994-04-04 | 1995-10-27 | Nissin Electric Co Ltd | Thin film vapor growth device |
US5531835A (en) | 1994-05-18 | 1996-07-02 | Applied Materials, Inc. | Patterned susceptor to reduce electrostatic force in a CVD chamber |
US5858819A (en) | 1994-06-15 | 1999-01-12 | Seiko Epson Corporation | Fabrication method for a thin film semiconductor device, the thin film semiconductor device itself, liquid crystal display, and electronic device |
US5504042A (en) | 1994-06-23 | 1996-04-02 | Texas Instruments Incorporated | Porous dielectric material with improved pore surface properties for electronics applications |
JP2709568B2 (en) | 1994-06-30 | 1998-02-04 | 日本プレシジョン・サーキッツ株式会社 | Down flow type spin dryer |
US5838029A (en) | 1994-08-22 | 1998-11-17 | Rohm Co., Ltd. | GaN-type light emitting device formed on a silicon substrate |
US5730801A (en) | 1994-08-23 | 1998-03-24 | Applied Materials, Inc. | Compartnetalized substrate processing chamber |
JP3632256B2 (en) | 1994-09-30 | 2005-03-23 | 株式会社デンソー | Manufacturing method of semiconductor device having silicon nitride film |
JP2845163B2 (en) | 1994-10-27 | 1999-01-13 | 日本電気株式会社 | Plasma processing method and apparatus |
US6699530B2 (en) * | 1995-07-06 | 2004-03-02 | Applied Materials, Inc. | Method for constructing a film on a semiconductor wafer |
FI97730C (en) | 1994-11-28 | 1997-02-10 | Mikrokemia Oy | Equipment for the production of thin films |
JPH08181135A (en) | 1994-12-22 | 1996-07-12 | Sharp Corp | Manufacture of semiconductor device |
JP3151118B2 (en) | 1995-03-01 | 2001-04-03 | 東京エレクトロン株式会社 | Heat treatment equipment |
US5518549A (en) | 1995-04-18 | 1996-05-21 | Memc Electronic Materials, Inc. | Susceptor and baffle therefor |
JP3360098B2 (en) | 1995-04-20 | 2002-12-24 | 東京エレクトロン株式会社 | Shower head structure of processing equipment |
US5852879A (en) | 1995-04-26 | 1998-12-29 | Schumaier; Daniel R. | Moisture sensitive item drying appliance |
SE506163C2 (en) | 1995-04-27 | 1997-11-17 | Ericsson Telefon Ab L M | Device at a silicon substrate having a recess for receiving an element and method for making such a device |
US6190634B1 (en) | 1995-06-07 | 2001-02-20 | President And Fellows Of Harvard College | Carbide nanomaterials |
US5683517A (en) | 1995-06-07 | 1997-11-04 | Applied Materials, Inc. | Plasma reactor with programmable reactant gas distribution |
JPH08335558A (en) | 1995-06-08 | 1996-12-17 | Nissin Electric Co Ltd | Thin film vapor phase deposition apparatus |
JP3380091B2 (en) | 1995-06-09 | 2003-02-24 | 株式会社荏原製作所 | Reactive gas injection head and thin film vapor phase growth apparatus |
US20020114886A1 (en) | 1995-07-06 | 2002-08-22 | Applied Materials, Inc. | Method of tisin deposition using a chemical vapor deposition process |
NO953217L (en) | 1995-08-16 | 1997-02-17 | Aker Eng As | Method and arrangement of pipe bundles |
US6113702A (en) | 1995-09-01 | 2000-09-05 | Asm America, Inc. | Wafer support system |
US5997588A (en) | 1995-10-13 | 1999-12-07 | Advanced Semiconductor Materials America, Inc. | Semiconductor processing system with gas curtain |
US5801104A (en) | 1995-10-24 | 1998-09-01 | Micron Technology, Inc. | Uniform dielectric film deposition on textured surfaces |
KR100201386B1 (en) | 1995-10-28 | 1999-06-15 | 구본준 | Reaction gas injecting apparatus of chemical vapor deposition apparatus |
US5736314A (en) | 1995-11-16 | 1998-04-07 | Microfab Technologies, Inc. | Inline thermo-cycler |
US5796074A (en) | 1995-11-28 | 1998-08-18 | Applied Materials, Inc. | Wafer heater assembly |
JPH09172055A (en) | 1995-12-19 | 1997-06-30 | Fujitsu Ltd | Electrostatic chuck and method for attracting wafer |
KR100267418B1 (en) | 1995-12-28 | 2000-10-16 | 엔도 마코토 | Plasma treatment and plasma treating device |
US5679215A (en) | 1996-01-02 | 1997-10-21 | Lam Research Corporation | Method of in situ cleaning a vacuum plasma processing chamber |
US6017818A (en) * | 1996-01-22 | 2000-01-25 | Texas Instruments Incorporated | Process for fabricating conformal Ti-Si-N and Ti-B-N based barrier films with low defect density |
US5632919A (en) | 1996-01-25 | 1997-05-27 | T.G.M., Inc. | Temperature controlled insulation system |
SE9600705D0 (en) | 1996-02-26 | 1996-02-26 | Abb Research Ltd | A susceptor for a device for epitaxially growing objects and such a device |
US5837320A (en) | 1996-02-27 | 1998-11-17 | The University Of New Mexico | Chemical vapor deposition of metal sulfide films from metal thiocarboxylate complexes with monodenate or multidentate ligands |
US5732744A (en) | 1996-03-08 | 1998-03-31 | Control Systems, Inc. | Method and apparatus for aligning and supporting semiconductor process gas delivery and regulation components |
DE19609678C2 (en) | 1996-03-12 | 2003-04-17 | Infineon Technologies Ag | Memory cell arrangement with stripe-shaped, parallel trenches and vertical MOS transistors and method for their production |
USD380527S (en) | 1996-03-19 | 1997-07-01 | Cherle Velez | Sink drain shield |
US5819434A (en) | 1996-04-25 | 1998-10-13 | Applied Materials, Inc. | Etch enhancement using an improved gas distribution plate |
US5920798A (en) | 1996-05-28 | 1999-07-06 | Matsushita Battery Industrial Co., Ltd. | Method of preparing a semiconductor layer for an optical transforming device |
US6342277B1 (en) | 1996-08-16 | 2002-01-29 | Licensee For Microelectronics: Asm America, Inc. | Sequential chemical vapor deposition |
US5993916A (en) | 1996-07-12 | 1999-11-30 | Applied Materials, Inc. | Method for substrate processing with improved throughput and yield |
US5827757A (en) | 1996-07-16 | 1998-10-27 | Direct Radiography Corp. | Fabrication of large area x-ray image capturing element |
US5724748A (en) | 1996-07-24 | 1998-03-10 | Brooks; Ray G. | Apparatus for packaging contaminant-sensitive articles and resulting package |
US5781693A (en) | 1996-07-24 | 1998-07-14 | Applied Materials, Inc. | Gas introduction showerhead for an RTP chamber with upper and lower transparent plates and gas flow therebetween |
KR0183912B1 (en) | 1996-08-08 | 1999-05-01 | 김광호 | Pumping facility connected to the multi-reaction chamber and method thereof |
US5916365A (en) | 1996-08-16 | 1999-06-29 | Sherman; Arthur | Sequential chemical vapor deposition |
JP3122618B2 (en) | 1996-08-23 | 2001-01-09 | 東京エレクトロン株式会社 | Plasma processing equipment |
US5928389A (en) | 1996-10-21 | 1999-07-27 | Applied Materials, Inc. | Method and apparatus for priority based scheduling of wafer processing within a multiple chamber semiconductor wafer processing tool |
US6347636B1 (en) | 1996-11-13 | 2002-02-19 | Applied Materials, Inc. | Methods and apparatus for gettering fluorine from chamber material surfaces |
US5855681A (en) | 1996-11-18 | 1999-01-05 | Applied Materials, Inc. | Ultra high throughput wafer vacuum processing system |
US5836483A (en) | 1997-02-05 | 1998-11-17 | Aerotech Dental Systems, Inc. | Self-regulating fluid dispensing cap with safety pressure relief valve for dental/medical unit fluid bottles |
US6367410B1 (en) | 1996-12-16 | 2002-04-09 | Applied Materials, Inc. | Closed-loop dome thermal control apparatus for a semiconductor wafer processing system |
US5953635A (en) | 1996-12-19 | 1999-09-14 | Intel Corporation | Interlayer dielectric with a composite dielectric stack |
US6035101A (en) | 1997-02-12 | 2000-03-07 | Applied Materials, Inc. | High temperature multi-layered alloy heater assembly and related methods |
US6461982B2 (en) | 1997-02-27 | 2002-10-08 | Micron Technology, Inc. | Methods for forming a dielectric film |
JP3752578B2 (en) | 1997-04-21 | 2006-03-08 | 株式会社フジキン | Heating device for fluid controller |
US6026762A (en) | 1997-04-23 | 2000-02-22 | Applied Materials, Inc. | Apparatus for improved remote microwave plasma source for use with substrate processing systems |
JP3230051B2 (en) | 1997-05-16 | 2001-11-19 | 東京エレクトロン株式会社 | Drying method and apparatus |
JPH1144799A (en) | 1997-05-27 | 1999-02-16 | Ushio Inc | Optical path split type ultraviolet irradiation device |
US6201999B1 (en) | 1997-06-09 | 2001-03-13 | Applied Materials, Inc. | Method and apparatus for automatically generating schedules for wafer processing within a multichamber semiconductor wafer processing tool |
US5968275A (en) | 1997-06-25 | 1999-10-19 | Lam Research Corporation | Methods and apparatus for passivating a substrate in a plasma reactor |
US6531193B2 (en) | 1997-07-07 | 2003-03-11 | The Penn State Research Foundation | Low temperature, high quality silicon dioxide thin films deposited using tetramethylsilane (TMS) for stress control and coverage applications |
US6576064B2 (en) | 1997-07-10 | 2003-06-10 | Sandia Corporation | Support apparatus for semiconductor wafer processing |
US6312525B1 (en) | 1997-07-11 | 2001-11-06 | Applied Materials, Inc. | Modular architecture for semiconductor wafer fabrication equipment |
US6083321A (en) | 1997-07-11 | 2000-07-04 | Applied Materials, Inc. | Fluid delivery system and method |
US6024799A (en) | 1997-07-11 | 2000-02-15 | Applied Materials, Inc. | Chemical vapor deposition manifold |
US5975492A (en) | 1997-07-14 | 1999-11-02 | Brenes; Arthur | Bellows driver slot valve |
US6099596A (en) | 1997-07-23 | 2000-08-08 | Applied Materials, Inc. | Wafer out-of-pocket detection tool |
US6020243A (en) | 1997-07-24 | 2000-02-01 | Texas Instruments Incorporated | Zirconium and/or hafnium silicon-oxynitride gate dielectric |
KR100385946B1 (en) | 1999-12-08 | 2003-06-02 | 삼성전자주식회사 | Method for forming a metal layer by an atomic layer deposition and a semiconductor device with the metal layer as a barrier metal layer, an upper electrode, or a lower electrode of capacitor |
US6287965B1 (en) | 1997-07-28 | 2001-09-11 | Samsung Electronics Co, Ltd. | Method of forming metal layer using atomic layer deposition and semiconductor device having the metal layer as barrier metal layer or upper or lower electrode of capacitor |
US7393561B2 (en) | 1997-08-11 | 2008-07-01 | Applied Materials, Inc. | Method and apparatus for layer by layer deposition of thin films |
JP3317209B2 (en) | 1997-08-12 | 2002-08-26 | 東京エレクトロンエイ・ティー株式会社 | Plasma processing apparatus and plasma processing method |
US6161500A (en) | 1997-09-30 | 2000-12-19 | Tokyo Electron Limited | Apparatus and method for preventing the premature mixture of reactant gases in CVD and PECVD reactions |
US5908672A (en) | 1997-10-15 | 1999-06-01 | Applied Materials, Inc. | Method and apparatus for depositing a planarized passivation layer |
US6325858B1 (en) | 1997-11-03 | 2001-12-04 | Asm America, Inc. | Long life high temperature process chamber |
JP3050193B2 (en) | 1997-11-12 | 2000-06-12 | 日本電気株式会社 | Semiconductor device and manufacturing method thereof |
EP1049640A4 (en) | 1997-11-28 | 2008-03-12 | Mattson Tech Inc | Systems and methods for low contamination, high throughput handling of workpieces for vacuum processing |
US6248168B1 (en) | 1997-12-15 | 2001-06-19 | Tokyo Electron Limited | Spin coating apparatus including aging unit and solvent replacement unit |
USD409894S (en) | 1997-12-30 | 1999-05-18 | Mcclurg Ben B | Sheet rock plug |
KR100249391B1 (en) | 1997-12-30 | 2000-03-15 | 김영환 | Heater block |
US6125789A (en) | 1998-01-30 | 2000-10-03 | Applied Materials, Inc. | Increasing the sensitivity of an in-situ particle monitor |
US6383955B1 (en) | 1998-02-05 | 2002-05-07 | Asm Japan K.K. | Silicone polymer insulation film on semiconductor substrate and method for forming the film |
TW437017B (en) | 1998-02-05 | 2001-05-28 | Asm Japan Kk | Silicone polymer insulation film on semiconductor substrate and method for formation thereof |
US6303523B2 (en) | 1998-02-11 | 2001-10-16 | Applied Materials, Inc. | Plasma processes for depositing low dielectric constant films |
US6413583B1 (en) | 1998-02-11 | 2002-07-02 | Applied Materials, Inc. | Formation of a liquid-like silica layer by reaction of an organosilicon compound and a hydroxyl forming compound |
US6050506A (en) | 1998-02-13 | 2000-04-18 | Applied Materials, Inc. | Pattern of apertures in a showerhead for chemical vapor deposition |
US6015465A (en) | 1998-04-08 | 2000-01-18 | Applied Materials, Inc. | Temperature control system for semiconductor process chamber |
US6218288B1 (en) | 1998-05-11 | 2001-04-17 | Micron Technology, Inc. | Multiple step methods for forming conformal layers |
KR100309918B1 (en) | 1998-05-16 | 2001-12-17 | 윤종용 | Liquid crystal display having wide viewing angle and method for manufacturing the same |
JP3208376B2 (en) | 1998-05-20 | 2001-09-10 | 株式会社半導体プロセス研究所 | Film forming method and semiconductor device manufacturing method |
JPH11343571A (en) | 1998-05-29 | 1999-12-14 | Ngk Insulators Ltd | Susceptor |
JPH11354637A (en) | 1998-06-11 | 1999-12-24 | Oki Electric Ind Co Ltd | Connection structure for wiring and formation of connection part of the wiring |
US6086677A (en) | 1998-06-16 | 2000-07-11 | Applied Materials, Inc. | Dual gas faceplate for a showerhead in a semiconductor wafer processing system |
US6302964B1 (en) | 1998-06-16 | 2001-10-16 | Applied Materials, Inc. | One-piece dual gas faceplate for a showerhead in a semiconductor wafer processing system |
US6148761A (en) | 1998-06-16 | 2000-11-21 | Applied Materials, Inc. | Dual channel gas distribution plate |
JP2963443B1 (en) | 1998-06-19 | 1999-10-18 | キヤノン販売株式会社 | Semiconductor device manufacturing equipment |
KR20000002833A (en) | 1998-06-23 | 2000-01-15 | 윤종용 | Semiconductor wafer boat |
US6232248B1 (en) | 1998-07-03 | 2001-05-15 | Tokyo Electron Limited | Single-substrate-heat-processing method for performing reformation and crystallization |
JP2000040728A (en) | 1998-07-22 | 2000-02-08 | Nippon Asm Kk | Wafer carrying mechanism |
US20010001384A1 (en) | 1998-07-29 | 2001-05-24 | Takeshi Arai | Silicon epitaxial wafer and production method therefor |
US6190732B1 (en) | 1998-09-03 | 2001-02-20 | Cvc Products, Inc. | Method and system for dispensing process gas for fabricating a device on a substrate |
USD451893S1 (en) | 1998-10-15 | 2001-12-11 | Meto International Gmbh | Arrangement of aluminum foil coils forming an inductor of a resonant frequency identification element |
US6454860B2 (en) | 1998-10-27 | 2002-09-24 | Applied Materials, Inc. | Deposition reactor having vaporizing, mixing and cleaning capabilities |
JP2000150617A (en) | 1998-11-17 | 2000-05-30 | Tokyo Electron Ltd | Transporter |
JP2000183346A (en) | 1998-12-15 | 2000-06-30 | Toshiba Corp | Semiconductor device and manufacture thereof |
US6129954A (en) | 1998-12-22 | 2000-10-10 | General Electric Company | Method for thermally spraying crack-free mullite coatings on ceramic-based substrates |
US6137240A (en) | 1998-12-31 | 2000-10-24 | Lumion Corporation | Universal ballast control circuit |
KR100331544B1 (en) | 1999-01-18 | 2002-04-06 | 윤종용 | Method for introducing gases into a reactor chamber and a shower head used therein |
TW455912B (en) | 1999-01-22 | 2001-09-21 | Sony Corp | Method and apparatus for film deposition |
US6044860A (en) | 1999-02-01 | 2000-04-04 | Spx Corporation | Adjustable lockout device for knife gate valves |
US6374831B1 (en) | 1999-02-04 | 2002-04-23 | Applied Materials, Inc. | Accelerated plasma clean |
IT1308606B1 (en) | 1999-02-12 | 2002-01-08 | Lpe Spa | DEVICE FOR HANDLING SUBSTRATES BY MEANS OF A SELF-LEVELING DEPRESSION SYSTEM IN INDUCTION EPISTAXIAL REACTORS WITH SUCCESSOR |
KR20010042649A (en) | 1999-02-12 | 2001-05-25 | 베리 아이클스 | Chemical vapor deposition of tungsten nitride |
US6250250B1 (en) | 1999-03-18 | 2001-06-26 | Yuri Maishev | Multiple-cell source of uniform plasma |
JP3398936B2 (en) | 1999-04-09 | 2003-04-21 | 日本エー・エス・エム株式会社 | Semiconductor processing equipment |
US6326597B1 (en) | 1999-04-15 | 2001-12-04 | Applied Materials, Inc. | Temperature control system for process chamber |
KR100347379B1 (en) | 1999-05-01 | 2002-08-07 | 주식회사 피케이엘 | Atomic layer deposition apparatus for depositing multi substrate |
JP3072989B1 (en) | 1999-05-14 | 2000-08-07 | 日本エー・エス・エム株式会社 | Film forming method in a film forming apparatus for forming a thin film on a semiconductor substrate |
JP4294791B2 (en) | 1999-05-17 | 2009-07-15 | アプライド マテリアルズ インコーポレイテッド | Semiconductor manufacturing equipment |
JP3668079B2 (en) | 1999-05-31 | 2005-07-06 | 忠弘 大見 | Plasma process equipment |
US6555183B2 (en) * | 1999-06-11 | 2003-04-29 | Applied Materials, Inc. | Plasma treatment of a titanium nitride film formed by chemical vapor deposition |
US6281098B1 (en) | 1999-06-15 | 2001-08-28 | Midwest Research Institute | Process for Polycrystalline film silicon growth |
US6821571B2 (en) | 1999-06-18 | 2004-11-23 | Applied Materials Inc. | Plasma treatment to enhance adhesion and to minimize oxidation of carbon-containing layers |
FR2795745B1 (en) | 1999-06-30 | 2001-08-03 | Saint Gobain Vitrage | PROCESS FOR DEPOSITING A TUNGSTENE AND / OR MOLYBDENE LAYER ON A GLASS, CERAMIC OR VITROCERAMIC SUBSTRATE, AND SUBSTRATE THUS COATED |
JP3252835B2 (en) | 1999-07-02 | 2002-02-04 | 松下電器産業株式会社 | Semiconductor device and manufacturing method thereof |
JP2001023955A (en) | 1999-07-07 | 2001-01-26 | Mitsubishi Electric Corp | Plasma processing apparatus |
EP1077479A1 (en) | 1999-08-17 | 2001-02-21 | Applied Materials, Inc. | Post-deposition treatment to enchance properties of Si-O-C low K film |
US6579833B1 (en) | 1999-09-01 | 2003-06-17 | The Board Of Trustees Of The University Of Illinois | Process for converting a metal carbide to carbon by etching in halogens |
US6429146B2 (en) | 1999-09-02 | 2002-08-06 | Micron Technology, Inc. | Wafer planarization using a uniform layer of material and method and apparatus for forming uniform layer of material used in semiconductor processing |
JP2001077088A (en) | 1999-09-02 | 2001-03-23 | Tokyo Electron Ltd | Plasma processing device |
US6511539B1 (en) | 1999-09-08 | 2003-01-28 | Asm America, Inc. | Apparatus and method for growth of a thin film |
US6355153B1 (en) | 1999-09-17 | 2002-03-12 | Nutool, Inc. | Chip interconnect and packaging deposition methods and structures |
US6420792B1 (en) | 1999-09-24 | 2002-07-16 | Texas Instruments Incorporated | Semiconductor wafer edge marking |
US6740853B1 (en) | 1999-09-29 | 2004-05-25 | Tokyo Electron Limited | Multi-zone resistance heater |
JP4209057B2 (en) | 1999-12-01 | 2009-01-14 | 東京エレクトロン株式会社 | Ceramic heater, substrate processing apparatus and substrate processing method using the same |
KR100369324B1 (en) | 1999-12-02 | 2003-01-24 | 한국전자통신연구원 | Method for fabricating planar type micro cavity |
FI118804B (en) | 1999-12-03 | 2008-03-31 | Asm Int | Process for making oxide films |
JP2001176952A (en) | 1999-12-21 | 2001-06-29 | Toshiba Mach Co Ltd | Positional shift detector for wafer |
