JP4777518B2 - カーボンナノチューブを生産するための方法および触媒 - Google Patents
カーボンナノチューブを生産するための方法および触媒 Download PDFInfo
- Publication number
- JP4777518B2 JP4777518B2 JP2000621281A JP2000621281A JP4777518B2 JP 4777518 B2 JP4777518 B2 JP 4777518B2 JP 2000621281 A JP2000621281 A JP 2000621281A JP 2000621281 A JP2000621281 A JP 2000621281A JP 4777518 B2 JP4777518 B2 JP 4777518B2
- Authority
- JP
- Japan
- Prior art keywords
- carbon
- carbon nanotubes
- temperature
- walled carbon
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 98
- 238000000034 method Methods 0.000 title claims abstract description 76
- 239000002041 carbon nanotube Substances 0.000 title claims abstract description 29
- 229910021393 carbon nanotube Inorganic materials 0.000 title claims abstract description 28
- 239000003054 catalyst Substances 0.000 title claims description 128
- 229910052751 metal Inorganic materials 0.000 claims abstract description 89
- 239000002184 metal Substances 0.000 claims abstract description 89
- 239000002109 single walled nanotube Substances 0.000 claims abstract description 87
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 47
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 31
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 19
- 229910052721 tungsten Inorganic materials 0.000 claims abstract description 12
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 11
- 239000002245 particle Substances 0.000 claims abstract description 8
- 239000007787 solid Substances 0.000 claims abstract description 6
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 42
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 42
- 238000004519 manufacturing process Methods 0.000 claims description 35
- 239000010419 fine particle Substances 0.000 claims description 32
- 239000007789 gas Substances 0.000 claims description 29
- 239000002048 multi walled nanotube Substances 0.000 claims description 27
- 239000000203 mixture Substances 0.000 claims description 15
- 239000001307 helium Substances 0.000 claims description 7
- 229910052734 helium Inorganic materials 0.000 claims description 7
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 claims description 7
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 5
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- 239000000395 magnesium oxide Substances 0.000 claims description 4
- 229910001111 Fine metal Inorganic materials 0.000 claims description 2
- 229910021536 Zeolite Inorganic materials 0.000 claims description 2
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
- 229910052786 argon Inorganic materials 0.000 claims description 2
- 239000003085 diluting agent Substances 0.000 claims description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 2
- 239000002808 molecular sieve Substances 0.000 claims description 2
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 2
- 239000010457 zeolite Substances 0.000 claims description 2
- 238000000151 deposition Methods 0.000 claims 1
- 230000003197 catalytic effect Effects 0.000 abstract description 13
- 229910052804 chromium Inorganic materials 0.000 abstract description 9
- 229910052759 nickel Inorganic materials 0.000 abstract description 4
- 239000000463 material Substances 0.000 abstract description 3
- 229910052741 iridium Inorganic materials 0.000 abstract description 2
- 229910052763 palladium Inorganic materials 0.000 abstract description 2
- 229910052697 platinum Inorganic materials 0.000 abstract description 2
- 229910052703 rhodium Inorganic materials 0.000 abstract description 2
- 229910052707 ruthenium Inorganic materials 0.000 abstract description 2
- 230000003647 oxidation Effects 0.000 description 65
- 238000007254 oxidation reaction Methods 0.000 description 65
- 239000000523 sample Substances 0.000 description 32
- 239000000047 product Substances 0.000 description 24
- 150000001722 carbon compounds Chemical class 0.000 description 22
- 239000002071 nanotube Substances 0.000 description 18
- 238000006243 chemical reaction Methods 0.000 description 17
- 238000007323 disproportionation reaction Methods 0.000 description 16
- 239000010439 graphite Substances 0.000 description 16
- 229910002804 graphite Inorganic materials 0.000 description 16
- 229910003481 amorphous carbon Inorganic materials 0.000 description 15
- 229910004298 SiO 2 Inorganic materials 0.000 description 13
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 12
- 150000002739 metals Chemical class 0.000 description 11
- 230000008569 process Effects 0.000 description 10
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 9
- 238000001000 micrograph Methods 0.000 description 9
- 230000005540 biological transmission Effects 0.000 description 8
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Chemical compound [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 8
- 238000004627 transmission electron microscopy Methods 0.000 description 8
- 238000004458 analytical method Methods 0.000 description 7
- 238000005516 engineering process Methods 0.000 description 7
- 229910002092 carbon dioxide Inorganic materials 0.000 description 6
- 239000001569 carbon dioxide Substances 0.000 description 6
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 6
- 239000010453 quartz Substances 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 229910052742 iron Inorganic materials 0.000 description 5
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 238000011002 quantification Methods 0.000 description 5
- 230000000630 rising effect Effects 0.000 description 5
- 239000012265 solid product Substances 0.000 description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- -1 bis (cyclopentadienyl) cobalt Chemical compound 0.000 description 4
- 239000002131 composite material Substances 0.000 description 4
- 230000007547 defect Effects 0.000 description 4
- 239000000835 fiber Substances 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 229930195733 hydrocarbon Natural products 0.000 description 4
- 150000002430 hydrocarbons Chemical group 0.000 description 4
- 238000000746 purification Methods 0.000 description 4
- 230000035484 reaction time Effects 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- 229910020515 Co—W Inorganic materials 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 238000012512 characterization method Methods 0.000 description 3
- 239000013068 control sample Substances 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 238000010891 electric arc Methods 0.000 description 3
- 238000001704 evaporation Methods 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- 230000002195 synergetic effect Effects 0.000 description 3
- 229910052723 transition metal Inorganic materials 0.000 description 3
- 150000003624 transition metals Chemical class 0.000 description 3
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 2
- XMWRBQBLMFGWIX-UHFFFAOYSA-N C60 fullerene Chemical compound C12=C3C(C4=C56)=C7C8=C5C5=C9C%10=C6C6=C4C1=C1C4=C6C6=C%10C%10=C9C9=C%11C5=C8C5=C8C7=C3C3=C7C2=C1C1=C2C4=C6C4=C%10C6=C9C9=C%11C5=C5C8=C3C3=C7C1=C1C2=C4C6=C2C9=C5C3=C12 XMWRBQBLMFGWIX-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- 229910003296 Ni-Mo Inorganic materials 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 2
- 239000012490 blank solution Substances 0.000 description 2
- 238000004523 catalytic cracking Methods 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 239000003426 co-catalyst Substances 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 238000006073 displacement reaction Methods 0.000 description 2
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 2
- 229910003472 fullerene Inorganic materials 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 239000011733 molybdenum Substances 0.000 description 2
- DDTIGTPWGISMKL-UHFFFAOYSA-N molybdenum nickel Chemical compound [Ni].[Mo] DDTIGTPWGISMKL-UHFFFAOYSA-N 0.000 description 2
- 229920000620 organic polymer Polymers 0.000 description 2
- 238000003908 quality control method Methods 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 239000012779 reinforcing material Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 238000001308 synthesis method Methods 0.000 description 2
- 238000002411 thermogravimetry Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- XQUPVDVFXZDTLT-UHFFFAOYSA-N 1-[4-[[4-(2,5-dioxopyrrol-1-yl)phenyl]methyl]phenyl]pyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C(C=C1)=CC=C1CC1=CC=C(N2C(C=CC2=O)=O)C=C1 XQUPVDVFXZDTLT-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 229910018487 Ni—Cr Inorganic materials 0.000 description 1
- 239000011398 Portland cement Substances 0.000 description 1
- 229910002839 Pt-Mo Inorganic materials 0.000 description 1
- 238000001069 Raman spectroscopy Methods 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000013504 Triton X-100 Substances 0.000 description 1
- 229920004890 Triton X-100 Polymers 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 239000004760 aramid Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 229920003235 aromatic polyamide Polymers 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 150000001721 carbon Chemical class 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000012159 carrier gas Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000005229 chemical vapour deposition Methods 0.000 description 1
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 1
- 229910001981 cobalt nitrate Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- YQZUTDPJTAZPQJ-UHFFFAOYSA-L cyclopentane;dichloromolybdenum Chemical compound Cl[Mo]Cl.[CH]1[CH][CH][CH][CH]1.[CH]1[CH][CH][CH][CH]1 YQZUTDPJTAZPQJ-UHFFFAOYSA-L 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001493 electron microscopy Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000003733 fiber-reinforced composite Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000007770 graphite material Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 229920000592 inorganic polymer Polymers 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 229910052747 lanthanoid Inorganic materials 0.000 description 1
- 150000002602 lanthanoids Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 238000004949 mass spectrometry Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 238000010606 normalization Methods 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229920003192 poly(bis maleimide) Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 239000009719 polyimide resin Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000010107 reaction injection moulding Methods 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000004621 scanning probe microscopy Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 238000000527 sonication Methods 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- 229910052713 technetium Inorganic materials 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical compound [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/15—Nano-sized carbon materials
- C01B32/158—Carbon nanotubes
- C01B32/16—Preparation
- C01B32/162—Preparation characterised by catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/18—Carbon
- B01J21/185—Carbon nanotubes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/882—Molybdenum and cobalt
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/888—Tungsten
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y15/00—Nanotechnology for interacting, sensing or actuating, e.g. quantum dots as markers in protein assays or molecular motors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
- D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
- D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
- D01F9/127—Carbon filaments; Apparatus specially adapted for the manufacture thereof by thermal decomposition of hydrocarbon gases or vapours or other carbon-containing compounds in the form of gas or vapour, e.g. carbon monoxide, alcohols
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
- D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
- D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
- D01F9/127—Carbon filaments; Apparatus specially adapted for the manufacture thereof by thermal decomposition of hydrocarbon gases or vapours or other carbon-containing compounds in the form of gas or vapour, e.g. carbon monoxide, alcohols
- D01F9/1271—Alkanes or cycloalkanes
- D01F9/1272—Methane
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
- D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
- D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
- D01F9/127—Carbon filaments; Apparatus specially adapted for the manufacture thereof by thermal decomposition of hydrocarbon gases or vapours or other carbon-containing compounds in the form of gas or vapour, e.g. carbon monoxide, alcohols
- D01F9/1278—Carbon monoxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2202/00—Structure or properties of carbon nanotubes
- C01B2202/02—Single-walled nanotubes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S977/00—Nanotechnology
- Y10S977/70—Nanostructure
- Y10S977/734—Fullerenes, i.e. graphene-based structures, such as nanohorns, nanococoons, nanoscrolls or fullerene-like structures, e.g. WS2 or MoS2 chalcogenide nanotubes, planar C3N4, etc.
- Y10S977/742—Carbon nanotubes, CNTs
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S977/00—Nanotechnology
- Y10S977/70—Nanostructure
- Y10S977/734—Fullerenes, i.e. graphene-based structures, such as nanohorns, nanococoons, nanoscrolls or fullerene-like structures, e.g. WS2 or MoS2 chalcogenide nanotubes, planar C3N4, etc.
