JP5143421B2 - 電子構成部品の製造方法 - Google Patents
電子構成部品の製造方法 Download PDFInfo
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- JP5143421B2 JP5143421B2 JP2006523187A JP2006523187A JP5143421B2 JP 5143421 B2 JP5143421 B2 JP 5143421B2 JP 2006523187 A JP2006523187 A JP 2006523187A JP 2006523187 A JP2006523187 A JP 2006523187A JP 5143421 B2 JP5143421 B2 JP 5143421B2
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- URDOJQUSEUXVRP-UHFFFAOYSA-N 3-triethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CCO[Si](OCC)(OCC)CCCOC(=O)C(C)=C URDOJQUSEUXVRP-UHFFFAOYSA-N 0.000 claims 1
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Description
ポリオルガノシロキサンエラストマー、例えばポリジメチルシロキサンベースのエラストマーは、それらの熱安定性及び広範な熱範囲に亘って応力を軽減する能力といったような特性のために、エレクロトニクス産業において頻繁に使用される。しかしながら、これらポリオルガノシロキサンエラストマーは、いくつかの有機化学物質、例えば溶媒及びエンジン油に対する耐性不良という欠点を有し得る。
本発明は、(1)電子基板上に組成物を塗布する工程、(2)電子部品を組成物に取り付ける工程、及び(3)組成物を硬化させて電子部品を電子基板に接着する工程を含み、任意で(4)上記工程(1)〜(3)を反復して、1つ又は複数の付加的電子部品を取り付ける工程を含む、電子構成部品を製造する方法であって、
前記組成物が、以下の:
(I)1分子当たり平均で少なくとも2つの不飽和有機基を有するポリオルガノシロキサン、
任意に、(II)1分子当たり平均で少なくとも2つのケイ素結合水素原子を有する有機水素ポリシロキサン、
(III)ヒドロシリル化触媒、
(IV)フルオロオルガノシリコーン、及び
(V)接着促進剤
を含む構成成分を混合することにより調製される、電子構成部品を製造する方法に関する。
量、比率及びパーセンテージは全て、別記しない限り重量単位である。以下は、本明細書中で用いる場合の定義の一覧である。
(I)1分子当たり平均で少なくとも2つの不飽和有機基を有するポリオルガノシロキサン(但し、構成成分(I)はフッ素原子を含有しない)、
任意に、(II)1分子当たり平均で少なくとも2つのケイ素結合水素原子を有する有機水素ポリシロキサン(但し、構成成分(II)はフッ素原子を含有しない)、
(III)ヒドロシリル化触媒、
(IV)フルオロオルガノシリコーン(但し、i)構成成分(IV)は、構成成分(I)、構成成分(II)又はそれらの両方と反応性である少なくとも1つの官能基を有し、且つii)構成成分(II)が存在しないとき、構成成分(IV)は1分子当たり平均で少なくとも2つのケイ素結合水素原子を有し、且つ)及び
(V)接着促進剤
を含む構成成分を混合することにより調製される組成物に関する。
構成成分(I)は、1分子当たり平均で少なくとも2つの不飽和有機基を有するポリオルガノシロキサンである。構成成分(I)は、線状、分岐状又は樹脂状構造を有してもよい。構成成分(I)は、ホモポリマー又はコポリマーであってもよい。不飽和有機基は2〜12個の炭素原子を有するアルケニル基であってもよく、例としてはビニル、アリル、ブテニル及びヘキセニルが挙げられるが、これらに限定されない。不飽和有機基は2〜12個の炭素原子を有するアルキニル基であってもよく、例としてはエチニル、プロピニル及びブチニルが挙げられるが、これらに限定されない。あるいは、不飽和有機基はアクリレート官能基又はメタクリレート官能基を含有してもよく、例としてはアクリロイルオキシアルキル、例えばアクリロイルオキシプロピル及びメタクリロイルオキシアルキル、例えばメタクリロイルオキシプロピルが挙げられるが、これらに限定されない。構成成分(I)中の不飽和有機基は、末端基位置、側基位置又は末端基位置及び側基位置の両方に位置してもよい。
(a)R1 3SiO(R1 2SiO)α(R1R2SiO)βSiR1 3、
(b)R3 2R4SiO(R3 2SiO)χ(R3R4SiO)δSiR3 2R4、又は
(c)それらの組合せ
のポリオルガノシロキサンを含んでもよい。
i)ジメチルビニルシロキシ末端ポリジメチルシロキサン、
ii)ジメチルビニルシロキシ末端ポリ(ジメチルシロキサン/メチルビニルシロキサン)、
iii)ジメチルビニルシロキシ末端ポリメチルビニルシロキサン、
iv)トリメチルシロキシ末端ポリ(ジメチルシロキサン/メチルビニルシロキサン)、
v)トリメチルシロキシ末端ポリメチルビニルシロキサン、
vi)ジメチルビニルシロキシ末端ポリ(ジメチルシロキサン/メチルフェニルシロキサン)、
vii)ジメチルビニルシロキシ末端ポリ(ジメチルシロキサン/ジフェニルシロキサン)、
viii)フェニル、メチル、ビニル−シロキシ末端ポリジメチルシロキサン、
ix)ジメチル−アクリロイルオキシプロピル−シロキシ末端ポリジメチルシロキサン、
x)ジメチル−メタクリロイルオキシプロピル−シロキシ末端ポリジメチルシロキサン、
xi)ジメチルヘキセニルシロキシ末端ポリジメチルシロキサン、
xii)ジメチルヘキセニルシロキシ末端ポリ(ジメチルシロキサン/メチルヘキセニルシロキサン)、
xiii)ジメチルヘキセニルシロキシ末端ポリメチルヘキセニルシロキサン、
xiv)トリメチルシロキシ末端ポリ(ジメチルシロキサン/メチルヘキセニルシロキサン)、
xv)ジメチルビニルシロキシ末端ポリ(ジメチルシロキサン/メチルシアノプロピルシロキサン)、及び
xvi)それらの組合せ
を含んでもよい。
構成成分(II)は、1分子当たり平均で少なくとも2つのケイ素結合水素原子を有する有機水素ポリシロキサンである。構成成分(II)は、ホモポリマー又はコポリマーであることができる。構成成分(II)は、線状、分岐状、環状又は樹脂性構造を有することができる。構成成分(II)中のケイ素結合水素原子は、末端基位置、側基位置又は末端基位置及び側基位置の両方に位置することができる。構成成分(II)は、フッ素原子を含有しない。
(a)R7 3SiO(R7 2SiO)ε(R7HSiO)φSiR7 3、
(b)R8 2HSiO(R8 2SiO)γ(R8HSiO)ηSiR8 2H、又は
(c)それらの組合せ
の化合物を含んでもよい。
i)ジメチル水素シロキシ末端ポリジメチルシロキサン、
ii)ジメチル水素シロキシ末端ポリ(ジメチルシロキサン/メチル水素シロキサン)、
iii)ジメチル水素シロキシ末端ポリメチル水素シロキサン、
iv)トリメチルシロキシ末端ポリ(ジメチルシロキサン/メチル水素シロキサン)、
v)トリメチルシロキシ末端ポリメチル水素シロキサン、
vi)H(CH3)2SiO1/2単位及びSiO4/2単位から本質的に成る樹脂、及び
vii)それらの組合せ。
構成成分(III)は、ヒドロシリル化触媒である。構成成分(III)は、組成物の重量を基にして、0.1〜1,000ppm、あるいは1〜500ppm、あるいは2〜200、あるいは5〜150ppmの白金族金属の量で組成物に添加される。適切なヒドロシリル化触媒は当該技術分野でよく知られており、市販されている。構成成分(III)は、白金、ロジウム、ルテニウム、パラジウム、オスミウム若しくはイリジウム金属又はその有機金属化合物又はそれらの組合せから選択される白金族金属を含んでもよい。構成成分(III)の例としては、塩化白金酸、塩化白金酸・六水和物、二塩化白金、並びに上記の化合物と低分子量オルガノポリシロキサンとの錯体、又はマトリックス若しくはコアシェル型構造中にマイクロカプセル封入された白金化合物のような化合物が挙げられる。白金と低分子量オルガノポリシロキサンとの錯体としては、白金との1,3−ジエテニル−1,1,3,3−テトラメチルジシロキサン錯体が挙げられる。これらの錯体は、樹脂マトリックス中にマイクロカプセル封入されてもよい。
構成成分(IV)は、構成成分(I)、構成成分(II)又はそれらの両方と反応性である少なくとも1つの官能基を有するフルオロオルガノシリコーンである。構成成分(II)が組成物中に存在しないとき、構成成分(IV)は1分子当たり平均で少なくとも2つのケイ素結合水素原子を有する。構成成分(IV)の粘度は特に制限されるものではないが、構成成分(IV)は、エポキシ基及びアルコキシ基を含有しなくてもよい。構成成分(IV)は、25℃で0.0001〜500Pa・sの粘度を有してもよい。
(a)R9 3SiO(R9 2SiO)ι(R9R10SiO)φSiR9 3、
(b)R11 2R12SiO(R11 2SiO)κ(R11R12SiO)λSiR11 2R12、
(c)F3C(CF2)νR13−Si−[O−Si(R14)2(R15)]3、
(d)R15R14 2SiO1/2単位、CF3(CF2)νR13SiO3/2単位及び任意にSiO4/2単位から本質的に成る樹脂性又は分岐状構造、又は
(e)それらの組合せ
の化合物を含んでもよい。
i)ジメチルビニルシロキシ末端ポリメチル3,3,3−トリフルオロプロピルシロキサン、
ii)ジメチルビニルシロキシ末端ポリ(メチル水素シロキサン/メチル−6,6,6,5,5,4,4,3,3−ノナフルオロヘキシルシロキサン)、
iii)トリメチルシロキシ末端ポリ(メチル水素シロキサン/メチル−6,6,6,5,5,4,4,3,3−ノナフルオロヘキシルシロキサン)、
iv)トリメチルシロキシ末端ポリ(メチル水素シロキサン/メチル−6,6,6,5,5,4,4,3,3−ノナフルオロヘキシルシロキサン)、及び
v)それらの組合せ。
構成成分(V)は、接着促進剤である。構成成分(VI)は、組成物を硬化させることにより調製される硬化シリコーンに接着性を与えるのに十分な量で組成物に添加される。構成成分(IV)及び構成成分(V)は、組成物を硬化させることにより調製される硬化シリコーンに耐ブリード性を提供するのに十分な量で組成物に一緒に添加される。構成成分(V)は、組成物の重量を基にして、0.01〜50重量部、あるいは0.05〜2重量部、あるいは0.5〜1.5重量部の量で組成物に添加されよい。
