JP6458156B2 - プラズマ処理方法 - Google Patents
プラズマ処理方法 Download PDFInfo
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- JP6458156B2 JP6458156B2 JP2017538254A JP2017538254A JP6458156B2 JP 6458156 B2 JP6458156 B2 JP 6458156B2 JP 2017538254 A JP2017538254 A JP 2017538254A JP 2017538254 A JP2017538254 A JP 2017538254A JP 6458156 B2 JP6458156 B2 JP 6458156B2
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- 238000003672 processing method Methods 0.000 title claims description 19
- 239000007789 gas Substances 0.000 claims description 209
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 23
- 229910052796 boron Inorganic materials 0.000 claims description 22
- 229910003481 amorphous carbon Inorganic materials 0.000 claims description 20
- 239000011737 fluorine Substances 0.000 claims description 20
- 229910052731 fluorine Inorganic materials 0.000 claims description 20
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 18
- 229910052736 halogen Inorganic materials 0.000 claims description 14
- 150000002367 halogens Chemical class 0.000 claims description 14
- 238000001020 plasma etching Methods 0.000 claims description 10
- ABTOQLMXBSRXSM-UHFFFAOYSA-N silicon tetrafluoride Chemical compound F[Si](F)(F)F ABTOQLMXBSRXSM-UHFFFAOYSA-N 0.000 claims description 9
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 8
- 229910001882 dioxygen Inorganic materials 0.000 claims description 8
- 238000005530 etching Methods 0.000 description 43
- 238000000034 method Methods 0.000 description 19
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 17
- 229910052710 silicon Inorganic materials 0.000 description 17
- 239000010703 silicon Substances 0.000 description 17
- 239000000654 additive Substances 0.000 description 12
- 230000000996 additive effect Effects 0.000 description 12
- 230000008569 process Effects 0.000 description 10
- VXEGSRKPIUDPQT-UHFFFAOYSA-N 4-[4-(4-methoxyphenyl)piperazin-1-yl]aniline Chemical compound C1=CC(OC)=CC=C1N1CCN(C=2C=CC(N)=CC=2)CC1 VXEGSRKPIUDPQT-UHFFFAOYSA-N 0.000 description 7
- 229910003902 SiCl 4 Inorganic materials 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 239000005049 silicon tetrachloride Substances 0.000 description 7
- 229920002120 photoresistant polymer Polymers 0.000 description 6
- 229910052814 silicon oxide Inorganic materials 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 238000001312 dry etching Methods 0.000 description 5
- 239000011261 inert gas Substances 0.000 description 5
- 230000008859 change Effects 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 3
- 229920005591 polysilicon Polymers 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- 230000005856 abnormality Effects 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910015900 BF3 Inorganic materials 0.000 description 1
- 239000004178 amaranth Substances 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052810 boron oxide Inorganic materials 0.000 description 1
- WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 238000009616 inductively coupled plasma Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- -1 silicon oxide compound Chemical class 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
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- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
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- H01L21/306—Chemical or electrical treatment, e.g. electrolytic etching
- H01L21/3065—Plasma etching; Reactive-ion etching
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- H01J37/32—Gas-filled discharge tubes
- H01J37/32009—Arrangements for generation of plasma specially adapted for examination or treatment of objects, e.g. plasma sources
- H01J37/32082—Radio frequency generated discharge
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- H01L21/02107—Forming insulating materials on a substrate
- H01L21/02109—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates
