JP2015511579A - チアゾリルイソオキサゾリンと殺菌剤を含んでいる活性化合物組合せ - Google Patents
チアゾリルイソオキサゾリンと殺菌剤を含んでいる活性化合物組合せ Download PDFInfo
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/34—Nitriles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
- A01N37/38—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
- A01N37/46—N-acyl derivatives
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- A—HUMAN NECESSITIES
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Abstract
Description
で表される少なくとも1種類のチアゾリルイソオキサゾリン又はその農薬的に許容される塩;
及び、
(B) 以下の群、
(1) エルゴステロール合成の阻害薬、
(2) 複合体I又はIIにおける呼吸鎖の阻害薬、
(3) 複合体IIIにおける呼吸鎖の阻害薬、
(4) 有糸分裂及び細胞分裂の阻害薬、
(5) 多部位に作用し得る化合物、
(6) 宿主の防御を誘発し得る化合物、
(7) アミノ酸及び/又はタンパク質の生合成の阻害薬、
(8) ATP産生の阻害薬、
(9) 細胞壁合成の阻害薬、
(10) 脂質及び膜の合成の阻害薬、
(11) メラニン生合成の阻害薬、
(12) 核酸合成の阻害薬、
(13) シグナル伝達の阻害薬、
(14) 脱共役剤として作用し得る化合物、
(15) 別の殺菌剤、
から選択される少なくとも1種類のさらなる活性化合物;
を含んでいる組合せを提供する。
(I−1) 2−{3−[2−(1−{[3,5−ビス(ジフルオロメチル)−1H−ピラゾール−1−イル]アセチル}ピペリジン−4−イル)−1,3−チアゾール−4−イル]−4,5−ジヒドロ−1,2−オキサゾール−5−イル}フェニル メタンスルホネート;
(I−2) 2−{3−[2−(1−{[3,5−ビス(ジフルオロメチル)−1H−ピラゾール−1−イル]アセチル}ピペリジン−4−イル)−1,3−チアゾール−4−イル]−4,5−ジヒドロ−1,2−オキサゾール−5−イル}−6−フルオロフェニル メタンスルホネート;
(I−3) 2−{3−[2−(1−{[3,5−ビス(ジフルオロメチル)−1H−ピラゾール−1−イル]アセチル}ピペリジン−4−イル)−1,3−チアゾール−4−イル]−4,5−ジヒドロ−1,2−オキサゾール−5−イル}−3−クロロフェニル メタンスルホネート;
(I−4) 2−{3−[2−(1−{[3,5−ビス(ジフルオロメチル)−1H−ピラゾール−1−イル]アセチル}ピペリジン−4−イル)−1,3−チアゾール−4−イル]−4,5−ジヒドロ−1,2−オキサゾール−5−イル}−5−メチルフェニル メタンスルホネート;
(I−5) 2−{3−[2−(1−{[3,5−ビス(ジフルオロメチル)−1H−ピラゾール−1−イル]アセチル}ピペリジン−4−イル)−1,3−チアゾール−4−イル]−4,5−ジヒドロ−1,2−オキサゾール−5−イル}−5−クロロフェニル メタンスルホネート;
(I−6) 2−{3−[2−(1−{[3,5−ビス(ジフルオロメチル)−1H−ピラゾール−1−イル]アセチル}ピペリジン−4−イル)−1,3−チアゾール−4−イル]−4,5−ジヒドロ−1,2−オキサゾール−5−イル}−4−メチルフェニル メタンスルホネート;
(I−7) 2−{3−[2−(1−{[3,5−ビス(ジフルオロメチル)−1H−ピラゾール−1−イル]アセチル}ピペリジン−4−イル)−1,3−チアゾール−4−イル]−4,5−ジヒドロ−1,2−オキサゾール−5−イル}−4−クロロフェニル メタンスルホネート;
(I−8) 2−{3−[2−(1−{[3,5−ビス(ジフルオロメチル)−1H−ピラゾール−1−イル]アセチル}ピペリジン−4−イル)−1,3−チアゾール−4−イル]−4,5−ジヒドロ−1,2−オキサゾール−5−イル}−6−クロロフェニル メタンスルホネート。
(1) エルゴステロール生合成の阻害薬、例えば、(1.1)アルジモルフ(1704−28−5)、(1.2)アザコナゾール(60207−31−0)、(1.3)ビテルタノール(55179−31−2)、(1.4)ブロムコナゾール(116255−48−2)、(1.5)シプロコナゾール(113096−99−4)、(1.6)ジクロブトラゾール(75736−33−3)、(1.7)ジフェノコナゾール(119446−68−3)、(1.8)ジニコナゾール(83657−24−3)、(1.9)ジニコナゾール−M(83657−18−5)、(1.10)ドデモルフ(1593−77−7)、(1.11)酢酸ドデモルフ(31717−87−0)、(1.12)エポキシコナゾール(106325−08−0)、(1.13)エタコナゾール(60207−93−4)、(1.14)フェナリモール(60168−88−9)、(1.15)フェンブコナゾール(114369−43−6)、(1.16)フェンヘキサミド(126