構成成分(I)〜(V)のほかに、任意の構成成分が組成物に添加されてもよい。適切な任意の構成成分としては、(VI)不飽和エステル官能化合物、(VII)ボイド低減剤、(VIII)顔料、(IX)充填剤、(X)硬化改質剤、(XI)レオロジー改質剤、及びそれらの組合せが挙げられる。
構成成分(VI)は、不飽和エステル官能化合物、すなわちヒドロシリル化を受けることができる、1分子当たり少なくとも1つのエステル基及び1分子当たり少なくとも1つの不飽和基を有する有機化合物である。構成成分(VI)は、以下のものを含んでよい:
構成成分(VII)は、ボイド低減剤である。構成成分(VII)は、ボイドを低減するのに十分な量で組成物に添加される。適切なボイド低減剤は当該技術分野でよく知られており、市販されている(例えばEP0850997A2並びに米国特許第4,273,902号及び同第5,684,060号を参照)。適切なボイド低減剤は、ゼオライト、無水硫酸アルミニウム、分子篩(好ましくは10Å又はそれ未満の孔直径を有する)、多孔質珪藻土、シリカゲル、活性炭、パラジウム化合物、例えばパラジウム金属、炭素又はアルミナ上に支持されるパラジウム金属のような基材、及び有機パラジウム化合物を含むことができる。
構成成分(VIII)は、顔料である。組成物に添加される構成成分(VIII)の量は、選択される顔料の種類に応じる。構成成分(VIII)は、組成物の重量を基にして、0.001%〜30%の量で組成物に添加されてよい。顔料は当該技術分野でよく知られており、市販されている。適切な顔料としては、カーボンブラック、例えばLB−1011Cカーボンブラック(Williams)、酸化クロム顔料、例えばHarcros G−6099、二酸化チタン、例えばDuPontから入手可能なもの、及びUV活性染料、例えばCiba Specialty ChemicalsからUVITEX OBの名称で市販されている(チオフェンジイル)ビス(t−ブチルベンゾキサゾール)が挙げられる。
構成成分(IX)は、充填剤である。組成物に添加される構成成分(IX)の量は、選択される充填剤の種類に応じる。構成成分(IX)は、組成物の重量を基にして、0.1%〜90%の量で組成物に添加されてよい。適切な充填剤としては、強化充填剤、例えばシリカ、チタニア及びそれらの組合せが挙げられる。適切な強化充填剤は当該技術分野でよく知られており、市販されており、例えばU.S. Silica (Berkeley Springs, WV)によりMIN−U−SILの名称で販売されている粉砕シリカ、又はCabot Corporation (Massachusetts)によりCAB−O−SILの名称で販売されているヒュームドシリカが挙げられる。
構成成分(X)は、硬化改質剤である。本発明の組成物の保存寿命若しくは作用時間又はその両方を延長するために、構成成分(X)を添加することができる。組成物の硬化温度を上げるために、構成成分(X)を添加することができる。適切な硬化改質剤は当該技術分野でよく知られており、市販されている。構成成分(X)の例としては、アセチレンアルコール、例えばメチルブチノール、エチニルシクロヘキサノール、ジメチルヘキシノール及びそれらの組合せ;シクロアルケニルシロキサン、例えばメチルビニルシクロシロキサン、例えば1,3,5,7−テトラメチル−1,3,5,7−テトラビニルシクロテトラシロキサン、1,3,5,7−テトラメチル−1,3,5,7−テトラヘキセニルシクロテトラシロキサン及びそれらの組合せ;エン−イン化合物、例えば3−メチル−3−ペンテン−1−イン、3,5−ジメチル−3−ヘキセン−1−イン;トリアゾール、例えばベンゾトリアゾール;ホスフィン;メルカプタン;ヒドラジン;アミン、例えばテトラメチルエチレンジアミン、ジアルキルフマレート、ジアルケニルフマレート、ジアルコキシアルキルフマレート、マレエート及びそれらの組合せが挙げられる。
構成成分(XI)は、レオロジー改質剤である。組成物のチキソトロピー性を変えるために、レオロジー改質剤を添加することができる。構成成分(XI)の例としては、流動制御添加剤;反応性希釈剤;沈降防止剤;アルファ−オレフィン;ヒドロキシル末端シリコーン有機コポリマー、例えばヒドロキシル末端ポリプロピレンオキシド−ジメチルシロキサンコポリマー(これに限定されない);並びにそれらの組合せが挙げられる。
構成成分(XII)は、スペーサーである。スペーサーは、有機粒子、無機粒子又はそれらの組合せを含むことができる。スペーサーは、熱伝導性、導電性又はその両方であることができる。スペーサーは、25μm〜250μmの粒子サイズを有することができる。スペーサーは、単分散ビーズを含むことができる。構成成分(XII)の量は、種々の因子、例えば粒子の分布、組成物の投入中に印加される圧力、投入温度等に応じる。組成物は、構成成分(IX)の一部の他に、又は代わりに添加される15%まで、あるいは5%までの構成成分(XII)を含有することができる。
その他の任意の構成成分は、上記のものの全部又は一部のほかに、又はその代わりに、添加されてもよいが、但し、任意の構成成分は、組成物が硬化して、上記のような改良された耐薬品性を有するシリコーン生成物を生成するのを妨げない。その他の任意の構成成分の例としては、酸受容体;酸化防止剤;安定剤、例えば酸化マグネシウム、水酸化カルシウム、金属塩添加剤、例えばEP0950685A1に開示されたもの、熱安定剤、及び紫外線(UV)安定剤;難燃剤;シリル化剤、例えば4−(トリメチルシリルオキシ)−3−ペンテン−2−オン及びN−(t−ブチルジメチルシリル)−N−メチルトリフルオロアセトアミド;乾燥剤、例えばゼオライト、無水硫酸アルミニウム、分子篩(好ましくは10Å又はそれ未満の孔直径を有する)、多孔質珪藻土、シリカゲル及び活性炭;並びに発泡剤、例えば水、メタノール、エタノール、イソ−プロピルアルコール、ベンジルアルコール、1,4ブタンジオール、1,5ペンタンジオール、1,7ヘプタンジオール及びシラノールが挙げられるが、これらに限定されない。
組成物中の構成成分は、組成物中のケイ素結合水素原子の総量対脂肪族不飽和基のモル比(SiHtot/Vitot)が少なくとも0.3、あるいは少なくとも0.5、あるいは少なくとも0.9、あるいは少なくとも1.0であるよう選択されてよい。SiHtot/Vitotは、5.0まで、あるいは3.0まで、あるいは2.0までであってもよい。理論に制約されることを望まないが、SiHtot/Vitotが低すぎる場合には、組成物は硬化しない可能性があるか、あるいはいくつかの基材に接着しない可能性があると考えられる。
組成物は、一部式組成物又は多部式組成物、例えば二部式組成物であってよい。多部式組成物では、構成成分(II)及び(III)は、別個の部に保存される。構成成分(I)及び(IV)〜(XII)のうちのいずれかを、どちらか又は両方の部に添加することができる。過度の実験をすることなく、各部に対する構成成分を選択する方法を、当業者は知っているであろう。
(I)1分子当たり平均で少なくとも2つの不飽和有機基を有するポリオルガノシロキサン(但し、構成成分(I)はフッ素原子を含有しない)、
(III)ヒドロシリル化触媒、
任意に(IV)フルオロオルガノシリコーン(但し、i)構成成分(IV)は、構成成分(I)、構成成分(II)又はそれらの両方と反応性である少なくとも1つの官能基を有し、且つii)構成成分(II)がキット中に存在しないとき、構成成分(IV)は1分子当たり平均で少なくとも2つのケイ素結合水素原子を有する)、
任意に(V)接着促進剤、
任意に(VI)不飽和エステル官能化合物、
任意に(VII)ボイド低減剤、
任意に(VIII)顔料、
任意に(IX)充填剤、
任意に(X)硬化改質剤、
任意に(XI)レオロジー改質剤、及び
任意に(XII)スペーサー、
そしてB部は、以下を包含する:
任意に(I)1分子当たり平均で少なくとも2つの不飽和有機基を有するポリオルガノシロキサン、
任意に、(II)1分子当たり平均で少なくとも2つのケイ素結合水素原子を有する有機水素ポリシロキサン(この場合、構成成分(II)はフッ素原子を含有しない)、
任意に(IV)フルオロオルガノシリコーン(但し、構成成分(IV)は、構成成分(I)、構成成分(II)又はそれらの両方と反応性である少なくとも1つの官能基を有する)、
任意に(V)接着促進剤、
任意に(VI)不飽和エステル官能化合物、
任意に(VII)ボイド低減剤、
任意に(VIII)顔料、
任意に(IX)充填剤、
任意に(X)硬化改質剤、
任意に(XI)レオロジー改質剤、及び
任意に(XII)スペーサー
但し、
(1)A部及びB部の少なくとも一方は構成成分(IV)を含有し、
(2)A部及びB部の少なくとも一方は構成成分(V)を含有し、且つ
(3)B部は構成成分(II)、(IV)、(V)、(VI)、(VII)、(VIII)、(IX)、(X)、(XI)及び(XII)を含有する。
上記の組成物は、任意の便利な手段により構成成分を混合することによって調製することができる。例えば組成物は、周囲温度で全ての構成成分を混合することにより調製することができる。構成成分(X)が存在する場合、構成成分(X)は構成成分(III)の前に添加されてもよい。
本発明の組成物は、表面又は界面特性又はその両方の改質が所望される一連の用途に関して有用である。例えば上記の組成物は、硬化して、接着剤;電子回路、平坦面、繊維又は小粒子のための保護コーティング;又はガスケット材料を形成する。この組成物の完全硬化又は部分硬化生成物の曝露表面も、別の接着剤による結合のための、又は別の基材への二次結合(例えば乾燥フィルム接着剤)のための基材としても有用であり得る。
(1)プラスチックハウジング上に上記の組成物を塗布すること、
(2)蓋の縁が組成物と接触するように、ハウジング上に蓋を載せること、及び
(3)その組み立て体を硬化させて密封ハウジングを形成すること
を包含する方法により、組み立て工程における電子回路のためのプラスチックハウジング上にプラスチック蓋をぴったり接着させるために用いることができる。
(1)電子回路基板上に上記の組成物を塗布すること、及び
(2)組成物を硬化させて密封回路基板を製造すること
を包含する方法により、電子回路基板を被覆するために用いることができる。
(1)電子基板上に上記の組成物を塗布すること、
(2)半導体ダイを組成物に取り付けること、及び
(3)組成物を硬化させて接合複合体を製造すること
を包含する方法で、ダイ取り付け用途のために用いることができる。
基剤は、次の構成成分:充填剤1、充填剤2、顔料、及びポリマー又は各試料のために選択されたポリマー類を1クオートロスミキサー中で混練することにより調製される。