JP3810604B2 (en) | 1999-12-21 | 2006-08-16 | Smc株式会社 | Gate valve |
US6576062B2 (en) | 2000-01-06 | 2003-06-10 | Tokyo Electron Limited | Film forming apparatus and film forming method |
US6541367B1 (en) | 2000-01-18 | 2003-04-01 | Applied Materials, Inc. | Very low dielectric constant plasma-enhanced CVD films |
KR100767762B1 (en) | 2000-01-18 | 2007-10-17 | 에이에스엠 저펜 가부시기가이샤 | A CVD semiconductor-processing device provided with a remote plasma source for self cleaning |
US6475930B1 (en) | 2000-01-31 | 2002-11-05 | Motorola, Inc. | UV cure process and tool for low k film formation |
US6436819B1 (en) | 2000-02-01 | 2002-08-20 | Applied Materials, Inc. | Nitrogen treatment of a metal nitride/metal stack |
US6521046B2 (en) | 2000-02-04 | 2003-02-18 | Kabushiki Kaisha Kobe Seiko Sho | Chamber material made of Al alloy and heater block |
US6372583B1 (en) | 2000-02-09 | 2002-04-16 | Intel Corporation | Process for making semiconductor device with epitaxially grown source and drain |
US6407435B1 (en) | 2000-02-11 | 2002-06-18 | Sharp Laboratories Of America, Inc. | Multilayer dielectric stack and method |
US6573030B1 (en) | 2000-02-17 | 2003-06-03 | Applied Materials, Inc. | Method for depositing an amorphous carbon layer |
TW476996B (en) | 2000-02-28 | 2002-02-21 | Mitsubishi Material Silicon | Semiconductor manufacturing method and semiconductor manufacturing apparatus |
DE60125338T2 (en) | 2000-03-07 | 2007-07-05 | Asm International N.V. | GRADED THIN LAYERS |
US6558755B2 (en) | 2000-03-20 | 2003-05-06 | Dow Corning Corporation | Plasma curing process for porous silica thin film |
US6576300B1 (en) | 2000-03-20 | 2003-06-10 | Dow Corning Corporation | High modulus, low dielectric constant coatings |
US6759098B2 (en) | 2000-03-20 | 2004-07-06 | Axcelis Technologies, Inc. | Plasma curing of MSQ-based porous low-k film materials |
US6913796B2 (en) | 2000-03-20 | 2005-07-05 | Axcelis Technologies, Inc. | Plasma curing process for porous low-k materials |
US6598559B1 (en) | 2000-03-24 | 2003-07-29 | Applied Materials, Inc. | Temperature controlled chamber |
JP2001342570A (en) | 2000-03-30 | 2001-12-14 | Hitachi Kokusai Electric Inc | Manufacturing method of semiconductor device and manufacturing apparatus of semiconductor |
AU2001247685A1 (en) | 2000-03-30 | 2001-10-15 | Tokyo Electron Limited | Method of and apparatus for tunable gas injection in a plasma processing system |
JP2001345263A (en) | 2000-03-31 | 2001-12-14 | Nikon Corp | Aligner, exposure method, and device-manufacturing method |
FI117979B (en) | 2000-04-14 | 2007-05-15 | Asm Int | Process for making oxide thin films |
US6329297B1 (en) | 2000-04-21 | 2001-12-11 | Applied Materials, Inc. | Dilute remote plasma clean |
US6635117B1 (en) | 2000-04-26 | 2003-10-21 | Axcelis Technologies, Inc. | Actively-cooled distribution plate for reducing reactive gas temperature in a plasma processing system |
US6387207B1 (en) | 2000-04-28 | 2002-05-14 | Applied Materials, Inc. | Integration of remote plasma generator with semiconductor processing chamber |
KR100367662B1 (en) | 2000-05-02 | 2003-01-10 | 주식회사 셈테크놀러지 | Hyperthermal Neutral Particle Beam Source and Neutral Particle Beam Processing Apparatus Employing the Same |
DE10021871A1 (en) | 2000-05-05 | 2001-11-15 | Infineon Technologies Ag | Method for producing a barrier layer in an electronic component and method for producing an electronic component with a barrier layer |
JP3448737B2 (en) | 2000-05-25 | 2003-09-22 | 住友重機械工業株式会社 | Wafer chuck cooling plate and wafer chuck |
EP2293322A1 (en) * | 2000-06-08 | 2011-03-09 | Genitech, Inc. | Method for forming a metal nitride layer |
US6863019B2 (en) | 2000-06-13 | 2005-03-08 | Applied Materials, Inc. | Semiconductor device fabrication chamber cleaning method and apparatus with recirculation of cleaning gas |
KR100406173B1 (en) | 2000-06-13 | 2003-11-19 | 주식회사 하이닉스반도체 | Heater Block Having Catalyst Injection means |
US6461435B1 (en) | 2000-06-22 | 2002-10-08 | Applied Materials, Inc. | Showerhead with reduced contact area |
KR100467366B1 (en) | 2000-06-30 | 2005-01-24 | 주식회사 하이닉스반도체 | A method for forming zirconium oxide film using atomic layer deposition |
US6874480B1 (en) | 2000-07-03 | 2005-04-05 | Combustion Dynamics Corp. | Flow meter |
US6821910B2 (en) | 2000-07-24 | 2004-11-23 | University Of Maryland, College Park | Spatially programmable microelectronics process equipment using segmented gas injection showerhead with exhaust gas recirculation |
US7223676B2 (en) | 2002-06-05 | 2007-05-29 | Applied Materials, Inc. | Very low temperature CVD process with independently variable conformality, stress and composition of the CVD layer |
US7166524B2 (en) | 2000-08-11 | 2007-01-23 | Applied Materials, Inc. | Method for ion implanting insulator material to reduce dielectric constant |
US6784108B1 (en) | 2000-08-31 | 2004-08-31 | Micron Technology, Inc. | Gas pulsing for etch profile control |
USD449873S1 (en) | 2000-09-22 | 2001-10-30 | James Bronson | Garbage disposal strainer and splash guard |
US6494065B2 (en) | 2000-09-26 | 2002-12-17 | Babbitt Steam Specialty Company | Valve lockout/tag out system |
US6370796B1 (en) | 2000-09-29 | 2002-04-16 | Sony Corporation | Heater block cooling system for wafer processing apparatus |
AU146326S (en) | 2000-09-29 | 2001-12-18 | American Standard Int Inc | Faucet |
US6578893B2 (en) | 2000-10-02 | 2003-06-17 | Ajs Automation, Inc. | Apparatus and methods for handling semiconductor wafers |
US6660660B2 (en) | 2000-10-10 | 2003-12-09 | Asm International, Nv. | Methods for making a dielectric stack in an integrated circuit |
US7204887B2 (en) | 2000-10-16 | 2007-04-17 | Nippon Steel Corporation | Wafer holding, wafer support member, wafer boat and heat treatment furnace |
JP4156788B2 (en) | 2000-10-23 | 2008-09-24 | 日本碍子株式会社 | Susceptor for semiconductor manufacturing equipment |
TW548239B (en) | 2000-10-23 | 2003-08-21 | Asm Microchemistry Oy | Process for producing aluminium oxide films at low temperatures |
US6824665B2 (en) | 2000-10-25 | 2004-11-30 | Shipley Company, L.L.C. | Seed layer deposition |
US6688784B1 (en) | 2000-10-25 | 2004-02-10 | Advanced Micro Devices, Inc. | Parallel plate development with multiple holes in top plate for control of developer flow and pressure |
US6445574B1 (en) | 2000-10-30 | 2002-09-03 | Motorola, Inc. | Electronic device |
JP2002158178A (en) | 2000-11-21 | 2002-05-31 | Hitachi Kokusai Electric Inc | Substrate processing apparatus and method of manufacturing semiconductor device |
US6689220B1 (en) * | 2000-11-22 | 2004-02-10 | Simplus Systems Corporation | Plasma enhanced pulsed layer deposition |
US6613695B2 (en) | 2000-11-24 | 2003-09-02 | Asm America, Inc. | Surface preparation prior to deposition |
US20020064592A1 (en) | 2000-11-29 | 2002-05-30 | Madhav Datta | Electroless method of seed layer depostion, repair, and fabrication of Cu interconnects |
EP1351283A4 (en) | 2000-12-05 | 2006-01-25 | Tokyo Electron Ltd | Method and apparatus for treating article to be treated |
KR100385947B1 (en) | 2000-12-06 | 2003-06-02 | 삼성전자주식회사 | Method of forming thin film by atomic layer deposition |
US6413321B1 (en) | 2000-12-07 | 2002-07-02 | Applied Materials, Inc. | Method and apparatus for reducing particle contamination on wafer backside during CVD process |
US20020076507A1 (en) | 2000-12-15 | 2002-06-20 | Chiang Tony P. | Process sequence for atomic layer deposition |
JP5068402B2 (en) | 2000-12-28 | 2012-11-07 | 公益財団法人国際科学振興財団 | Dielectric film and method for forming the same, semiconductor device, nonvolatile semiconductor memory device, and method for manufacturing semiconductor device |
US6398184B1 (en) | 2000-12-29 | 2002-06-04 | General Signal Corporation | Lock device and lock method for knife gate valves |
US7172497B2 (en) | 2001-01-05 | 2007-02-06 | Asm Nutool, Inc. | Fabrication of semiconductor interconnect structures |
US6583048B2 (en) | 2001-01-17 | 2003-06-24 | Air Products And Chemicals, Inc. | Organosilicon precursors for interlayer dielectric films with low dielectric constants |
US7087482B2 (en) | 2001-01-19 | 2006-08-08 | Samsung Electronics Co., Ltd. | Method of forming material using atomic layer deposition and method of forming capacitor of semiconductor device using the same |
JP4644943B2 (en) | 2001-01-23 | 2011-03-09 | 東京エレクトロン株式会社 | Processing equipment |
JP3626933B2 (en) | 2001-02-08 | 2005-03-09 | 東京エレクトロン株式会社 | Manufacturing method of substrate mounting table |
EP1421607A2 (en) | 2001-02-12 | 2004-05-26 | ASM America, Inc. | Improved process for deposition of semiconductor films |
US20020108670A1 (en) | 2001-02-12 | 2002-08-15 | Baker John Eric | High purity chemical container with external level sensor and removable dip tube |
US6613656B2 (en) | 2001-02-13 | 2003-09-02 | Micron Technology, Inc. | Sequential pulse deposition |
US6632478B2 (en) | 2001-02-22 | 2003-10-14 | Applied Materials, Inc. | Process for forming a low dielectric constant carbon-containing film |
JP4487135B2 (en) | 2001-03-05 | 2010-06-23 | 東京エレクトロン株式会社 | Fluid control device |
US6716571B2 (en) | 2001-03-28 | 2004-04-06 | Advanced Micro Devices, Inc. | Selective photoresist hardening to facilitate lateral trimming |
US6521295B1 (en) | 2001-04-17 | 2003-02-18 | Pilkington North America, Inc. | Chemical vapor deposition of antimony-doped metal oxide and the coated article made thereby |
US6482331B2 (en) | 2001-04-18 | 2002-11-19 | Taiwan Semiconductor Manufacturing Co., Ltd. | Method for preventing contamination in a plasma process chamber |
US6753507B2 (en) | 2001-04-27 | 2004-06-22 | Kyocera Corporation | Wafer heating apparatus |
US20030019428A1 (en) | 2001-04-28 | 2003-01-30 | Applied Materials, Inc. | Chemical vapor deposition chamber |
US6847014B1 (en) | 2001-04-30 | 2005-01-25 | Lam Research Corporation | Method and apparatus for controlling the spatial temperature distribution across the surface of a workpiece support |
US6528430B2 (en) | 2001-05-01 | 2003-03-04 | Samsung Electronics Co., Ltd. | Method of forming silicon containing thin films by atomic layer deposition utilizing Si2C16 and NH3 |
US6864041B2 (en) | 2001-05-02 | 2005-03-08 | International Business Machines Corporation | Gate linewidth tailoring and critical dimension control for sub-100 nm devices using plasma etching |
US6627268B1 (en) | 2001-05-03 | 2003-09-30 | Novellus Systems, Inc. | Sequential ion, UV, and electron induced chemical vapor deposition |
JP2002343790A (en) | 2001-05-21 | 2002-11-29 | Nec Corp | Vapor-phase deposition method of metallic compound thin film and method for manufacturing semiconductor device |
US6528767B2 (en) | 2001-05-22 | 2003-03-04 | Applied Materials, Inc. | Pre-heating and load lock pedestal material for high temperature CVD liquid crystal and flat panel display applications |
US7037574B2 (en) | 2001-05-23 | 2006-05-02 | Veeco Instruments, Inc. | Atomic layer deposition for fabricating thin films |
US6472266B1 (en) | 2001-06-18 | 2002-10-29 | Taiwan Semiconductor Manufacturing Company | Method to reduce bit line capacitance in cub drams |
US6391803B1 (en) | 2001-06-20 | 2002-05-21 | Samsung Electronics Co., Ltd. | Method of forming silicon containing thin films by atomic layer deposition utilizing trisdimethylaminosilane |
US6709989B2 (en) | 2001-06-21 | 2004-03-23 | Motorola, Inc. | Method for fabricating a semiconductor structure including a metal oxide interface with silicon |
US6420279B1 (en) | 2001-06-28 | 2002-07-16 | Sharp Laboratories Of America, Inc. | Methods of using atomic layer deposition to deposit a high dielectric constant material on a substrate |
JP3708031B2 (en) | 2001-06-29 | 2005-10-19 | 株式会社日立製作所 | Plasma processing apparatus and processing method |
TW539822B (en) | 2001-07-03 | 2003-07-01 | Asm Inc | Source chemical container assembly |
CN1277293C (en) | 2001-07-10 | 2006-09-27 | 东京毅力科创株式会社 | Dry etching method |
KR100400044B1 (en) | 2001-07-16 | 2003-09-29 | 삼성전자주식회사 | Shower head of wafer treatment apparatus having gap controller |
US6677254B2 (en) | 2001-07-23 | 2004-01-13 | Applied Materials, Inc. | Processes for making a barrier between a dielectric and a conductor and products produced therefrom |
US6638839B2 (en) | 2001-07-26 | 2003-10-28 | The University Of Toledo | Hot-filament chemical vapor deposition chamber and process with multiple gas inlets |
WO2003012843A1 (en) | 2001-07-31 | 2003-02-13 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Method and apparatus for cleaning and method and apparatus for etching |
US6531412B2 (en) | 2001-08-10 | 2003-03-11 | International Business Machines Corporation | Method for low temperature chemical vapor deposition of low-k films using selected cyclosiloxane and ozone gases for semiconductor applications |
JP2003059999A (en) | 2001-08-14 | 2003-02-28 | Tokyo Electron Ltd | Treating system |
US6820570B2 (en) | 2001-08-15 | 2004-11-23 | Nobel Biocare Services Ag | Atomic layer deposition reactor |
JP2003060076A (en) | 2001-08-21 | 2003-02-28 | Nec Corp | Semiconductor device and manufacturing method therefor |
US6521547B1 (en) | 2001-09-07 | 2003-02-18 | United Microelectronics Corp. | Method of repairing a low dielectric constant material layer |
US6756318B2 (en) | 2001-09-10 | 2004-06-29 | Tegal Corporation | Nanolayer thick film processing system and method |
US6541370B1 (en) | 2001-09-17 | 2003-04-01 | Taiwan Semiconductor Manufacturing Co., Ltd. | Composite microelectronic dielectric layer with inhibited crack susceptibility |
US6607976B2 (en) | 2001-09-25 | 2003-08-19 | Applied Materials, Inc. | Copper interconnect barrier layer structure and formation method |
US20030059535A1 (en) | 2001-09-25 | 2003-03-27 | Lee Luo | Cycling deposition of low temperature films in a cold wall single wafer process chamber |
US6960537B2 (en) | 2001-10-02 | 2005-11-01 | Asm America, Inc. | Incorporation of nitrogen into high k dielectric film |
US6720259B2 (en) | 2001-10-02 | 2004-04-13 | Genus, Inc. | Passivation method for improved uniformity and repeatability for atomic layer deposition and chemical vapor deposition |
KR100431658B1 (en) | 2001-10-05 | 2004-05-17 | 삼성전자주식회사 | Apparatus for heating a substrate and apparatus having the same |
TW563176B (en) | 2001-10-26 | 2003-11-21 | Applied Materials Inc | Gas delivery apparatus for atomic layer deposition |
US6916398B2 (en) | 2001-10-26 | 2005-07-12 | Applied Materials, Inc. | Gas delivery apparatus and method for atomic layer deposition |
AU2002343583A1 (en) | 2001-10-29 | 2003-05-12 | Genus, Inc. | Chemical vapor deposition system |
KR100760291B1 (en) | 2001-11-08 | 2007-09-19 | 에이에스엠지니텍코리아 주식회사 | Method for forming thin film |
KR20030039247A (en) | 2001-11-12 | 2003-05-17 | 주성엔지니어링(주) | Susceptor |
WO2003044843A2 (en) | 2001-11-16 | 2003-05-30 | Trikon Holdings Limited | Forming low k dielectric layers |
US6926774B2 (en) | 2001-11-21 | 2005-08-09 | Applied Materials, Inc. | Piezoelectric vaporizer |
USD461233S1 (en) | 2001-11-29 | 2002-08-06 | James Michael Whalen | Marine deck drain strainer |
KR100446619B1 (en) | 2001-12-14 | 2004-09-04 | 삼성전자주식회사 | Inductively coupled plasma system |
JP3891267B2 (en) | 2001-12-25 | 2007-03-14 | キヤノンアネルバ株式会社 | Silicon oxide film manufacturing method |
US7125812B2 (en) | 2002-01-15 | 2006-10-24 | Tokyo Electron Limited | CVD method and device for forming silicon-containing insulation film |
JP4908738B2 (en) | 2002-01-17 | 2012-04-04 | サンデュー・テクノロジーズ・エルエルシー | ALD method |
US6760981B2 (en) | 2002-01-18 | 2004-07-13 | Speedline Technologies, Inc. | Compact convection drying chamber for drying printed circuit boards and other electronic assemblies by enhanced evaporation |
US20030141820A1 (en) | 2002-01-30 | 2003-07-31 | Applied Materials, Inc. | Method and apparatus for substrate processing |
US6899507B2 (en) | 2002-02-08 | 2005-05-31 | Asm Japan K.K. | Semiconductor processing apparatus comprising chamber partitioned into reaction and transfer sections |
US6734090B2 (en) | 2002-02-20 | 2004-05-11 | International Business Machines Corporation | Method of making an edge seal for a semiconductor device |
DE10207131B4 (en) | 2002-02-20 | 2007-12-20 | Infineon Technologies Ag | Process for forming a hardmask in a layer on a flat disk |
US20030170583A1 (en) | 2002-03-01 | 2003-09-11 | Hitachi Kokusai Electric Inc. | Heat treatment apparatus and a method for fabricating substrates |
KR100449028B1 (en) | 2002-03-05 | 2004-09-16 | 삼성전자주식회사 | Method for forming thin film using ALD |
EP1485513A2 (en) | 2002-03-08 | 2004-12-15 | Sundew Technologies, LLC | Ald method and apparatus |
JP2003264186A (en) | 2002-03-11 | 2003-09-19 | Asm Japan Kk | Cleaning method of treatment chamber in cvd device |
US6800134B2 (en) | 2002-03-26 | 2004-10-05 | Micron Technology, Inc. | Chemical vapor deposition methods and atomic layer deposition methods |
US6825134B2 (en) | 2002-03-26 | 2004-11-30 | Applied Materials, Inc. | Deposition of film layers by alternately pulsing a precursor and high frequency power in a continuous gas flow |
JP4099092B2 (en) | 2002-03-26 | 2008-06-11 | 東京エレクトロン株式会社 | Substrate processing apparatus, substrate processing method, and high-speed rotary valve |
JP4128383B2 (en) | 2002-03-27 | 2008-07-30 | 東京エレクトロン株式会社 | Processing apparatus and processing method |
WO2003083167A1 (en) | 2002-03-28 | 2003-10-09 | President And Fellows Of Harvard College | Vapor deposition of silicon dioxide nanolaminates |
JP4106948B2 (en) | 2002-03-29 | 2008-06-25 | 東京エレクトロン株式会社 | Processed object jump detection device, process object jump detection method, plasma processing apparatus, and plasma processing method |
US6594550B1 (en) | 2002-03-29 | 2003-07-15 | Asm America, Inc. | Method and system for using a buffer to track robotic movement |
US7988833B2 (en) | 2002-04-12 | 2011-08-02 | Schneider Electric USA, Inc. | System and method for detecting non-cathode arcing in a plasma generation apparatus |
US6710312B2 (en) | 2002-04-12 | 2004-03-23 | B H Thermal Corporation | Heating jacket assembly with field replaceable thermostat |
US6846515B2 (en) | 2002-04-17 | 2005-01-25 | Air Products And Chemicals, Inc. | Methods for using porogens and/or porogenated precursors to provide porous organosilica glass films with low dielectric constants |
US8293001B2 (en) | 2002-04-17 | 2012-10-23 | Air Products And Chemicals, Inc. | Porogens, porogenated precursors and methods for using the same to provide porous organosilica glass films with low dielectric constants |
US7589029B2 (en) | 2002-05-02 | 2009-09-15 | Micron Technology, Inc. | Atomic layer deposition and conversion |
US7045430B2 (en) | 2002-05-02 | 2006-05-16 | Micron Technology Inc. | Atomic layer-deposited LaAlO3 films for gate dielectrics |