- Y10S977/742—Carbon nanotubes, CNTs
- Y10S977/75—Single-walled
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S977/00—Nanotechnology
- Y10S977/70—Nanostructure
- Y10S977/773—Nanoparticle, i.e. structure having three dimensions of 100 nm or less
- Y10S977/775—Nanosized powder or flake, e.g. nanosized catalyst
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S977/00—Nanotechnology
- Y10S977/70—Nanostructure
- Y10S977/813—Of specified inorganic semiconductor composition, e.g. periodic table group IV-VI compositions
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S977/00—Nanotechnology
- Y10S977/70—Nanostructure
- Y10S977/832—Nanostructure having specified property, e.g. lattice-constant, thermal expansion coefficient
- Y10S977/835—Chemical or nuclear reactivity/stability of composition or compound forming nanomaterial
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S977/00—Nanotechnology
- Y10S977/84—Manufacture, treatment, or detection of nanostructure
- Y10S977/842—Manufacture, treatment, or detection of nanostructure for carbon nanotubes or fullerenes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S977/00—Nanotechnology
- Y10S977/84—Manufacture, treatment, or detection of nanostructure
- Y10S977/842—Manufacture, treatment, or detection of nanostructure for carbon nanotubes or fullerenes
- Y10S977/843—Gas phase catalytic growth, i.e. chemical vapor deposition
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2918—Rod, strand, filament or fiber including free carbon or carbide or therewith [not as steel]
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Nanotechnology (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- General Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Inorganic Chemistry (AREA)
- Composite Materials (AREA)
- Manufacturing & Machinery (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Catalysts (AREA)
- Carbon And Carbon Compounds (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US13720699P | 1999-06-02 | 1999-06-02 | |
| US60/137,206 | 1999-06-02 | ||
| US09/389,553 | 1999-09-03 | ||
| US09/389,553 US6333016B1 (en) | 1999-06-02 | 1999-09-03 | Method of producing carbon nanotubes |
| PCT/US2000/015362 WO2000073205A1 (en) | 1999-06-02 | 2000-06-01 | Method of producing carbon nanotubes and catalysts therefor |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2003500326A JP2003500326A (ja) | 2003-01-07 |
| JP2003500326A5 JP2003500326A5 (enExample) | 2010-02-04 |
| JP4777518B2 true JP4777518B2 (ja) | 2011-09-21 |
Family
ID=26835027
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2000621281A Expired - Lifetime JP4777518B2 (ja) | 1999-06-02 | 2000-06-01 | カーボンナノチューブを生産するための方法および触媒 |
Country Status (12)
| Country | Link |
|---|---|
| US (7) | US6333016B1 (enExample) |
| EP (1) | EP1192104B1 (enExample) |
| JP (1) | JP4777518B2 (enExample) |
| CN (2) | CN1360558A (enExample) |
| AT (1) | ATE369314T1 (enExample) |
| AU (1) | AU780726B2 (enExample) |
| BR (1) | BR0011106A (enExample) |
| CA (1) | CA2375887C (enExample) |
| DE (1) | DE60035875T2 (enExample) |
| ES (1) | ES2291212T3 (enExample) |
| MX (1) | MXPA01012386A (enExample) |
| WO (1) | WO2000073205A1 (enExample) |
Families Citing this family (341)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1998005920A1 (en) * | 1996-08-08 | 1998-02-12 | William Marsh Rice University | Macroscopically manipulable nanoscale devices made from nanotube assemblies |
| AU746882B2 (en) * | 1998-08-20 | 2002-05-02 | Conoco Inc. | Fischer-tropsch processes using xerogel and aerogel catalysts by destabilizing aqueous colloids |
| US6319872B1 (en) | 1998-08-20 | 2001-11-20 | Conoco Inc | Fischer-Tropsch processes using catalysts on mesoporous supports |
| US7125534B1 (en) | 1998-09-18 | 2006-10-24 | William Marsh Rice University | Catalytic growth of single- and double-wall carbon nanotubes from metal particles |
| JP4746183B2 (ja) | 1998-09-18 | 2011-08-10 | ウィリアム・マーシュ・ライス・ユニバーシティ | 溶媒和を容易にするための単層カーボンナノチューブの化学的誘導体化及び誘導体化ナノチューブの使用 |
| US6835366B1 (en) | 1998-09-18 | 2004-12-28 | William Marsh Rice University | Chemical derivatization of single-wall carbon nanotubes to facilitate solvation thereof, and use of derivatized nanotubes |
| US6692717B1 (en) | 1999-09-17 | 2004-02-17 | William Marsh Rice University | Catalytic growth of single-wall carbon nanotubes from metal particles |
| CN100340476C (zh) | 1998-11-03 | 2007-10-03 | 威廉马歇莱思大学 | 由高压co气相成核和生长单壁碳质毫微管 |
| US6265466B1 (en) * | 1999-02-12 | 2001-07-24 | Eikos, Inc. | Electromagnetic shielding composite comprising nanotubes |
| US6518218B1 (en) * | 1999-03-31 | 2003-02-11 | General Electric Company | Catalyst system for producing carbon fibrils |
| US7816709B2 (en) * | 1999-06-02 | 2010-10-19 | The Board Of Regents Of The University Of Oklahoma | Single-walled carbon nanotube-ceramic composites and methods of use |
| US20030091496A1 (en) * | 2001-07-23 | 2003-05-15 | Resasco Daniel E. | Method and catalyst for producing single walled carbon nanotubes |
| US6333016B1 (en) * | 1999-06-02 | 2001-12-25 | The Board Of Regents Of The University Of Oklahoma | Method of producing carbon nanotubes |
| US7336474B2 (en) * | 1999-09-23 | 2008-02-26 | Schlumberger Technology Corporation | Microelectromechanical devices |
| US6923946B2 (en) * | 1999-11-26 | 2005-08-02 | Ut-Battelle, Llc | Condensed phase conversion and growth of nanorods instead of from vapor |
| KR100350535B1 (ko) * | 1999-12-10 | 2002-08-28 | 삼성에스디아이 주식회사 | 리튬 이차 전지용 음극 활물질 및 그의 제조 방법 |
| US7879308B1 (en) * | 2000-03-17 | 2011-02-01 | University Of Central Florida Research Foundation, Inc. | Multiwall carbon nanotube field emitter fabricated by focused ion beam technique |
| US20030159283A1 (en) * | 2000-04-22 | 2003-08-28 | White Craig W. | Optical fiber cable |
| US6919064B2 (en) | 2000-06-02 | 2005-07-19 | The Board Of Regents Of The University Of Oklahoma | Process and apparatus for producing single-walled carbon nanotubes |
| US6413487B1 (en) * | 2000-06-02 | 2002-07-02 | The Board Of Regents Of The University Of Oklahoma | Method and apparatus for producing carbon nanotubes |
| JP4896345B2 (ja) * | 2000-06-16 | 2012-03-14 | ザ ペン ステイト リサーチ ファンデーション | 炭素質物品を製造するための方法および装置 |
| AU2001268019A1 (en) * | 2000-07-07 | 2002-01-21 | National University Of Singapore | Method for hydrogen production |
| JP3610325B2 (ja) | 2000-09-01 | 2005-01-12 | キヤノン株式会社 | 電子放出素子、電子源及び画像形成装置の製造方法 |
| JP3658346B2 (ja) * | 2000-09-01 | 2005-06-08 | キヤノン株式会社 | 電子放出素子、電子源および画像形成装置、並びに電子放出素子の製造方法 |
| JP3639809B2 (ja) * | 2000-09-01 | 2005-04-20 | キヤノン株式会社 | 電子放出素子,電子放出装置,発光装置及び画像表示装置 |
| JP3639808B2 (ja) * | 2000-09-01 | 2005-04-20 | キヤノン株式会社 | 電子放出素子及び電子源及び画像形成装置及び電子放出素子の製造方法 |
| US6953562B2 (en) * | 2001-12-11 | 2005-10-11 | Catalytic Materials, Llc | Preparation of multifaceted graphitic nanotubes |
| WO2002022499A1 (en) | 2000-09-18 | 2002-03-21 | President And Fellows Of Harvard College | Fabrication of nanotube microscopy tips |
| JP3634781B2 (ja) * | 2000-09-22 | 2005-03-30 | キヤノン株式会社 | 電子放出装置、電子源、画像形成装置及びテレビジョン放送表示装置 |
| US6743408B2 (en) | 2000-09-29 | 2004-06-01 | President And Fellows Of Harvard College | Direct growth of nanotubes, and their use in nanotweezers |
| AU2002254368B2 (en) * | 2001-03-26 | 2007-07-19 | Eikos, Inc. | Carbon nanotubes in structures and repair compositions |
| CA2442310A1 (en) | 2001-03-26 | 2002-10-03 | Eikos, Inc. | Coatings containing carbon nanotubes |
| JP3768908B2 (ja) * | 2001-03-27 | 2006-04-19 | キヤノン株式会社 | 電子放出素子、電子源、画像形成装置 |
| US6890506B1 (en) * | 2001-04-12 | 2005-05-10 | Penn State Research Foundation | Method of forming carbon fibers |
| JP4622145B2 (ja) * | 2001-04-25 | 2011-02-02 | ソニー株式会社 | 電子放出装置の製造方法、冷陰極電界電子放出素子の製造方法、及び、冷陰極電界電子放出表示装置の製造方法 |
| US6762237B2 (en) | 2001-06-08 | 2004-07-13 | Eikos, Inc. | Nanocomposite dielectrics |
| US6670300B2 (en) * | 2001-06-18 | 2003-12-30 | Battelle Memorial Institute | Textured catalysts, methods of making textured catalysts, and methods of catalyzing reactions conducted in hydrothermal conditions |
| ES2238582T5 (es) * | 2001-07-03 | 2010-05-26 | Facultes Universitaires Notre-Dame De La Paix | Soportes de catalizador y nanotubos de carbono producidos sobre dichos soportes. |
| US6706402B2 (en) | 2001-07-25 | 2004-03-16 | Nantero, Inc. | Nanotube films and articles |
| US6924538B2 (en) | 2001-07-25 | 2005-08-02 | Nantero, Inc. | Devices having vertically-disposed nanofabric articles and methods of making the same |
| US7259410B2 (en) | 2001-07-25 | 2007-08-21 | Nantero, Inc. | Devices having horizontally-disposed nanofabric articles and methods of making the same |
| US7566478B2 (en) | 2001-07-25 | 2009-07-28 | Nantero, Inc. | Methods of making carbon nanotube films, layers, fabrics, ribbons, elements and articles |
| US6835591B2 (en) | 2001-07-25 | 2004-12-28 | Nantero, Inc. | Methods of nanotube films and articles |
| US6919592B2 (en) | 2001-07-25 | 2005-07-19 | Nantero, Inc. | Electromechanical memory array using nanotube ribbons and method for making same |
| US6574130B2 (en) | 2001-07-25 | 2003-06-03 | Nantero, Inc. | Hybrid circuit having nanotube electromechanical memory |
