JP5044074B2 - 熱発泡性マイクロスフェアー及びその製造方法 - Google Patents
熱発泡性マイクロスフェアー及びその製造方法 Download PDFInfo
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- JP5044074B2 JP5044074B2 JP2001174946A JP2001174946A JP5044074B2 JP 5044074 B2 JP5044074 B2 JP 5044074B2 JP 2001174946 A JP2001174946 A JP 2001174946A JP 2001174946 A JP2001174946 A JP 2001174946A JP 5044074 B2 JP5044074 B2 JP 5044074B2
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- Prior art keywords
- polymerization
- thermally foamable
- organosilicon compound
- polymerizable
- foaming
- Prior art date
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- 238000004519 manufacturing process Methods 0.000 title claims description 24
- 150000003961 organosilicon compounds Chemical class 0.000 claims abstract description 65
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- 238000006116 polymerization reaction Methods 0.000 claims description 111
- 239000002245 particle Substances 0.000 claims description 88
- 239000000178 monomer Substances 0.000 claims description 72
- 239000000203 mixture Substances 0.000 claims description 71
- 238000010557 suspension polymerization reaction Methods 0.000 claims description 65
- 239000002612 dispersion medium Substances 0.000 claims description 60
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- 239000010419 fine particle Substances 0.000 claims description 39
- 238000000034 method Methods 0.000 claims description 37
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- 239000006185 dispersion Substances 0.000 claims description 28
- 239000004088 foaming agent Substances 0.000 claims description 28
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 claims description 25
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 13
- 229920002554 vinyl polymer Polymers 0.000 claims description 9
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 5
- 230000002378 acidificating effect Effects 0.000 claims description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 4
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- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 description 10
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 10
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 10
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- 239000003505 polymerization initiator Substances 0.000 description 9
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- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 5
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- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
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- MEFJMBSAHDEPGF-UHFFFAOYSA-N hexanedioic acid;2-(2-hydroxyethylamino)ethanol Chemical compound OCCNCCO.OC(=O)CCCCC(O)=O MEFJMBSAHDEPGF-UHFFFAOYSA-N 0.000 description 4
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 4
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 3
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- 150000000996 L-ascorbic acids Chemical class 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
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- 229910052783 alkali metal Inorganic materials 0.000 description 3
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- 229910017053 inorganic salt Inorganic materials 0.000 description 3
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- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 3
- 239000002699 waste material Substances 0.000 description 3
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- WYGWHHGCAGTUCH-UHFFFAOYSA-N 2-[(2-cyano-4-methylpentan-2-yl)diazenyl]-2,4-dimethylpentanenitrile Chemical compound CC(C)CC(C)(C#N)N=NC(C)(C#N)CC(C)C WYGWHHGCAGTUCH-UHFFFAOYSA-N 0.000 description 2
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- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
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- 230000008901 benefit Effects 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
- 238000007385 chemical modification Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 239000012933 diacyl peroxide Substances 0.000 description 1
- WHGNXNCOTZPEEK-UHFFFAOYSA-N dimethoxy-methyl-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](C)(OC)CCCOCC1CO1 WHGNXNCOTZPEEK-UHFFFAOYSA-N 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 1