JP2003324072A (en) | 2002-05-07 | 2003-11-14 | Nec Electronics Corp | Semiconductor manufacturing equipment |
US7122844B2 (en) | 2002-05-13 | 2006-10-17 | Cree, Inc. | Susceptor for MOCVD reactor |
US6682973B1 (en) | 2002-05-16 | 2004-01-27 | Advanced Micro Devices, Inc. | Formation of well-controlled thin SiO, SiN, SiON layer for multilayer high-K dielectric applications |
KR100466818B1 (en) | 2002-05-17 | 2005-01-24 | 주식회사 하이닉스반도체 | Method of forming a insulating layer in a semiconductor device |
US6902656B2 (en) * | 2002-05-24 | 2005-06-07 | Dalsa Semiconductor Inc. | Fabrication of microstructures with vacuum-sealed cavity |
US7135421B2 (en) | 2002-06-05 | 2006-11-14 | Micron Technology, Inc. | Atomic layer-deposited hafnium aluminum oxide |
US20060014384A1 (en) | 2002-06-05 | 2006-01-19 | Jong-Cheol Lee | Method of forming a layer and forming a capacitor of a semiconductor device having the same layer |
US7195693B2 (en) | 2002-06-05 | 2007-03-27 | Advanced Thermal Sciences | Lateral temperature equalizing system for large area surfaces during processing |
JP2004014952A (en) | 2002-06-10 | 2004-01-15 | Tokyo Electron Ltd | Processing system and processing method |
US6858547B2 (en) | 2002-06-14 | 2005-02-22 | Applied Materials, Inc. | System and method for forming a gate dielectric |
US7067439B2 (en) | 2002-06-14 | 2006-06-27 | Applied Materials, Inc. | ALD metal oxide deposition process using direct oxidation |
US7601225B2 (en) | 2002-06-17 | 2009-10-13 | Asm International N.V. | System for controlling the sublimation of reactants |
US20040018750A1 (en) | 2002-07-02 | 2004-01-29 | Sophie Auguste J.L. | Method for deposition of nitrogen doped silicon carbide films |
US6821347B2 (en) | 2002-07-08 | 2004-11-23 | Micron Technology, Inc. | Apparatus and method for depositing materials onto microelectronic workpieces |
US6976822B2 (en) | 2002-07-16 | 2005-12-20 | Semitool, Inc. | End-effectors and transfer devices for handling microelectronic workpieces |
US7186385B2 (en) | 2002-07-17 | 2007-03-06 | Applied Materials, Inc. | Apparatus for providing gas to a processing chamber |
US7357138B2 (en) | 2002-07-18 | 2008-04-15 | Air Products And Chemicals, Inc. | Method for etching high dielectric constant materials and for cleaning deposition chambers for high dielectric constant materials |
TW200427858A (en) | 2002-07-19 | 2004-12-16 | Asml Us Inc | Atomic layer deposition of high k dielectric films |
KR100447284B1 (en) | 2002-07-19 | 2004-09-07 | 삼성전자주식회사 | Method of cleaning chemical vapor deposition chamber |
CN1643674A (en) | 2002-07-19 | 2005-07-20 | 阿维扎技术公司 | Low temperature dielectric deposition using aminosilane and ozone |
TWI294792B (en) | 2002-07-19 | 2008-03-21 | Mykrolis Corp | Liquid flow controller and precision dispense apparatus and system |
US7294582B2 (en) | 2002-07-19 | 2007-11-13 | Asm International, N.V. | Low temperature silicon compound deposition |
JP5005170B2 (en) | 2002-07-19 | 2012-08-22 | エーエスエム アメリカ インコーポレイテッド | Method for forming ultra-high quality silicon-containing compound layer |
US6921062B2 (en) | 2002-07-23 | 2005-07-26 | Advanced Technology Materials, Inc. | Vaporizer delivery ampoule |
US7223323B2 (en) | 2002-07-24 | 2007-05-29 | Applied Materials, Inc. | Multi-chemistry plating system |
KR100464855B1 (en) | 2002-07-26 | 2005-01-06 | 삼성전자주식회사 | method for forming a thin film, and method for forming a capacitor and a transistor of a semiconductor device using the same |
EP1525337A2 (en) | 2002-07-30 | 2005-04-27 | ASM America, Inc. | Sublimation system employing carrier gas |
DE10235427A1 (en) | 2002-08-02 | 2004-02-12 | Eos Gmbh Electro Optical Systems | Device for producing three-dimensional objects under the action of electromagnetic or particle radiation has a switching unit for switching the radiation between the construction regions so that each construction region is irradiated |
US7153542B2 (en) | 2002-08-06 | 2006-12-26 | Tegal Corporation | Assembly line processing method |
KR100480610B1 (en) | 2002-08-09 | 2005-03-31 | 삼성전자주식회사 | Forming method for fine patterns using silicon oxide layer |
JP4034145B2 (en) | 2002-08-09 | 2008-01-16 | 住友大阪セメント株式会社 | Susceptor device |
TW200408323A (en) | 2002-08-18 | 2004-05-16 | Asml Us Inc | Atomic layer deposition of high k metal oxides |
TW200408015A (en) | 2002-08-18 | 2004-05-16 | Asml Us Inc | Atomic layer deposition of high K metal silicates |
US6649921B1 (en) | 2002-08-19 | 2003-11-18 | Fusion Uv Systems, Inc. | Apparatus and method providing substantially two-dimensionally uniform irradiation |
US20040036129A1 (en) | 2002-08-22 | 2004-02-26 | Micron Technology, Inc. | Atomic layer deposition of CMOS gates with variable work functions |
US6967154B2 (en) | 2002-08-26 | 2005-11-22 | Micron Technology, Inc. | Enhanced atomic layer deposition |
US6794284B2 (en) | 2002-08-28 | 2004-09-21 | Micron Technology, Inc. | Systems and methods for forming refractory metal nitride layers using disilazanes |
JP2004091848A (en) | 2002-08-30 | 2004-03-25 | Tokyo Electron Ltd | Gaseous raw material supply system for thin film forming apparatus and thin film forming apparatus |
US6884066B2 (en) | 2002-09-10 | 2005-04-26 | Fsi International, Inc. | Thermal process station with heated lid |
US7011299B2 (en) | 2002-09-16 | 2006-03-14 | Matheson Tri-Gas, Inc. | Liquid vapor delivery system and method of maintaining a constant level of fluid therein |
KR100497748B1 (en) | 2002-09-17 | 2005-06-29 | 주식회사 무한 | ALD equament and ALD methode |
US7411352B2 (en) | 2002-09-19 | 2008-08-12 | Applied Process Technologies, Inc. | Dual plasma beam sources and method |
JP2004128019A (en) | 2002-09-30 | 2004-04-22 | Applied Materials Inc | Method and apparatus for plasma processing |
JP2004127957A (en) | 2002-09-30 | 2004-04-22 | Fujitsu Ltd | Process for fabricating semiconductor device, and semiconductor device |
JP2004134553A (en) | 2002-10-10 | 2004-04-30 | Sony Corp | Process for forming resist pattern and process for fabricating semiconductor device |
EP1408140A1 (en) | 2002-10-11 | 2004-04-14 | STMicroelectronics S.r.l. | A high-density plasma process for depositing a layer of Silicon Nitride |
US6905737B2 (en) | 2002-10-11 | 2005-06-14 | Applied Materials, Inc. | Method of delivering activated species for rapid cyclical deposition |
KR100460841B1 (en) | 2002-10-22 | 2004-12-09 | 한국전자통신연구원 | Method for forming nitrogen containing oxide thin film by plasma enhanced atomic layer deposition |
KR100520902B1 (en) | 2002-11-20 | 2005-10-12 | 주식회사 아이피에스 | Method for depositing thin film on wafer using Aluminum compound |
KR100496265B1 (en) | 2002-11-29 | 2005-06-17 | 한국전자통신연구원 | Method of forming a thin film in a semiconductor device |
TW200410337A (en) | 2002-12-02 | 2004-06-16 | Au Optronics Corp | Dry cleaning method for plasma reaction chamber |
US7122414B2 (en) | 2002-12-03 | 2006-10-17 | Asm International, Inc. | Method to fabricate dual metal CMOS devices |
US6858524B2 (en) | 2002-12-03 | 2005-02-22 | Asm International, Nv | Method of depositing barrier layer for metal gates |
US6895158B2 (en) | 2002-12-09 | 2005-05-17 | Eastman Kodak Company | Waveguide and method of smoothing optical surfaces |
US7092287B2 (en) | 2002-12-18 | 2006-08-15 | Asm International N.V. | Method of fabricating silicon nitride nanodots |
AU2003301074A1 (en) | 2002-12-20 | 2004-07-22 | Brooks Automation, Inc. | System and method for on-the-fly eccentricity recognition |
USD486891S1 (en) | 2003-01-21 | 2004-02-17 | Richard W. Cronce, Jr. | Vent pipe protective cover |
USD497977S1 (en) | 2003-01-22 | 2004-11-02 | Tour & Andersson Ab | Sealing ring membrane |
US7122222B2 (en) | 2003-01-23 | 2006-10-17 | Air Products And Chemicals, Inc. | Precursors for depositing silicon containing films and processes thereof |
US20040144980A1 (en) | 2003-01-27 | 2004-07-29 | Ahn Kie Y. | Atomic layer deposition of metal oxynitride layers as gate dielectrics and semiconductor device structures utilizing metal oxynitride layers |
US7129165B2 (en) | 2003-02-04 | 2006-10-31 | Asm Nutool, Inc. | Method and structure to improve reliability of copper interconnects |
US7163721B2 (en) | 2003-02-04 | 2007-01-16 | Tegal Corporation | Method to plasma deposit on organic polymer dielectric film |
WO2004070816A1 (en) | 2003-02-06 | 2004-08-19 | Tokyo Electron Limited | Plasma processing method, semiconductor substrate and plasma processing system |
US6876017B2 (en) | 2003-02-08 | 2005-04-05 | Intel Corporation | Polymer sacrificial light absorbing structure and method |
TWI338323B (en) | 2003-02-17 | 2011-03-01 | Nikon Corp | Stage device, exposure device and manufacguring method of devices |
US6930059B2 (en) | 2003-02-27 | 2005-08-16 | Sharp Laboratories Of America, Inc. | Method for depositing a nanolaminate film by atomic layer deposition |
US20040168627A1 (en) | 2003-02-27 | 2004-09-02 | Sharp Laboratories Of America, Inc. | Atomic layer deposition of oxide film |
US7091453B2 (en) | 2003-02-27 | 2006-08-15 | Dainippon Screen Mfg. Co., Ltd. | Heat treatment apparatus by means of light irradiation |
US7192892B2 (en) | 2003-03-04 | 2007-03-20 | Micron Technology, Inc. | Atomic layer deposited dielectric layers |
US7098149B2 (en) | 2003-03-04 | 2006-08-29 | Air Products And Chemicals, Inc. | Mechanical enhancement of dense and porous organosilicate materials by UV exposure |
JP2004273766A (en) | 2003-03-07 | 2004-09-30 | Watanabe Shoko:Kk | Vaporizing device and film forming device using it, and method for vaporising and film forming |
JP4369203B2 (en) | 2003-03-24 | 2009-11-18 | 信越化学工業株式会社 | Antireflection film material, substrate having antireflection film, and pattern forming method |
WO2004086496A1 (en) | 2003-03-26 | 2004-10-07 | Shin-Etsu Handotai Co., Ltd. | Heat treatment-purpose wafer support tool, and heat treatment device |
JP2004294638A (en) | 2003-03-26 | 2004-10-21 | Tokyo Ohka Kogyo Co Ltd | Negative resist material and method for forming resist pattern |
US7208389B1 (en) | 2003-03-31 | 2007-04-24 | Novellus Systems, Inc. | Method of porogen removal from porous low-k films using UV radiation |
US20040198069A1 (en) | 2003-04-04 | 2004-10-07 | Applied Materials, Inc. | Method for hafnium nitride deposition |
US7037376B2 (en) | 2003-04-11 | 2006-05-02 | Applied Materials Inc. | Backflush chamber clean |
US7077973B2 (en) | 2003-04-18 | 2006-07-18 | Applied Materials, Inc. | Methods for substrate orientation |
TW200506093A (en) | 2003-04-21 | 2005-02-16 | Aviza Tech Inc | System and method for forming multi-component films |
US7221553B2 (en) | 2003-04-22 | 2007-05-22 | Applied Materials, Inc. | Substrate support having heat transfer system |
US20040261712A1 (en) | 2003-04-25 | 2004-12-30 | Daisuke Hayashi | Plasma processing apparatus |
US7601223B2 (en) | 2003-04-29 | 2009-10-13 | Asm International N.V. | Showerhead assembly and ALD methods |
US7033113B2 (en) | 2003-05-01 | 2006-04-25 | Shell Oil Company | Mid-line connector and method for pipe-in-pipe electrical heating |
US6939817B2 (en) | 2003-05-08 | 2005-09-06 | Micron Technology, Inc. | Removal of carbon from an insulative layer using ozone |
US7265061B1 (en) | 2003-05-09 | 2007-09-04 | Novellus Systems, Inc. | Method and apparatus for UV exposure of low dielectric constant materials for porogen removal and improved mechanical properties |
EP1623454A2 (en) | 2003-05-09 | 2006-02-08 | ASM America, Inc. | Reactor surface passivation through chemical deactivation |
US8512798B2 (en) | 2003-06-05 | 2013-08-20 | Superpower, Inc. | Plasma assisted metalorganic chemical vapor deposition (MOCVD) system |
US7141500B2 (en) | 2003-06-05 | 2006-11-28 | American Air Liquide, Inc. | Methods for forming aluminum containing films utilizing amino aluminum precursors |
WO2004114368A2 (en) | 2003-06-13 | 2004-12-29 | Arizona Board Of Regents, A Body Corporate Of The State Of Arizona Acting For And On Behalf Of Arizona State University | METHOD FOR PREPARING GE1-x-ySnxEy (E=P, As, Sb) SEMICONDUCTORS AND RELATED Si-Ge-Sn-E AND Si-Ge-E ANALOGS |
US7589003B2 (en) | 2003-06-13 | 2009-09-15 | Arizona Board Of Regents, Acting For And On Behalf Of Arizona State University, A Corporate Body Organized Under Arizona Law | GeSn alloys and ordered phases with direct tunable bandgaps grown directly on silicon |
US7598513B2 (en) | 2003-06-13 | 2009-10-06 | Arizona Board Of Regents, Acting For And On Behalf Of Arizona State University, A Corporate Body Organized Under Arizona Law | SixSnyGe1-x-y and related alloy heterostructures based on Si, Ge and Sn |
US7192824B2 (en) | 2003-06-24 | 2007-03-20 | Micron Technology, Inc. | Lanthanide oxide / hafnium oxide dielectric layers |
KR20050001793A (en) | 2003-06-26 | 2005-01-07 | 삼성전자주식회사 | In-situ analysis method for atomic layer deposition process |
US7547363B2 (en) | 2003-07-08 | 2009-06-16 | Tosoh Finechem Corporation | Solid organometallic compound-filled container and filling method thereof |
US7055875B2 (en) | 2003-07-11 | 2006-06-06 | Asyst Technologies, Inc. | Ultra low contact area end effector |
JP4298421B2 (en) | 2003-07-23 | 2009-07-22 | エスペック株式会社 | Thermal plate and test equipment |
US6909839B2 (en) | 2003-07-23 | 2005-06-21 | Advanced Technology Materials, Inc. | Delivery systems for efficient vaporization of precursor source material |
US7122481B2 (en) | 2003-07-25 | 2006-10-17 | Intel Corporation | Sealing porous dielectrics with silane coupling reagents |
US7399388B2 (en) | 2003-07-25 | 2008-07-15 | Applied Materials, Inc. | Sequential gas flow oxide deposition technique |
JP2007516599A (en) | 2003-08-04 | 2007-06-21 | エーエスエム アメリカ インコーポレイテッド | Surface preparation before deposition on germanium |
JP2005072405A (en) | 2003-08-27 | 2005-03-17 | Sony Corp | Forming method of thin film and manufacturing method of semiconductor device |
CN100495655C (en) | 2003-09-03 | 2009-06-03 | 东京毅力科创株式会社 | Gas treatment device and heat readiting method |
US7335277B2 (en) | 2003-09-08 | 2008-02-26 | Hitachi High-Technologies Corporation | Vacuum processing apparatus |
US7235482B2 (en) | 2003-09-08 | 2007-06-26 | Taiwan Semiconductor Manufacturing Company, Ltd. | Method of manufacturing a contact interconnection layer containing a metal and nitrogen by atomic layer deposition for deep sub-micron semiconductor technology |
US7414281B1 (en) | 2003-09-09 | 2008-08-19 | Spansion Llc | Flash memory with high-K dielectric material between substrate and gate |
KR100551138B1 (en) | 2003-09-09 | 2006-02-10 | 어댑티브프라즈마테크놀로지 주식회사 | Adaptively plasma source for generating uniform plasma |
US7132201B2 (en) | 2003-09-12 | 2006-11-07 | Micron Technology, Inc. | Transparent amorphous carbon structure in semiconductor devices |
US6911399B2 (en) | 2003-09-19 | 2005-06-28 | Applied Materials, Inc. | Method of controlling critical dimension microloading of photoresist trimming process by selective sidewall polymer deposition |
CN101914760B (en) | 2003-09-19 | 2012-08-29 | 株式会社日立国际电气 | Producing method of semiconductor device and substrate processing apparatus |
JP4524554B2 (en) | 2003-09-25 | 2010-08-18 | 信越化学工業株式会社 | Method for producing γ, δ-unsaturated carboxylic acid and silyl ester thereof, organosilicon compound having carboxyl group and method for producing the same |
US7156380B2 (en) | 2003-09-29 | 2007-01-02 | Asm International, N.V. | Safe liquid source containers |
US7205247B2 (en) | 2003-09-30 | 2007-04-17 | Aviza Technology, Inc. | Atomic layer deposition of hafnium-based high-k dielectric |
US20050069651A1 (en) | 2003-09-30 | 2005-03-31 | Tokyo Electron Limited | Plasma processing system |
US6875677B1 (en) | 2003-09-30 | 2005-04-05 | Sharp Laboratories Of America, Inc. | Method to control the interfacial layer for deposition of high dielectric constant films |
US6974781B2 (en) | 2003-10-20 | 2005-12-13 | Asm International N.V. | Reactor precoating for reduced stress and uniform CVD |
US7020981B2 (en) | 2003-10-29 | 2006-04-04 | Asm America, Inc | Reaction system for growing a thin film |
US7329947B2 (en) | 2003-11-07 | 2008-02-12 | Sumitomo Mitsubishi Silicon Corporation | Heat treatment jig for semiconductor substrate |
US8313277B2 (en) | 2003-11-10 | 2012-11-20 | Brooks Automation, Inc. | Semiconductor manufacturing process modules |
US7071118B2 (en) | 2003-11-12 | 2006-07-04 | Veeco Instruments, Inc. | Method and apparatus for fabricating a conformal thin film on a substrate |
US20050153571A1 (en) | 2003-11-17 | 2005-07-14 | Yoshihide Senzaki | Nitridation of high-k dielectric films |
KR100550641B1 (en) | 2003-11-22 | 2006-02-09 | 주식회사 하이닉스반도체 | Dielectric layer alloyed hafnium oxide and aluminium oxide and method for fabricating the same |
JP4725085B2 (en) | 2003-12-04 | 2011-07-13 | 株式会社豊田中央研究所 | Amorphous carbon, amorphous carbon coating member and amorphous carbon film forming method |
US7431966B2 (en) | 2003-12-09 | 2008-10-07 | Micron Technology, Inc. | Atomic layer deposition method of depositing an oxide on a substrate |
US7143897B1 (en) | 2003-12-09 | 2006-12-05 | H20 International, Inc. | Water filter |
KR100549273B1 (en) | 2004-01-15 | 2006-02-03 | 주식회사 테라세미콘 | Wafer-Holder for Semiconductor Manufacturing Process |
JP4513329B2 (en) | 2004-01-16 | 2010-07-28 | 東京エレクトロン株式会社 | Processing equipment |
US7071051B1 (en) | 2004-01-20 | 2006-07-04 | Advanced Micro Devices, Inc. | Method for forming a thin, high quality buffer layer in a field effect transistor and related structure |
US7354847B2 (en) | 2004-01-26 | 2008-04-08 | Taiwan Semiconductor Manufacturing Company | Method of trimming technology |
CN100452306C (en) | 2004-01-30 | 2009-01-14 | 东京毅力科创株式会社 | Substrate holder having a fluid gap and method of fabricating the substrate holder |
DE102004005385A1 (en) | 2004-02-03 | 2005-10-20 | Infineon Technologies Ag | Use of dissolved hafnium alkoxides or zirconium alkoxides as precursors for hafnium oxide and hafnium oxynitride layers or zirconium oxide and zirconium oxynitride layers |
US20050181535A1 (en) | 2004-02-17 | 2005-08-18 | Yun Sun J. | Method of fabricating passivation layer for organic devices |
US7088003B2 (en) | 2004-02-19 | 2006-08-08 | International Business Machines Corporation | Structures and methods for integration of ultralow-k dielectrics with improved reliability |
US20050187647A1 (en) | 2004-02-19 | 2005-08-25 | Kuo-Hua Wang | Intelligent full automation controlled flow for a semiconductor furnace tool |
US20060062910A1 (en) | 2004-03-01 | 2006-03-23 | Meiere Scott H | Low zirconium, hafnium-containing compositions, processes for the preparation thereof and methods of use thereof |