| US7118693B2 (en) * | 2001-07-27 | 2006-10-10 | Eikos, Inc. | Conformal coatings comprising carbon nanotubes |
| US6897603B2 (en) | 2001-08-24 | 2005-05-24 | Si Diamond Technology, Inc. | Catalyst for carbon nanotube growth |
| US6596187B2 (en) * | 2001-08-29 | 2003-07-22 | Motorola, Inc. | Method of forming a nano-supported sponge catalyst on a substrate for nanotube growth |
| JP3703415B2 (ja) * | 2001-09-07 | 2005-10-05 | キヤノン株式会社 | 電子放出素子、電子源及び画像形成装置、並びに電子放出素子及び電子源の製造方法 |
| JP3605105B2 (ja) * | 2001-09-10 | 2004-12-22 | キヤノン株式会社 | 電子放出素子、電子源、発光装置、画像形成装置および基板の各製造方法 |
| US20030072942A1 (en) * | 2001-10-17 | 2003-04-17 | Industrial Technology Research Institute | Combinative carbon material |
| SG126710A1 (en) * | 2001-10-31 | 2006-11-29 | Univ Singapore | Carbon nanotubes fabrication and hydrogen production |
| WO2003037792A1 (en) * | 2001-10-31 | 2003-05-08 | National University Of Singapore | Large-scale synthesis of single-walled carbon nanotubes by group viiib catalysts promoted by group vib metals |
| JP3579689B2 (ja) * | 2001-11-12 | 2004-10-20 | 独立行政法人 科学技術振興機構 | 吸熱性反応を利用した機能性ナノ材料の製造方法 |
| CN101397134B (zh) * | 2001-11-28 | 2013-08-21 | 东丽株式会社 | 中空纳米纤维以及含有中空纳米纤维的组合物 |
| US7485279B2 (en) * | 2001-12-18 | 2009-02-03 | Yale University | Growth of nanostructures with controlled diameter |
| US7357983B2 (en) * | 2001-12-18 | 2008-04-15 | Yale University | Controlled growth of single-wall carbon nanotubes |
| US7176505B2 (en) | 2001-12-28 | 2007-02-13 | Nantero, Inc. | Electromechanical three-trace junction devices |
| US7338648B2 (en) * | 2001-12-28 | 2008-03-04 | The Penn State Research Foundation | Method for low temperature synthesis of single wall carbon nanotubes |
| US6784028B2 (en) * | 2001-12-28 | 2004-08-31 | Nantero, Inc. | Methods of making electromechanical three-trace junction devices |
| JP4404961B2 (ja) * | 2002-01-08 | 2010-01-27 | 双葉電子工業株式会社 | カーボンナノ繊維の製造方法。 |
| TWI236505B (en) * | 2002-01-14 | 2005-07-21 | Nat Science Council | Thermal cracking chemical vapor deposition process for nanocarbonaceous material |
| CN100556799C (zh) * | 2002-02-13 | 2009-11-04 | 株式会社东京大学Tlo | 单层碳纳米管的制造方法、单层碳纳米管和含单层碳纳米管的组合物 |
| WO2003072859A1 (en) * | 2002-02-22 | 2003-09-04 | Rensselaer Polytechnic Institute | Direct synthesis of long single-walled carbon nanotube strands |
| CN1176014C (zh) * | 2002-02-22 | 2004-11-17 | 清华大学 | 一种直接合成超长连续单壁碳纳米管的工艺方法 |
| US6858197B1 (en) | 2002-03-13 | 2005-02-22 | The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration | Controlled patterning and growth of single wall and multi-wall carbon nanotubes |
| RU2217394C1 (ru) * | 2002-03-25 | 2003-11-27 | Слепцов Владимир Владимирович | Просветляющее оптическое многослойное покрытие |
| US6774333B2 (en) * | 2002-03-26 | 2004-08-10 | Intel Corporation | Method and system for optically sorting and/or manipulating carbon nanotubes |
| US7335395B2 (en) | 2002-04-23 | 2008-02-26 | Nantero, Inc. | Methods of using pre-formed nanotubes to make carbon nanotube films, layers, fabrics, ribbons, elements and articles |
| CA2584508A1 (en) * | 2002-05-09 | 2003-11-09 | Institut National De La Recherche Scientifique | Method for producing single-wall carbon nanotubes |
| WO2003101908A1 (en) * | 2002-06-03 | 2003-12-11 | Zakrytoe Akcionernoe Obschestvo 'astrin-Holding' | Compound for producing building materials |
| US7153903B1 (en) | 2002-06-19 | 2006-12-26 | The Board Of Regents Of The University Of Oklahoma | Carbon nanotube-filled composites prepared by in-situ polymerization |
| US7829622B2 (en) * | 2002-06-19 | 2010-11-09 | The Board Of Regents Of The University Of Oklahoma | Methods of making polymer composites containing single-walled carbon nanotubes |
| KR100481736B1 (ko) * | 2002-07-10 | 2005-04-08 | 주식회사 동운인터내셔널 | 콜로이드 실리카 템플레이트를 이용한 수 나노미터에서수십 나노 미터크기의 탄소나노캡슐의 제조방법 |
| GB0216654D0 (en) * | 2002-07-17 | 2002-08-28 | Univ Cambridge Tech | CVD Synthesis of carbon nanoutubes |
| US7250148B2 (en) * | 2002-07-31 | 2007-07-31 | Carbon Nanotechnologies, Inc. | Method for making single-wall carbon nanotubes using supported catalysts |
| US7098056B2 (en) * | 2002-08-09 | 2006-08-29 | Nanoink, Inc. | Apparatus, materials, and methods for fabrication and catalysis |
| DE60329739D1 (de) * | 2002-08-24 | 2009-12-03 | Haldor Topsoe As | Rheniumsulfid Nanoröhrenmaterial und Verfahren zur Herstellung |
| JP3625467B2 (ja) * | 2002-09-26 | 2005-03-02 | キヤノン株式会社 | カーボンファイバーを用いた電子放出素子、電子源および画像形成装置の製造方法 |
| US7078008B2 (en) * | 2002-10-01 | 2006-07-18 | Conocophillips Company | Process for converting alkanes to carbon filaments |
| WO2004035883A2 (en) * | 2002-10-17 | 2004-04-29 | Nexen Nano Tech Co., Ltd | Fibrous nano-carbon and preparation method thereof |
| KR20030013351A (ko) * | 2002-10-18 | 2003-02-14 | 이영희 | 국부적 가열을 이용한 탄소나노튜브 열분해 합성법 |
| US7253434B2 (en) * | 2002-10-29 | 2007-08-07 | President And Fellows Of Harvard College | Suspended carbon nanotube field effect transistor |
| JP5025132B2 (ja) * | 2002-10-29 | 2012-09-12 | プレジデント・アンド・フェローズ・オブ・ハーバード・カレッジ | カーボンナノチューブ素子の製造 |
| JP3876313B2 (ja) * | 2002-11-12 | 2007-01-31 | 国立大学法人 北海道大学 | 繊維状固体炭素集合体の製造方法 |
| US6998103B1 (en) | 2002-11-15 | 2006-02-14 | The Regents Of The University Of California | Method for producing carbon nanotubes |
| CN100415642C (zh) * | 2002-11-15 | 2008-09-03 | 麦克吉尔大学 | 使用dc非转移热等离子炬制造碳纳米管的方法 |
| JP2006505483A (ja) * | 2002-11-26 | 2006-02-16 | カーボン ナノテクノロジーズ インコーポレーテッド | カーボンナノチューブ微粒子、組成物及びその使用法 |
| US20040109652A1 (en) * | 2002-12-04 | 2004-06-10 | Alcatel | Fiber optic cables with a hydrogen absorbing material |
| US7282191B1 (en) * | 2002-12-06 | 2007-10-16 | The Board Of Trustees Of The Leland Stanford Junior University | Carbon nanotube growth |
| US20040265212A1 (en) * | 2002-12-06 | 2004-12-30 | Vijay Varadan | Synthesis of coiled carbon nanotubes by microwave chemical vapor deposition |
| EP1586146A4 (en) * | 2002-12-20 | 2006-02-01 | Alnaire Laboratoires Corp | OPTICAL PUMP LASER |
| US7560136B2 (en) | 2003-01-13 | 2009-07-14 | Nantero, Inc. | Methods of using thin metal layers to make carbon nanotube films, layers, fabrics, ribbons, elements and articles |
| US20050112051A1 (en) * | 2003-01-17 | 2005-05-26 | Duke University | Systems and methods for producing single-walled carbon nanotubes (SWNTS) on a substrate |
| US6764874B1 (en) * | 2003-01-30 | 2004-07-20 | Motorola, Inc. | Method for chemical vapor deposition of single walled carbon nanotubes |
| EP1445236A1 (fr) | 2003-02-05 | 2004-08-11 | Université de Liège | Procédé et installation pour la fabrication de nanotubes de carbone |
| US7419601B2 (en) | 2003-03-07 | 2008-09-02 | Seldon Technologies, Llc | Nanomesh article and method of using the same for purifying fluids |
| DE602004028298D1 (de) * | 2003-03-07 | 2010-09-02 | Seldon Technologies Llc | Reinigung von Flüssigkeiten mit Nanomaterialien |
| US7335344B2 (en) * | 2003-03-14 | 2008-02-26 | Massachusetts Institute Of Technology | Method and apparatus for synthesizing filamentary structures |
| WO2004083113A1 (en) * | 2003-03-20 | 2004-09-30 | Cheol-Jin Lee | Massive synthesis method of double-walled carbon nanotubes using the vapor phase growth |
| EP1626862A4 (en) * | 2003-04-28 | 2011-01-12 | Leandro Balzano | SINGLE-WALL CARBON NANOTUBE CERAMIC COMPOSITES AND METHODS OF USE |
| JP2006524631A (ja) * | 2003-04-28 | 2006-11-02 | リーンドロ バルザーノ, | 単一壁のカーボンナノチューブ−セラミック複合体および使用方法 |
| US7666381B2 (en) * | 2003-06-10 | 2010-02-23 | Plasmet Corporation | Continuous production of carbon nanomaterials using a high temperature inductively coupled plasma |
| US8187703B2 (en) * | 2003-06-16 | 2012-05-29 | William Marsh Rice University | Fiber-reinforced polymer composites containing functionalized carbon nanotubes |
| US20050104258A1 (en) * | 2003-07-02 | 2005-05-19 | Physical Sciences, Inc. | Patterned electrospinning |
| US7790135B2 (en) * | 2003-07-02 | 2010-09-07 | Physical Sciences, Inc. | Carbon and electrospun nanostructures |
| GB0316367D0 (en) | 2003-07-11 | 2003-08-13 | Univ Cambridge Tech | Production of agglomerates from gas phase |
| KR20060060682A (ko) * | 2003-08-08 | 2006-06-05 | 제너럴 일렉트릭 캄파니 | 탄소 나노튜브를 포함하는 전기 전도성 조성물 및 그의제조방법 |
| US20050112450A1 (en) * | 2003-09-08 | 2005-05-26 | Intematix Corporation | Low platinum fuel cell catalysts and method for preparing the same |
| US8211593B2 (en) | 2003-09-08 | 2012-07-03 | Intematix Corporation | Low platinum fuel cells, catalysts, and method for preparing the same |
| US7351444B2 (en) * | 2003-09-08 | 2008-04-01 | Intematix Corporation | Low platinum fuel cell catalysts and method for preparing the same |
| US7597941B2 (en) * | 2003-09-09 | 2009-10-06 | University Of Louisville Research Foundation, Inc. | Tubular carbon nano/micro structures and method of making same |
| US20050214197A1 (en) * | 2003-09-17 | 2005-09-29 | Molecular Nanosystems, Inc. | Methods for producing and using catalytic substrates for carbon nanotube growth |
| US7235159B2 (en) * | 2003-09-17 | 2007-06-26 | Molecular Nanosystems, Inc. | Methods for producing and using catalytic substrates for carbon nanotube growth |