試料は、参考例1の方法に従って調製される。参考例2〜6に関する成分及び量は表1である。参考例7〜13に関する成分及び量は表2である。24時間後にブリードの範囲が変化%として測定される。結果は表1及び2である。
試料は、参考例1の方法に従って調製される。参考例14〜16に関する成分及び量は表3である。24時間後にブリードの範囲が変化%として測定される。結果は表3である。
Claims (15)
- (1)電子基板上に組成物を塗布する工程、
(2)電子部品を組成物に取り付ける工程、及び
(3)組成物を硬化させて電子部品を電子基板に接着する工程
を含み、任意で(4)上記工程(1)〜(3)を反復して、1つ又は複数の付加的電子部品を取り付ける工程を含む、電子構成部品を製造する方法であって、
前記組成物が、以下の:
(I)1分子当たり平均で少なくとも2つの不飽和有機基を有するポリオルガノシロキサン流体(但し、構成成分(I)はフッ素原子を含有しない)、
任意に、(II)1分子当たり平均で少なくとも2つのケイ素結合水素原子を有する有機水素ポリシロキサン(但し、構成成分(II)はフッ素原子を含有しない)、
(III)ヒドロシリル化触媒、
(IV)以下:
i)ジメチルビニルシロキシ末端ポリメチル3,3,3−トリフルオロプロピルシロキサン、
ii)ジメチルビニルシロキシ末端ポリ(メチル水素シロキサン/メチル−6,6,6,5,5,4,4,3,3−ノナフルオロヘキシルシロキサン)、
iii)トリメチルシロキシ末端ポリ(メチル水素シロキサン/メチル−6,6,6,5,5,4,4,3,3−ノナフルオロヘキシルシロキサン)、又は
iv)それらの組合せ
から成る群から選択され、構成成分(I)の重量を基にして0.01〜100重量部のフルオロオルガノシリコーンであって、
但し、(1)構成成分(IV)は、構成成分(I)、構成成分(II)又はそれらの両方と反応する少なくとも1つの官能基を有し、
(2)構成成分(II)が存在しないとき、構成成分(IV)は1分子当たり平均で少なくとも2つのケイ素結合水素原子を有し、且つ
(3)構成成分(IV)は、組成物の硬化生成物に耐薬品性を提供するのに十分な量で組成物に添加されるフルオロオルガノシリコーン、及び
(V)組成物の重量を基にして0.01〜50重量部の接着促進剤
を含む構成成分を混合することにより調製される、電子構成部品を製造する方法。 - 構成成分(II)が存在し、且つ構成成分(II)は、HR6 2SiO1/2、R6 3SiO1/2、HR6SiO2/2、R6 2SiO2/2、R6SiO3/2、SiO4/2(ここで、R6は、各々独立して、アルキル基、芳香族基及びシアノアルキル基から選択される)又はそれらの組合せから選択されるシロキサン単位を含む請求項1に記載の方法。
- 構成成分(III)は、マイクロカプセル封入ヒドロシリル化触媒を含む請求項1に記載の方法。
- 構成成分(IV)は、トリメチルシロキシ末端ポリ(メチル水素シロキサン/メチル−6,6,6,5,5,4,4,3,3−ノナフルオロヘキシルシロキサン)を含む請求項1に記載の方法。
- 構成成分(V)は、ヒドロキシ末端ポリ(ジメチルシロキサン/メチルビニルシロキサン)と(グリシドキシプロピル)トリメトキシシランとの反応生成物を含む請求項1に記載の方法。
- 構成成分(V)は、遷移金属キレート化合物、アルコキシシラン、アルコキシシランとヒドロキシ官能ポリオルガノシロキサンとの組合せ、又はそれらの組合せを含む請求項1に記載の方法。
- 構成成分(V)は、不飽和アルコキシシラン、エポキシ官能アルコキシシラン、エポキシ官能シロキサン、又はそれらの組合せを含む請求項1に記載の方法。
- 構成成分(V)は、式R28 μSi(OR29)(4-μ)(式中、μは1、2又は3であり、R28は、各々独立して、(i)3−グリシドキシプロピル、(エポキシシクロヘキシル)エチル、(ii)3−メタクリロイルオキシプロピル、3−アクリロイルオキシプロピル、及び(iii)ビニル、アリル、ヘキセニル、ウンデシレニルのうちのいずれか一つから選択されるが、但し、少なくとも1つのR28が(i)又は(ii)から選択され、且つR29は、各々独立して、少なくとも1個の炭素原子を有する非置換飽和炭化水素基である)のアルコキシシランを含む請求項1に記載の方法。
- 構成成分(V)は、3−グリシドキシプロピルトリメトキシシラン、3−グリシドキシプロピルトリエトキシシラン、(エポキシシクロヘキシル)エチルジメトキシシラン、(エポキシシクロヘキシル)エチルジエトキシシラン、ビニルトリメトキシシラン、アリルトリメトキシシラン、アリルトリエトキシシラン、ヘキセニルトリメトキシシラン、ウンデシレニルトリメトキシシラン、3−メタクリロイルオキシプロピルトリメトキシシラン、3−メタクリロイルオキシプロピルトリエトキシシラン、3−アクリロイルオキシプロピルトリメトキシシラン、3−アクリロイルオキシプロピルトリエトキシシラン、又はそれらの組合せを含む請求項1に記載の方法。
- 構成成分(V)は、ヒドロキシ末端ポリオルガノシロキサンとエポキシ官能アルコキシシラン若しくは不飽和アルコキシシランとの反応生成物、又はヒドロキシ末端ポリオルガノシロキサンとエポキシ官能アルコキシシラン若しくは不飽和アルコキシシランとの物理的配合物を含む請求項1に記載の方法。
- 前記組成物が、(VI)不飽和エステル官能化合物、(VII)ボイド低減剤、(VIII)顔料、(IX)充填剤、(X)硬化改質剤、(XI)レオロジー改質剤、(XII)スペーサー、(XIII)酸受容体、(XIV)酸化防止剤、(XV)安定剤、(XVI)難燃剤、(XVII)流動制御添加剤、(XVIII)反応性希釈剤、(XIX)沈降防止剤、(XX)シリル化剤、(XXI)乾燥剤、(XXII)発泡剤、又はそれらの組合せをさらに含む請求項1に記載の方法。
- 前記電子部品が半導体ダイであり、任意で、以下の:
(5)半導体ダイ又は半導体ダイスをワイヤボンディングする工程
(6)清浄化する工程
(7)半導体ダイ又は半導体ダイスを成形化合物でオーバーモールディングする工程、及び
(8)はんだボールを取り付けて、完成パッケージを形成する工程
の1つ以上をさらに含む請求項1に記載の方法。 - 前記電子基板が、エポキシ、ポリカーボネート、ポリ(ブチレンテレフタレート)樹脂、ポリアミド樹脂、ポリアミド樹脂とシンジオタクチックポリスチレンとの配合物、アクリロニトリル−ブタジエン−スチレン、スチレン修飾ポリ(フェニレンオキシド)、ポリ(フェニレンスルフィド)、ビニルエステル、ポリフタルアミド、ポリイミド、ケイ素、アルミニウム、ステンレススチール合金、チタン、銅、ニッケル、銀、金及びそれらの組合せを含む請求項1又は12に記載の方法。
- (1)電子回路のためのプラスチックハウジング上に組成物を塗布する工程、
(2)プラスチック蓋の縁が該組成物と接触するように、該プラスチック蓋を該プラスチックハウジング上に載せる工程、及び
(3)組成物を硬化させて該プラスチック蓋を該プラスチックハウジングに接着する工程
を含み、任意で(4)上記工程(1)〜(3)を反復して、1つ又は複数の付加的電子部品を取り付ける工程を含む、電子構成部品を製造する方法であって、
前記組成物が、以下の:
(I)1分子当たり平均で少なくとも2つの不飽和有機基を有するポリオルガノシロキサン流体(但し、構成成分(I)はフッ素原子を含有しない)、
任意に、(II)1分子当たり平均で少なくとも2つのケイ素結合水素原子を有する有機水素ポリシロキサン(但し、構成成分(II)はフッ素原子を含有しない)、
(III)ヒドロシリル化触媒、
(IV)以下:
i)ジメチルビニルシロキシ末端ポリメチル3,3,3−トリフルオロプロピルシロキサン、
ii)ジメチルビニルシロキシ末端ポリ(メチル水素シロキサン/メチル−6,6,6,5,5,4,4,3,3−ノナフルオロヘキシルシロキサン)、
iii)トリメチルシロキシ末端ポリ(メチル水素シロキサン/メチル−6,6,6,5,5,4,4,3,3−ノナフルオロヘキシルシロキサン)、又は
iv)それらの組合せ
から成る群から選択され、構成成分(I)の重量を基にして0.01〜100重量部のフルオロオルガノシリコーンであって、
但し、(1)構成成分(IV)は、構成成分(I)、構成成分(II)又はそれらの両方と反応する少なくとも1つの官能基を有し、
(2)構成成分(II)が存在しないとき、構成成分(IV)は1分子当たり平均で少なくとも2つのケイ素結合水素原子を有し、且つ
(3)構成成分(IV)は、組成物の硬化生成物に耐薬品性を提供するのに十分な量で組成物に添加されるフルオロオルガノシリコーン、及び
(V)組成物の重量を基にして0.01〜50重量部の接着促進剤
を含む構成成分を混合することにより調製される、電子構成部品を製造する方法。 - (1)電子回路基板上に組成物を塗布する工程、及び
(2)組成物を硬化させて密封回路基板を製造する工程
を含む、電子構成部品を製造する方法であって、
前記組成物が、以下の:
(I)1分子当たり平均で少なくとも2つの不飽和有機基を有するポリオルガノシロキサン流体(但し、構成成分(I)はフッ素原子を含有しない)、
任意に、(II)1分子当たり平均で少なくとも2つのケイ素結合水素原子を有する有機水素ポリシロキサン(但し、構成成分(II)はフッ素原子を含有しない)、
(III)ヒドロシリル化触媒、
(IV)以下:
i)ジメチルビニルシロキシ末端ポリメチル3,3,3−トリフルオロプロピルシロキサン、
ii)ジメチルビニルシロキシ末端ポリ(メチル水素シロキサン/メチル−6,6,6,5,5,4,4,3,3−ノナフルオロヘキシルシロキサン)、
iii)トリメチルシロキシ末端ポリ(メチル水素シロキサン/メチル−6,6,6,5,5,4,4,3,3−ノナフルオロヘキシルシロキサン)、又は
iv)それらの組合せ
から成る群から選択され、構成成分(I)の重量を基にして0.01〜100重量部のフルオロオルガノシリコーンであって、
但し、(1)構成成分(IV)は、構成成分(I)、構成成分(II)又はそれらの両方と反応する少なくとも1つの官能基を有し、
(2)構成成分(II)が存在しないとき、構成成分(IV)は1分子当たり平均で少なくとも2つのケイ素結合水素原子を有し、且つ
(3)構成成分(IV)は、組成物の硬化生成物に耐薬品性を提供するのに十分な量で組成物に添加されるフルオロオルガノシリコーン、及び
(V)組成物の重量を基にして0.01〜50重量部の接着促進剤
を含む構成成分を混合することにより調製される、電子構成部品を製造する方法。
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JP2006523187A Expired - Fee Related JP5143421B2 (ja) | 2003-08-14 | 2004-07-09 | 電子構成部品の製造方法 |