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 229940119545 isobornyl methacrylate Drugs 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Chemical class 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 150000004692 metal hydroxides Chemical class 0.000 description 1
- LUCXVPAZUDVVBT-UHFFFAOYSA-N methyl-[3-(2-methylphenoxy)-3-phenylpropyl]azanium;chloride Chemical compound Cl.C=1C=CC=CC=1C(CCNC)OC1=CC=CC=C1C LUCXVPAZUDVVBT-UHFFFAOYSA-N 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000003094 microcapsule Substances 0.000 description 1
- AIRYAPRCQFBWIL-UHFFFAOYSA-N n,n-bis[3-[dimethoxy(methyl)silyl]propyl]-2-methylprop-2-enamide Chemical compound CO[Si](C)(OC)CCCN(C(=O)C(C)=C)CCC[Si](C)(OC)OC AIRYAPRCQFBWIL-UHFFFAOYSA-N 0.000 description 1
- 239000010434 nepheline Substances 0.000 description 1
- 229910052664 nepheline Inorganic materials 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920001084 poly(chloroprene) Polymers 0.000 description 1
- 235000019275 potassium ascorbate Nutrition 0.000 description 1
- 229940017794 potassium ascorbate Drugs 0.000 description 1
- 235000010289 potassium nitrite Nutrition 0.000 description 1
- 239000004304 potassium nitrite Substances 0.000 description 1
- CONVKSGEGAVTMB-RXSVEWSESA-M potassium-L-ascorbate Chemical compound [K+].OC[C@H](O)[C@H]1OC(=O)C(O)=C1[O-] CONVKSGEGAVTMB-RXSVEWSESA-M 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 239000008262 pumice Substances 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 239000011044 quartzite Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- PPASLZSBLFJQEF-RKJRWTFHSA-M sodium ascorbate Substances [Na+].OC[C@@H](O)[C@H]1OC(=O)C(O)=C1[O-] PPASLZSBLFJQEF-RKJRWTFHSA-M 0.000 description 1
- 235000010378 sodium ascorbate Nutrition 0.000 description 1
- 229960005055 sodium ascorbate Drugs 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- PPASLZSBLFJQEF-RXSVEWSESA-M sodium-L-ascorbate Chemical compound [Na+].OC[C@H](O)[C@H]1OC(=O)C(O)=C1[O-] PPASLZSBLFJQEF-RXSVEWSESA-M 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000001119 stannous chloride Substances 0.000 description 1
- 235000011150 stannous chloride Nutrition 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 238000010558 suspension polymerization method Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- CZDYPVPMEAXLPK-UHFFFAOYSA-N tetramethylsilane Chemical compound C[Si](C)(C)C CZDYPVPMEAXLPK-UHFFFAOYSA-N 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 125000003396 thiol group Chemical group [H]S* 0.000 description 1
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- GQIUQDDJKHLHTB-UHFFFAOYSA-N trichloro(ethenyl)silane Chemical compound Cl[Si](Cl)(Cl)C=C GQIUQDDJKHLHTB-UHFFFAOYSA-N 0.000 description 1
- FLTJDUOFAQWHDF-UHFFFAOYSA-N trimethyl pentane Natural products CCCCC(C)(C)C FLTJDUOFAQWHDF-UHFFFAOYSA-N 0.000 description 1
- HYWCXWRMUZYRPH-UHFFFAOYSA-N trimethyl(prop-2-enyl)silane Chemical compound C[Si](C)(C)CC=C HYWCXWRMUZYRPH-UHFFFAOYSA-N 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 239000005050 vinyl trichlorosilane Substances 0.000 description 1
- 235000019154 vitamin C Nutrition 0.000 description 1
- 239000011718 vitamin C Substances 0.000 description 1
- 239000013585 weight reducing agent Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
- B01J13/06—Making microcapsules or microballoons by phase separation
- B01J13/14—Polymerisation; cross-linking
- B01J13/18—In situ polymerisation with all reactants being present in the same phase
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
- B01J13/06—Making microcapsules or microballoons by phase separation
- B01J13/14—Polymerisation; cross-linking
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/50—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by form
- D21H21/52—Additives of definite length or shape
- D21H21/54—Additives of definite length or shape being spherical, e.g. microcapsules, beads
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/59—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2984—Microcapsule with fluid core [includes liposome]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2984—Microcapsule with fluid core [includes liposome]
- Y10T428/2985—Solid-walled microcapsule from synthetic polymer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2991—Coated
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2991—Coated
- Y10T428/2993—Silicic or refractory material containing [e.g., tungsten oxide, glass, cement, etc.]