| US7347981B2 (en) * | 2003-09-25 | 2008-03-25 | The Penn State Research Foundation | Directed flow method and system for bulk separation of single-walled tubular fullerenes based on helicity |
| US20060024227A1 (en) * | 2003-10-16 | 2006-02-02 | Shigeo Maruyama | Array of single-walled carbon nanotubes and process for preparaton thereof |
| US6885010B1 (en) | 2003-11-12 | 2005-04-26 | Thermo Electron Corporation | Carbon nanotube electron ionization sources |
| US7163967B2 (en) * | 2003-12-01 | 2007-01-16 | Cryovac, Inc. | Method of increasing the gas transmission rate of a film |
| JP2007521664A (ja) | 2003-12-11 | 2007-08-02 | イエール ユニバーシティ | 制御された直径を有するホウ素ナノ構造体の成長 |
| EP1694887A2 (en) * | 2003-12-12 | 2006-08-30 | Yale University | Controlled growth of gallium nitride nanostructures |
| CN1922347A (zh) * | 2003-12-15 | 2007-02-28 | 丹尼尔·E·里萨斯科 | 铼催化剂和用于生产单壁碳纳米管的方法 |
| US20050133258A1 (en) * | 2003-12-23 | 2005-06-23 | Schlumberger Technology Corporation | [nanotube electron emission thermal energy transfer devices] |
| US7618300B2 (en) * | 2003-12-24 | 2009-11-17 | Duke University | Method of synthesizing small-diameter carbon nanotubes with electron field emission properties |
| US20050147746A1 (en) * | 2003-12-30 | 2005-07-07 | Dubin Valery M. | Nanotube growth and device formation |
| US7335327B2 (en) * | 2003-12-31 | 2008-02-26 | Cryovac, Inc. | Method of shrinking a film |
| WO2005069765A2 (en) * | 2004-01-09 | 2005-08-04 | Olga Matarredona | Carbon nanotube pastes and methods of use |
| AU2005230961B2 (en) * | 2004-01-15 | 2010-11-11 | Nanocomp Technologies, Inc. | Systems and methods for synthesis of extended length nanostructures |
| JP4239848B2 (ja) * | 2004-02-16 | 2009-03-18 | 富士ゼロックス株式会社 | マイクロ波用アンテナおよびその製造方法 |
| US20050266162A1 (en) * | 2004-03-12 | 2005-12-01 | Jiazhong Luo | Carbon nanotube stripping solutions and methods |
| US8632699B2 (en) * | 2004-04-07 | 2014-01-21 | Eikos, Inc. | Fugitive viscosity and stability modifiers for carbon nanotube compositions |
| US7144563B2 (en) * | 2004-04-22 | 2006-12-05 | Clemson University | Synthesis of branched carbon nanotubes |
| US7802441B2 (en) * | 2004-05-12 | 2010-09-28 | Electro Industries, Inc. | Heat pump with accumulator at boost compressor output |
| US7169374B2 (en) * | 2004-05-12 | 2007-01-30 | The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration | Templated growth of carbon nanotubes |
| US20110024697A1 (en) * | 2004-05-18 | 2011-02-03 | Board Of Trustees Of The University Of Arkansas | Methods of Producing Carbon Nanotubes and Applications of Same |
| JP4245514B2 (ja) * | 2004-05-24 | 2009-03-25 | 日信工業株式会社 | 炭素繊維複合材料及びその製造方法、炭素繊維複合金属材料の製造方法、炭素繊維複合非金属材料の製造方法 |
| WO2005119772A2 (en) * | 2004-06-02 | 2005-12-15 | Douglas Joel S | Coatings comprising carbon nanotubes |
| US8367034B2 (en) * | 2004-06-04 | 2013-02-05 | The Trustees Of Columbia University In The City Of New York | Methods for preparing single-walled carbon nanotubes |
| DE102004028276B4 (de) * | 2004-06-11 | 2008-08-21 | Universität Karlsruhe | Vorrichtung zur Reinigung von Abgasen einer Verbrennungskraftmaschine |
| US7838165B2 (en) * | 2004-07-02 | 2010-11-23 | Kabushiki Kaisha Toshiba | Carbon fiber synthesizing catalyst and method of making thereof |
| US7922993B2 (en) * | 2004-07-09 | 2011-04-12 | Clean Technology International Corporation | Spherical carbon nanostructure and method for producing spherical carbon nanostructures |
| US7550128B2 (en) * | 2004-07-09 | 2009-06-23 | Clean Technologies International Corporation | Method and apparatus for producing carbon nanostructures |
| US20060008403A1 (en) * | 2004-07-09 | 2006-01-12 | Clean Technologies International Corporation | Reactant liquid system for facilitating the production of carbon nanostructures |
| US7563426B2 (en) * | 2004-07-09 | 2009-07-21 | Clean Technologies International Corporation | Method and apparatus for preparing a collection surface for use in producing carbon nanostructures |
| JP2006027948A (ja) * | 2004-07-15 | 2006-02-02 | Electric Power Dev Co Ltd | 単層カーボンナノチューブの製法 |
| JP2006027949A (ja) * | 2004-07-15 | 2006-02-02 | Electric Power Dev Co Ltd | 炭素酸化物含有ガスの利用方法 |
| JP2006027947A (ja) * | 2004-07-15 | 2006-02-02 | Electric Power Dev Co Ltd | 単層カーボンナノチューブの製法 |
| US20060025515A1 (en) * | 2004-07-27 | 2006-02-02 | Mainstream Engineering Corp. | Nanotube composites and methods for producing |
| US7587985B2 (en) * | 2004-08-16 | 2009-09-15 | Clean Technology International Corporation | Method and apparatus for producing fine carbon particles |
| JP5374801B2 (ja) * | 2004-08-31 | 2013-12-25 | 富士通株式会社 | 炭素元素からなる線状構造物質の形成体及び形成方法 |
| US20060078489A1 (en) | 2004-09-09 | 2006-04-13 | Avetik Harutyunyan | Synthesis of small and narrow diameter distributed carbon single walled nanotubes |
| JP4888942B2 (ja) * | 2004-09-22 | 2012-02-29 | 国立大学法人 名古屋工業大学 | 気相法カーボンナノチューブの製造方法 |
| US20060083927A1 (en) * | 2004-10-15 | 2006-04-20 | Zyvex Corporation | Thermal interface incorporating nanotubes |
| US20080031802A1 (en) * | 2004-10-22 | 2008-02-07 | Hyperion Catalysis International, Inc. | Ozonolysis of carbon nanotubes |
| AU2005307779A1 (en) * | 2004-11-16 | 2006-05-26 | Hyperion Catalysis International, Inc. | Method for preparing single walled carbon nanotubes |
| EP1828447B1 (en) * | 2004-11-16 | 2011-01-26 | Hyperion Catalysis International, Inc. | Method for preparing supported catalysts from metal loaded carbon nanotubes |
| US7923403B2 (en) * | 2004-11-16 | 2011-04-12 | Hyperion Catalysis International, Inc. | Method for preparing catalysts supported on carbon nanotubes networks |
| EP1827681A4 (en) * | 2004-11-17 | 2011-05-11 | Hyperion Catalysis Int | METHODS FOR PREPARING CATALYTIC CARRIERS AND SUPPORTED CATALYSTS FROM SINGLE-WALL CARBON NANOTUBES |
| US7485600B2 (en) * | 2004-11-17 | 2009-02-03 | Honda Motor Co., Ltd. | Catalyst for synthesis of carbon single-walled nanotubes |
| US20060122056A1 (en) * | 2004-12-02 | 2006-06-08 | Columbian Chemicals Company | Process to retain nano-structure of catalyst particles before carbonaceous nano-materials synthesis |
| US7718223B1 (en) * | 2004-12-07 | 2010-05-18 | The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration (Nasa) | Control of carbon nanotube density and tower height in an array |
| US7704547B1 (en) | 2004-12-07 | 2010-04-27 | The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration (Nasa) | Carbon nanotube growth density control |
| US7871591B2 (en) * | 2005-01-11 | 2011-01-18 | Honda Motor Co., Ltd. | Methods for growing long carbon single-walled nanotubes |
| EP1868720A4 (en) * | 2005-02-07 | 2014-07-30 | Hyperion Catalysis Int | CATALYST WITH EASY CARBON CANNON |
| JP2006219362A (ja) * | 2005-02-08 | 2006-08-24 | Microphase Co Ltd | 液相中への気相導入によるカーボンナノチューブ膜の合成方法および合成装置 |
| JP2006231107A (ja) * | 2005-02-22 | 2006-09-07 | National Institute Of Advanced Industrial & Technology | ナノカーボン材料製造用触媒、触媒微粒子、ナノカーボン材料製造用触媒の製造方法 |
| CA2500766A1 (en) * | 2005-03-14 | 2006-09-14 | National Research Council Of Canada | Method and apparatus for the continuous production and functionalization of single-walled carbon nanotubes using a high frequency induction plasma torch |
| KR100698393B1 (ko) | 2005-03-23 | 2007-03-23 | 한국기계연구원 | 수용성 촉매를 이용한 단일층 탄소나노튜브의 선택적성장방법 및 이에 의해 형성된 단일층 탄소나노튜브를포함하는 전자소자 또는 광전소자 |
| US7947247B2 (en) * | 2005-03-29 | 2011-05-24 | Hyperion Catalysis International, Inc. | Method for preparing single walled carbon nanotubes from a metal layer |
| EP1871934A4 (en) * | 2005-03-29 | 2012-06-20 | Hyperion Catalysis Int | PROCESS FOR THE PREPARATION OF SINGLE-WALL CARBON NANOTUBES FROM A METAL LAYER |
| US20060223243A1 (en) * | 2005-03-30 | 2006-10-05 | Marko Radosavljevic | Carbon nanotube - metal contact with low contact resistance |
| US20060223191A1 (en) * | 2005-04-05 | 2006-10-05 | Avetik Harutyunyan | Methods for measuring carbon single-walled nanotube content of carbon soot |
| CA2603352C (en) * | 2005-04-06 | 2013-10-01 | Jene Golovchenko | Molecular characterization with carbon nanotube control |
| US20060231946A1 (en) * | 2005-04-14 | 2006-10-19 | Molecular Nanosystems, Inc. | Nanotube surface coatings for improved wettability |
| US7596751B2 (en) * | 2005-04-22 | 2009-09-29 | Hewlett-Packard Development Company, L.P. | Contact sheet based image management |
| US20060245996A1 (en) * | 2005-04-27 | 2006-11-02 | Peking University | Method of synthesizing single walled carbon nanotubes |
| US20080286546A1 (en) * | 2005-05-03 | 2008-11-20 | Nanocomp Technologies, Inc. | Continuous glassy carbon composite materials reinforced with carbon nanotubes and methods of manufacturing same |
| RU2287505C1 (ru) * | 2005-05-03 | 2006-11-20 | Ижевский государственный технический университет | Формовочная смесь для пенобетона |
| EP2537800A3 (en) * | 2005-05-03 | 2016-10-19 | Nanocomp Technologies, Inc. | Carbon composite materials and methods of manufacturing same |
| US7754183B2 (en) * | 2005-05-20 | 2010-07-13 | Clemson University Research Foundation | Process for preparing carbon nanostructures with tailored properties and products utilizing same |
| US20080199389A1 (en) * | 2005-05-23 | 2008-08-21 | Chiu Wilson K S | Method and device for producing carbon nanotubes |