US20050214458A1 (en) | 2004-03-01 | 2005-09-29 | Meiere Scott H | Low zirconium hafnium halide compositions |
WO2005087974A2 (en) | 2004-03-05 | 2005-09-22 | Applied Materials, Inc. | Cvd processes for the deposition of amorphous carbon films |
US7079740B2 (en) | 2004-03-12 | 2006-07-18 | Applied Materials, Inc. | Use of amorphous carbon film as a hardmask in the fabrication of optical waveguides |
KR100538096B1 (en) | 2004-03-16 | 2005-12-21 | 삼성전자주식회사 | Method for forming a capacitor using atomic layer deposition method |
US7524735B1 (en) | 2004-03-25 | 2009-04-28 | Novellus Systems, Inc | Flowable film dielectric gap fill process |
US7582555B1 (en) | 2005-12-29 | 2009-09-01 | Novellus Systems, Inc. | CVD flowable gap fill |
US20050214457A1 (en) | 2004-03-29 | 2005-09-29 | Applied Materials, Inc. | Deposition of low dielectric constant films by N2O addition |
US20050221618A1 (en) | 2004-03-31 | 2005-10-06 | Amrhein Frederick J | System for controlling a plenum output flow geometry |
CN1292092C (en) | 2004-04-01 | 2006-12-27 | 南昌大学 | Bilayer inlet gas spray nozzle in use for metal-organic chemical vapor deposition device |
US7585371B2 (en) | 2004-04-08 | 2009-09-08 | Micron Technology, Inc. | Substrate susceptors for receiving semiconductor substrates to be deposited upon |
US20050227502A1 (en) | 2004-04-12 | 2005-10-13 | Applied Materials, Inc. | Method for forming an ultra low dielectric film by forming an organosilicon matrix and large porogens as a template for increased porosity |
US7273526B2 (en) | 2004-04-15 | 2007-09-25 | Asm Japan K.K. | Thin-film deposition apparatus |
US8083853B2 (en) | 2004-05-12 | 2011-12-27 | Applied Materials, Inc. | Plasma uniformity control by gas diffuser hole design |
US7785672B2 (en) | 2004-04-20 | 2010-08-31 | Applied Materials, Inc. | Method of controlling the film properties of PECVD-deposited thin films |
US20060019502A1 (en) | 2004-07-23 | 2006-01-26 | Park Beom S | Method of controlling the film properties of a CVD-deposited silicon nitride film |
USD553104S1 (en) | 2004-04-21 | 2007-10-16 | Tokyo Electron Limited | Absorption board for an electric chuck used in semiconductor manufacture |
KR100840705B1 (en) | 2004-04-21 | 2008-06-24 | 가부시키가이샤 히다치 고쿠사이 덴키 | Heat treating device |
US7708859B2 (en) | 2004-04-30 | 2010-05-04 | Lam Research Corporation | Gas distribution system having fast gas switching capabilities |
US7049247B2 (en) | 2004-05-03 | 2006-05-23 | International Business Machines Corporation | Method for fabricating an ultralow dielectric constant material as an intralevel or interlevel dielectric in a semiconductor device and electronic device made |
US20050252449A1 (en) | 2004-05-12 | 2005-11-17 | Nguyen Son T | Control of gas flow and delivery to suppress the formation of particles in an MOCVD/ALD system |
US20060019033A1 (en) | 2004-05-21 | 2006-01-26 | Applied Materials, Inc. | Plasma treatment of hafnium-containing materials |
US8119210B2 (en) | 2004-05-21 | 2012-02-21 | Applied Materials, Inc. | Formation of a silicon oxynitride layer on a high-k dielectric material |
JP2005340251A (en) | 2004-05-24 | 2005-12-08 | Shin Etsu Chem Co Ltd | Plasma processing apparatus and shower plate therefor |
US7271093B2 (en) | 2004-05-24 | 2007-09-18 | Asm Japan K.K. | Low-carbon-doped silicon oxide film and damascene structure using same |
US20050266173A1 (en) | 2004-05-26 | 2005-12-01 | Tokyo Electron Limited | Method and apparatus of distributed plasma processing system for conformal ion stimulated nanoscale deposition process |
US7580388B2 (en) | 2004-06-01 | 2009-08-25 | Lg Electronics Inc. | Method and apparatus for providing enhanced messages on common control channel in wireless communication system |
US7651583B2 (en) | 2004-06-04 | 2010-01-26 | Tokyo Electron Limited | Processing system and method for treating a substrate |
US7396743B2 (en) | 2004-06-10 | 2008-07-08 | Singh Kaushal K | Low temperature epitaxial growth of silicon-containing films using UV radiation |
US7132360B2 (en) | 2004-06-10 | 2006-11-07 | Freescale Semiconductor, Inc. | Method for treating a semiconductor surface to form a metal-containing layer |
KR100589062B1 (en) | 2004-06-10 | 2006-06-12 | 삼성전자주식회사 | Method of forming a thin film using an atomic layer deposition process and method of forming a capacitor of a semiconductor device using the same |
JP4534619B2 (en) | 2004-06-21 | 2010-09-01 | 株式会社Sumco | Heat treatment jig for semiconductor silicon substrate |
US7687997B2 (en) | 2004-07-09 | 2010-03-30 | Koninklijke Philips Electronics N.V. | UVC/VUV dielectric barrier discharge lamp with reflector |
US7094442B2 (en) | 2004-07-13 | 2006-08-22 | Applied Materials, Inc. | Methods for the reduction and elimination of particulate contamination with CVD of amorphous carbon |
US7422653B2 (en) | 2004-07-13 | 2008-09-09 | Applied Materials, Inc. | Single-sided inflatable vertical slit valve |
KR100578819B1 (en) | 2004-07-15 | 2006-05-11 | 삼성전자주식회사 | method of manufacturing a thin layer using atomic layer deposition, and method of manufacturing a gate structure and a capacitor using the same |
US20060016783A1 (en) | 2004-07-22 | 2006-01-26 | Dingjun Wu | Process for titanium nitride removal |
US20060021703A1 (en) | 2004-07-29 | 2006-02-02 | Applied Materials, Inc. | Dual gas faceplate for a showerhead in a semiconductor wafer processing system |
PL1771599T3 (en) | 2004-07-30 | 2008-04-30 | Lpe Spa | Epitaxial reactor with susceptor controlled positioning |
US7470633B2 (en) | 2004-08-09 | 2008-12-30 | Asm Japan K.K. | Method of forming a carbon polymer film using plasma CVD |
KR101071136B1 (en) | 2004-08-27 | 2011-10-10 | 엘지디스플레이 주식회사 | apparatus for processing a thin film on substrate for flat panel display device |
ITMI20041677A1 (en) | 2004-08-30 | 2004-11-30 | E T C Epitaxial Technology Ct | CLEANING PROCESS AND OPERATIONAL PROCESS FOR A CVD REACTOR. |
DE102004042431B4 (en) | 2004-08-31 | 2008-07-03 | Schott Ag | Method and device for plasma coating of workpieces with spectral evaluation of the process parameters and use of the device |
US8158488B2 (en) | 2004-08-31 | 2012-04-17 | Micron Technology, Inc. | Method of increasing deposition rate of silicon dioxide on a catalyst |
US7910288B2 (en) | 2004-09-01 | 2011-03-22 | Micron Technology, Inc. | Mask material conversion |
US7253084B2 (en) | 2004-09-03 | 2007-08-07 | Asm America, Inc. | Deposition from liquid sources |
US20060137609A1 (en) | 2004-09-13 | 2006-06-29 | Puchacz Jerzy P | Multi-single wafer processing apparatus |
US20060060930A1 (en) | 2004-09-17 | 2006-03-23 | Metz Matthew V | Atomic layer deposition of high dielectric constant gate dielectrics |
DE102005045081B4 (en) | 2004-09-29 | 2011-07-07 | Covalent Materials Corp. | susceptor |
US7241475B2 (en) | 2004-09-30 | 2007-07-10 | The Aerospace Corporation | Method for producing carbon surface films by plasma exposure of a carbide compound |
US6874247B1 (en) | 2004-10-12 | 2005-04-05 | Tsang-Hung Hsu | Toothbrush dryer |
US20060257563A1 (en) | 2004-10-13 | 2006-11-16 | Seok-Joo Doh | Method of fabricating silicon-doped metal oxide layer using atomic layer deposition technique |
CN101061578A (en) | 2004-10-19 | 2007-10-24 | 佳能安内华股份有限公司 | Substrate supporting/transferring tray |
US7790633B1 (en) | 2004-10-26 | 2010-09-07 | Novellus Systems, Inc. | Sequential deposition/anneal film densification method |
US7163900B2 (en) | 2004-11-01 | 2007-01-16 | Infineon Technologies Ag | Using polydentate ligands for sealing pores in low-k dielectrics |
JP2006135161A (en) | 2004-11-08 | 2006-05-25 | Canon Inc | Method and apparatus for forming insulating film |
JP4435666B2 (en) | 2004-11-09 | 2010-03-24 | 東京エレクトロン株式会社 | Plasma processing method, film forming method |
US7678682B2 (en) | 2004-11-12 | 2010-03-16 | Axcelis Technologies, Inc. | Ultraviolet assisted pore sealing of porous low k dielectric films |
TWI536429B (en) | 2004-11-18 | 2016-06-01 | 尼康股份有限公司 | A position measuring method, a position control method, a measuring method, a loading method, an exposure method and an exposure apparatus, and a device manufacturing method |
KR100773755B1 (en) | 2004-11-18 | 2007-11-09 | 주식회사 아이피에스 | A method for depositing thin film using ALD |
CN101728206B (en) | 2004-11-24 | 2011-11-23 | 欧瑞康太阳能股份公司(特吕巴赫) | Vacuum processing chamber for very large area substrates |
US20060113806A1 (en) | 2004-11-29 | 2006-06-01 | Asm Japan K.K. | Wafer transfer mechanism |
US20060113675A1 (en) | 2004-12-01 | 2006-06-01 | Chung-Liang Chang | Barrier material and process for Cu interconnect |
US7235501B2 (en) | 2004-12-13 | 2007-06-26 | Micron Technology, Inc. | Lanthanum hafnium oxide dielectrics |
US7290813B2 (en) | 2004-12-16 | 2007-11-06 | Asyst Technologies, Inc. | Active edge grip rest pad |
US7396732B2 (en) | 2004-12-17 | 2008-07-08 | Interuniversitair Microelektronica Centrum Vzw (Imec) | Formation of deep trench airgaps and related applications |
US7396412B2 (en) | 2004-12-22 | 2008-07-08 | Sokudo Co., Ltd. | Coat/develop module with shared dispense |
JP4560681B2 (en) | 2004-12-24 | 2010-10-13 | ミネベア株式会社 | Multi-lamp type discharge lamp lighting device |
JP2006186271A (en) | 2004-12-28 | 2006-07-13 | Sharp Corp | Vapor phase deposition device and manufacturing method of film-formed substrate |
KR20070107017A (en) | 2004-12-30 | 2007-11-06 | 어플라이드 머티어리얼스, 인코포레이티드 | Line edge roughness reduction compatible with trimming |
US7846499B2 (en) | 2004-12-30 | 2010-12-07 | Asm International N.V. | Method of pulsing vapor precursors in an ALD reactor |
US7560395B2 (en) | 2005-01-05 | 2009-07-14 | Micron Technology, Inc. | Atomic layer deposited hafnium tantalum oxide dielectrics |
US7598516B2 (en) | 2005-01-07 | 2009-10-06 | International Business Machines Corporation | Self-aligned process for nanotube/nanowire FETs |
US8211230B2 (en) | 2005-01-18 | 2012-07-03 | Asm America, Inc. | Reaction system for growing a thin film |
KR100640550B1 (en) | 2005-01-26 | 2006-10-31 | 주식회사 아이피에스 | a method for depositing thin film using ALD |
US7298009B2 (en) | 2005-02-01 | 2007-11-20 | Infineon Technologies Ag | Semiconductor method and device with mixed orientation substrate |
US7135402B2 (en) | 2005-02-01 | 2006-11-14 | Taiwan Semiconductor Manufacturing Company, Ltd. | Sealing pores of low-k dielectrics using CxHy |
TW200634982A (en) | 2005-02-22 | 2006-10-01 | Asm Inc | Plasma pre-treating surfaces for atomic layer deposition |
JP4764028B2 (en) | 2005-02-28 | 2011-08-31 | 株式会社日立ハイテクノロジーズ | Plasma processing method |
US6972478B1 (en) | 2005-03-07 | 2005-12-06 | Advanced Micro Devices, Inc. | Integrated circuit and method for its manufacture |
US7629267B2 (en) | 2005-03-07 | 2009-12-08 | Asm International N.V. | High stress nitride film and method for formation thereof |
US7314835B2 (en) | 2005-03-21 | 2008-01-01 | Tokyo Electron Limited | Plasma enhanced atomic layer deposition system and method |
US7422636B2 (en) | 2005-03-25 | 2008-09-09 | Tokyo Electron Limited | Plasma enhanced atomic layer deposition system having reduced contamination |
US20060226117A1 (en) | 2005-03-29 | 2006-10-12 | Bertram Ronald T | Phase change based heating element system and method |
WO2006110750A2 (en) | 2005-04-07 | 2006-10-19 | Aviza Technology, Inc. | Multilayer, multicomponent high-k films and methods for depositing the same |
US7479198B2 (en) | 2005-04-07 | 2009-01-20 | Timothy D'Annunzio | Methods for forming nanofiber adhesive structures |
KR100640640B1 (en) | 2005-04-19 | 2006-10-31 | 삼성전자주식회사 | Method of forming fine pattern of semiconductor device using fine pitch hardmask |
JP4694878B2 (en) | 2005-04-20 | 2011-06-08 | Okiセミコンダクタ株式会社 | Semiconductor manufacturing apparatus and semiconductor device manufacturing method |
US7160819B2 (en) | 2005-04-25 | 2007-01-09 | Sharp Laboratories Of America, Inc. | Method to perform selective atomic layer deposition of zinc oxide |
US8137465B1 (en) | 2005-04-26 | 2012-03-20 | Novellus Systems, Inc. | Single-chamber sequential curing of semiconductor wafers |
US20060251827A1 (en) | 2005-05-09 | 2006-11-09 | Applied Materials, Inc. | Tandem uv chamber for curing dielectric materials |
US7875556B2 (en) | 2005-05-16 | 2011-01-25 | Air Products And Chemicals, Inc. | Precursors for CVD silicon carbo-nitride and silicon nitride films |
US7312162B2 (en) | 2005-05-17 | 2007-12-25 | Applied Materials, Inc. | Low temperature plasma deposition process for carbon layer deposition |
US7422775B2 (en) | 2005-05-17 | 2008-09-09 | Applied Materials, Inc. | Process for low temperature plasma deposition of an optical absorption layer and high speed optical annealing |
US7109098B1 (en) | 2005-05-17 | 2006-09-19 | Applied Materials, Inc. | Semiconductor junction formation process including low temperature plasma deposition of an optical absorption layer and high speed optical annealing |
US20060260545A1 (en) | 2005-05-17 | 2006-11-23 | Kartik Ramaswamy | Low temperature absorption layer deposition and high speed optical annealing system |
US20070155138A1 (en) | 2005-05-24 | 2007-07-05 | Pierre Tomasini | Apparatus and method for depositing silicon germanium films |
US7732342B2 (en) | 2005-05-26 | 2010-06-08 | Applied Materials, Inc. | Method to increase the compressive stress of PECVD silicon nitride films |
TW200709296A (en) | 2005-05-31 | 2007-03-01 | Tokyo Electron Ltd | Plasma treatment apparatus and plasma treatment method |
KR100960273B1 (en) | 2005-06-13 | 2010-06-04 | 가부시키가이샤 히다치 고쿠사이 덴키 | Process for Production of Semiconductor Device and Apparatus for Treatment of Substrate |
US20060278524A1 (en) | 2005-06-14 | 2006-12-14 | Stowell Michael W | System and method for modulating power signals to control sputtering |
JP4853857B2 (en) | 2005-06-15 | 2012-01-11 | 東京エレクトロン株式会社 | Substrate processing method, computer-readable recording medium, and substrate processing apparatus |
JP4753173B2 (en) | 2005-06-17 | 2011-08-24 | 株式会社フジキン | Fluid control device |
JP2007005582A (en) | 2005-06-24 | 2007-01-11 | Asm Japan Kk | Substrate transfer apparatus and semiconductor substrate manufacturing apparatus mounted with the same |
US7575990B2 (en) | 2005-07-01 | 2009-08-18 | Macronix International Co., Ltd. | Method of forming self-aligned contacts and local interconnects |
EP1907599A2 (en) | 2005-07-08 | 2008-04-09 | Aviza Technology, Inc. | Method for depositing silicon-containing films |
US20070010072A1 (en) | 2005-07-09 | 2007-01-11 | Aviza Technology, Inc. | Uniform batch film deposition process and films so produced |
US8771806B2 (en) | 2005-07-09 | 2014-07-08 | Bang-Kwon Kang | Surface coating method for hydrophobic and superhydrophobic treatment in atmospheric pressure plasma |
US7762755B2 (en) | 2005-07-11 | 2010-07-27 | Brooks Automation, Inc. | Equipment storage for substrate processing apparatus |
US7925378B2 (en) | 2005-07-11 | 2011-04-12 | Brooks Automation, Inc. | Process apparatus with on-the-fly workpiece centering |
US7314838B2 (en) | 2005-07-21 | 2008-01-01 | Taiwan Semiconductor Manufacturing Co., Ltd. | Method for forming a high density dielectric film by chemical vapor deposition |
JP2007035747A (en) | 2005-07-25 | 2007-02-08 | Sumitomo Electric Ind Ltd | Wafer holder, and wafer prober equipped with the same |
JP2007035899A (en) | 2005-07-27 | 2007-02-08 | Sumitomo Electric Ind Ltd | Wafer holding body for wafer prober, and wafer prober mounting the same |
TWI313486B (en) | 2005-07-28 | 2009-08-11 | Nuflare Technology Inc | Position measurement apparatus and method and writing apparatus and method |
US20070028842A1 (en) | 2005-08-02 | 2007-02-08 | Makoto Inagawa | Vacuum chamber bottom |
US20090045829A1 (en) | 2005-08-04 | 2009-02-19 | Sumitomo Electric Industries, Ltd. | Wafer holder for wafer prober and wafer prober equipped with same |
US20070037412A1 (en) | 2005-08-05 | 2007-02-15 | Tokyo Electron Limited | In-situ atomic layer deposition |
US7312148B2 (en) | 2005-08-08 | 2007-12-25 | Applied Materials, Inc. | Copper barrier reflow process employing high speed optical annealing |
US7335611B2 (en) | 2005-08-08 | 2008-02-26 | Applied Materials, Inc. | Copper conductor annealing process employing high speed optical annealing with a low temperature-deposited optical absorber layer |
US7323401B2 (en) | 2005-08-08 | 2008-01-29 | Applied Materials, Inc. | Semiconductor substrate process using a low temperature deposited carbon-containing hard mask |
US7429532B2 (en) | 2005-08-08 | 2008-09-30 | Applied Materials, Inc. | Semiconductor substrate process using an optically writable carbon-containing mask |
US20090130331A1 (en) * | 2005-08-16 | 2009-05-21 | Hitachi Kokusai Electric Inc. | Method of Forming Thin Film and Method of Manufacturing Semiconductor Device |
US7718225B2 (en) | 2005-08-17 | 2010-05-18 | Applied Materials, Inc. | Method to control semiconductor film deposition characteristics |
USD557226S1 (en) | 2005-08-25 | 2007-12-11 | Hitachi High-Technologies Corporation | Electrode cover for a plasma processing apparatus |
US7402534B2 (en) | 2005-08-26 | 2008-07-22 | Applied Materials, Inc. | Pretreatment processes within a batch ALD reactor |
US7393736B2 (en) | 2005-08-29 | 2008-07-01 | Micron Technology, Inc. | Atomic layer deposition of Zrx Hfy Sn1-x-y O2 films as high k gate dielectrics |
JP4815600B2 (en) | 2005-09-06 | 2011-11-16 | 株式会社テラセミコン | Polycrystalline silicon thin film manufacturing method and manufacturing apparatus thereof |
JP2007088113A (en) | 2005-09-21 | 2007-04-05 | Sony Corp | Manufacturing method of semiconductor device |
US20070065578A1 (en) | 2005-09-21 | 2007-03-22 | Applied Materials, Inc. | Treatment processes for a batch ALD reactor |
US7691204B2 (en) | 2005-09-30 | 2010-04-06 | Applied Materials, Inc. | Film formation apparatus and methods including temperature and emissivity/pattern compensation |
US7785658B2 (en) | 2005-10-07 | 2010-08-31 | Asm Japan K.K. | Method for forming metal wiring structure |
US7691205B2 (en) | 2005-10-18 | 2010-04-06 | Asm Japan K.K. | Substrate-supporting device |
US7994721B2 (en) | 2005-10-27 | 2011-08-09 | Luxim Corporation | Plasma lamp and methods using a waveguide body and protruding bulb |
US7638951B2 (en) | 2005-10-27 | 2009-12-29 | Luxim Corporation | Plasma lamp with stable feedback amplification and method therefor |
US7906910B2 (en) | 2005-10-27 | 2011-03-15 | Luxim Corporation | Plasma lamp with conductive material positioned relative to RF feed |
DE102005051994B4 (en) | 2005-10-31 | 2011-12-01 | Globalfoundries Inc. | Deformation technique in silicon-based transistors using embedded semiconductor layers with atoms of large covalent radius |
JP4940635B2 (en) | 2005-11-14 | 2012-05-30 | 東京エレクトロン株式会社 | Heating device, heat treatment device and storage medium |