- Y10T428/2995—Silane, siloxane or silicone coating
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Manufacturing Of Micro-Capsules (AREA)
- Polymerisation Methods In General (AREA)
- Fertilizers (AREA)
Priority Applications (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001174946A JP5044074B2 (ja) | 2001-06-11 | 2001-06-11 | 熱発泡性マイクロスフェアー及びその製造方法 |
| CNB028117336A CN100436562C (zh) | 2001-06-11 | 2002-06-10 | 热发泡性微球体及其制造方法 |
| AT02733441T ATE455593T1 (de) | 2001-06-11 | 2002-06-10 | Thermisch expandierbare mikrokugel und verfahren zu deren herstellung |
| DE60235165T DE60235165D1 (de) | 2001-06-11 | 2002-06-10 | Thermisch expandierbare mikrokugel und verfahren zu deren herstellung |
| US10/480,207 US7931967B2 (en) | 2001-06-11 | 2002-06-10 | Thermally foamable microsphere and production process thereof |
| PCT/JP2002/005737 WO2002100971A1 (fr) | 2001-06-11 | 2002-06-10 | Microspheres expansibles a la chaleur et leur procede d'obtention |
| EP02733441A EP1408097B2 (en) | 2001-06-11 | 2002-06-10 | Heat-expandable microsphere and process for producing the same |
| TW091112607A TWI302567B (enExample) | 2001-06-11 | 2002-06-11 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001174946A JP5044074B2 (ja) | 2001-06-11 | 2001-06-11 | 熱発泡性マイクロスフェアー及びその製造方法 |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2012113529A Division JP5604472B2 (ja) | 2012-05-17 | 2012-05-17 | 熱発泡性マイクロスフェアー及びその製造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2002363537A JP2002363537A (ja) | 2002-12-18 |
| JP5044074B2 true JP5044074B2 (ja) | 2012-10-10 |
Family
ID=19016159
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2001174946A Expired - Fee Related JP5044074B2 (ja) | 2001-06-11 | 2001-06-11 | 熱発泡性マイクロスフェアー及びその製造方法 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US7931967B2 (enExample) |
| EP (1) | EP1408097B2 (enExample) |
| JP (1) | JP5044074B2 (enExample) |
| CN (1) | CN100436562C (enExample) |
| AT (1) | ATE455593T1 (enExample) |
| DE (1) | DE60235165D1 (enExample) |
| TW (1) | TWI302567B (enExample) |
| WO (1) | WO2002100971A1 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2012167286A (ja) * | 2012-05-17 | 2012-09-06 | Kureha Corp | 熱発泡性マイクロスフェアー及びその製造方法 |
Families Citing this family (52)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7838037B2 (en) * | 1999-11-17 | 2010-11-23 | Tagra Biotechnologies Ltd. | Method of microencapsulation |
| US6866906B2 (en) | 2000-01-26 | 2005-03-15 | International Paper Company | Cut resistant paper and paper articles and method for making same |
| JP4721596B2 (ja) * | 2001-09-28 | 2011-07-13 | 株式会社クレハ | 低密度発泡紙及びその製造方法 |
| DE60333856D1 (de) | 2002-09-13 | 2010-09-30 | Int Paper Co | Papier mit verbesserter steifigkeit und fülle und dessen herstellung |
| WO2004074396A1 (ja) * | 2003-02-24 | 2004-09-02 | Matsumoto Yushi-Seiyaku Co., Ltd. | 熱膨張性微小球、その製造方法およびその使用方法 |