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---|---|
US (2) | US20050038188A1 (ja) |
EP (2) | EP1741755B1 (ja) |
JP (1) | JP5143421B2 (ja) |
KR (1) | KR101074643B1 (ja) |
AT (2) | ATE440914T1 (ja) |
DE (2) | DE602004022873D1 (ja) |
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Families Citing this family (69)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20030168731A1 (en) * | 2002-03-11 | 2003-09-11 | Matayabas James Christopher | Thermal interface material and method of fabricating the same |
US20050038188A1 (en) | 2003-08-14 | 2005-02-17 | Dongchan Ahn | Silicones having improved chemical resistance and curable silicone compositions having improved migration resistance |
US20050038183A1 (en) * | 2003-08-14 | 2005-02-17 | Dongchan Ahn | Silicones having improved surface properties and curable silicone compositions for preparing the silicones |
US7045586B2 (en) | 2003-08-14 | 2006-05-16 | Dow Corning Corporation | Adhesives having improved chemical resistance and curable silicone compositions for preparing the adhesives |
JP2008534032A (ja) * | 2005-02-09 | 2008-08-28 | アンジオダイナミックス,インク. | カテーテル用補強バルーン |
KR100839780B1 (ko) * | 2006-01-18 | 2008-06-19 | 주식회사 엘지화학 | 유연성 기판 반송용 점착제 |
GB0616021D0 (en) * | 2006-08-14 | 2006-09-20 | Dow Corning | Silicone release coating compositions |
US7834083B2 (en) * | 2006-10-11 | 2010-11-16 | Samsung Electro-Mechanics Co., Ltd. | Nanocomposite composition comprising transparent nanoparticles |
WO2008103221A1 (en) * | 2007-02-22 | 2008-08-28 | Dow Corning Corporation | Process for preparing conductive films and articles prepared using the process |
DE102008000517B4 (de) * | 2008-03-05 | 2018-04-26 | Robert Bosch Automotive Steering Gmbh | Verfahren zum druckdichten Fügen eines metallischen Lenkgetriebegehäuses mit einem Kunststoffgehäusedeckel |
GB0814486D0 (en) * | 2008-08-07 | 2008-09-10 | Pyroban Ltd | Thermal barrier for hazardous enviroment |
DE102009002231A1 (de) * | 2009-04-06 | 2010-10-07 | Wacker Chemie Ag | Bei Raumtemperatur selbsthaftende Pt-katalysierte additions-vernetzende Siliconzusammensetzungen |
CN101811890B (zh) * | 2009-12-28 | 2012-09-05 | 河北理工大学 | 耐酸复相陶瓷涂层及其制备方法 |
JP5844252B2 (ja) * | 2010-04-02 | 2016-01-13 | 株式会社カネカ | 硬化性樹脂組成物、硬化性樹脂組成物タブレット、成形体、半導体のパッケージ、半導体部品及び発光ダイオード |
US9993793B2 (en) | 2010-04-28 | 2018-06-12 | The Procter & Gamble Company | Delivery particles |
US9186642B2 (en) | 2010-04-28 | 2015-11-17 | The Procter & Gamble Company | Delivery particle |
CN103619981A (zh) * | 2010-12-22 | 2014-03-05 | 道康宁公司 | 有机硅组合物、有机硅粘合剂、涂布和层合基底 |
WO2012138690A2 (en) | 2011-04-07 | 2012-10-11 | The Procter & Gamble Company | Conditioner compositions with increased deposition of polyacrylate microcapsules |
CN103458859A (zh) | 2011-04-07 | 2013-12-18 | 宝洁公司 | 具有增强的聚丙烯酸酯微胶囊的沉积的个人清洁组合物 |
WO2012138696A2 (en) | 2011-04-07 | 2012-10-11 | The Procter & Gamble Company | Shampoo compositions with increased deposition of polyacrylate microcapsules |
EP2788402A1 (en) | 2011-12-06 | 2014-10-15 | Dow Corning Corporation | Curable silicone composition, cured material, manufactured articles, methods and uses |
CN102516870B (zh) * | 2011-12-21 | 2014-04-02 | 天津灯塔涂料工业发展有限公司 | 铝色环氧有机硅耐热漆及制备方法 |
CN102977607B (zh) * | 2012-12-12 | 2015-09-30 | 黄山市强路新材料有限公司 | 一种阻燃高抗撕液态硅树脂 |
CN102977606A (zh) * | 2012-12-12 | 2013-03-20 | 黄山市强路新材料有限公司 | 一种阻燃高抗撕液态硅树脂的制备方法 |
EP2938679B1 (en) * | 2012-12-28 | 2021-08-18 | Dow Silicones Corporation | Curable organopolysiloxane composition for transducers and applications of such curable silicone composition for transducers |
KR101983010B1 (ko) | 2012-12-28 | 2019-09-10 | 다우 코닝 도레이 캄파니 리미티드 | 변환기용 경화성 유기폴리실록산 조성물 및 그러한 변환기용 경화성 실리콘 조성물의 응용 |
WO2014160067A1 (en) * | 2013-03-14 | 2014-10-02 | Dow Corning Corporation | Thermally curable silicone compositions as temporary bonding adhesives |
TWI535792B (zh) * | 2013-10-24 | 2016-06-01 | 瓦克化學公司 | Led封裝材料 |
GB2530388A (en) * | 2014-07-25 | 2016-03-23 | Dow Corning | Fluoro-silicone compositions as temporary bonding adhesives field of the invention |
JP5956697B1 (ja) * | 2014-12-18 | 2016-07-27 | モメンティブ・パフォーマンス・マテリアルズ・ジャパン合同会社 | 難燃性ポリオルガノシロキサン組成物、難燃性硬化物、光学用部材、光源用レンズまたはカバー、および成形方法 |
DE102015101748A1 (de) | 2015-02-06 | 2016-08-11 | Osram Opto Semiconductors Gmbh | Elektronisches Bauelement mit einem Werkstoff umfassend Epoxysilan-modifiziertes Polyorganosiloxan |
US10147631B2 (en) | 2016-09-26 | 2018-12-04 | Dow Silicones Corporation | Fluoro-silicone compositions as temporary bonding adhesives |
US11008480B2 (en) | 2016-12-23 | 2021-05-18 | Dow (Shanghai) Holding Co., Ltd | Polyorganosiloxane release coating and method for its preparation and use |