GB2432363B (en) | 2005-11-16 | 2010-06-23 | Epichem Ltd | Hafnocene and zirconocene precursors, and use thereof in atomic layer deposition |
KR100660890B1 (en) | 2005-11-16 | 2006-12-26 | 삼성전자주식회사 | Method for forming silicon dioxide film using atomic layer deposition |
US7897217B2 (en) * | 2005-11-18 | 2011-03-01 | Tokyo Electron Limited | Method and system for performing plasma enhanced atomic layer deposition |
US20070116873A1 (en) | 2005-11-18 | 2007-05-24 | Tokyo Electron Limited | Apparatus for thermal and plasma enhanced vapor deposition and method of operating |
US7629277B2 (en) | 2005-11-23 | 2009-12-08 | Honeywell International Inc. | Frag shield |
US20070125762A1 (en) | 2005-12-01 | 2007-06-07 | Applied Materials, Inc. | Multi-zone resistive heater |
JP4666496B2 (en) | 2005-12-07 | 2011-04-06 | 大日本スクリーン製造株式会社 | Substrate heat treatment equipment |
US7592251B2 (en) | 2005-12-08 | 2009-09-22 | Micron Technology, Inc. | Hafnium tantalum titanium oxide films |
US7381644B1 (en) | 2005-12-23 | 2008-06-03 | Novellus Systems, Inc. | Pulsed PECVD method for modulating hydrogen content in hard mask |
JP4629574B2 (en) | 2005-12-27 | 2011-02-09 | 日本発條株式会社 | Substrate support device and manufacturing method thereof |
KR101296911B1 (en) | 2005-12-28 | 2013-08-14 | 엘지디스플레이 주식회사 | Apparatus For Fabricating Flat Panel Display, Detector Static Electricity Quantity Thereof And Method For Detecting |
TWI284390B (en) | 2006-01-10 | 2007-07-21 | Ind Tech Res Inst | Manufacturing method of charge store device |
US8088248B2 (en) | 2006-01-11 | 2012-01-03 | Lam Research Corporation | Gas switching section including valves having different flow coefficients for gas distribution system |
JP2007191792A (en) | 2006-01-19 | 2007-08-02 | Atto Co Ltd | Gas separation type showerhead |
US20080254220A1 (en) | 2006-01-20 | 2008-10-16 | Tokyo Electron Limited | Plasma processing apparatus |
US20070173071A1 (en) | 2006-01-20 | 2007-07-26 | International Business Machines Corporation | SiCOH dielectric |
US8673413B2 (en) | 2006-01-27 | 2014-03-18 | Tosoh Finechem Corporation | Method for packing solid organometallic compound and packed container |
JP4854317B2 (en) | 2006-01-31 | 2012-01-18 | 東京エレクトロン株式会社 | Substrate processing method |
US8057603B2 (en) | 2006-02-13 | 2011-11-15 | Tokyo Electron Limited | Method of cleaning substrate processing chamber, storage medium, and substrate processing chamber |
US20070207275A1 (en) | 2006-02-21 | 2007-09-06 | Applied Materials, Inc. | Enhancement of remote plasma source clean for dielectric films |
US7740705B2 (en) | 2006-03-08 | 2010-06-22 | Tokyo Electron Limited | Exhaust apparatus configured to reduce particle contamination in a deposition system |
US7794546B2 (en) | 2006-03-08 | 2010-09-14 | Tokyo Electron Limited | Sealing device and method for a processing system |
US7460003B2 (en) | 2006-03-09 | 2008-12-02 | International Business Machines Corporation | Electronic fuse with conformal fuse element formed over a freestanding dielectric spacer |
US7494882B2 (en) | 2006-03-10 | 2009-02-24 | Texas Instruments Incorporated | Manufacturing a semiconductive device using a controlled atomic layer removal process |
KR20070093493A (en) | 2006-03-14 | 2007-09-19 | 엘지이노텍 주식회사 | Susceptor and semiconductor manufacturing device |
US8268078B2 (en) | 2006-03-16 | 2012-09-18 | Tokyo Electron Limited | Method and apparatus for reducing particle contamination in a deposition system |
US20070218200A1 (en) | 2006-03-16 | 2007-09-20 | Kenji Suzuki | Method and apparatus for reducing particle formation in a vapor distribution system |
US7566891B2 (en) | 2006-03-17 | 2009-07-28 | Applied Materials, Inc. | Apparatus and method for treating a substrate with UV radiation using primary and secondary reflectors |
US7410915B2 (en) | 2006-03-23 | 2008-08-12 | Asm Japan K.K. | Method of forming carbon polymer film using plasma CVD |
US20070234955A1 (en) | 2006-03-29 | 2007-10-11 | Tokyo Electron Limited | Method and apparatus for reducing carbon monoxide poisoning at the peripheral edge of a substrate in a thin film deposition system |
JP2007266464A (en) | 2006-03-29 | 2007-10-11 | Hitachi Ltd | Manufacturing method of semiconductor integrated circuit device |
US8951478B2 (en) | 2006-03-30 | 2015-02-10 | Applied Materials, Inc. | Ampoule with a thermally conductive coating |
US7780865B2 (en) | 2006-03-31 | 2010-08-24 | Applied Materials, Inc. | Method to improve the step coverage and pattern loading for dielectric films |
US20070237697A1 (en) | 2006-03-31 | 2007-10-11 | Tokyo Electron Limited | Method of forming mixed rare earth oxide and aluminate films by atomic layer deposition |
US20070287301A1 (en) | 2006-03-31 | 2007-12-13 | Huiwen Xu | Method to minimize wet etch undercuts and provide pore sealing of extreme low k (k<2.5) dielectrics |
US7396491B2 (en) | 2006-04-06 | 2008-07-08 | Osram Sylvania Inc. | UV-emitting phosphor and lamp containing same |
US7902074B2 (en) | 2006-04-07 | 2011-03-08 | Micron Technology, Inc. | Simplified pitch doubling process flow |
US20070248767A1 (en) | 2006-04-19 | 2007-10-25 | Asm Japan K.K. | Method of self-cleaning of carbon-based film |
US7410852B2 (en) | 2006-04-21 | 2008-08-12 | International Business Machines Corporation | Opto-thermal annealing methods for forming metal gate and fully silicided gate field effect transistors |
FR2900276B1 (en) | 2006-04-25 | 2008-09-12 | St Microelectronics Sa | PEALD DEPOSITION OF A SILICON MATERIAL |
US7537804B2 (en) | 2006-04-28 | 2009-05-26 | Micron Technology, Inc. | ALD methods in which two or more different precursors are utilized with one or more reactants to form materials over substrates |
US8231799B2 (en) | 2006-04-28 | 2012-07-31 | Applied Materials, Inc. | Plasma reactor apparatus with multiple gas injection zones having time-changing separate configurable gas compositions for each zone |
US7875312B2 (en) | 2006-05-23 | 2011-01-25 | Air Products And Chemicals, Inc. | Process for producing silicon oxide films for organoaminosilane precursors |
US7825038B2 (en) | 2006-05-30 | 2010-11-02 | Applied Materials, Inc. | Chemical vapor deposition of high quality flow-like silicon dioxide using a silicon containing precursor and atomic oxygen |
US7790634B2 (en) | 2006-05-30 | 2010-09-07 | Applied Materials, Inc | Method for depositing and curing low-k films for gapfill and conformal film applications |
CN101460657A (en) | 2006-06-02 | 2009-06-17 | 乔治洛德方法研究和开发液化空气有限公司 | Method of forming high-k dielectric films based on novel titanium, zirconium, and hafnium precursors and their use for semiconductor manufacturing |
US20070277735A1 (en) | 2006-06-02 | 2007-12-06 | Nima Mokhlesi | Systems for Atomic Layer Deposition of Oxides Using Krypton as an Ion Generating Feeding Gas |
US8278176B2 (en) | 2006-06-07 | 2012-10-02 | Asm America, Inc. | Selective epitaxial formation of semiconductor films |
US7691757B2 (en) | 2006-06-22 | 2010-04-06 | Asm International N.V. | Deposition of complex nitride films |
US7554103B2 (en) | 2006-06-26 | 2009-06-30 | Applied Materials, Inc. | Increased tool utilization/reduction in MWBC for UV curing chamber |
US20080153311A1 (en) | 2006-06-28 | 2008-06-26 | Deenesh Padhi | Method for depositing an amorphous carbon film with improved density and step coverage |
US7867578B2 (en) | 2006-06-28 | 2011-01-11 | Applied Materials, Inc. | Method for depositing an amorphous carbon film with improved density and step coverage |
US7416989B1 (en) | 2006-06-30 | 2008-08-26 | Novellus Systems, Inc. | Adsorption based material removal process |
WO2008004278A1 (en) | 2006-07-04 | 2008-01-10 | Toshiba Mitsubishi-Electric Industrial Systems Corporation | Apparatus for concentrating/diluting specific gas and method of concentrating/diluting specific gas |
JP4193883B2 (en) | 2006-07-05 | 2008-12-10 | 住友電気工業株式会社 | Metalorganic vapor phase epitaxy system |
KR100799735B1 (en) | 2006-07-10 | 2008-02-01 | 삼성전자주식회사 | Method of forming metal oxide and apparatus for performing the same |
KR100791334B1 (en) | 2006-07-26 | 2008-01-07 | 삼성전자주식회사 | Method of forming a metal oxide by atomic layer deposition |
FR2904328B1 (en) | 2006-07-27 | 2008-10-24 | St Microelectronics Sa | DEPOSITION BY ADSORPTION UNDER AN ELECTRIC FIELD |
US7749879B2 (en) | 2006-08-03 | 2010-07-06 | Micron Technology, Inc. | ALD of silicon films on germanium |
US7514375B1 (en) | 2006-08-08 | 2009-04-07 | Novellus Systems, Inc. | Pulsed bias having high pulse frequency for filling gaps with dielectric material |
GB0615722D0 (en) | 2006-08-08 | 2006-09-20 | Boc Group Plc | Apparatus for conveying a waste stream |
US8080282B2 (en) | 2006-08-08 | 2011-12-20 | Asm Japan K.K. | Method for forming silicon carbide film containing oxygen |
TW200814131A (en) | 2006-08-11 | 2008-03-16 | Schott Ag | External electrode fluorescent lamp with optimized operating efficiency |
WO2008020267A2 (en) | 2006-08-16 | 2008-02-21 | Freescale Semiconductor, Inc. | Etch method in the manufacture of an integrated circuit |
US7611980B2 (en) | 2006-08-30 | 2009-11-03 | Micron Technology, Inc. | Single spacer process for multiplying pitch by a factor greater than two and related intermediate IC structures |
US7690881B2 (en) | 2006-08-30 | 2010-04-06 | Asm Japan K.K. | Substrate-processing apparatus with buffer mechanism and substrate-transferring apparatus |
KR100753020B1 (en) | 2006-08-30 | 2007-08-30 | 한국화학연구원 | Preparation of nanolaminates by atomic layer deposition for non-volatile floating gate memory devices |
US7605030B2 (en) | 2006-08-31 | 2009-10-20 | Micron Technology, Inc. | Hafnium tantalum oxynitride high-k dielectric and metal gates |
US20080057659A1 (en) | 2006-08-31 | 2008-03-06 | Micron Technology, Inc. | Hafnium aluminium oxynitride high-K dielectric and metal gates |
US7544604B2 (en) | 2006-08-31 | 2009-06-09 | Micron Technology, Inc. | Tantalum lanthanide oxynitride films |
JP4943780B2 (en) | 2006-08-31 | 2012-05-30 | 株式会社日立ハイテクノロジーズ | Plasma processing apparatus and plasma processing method |
US20080241805A1 (en) | 2006-08-31 | 2008-10-02 | Q-Track Corporation | System and method for simulated dosimetry using a real time locating system |
JP4762835B2 (en) | 2006-09-07 | 2011-08-31 | 東京エレクトロン株式会社 | Substrate processing method, substrate processing apparatus, program, and program recording medium |
USD613829S1 (en) | 2006-09-13 | 2010-04-13 | Hayward Industries, Inc. | Circular suction outlet assembly cover |
US7789965B2 (en) | 2006-09-19 | 2010-09-07 | Asm Japan K.K. | Method of cleaning UV irradiation chamber |
US7976898B2 (en) | 2006-09-20 | 2011-07-12 | Asm Genitech Korea Ltd. | Atomic layer deposition apparatus |
US7718553B2 (en) | 2006-09-21 | 2010-05-18 | Asm Japan K.K. | Method for forming insulation film having high density |
JP2008074963A (en) | 2006-09-21 | 2008-04-03 | Fujifilm Corp | Composition, film and method for producing the same |
US7723648B2 (en) | 2006-09-25 | 2010-05-25 | Tokyo Electron Limited | Temperature controlled substrate holder with non-uniform insulation layer for a substrate processing system |
US8137048B2 (en) | 2006-09-27 | 2012-03-20 | Vserv Technologies | Wafer processing system with dual wafer robots capable of asynchronous motion |
TWI462179B (en) | 2006-09-28 | 2014-11-21 | Tokyo Electron Ltd | Film formation method and apparatus for forming silicon oxide film |
US7476291B2 (en) | 2006-09-28 | 2009-01-13 | Lam Research Corporation | High chamber temperature process and chamber design for photo-resist stripping and post-metal etch passivation |
DE102006046374B4 (en) | 2006-09-29 | 2010-11-11 | Advanced Micro Devices, Inc., Sunnyvale | A method of reducing paint poisoning during patterning of silicon nitride films in a semiconductor device |
US7767262B2 (en) | 2006-09-29 | 2010-08-03 | Tokyo Electron Limited | Nitrogen profile engineering in nitrided high dielectric constant films |
US8986456B2 (en) | 2006-10-10 | 2015-03-24 | Asm America, Inc. | Precursor delivery system |
USD593969S1 (en) | 2006-10-10 | 2009-06-09 | Tokyo Electron Limited | Processing chamber for manufacturing semiconductors |
JP5073751B2 (en) | 2006-10-10 | 2012-11-14 | エーエスエム アメリカ インコーポレイテッド | Precursor delivery system |
CN100451163C (en) | 2006-10-18 | 2009-01-14 | 中微半导体设备(上海)有限公司 | Gas distribution device for treating reactor by semiconductor technological element and reactor thereof |
JP2008108991A (en) | 2006-10-27 | 2008-05-08 | Daihen Corp | Work holding mechanism |
US7851232B2 (en) | 2006-10-30 | 2010-12-14 | Novellus Systems, Inc. | UV treatment for carbon-containing low-k dielectric repair in semiconductor processing |
US7888273B1 (en) | 2006-11-01 | 2011-02-15 | Novellus Systems, Inc. | Density gradient-free gap fill |
US7611751B2 (en) | 2006-11-01 | 2009-11-03 | Asm America, Inc. | Vapor deposition of metal carbide films |
US7727864B2 (en) | 2006-11-01 | 2010-06-01 | Asm America, Inc. | Controlled composition using plasma-enhanced atomic layer deposition |
US7955516B2 (en) | 2006-11-02 | 2011-06-07 | Applied Materials, Inc. | Etching of nano-imprint templates using an etch reactor |
JP2008117903A (en) | 2006-11-02 | 2008-05-22 | Toshiba Corp | Method of manufacturing semiconductor device |
WO2008056295A1 (en) | 2006-11-09 | 2008-05-15 | Nxp B.V. | A semiconductor device and a method of manufacturing thereof |
US7776395B2 (en) | 2006-11-14 | 2010-08-17 | Applied Materials, Inc. | Method of depositing catalyst assisted silicates of high-k materials |
US7749574B2 (en) | 2006-11-14 | 2010-07-06 | Applied Materials, Inc. | Low temperature ALD SiO2 |
US7671134B2 (en) | 2006-11-15 | 2010-03-02 | Brady Worldwide, Inc. | Compositions with improved adhesion to low surface energy substrates |
US7976634B2 (en) | 2006-11-21 | 2011-07-12 | Applied Materials, Inc. | Independent radiant gas preheating for precursor disassociation control and gas reaction kinetics in low temperature CVD systems |
US20080124946A1 (en) | 2006-11-28 | 2008-05-29 | Air Products And Chemicals, Inc. | Organosilane compounds for modifying dielectrical properties of silicon oxide and silicon nitride films |
US7807575B2 (en) | 2006-11-29 | 2010-10-05 | Micron Technology, Inc. | Methods to reduce the critical dimension of semiconductor devices |
US20080193673A1 (en) | 2006-12-05 | 2008-08-14 | Applied Materials, Inc. | Method of processing a workpiece using a mid-chamber gas distribution plate, tuned plasma flow control grid and electrode |
EP2089897A2 (en) | 2006-12-07 | 2009-08-19 | Innovalight, Inc. | Methods for creating a densified group iv semiconductor nanoparticle thin film |
US7960236B2 (en) | 2006-12-12 | 2011-06-14 | Applied Materials, Inc. | Phosphorus containing Si epitaxial layers in N-type source/drain junctions |
DE102007003416A1 (en) | 2007-01-16 | 2008-07-17 | Hansgrohe Ag | shower |
DE102007002962B3 (en) | 2007-01-19 | 2008-07-31 | Qimonda Ag | Method for producing a dielectric layer and for producing a capacitor |
JP5109376B2 (en) | 2007-01-22 | 2012-12-26 | 東京エレクトロン株式会社 | Heating device, heating method and storage medium |
WO2008143716A2 (en) | 2007-01-22 | 2008-11-27 | Innovalight, Inc. | In situ modification of group iv nanoparticles using gas phase nanoparticle reactors |
US7550090B2 (en) | 2007-01-23 | 2009-06-23 | Applied Materials, Inc. | Oxygen plasma clean to remove carbon species deposited on a glass dome surface |
US7833353B2 (en) | 2007-01-24 | 2010-11-16 | Asm Japan K.K. | Liquid material vaporization apparatus for semiconductor processing apparatus |
US20080173239A1 (en) | 2007-01-24 | 2008-07-24 | Yuri Makarov | Method, system, and apparatus for the growth of SiC and related or similar material, by chemical vapor deposition, using precursors in modified cold-wall reactor |
US20080179715A1 (en) | 2007-01-30 | 2008-07-31 | Micron Technology, Inc. | Shallow trench isolation using atomic layer deposition during fabrication of a semiconductor device |
JP2008192643A (en) | 2007-01-31 | 2008-08-21 | Tokyo Electron Ltd | Substrate treating equipment |
US7500397B2 (en) | 2007-02-15 | 2009-03-10 | Air Products And Chemicals, Inc. | Activated chemical process for enhancing material properties of dielectric films |
JP2008202107A (en) | 2007-02-21 | 2008-09-04 | Hitachi Kokusai Electric Inc | Substrate-treating apparatus |
JP4805862B2 (en) | 2007-02-21 | 2011-11-02 | 富士通セミコンダクター株式会社 | Substrate processing apparatus, substrate processing method, and semiconductor device manufacturing method |
US20080207007A1 (en) | 2007-02-27 | 2008-08-28 | Air Products And Chemicals, Inc. | Plasma Enhanced Cyclic Chemical Vapor Deposition of Silicon-Containing Films |
DE102007009914B4 (en) | 2007-02-28 | 2010-04-22 | Advanced Micro Devices, Inc., Sunnyvale | Semiconductor device in the form of a field effect transistor with an interlayer dielectric material with increased internal stress and method for producing the same |
US20080216077A1 (en) | 2007-03-02 | 2008-09-04 | Applied Materials, Inc. | Software sequencer for integrated substrate processing system |
US20080220619A1 (en) | 2007-03-09 | 2008-09-11 | Asm Japan K.K. | Method for increasing mechanical strength of dielectric film by using sequential combination of two types of uv irradiation |
US7833913B2 (en) | 2007-03-20 | 2010-11-16 | Tokyo Electron Limited | Method of forming crystallographically stabilized doped hafnium zirconium based films |
US7763869B2 (en) | 2007-03-23 | 2010-07-27 | Asm Japan K.K. | UV light irradiating apparatus with liquid filter |
US7435987B1 (en) | 2007-03-27 | 2008-10-14 | Intel Corporation | Forming a type I heterostructure in a group IV semiconductor |
US7651961B2 (en) | 2007-03-30 | 2010-01-26 | Tokyo Electron Limited | Method for forming strained silicon nitride films and a device containing such films |
US20080241384A1 (en) | 2007-04-02 | 2008-10-02 | Asm Genitech Korea Ltd. | Lateral flow deposition apparatus and method of depositing film by using the apparatus |
US8235001B2 (en) | 2007-04-02 | 2012-08-07 | Hitachi Kokusai Electric Inc. | Substrate processing apparatus and method for manufacturing semiconductor device |
KR100829759B1 (en) | 2007-04-04 | 2008-05-15 | 삼성에스디아이 주식회사 | Carbon nanotube hybrid systems using carbide derived carbon, electron emitter comprising the same and electron emission device comprising the electron emitter |
US8357214B2 (en) | 2007-04-26 | 2013-01-22 | Trulite, Inc. | Apparatus, system, and method for generating a gas from solid reactant pouches |
US7575968B2 (en) | 2007-04-30 | 2009-08-18 | Freescale Semiconductor, Inc. | Inverse slope isolation and dual surface orientation integration |