| EP1611285A2 (en) * | 2003-04-07 | 2006-01-04 | International Paper Company | Papers for liquid electrophotographic printing and method for making same |
| JP4738746B2 (ja) * | 2004-01-20 | 2011-08-03 | セメダイン株式会社 | 耐火構造体用硬化性組成物、シーリング材及びそれを用いた耐火工法 |
| JP4567980B2 (ja) * | 2004-01-26 | 2010-10-27 | 三洋化成工業株式会社 | 熱膨張性マイクロカプセルおよび中空樹脂粒子 |
| US7361399B2 (en) * | 2004-05-24 | 2008-04-22 | International Paper Company | Gloss coated multifunctional printing paper |
| JP2006035092A (ja) * | 2004-07-27 | 2006-02-09 | Sanyo Chem Ind Ltd | 中空樹脂粒子と無機微粒子との混合物の製造方法 |
| JP4217200B2 (ja) * | 2004-09-24 | 2009-01-28 | 積水化学工業株式会社 | 中空樹脂微粒子の製造方法、中空樹脂微粒子、反射防止フィルム用コーティング剤及び反射防止フィルム |
| RU2506363C2 (ru) | 2005-03-11 | 2014-02-10 | Интернэшнл Пэйпа Кампани | Бумажная или картонная основа, содержащая целлюлозные волокна и расширяемые микросферы, и упаковочная тара, содержащая эту основу |
| JP2006326501A (ja) * | 2005-05-26 | 2006-12-07 | Casio Electronics Co Ltd | 中空マイクロカプセル及びその製造方法 |
| WO2007036981A1 (ja) | 2005-09-27 | 2007-04-05 | Cemedine Co., Ltd. | 硬化性組成物 |
| EP1964903B1 (en) * | 2005-12-19 | 2017-03-22 | Kureha Corporation | Heat-expandable microspheres, process for production of the same and uses thereof |
| EP3246465B1 (en) | 2006-01-17 | 2020-10-14 | International Paper Company | Paper substrates containing high surface sizing and low internal sizing and having high dimensional stability |
| RU2432201C2 (ru) * | 2006-02-10 | 2011-10-27 | Акцо Нобель Н.В. | Микросферы |
| US7956096B2 (en) | 2006-02-10 | 2011-06-07 | Akzo Nobel N.V. | Microspheres |
| US8388809B2 (en) | 2006-02-10 | 2013-03-05 | Akzo Nobel N.V. | Microspheres |
| WO2007091961A1 (en) * | 2006-02-10 | 2007-08-16 | Akzo Nobel N.V. | Microspheres |
| US7943011B2 (en) * | 2006-05-05 | 2011-05-17 | International Paper Company | Paperboard material with expanded polymeric microspheres |
| PL2559809T3 (pl) | 2008-03-31 | 2016-03-31 | Int Paper Co | Arkusz drukowy o lepszej jakości wydruku przy niskich poziomach dodatków |
| CN103088699B (zh) * | 2008-06-20 | 2015-04-22 | 国际纸业公司 | 具有改良光学特性的组合物和记录片材 |
| CN104032622A (zh) * | 2008-08-28 | 2014-09-10 | 国际纸业公司 | 可膨胀的微球及其制造和使用方法 |
| WO2010036521A1 (en) | 2008-09-26 | 2010-04-01 | International Paper Company | Composition suitable for multifunctional printing and recording sheet containing same |
| JP5202284B2 (ja) * | 2008-12-22 | 2013-06-05 | 株式会社日立産機システム | 熱硬化性樹脂組成物 |
| JP2010202805A (ja) * | 2009-03-04 | 2010-09-16 | Sekisui Chem Co Ltd | 熱膨張性マイクロカプセル及び熱膨張性マイクロカプセルの製造方法 |
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| JP5731110B2 (ja) * | 2009-09-18 | 2015-06-10 | 積水化学工業株式会社 | 発泡粒子、発泡性組成物、及び、発泡成形体の製造方法 |
| JP5427529B2 (ja) * | 2009-09-28 | 2014-02-26 | 積水化学工業株式会社 | 発泡粒子及び発泡成形体の製造方法 |
| CN102725689B (zh) | 2010-01-22 | 2014-10-08 | 帝斯曼知识产权资产管理有限公司 | 能固化成具有选择性视觉效果的层的液体可辐射固化树脂及其使用方法 |