| JP4972640B2 (ja) * | 2005-05-26 | 2012-07-11 | ナノコンプ テクノロジーズ インコーポレイテッド | 電子部品の熱管理のためのシステムおよび方法 |
| KR101289256B1 (ko) | 2005-06-28 | 2013-07-24 | 더 보드 오브 리젠츠 오브 더 유니버시티 오브 오클라호마 | 탄소 나노튜브의 성장 및 수득 방법 |
| US20080274036A1 (en) * | 2005-06-28 | 2008-11-06 | Resasco Daniel E | Microstructured catalysts and methods of use for producing carbon nanotubes |
| US20070006583A1 (en) * | 2005-07-06 | 2007-01-11 | Schlumberger Technology Corporation | Nanotube electron emission thermal energy transfer devices |
| CA2616151C (en) | 2005-07-28 | 2015-11-03 | Nanocomp Technologies, Inc. | Systems and methods for formation and harvesting of nanofibrous materials |
| JP2009521535A (ja) * | 2005-08-08 | 2009-06-04 | キャボット コーポレイション | ナノチューブを含むポリマー組成物 |
| US7678841B2 (en) * | 2005-08-19 | 2010-03-16 | Cryovac, Inc. | Increasing the gas transmission rate of a film comprising fullerenes |
| US20070116629A1 (en) * | 2005-09-15 | 2007-05-24 | Avetik Harutyunyan | Methods for synthesis of high quality carbon single-walled nanotubes |
| US8252405B2 (en) * | 2005-10-27 | 2012-08-28 | The Board Of Trustees Of The Leland Stanford Junior University | Single-walled carbon nanotubes and methods of preparation thereof |
| US9440003B2 (en) * | 2005-11-04 | 2016-09-13 | Boston Scientific Scimed, Inc. | Medical devices having particle-containing regions with diamond-like coatings |
| WO2008048286A2 (en) * | 2005-11-04 | 2008-04-24 | Nanocomp Technologies, Inc. | Nanostructured antennas and methods of manufacturing same |
| AU2006349607A1 (en) * | 2005-11-16 | 2008-05-02 | Hyperion Catalysis International, Inc. | Mixed structures of single walled and multi walled carbon nanotubes |
| JP4984498B2 (ja) * | 2005-11-18 | 2012-07-25 | ソニー株式会社 | 機能素子及びその製造方法 |
| US8264137B2 (en) * | 2006-01-03 | 2012-09-11 | Samsung Electronics Co., Ltd. | Curing binder material for carbon nanotube electron emission cathodes |
| US20080279753A1 (en) * | 2006-01-30 | 2008-11-13 | Harutyunyan Avetik R | Method and Apparatus for Growth of High Quality Carbon Single-Walled Nanotubes |
| JP2009530214A (ja) * | 2006-01-30 | 2009-08-27 | 本田技研工業株式会社 | カーボン単層ナノチューブの成長のための触媒 |
| WO2008054839A2 (en) * | 2006-03-03 | 2008-05-08 | William Marsh Rice University | Carbon nanotube diameter selection by pretreatment of metal catalysts on surfaces |
| JP2009538262A (ja) * | 2006-03-29 | 2009-11-05 | ハイピリオン カタリシス インターナショナル インコーポレイテッド | 均一な単層ナノチューブの製造方法 |
| US8129463B2 (en) * | 2006-03-31 | 2012-03-06 | Applied Nanotech Holdings, Inc. | Carbon nanotube-reinforced nanocomposites |
| US20070276077A1 (en) * | 2006-04-05 | 2007-11-29 | Nano-Proprietary, Inc. | Composites |
| US20110160346A1 (en) * | 2006-03-31 | 2011-06-30 | Applied Nanotech Holdings, Inc. | Dispersion of carbon nanotubes by microfluidic process |
| US8283403B2 (en) * | 2006-03-31 | 2012-10-09 | Applied Nanotech Holdings, Inc. | Carbon nanotube-reinforced nanocomposites |
| US20080090951A1 (en) * | 2006-03-31 | 2008-04-17 | Nano-Proprietary, Inc. | Dispersion by Microfluidic Process |
| US8445587B2 (en) * | 2006-04-05 | 2013-05-21 | Applied Nanotech Holdings, Inc. | Method for making reinforced polymer matrix composites |
| TW200800387A (en) * | 2006-06-01 | 2008-01-01 | Ritek Corp | Catalyst for catalyzing carbon nanotubes growth |
| TW200801223A (en) * | 2006-06-01 | 2008-01-01 | Ritek Corp | Method of preparing single wall carbon nanotubes |
| US20080233402A1 (en) * | 2006-06-08 | 2008-09-25 | Sid Richardson Carbon & Gasoline Co. | Carbon black with attached carbon nanotubes and method of manufacture |
| US20100137528A1 (en) * | 2006-08-29 | 2010-06-03 | Sample Jennifer L | Method for Functionalizing Nanotubes and Improved Polymer-Nanotube Composites Formed Using Same |
| US20080292835A1 (en) * | 2006-08-30 | 2008-11-27 | Lawrence Pan | Methods for forming freestanding nanotube objects and objects so formed |
| JP5343228B2 (ja) * | 2006-09-22 | 2013-11-13 | 大塚化学株式会社 | カーボンナノチューブ担持金属酸化物粒子及び顆粒状カーボンナノチューブ |
| US8158217B2 (en) | 2007-01-03 | 2012-04-17 | Applied Nanostructured Solutions, Llc | CNT-infused fiber and method therefor |
| US8951632B2 (en) | 2007-01-03 | 2015-02-10 | Applied Nanostructured Solutions, Llc | CNT-infused carbon fiber materials and process therefor |
| US20100279569A1 (en) * | 2007-01-03 | 2010-11-04 | Lockheed Martin Corporation | Cnt-infused glass fiber materials and process therefor |
| US8951631B2 (en) | 2007-01-03 | 2015-02-10 | Applied Nanostructured Solutions, Llc | CNT-infused metal fiber materials and process therefor |
| US9005755B2 (en) | 2007-01-03 | 2015-04-14 | Applied Nanostructured Solutions, Llc | CNS-infused carbon nanomaterials and process therefor |
| US20120189846A1 (en) * | 2007-01-03 | 2012-07-26 | Lockheed Martin Corporation | Cnt-infused ceramic fiber materials and process therefor |
| US8075869B2 (en) * | 2007-01-24 | 2011-12-13 | Eden Energy Ltd. | Method and system for producing a hydrogen enriched fuel using microwave assisted methane decomposition on catalyst |
| US8092778B2 (en) * | 2007-01-24 | 2012-01-10 | Eden Energy Ltd. | Method for producing a hydrogen enriched fuel and carbon nanotubes using microwave assisted methane decomposition on catalyst |
| US8021448B2 (en) * | 2007-01-25 | 2011-09-20 | Eden Energy Ltd. | Method and system for producing a hydrogen enriched fuel using microwave assisted methane plasma decomposition on catalyst |
| JP5595737B2 (ja) * | 2007-02-27 | 2014-09-24 | ナノコンプ テクノロジーズ インコーポレイテッド | 熱保護材料およびその製造方法 |
| US8813352B2 (en) * | 2007-05-17 | 2014-08-26 | The Boeing Company | Methods for fabricating a conductor |
| US9061913B2 (en) | 2007-06-15 | 2015-06-23 | Nanocomp Technologies, Inc. | Injector apparatus and methods for production of nanostructures |
| JP5110574B2 (ja) * | 2007-06-25 | 2012-12-26 | 独立行政法人産業技術総合研究所 | 高アスペクト比のカーボンナノチューブとイオン液体から構成される導電性薄膜、アクチュエータ素子 |
| EP2173655B1 (en) | 2007-07-09 | 2020-04-08 | Nanocomp Technologies, Inc. | Chemically-assisted alignment of nanotubes within extensible structures |
| EP2173473A2 (en) * | 2007-07-25 | 2010-04-14 | Nanocomp Technologies, Inc. | Systems and methods for controlling chirality of nanotubes |
| WO2009021069A1 (en) | 2007-08-07 | 2009-02-12 | Nanocomp Technologies, Inc. | Electrically and thermally non-metallic conductive nanostructure-based adapters |
| US20090081383A1 (en) * | 2007-09-20 | 2009-03-26 | Lockheed Martin Corporation | Carbon Nanotube Infused Composites via Plasma Processing |
| US20090081441A1 (en) * | 2007-09-20 | 2009-03-26 | Lockheed Martin Corporation | Fiber Tow Comprising Carbon-Nanotube-Infused Fibers |
| RU2360891C1 (ru) * | 2007-09-21 | 2009-07-10 | Государственное образовательное учреждение высшего профессионального образования "Петербургский государственный университет путей сообщения" | Сырьевая смесь для пенобетона |
| JP5539210B2 (ja) * | 2007-10-02 | 2014-07-02 | プレジデント アンド フェローズ オブ ハーバード カレッジ | ナノポアデバイスのためのカーボンナノチューブ合成 |
| CN101469453B (zh) * | 2007-12-28 | 2012-01-25 | 北京化工大学 | 一种合金纳米管及其制备方法 |
| WO2009094543A1 (en) * | 2008-01-25 | 2009-07-30 | Hyperion Catalysis International, Inc. | Processes for the recovery of catalytic metal and carbon nanotubes |
| US20090205254A1 (en) * | 2008-02-14 | 2009-08-20 | Zhonghua John Zhu | Method And System For Converting A Methane Gas To A Liquid Fuel |
| CN101481788A (zh) * | 2008-03-04 | 2009-07-15 | 浙江大学 | 单壁碳纳米管薄膜的制备方法 |
| KR101543052B1 (ko) | 2008-03-07 | 2015-08-07 | 히타치가세이가부시끼가이샤 | 카본나노튜브의 제조방법 및 카본나노튜브 제조장치 |
| EP2276341A1 (en) * | 2008-03-07 | 2011-01-26 | Dow AgroSciences LLC | Stabilized oil-in-water emulsions including meptyl dinocap |
| DE102008023229B4 (de) * | 2008-05-02 | 2013-06-27 | Helmholtz-Zentrum Dresden - Rossendorf E.V. | Verfahren zur Herstellung von Kohlenstoffnanoröhrchen auf einem Trägersubstrat, durch das Verfahren hergestellte Kohlenstoffnanoröhrchen und deren Verwendung |
| CA2723619A1 (en) | 2008-05-07 | 2009-11-12 | Nanocomp Technologies, Inc. | Nanostructure-based heating devices and method of use |
| CA2723486A1 (en) | 2008-05-07 | 2010-04-01 | Nanocomp Technologies, Inc. | Nanostructure composite sheets and methods of use |
| US8133793B2 (en) | 2008-05-16 | 2012-03-13 | Sandisk 3D Llc | Carbon nano-film reversible resistance-switchable elements and methods of forming the same |
| US8569730B2 (en) * | 2008-07-08 | 2013-10-29 | Sandisk 3D Llc | Carbon-based interface layer for a memory device and methods of forming the same |
| JP5409094B2 (ja) | 2008-07-17 | 2014-02-05 | 富士フイルム株式会社 | 曲面状成形体及びその製造方法並びに車両灯具用前面カバー及びその製造方法 |
| WO2010014650A2 (en) * | 2008-07-29 | 2010-02-04 | Honda Motor Co., Ltd. | Preferential growth of single-walled carbon nanotubes with metallic conductivity |
| US8466044B2 (en) * | 2008-08-07 | 2013-06-18 | Sandisk 3D Llc | Memory cell that includes a carbon-based memory element and methods forming the same |
| US8835892B2 (en) * | 2008-10-30 | 2014-09-16 | Sandisk 3D Llc | Electronic devices including carbon nano-tube films having boron nitride-based liners, and methods of forming the same |
| US20100108976A1 (en) * | 2008-10-30 | 2010-05-06 | Sandisk 3D Llc | Electronic devices including carbon-based films, and methods of forming such devices |