EP3645651B1 (en) | 2017-10-19 | 2023-09-06 | Dow Silicones Corporation | A method for fabricating a flexible organic light emitting diode using a pressure sensitive adhesive composition |
US10876019B2 (en) | 2017-10-19 | 2020-12-29 | Dow Silicones Corporation | Polyorganosiloxane compositions containing a 2-substituted-1-alkynyl-1-cyclohexanol useful as a hydrosilylation reaction inhibitor |
CN108586747B (zh) * | 2018-04-11 | 2020-11-06 | 杭州师范大学 | 一种中高苯基含量甲基苯基硅油的制备方法 |
CN109439274B (zh) * | 2018-11-02 | 2020-11-10 | 烟台德邦科技有限公司 | 一种耐油密封胶的制备方法 |
JP7499250B2 (ja) | 2018-12-21 | 2024-06-13 | ダウ シリコーンズ コーポレーション | 多官能性オルガノシロキサン、それを含有する組成物、及びその調製方法 |
CN113056502B (zh) | 2018-12-21 | 2023-01-24 | 美国陶氏有机硅公司 | 多官能有机硅氧烷、包含多官能有机硅氧烷的组合物及其制备方法 |
JP2022515367A (ja) | 2018-12-21 | 2022-02-18 | ダウ シリコーンズ コーポレーション | 多官能性オルガノシロキサンの製造方法及びそれを含有する組成物 |
US11685844B2 (en) | 2019-05-16 | 2023-06-27 | Dow Silicones Corporation | Polysiloxane controlled release additive, method for the preparation thereof, and release coating composition |
JP7323653B2 (ja) * | 2019-07-03 | 2023-08-08 | ダウ シリコーンズ コーポレーション | フルオロシリコーン添加剤を含有するシリコーン感圧接着剤組成物並びにその調製方法及びその使用 |
CN110408031A (zh) * | 2019-07-12 | 2019-11-05 | 湖北大学 | 具有多端官能团的活性支化碳硅烷及其制备方法 |
WO2021031185A1 (en) | 2019-08-22 | 2021-02-25 | Dow Silicones Corporation | Polyorganosiloxane release coating composition |
WO2021061417A1 (en) | 2019-09-26 | 2021-04-01 | Dow Silicones Corporation | Silicone release coating composition and methods for the preparation and use of same |
EP4051748A4 (en) | 2019-10-31 | 2023-08-16 | Dow Silicones Corporation | SILICIONE-BASED PRESSURE-SENSITIVE ADHESIVE COMPOSITION AND METHODS OF PREPARING AND USING IT |
WO2021113058A1 (en) | 2019-12-02 | 2021-06-10 | Dow Silicones Corporation | Composition for preparing a release coating |
CN114761467B (zh) | 2019-12-02 | 2023-05-12 | 美国陶氏有机硅公司 | 用于制备防粘涂料的组合物 |
CN113207295B (zh) | 2019-12-02 | 2022-06-03 | 美国陶氏有机硅公司 | 用于制备防粘涂料的组合物 |
EP4069765B1 (en) | 2019-12-02 | 2023-12-06 | Dow Silicones Corporation | Composition for preparing a release coating |
JP2023508670A (ja) | 2019-12-30 | 2023-03-03 | ダウ シリコーンズ コーポレーション | 感圧接着剤組成物 |
KR20220120673A (ko) | 2019-12-30 | 2022-08-30 | 다우 실리콘즈 코포레이션 | 이형 코팅 제조용 조성물, 이형 코팅 조성물, 및 관련 방법 |
US20230047845A1 (en) | 2019-12-30 | 2023-02-16 | Dow Sillicones Corporation | Composition for preparing a release coating, release coating composition, and related methods |
CN111057242B (zh) * | 2019-12-31 | 2022-08-12 | 惠州市安品新材料有限公司 | 有机硅锚固剂的制备方法和应用 |
EP3874004B1 (en) | 2020-01-15 | 2023-10-11 | Dow Silicones Corporation | Silicone pressure sensitive adhesive composition and methods for the preparation and use thereof |
RU2727373C1 (ru) * | 2020-01-30 | 2020-07-21 | Общество с ограниченной ответственностью "ВЛАДСИЛАН" (ООО "ВЛАДСИЛАН") | Композиция на основе линейно-лестничного силоксанового блок-сополимера для получения защитных покрытий |
WO2021262337A1 (en) | 2020-06-22 | 2021-12-30 | Dow Silicones Corporation | Low intensity radiation curable silicone release coating composition and method for its preparation and use |
WO2021262494A1 (en) | 2020-06-24 | 2021-12-30 | Dow Silicones Corporation | Methods for making polyfunctional organosiloxanes and compositions containing same |
WO2022061795A1 (en) | 2020-09-27 | 2022-03-31 | Dow Silicones Corporation | Additive organopolysiloxane composition, curable composition, and film |
CN116998005A (zh) | 2021-04-09 | 2023-11-03 | 美国陶氏有机硅公司 | 压敏粘合剂组合物及其制备方法和在柔性有机发光二极管应用中的用途 |
CN117178005A (zh) | 2021-05-24 | 2023-12-05 | 美国陶氏有机硅公司 | 用于制备防粘涂料的组合物和制备涂布基底的方法 |
JP7343714B2 (ja) | 2021-07-21 | 2023-09-12 | ダウ グローバル テクノロジーズ エルエルシー | シリコーン感圧接着剤ベースの水性分散液及び分散液の調製及び使用方法 |
CN118318014A (zh) | 2021-12-21 | 2024-07-09 | 美国陶氏有机硅公司 | 离型涂层组合物 |
WO2023146692A1 (en) | 2022-01-26 | 2023-08-03 | Dow Silicones Corporation | Pressure sensitive adhesive composition and methods for its preparation and use in flexible organic light emitting diode applications |
KR20240026214A (ko) | 2022-03-30 | 2024-02-27 | 다우 실리콘즈 코포레이션 | 실리콘 감압성 접착제용 경화성 조성물 |
WO2024006430A1 (en) | 2022-06-30 | 2024-01-04 | Dow Silicones Corporation | Composition for preparing a release coating |
TW202407051A (zh) * | 2022-08-01 | 2024-02-16 | 日商陶氏東麗股份有限公司 | 光擴散性聚矽氧組成物以及光擴散材 |
WO2024108429A1 (en) | 2022-11-23 | 2024-05-30 | Dow Silicones Corporation | Composition for preparing a release coating and method of preparing coated substrate |
CN115746699B (zh) * | 2022-11-24 | 2023-10-31 | 杭州之江有机硅化工有限公司 | 一种透明有机硅涂覆胶组合物及其制备方法和应用 |
Family Cites Families (106)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2676182A (en) * | 1950-09-13 | 1954-04-20 | Dow Corning | Copolymeric siloxanes and methods of preparing them |