US7713874B2 (en) | 2007-05-02 | 2010-05-11 | Asm America, Inc. | Periodic plasma annealing in an ALD-type process |
JP5103056B2 (en) | 2007-05-15 | 2012-12-19 | ルネサスエレクトロニクス株式会社 | Manufacturing method of semiconductor device |
US7942969B2 (en) | 2007-05-30 | 2011-05-17 | Applied Materials, Inc. | Substrate cleaning chamber and components |
US20080299326A1 (en) | 2007-05-30 | 2008-12-04 | Asm Japan K.K. | Plasma cvd apparatus having non-metal susceptor |
US7807578B2 (en) | 2007-06-01 | 2010-10-05 | Applied Materials, Inc. | Frequency doubling using spacer mask |
US20080302303A1 (en) | 2007-06-07 | 2008-12-11 | Applied Materials, Inc. | Methods and apparatus for depositing a uniform silicon film with flow gradient designs |
US8142606B2 (en) | 2007-06-07 | 2012-03-27 | Applied Materials, Inc. | Apparatus for depositing a uniform silicon film and methods for manufacturing the same |
KR101217778B1 (en) | 2007-06-08 | 2013-01-02 | 도쿄엘렉트론가부시키가이샤 | patterning method |
JP4427562B2 (en) | 2007-06-11 | 2010-03-10 | 株式会社東芝 | Pattern formation method |
US8017182B2 (en) | 2007-06-21 | 2011-09-13 | Asm International N.V. | Method for depositing thin films by mixed pulsed CVD and ALD |
USD575713S1 (en) | 2007-06-21 | 2008-08-26 | Ratcliffe Peter W | Vehicle accessory |
CN100590804C (en) | 2007-06-22 | 2010-02-17 | 中芯国际集成电路制造(上海)有限公司 | Method for depositing atomic layer and semiconductor device formed by the same |
US20090000550A1 (en) | 2007-06-29 | 2009-01-01 | Applied Materials, Inc. | Manifold assembly |
US20090033907A1 (en) | 2007-07-05 | 2009-02-05 | Nikon Corporation | Devices and methods for decreasing residual chucking forces |
US7501292B2 (en) | 2007-07-19 | 2009-03-10 | Asm Japan K.K. | Method for managing UV irradiation for curing semiconductor substrate |
JP4900110B2 (en) | 2007-07-20 | 2012-03-21 | 東京エレクトロン株式会社 | Chemical vaporization tank and chemical treatment system |
US8008166B2 (en) | 2007-07-26 | 2011-08-30 | Applied Materials, Inc. | Method and apparatus for cleaning a substrate surface |
US7720560B2 (en) | 2007-07-26 | 2010-05-18 | International Business Machines Corporation | Semiconductor manufacturing process monitoring |
US8004045B2 (en) | 2007-07-27 | 2011-08-23 | Panasonic Corporation | Semiconductor device and method for producing the same |
WO2009023169A1 (en) | 2007-08-10 | 2009-02-19 | Nano Terra Inc. | Structured smudge-resistant coatings and methods of making and using the same |
US20090041952A1 (en) | 2007-08-10 | 2009-02-12 | Asm Genitech Korea Ltd. | Method of depositing silicon oxide films |
US7745352B2 (en) | 2007-08-27 | 2010-06-29 | Applied Materials, Inc. | Curing methods for silicon dioxide thin films deposited from alkoxysilane precursor with harp II process |
US8334015B2 (en) | 2007-09-05 | 2012-12-18 | Intermolecular, Inc. | Vapor based combinatorial processing |
JP5663305B2 (en) | 2007-09-07 | 2015-02-04 | フジフィルム マニュファクチュアリング ヨーロッパ ビー.ヴィ. | Method and apparatus for atomic layer deposition using atmospheric pressure glow discharge plasma |
CA122619S (en) | 2007-10-09 | 2010-01-27 | Silvano Breda | Shower strainer |
JP5347294B2 (en) | 2007-09-12 | 2013-11-20 | 東京エレクトロン株式会社 | Film forming apparatus, film forming method, and storage medium |
JP4986784B2 (en) | 2007-09-18 | 2012-07-25 | 東京エレクトロン株式会社 | Processing system control apparatus, processing system control method, and storage medium storing control program |
JP5236983B2 (en) | 2007-09-28 | 2013-07-17 | 東京エレクトロン株式会社 | Semiconductor device manufacturing method, semiconductor device manufacturing apparatus, control program, and program storage medium |
US20090085156A1 (en) | 2007-09-28 | 2009-04-02 | Gilbert Dewey | Metal surface treatments for uniformly growing dielectric layers |
US8041450B2 (en) | 2007-10-04 | 2011-10-18 | Asm Japan K.K. | Position sensor system for substrate transfer robot |
US7776698B2 (en) | 2007-10-05 | 2010-08-17 | Applied Materials, Inc. | Selective formation of silicon carbon epitaxial layer |
US20090090382A1 (en) | 2007-10-05 | 2009-04-09 | Asm Japan K.K. | Method of self-cleaning of carbon-based film |
US20090095221A1 (en) | 2007-10-16 | 2009-04-16 | Alexander Tam | Multi-gas concentric injection showerhead |
US7541297B2 (en) | 2007-10-22 | 2009-06-02 | Applied Materials, Inc. | Method and system for improving dielectric film quality for void free gap fill |
US7867923B2 (en) | 2007-10-22 | 2011-01-11 | Applied Materials, Inc. | High quality silicon oxide films by remote plasma CVD from disilane precursors |
US7803722B2 (en) | 2007-10-22 | 2010-09-28 | Applied Materials, Inc | Methods for forming a dielectric layer within trenches |
US7615831B2 (en) | 2007-10-26 | 2009-11-10 | International Business Machines Corporation | Structure and method for fabricating self-aligned metal contacts |
US7939447B2 (en) | 2007-10-26 | 2011-05-10 | Asm America, Inc. | Inhibitors for selective deposition of silicon containing films |
CA123272S (en) | 2007-11-19 | 2010-01-27 | Silvano Breda | Shower strainer |
US8272516B2 (en) | 2007-11-19 | 2012-09-25 | Caterpillar Inc. | Fluid filter system |
CA123273S (en) | 2007-11-19 | 2010-01-27 | Silvano Breda | Shower strainer |
US8021723B2 (en) | 2007-11-27 | 2011-09-20 | Asm Japan K.K. | Method of plasma treatment using amplitude-modulated RF power |
EP2215650B1 (en) | 2007-11-28 | 2016-06-22 | Philips Intellectual Property & Standards GmbH | Dielectric barrier discharge lamp |
US8060252B2 (en) | 2007-11-30 | 2011-11-15 | Novellus Systems, Inc. | High throughput method of in transit wafer position correction in system using multiple robots |
US7651959B2 (en) | 2007-12-03 | 2010-01-26 | Asm Japan K.K. | Method for forming silazane-based dielectric film |
US20090139657A1 (en) | 2007-12-04 | 2009-06-04 | Applied Materials, Inc. | Etch system |
US8440569B2 (en) | 2007-12-07 | 2013-05-14 | Cadence Design Systems, Inc. | Method of eliminating a lithography operation |
KR100956247B1 (en) | 2007-12-13 | 2010-05-06 | 삼성엘이디 주식회사 | Metal Organic Chemical Vapor Deposition Apparatus |
US8003174B2 (en) | 2007-12-13 | 2011-08-23 | Asm Japan K.K. | Method for forming dielectric film using siloxane-silazane mixture |
US20100259152A1 (en) | 2007-12-17 | 2010-10-14 | Orc Manufacturing Co., Ltd. | Discharge lamp |
US8092606B2 (en) | 2007-12-18 | 2012-01-10 | Asm Genitech Korea Ltd. | Deposition apparatus |
KR101542636B1 (en) | 2007-12-19 | 2015-08-06 | 램 리써치 코포레이션 | A method of treating a nanoporous low-k dielectric material |
US7678715B2 (en) | 2007-12-21 | 2010-03-16 | Applied Materials, Inc. | Low wet etch rate silicon nitride film |
US8501637B2 (en) | 2007-12-21 | 2013-08-06 | Asm International N.V. | Silicon dioxide thin films by ALD |
KR101013413B1 (en) | 2008-01-07 | 2011-02-14 | 한국과학기술연구원 | Method for the fabrication of transparent gas barrier film using plasma surface treatment |
US7935940B1 (en) | 2008-01-08 | 2011-05-03 | Novellus Systems, Inc. | Measuring in-situ UV intensity in UV cure tool |
US20090203197A1 (en) | 2008-02-08 | 2009-08-13 | Hiroji Hanawa | Novel method for conformal plasma immersed ion implantation assisted by atomic layer deposition |
GB0802486D0 (en) | 2008-02-12 | 2008-03-19 | Gilbert Patrick C | Warm water economy device |
US20090214777A1 (en) | 2008-02-22 | 2009-08-27 | Demetrius Sarigiannis | Multiple ampoule delivery systems |
KR100968132B1 (en) | 2008-02-29 | 2010-07-06 | (주)얼라이드 테크 파인더즈 | Rotational antenna and semiconductor device including the same |
USD585968S1 (en) | 2008-03-06 | 2009-02-03 | West Coast Washers, Inc. | Pipe flashing |
EP2099067A1 (en) | 2008-03-07 | 2009-09-09 | Nederlandse Organisatie voor toegepast- natuurwetenschappelijk onderzoek TNO | Process for adjusting the friction coefficient between surfaces of two solid objects |
US20090246399A1 (en) | 2008-03-28 | 2009-10-01 | Asm Japan K.K. | Method for activating reactive oxygen species for cleaning carbon-based film deposition |
US8252114B2 (en) | 2008-03-28 | 2012-08-28 | Tokyo Electron Limited | Gas distribution system and method for distributing process gas in a processing system |
US7816278B2 (en) | 2008-03-28 | 2010-10-19 | Tokyo Electron Limited | In-situ hybrid deposition of high dielectric constant films using atomic layer deposition and chemical vapor deposition |
USD590933S1 (en) | 2008-03-31 | 2009-04-21 | Mcp Industries, Inc. | Vent cap device |
US7659158B2 (en) | 2008-03-31 | 2010-02-09 | Applied Materials, Inc. | Atomic layer deposition processes for non-volatile memory devices |
US7963736B2 (en) | 2008-04-03 | 2011-06-21 | Asm Japan K.K. | Wafer processing apparatus with wafer alignment device |
US20090250955A1 (en) | 2008-04-07 | 2009-10-08 | Applied Materials, Inc. | Wafer transfer blade |
WO2009129391A2 (en) | 2008-04-17 | 2009-10-22 | Applied Materials, Inc. | Low temperature thin film transistor process, device property, and device stability improvement |
US20090269506A1 (en) | 2008-04-24 | 2009-10-29 | Seiji Okura | Method and apparatus for cleaning of a CVD reactor |
US8252194B2 (en) | 2008-05-02 | 2012-08-28 | Micron Technology, Inc. | Methods of removing silicon oxide |
US7632549B2 (en) | 2008-05-05 | 2009-12-15 | Asm Japan K.K. | Method of forming a high transparent carbon film |
US8076237B2 (en) | 2008-05-09 | 2011-12-13 | Asm America, Inc. | Method and apparatus for 3D interconnect |
US20090286402A1 (en) | 2008-05-13 | 2009-11-19 | Applied Materials, Inc | Method for critical dimension shrink using conformal pecvd films |
US8277670B2 (en) | 2008-05-13 | 2012-10-02 | Lam Research Corporation | Plasma process with photoresist mask pretreatment |
US8333842B2 (en) | 2008-05-15 | 2012-12-18 | Applied Materials, Inc. | Apparatus for etching semiconductor wafers |
US8298628B2 (en) | 2008-06-02 | 2012-10-30 | Air Products And Chemicals, Inc. | Low temperature deposition of silicon-containing films |
WO2009146744A1 (en) | 2008-06-05 | 2009-12-10 | Osram Gesellschaft mit beschränkter Haftung | Method for treating surfaces, lamp for said method, and irradiation system having said lamp |
JP2009295932A (en) | 2008-06-09 | 2009-12-17 | Canon Inc | Exposure device and device manufacturing method |
US8726837B2 (en) | 2008-06-23 | 2014-05-20 | Applied Materials, Inc. | Semiconductor process chamber vision and monitoring system |
US8702867B2 (en) | 2008-07-08 | 2014-04-22 | Jusung Engineering Co., Ltd. | Gas distribution plate and substrate treating apparatus including the same |
US8058138B2 (en) | 2008-07-17 | 2011-11-15 | Micron Technology, Inc. | Gap processing |
USD614593S1 (en) | 2008-07-21 | 2010-04-27 | Asm Genitech Korea Ltd | Substrate support for a semiconductor deposition apparatus |
USD609652S1 (en) | 2008-07-22 | 2010-02-09 | Tokyo Electron Limited | Wafer attracting plate |
WO2010017136A1 (en) | 2008-08-04 | 2010-02-11 | Amir Dassoud Dabiran | Microchannel plate photocathode |
KR20100015213A (en) | 2008-08-04 | 2010-02-12 | 삼성전기주식회사 | Showerhead and chemical vapor deposition apparatus having the same |
WO2010017555A1 (en) | 2008-08-08 | 2010-02-11 | Cornell Research Foundation, Inc. | Inorganic bulk multijunction materials and processes for preparing the same |
US8129555B2 (en) | 2008-08-12 | 2012-03-06 | Air Products And Chemicals, Inc. | Precursors for depositing silicon-containing films and methods for making and using same |
US8263502B2 (en) | 2008-08-13 | 2012-09-11 | Synos Technology, Inc. | Forming substrate structure by filling recesses with deposition material |
JP5338335B2 (en) | 2008-08-13 | 2013-11-13 | 東京エレクトロン株式会社 | Opening / closing device and probe device of transfer container |
KR101017170B1 (en) | 2008-08-13 | 2011-02-25 | 주식회사 동부하이텍 | Back metal process chamber |
US8147648B2 (en) | 2008-08-15 | 2012-04-03 | Lam Research Corporation | Composite showerhead electrode assembly for a plasma processing apparatus |
US20100055442A1 (en) | 2008-09-03 | 2010-03-04 | International Business Machines Corporation | METHOD OF PE-ALD OF SiNxCy AND INTEGRATION OF LINER MATERIALS ON POROUS LOW K SUBSTRATES |
JP2010087467A (en) | 2008-09-04 | 2010-04-15 | Tokyo Electron Ltd | Film deposition apparatus, substrate processing apparatus, film deposition method, and recording medium with recorded program for implementing the film deposition method |
USD643055S1 (en) | 2008-09-11 | 2011-08-09 | Asm Japan K.K. | Heater block for use in a semiconductor processing tool |
US9711373B2 (en) | 2008-09-22 | 2017-07-18 | Taiwan Semiconductor Manufacturing Company, Ltd. | Method of fabricating a gate dielectric for high-k metal gate devices |
DE102008049353A1 (en) | 2008-09-29 | 2010-04-08 | Vat Holding Ag | vacuum valve |
US20100081293A1 (en) | 2008-10-01 | 2010-04-01 | Applied Materials, Inc. | Methods for forming silicon nitride based film or silicon carbon based film |
USD609655S1 (en) | 2008-10-03 | 2010-02-09 | Ngk Insulators, Ltd. | Electrostatic chuck |
KR101632031B1 (en) | 2008-10-07 | 2016-06-21 | 어플라이드 머티어리얼스, 인코포레이티드 | Apparatus for efficient removal of halogen residues from etched substrates |
KR101627297B1 (en) | 2008-10-13 | 2016-06-03 | 한국에이에스엠지니텍 주식회사 | Plasma processing member, deposition apparatus including the same and depositing method using the same |
KR101357181B1 (en) | 2008-10-14 | 2014-01-29 | 어플라이드 머티어리얼스, 인코포레이티드 | Method for depositing conformal amorphous carbon film by plasma-enhanced chemical vapor deposition (pecvd) |
WO2010044978A1 (en) | 2008-10-15 | 2010-04-22 | Arizona Board of Regents, a body corporate acting for and on behalf of Arizona State University | Hybrid group iv/iii-v semiconductor structures |
US7745346B2 (en) | 2008-10-17 | 2010-06-29 | Novellus Systems, Inc. | Method for improving process control and film conformality of PECVD film |
JP2010097834A (en) | 2008-10-17 | 2010-04-30 | Ushio Inc | Backlight unit |
WO2010062582A2 (en) | 2008-10-27 | 2010-06-03 | Applied Materials, Inc. | Vapor deposition method for ternary compounds |
JP5062143B2 (en) | 2008-11-10 | 2012-10-31 | 東京エレクトロン株式会社 | Deposition equipment |
US8647722B2 (en) | 2008-11-14 | 2014-02-11 | Asm Japan K.K. | Method of forming insulation film using plasma treatment cycles |
US10378106B2 (en) | 2008-11-14 | 2019-08-13 | Asm Ip Holding B.V. | Method of forming insulation film by modified PEALD |
JP2010153769A (en) | 2008-11-19 | 2010-07-08 | Tokyo Electron Ltd | Substrate position sensing device, substrate position sensing method, film forming device, film forming method, program, and computer readable storage medium |
US20100130017A1 (en) | 2008-11-21 | 2010-05-27 | Axcelis Technologies, Inc. | Front end of line plasma mediated ashing processes and apparatus |
US9714465B2 (en) | 2008-12-01 | 2017-07-25 | Applied Materials, Inc. | Gas distribution blocker apparatus |
US8138676B2 (en) | 2008-12-01 | 2012-03-20 | Mills Robert L | Methods and systems for dimmable fluorescent lighting using multiple frequencies |
EP2194574B1 (en) | 2008-12-02 | 2018-11-07 | IMEC vzw | Method for producing interconnect structures for integrated circuits |
JP5390846B2 (en) | 2008-12-09 | 2014-01-15 | 東京エレクトロン株式会社 | Plasma etching apparatus and plasma cleaning method |
US20100151206A1 (en) | 2008-12-11 | 2010-06-17 | Air Products And Chemicals, Inc. | Method for Removal of Carbon From An Organosilicate Material |
KR20100075070A (en) | 2008-12-24 | 2010-07-02 | 삼성전자주식회사 | Fabrication method of nonvolatile memory device |
US8216380B2 (en) | 2009-01-08 | 2012-07-10 | Asm America, Inc. | Gap maintenance for opening to process chamber |
US20100176513A1 (en) | 2009-01-09 | 2010-07-15 | International Business Machines Corporation | Structure and method of forming metal interconnect structures in ultra low-k dielectrics |
WO2010081003A2 (en) | 2009-01-11 | 2010-07-15 | Applied Materials, Inc. | Systems, apparatus and methods for moving substrates |
US8151814B2 (en) | 2009-01-13 | 2012-04-10 | Asm Japan K.K. | Method for controlling flow and concentration of liquid precursor |
USD606952S1 (en) | 2009-01-16 | 2009-12-29 | Asm Genitech Korea Ltd. | Plasma inducing plate for semiconductor deposition apparatus |
US8591659B1 (en) | 2009-01-16 | 2013-11-26 | Novellus Systems, Inc. | Plasma clean method for deposition chamber |
US7919416B2 (en) | 2009-01-21 | 2011-04-05 | Asm Japan K.K. | Method of forming conformal dielectric film having Si-N bonds by PECVD |
US8142862B2 (en) | 2009-01-21 | 2012-03-27 | Asm Japan K.K. | Method of forming conformal dielectric film having Si-N bonds by PECVD |
US7972980B2 (en) | 2009-01-21 | 2011-07-05 | Asm Japan K.K. | Method of forming conformal dielectric film having Si-N bonds by PECVD |
US8680650B2 (en) | 2009-02-03 | 2014-03-25 | Micron Technology, Inc. | Capacitor structures having improved area efficiency |
US8307472B1 (en) | 2009-02-04 | 2012-11-13 | Thomas Jason Saxon | Light emitting diode system |
KR101691044B1 (en) | 2009-02-04 | 2016-12-29 | 맷슨 테크놀로지, 인크. | Electrostatic chuck system and process for radially tuning the temperature profile across the surface of a substrate |
US8287648B2 (en) | 2009-02-09 | 2012-10-16 | Asm America, Inc. | Method and apparatus for minimizing contamination in semiconductor processing chamber |
JPWO2010093041A1 (en) | 2009-02-16 | 2012-08-16 | 三菱樹脂株式会社 | Method for producing gas barrier laminate film |
JP2010205967A (en) | 2009-03-04 | 2010-09-16 | Tokyo Electron Ltd | Plasma etching method, plasma etching device, and computer storage medium |
JP5221421B2 (en) | 2009-03-10 | 2013-06-26 | 東京エレクトロン株式会社 | Shower head and plasma processing apparatus |
US8703624B2 (en) | 2009-03-13 | 2014-04-22 | Air Products And Chemicals, Inc. | Dielectric films comprising silicon and methods for making same |
WO2010109848A1 (en) | 2009-03-26 | 2010-09-30 | パナソニック株式会社 | Plasma processing apparatus and plasma processing method |
JP5292160B2 (en) | 2009-03-31 | 2013-09-18 | 東京エレクトロン株式会社 | Gas flow path structure and substrate processing apparatus |
US8197915B2 (en) | 2009-04-01 | 2012-06-12 | Asm Japan K.K. | Method of depositing silicon oxide film by plasma enhanced atomic layer deposition at low temperature |
US8284601B2 (en) | 2009-04-01 | 2012-10-09 | Samsung Electronics Co., Ltd. | Semiconductor memory device comprising three-dimensional memory cell array |
US9394608B2 (en) | 2009-04-06 | 2016-07-19 | Asm America, Inc. | Semiconductor processing reactor and components thereof |
JP5338443B2 (en) | 2009-04-14 | 2013-11-13 | 信越半導体株式会社 | Manufacturing method of SOI wafer |
SG174993A1 (en) | 2009-04-21 | 2011-11-28 | Applied Materials Inc | Cvd apparatus for improved film thickness non-uniformity and particle performance |
US8071452B2 (en) | 2009-04-27 | 2011-12-06 | Asm America, Inc. | Atomic layer deposition of hafnium lanthanum oxides |