| US8421050B2 (en) * | 2008-10-30 | 2013-04-16 | Sandisk 3D Llc | Electronic devices including carbon nano-tube films having carbon-based liners, and methods of forming the same |
| CN102216212A (zh) * | 2008-11-18 | 2011-10-12 | 马来西亚理科大学 | 一种生产碳纳米管(CNTs)的方法 |
| US8354291B2 (en) | 2008-11-24 | 2013-01-15 | University Of Southern California | Integrated circuits based on aligned nanotubes |
| CN102317200B (zh) | 2009-02-17 | 2014-04-09 | 应用纳米结构方案公司 | 包括纤维上的碳纳米管的复合材料 |
| CA2752525C (en) | 2009-02-27 | 2017-05-16 | Applied Nanostructured Solutions, Llc | Low temperature cnt growth using gas-preheat method |
| US20100224129A1 (en) * | 2009-03-03 | 2010-09-09 | Lockheed Martin Corporation | System and method for surface treatment and barrier coating of fibers for in situ cnt growth |
| US8324087B2 (en) * | 2009-03-19 | 2012-12-04 | University Of Southern California | Scalable light-induced metallic to semiconducting conversion of carbon nanotubes and applications to field-effect transistor devices |
| US8183121B2 (en) * | 2009-03-31 | 2012-05-22 | Sandisk 3D Llc | Carbon-based films, and methods of forming the same, having dielectric filler material and exhibiting reduced thermal resistance |
| AU2010235123A1 (en) * | 2009-04-10 | 2011-10-06 | Applied Nanostructured Solutions Llc | Apparatus and method for the production of carbon nanotubes on a continuously moving substrate |
| US20100272891A1 (en) * | 2009-04-10 | 2010-10-28 | Lockheed Martin Corporation | Apparatus and method for the production of carbon nanotubes on a continuously moving substrate |
| KR20120002980A (ko) * | 2009-04-10 | 2012-01-09 | 어플라이드 나노스트럭처드 솔루션스, 엘엘씨. | 탄소 나노튜브를 섬유에 주입하기 위한 수직로의 사용 방법 및 장치 |
| NZ595714A (en) | 2009-04-17 | 2014-08-29 | Seerstone Llc | Method for producing solid carbon by reducing carbon oxides |
| US9111658B2 (en) | 2009-04-24 | 2015-08-18 | Applied Nanostructured Solutions, Llc | CNS-shielded wires |
| KR20120017034A (ko) | 2009-04-24 | 2012-02-27 | 어플라이드 나노스트럭처드 솔루션스, 엘엘씨. | Cnt 기반 시그니처 제어 물질 |
| CA2760144A1 (en) | 2009-04-27 | 2010-11-11 | Applied Nanostructured Solutions, Llc | Cnt-based resistive heating for deicing composite structures |
| KR20120005470A (ko) * | 2009-04-30 | 2012-01-16 | 어플라이드 나노스트럭처드 솔루션스, 엘엘씨. | 탄소 나노튜브 합성 방법 및 시스템 |
| US8354593B2 (en) | 2009-07-10 | 2013-01-15 | Nanocomp Technologies, Inc. | Hybrid conductors and method of making same |
| CA2768474A1 (en) * | 2009-07-17 | 2011-01-20 | Southwest Nanotechnologies, Inc. | Catalyst and methods for producing multi-wall carbon nanotubes |
| CN102574688A (zh) | 2009-07-31 | 2012-07-11 | 麻省理工学院 | 涉及形成碳基纳米管的系统和方法 |
| EP2461953A4 (en) | 2009-08-03 | 2014-05-07 | Applied Nanostructured Sols | USE OF NANOPARTICLES IN COMPOSITE FIBERS |
| EP2476648B1 (en) | 2009-09-10 | 2018-07-25 | The University of Tokyo | Method for simultaneously producing carbon nanotubes and hydrogen |
| US20110073344A1 (en) * | 2009-09-29 | 2011-03-31 | Hyperion Catalysis International, Inc. | Gasket containing carbon nanotubes |
| RU2414296C1 (ru) * | 2009-10-29 | 2011-03-20 | Инфра Текнолоджиз Лтд. | Катализатор для синтеза углеводородов из со и h2 и способ его получения |
| JP5937009B2 (ja) * | 2009-11-02 | 2016-06-22 | アプライド ナノストラクチャード ソリューションズ リミテッド ライアビリティー カンパニーApplied Nanostructured Solutions, Llc | Cnt導入アラミド繊維材料及びそのための方法 |
| US20110101302A1 (en) * | 2009-11-05 | 2011-05-05 | University Of Southern California | Wafer-scale fabrication of separated carbon nanotube thin-film transistors |
| KR20120117978A (ko) | 2009-11-23 | 2012-10-25 | 어플라이드 나노스트럭처드 솔루션스, 엘엘씨. | 카본 나노튜브-주입된 섬유 재료를 포함하는 세라믹 복합재료 및 이의 제조방법 |
| US8662449B2 (en) * | 2009-11-23 | 2014-03-04 | Applied Nanostructured Solutions, Llc | CNT-tailored composite air-based structures |
| US20110123735A1 (en) * | 2009-11-23 | 2011-05-26 | Applied Nanostructured Solutions, Llc | Cnt-infused fibers in thermoset matrices |
| CN103079805B (zh) | 2009-12-14 | 2015-02-11 | 应用纳米结构方案公司 | 含有碳纳米管并入的纤维材料的防火复合材料和制品 |
| US9167736B2 (en) | 2010-01-15 | 2015-10-20 | Applied Nanostructured Solutions, Llc | CNT-infused fiber as a self shielding wire for enhanced power transmission line |
| JP5830471B2 (ja) | 2010-02-02 | 2015-12-09 | アプライド ナノストラクチャード ソリューションズ リミテッド ライアビリティー カンパニーApplied Nanostructuredsolutions, Llc | 平行に配列されたカーボン・ナノチューブを含むカーボン・ナノチューブ導入繊維材料の生産方法 |
| AU2011223743A1 (en) | 2010-03-02 | 2012-08-30 | Applied Nanostructured Solutions,Llc | Electrical devices containing carbon nanotube-infused fibers and methods for production thereof |
| EP2543099A4 (en) | 2010-03-02 | 2018-03-28 | Applied NanoStructured Solutions, LLC | Spiral wound electrical devices containing carbon nanotube-infused electrode materials and methods and apparatuses for production thereof |
| US8780526B2 (en) | 2010-06-15 | 2014-07-15 | Applied Nanostructured Solutions, Llc | Electrical devices containing carbon nanotube-infused fibers and methods for production thereof |
| CN101905881B (zh) * | 2010-08-02 | 2013-05-22 | 无锡诚信碳材料科技有限公司 | 一种石墨化程度高的纳米碳材料制备方法 |
| US8809230B2 (en) | 2010-08-02 | 2014-08-19 | Lawrence Livermore National Security, Llc | Porous substrates filled with nanomaterials |
| CN103058169A (zh) * | 2010-08-02 | 2013-04-24 | 无锡诚信碳材料科技有限公司 | 一种石墨化程度高的纳米碳材料制备方法 |
| US8198498B2 (en) * | 2010-08-19 | 2012-06-12 | Kamyar Keyvanloo | Carbon nanotube catalyst for olefin production |
| US9017854B2 (en) | 2010-08-30 | 2015-04-28 | Applied Nanostructured Solutions, Llc | Structural energy storage assemblies and methods for production thereof |
| CN103097039A (zh) | 2010-09-14 | 2013-05-08 | 应用奈米结构公司 | 长有碳纳米管玻璃基板及其制造方法 |
| CA2809285A1 (en) | 2010-09-22 | 2012-03-29 | Applied Nanostructured Solutions, Llc | Carbon fiber substrates having carbon nanotubes grown thereon and processes for production thereof |
| US8853932B2 (en) * | 2010-09-23 | 2014-10-07 | Indian Institute Of Technology Kanpur | Filament including carbon nanotubes and method of making a filament including carbon nanotubes |
| AU2011305751A1 (en) | 2010-09-23 | 2012-06-21 | Applied Nanostructured Solutions, Llc | CNT-infused fiber as a self shielding wire for enhanced power transmission line |
| US9663368B2 (en) | 2010-10-28 | 2017-05-30 | Massachusetts Institute Of Technology | Carbon-based nanostructure formation using large scale active growth structures |
| US20120125700A1 (en) * | 2010-11-22 | 2012-05-24 | Bailey Sr Rudolph Volroy | Electric and other vehicles with wind turbine charging devices |
| US8664198B2 (en) | 2011-02-28 | 2014-03-04 | The University Of Central Oklahoma | Immunologically modified carbon nanotubes for cancer treatment |
| US8692230B2 (en) | 2011-03-29 | 2014-04-08 | University Of Southern California | High performance field-effect transistors |
| JP6016036B2 (ja) * | 2011-05-13 | 2016-11-02 | 国立大学法人 熊本大学 | カーボンナノチューブ複合電極及びその製造方法 |
| US8860137B2 (en) * | 2011-06-08 | 2014-10-14 | University Of Southern California | Radio frequency devices based on carbon nanomaterials |
| CN102502580B (zh) * | 2011-10-27 | 2014-08-27 | 清华大学 | 一种碳纳米管阵列及其制备方法与在制备超级电容器中的应用 |
| CN102500364A (zh) * | 2011-11-30 | 2012-06-20 | 西安理工大学 | 一种在Si衬底上制备纳米Pt催化剂颗粒的方法 |
| CA2858725C (en) * | 2011-12-12 | 2018-09-18 | Exxonmobil Upstream Research Company | Method and systems for forming carbon nanotubes |
| KR101431953B1 (ko) * | 2012-01-11 | 2014-08-19 | 주식회사 엘지화학 | 카본나노튜브용 균질 담지 촉매의 제조방법 |
| US9085464B2 (en) | 2012-03-07 | 2015-07-21 | Applied Nanostructured Solutions, Llc | Resistance measurement system and method of using the same |
| WO2013155111A1 (en) | 2012-04-09 | 2013-10-17 | Nanocomp Technologies, Inc. | Nanotube material having conductive deposits to increase conductivity |
| NO2749379T3 (enExample) | 2012-04-16 | 2018-07-28 | ||
| US9796591B2 (en) | 2012-04-16 | 2017-10-24 | Seerstone Llc | Methods for reducing carbon oxides with non ferrous catalysts and forming solid carbon products |
| EP2838838A4 (en) | 2012-04-16 | 2015-10-21 | Seerstone Llc | METHOD AND SYSTEMS FOR DETECTING AND SEQUESTRATING CARBON AND REDUCING THE MASS OF CARBOX OXIDES IN A GAS FLOW |
| US9475699B2 (en) | 2012-04-16 | 2016-10-25 | Seerstone Llc. | Methods for treating an offgas containing carbon oxides |
| WO2013158160A1 (en) | 2012-04-16 | 2013-10-24 | Seerstone Llc | Method for producing solid carbon by reducing carbon dioxide |
| US9896341B2 (en) | 2012-04-23 | 2018-02-20 | Seerstone Llc | Methods of forming carbon nanotubes having a bimodal size distribution |
| CN103537293B (zh) * | 2012-07-12 | 2015-12-16 | 北京大学 | 用于制备手性选择性和导电性选择性单壁碳纳米管的催化剂及其制备方法和应用 |
| US10815124B2 (en) | 2012-07-12 | 2020-10-27 | Seerstone Llc | Solid carbon products comprising carbon nanotubes and methods of forming same |
| CN107651667A (zh) | 2012-07-12 | 2018-02-02 | 赛尔斯通股份有限公司 | 包含碳纳米管的固体碳产物以及其形成方法 |
| MX2015000580A (es) | 2012-07-13 | 2015-08-20 | Seerstone Llc | Metodos y sistemas para formar productos de carbono solido y amoniaco. |
| US9779845B2 (en) | 2012-07-18 | 2017-10-03 | Seerstone Llc | Primary voltaic sources including nanofiber Schottky barrier arrays and methods of forming same |