US3159601A (en) * | 1962-07-02 | 1964-12-01 | Gen Electric | Platinum-olefin complex catalyzed addition of hydrogen- and alkenyl-substituted siloxanes |
US3220972A (en) * | 1962-07-02 | 1965-11-30 | Gen Electric | Organosilicon process using a chloroplatinic acid reaction product as the catalyst |
US3296291A (en) * | 1962-07-02 | 1967-01-03 | Gen Electric | Reaction of silanes with unsaturated olefinic compounds |
NL131800C (ja) * | 1965-05-17 | |||
NL129346C (ja) * | 1966-06-23 | |||
US3516946A (en) * | 1967-09-29 | 1970-06-23 | Gen Electric | Platinum catalyst composition for hydrosilation reactions |
US3814730A (en) * | 1970-08-06 | 1974-06-04 | Gen Electric | Platinum complexes of unsaturated siloxanes and platinum containing organopolysiloxanes |
US3989667A (en) * | 1974-12-02 | 1976-11-02 | Dow Corning Corporation | Olefinic siloxanes as platinum inhibitors |
US3975362A (en) * | 1975-04-28 | 1976-08-17 | Dow Corning Corporation | Low temperature reversion resistant organosilicon polymers |
US3989668A (en) * | 1975-07-14 | 1976-11-02 | Dow Corning Corporation | Method of making a silicone elastomer and the elastomer prepared thereby |
US4087585A (en) * | 1977-05-23 | 1978-05-02 | Dow Corning Corporation | Self-adhering silicone compositions and preparations thereof |
US4329273A (en) | 1978-03-07 | 1982-05-11 | General Electric Company | Self-bonding silicone rubber compositions |
JPS591241B2 (ja) * | 1978-06-30 | 1984-01-11 | 而至歯科工業株式会社 | 歯科用シリコ−ン組成物およびその使用法 |
US4370358A (en) * | 1980-09-22 | 1983-01-25 | General Electric Company | Ultraviolet curable silicone adhesives |
US4386170A (en) * | 1980-10-31 | 1983-05-31 | Dow Corning Corporation | Curable fluorinated silicone elastomer |
US4348454A (en) * | 1981-03-02 | 1982-09-07 | General Electric Company | Ultraviolet light curable acrylic functional silicone compositions |
US4360610A (en) * | 1981-03-23 | 1982-11-23 | Dow Corning Corporation | Method of improving silicone rubber composition |
US4355121A (en) * | 1981-04-09 | 1982-10-19 | General Electric Company | Heat strength curable silicone rubber compositions |
JPS5945356A (ja) * | 1982-09-08 | 1984-03-14 | Toray Silicone Co Ltd | 導電性シリコ−ンゴム組成物 |
US4492786A (en) * | 1983-08-26 | 1985-01-08 | General Electric Company | Modified organopolysiloxane composition |
US4584355A (en) * | 1984-10-29 | 1986-04-22 | Dow Corning Corporation | Silicone pressure-sensitive adhesive process and product with improved lap-shear stability-I |
US4585836A (en) | 1984-10-29 | 1986-04-29 | Dow Corning Corporation | Silicone pressure-sensitive adhesive process and product with improved lap-shear stability-II |
US4591622A (en) | 1984-10-29 | 1986-05-27 | Dow Corning Corporation | Silicone pressure-sensitive adhesive process and product thereof |
JPS61195129A (ja) | 1985-02-22 | 1986-08-29 | Toray Silicone Co Ltd | 有機けい素重合体の製造方法 |
US4584361A (en) * | 1985-06-03 | 1986-04-22 | Dow Corning Corporation | Storage stable, one part polyorganosiloxane compositions |
JPS6348901A (ja) | 1986-08-19 | 1988-03-01 | Mitsubishi Electric Corp | マイクロ波デバイス |
JPS63205359A (ja) | 1987-02-20 | 1988-08-24 | Shin Etsu Chem Co Ltd | 硬化性フツ素シリコ−ン組成物 |
US4766176A (en) | 1987-07-20 | 1988-08-23 | Dow Corning Corporation | Storage stable heat curable organosiloxane compositions containing microencapsulated platinum-containing catalysts |
US4784879A (en) | 1987-07-20 | 1988-11-15 | Dow Corning Corporation | Method for preparing a microencapsulated compound of a platinum group metal |
JPH0689224B2 (ja) * | 1987-09-11 | 1994-11-09 | ポリプラスチックス株式会社 | 低応力封止材 |
JP2630993B2 (ja) | 1988-06-23 | 1997-07-16 | 東レ・ダウコーニング・シリコーン株式会社 | ヒドロシリル化反応用白金系触媒含有粒状物およびその製造方法 |
JPH0214244A (ja) | 1988-06-30 | 1990-01-18 | Toray Dow Corning Silicone Co Ltd | 加熱硬化性オルガノポリシロキサン組成物 |
US5082706A (en) | 1988-11-23 | 1992-01-21 | Dow Corning Corporation | Pressure sensitive adhesive/release liner laminate |
JP2502714B2 (ja) * | 1988-12-05 | 1996-05-29 | 東芝シリコーン株式会社 | 室温硬化性ポリオルガノシロキサン組成物 |
ATE129267T1 (de) * | 1989-02-02 | 1995-11-15 | Canon Kk | Silikonzusammensetzung, elastischer drehkörper und diesen verwendende fixiervorrichtung. |
JPH02218755A (ja) | 1989-02-20 | 1990-08-31 | Toray Dow Corning Silicone Co Ltd | 硬化性オルガノポリシロキサン組成物 |
JPH02298549A (ja) | 1989-05-12 | 1990-12-10 | Shin Etsu Chem Co Ltd | 接着性組成物 |
US5036117A (en) | 1989-11-03 | 1991-07-30 | Dow Corning Corporation | Heat-curable silicone compositions having improved bath life |
US4946878A (en) * | 1990-01-29 | 1990-08-07 | Dow Corning Corporation | Rapidly curable extrudable organosiloxane compositions |
US5082894A (en) * | 1990-03-19 | 1992-01-21 | Dow Corning Corporation | Storage stable one-part organosiloxane compositions |
JPH07119364B2 (ja) * | 1990-08-03 | 1995-12-20 | 信越化学工業株式会社 | 硬化性シリコーン組成物およびその硬化物 |