| EP2554620B1 (en) | 2010-03-31 | 2018-04-11 | Sekisui Chemical Co., Ltd. | Thermally expandable microcapsule, method for producing thermally expandable microcapsule, foamable masterbatch and foam molded article |
| JP5825506B2 (ja) * | 2011-02-25 | 2015-12-02 | 横浜ゴム株式会社 | タイヤトレッド用ゴム組成物 |
| JP2013053275A (ja) * | 2011-09-06 | 2013-03-21 | Sekisui Chem Co Ltd | 熱膨張性マイクロカプセルの製造方法 |
| US9206552B2 (en) | 2012-02-17 | 2015-12-08 | International Paper Company | Absorbent plastic pigment with improved print density containing and recording sheet containing same |
| TW201422405A (zh) * | 2012-12-10 | 2014-06-16 | zhi-peng Chen | 球體之一體成型製造方法 |
| BR112016002056A2 (pt) | 2013-07-29 | 2017-08-01 | Takasago Perfumery Co Ltd | microcápsulas |
| JP6438214B2 (ja) * | 2014-05-21 | 2018-12-12 | 株式会社クレハ | 熱膨張性マイクロスフェアーの製造方法、該製造方法で製造された熱膨張性マイクロスフェアー、及び該製造方法に用いるコロイダルシリカの判別方法 |
| CN104532475A (zh) * | 2014-12-15 | 2015-04-22 | 梁晋煜 | 一种制作球形立体棉的方法 |
| CN110327858B (zh) * | 2015-01-08 | 2021-09-21 | 积水化成品工业株式会社 | 中空颗粒、其制备方法、其用途以及生产微囊颗粒的方法 |
| CN104788797B (zh) * | 2015-04-03 | 2017-05-03 | 上海杰上杰化学有限公司 | 可发泡树脂粒子及用其制备发泡材料的方法 |
| SE542160C2 (en) * | 2015-06-29 | 2020-03-03 | Matsumoto Yushi Seiyaku Kk | Process for producing heat-expandable microspheres and application thereof |
| JP6610174B2 (ja) * | 2015-11-06 | 2019-11-27 | コニカミノルタ株式会社 | 中空粒子の製造方法 |
| CN105384958A (zh) * | 2015-12-19 | 2016-03-09 | 仇颖超 | 一种二氧化硅溶胶改性偶氮二甲酰胺发泡剂的制备方法 |
| CN108697595B (zh) * | 2016-02-29 | 2022-01-14 | 积水化成品工业株式会社 | 内含二氧化硅的微胶囊树脂颗粒、其生产方法及其用途 |
| KR102621431B1 (ko) * | 2017-09-29 | 2024-01-08 | 다우 글로벌 테크놀로지스 엘엘씨 | 반경방향 편차를 갖는 입자 |
| CN111278874B (zh) * | 2017-09-29 | 2023-12-22 | 罗门哈斯公司 | 制备具有径向变化的颗粒 |
| CA3094007C (en) * | 2018-03-21 | 2023-08-15 | Nouryon Chemicals International B.V. | Coatings with solar reflective properties |
| KR102202059B1 (ko) | 2018-05-11 | 2021-01-12 | 주식회사 엘지화학 | 고흡수성 수지 시트의 제조 방법 |
| WO2020114784A1 (en) | 2018-12-05 | 2020-06-11 | Sabic Global Technologies B.V. | Expandable, shelf stable polymer bead |
| EP3816143B1 (en) | 2019-10-30 | 2023-07-26 | Alloy Surfaces Company, Inc. | Pyrophoric pellets that emit infrared radiation |
| CN118574669A (zh) * | 2022-01-21 | 2024-08-30 | 松本油脂制药株式会社 | 热膨胀性微球、中空粒子及它们的用途 |
Family Cites Families (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3142583A (en) * | 1960-04-05 | 1964-07-28 | Walter M Mcmahon | Inorganic coating composition |
| NL302030A (enExample) * | 1962-12-21 | 1900-01-01 | ||
| US3615972A (en) * | 1967-04-28 | 1971-10-26 | Dow Chemical Co | Expansible thermoplastic polymer particles containing volatile fluid foaming agent and method of foaming the same |
| US3740359A (en) † | 1972-07-10 | 1973-06-19 | Dow Chemical Co | Vinylidene chloride expandable microspheres |
| DE3129515C2 (de) | 1980-07-29 | 1986-07-24 | Hitachi Chemical Co., Ltd., Tokio/Tokyo | Schäumbare Styrolharzmasse und Verfahren zu ihrer Herstellung |