| JP5952497B2 (ja) | 2012-07-23 | 2016-07-13 | ヒューレット−パッカード・インデイゴ・ビー・ブイHewlett−Packard Indigo B.V. | 静電印刷用インク組成物 |
| TWI482192B (zh) | 2012-08-22 | 2015-04-21 | Univ Nat Defense | 場發射陰極元件之製造方法、其場發射陰極元件及其場發射發光燈源 |
| CN104718170A (zh) | 2012-09-04 | 2015-06-17 | Ocv智识资本有限责任公司 | 碳强化的增强纤维在含水或非水介质内的分散 |
| WO2014076576A2 (en) | 2012-11-14 | 2014-05-22 | The Pontificia Universidad Católica Madre Y Maestra | Carbon nanotubes conformally coated with diamond nanocrystals or silicon carbide, methods of making the same and methods of their use |
| JP6389824B2 (ja) | 2012-11-29 | 2018-09-12 | シーアストーン リミテッド ライアビリティ カンパニー | 固体炭素材料を製造するための反応器および方法 |
| EP2961535B1 (en) | 2013-02-28 | 2018-01-17 | N12 Technologies, Inc. | Cartridge-based dispensing of nanostructure films |
| US10086349B2 (en) | 2013-03-15 | 2018-10-02 | Seerstone Llc | Reactors, systems, and methods for forming solid products |
| ES2900814T3 (es) | 2013-03-15 | 2022-03-18 | Seerstone Llc | Electrodos que comprenden carbono nanoestructurado |
| WO2014151144A1 (en) | 2013-03-15 | 2014-09-25 | Seerstone Llc | Carbon oxide reduction with intermetallic and carbide catalysts |
| EP3129133B1 (en) | 2013-03-15 | 2024-10-09 | Seerstone LLC | Systems for producing solid carbon by reducing carbon oxides |
| US9783416B2 (en) | 2013-03-15 | 2017-10-10 | Seerstone Llc | Methods of producing hydrogen and solid carbon |
| ES2943257T3 (es) | 2013-06-17 | 2023-06-12 | Nanocomp Technologies Inc | Agentes exfoliantes-dispersantes para nanotubos, haces y fibras |
| WO2015195773A1 (en) | 2014-06-18 | 2015-12-23 | Sid Richardson Carbon, Ltd | Nanospike hybrid carbon black |
| CN104226362A (zh) * | 2014-10-16 | 2014-12-24 | 北京师范大学 | 一种非均相芬顿催化剂及其用途 |
| US9379327B1 (en) | 2014-12-16 | 2016-06-28 | Carbonics Inc. | Photolithography based fabrication of 3D structures |
| JP6821575B2 (ja) | 2015-02-03 | 2021-01-27 | ナノコンプ テクノロジーズ,インク. | カーボンナノチューブ構造体およびその生成のための方法 |
| KR101785774B1 (ko) * | 2015-02-06 | 2017-10-17 | 주식회사 엘지화학 | 부정형 알파-알루미나를 함유하는 카본나노튜브 합성용 촉매 및 이를 이용한 카본나노튜브의 제조방법 |
| WO2017148539A1 (en) | 2016-03-04 | 2017-09-08 | Hp Indigo B.V. | Electrostatic ink composition |
| WO2018022999A1 (en) | 2016-07-28 | 2018-02-01 | Seerstone Llc. | Solid carbon products comprising compressed carbon nanotubes in a container and methods of forming same |
| US10581082B2 (en) | 2016-11-15 | 2020-03-03 | Nanocomp Technologies, Inc. | Systems and methods for making structures defined by CNT pulp networks |
| US11279836B2 (en) | 2017-01-09 | 2022-03-22 | Nanocomp Technologies, Inc. | Intumescent nanostructured materials and methods of manufacturing same |
| CN109399611A (zh) * | 2017-08-16 | 2019-03-01 | 东北林业大学 | 一种碳纳米管的制备方法 |
| WO2020022822A1 (ko) * | 2018-07-27 | 2020-01-30 | 주식회사 엘지화학 | 탄소나노튜브, 이의 제조방법 및 이를 포함하는 일차전지용 양극 |
| WO2020148670A2 (en) * | 2019-01-15 | 2020-07-23 | Sabinano (Pty) Ltd. | Carbon nanotubes and method of producing carbon nanotubes |
| KR102405026B1 (ko) * | 2019-06-17 | 2022-06-02 | 전남대학교산학협력단 | 탄소나노튜브 합성용 촉매 입자 집합체 제조 방법 및 이를 이용한 에미터용 탄소나노튜브 제조 방법 |
| US11508498B2 (en) | 2019-11-26 | 2022-11-22 | Trimtabs Ltd | Cables and methods thereof |
| KR20230160863A (ko) * | 2021-03-19 | 2023-11-24 | 캐즘 어드밴스드 머티리얼스, 인크. | 길고 좁은 직경의 탄소 나노튜브 및 이를 제조하기 위한 촉매 |
| CN113663690B (zh) * | 2021-08-30 | 2023-08-15 | 福建海梵领航科技有限公司 | 一种制备小管径单壁碳纳米管的催化剂及制备方法和应用 |
| JPWO2024190472A1 (enExample) * | 2023-03-10 | 2024-09-19 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10121334A (ja) * | 1988-01-28 | 1998-05-12 | Hyperion Catalysis Internatl | 炭素フィブリル材料を含む複合体 |
| JPH11139815A (ja) * | 1997-11-07 | 1999-05-25 | Canon Inc | カーボンナノチューブデバイスおよびその製造方法 |
| JP2002526361A (ja) * | 1998-09-18 | 2002-08-20 | ウィリアム・マーシュ・ライス・ユニバーシティ | 金属粒子からの単層カーボンナノチューブの接触成長 |
| JP2003524516A (ja) * | 1999-03-31 | 2003-08-19 | ゼネラル・エレクトリック・カンパニイ | カーボンフィブリル製造用の触媒系 |
Family Cites Families (72)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3746657A (en) * | 1971-06-28 | 1973-07-17 | Standard Oil Co | Catalyst manufacturing process |
| US4361711A (en) * | 1981-12-18 | 1982-11-30 | The Standard Oil Company | Alcohols from olefins and synthesis gas |
| US4574120A (en) * | 1984-10-15 | 1986-03-04 | Shell Oil Company | Method for preparing high activity silica supported hydrotreating catalysts |
| US4663230A (en) | 1984-12-06 | 1987-05-05 | Hyperion Catalysis International, Inc. | Carbon fibrils, method for producing same and compositions containing same |
| US5707916A (en) | 1984-12-06 | 1998-01-13 | Hyperion Catalysis International, Inc. | Carbon fibrils |
| US6375917B1 (en) | 1984-12-06 | 2002-04-23 | Hyperion Catalysis International, Inc. | Apparatus for the production of carbon fibrils by catalysis and methods thereof |
| US5165909A (en) | 1984-12-06 | 1992-11-24 | Hyperion Catalysis Int'l., Inc. | Carbon fibrils and method for producing same |
| US5445327A (en) | 1989-07-27 | 1995-08-29 | Hyperion Catalysis International, Inc. | Process for preparing composite structures |
| ZA907803B (en) * | 1989-09-28 | 1991-07-31 | Hyperion Catalysis Int | Electrochemical cells and preparing carbon fibrils |
| DE4004911C2 (de) * | 1990-02-16 | 1999-09-23 | Horst Grochowski | Verfahren und Vorrichtung zum Behandeln von wenigstens einem Fluid mittels eines als Schüttgut vorliegenden Feststoffes in einem Wanderbettreaktor |
| US5227038A (en) | 1991-10-04 | 1993-07-13 | William Marsh Rice University | Electric arc process for making fullerenes |
| JP2687794B2 (ja) | 1991-10-31 | 1997-12-08 | 日本電気株式会社 | 円筒状構造をもつ黒鉛繊維 |
| US5300203A (en) | 1991-11-27 | 1994-04-05 | William Marsh Rice University | Process for making fullerenes by the laser evaporation of carbon |
| US6573643B1 (en) | 1992-03-16 | 2003-06-03 | Si Diamond Technology, Inc. | Field emission light source |
| JPH06122489A (ja) | 1992-10-07 | 1994-05-06 | Dainippon Printing Co Ltd | 花束用包装袋 |
| US5591312A (en) | 1992-10-09 | 1997-01-07 | William Marsh Rice University | Process for making fullerene fibers |
| TW295579B (enExample) * | 1993-04-06 | 1997-01-11 | Showa Denko Kk | |
| US5424054A (en) | 1993-05-21 | 1995-06-13 | International Business Machines Corporation | Carbon fibers and method for their production |
| US5641466A (en) | 1993-06-03 | 1997-06-24 | Nec Corporation | Method of purifying carbon nanotubes |
| WO1995000440A1 (en) | 1993-06-28 | 1995-01-05 | William Marsh Rice University | Solar process for making fullerenes |
| JPH0822733B2 (ja) | 1993-08-04 | 1996-03-06 | 工業技術院長 | カーボンナノチューブの分離精製方法 |
| US5543378A (en) | 1993-10-13 | 1996-08-06 | E. I. Du Pont De Nemours And Company | Carbon nanostructures encapsulating palladium |
| JP2526408B2 (ja) | 1994-01-28 | 1996-08-21 | 工業技術院長 | カ―ボンナノチュ―ブの連続製造方法及び装置 |
| JP2611179B2 (ja) | 1994-02-25 | 1997-05-21 | 工業技術院長 | フラーレンの製造方法及び装置 |
| WO1995026925A1 (en) | 1994-03-30 | 1995-10-12 | Massachusetts Institute Of Technology | Production of fullerenic nanostructures in flames |
| JP3298735B2 (ja) | 1994-04-28 | 2002-07-08 | 科学技術振興事業団 | フラーレン複合体 |
| JP2595903B2 (ja) | 1994-07-05 | 1997-04-02 | 日本電気株式会社 | 液相におけるカーボン・ナノチューブの精製・開口方法および官能基の導入方法 |
| JP2590442B2 (ja) | 1994-09-27 | 1997-03-12 | 工業技術院長 | カーボンナノチューブの分離精製方法 |
| US5780101A (en) | 1995-02-17 | 1998-07-14 | Arizona Board Of Regents On Behalf Of The University Of Arizona | Method for producing encapsulated nanoparticles and carbon nanotubes using catalytic disproportionation of carbon monoxide |
| US5814290A (en) | 1995-07-24 | 1998-09-29 | Hyperion Catalysis International | Silicon nitride nanowhiskers and method of making same |
| US6183714B1 (en) | 1995-09-08 | 2001-02-06 | Rice University | Method of making ropes of single-wall carbon nanotubes |
| JP2873930B2 (ja) | 1996-02-13 | 1999-03-24 | 工業技術院長 | カーボンナノチューブを有する炭素質固体構造体、炭素質固体構造体からなる電子線源素子用電子放出体、及び炭素質固体構造体の製造方法 |
| BR9710709A (pt) | 1996-05-15 | 1999-08-17 | Hyperion Catalysis Int | Estruturas de carbono porosas e rigidas processos de fabrica-Æo processos de uso e produtos que as cont-m |
| CN1057940C (zh) * | 1996-07-17 | 2000-11-01 | 厦门大学 | 过渡金属氧化物催化剂及用于制备均匀管径碳纳米管的方法 |
| WO1998005920A1 (en) * | 1996-08-08 | 1998-02-12 | William Marsh Rice University | Macroscopically manipulable nanoscale devices made from nanotube assemblies |
| US5753088A (en) | 1997-02-18 | 1998-05-19 | General Motors Corporation | Method for making carbon nanotubes |
| US5997832A (en) | 1997-03-07 | 1999-12-07 | President And Fellows Of Harvard College | Preparation of carbide nanorods |
| US6683783B1 (en) * | 1997-03-07 | 2004-01-27 | William Marsh Rice University | Carbon fibers formed from single-wall carbon nanotubes |
| EP1015384B1 (en) | 1997-03-07 | 2005-07-13 | William Marsh Rice University | Carbon fibers formed from single-wall carbon nanotubes |
| JP3183845B2 (ja) | 1997-03-21 | 2001-07-09 | 財団法人ファインセラミックスセンター | カーボンナノチューブ及びカーボンナノチューブ膜の製造方法 |
| US6221330B1 (en) | 1997-08-04 | 2001-04-24 | Hyperion Catalysis International Inc. | Process for producing single wall nanotubes using unsupported metal catalysts |
| US5997823A (en) * | 1997-08-18 | 1999-12-07 | Noxso Corporation | Processes and apparatus for removing acid gases from flue gas |
| JP3415038B2 (ja) | 1998-03-25 | 2003-06-09 | 株式会社島津製作所 | カーボンの製造方法 |