US5858468A (en) * | 1990-10-29 | 1999-01-12 | Mcdonnell Douglas Corporation | Chemical resistant coatings |
US5110845A (en) * | 1990-12-03 | 1992-05-05 | Dow Corning Corporation | Extrudable curable organosiloxane compositions |
JPH04222871A (ja) | 1990-12-25 | 1992-08-12 | Toray Dow Corning Silicone Co Ltd | 硬化性オルガノポリシロキサン組成物 |
JP3029680B2 (ja) * | 1991-01-29 | 2000-04-04 | 東レ・ダウコーニング・シリコーン株式会社 | オルガノペンタシロキサンおよびその製造方法 |
JP3270489B2 (ja) | 1991-01-30 | 2002-04-02 | 東レ・ダウコーニング・シリコーン株式会社 | 硬化性オルガノポリシロキサン組成物 |
GB9103191D0 (en) | 1991-02-14 | 1991-04-03 | Dow Corning | Platinum complexes and use thereof |
US5164461A (en) | 1991-03-14 | 1992-11-17 | General Electric Company | Addition-curable silicone adhesive compositions |
US6004679A (en) * | 1991-03-14 | 1999-12-21 | General Electric Company | Laminates containing addition-curable silicone adhesive compositions |
US5302632A (en) * | 1991-04-22 | 1994-04-12 | Dow Corning Corporation | High consistency organosiloxane compositions comprising fluorinated and non-fluorinated polyorganosiloxanes |
JP2511348B2 (ja) * | 1991-10-17 | 1996-06-26 | 東レ・ダウコーニング・シリコーン株式会社 | オルガノポリシロキサンおよびその製造方法 |
JP2753662B2 (ja) * | 1992-03-03 | 1998-05-20 | 信越化学工業株式会社 | 接着剤組成物 |
US5248715A (en) * | 1992-07-30 | 1993-09-28 | Dow Corning Corporation | Self-adhering silicone rubber with low compression set |
JPH07216233A (ja) * | 1992-09-21 | 1995-08-15 | Toray Dow Corning Silicone Co Ltd | フルオロシリコーンゴム組成物 |
US5254623A (en) * | 1992-09-25 | 1993-10-19 | Dow Corning Corporation | Curable fluorinated organosiloxane compositions exhibiting improved adhesion |
JP3378597B2 (ja) | 1992-09-28 | 2003-02-17 | 東レ・ダウコーニング・シリコーン株式会社 | 耐油性シリコーンゴム組成物 |
JPH06145525A (ja) | 1992-11-05 | 1994-05-24 | Toray Dow Corning Silicone Co Ltd | 硬化性オルガノポリシロキサン組成物 |
US5270425A (en) * | 1992-11-23 | 1993-12-14 | Dow Corning Corporation | One-part curable organosiloxane compositions |
JPH0718183A (ja) * | 1993-06-30 | 1995-01-20 | Toray Dow Corning Silicone Co Ltd | 硬化性シリコーン組成物 |
JP3024445B2 (ja) * | 1993-06-30 | 2000-03-21 | 信越化学工業株式会社 | 剥離剤用シリコーン組成物及び剥離紙 |
US5373078A (en) * | 1993-10-29 | 1994-12-13 | Dow Corning Corporation | Low viscosity curable organosiloxane compositions |
JPH07145322A (ja) * | 1993-11-25 | 1995-06-06 | Toray Dow Corning Silicone Co Ltd | 硬化性オルガノポリシロキサン組成物 |
JPH07150044A (ja) * | 1993-11-25 | 1995-06-13 | Toray Dow Corning Silicone Co Ltd | 硬化性ポリマー組成物 |
JP3153089B2 (ja) * | 1993-12-24 | 2001-04-03 | 信越化学工業株式会社 | オルガノポリシロキサン組成物 |
US5447987A (en) * | 1993-12-24 | 1995-09-05 | Shin-Etsu Chemical Co., Ltd. | Organopolysiloxane compositions |
EP0661335A1 (en) | 1993-12-27 | 1995-07-05 | Dow Corning Corporation | Organosiloxane compositions capable of curing against acid-containing solder fluxes |
US5616403A (en) * | 1994-07-11 | 1997-04-01 | General Electric Company | Fluorosilicone coatings |
JPH0873809A (ja) * | 1994-08-31 | 1996-03-19 | Toray Dow Corning Silicone Co Ltd | 剥離性皮膜形成性有機ケイ素重合体組成物 |
DE19526300A1 (de) | 1995-05-19 | 1996-11-21 | Gen Electric | Silicon-Haftkleber hohen Feststoffgehaltes mit verbesserter Überlapp-Scherfestigkeit |
JPH0925415A (ja) * | 1995-07-10 | 1997-01-28 | Nitto Denko Corp | 硬化性含フッ素シリコーン組成物 |
US5595826A (en) * | 1995-10-11 | 1997-01-21 | Dow Corning Corporation | Curable organopolysiloxane compositions with improved adhesion |
GB9526498D0 (en) * | 1995-12-23 | 1996-02-28 | Dow Corning | Silicone release coating compositions |
US5684060A (en) * | 1996-04-09 | 1997-11-04 | Minnesota Mining And Manufacturing Company | Compositions containing inorganic, organic and organometallic palladium hydrogen scavengers |
JPH09286919A (ja) * | 1996-04-18 | 1997-11-04 | Toray Dow Corning Silicone Co Ltd | 硬化性オルガノポリシロキサン組成物およびその硬化物 |
JPH09286971A (ja) | 1996-04-19 | 1997-11-04 | Toray Dow Corning Silicone Co Ltd | シリコーン系ダイボンディング剤、半導体装置の製造方法および半導体装置 |
US5665794A (en) * | 1996-05-20 | 1997-09-09 | Dow Corning Corporation | Method for controlling cure initiation and curing times of platinum group metal curing fluorosilicone compositions |
EP0850997A3 (en) | 1996-12-24 | 2001-03-14 | Dow Corning Corporation | Filled addition curable compositions having reduced gassing and increased shelf stability |
EP0850999A3 (en) * | 1996-12-30 | 1998-12-02 | Dow Corning Corporation | Silicone release coating compositions |
US5777047A (en) * | 1996-12-30 | 1998-07-07 | Dow Corning Corporation | Organosiloxane compositions with fluorinated resins curable to silicone elastomers having low weep |
US5756598A (en) * | 1996-12-30 | 1998-05-26 | Dow Corning Corporation | Resin-containing organosiloxane compositions curable to silicone elastomers having low weep |