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- H01L21/027—Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34
- H01L21/0271—Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34 comprising organic layers
- H01L21/0273—Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34 comprising organic layers characterised by the treatment of photoresist layers
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- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/31—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
- H01L21/3105—After-treatment
- H01L21/311—Etching the insulating layers by chemical or physical means
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- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
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- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
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- H05H—PLASMA TECHNIQUE; PRODUCTION OF ACCELERATED ELECTRICALLY-CHARGED PARTICLES OR OF NEUTRONS; PRODUCTION OR ACCELERATION OF NEUTRAL MOLECULAR OR ATOMIC BEAMS
- H05H1/00—Generating plasma; Handling plasma
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- Chemical & Material Sciences (AREA)
- Plasma & Fusion (AREA)
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- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
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Description
102:ウェハ
103:試料台
104:第一の整合器
105:バイアス印加用の高周波電源
106:直流電源
107:温調ユニット
108:アンテナ
109:第二の整合器
110:プラズマ生成用の高周波電源
111:ソレノイドコイル
112:シャワープレート
113:内側ガス供給路
114:外側ガス供給路
115:メインガス系統
116:内側添加ガス系統
117:外側添加ガス系統
118:流量制御器A
119:流量制御器B
120:流量制御器C
121a:流量制御器D
121b:流量制御器D
121c:流量制御器D
122a:流量制御器E
122b:流量制御器E
123:ストップバルブ
124:ガス分流器
201:シリコン酸化膜とポリシリコン膜のペア層
202:B−Doped ACL膜
203:シリコン酸窒化膜
204:反射防止膜
205:フォトレジスト膜
301:サイドエッチ
302:ボーイング
303:エッチストップ
304:ファセッティング
Claims (7)
- ホウ素が含有されたアモルファスカーボン膜を有する積層膜をプラズマエッチングすることによりマスクを形成するプラズマ処理方法において、
酸素ガスとフッ素含有ガスとハロゲンガスと四フッ化シリコンガスの混合ガスを用いて前記ホウ素が含有されたアモルファスカーボン膜をプラズマエッチングすることを特徴とするプラズマ処理方法。 - 請求項1に記載のプラズマ処理方法において、
前記フッ素含有ガスは、CHF3ガス、CH2F2ガス、CH3Fガス、NF3ガス、CF4ガスまたはSF6ガスであり、
前記ハロゲンガスは、Cl2ガス、HBrガスまたはHIガスであることを特徴とするプラズマ処理方法。 - 請求項1に記載のプラズマ処理方法において、
前記混合ガスに対する前記ハロゲンガスの流量比率は、前記混合ガスに対する前記フッ素含有ガスの流量比率より高いことを特徴とするプラズマ処理方法。 - 請求項1に記載のプラズマ処理方法において、
前記積層膜が成膜された試料を載置する試料台に1000W以上の高周波電力を供給するまたは前記試料台に1350V以上のピーク間高周波電圧を印加することにより前記ホウ素が含有されたアモルファスカーボン膜をプラズマエッチングすることを特徴とするプラズマ処理方法。 - 請求項1ないし請求項4のいずれか一項に記載のプラズマ処理方法において、
圧力を4Pa以上として前記ホウ素が含有されたアモルファスカーボン膜をプラズマエッチングすることを特徴とするプラズマ処理方法。 - 請求項1に記載のプラズマ処理方法において、
O2ガスとCHF3ガスとCl2ガスとSiF 4ガスの混合ガスを用いて前記ホウ素が含有されたアモルファスカーボン膜をプラズマエッチングすることを特徴とするプラズマ処理方法。 - アモルファスカーボン膜を有する積層膜をプラズマエッチングすることによりマスクを形成するプラズマ処理方法において、
酸素ガスとフッ素含有ガスとハロゲンガスと四フッ化シリコンガスの混合ガスを用いて前記アモルファスカーボン膜をプラズマエッチングすることを特徴とするプラズマ処理方法。
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JP2016062977 | 2016-03-28 | ||
JP2016062977 | 2016-03-28 | ||
PCT/JP2017/003258 WO2017154407A1 (ja) | 2016-03-28 | 2017-01-31 | プラズマ処理方法およびプラズマ処理装置 |
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JP2018119547A Division JP6580215B2 (ja) | 2016-03-28 | 2018-06-25 | プラズマ処理方法 |
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JPWO2017154407A1 JPWO2017154407A1 (ja) | 2018-03-15 |
JP6458156B2 true JP6458156B2 (ja) | 2019-01-23 |
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JP2017538254A Active JP6458156B2 (ja) | 2016-03-28 | 2017-01-31 | プラズマ処理方法 |
JP2018119547A Active JP6580215B2 (ja) | 2016-03-28 | 2018-06-25 | プラズマ処理方法 |
JP2019129708A Active JP6734973B2 (ja) | 2016-03-28 | 2019-07-12 | プラズマ処理方法 |
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Country Status (6)
Country | Link |
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US (1) | US10157750B2 (ja) |
JP (3) | JP6458156B2 (ja) |
KR (3) | KR101990332B1 (ja) |
CN (2) | CN107438892B (ja) |
TW (2) | TWI638406B (ja) |
WO (1) | WO2017154407A1 (ja) |
Families Citing this family (296)
Publication number | Priority date | Publication date | Assignee | Title |
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