JP5136574B2 (en) | 2009-05-01 | 2013-02-06 | 東京エレクトロン株式会社 | Plasma processing apparatus and plasma processing method |
US7842622B1 (en) | 2009-05-15 | 2010-11-30 | Asm Japan K.K. | Method of forming highly conformal amorphous carbon layer |
US8004198B2 (en) | 2009-05-28 | 2011-08-23 | Osram Sylvania Inc. | Resetting an electronic ballast in the event of fault |
US20100317198A1 (en) | 2009-06-12 | 2010-12-16 | Novellus Systems, Inc. | Remote plasma processing of interface surfaces |
USD652896S1 (en) | 2009-06-17 | 2012-01-24 | Neoperl Gmbh | Faucet stream former |
US7825040B1 (en) | 2009-06-22 | 2010-11-02 | Asm Japan K.K. | Method for depositing flowable material using alkoxysilane or aminosilane precursor |
US20110006406A1 (en) | 2009-07-08 | 2011-01-13 | Imec | Fabrication of porogen residues free and mechanically robust low-k materials |
KR101110080B1 (en) | 2009-07-08 | 2012-03-13 | 주식회사 유진테크 | Method for processing substrate |
JP2011023718A (en) | 2009-07-15 | 2011-02-03 | Asm Japan Kk | METHOD FOR FORMING STRESS-TUNED DIELECTRIC FILM HAVING Si-N BOND BY PEALD |
JP5646478B2 (en) | 2009-07-17 | 2014-12-24 | 三井化学株式会社 | Laminated body and method for producing the same |
US8071451B2 (en) | 2009-07-29 | 2011-12-06 | Axcelis Technologies, Inc. | Method of doping semiconductors |
US8741788B2 (en) | 2009-08-06 | 2014-06-03 | Applied Materials, Inc. | Formation of silicon oxide using non-carbon flowable CVD processes |
US8877655B2 (en) | 2010-05-07 | 2014-11-04 | Asm America, Inc. | Systems and methods for thin-film deposition of metal oxides using excited nitrogen-oxygen species |
US8883270B2 (en) | 2009-08-14 | 2014-11-11 | Asm America, Inc. | Systems and methods for thin-film deposition of metal oxides using excited nitrogen—oxygen species |
US8802201B2 (en) | 2009-08-14 | 2014-08-12 | Asm America, Inc. | Systems and methods for thin-film deposition of metal oxides using excited nitrogen-oxygen species |
KR101031226B1 (en) | 2009-08-21 | 2011-04-29 | 에이피시스템 주식회사 | Heater block of rapid thermal processing apparatus |
CN102414801A (en) | 2009-08-27 | 2012-04-11 | 应用材料公司 | Method of decontamination of process chamber after in-situ chamber clean |
USD634719S1 (en) | 2009-08-27 | 2011-03-22 | Ebara Corporation | Elastic membrane for semiconductor wafer polishing apparatus |
WO2011026064A1 (en) | 2009-08-31 | 2011-03-03 | The Penn State Research Foundation | Improved plasma enhanced atomic layer deposition process |
JP2011054708A (en) * | 2009-09-01 | 2011-03-17 | Elpida Memory Inc | Insulating film, method of manufacturing the same, semiconductor device, and data processing system |
JP5457109B2 (en) | 2009-09-02 | 2014-04-02 | 東京エレクトロン株式会社 | Plasma processing equipment |
DE212010000009U1 (en) | 2009-09-10 | 2011-05-26 | LAM RESEARCH CORPORATION (Delaware Corporation), California | Interchangeable upper chamber parts of a plasma processing device |
US20110061810A1 (en) | 2009-09-11 | 2011-03-17 | Applied Materials, Inc. | Apparatus and Methods for Cyclical Oxidation and Etching |
EP2306497B1 (en) | 2009-10-02 | 2012-06-06 | Imec | Method for manufacturing a low defect interface between a dielectric and a III/V compound |
US8173554B2 (en) | 2009-10-14 | 2012-05-08 | Asm Japan K.K. | Method of depositing dielectric film having Si-N bonds by modified peald method |
US8415259B2 (en) | 2009-10-14 | 2013-04-09 | Asm Japan K.K. | Method of depositing dielectric film by modified PEALD method |
US8465791B2 (en) | 2009-10-16 | 2013-06-18 | Msp Corporation | Method for counting particles in a gas |
US20110097901A1 (en) | 2009-10-26 | 2011-04-28 | Applied Materials, Inc. | Dual mode inductively coupled plasma reactor with adjustable phase coil assembly |
JP5451324B2 (en) | 2009-11-10 | 2014-03-26 | 株式会社日立ハイテクノロジーズ | Plasma processing equipment |
US8854734B2 (en) | 2009-11-12 | 2014-10-07 | Vela Technologies, Inc. | Integrating optical system and methods |
US8367528B2 (en) | 2009-11-17 | 2013-02-05 | Asm America, Inc. | Cyclical epitaxial deposition and etch |
EP2336824A1 (en) | 2009-11-19 | 2011-06-22 | Rohm and Haas Electronic Materials, L.L.C. | Methods of forming electronic devices |
KR20110055912A (en) | 2009-11-20 | 2011-05-26 | 주식회사 하이닉스반도체 | Method for forming fine pattern in semiconductor device |
AU329418S (en) | 2009-11-23 | 2010-01-29 | Pusher tool | |
US20110139748A1 (en) | 2009-12-15 | 2011-06-16 | University Of Houston | Atomic layer etching with pulsed plasmas |
US8328494B2 (en) | 2009-12-15 | 2012-12-11 | Varian Semiconductor Equipment Associates, Inc. | In vacuum optical wafer heater for cryogenic processing |
US20110159202A1 (en) | 2009-12-29 | 2011-06-30 | Asm Japan K.K. | Method for Sealing Pores at Surface of Dielectric Layer by UV Light-Assisted CVD |
USD653734S1 (en) | 2010-01-08 | 2012-02-07 | Bulk Tank, Inc. | Screened gasket |
US20110183269A1 (en) | 2010-01-25 | 2011-07-28 | Hongbin Zhu | Methods Of Forming Patterns, And Methods For Trimming Photoresist Features |
US8480942B2 (en) | 2010-01-27 | 2013-07-09 | The Board Of Trustees Of The University Of Illinois | Method of forming a patterned layer of a material on a substrate |
KR101259862B1 (en) | 2010-02-05 | 2013-05-02 | 도쿄엘렉트론가부시키가이샤 | Substrate holder, substrate transfer apparatus, and substrate processing apparatus |
KR101080604B1 (en) | 2010-02-09 | 2011-11-04 | 성균관대학교산학협력단 | atomic layer etching apparatus and etching method using the same |
US8293658B2 (en) | 2010-02-17 | 2012-10-23 | Asm America, Inc. | Reactive site deactivation against vapor deposition |
US8241991B2 (en) | 2010-03-05 | 2012-08-14 | Asm Japan K.K. | Method for forming interconnect structure having airgap |
FR2957716B1 (en) | 2010-03-18 | 2012-10-05 | Soitec Silicon On Insulator | METHOD FOR FINISHING A SEMICONDUCTOR TYPE SUBSTRATE ON INSULATION |
US8709551B2 (en) | 2010-03-25 | 2014-04-29 | Novellus Systems, Inc. | Smooth silicon-containing films |
EP2378543B1 (en) | 2010-04-14 | 2015-05-20 | ASM Genitech Korea Ltd. | Method of forming semiconductor patterns |
US8728956B2 (en) | 2010-04-15 | 2014-05-20 | Novellus Systems, Inc. | Plasma activated conformal film deposition |
US8956983B2 (en) | 2010-04-15 | 2015-02-17 | Novellus Systems, Inc. | Conformal doping via plasma activated atomic layer deposition and conformal film deposition |
US20110265951A1 (en) | 2010-04-30 | 2011-11-03 | Applied Materials, Inc. | Twin chamber processing system |
US8707754B2 (en) | 2010-04-30 | 2014-04-29 | Applied Materials, Inc. | Methods and apparatus for calibrating flow controllers in substrate processing systems |
US8496756B2 (en) | 2010-04-30 | 2013-07-30 | Applied Materials, Inc. | Methods for processing substrates in process systems having shared resources |
US20110294075A1 (en) | 2010-05-25 | 2011-12-01 | United Microelectronics Corp. | Patterning method |
US8912353B2 (en) | 2010-06-02 | 2014-12-16 | Air Products And Chemicals, Inc. | Organoaminosilane precursors and methods for depositing films comprising same |
JP5525339B2 (en) | 2010-06-10 | 2014-06-18 | ナブテスコ株式会社 | Robot arm |
US9443753B2 (en) | 2010-07-30 | 2016-09-13 | Applied Materials, Inc. | Apparatus for controlling the flow of a gas in a process chamber |
US8669185B2 (en) | 2010-07-30 | 2014-03-11 | Asm Japan K.K. | Method of tailoring conformality of Si-containing film |
US8357608B2 (en) | 2010-08-09 | 2013-01-22 | International Business Machines Corporation | Multi component dielectric layer |
US9449858B2 (en) | 2010-08-09 | 2016-09-20 | Applied Materials, Inc. | Transparent reflector plate for rapid thermal processing chamber |
US8685845B2 (en) | 2010-08-20 | 2014-04-01 | International Business Machines Corporation | Epitaxial growth of silicon doped with carbon and phosphorus using hydrogen carrier gas |
US8945305B2 (en) | 2010-08-31 | 2015-02-03 | Micron Technology, Inc. | Methods of selectively forming a material using parylene coating |
EP2426233B1 (en) | 2010-09-03 | 2013-05-01 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Use of dialkyl monoalkoxy aluminum for the growth of Al2O3 thin films for photovoltaic applications |
US8394466B2 (en) | 2010-09-03 | 2013-03-12 | Asm Japan K.K. | Method of forming conformal film having si-N bonds on high-aspect ratio pattern |
US8192901B2 (en) | 2010-10-21 | 2012-06-05 | Asahi Glass Company, Limited | Glass substrate-holding tool |
USD654884S1 (en) | 2010-10-21 | 2012-02-28 | Tokyo Electron Limited | Top plate for reactor for manufacturing semiconductor |
US8845806B2 (en) | 2010-10-22 | 2014-09-30 | Asm Japan K.K. | Shower plate having different aperture dimensions and/or distributions |
WO2012057967A2 (en) | 2010-10-27 | 2012-05-03 | Applied Materials, Inc. | Methods and apparatus for controlling photoresist line width roughness |
KR20130135261A (en) | 2010-11-03 | 2013-12-10 | 어플라이드 머티어리얼스, 인코포레이티드 | Apparatus and methods for deposition of silicon carbide and silicon carbonitride films |
US8470187B2 (en) | 2010-11-05 | 2013-06-25 | Asm Japan K.K. | Method of depositing film with tailored comformality |
WO2012061278A1 (en) | 2010-11-05 | 2012-05-10 | Synos Technology, Inc. | Radical reactor with multiple plasma chambers |
US20120121823A1 (en) | 2010-11-12 | 2012-05-17 | Applied Materials, Inc. | Process for lowering adhesion layer thickness and improving damage resistance for thin ultra low-k dielectric film |
CN106887399B (en) | 2010-12-20 | 2020-02-21 | Ev 集团 E·索尔纳有限责任公司 | Accommodating device for holding wafers |
JP5735304B2 (en) | 2010-12-21 | 2015-06-17 | 株式会社日立国際電気 | Substrate processing apparatus, substrate manufacturing method, semiconductor device manufacturing method, and gas supply pipe |
US8314034B2 (en) | 2010-12-23 | 2012-11-20 | Intel Corporation | Feature size reduction |
JP5675331B2 (en) | 2010-12-27 | 2015-02-25 | 東京エレクトロン株式会社 | How to fill trench |
JP2012138500A (en) | 2010-12-27 | 2012-07-19 | Tokyo Electron Ltd | Method for forming silicon oxide film on tungsten film or tungsten oxide film and film forming device |
JP5573666B2 (en) | 2010-12-28 | 2014-08-20 | 東京エレクトロン株式会社 | Raw material supply apparatus and film forming apparatus |
US8901016B2 (en) | 2010-12-28 | 2014-12-02 | Asm Japan K.K. | Method of forming metal oxide hardmask |
FR2970110B1 (en) | 2010-12-29 | 2013-09-06 | St Microelectronics Crolles 2 | PROCESS FOR PRODUCING A POLYCRYSTALLINE DIELECTRIC LAYER |
JP6104817B2 (en) | 2010-12-30 | 2017-03-29 | アプライド マテリアルズ インコーポレイテッドApplied Materials,Incorporated | Thin film deposition using microwave plasma |
JP5609663B2 (en) | 2011-01-18 | 2014-10-22 | 旭硝子株式会社 | Glass substrate holding means and EUV mask blank manufacturing method using the same |
US8465811B2 (en) | 2011-01-28 | 2013-06-18 | Asm Japan K.K. | Method of depositing film by atomic layer deposition with pulse-time-modulated plasma |
US20120263876A1 (en) | 2011-02-14 | 2012-10-18 | Asm Ip Holding B.V. | Deposition of silicon dioxide on hydrophobic surfaces |
US8563443B2 (en) | 2011-02-18 | 2013-10-22 | Asm Japan K.K. | Method of depositing dielectric film by ALD using precursor containing silicon, hydrocarbon, and halogen |
US8329599B2 (en) | 2011-02-18 | 2012-12-11 | Asm Japan K.K. | Method of depositing dielectric film by ALD using precursor containing silicon, hydrocarbon, and halogen |
CN202259160U (en) | 2011-02-21 | 2012-05-30 | 盛陶盟(香港)有限公司 | Ceramic glass composite electrode and fluorescent lamp thereof |
US8466411B2 (en) | 2011-03-03 | 2013-06-18 | Asm Japan K.K. | Calibration method of UV sensor for UV curing |
CN102655086B (en) | 2011-03-03 | 2015-07-01 | 东京毅力科创株式会社 | Semiconductor device manufacturing method |
JP5820731B2 (en) | 2011-03-22 | 2015-11-24 | 株式会社日立国際電気 | Substrate processing apparatus and solid material replenishment method |
JP5203482B2 (en) | 2011-03-28 | 2013-06-05 | 株式会社小松製作所 | Heating device |
JP5922219B2 (en) | 2011-03-31 | 2016-05-24 | アイメックImec | Method for growing single crystal tin-containing semiconductor material |
US8900402B2 (en) | 2011-05-10 | 2014-12-02 | Lam Research Corporation | Semiconductor processing system having multiple decoupled plasma sources |
US8298951B1 (en) | 2011-04-13 | 2012-10-30 | Asm Japan K.K. | Footing reduction using etch-selective layer |
US20140056679A1 (en) | 2011-04-15 | 2014-02-27 | Tazmo Co., Ltd. | Wafer exchange apparatus and wafer supporting hand |
US8871617B2 (en) | 2011-04-22 | 2014-10-28 | Asm Ip Holding B.V. | Deposition and reduction of mixed metal oxide thin films |
US8492170B2 (en) | 2011-04-25 | 2013-07-23 | Applied Materials, Inc. | UV assisted silylation for recovery and pore sealing of damaged low K films |
US8592005B2 (en) | 2011-04-26 | 2013-11-26 | Asm Japan K.K. | Atomic layer deposition for controlling vertical film growth |
USD655055S1 (en) | 2011-04-28 | 2012-02-28 | Carolyn Grace Toll | Pet outfit |
US8809170B2 (en) | 2011-05-19 | 2014-08-19 | Asm America Inc. | High throughput cyclical epitaxial deposition and etch process |
US20120304935A1 (en) | 2011-05-31 | 2012-12-06 | Oosterlaken Theodorus G M | Bubbler assembly and method for vapor flow control |
US9312155B2 (en) | 2011-06-06 | 2016-04-12 | Asm Japan K.K. | High-throughput semiconductor-processing apparatus equipped with multiple dual-chamber modules |
US8927318B2 (en) | 2011-06-14 | 2015-01-06 | International Business Machines Corporation | Spalling methods to form multi-junction photovoltaic structure |
US9175392B2 (en) | 2011-06-17 | 2015-11-03 | Intermolecular, Inc. | System for multi-region processing |
US9793148B2 (en) | 2011-06-22 | 2017-10-17 | Asm Japan K.K. | Method for positioning wafers in multiple wafer transport |
US10364496B2 (en) | 2011-06-27 | 2019-07-30 | Asm Ip Holding B.V. | Dual section module having shared and unshared mass flow controllers |
US8962400B2 (en) | 2011-07-07 | 2015-02-24 | Taiwan Semiconductor Manufacturing Company, Ltd. | In-situ doping of arsenic for source and drain epitaxy |
US20130014697A1 (en) | 2011-07-12 | 2013-01-17 | Asm Japan K.K. | Container Having Multiple Compartments Containing Liquid Material for Multiple Wafer-Processing Chambers |
US10854498B2 (en) | 2011-07-15 | 2020-12-01 | Asm Ip Holding B.V. | Wafer-supporting device and method for producing same |
JP5940342B2 (en) | 2011-07-15 | 2016-06-29 | 東京エレクトロン株式会社 | Substrate transport apparatus, substrate processing system, substrate transport method, and storage medium |
US8617411B2 (en) | 2011-07-20 | 2013-12-31 | Lam Research Corporation | Methods and apparatus for atomic layer etching |
US20130023129A1 (en) | 2011-07-20 | 2013-01-24 | Asm America, Inc. | Pressure transmitter for a semiconductor processing environment |
US8778448B2 (en) | 2011-07-21 | 2014-07-15 | International Business Machines Corporation | Method of stabilizing hydrogenated amorphous silicon and amorphous hydrogenated silicon alloys |
US8551892B2 (en) | 2011-07-27 | 2013-10-08 | Asm Japan K.K. | Method for reducing dielectric constant of film using direct plasma of hydrogen |
US20130048606A1 (en) | 2011-08-31 | 2013-02-28 | Zhigang Mao | Methods for in-situ chamber dry clean in photomask plasma etching processing chamber |
US20130217241A1 (en) | 2011-09-09 | 2013-08-22 | Applied Materials, Inc. | Treatments for decreasing etch rates after flowable deposition of silicon-carbon-and-nitrogen-containing layers |
US20130217239A1 (en) | 2011-09-09 | 2013-08-22 | Applied Materials, Inc. | Flowable silicon-and-carbon-containing layers for semiconductor processing |
US20130217240A1 (en) | 2011-09-09 | 2013-08-22 | Applied Materials, Inc. | Flowable silicon-carbon-nitrogen layers for semiconductor processing |
US20130064973A1 (en) | 2011-09-09 | 2013-03-14 | Taiwan Semiconductor Manufacturing Company, Ltd. | Chamber Conditioning Method |
US20130217243A1 (en) | 2011-09-09 | 2013-08-22 | Applied Materials, Inc. | Doping of dielectric layers |
US20130068970A1 (en) | 2011-09-21 | 2013-03-21 | Asm Japan K.K. | UV Irradiation Apparatus Having UV Lamp-Shared Multiple Process Stations |
JP5549655B2 (en) | 2011-09-26 | 2014-07-16 | 株式会社安川電機 | Hand and robot |
US8993072B2 (en) | 2011-09-27 | 2015-03-31 | Air Products And Chemicals, Inc. | Halogenated organoaminosilane precursors and methods for depositing films comprising same |
US9644796B2 (en) | 2011-09-29 | 2017-05-09 | Applied Materials, Inc. | Methods for in-situ calibration of a flow controller |
US8569184B2 (en) | 2011-09-30 | 2013-10-29 | Asm Japan K.K. | Method for forming single-phase multi-element film by PEALD |
US9096931B2 (en) | 2011-10-27 | 2015-08-04 | Asm America, Inc | Deposition valve assembly and method of heating the same |
US9341296B2 (en) | 2011-10-27 | 2016-05-17 | Asm America, Inc. | Heater jacket for a fluid line |
US9017481B1 (en) | 2011-10-28 | 2015-04-28 | Asm America, Inc. | Process feed management for semiconductor substrate processing |
TWI606136B (en) | 2011-11-04 | 2017-11-21 | Asm國際股份有限公司 | Method for depositing doped silicon oxide and atomic layer deposition process for depositing doped silicon oxide on substrate |
US8927059B2 (en) | 2011-11-08 | 2015-01-06 | Applied Materials, Inc. | Deposition of metal films using alane-based precursors |
US20130122712A1 (en) | 2011-11-14 | 2013-05-16 | Jong Mun Kim | Method of etching high aspect ratio features in a dielectric layer |
US9167625B2 (en) | 2011-11-23 | 2015-10-20 | Asm Ip Holding B.V. | Radiation shielding for a substrate holder |
US9005539B2 (en) | 2011-11-23 | 2015-04-14 | Asm Ip Holding B.V. | Chamber sealing member |
US10276410B2 (en) | 2011-11-25 | 2019-04-30 | Nhk Spring Co., Ltd. | Substrate support device |
US8633115B2 (en) | 2011-11-30 | 2014-01-21 | Applied Materials, Inc. | Methods for atomic layer etching |
USD691974S1 (en) | 2011-12-22 | 2013-10-22 | Tokyo Electron Limited | Holding pad for transferring a wafer |
CN106847875B (en) | 2011-12-23 | 2021-04-20 | 索尼公司 | Non-planar gate fully-enclosed device and method of making same |
US8883028B2 (en) | 2011-12-28 | 2014-11-11 | Lam Research Corporation | Mixed mode pulsing etching in plasma processing systems |
US8623468B2 (en) * | 2012-01-05 | 2014-01-07 | Taiwan Semiconductor Manufacturing Company, Ltd. | Methods of fabricating metal hard masks |
USD676943S1 (en) | 2012-01-11 | 2013-02-26 | Bill Kluss | Pipe end cap |
US20130183814A1 (en) | 2012-01-13 | 2013-07-18 | Applied Materials, Inc. | Method of depositing a silicon germanium tin layer on a substrate |
USD665055S1 (en) | 2012-01-24 | 2012-08-07 | Asm Ip Holding B.V. | Shower plate |
JP5601331B2 (en) | 2012-01-26 | 2014-10-08 | 株式会社安川電機 | Robot hand and robot |
US8728955B2 (en) | 2012-02-14 | 2014-05-20 | Novellus Systems, Inc. | Method of plasma activated deposition of a conformal film on a substrate surface |