US5683527A (en) * | 1996-12-30 | 1997-11-04 | Dow Corning Corporation | Foamable organosiloxane compositions curable to silicone foams having improved adhesion |
JPH115902A (ja) | 1997-06-17 | 1999-01-12 | Shin Etsu Chem Co Ltd | 硬化性シリコーンゴム組成物 |
JP3454095B2 (ja) | 1997-07-14 | 2003-10-06 | 信越化学工業株式会社 | 液状硬化性組成物 |
JP3885843B2 (ja) * | 1997-11-28 | 2007-02-28 | 東レ・ダウコーニング株式会社 | シリコーン系剥離剤用消泡剤 |
US6201092B1 (en) | 1998-02-04 | 2001-03-13 | Shin-Etsu Chemical Co., Ltd. | Addition curing type silicone compositions |
JP3444199B2 (ja) * | 1998-06-17 | 2003-09-08 | 信越化学工業株式会社 | 熱伝導性シリコーンゴム組成物及びその製造方法 |
JP2000078679A (ja) | 1998-08-27 | 2000-03-14 | Nec Home Electronics Ltd | ワイヤレスマイクロフォン装置 |
US6297305B1 (en) | 1998-09-02 | 2001-10-02 | Dow Corning Toray Silicone Company, Ltd. | Curable silicone composition |
US5989719A (en) * | 1998-10-13 | 1999-11-23 | Dow Corning Corporation | Oil resistant liquid silicone rubber compositions |
US6056976A (en) * | 1998-11-12 | 2000-05-02 | Leiras Oy | Elastomer, its preparation and use |
DE69905542T2 (de) | 1998-11-30 | 2003-12-11 | Shin-Etsu Chemical Co., Ltd. | Additionshärtbare Silikonelastomermischung |
US6362554B1 (en) * | 1999-07-29 | 2002-03-26 | Encap Motor Corporation | Stator assembly |
DE10019599A1 (de) | 2000-04-20 | 2001-10-31 | Wacker Chemie Gmbh | Selbsthaftende additionsvernetzende Siliconzusammensetzungen |
JP2001352768A (ja) | 2000-06-05 | 2001-12-21 | Canon Inc | 積層電気−機械エネルギー変換素子および振動波駆動装置 |
JP3944681B2 (ja) * | 2000-07-11 | 2007-07-11 | 信越化学工業株式会社 | シリコーンゴム接着剤組成物及び該接着剤組成物と熱可塑性樹脂との一体成形体 |
JP2002020719A (ja) | 2000-07-11 | 2002-01-23 | Shin Etsu Chem Co Ltd | シリコーンゴム接着剤組成物及び該接着剤組成物と熱可塑性樹脂との一体成形体 |
JP2002194201A (ja) | 2000-12-22 | 2002-07-10 | Shin Etsu Chem Co Ltd | 硬化性フルオロポリエーテル系ゴム組成物 |
US20020089240A1 (en) * | 2001-01-09 | 2002-07-11 | Du Hung T. | Electric motor having armature coated with a thermally conductive plastic |
US6512037B1 (en) * | 2001-06-06 | 2003-01-28 | Dow Corning Corporation | Silicone composition and cured silicone product |
JP4772239B2 (ja) * | 2001-10-02 | 2011-09-14 | ポリマテック株式会社 | 黒鉛化炭素粉末及び熱伝導性複合材料組成物 |
US6911166B2 (en) * | 2001-10-17 | 2005-06-28 | Encap Motor Corporation | Method of encapsulating hard disc drive and other electrical components |
US6685855B1 (en) * | 2003-06-11 | 2004-02-03 | Cool Options, Inc. | Method of making thermally-conductive casings for optical heads in optical disc players |
US7045586B2 (en) | 2003-08-14 | 2006-05-16 | Dow Corning Corporation | Adhesives having improved chemical resistance and curable silicone compositions for preparing the adhesives |
US20050038188A1 (en) | 2003-08-14 | 2005-02-17 | Dongchan Ahn | Silicones having improved chemical resistance and curable silicone compositions having improved migration resistance |
US20050038183A1 (en) * | 2003-08-14 | 2005-02-17 | Dongchan Ahn | Silicones having improved surface properties and curable silicone compositions for preparing the silicones |
-
2003
- 2003-08-14 US US10/641,810 patent/US20050038188A1/en not_active Abandoned
-
2004
- 2004-07-09 EP EP06076803A patent/EP1741755B1/en not_active Expired - Lifetime
- 2004-07-09 AT AT06076803T patent/ATE440914T1/de not_active IP Right Cessation
- 2004-07-09 EP EP04777771A patent/EP1664198B1/en not_active Expired - Lifetime
- 2004-07-09 AT AT04777771T patent/ATE364661T1/de not_active IP Right Cessation
- 2004-07-09 DE DE200460022873 patent/DE602004022873D1/de not_active Expired - Lifetime
- 2004-07-09 WO PCT/US2004/021903 patent/WO2005019342A1/en active IP Right Grant
- 2004-07-09 JP JP2006523187A patent/JP5143421B2/ja not_active Expired - Fee Related
- 2004-07-09 DE DE602004007016T patent/DE602004007016T2/de not_active Expired - Lifetime
- 2004-07-29 TW TW93122756A patent/TWI350845B/zh not_active IP Right Cessation
-
2005
- 2005-07-13 US US11/180,456 patent/US7521124B2/en not_active Expired - Fee Related
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2006
- 2006-02-14 KR KR20067003096A patent/KR101074643B1/ko not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
EP1741755B1 (en) | 2009-08-26 |
DE602004007016D1 (de) | 2007-07-26 |
WO2005019342A1 (en) | 2005-03-03 |
EP1664198B1 (en) | 2007-06-13 |
EP1741755A2 (en) | 2007-01-10 |
TWI350845B (en) | 2011-10-21 |
US7521124B2 (en) | 2009-04-21 |
KR20060080177A (ko) | 2006-07-07 |
TW200510483A (en) | 2005-03-16 |
EP1741755A3 (en) | 2007-01-24 |
EP1664198A1 (en) | 2006-06-07 |
ATE440914T1 (de) | 2009-09-15 |
US20050038188A1 (en) | 2005-02-17 |
US20050271884A1 (en) | 2005-12-08 |
KR101074643B1 (ko) | 2011-10-19 |
ATE364661T1 (de) | 2007-07-15 |
JP2007502344A (ja) | 2007-02-08 |
DE602004022873D1 (de) | 2009-10-08 |
DE602004007016T2 (de) | 2008-02-07 |
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