| US6426134B1 (en) | 1998-06-30 | 2002-07-30 | E. I. Du Pont De Nemours And Company | Single-wall carbon nanotube-polymer composites |
| US6346189B1 (en) | 1998-08-14 | 2002-02-12 | The Board Of Trustees Of The Leland Stanford Junior University | Carbon nanotube structures made using catalyst islands |
| US7282260B2 (en) | 1998-09-11 | 2007-10-16 | Unitech, Llc | Electrically conductive and electromagnetic radiation absorptive coating compositions and the like |
| JP4746183B2 (ja) | 1998-09-18 | 2011-08-10 | ウィリアム・マーシュ・ライス・ユニバーシティ | 溶媒和を容易にするための単層カーボンナノチューブの化学的誘導体化及び誘導体化ナノチューブの使用 |
| US6692717B1 (en) | 1999-09-17 | 2004-02-17 | William Marsh Rice University | Catalytic growth of single-wall carbon nanotubes from metal particles |
| US6479939B1 (en) | 1998-10-16 | 2002-11-12 | Si Diamond Technology, Inc. | Emitter material having a plurlarity of grains with interfaces in between |
| CN100340476C (zh) * | 1998-11-03 | 2007-10-03 | 威廉马歇莱思大学 | 由高压co气相成核和生长单壁碳质毫微管 |
| US6333016B1 (en) | 1999-06-02 | 2001-12-25 | The Board Of Regents Of The University Of Oklahoma | Method of producing carbon nanotubes |
| US20030091496A1 (en) * | 2001-07-23 | 2003-05-15 | Resasco Daniel E. | Method and catalyst for producing single walled carbon nanotubes |
| US6312303B1 (en) | 1999-07-19 | 2001-11-06 | Si Diamond Technology, Inc. | Alignment of carbon nanotubes |
| US6664722B1 (en) | 1999-12-02 | 2003-12-16 | Si Diamond Technology, Inc. | Field emission material |
| US6401526B1 (en) | 1999-12-10 | 2002-06-11 | The Board Of Trustees Of The Leland Stanford Junior University | Carbon nanotubes and methods of fabrication thereof using a liquid phase catalyst precursor |
| US6599961B1 (en) | 2000-02-01 | 2003-07-29 | University Of Kentucky Research Foundation | Polymethylmethacrylate augmented with carbon nanotubes |
| US6413487B1 (en) | 2000-06-02 | 2002-07-02 | The Board Of Regents Of The University Of Oklahoma | Method and apparatus for producing carbon nanotubes |
| US20020102193A1 (en) | 2001-01-31 | 2002-08-01 | William Marsh Rice University | Process utilizing two zones for making single-wall carbon nanotubes |
| US7090819B2 (en) * | 2001-02-12 | 2006-08-15 | William Marsh Rice University | Gas-phase process for purifying single-wall carbon nanotubes and compositions thereof |
| US6752977B2 (en) * | 2001-02-12 | 2004-06-22 | William Marsh Rice University | Process for purifying single-wall carbon nanotubes and compositions thereof |
| US20030077515A1 (en) | 2001-04-02 | 2003-04-24 | Chen George Zheng | Conducting polymer-carbon nanotube composite materials and their uses |
| US6656339B2 (en) | 2001-08-29 | 2003-12-02 | Motorola, Inc. | Method of forming a nano-supported catalyst on a substrate for nanotube growth |
| US6596187B2 (en) | 2001-08-29 | 2003-07-22 | Motorola, Inc. | Method of forming a nano-supported sponge catalyst on a substrate for nanotube growth |
| US20030089893A1 (en) | 2001-10-29 | 2003-05-15 | Hyperion Catalysis International, Inc. | Polymers containing functionalized carbon nanotubes |
| US7138100B2 (en) | 2001-11-21 | 2006-11-21 | William Marsh Rice Univesity | Process for making single-wall carbon nanotubes utilizing refractory particles |
| US6699457B2 (en) | 2001-11-29 | 2004-03-02 | Wisconsin Alumni Research Foundation | Low-temperature hydrogen production from oxygenated hydrocarbons |
| US7148269B2 (en) | 2002-03-11 | 2006-12-12 | Trustees Of The University Of Pennsylvania | Interfacial polymer incorporation of nanotubes |
| US7153903B1 (en) | 2002-06-19 | 2006-12-26 | The Board Of Regents Of The University Of Oklahoma | Carbon nanotube-filled composites prepared by in-situ polymerization |
| JP3606855B2 (ja) | 2002-06-28 | 2005-01-05 | ドン ウン インターナショナル カンパニー リミテッド | 炭素ナノ粒子の製造方法 |
| JP2006524631A (ja) | 2003-04-28 | 2006-11-02 | リーンドロ バルザーノ, | 単一壁のカーボンナノチューブ−セラミック複合体および使用方法 |
| JP2006228824A (ja) | 2005-02-15 | 2006-08-31 | Tokyo Coil Engineering Kk | インダクタ及びその製造方法 |
| JP5002794B2 (ja) | 2006-12-19 | 2012-08-15 | 旭精工株式会社 | 硬貨入出金機の硬貨補給装置 |
-
1999
- 1999-09-03 US US09/389,553 patent/US6333016B1/en not_active Expired - Lifetime
-
2000
- 2000-06-01 EP EP00939548A patent/EP1192104B1/en not_active Expired - Lifetime
- 2000-06-01 JP JP2000621281A patent/JP4777518B2/ja not_active Expired - Lifetime
- 2000-06-01 WO PCT/US2000/015362 patent/WO2000073205A1/en not_active Ceased
- 2000-06-01 CN CN00808276A patent/CN1360558A/zh active Pending
- 2000-06-01 AU AU54622/00A patent/AU780726B2/en not_active Ceased
- 2000-06-01 CA CA002375887A patent/CA2375887C/en not_active Expired - Fee Related
- 2000-06-01 CN CNB031086187A patent/CN100564251C/zh not_active Expired - Lifetime
- 2000-06-01 AT AT00939548T patent/ATE369314T1/de not_active IP Right Cessation
- 2000-06-01 ES ES00939548T patent/ES2291212T3/es not_active Expired - Lifetime
- 2000-06-01 BR BR0011106-6A patent/BR0011106A/pt not_active IP Right Cessation
- 2000-06-01 MX MXPA01012386A patent/MXPA01012386A/es active IP Right Grant
- 2000-06-01 DE DE60035875T patent/DE60035875T2/de not_active Expired - Lifetime
-
2001
- 2001-11-19 US US09/988,847 patent/US20020165091A1/en not_active Abandoned
-
2003
- 2003-04-25 US US10/423,687 patent/US6994907B2/en not_active Expired - Lifetime
-
2004
- 2004-01-08 US US10/754,002 patent/US6962892B2/en not_active Expired - Lifetime
- 2004-08-25 US US10/926,317 patent/US7094386B2/en not_active Expired - Lifetime
-
2006
- 2006-01-24 US US11/338,170 patent/US7563428B2/en not_active Expired - Fee Related
-
2007
- 2007-05-25 US US11/805,917 patent/US20080107588A1/en not_active Abandoned
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10121334A (ja) * | 1988-01-28 | 1998-05-12 | Hyperion Catalysis Internatl | 炭素フィブリル材料を含む複合体 |
| JPH11139815A (ja) * | 1997-11-07 | 1999-05-25 | Canon Inc | カーボンナノチューブデバイスおよびその製造方法 |
| JP2002526361A (ja) * | 1998-09-18 | 2002-08-20 | ウィリアム・マーシュ・ライス・ユニバーシティ | 金属粒子からの単層カーボンナノチューブの接触成長 |
| JP2003524516A (ja) * | 1999-03-31 | 2003-08-19 | ゼネラル・エレクトリック・カンパニイ | カーボンフィブリル製造用の触媒系 |
Also Published As
| Publication number | Publication date |
|---|---|
| US20070116630A1 (en) | 2007-05-24 |
| CA2375887A1 (en) | 2000-12-07 |
| ES2291212T3 (es) | 2008-03-01 |
| AU780726B2 (en) | 2005-04-14 |
| AU5462200A (en) | 2000-12-18 |
| US7563428B2 (en) | 2009-07-21 |
| JP2003500326A (ja) | 2003-01-07 |
| US20040186011A1 (en) | 2004-09-23 |
| CN100564251C (zh) | 2009-12-02 |
| US20020165091A1 (en) | 2002-11-07 |
| CN1360558A (zh) | 2002-07-24 |
| WO2000073205A1 (en) | 2000-12-07 |
| BR0011106A (pt) | 2002-03-05 |
| EP1192104B1 (en) | 2007-08-08 |
| US20050025696A1 (en) | 2005-02-03 |
| DE60035875D1 (de) | 2007-09-20 |
| US7094386B2 (en) | 2006-08-22 |
| US6962892B2 (en) | 2005-11-08 |
| MXPA01012386A (es) | 2002-11-07 |
| DE60035875T2 (de) | 2008-04-30 |
| CA2375887C (en) | 2008-09-23 |
| ATE369314T1 (de) | 2007-08-15 |
| WO2000073205A9 (en) | 2002-06-20 |
| US20080107588A1 (en) | 2008-05-08 |
| EP1192104A1 (en) | 2002-04-03 |
| US6333016B1 (en) | 2001-12-25 |
| US20040070009A1 (en) | 2004-04-15 |
| CN1495127A (zh) | 2004-05-12 |
| US6994907B2 (en) | 2006-02-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP4777518B2 (ja) | カーボンナノチューブを生産するための方法および触媒 | |
| EP1694891B1 (en) | Rhenium catalysts and methods for production of single-walled carbon nanotubes | |
| JP5102633B2 (ja) | 長いカーボン単層ナノチューブを成長させるための方法 | |
| JP6158981B2 (ja) | 高品質なカーボン単層ナノチューブの合成 | |
| US20090136413A1 (en) | Method for enhanced synthesis of carbon nanostructures | |
| CN101189371B (zh) | 单壁碳纳米管催化剂 | |
| JP2009528969A (ja) | 高品質単層カーボンナノチューブ成長の方法および装置 | |
| WO2010036394A2 (en) | Effect of hydrocarbon and transport gas feedstock on efficiency and quality of grown single-walled nanotubes | |
| Awadallah et al. | Synthesis of carbon nanotubes by CCVD of natural gas using hydrotreating catalysts | |
| WO2007035241A2 (en) | Methods for synthesis of high quality carbon single-walled nanotubes | |
| Shajahan et al. | Low cost growth route for single-walled carbon nanotubes from decomposition of acetylene over magnesia supported Fe-Mo catalyst | |
| AU2005203047B2 (en) | Method of producing carbon nanotubes and catalysts therefor | |
| HK1063772A (en) | Method of producing carbon nanotubes and catalysts therefor |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20070528 |
|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20070528 |
|
| RD02 | Notification of acceptance of power of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7422 Effective date: 20090420 |
|
| RD04 | Notification of resignation of power of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7424 Effective date: 20090423 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20091209 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20100921 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20101220 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20110531 |
|
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20110630 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 4777518 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20140708 Year of fee payment: 3 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| EXPY | Cancellation because of completion of term |