JP5912637B2 (en) | 2012-02-17 | 2016-04-27 | 東京エレクトロン株式会社 | Manufacturing method of semiconductor device |
US20130224964A1 (en) | 2012-02-28 | 2013-08-29 | Asm Ip Holding B.V. | Method for Forming Dielectric Film Containing Si-C bonds by Atomic Layer Deposition Using Precursor Containing Si-C-Si bond |
US9202727B2 (en) | 2012-03-02 | 2015-12-01 | ASM IP Holding | Susceptor heater shim |
KR102140719B1 (en) | 2012-03-09 | 2020-08-03 | 에어 프로덕츠 앤드 케미칼스, 인코오포레이티드 | Barrier materials for display devices |
US8912101B2 (en) | 2012-03-15 | 2014-12-16 | Asm Ip Holding B.V. | Method for forming Si-containing film using two precursors by ALD |
USD715410S1 (en) | 2012-03-21 | 2014-10-14 | Blucher Metal A/S | Roof drain |
US9082684B2 (en) | 2012-04-02 | 2015-07-14 | Applied Materials, Inc. | Method of epitaxial doped germanium tin alloy formation |
US8946830B2 (en) | 2012-04-04 | 2015-02-03 | Asm Ip Holdings B.V. | Metal oxide protective layer for a semiconductor device |
US9460912B2 (en) | 2012-04-12 | 2016-10-04 | Air Products And Chemicals, Inc. | High temperature atomic layer deposition of silicon oxide thin films |
US8535767B1 (en) | 2012-04-18 | 2013-09-17 | Asm Ip Holding B.V. | Method for repairing damage of dielectric film by hydrocarbon restoration and hydrocarbon depletion using UV irradiation |
US8647439B2 (en) | 2012-04-26 | 2014-02-11 | Applied Materials, Inc. | Method of epitaxial germanium tin alloy surface preparation |
TWI622664B (en) | 2012-05-02 | 2018-05-01 | Asm智慧財產控股公司 | Phase-stabilized thin films, structures and devices including the thin films, and methods of forming same |
US8728832B2 (en) | 2012-05-07 | 2014-05-20 | Asm Ip Holdings B.V. | Semiconductor device dielectric interface layer |
US8785215B2 (en) | 2012-05-31 | 2014-07-22 | Asm Ip Holding B.V. | Method for repairing damage of dielectric film by cyclic processes |
US9337018B2 (en) | 2012-06-01 | 2016-05-10 | Air Products And Chemicals, Inc. | Methods for depositing films with organoaminodisilane precursors |
US9978585B2 (en) | 2012-06-01 | 2018-05-22 | Versum Materials Us, Llc | Organoaminodisilane precursors and methods for depositing films comprising same |
US20130330911A1 (en) | 2012-06-08 | 2013-12-12 | Yi-Chiau Huang | Method of semiconductor film stabilization |
US8722546B2 (en) | 2012-06-11 | 2014-05-13 | Asm Ip Holding B.V. | Method for forming silicon-containing dielectric film by cyclic deposition with side wall coverage control |
US9984866B2 (en) | 2012-06-12 | 2018-05-29 | Component Re-Engineering Company, Inc. | Multiple zone heater |
US8933375B2 (en) | 2012-06-27 | 2015-01-13 | Asm Ip Holding B.V. | Susceptor heater and method of heating a substrate |
US9023737B2 (en) | 2012-07-11 | 2015-05-05 | Asm Ip Holding B.V. | Method for forming conformal, homogeneous dielectric film by cyclic deposition and heat treatment |
US8784950B2 (en) | 2012-07-16 | 2014-07-22 | Asm Ip Holding B.V. | Method for forming aluminum oxide film using Al compound containing alkyl group and alkoxy or alkylamine group |
JP2015528011A (en) | 2012-07-20 | 2015-09-24 | レール・リキード−ソシエテ・アノニム・プール・レテュード・エ・レクスプロワタシオン・デ・プロセデ・ジョルジュ・クロード | Organosilane precursor for ALD / CVD silicon-containing films |
US9558931B2 (en) | 2012-07-27 | 2017-01-31 | Asm Ip Holding B.V. | System and method for gas-phase sulfur passivation of a semiconductor surface |
US9117866B2 (en) | 2012-07-31 | 2015-08-25 | Asm Ip Holding B.V. | Apparatus and method for calculating a wafer position in a processing chamber under process conditions |
US8911826B2 (en) | 2012-08-02 | 2014-12-16 | Asm Ip Holding B.V. | Method of parallel shift operation of multiple reactors |
US8664627B1 (en) | 2012-08-08 | 2014-03-04 | Asm Ip Holding B.V. | Method for supplying gas with flow rate gradient over substrate |
US8912070B2 (en) | 2012-08-16 | 2014-12-16 | The Institute of Microelectronics Chinese Academy of Science | Method for manufacturing semiconductor device |
US9169975B2 (en) | 2012-08-28 | 2015-10-27 | Asm Ip Holding B.V. | Systems and methods for mass flow controller verification |
US9659799B2 (en) | 2012-08-28 | 2017-05-23 | Asm Ip Holding B.V. | Systems and methods for dynamic semiconductor process scheduling |
US8742668B2 (en) | 2012-09-05 | 2014-06-03 | Asm Ip Holdings B.V. | Method for stabilizing plasma ignition |
CN104603914B (en) | 2012-09-07 | 2017-07-14 | 应用材料公司 | The integrated processing of porous dielectric, polymer-coated substrate and epoxides in multi-chamber vacuum system |
US9021985B2 (en) | 2012-09-12 | 2015-05-05 | Asm Ip Holdings B.V. | Process gas management for an inductively-coupled plasma deposition reactor |
US20140077240A1 (en) | 2012-09-17 | 2014-03-20 | Radek Roucka | Iv material photonic device on dbr |
US8921207B2 (en) | 2012-09-24 | 2014-12-30 | Asm Ip Holding B.V., Inc. | Tin precursors for vapor deposition and deposition processes |
US9324811B2 (en) | 2012-09-26 | 2016-04-26 | Asm Ip Holding B.V. | Structures and devices including a tensile-stressed silicon arsenic layer and methods of forming same |
JP6042160B2 (en) | 2012-10-03 | 2016-12-14 | 東京エレクトロン株式会社 | Film forming method and film forming apparatus |
US9353441B2 (en) | 2012-10-05 | 2016-05-31 | Asm Ip Holding B.V. | Heating/cooling pedestal for semiconductor-processing apparatus |
US20140099798A1 (en) | 2012-10-05 | 2014-04-10 | Asm Ip Holding B.V. | UV-Curing Apparatus Provided With Wavelength-Tuned Excimer Lamp and Method of Processing Semiconductor Substrate Using Same |
US10714315B2 (en) | 2012-10-12 | 2020-07-14 | Asm Ip Holdings B.V. | Semiconductor reaction chamber showerhead |
JP2014086472A (en) | 2012-10-19 | 2014-05-12 | Sinfonia Technology Co Ltd | Clamp device and workpiece conveyer robot |
US20140116335A1 (en) | 2012-10-31 | 2014-05-01 | Asm Ip Holding B.V. | UV Irradiation Apparatus with Cleaning Mechanism and Method for Cleaning UV Irradiation Apparatus |
JP5960028B2 (en) | 2012-10-31 | 2016-08-02 | 東京エレクトロン株式会社 | Heat treatment equipment |
US9105587B2 (en) | 2012-11-08 | 2015-08-11 | Micron Technology, Inc. | Methods of forming semiconductor structures with sulfur dioxide etch chemistries |
US8784951B2 (en) | 2012-11-16 | 2014-07-22 | Asm Ip Holding B.V. | Method for forming insulation film using non-halide precursor having four or more silicons |
US9640416B2 (en) | 2012-12-26 | 2017-05-02 | Asm Ip Holding B.V. | Single-and dual-chamber module-attachable wafer-handling chamber |
US20140182053A1 (en) | 2012-12-29 | 2014-07-03 | Alexander Yeh Industry Co., Ltd. | Pullable drain plug |
US9018093B2 (en) | 2013-01-25 | 2015-04-28 | Asm Ip Holding B.V. | Method for forming layer constituted by repeated stacked layers |
US8894870B2 (en) | 2013-02-01 | 2014-11-25 | Asm Ip Holding B.V. | Multi-step method and apparatus for etching compounds containing a metal |
KR20140102782A (en) | 2013-02-14 | 2014-08-25 | 삼성전자주식회사 | Blade for transferring wafer and wafer transferring apparatus having the same |
US8790743B1 (en) | 2013-03-04 | 2014-07-29 | Asm Ip Holding B.V. | Method for controlling cyclic plasma-assisted process |
US9589770B2 (en) | 2013-03-08 | 2017-03-07 | Asm Ip Holding B.V. | Method and systems for in-situ formation of intermediate reactive species |
US9484191B2 (en) | 2013-03-08 | 2016-11-01 | Asm Ip Holding B.V. | Pulsed remote plasma method and system |
USD723153S1 (en) | 2013-03-08 | 2015-02-24 | Olen Borkholder | Recess ceiling fan bezel |
US8841182B1 (en) | 2013-03-14 | 2014-09-23 | Asm Ip Holding B.V. | Silane and borane treatments for titanium carbide films |
US9666702B2 (en) | 2013-03-15 | 2017-05-30 | Matthew H. Kim | Advanced heterojunction devices and methods of manufacturing advanced heterojunction devices |
JP6096547B2 (en) | 2013-03-21 | 2017-03-15 | 東京エレクトロン株式会社 | Plasma processing apparatus and shower plate |
USD734377S1 (en) | 2013-03-28 | 2015-07-14 | Hirata Corporation | Top cover of a load lock chamber |
US8864202B1 (en) | 2013-04-12 | 2014-10-21 | Varian Semiconductor Equipment Associates, Inc. | Spring retained end effector contact pad |
US9142393B2 (en) | 2013-05-23 | 2015-09-22 | Asm Ip Holding B.V. | Method for cleaning reaction chamber using pre-cleaning process |
US9365924B2 (en) | 2013-05-23 | 2016-06-14 | Asm Ip Holding B.V. | Method for forming film by plasma-assisted deposition using two-frequency combined pulsed RF power |
USD726365S1 (en) | 2013-05-29 | 2015-04-07 | Sis Resources Ltd. | Mouthpiece plug for electronic cigarette |
US9245740B2 (en) | 2013-06-07 | 2016-01-26 | Dnf Co., Ltd. | Amino-silyl amine compound, method for preparing the same and silicon-containing thin-film using the same |
US9117657B2 (en) | 2013-06-07 | 2015-08-25 | Asm Ip Holding B.V. | Method for filling recesses using pre-treatment with hydrocarbon-containing gas |
US9123510B2 (en) | 2013-06-12 | 2015-09-01 | ASM IP Holding, B.V. | Method for controlling in-plane uniformity of substrate processed by plasma-assisted process |
US20140367043A1 (en) | 2013-06-17 | 2014-12-18 | Applied Materials, Inc. | Method for fast and repeatable plasma ignition and tuning in plasma chambers |
US10036089B2 (en) | 2013-06-26 | 2018-07-31 | Applied Materials, Inc. | Methods of depositing a metal alloy film |
US9677176B2 (en) | 2013-07-03 | 2017-06-13 | Novellus Systems, Inc. | Multi-plenum, dual-temperature showerhead |
JP5861676B2 (en) | 2013-07-08 | 2016-02-16 | 株式会社安川電機 | Adsorption structure, robot hand and robot |
USD705745S1 (en) | 2013-07-08 | 2014-05-27 | Witricity Corporation | Printed resonator coil |
US8940646B1 (en) | 2013-07-12 | 2015-01-27 | Lam Research Corporation | Sequential precursor dosing in an ALD multi-station/batch reactor |
US8993054B2 (en) | 2013-07-12 | 2015-03-31 | Asm Ip Holding B.V. | Method and system to reduce outgassing in a reaction chamber |
US9018111B2 (en) | 2013-07-22 | 2015-04-28 | Asm Ip Holding B.V. | Semiconductor reaction chamber with plasma capabilities |
US9396934B2 (en) | 2013-08-14 | 2016-07-19 | Asm Ip Holding B.V. | Methods of forming films including germanium tin and structures and devices including the films |
US9190263B2 (en) | 2013-08-22 | 2015-11-17 | Asm Ip Holding B.V. | Method for forming SiOCH film using organoaminosilane annealing |
US9136108B2 (en) | 2013-09-04 | 2015-09-15 | Asm Ip Holding B.V. | Method for restoring porous surface of dielectric layer by UV light-assisted ALD |
USD716742S1 (en) | 2013-09-13 | 2014-11-04 | Asm Ip Holding B.V. | Substrate supporter for semiconductor deposition apparatus |
USD724553S1 (en) | 2013-09-13 | 2015-03-17 | Asm Ip Holding B.V. | Substrate supporter for semiconductor deposition apparatus |
US10312127B2 (en) | 2013-09-16 | 2019-06-04 | Applied Materials, Inc. | Compliant robot blade for defect reduction |
US9202738B2 (en) | 2013-09-26 | 2015-12-01 | Applied Materials, Inc. | Pneumatic end effector apparatus and substrate transportation systems with annular flow channel |
US9240412B2 (en) | 2013-09-27 | 2016-01-19 | Asm Ip Holding B.V. | Semiconductor structure and device and methods of forming same using selective epitaxial process |
US9556516B2 (en) | 2013-10-09 | 2017-01-31 | ASM IP Holding B.V | Method for forming Ti-containing film by PEALD using TDMAT or TDEAT |
US9029272B1 (en) | 2013-10-31 | 2015-05-12 | Asm Ip Holding B.V. | Method for treating SiOCH film with hydrogen plasma |
USD739222S1 (en) | 2013-11-13 | 2015-09-22 | Jeff Chadbourne | Two-piece magnetic clamp |
US9605343B2 (en) | 2013-11-13 | 2017-03-28 | Asm Ip Holding B.V. | Method for forming conformal carbon films, structures conformal carbon film, and system of forming same |
US10179947B2 (en) | 2013-11-26 | 2019-01-15 | Asm Ip Holding B.V. | Method for forming conformal nitrided, oxidized, or carbonized dielectric film by atomic layer deposition |
US10431489B2 (en) | 2013-12-17 | 2019-10-01 | Applied Materials, Inc. | Substrate support apparatus having reduced substrate particle generation |
US9698035B2 (en) | 2013-12-23 | 2017-07-04 | Lam Research Corporation | Microstructures for improved wafer handling |
USD724701S1 (en) | 2014-02-04 | 2015-03-17 | ASM IP Holding, B.V. | Shower plate |
USD726884S1 (en) | 2014-02-04 | 2015-04-14 | Asm Ip Holding B.V. | Heater block |
USD720838S1 (en) | 2014-02-04 | 2015-01-06 | Asm Ip Holding B.V. | Shower plate |
US9370863B2 (en) | 2014-02-04 | 2016-06-21 | Asm Ip Holding B.V. | Anti-slip end-effector for transporting workpiece |
USD732644S1 (en) | 2014-02-04 | 2015-06-23 | Asm Ip Holding B.V. | Top plate |
USD725168S1 (en) | 2014-02-04 | 2015-03-24 | Asm Ip Holding B.V. | Heater block |
USD732145S1 (en) | 2014-02-04 | 2015-06-16 | Asm Ip Holding B.V. | Shower plate |
US10683571B2 (en) | 2014-02-25 | 2020-06-16 | Asm Ip Holding B.V. | Gas supply manifold and method of supplying gases to chamber using same |
US9447498B2 (en) | 2014-03-18 | 2016-09-20 | Asm Ip Holding B.V. | Method for performing uniform processing in gas system-sharing multiple reaction chambers |
US10167557B2 (en) | 2014-03-18 | 2019-01-01 | Asm Ip Holding B.V. | Gas distribution system, reactor including the system, and methods of using the same |
US20150267295A1 (en) | 2014-03-19 | 2015-09-24 | Asm Ip Holding B.V. | Removable substrate tray and assembly and reactor including same |
US11015245B2 (en) | 2014-03-19 | 2021-05-25 | Asm Ip Holding B.V. | Gas-phase reactor and system having exhaust plenum and components thereof |
US9343350B2 (en) | 2014-04-03 | 2016-05-17 | Asm Ip Holding B.V. | Anti-slip end effector for transporting workpiece using van der waals force |
US9663857B2 (en) | 2014-04-07 | 2017-05-30 | Asm Ip Holding B.V. | Method for stabilizing reaction chamber pressure |
US9404587B2 (en) | 2014-04-24 | 2016-08-02 | ASM IP Holding B.V | Lockout tagout for semiconductor vacuum valve |
US9464352B2 (en) | 2014-05-02 | 2016-10-11 | Asm Ip Holding B.V. | Low-oxidation plasma-assisted process |
TWI518751B (en) | 2014-05-14 | 2016-01-21 | 國立清華大學 | A carrier channel with gradient distributing element concentration |
USD743513S1 (en) | 2014-06-13 | 2015-11-17 | Asm Ip Holding B.V. | Seal ring |
US10858737B2 (en) | 2014-07-28 | 2020-12-08 | Asm Ip Holding B.V. | Showerhead assembly and components thereof |
US9890456B2 (en) | 2014-08-21 | 2018-02-13 | Asm Ip Holding B.V. | Method and system for in situ formation of gas-phase compounds |
-
2013
- 2013-10-09 US US14/050,150 patent/US9556516B2/en active Active
-
2014
- 2014-10-03 TW TW103134537A patent/TWI625414B/en active
- 2014-10-06 JP JP2014205548A patent/JP6472203B2/en active Active
- 2014-10-08 KR KR1020140136089A patent/KR102332870B1/en active IP Right Grant
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20020064598A1 (en) * | 1999-06-11 | 2002-05-30 | Shulin Wang | Method of depositing a thick titanium nitride film |
US20030143328A1 (en) * | 2002-01-26 | 2003-07-31 | Applied Materials, Inc. | Apparatus and method for plasma assisted deposition |
US20060032443A1 (en) * | 2004-07-28 | 2006-02-16 | Kazuhide Hasebe | Film formation method and apparatus for semiconductor process |
KR20100015073A (en) * | 2008-08-04 | 2010-02-12 | 한국과학기술원 | Method for manufacturing thin film transistors based on titanium oxides as active layer and thin film transistors thereof |
US20100032842A1 (en) * | 2008-08-07 | 2010-02-11 | Texas Instruments Incorporated | MODULATED DEPOSITION PROCESS FOR STRESS CONTROL IN THICK TiN FILMS |
JP2010258413A (en) * | 2009-04-01 | 2010-11-11 | Elpida Memory Inc | Method of manufacturing capacitive insulating film for capacitor |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20180010323A (en) * | 2015-06-18 | 2018-01-30 | 어플라이드 머티어리얼스, 인코포레이티드 | Deposition methods for uniform and conformal hybrid titanium oxide films |
WO2021030332A1 (en) * | 2019-08-13 | 2021-02-18 | Applied Materials, Inc. | Peald titanium nitride with direct microwave plasma |
US11823870B2 (en) | 2019-08-13 | 2023-11-21 | Applied Materials, Inc. | PEALD titanium nitride with direct microwave plasma |
Also Published As
Publication number | Publication date |
---|---|
TWI625414B (en) | 2018-06-01 |
JP6472203B2 (en) | 2019-02-20 |
US9556516B2 (en) | 2017-01-31 |
US20150099072A1 (en) | 2015-04-09 |
KR102332870B1 (en) | 2021-11-29 |
TW201527579A (en) | 2015-07-16 |
JP2015074831A (en) | 2015-04-20 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
KR102332870B1 (en) | Method for forming ti-containing film by peald using tdmat or tdeat | |
KR102602311B1 (en) | NbMC LAYERS | |
TWI756350B (en) | Method for depositing oxide film by thermal ald and peald | |
KR102541097B1 (en) | Method for depositing metal-containing film using particle-reduction step | |
KR102373917B1 (en) | Method for forming conformal nitrided, oxidized, or carbonized dielectric film by atomic layer deposition | |
CN107313027B (en) | Multi-component coating composition, method of forming the same, and semiconductor process chamber component | |
TWI713551B (en) | Method for forming aluminum nitride-based film by peald | |
TWI780541B (en) | Atomic layer deposition process and fluoride thin film | |
KR102013927B1 (en) | Deposition of smooth metal nitride films | |
KR20180116761A (en) | Method of Plasma-Assisted Cyclic Deposition Using Ramp-Down Flow of Reactant Gas | |
KR20170044602A (en) | Method for depositing dielectric film in trenches by PEALD | |
US20150162185A1 (en) | Atomic layer deposition of silicon carbon nitride based materials | |
TW201809333A (en) | Processes and methods for selective deposition on first surface of substrate relative to second surface of substrate | |
TWI737612B (en) | Deposition methods for uniform and conformal hybrid titanium oxide films | |
JP2007051327A (en) | Film deposition method | |
US11667575B2 (en) | Erosion resistant metal oxide coatings | |
JP7405572B2 (en) | Method of forming oxynitride film | |
US20230139917A1 (en) | Selective deposition using thermal and plasma-enhanced process | |
US20230395372A1 (en) | Method and system for forming patterned structures using multiple patterning process | |
US20230227965A1 (en) | Method and apparatus for forming a patterned structure on a substrate | |
JP2020172704A (en) | Selective deposition of metal oxide on metal surface | |
KR20230062782A (en) | Selective deposition of material comprising silicon and oxygen using plasma | |
TW202132600A (en) | Method for etching or deposition | |
KR20070038294A (en) | Method of depositing an atomic layer |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A201 | Request for examination | ||
E902 | Notification of reason for refusal | ||
E701 | Decision to grant or registration of patent right | ||
GRNT | Written decision to grant |