| JPS5846251B2 (ja) * | 1980-07-29 | 1983-10-15 | 日立化成工業株式会社 | 発泡性ビニル系重合体粒子の製造法 |
| JPS5938241A (ja) * | 1982-08-26 | 1984-03-02 | Sekisui Plastics Co Ltd | 発泡性粒子の製造法 |
| JPS6019033A (ja) * | 1983-07-12 | 1985-01-31 | Matsumoto Yushi Seiyaku Kk | 中空マイクロバル−ンおよびその製法 |
| JPS62286534A (ja) * | 1986-06-04 | 1987-12-12 | Matsumoto Yushi Seiyaku Kk | 熱膨張性マイクロカプセルの製造法 |
| JPH04202443A (ja) * | 1990-11-30 | 1992-07-23 | Dainippon Ink & Chem Inc | 発泡性ビニル系樹脂粒子の製造方法 |
| JP3012950B2 (ja) * | 1991-04-19 | 2000-02-28 | 永和化成工業株式会社 | 発泡剤組成物 |
| JP3110526B2 (ja) * | 1991-11-08 | 2000-11-20 | 水澤化学工業株式会社 | ハイドロタルサイト被覆粒子、その製法及び樹脂用配合剤 |
| JPH06240040A (ja) | 1993-02-16 | 1994-08-30 | Dainichiseika Color & Chem Mfg Co Ltd | 複合マイクロバルーン及びその製造方法 |
| US5461125A (en) * | 1993-04-30 | 1995-10-24 | Minnesota Mining And Manufacturing Company | Waterborne core-shell latex polymers |
| JPH10176078A (ja) * | 1996-12-20 | 1998-06-30 | Hitachi Chem Co Ltd | 発泡性樹脂粒子およびその製造法 |
| US5834526A (en) * | 1997-07-11 | 1998-11-10 | Wu; Huey S. | Expandable hollow particles |
| JPH11181210A (ja) | 1997-12-17 | 1999-07-06 | Toagosei Co Ltd | 安定化された水性硬化性組成物 |
| CA2320966A1 (en) * | 1998-01-26 | 1999-07-29 | Kureha Chemical Industry Company, Limited | Expandable microspheres and process for producing the same |
| JP4620812B2 (ja) | 1998-01-26 | 2011-01-26 | 株式会社クレハ | 発泡性マイクロスフェアーの製造方法 |
| DE19810803A1 (de) * | 1998-03-12 | 1999-09-16 | Wacker Chemie Gmbh | Verfahren zur Herstellung mikroverkapselter Produkte mit Organopolysiloxanwänden |
| JPH11335509A (ja) | 1998-05-22 | 1999-12-07 | Toagosei Co Ltd | 水性組成物 |
| JP2000086937A (ja) * | 1998-09-11 | 2000-03-28 | Matsushita Electric Ind Co Ltd | 耐熱性断熱材料と耐熱性断熱材料の製造方法 |
| US7252882B2 (en) | 2000-04-28 | 2007-08-07 | Kureha Corporation | Thermally foamable microsphere and production process thereof |
| DE60121328T3 (de) | 2000-04-28 | 2016-09-15 | Kureha Corp. | Thermisch ausdehnbare mikroteilchen und verfahren zu ihrer herstellung |
| WO2002096635A1 (en) * | 2001-05-25 | 2002-12-05 | Apache Products Company | Expandable microspheres for foam insulation and methods |
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2001
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2012167286A (ja) * | 2012-05-17 | 2012-09-06 | Kureha Corp | 熱発泡性マイクロスフェアー及びその製造方法 |
Also Published As
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|---|---|
| JP2002363537A (ja) | 2002-12-18 |
| DE60235165D1 (de) | 2010-03-11 |
| EP1408097A4 (en) | 2006-10-18 |
| ATE455593T1 (de) | 2010-02-15 |
| US20040157057A1 (en) | 2004-08-12 |
| EP1408097B2 (en) | 2012-10-10 |
| EP1408097B1 (en) | 2010-01-20 |
| CN1514865A (zh) | 2004-07-21 |
| TWI302567B (enExample) | 2008-11-01 |
| WO2002100971A1 (fr) | 2002-12-19 |
| US7931967B2 (en) | 2011-04-26 |
| CN100436562C (zh) | 2008-11-26 |
| EP1408097A1 (en) | 2004-04-14 |
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