833−17−8)、(1.17)フェンプロピジン(67306−00−7)、(1.18)フェンプロピモルフ(67306−03−0)、(1.19)フルキンコナゾール(136426−54−5)、(1.20)フルルプリミドール(56425−91−3)、(1.21)フルシラゾール(85509−19−9)、(1.22)フルトリアホール(76674−21−0)、(1.23)フルコナゾール(112839−33−5)、(1.24)フルコナゾール−シス(112839−32−4)、(1.25)ヘキサコナゾール(79983−71−4)、(1.26)イマザリル(60534−80−7)、(1.27)硫酸イマザリル(58594−72−2)、(1.28)イミベンコナゾール(86598−92−7)、(1.29)イプコナゾール(125225−28−7)、(1.30)メトコナゾール(125116−23−6)、(1.31)ミクロブタニル(88671−89−0)、(1.32)ナフチフィン(65472−88−0)、(1.33)ヌアリモール(63284−71−9)、(1.34)オキシポコナゾール(174212−12−5)、(1.35)パクロブトラゾール(76738−62−0)、(1.36)ペフラゾエート(101903−30−4)、(1.37)ペンコナゾール(66246−88−6)、(1.38)ピペラリン(3478−94−2)、(1.39)プロクロラズ(67747−09−5)、(1.40)プロピコナゾール(60207−90−1)、(1.41)プロチオコナゾール(178928−70−6)、(1.42)ピリブチカルブ(88678−67−5)、(1.43)ピリフェノックス(88283−41−4)、(1.44)キンコナゾール(103970−75−8)、(1.45)シメコナゾール(149508−90−7)、(1.46)スピロキサミン(118134−30−8)、(1.47)テブコナゾール(107534−96−3)、(1.48)テルビナフィン(91161−71−6)、(1.49)テトラコナゾール(112281−77−3)、(1.50)トリアジメホン(43121−43−3)、(1.51)トリアジメノール(89482−17−7)、(1.52)トリデモルフ(81412−43−3)、(1.53)トリフルミゾール(68694−11−1)、(1.54)トリホリン(26644−46−2)、(1.55)トリチコナゾール(131983−72−7)、(1.56)ウニコナゾール(83657−22−1)、(1.57)ウニコナゾール−p(83657−17−4)、(1.58)ビニコナゾール(77174−66−4)、(1.59)ボリコナゾール(137234−62−9)、(1.60)1−(4−クロロフェニル)−2−(1H−1,2,4−トリアゾール−1−イル)シクロヘプタノール(129586−32−9)、(1.61)1−(2,2−ジメチル−2,3−ジヒドロ−1H−インデン−1−イル)−1H−イミダゾール−5−カルボン酸メチル(110323−95−0)、(1.62)N’−{5−(ジフルオロメチル)−2−メチル−4−[3−(トリメチルシリル)プロポキシ]フェニル}−N−エチル−N−メチルイミドホルムアミド、(1.63)N−エチル−N−メチル−N’−{2−メチル−5−(トリフルオロメチル)−4−[3−(トリメチルシリル)プロポキシ]フェニル}イミドホルムアミド、(1.64)O−[1−(4−メトキシフェノキシ)−3,3−ジメチルブタン−2−イル] 1H−イミダゾール−1−カルボチオエート(111226−71−2);
(2) 複合体I又はIIにおける呼吸鎖の阻害薬、例えば、(2.1)ビキサフェン(581809−46−3)、(2.2)ボスカリド(188425−85−6)、(2.3)カルボキシン(5234−68−4)、(2.4)ジフルメトリム(130339−07−0)、(2.5)フェンフラム(24691−80−3)、(2.6)フルオピラム(658066−35−4)、(2.7)フルトラニル(66332−96−5)、(2.8)フルキサピロキサド(907204−31−3)、(2.9)フラメトピル(123572−88−3)、(2.10)フルメシクロックス(60568−05−0)、(2.11)イソピラザム(シン−エピマー性ラセミ化合物(1RS,4SR,9RS)とアンチ−エピマー性ラセミ化合物(1RS,4SR,9SR)の混合物)(881685−58−1)、(2.12)イソピラザム(アンチ−エピマー性ラセミ化合物 1RS,4SR,9SR)、(2.13)イソピラザム(アンチ−エピマー性エナンチオマー 1R,4S,9S)、(2.14)イソピラザム(アンチ−エピマー性エナンチオマー 1S,4R,9R)、(2.15)イソピラザム(シン−エピマー性ラセミ化合物 1RS,4SR,9RS)、(2.16)イソピラザム(シン−エピマー性エナンチオマー 1R,4S,9R)、(2.17)イソピラザム(シン−エピマー性エナンチオマー 1S,4R,9S)、(2.18)メプロニル(55814−41−0)、(2.19)オキシカルボキシン(5259−88−1)、(2.20)ペンフルフェン(494793−67−8)、(2.21)ペンチオピラド(183675−82−3)、(2.22)セダキサン(874967−67−6)、(2.23)チフルザミド(130000−40−7)、(2.24)1−メチル−N−[2−(1,1,2,2−テトラフルオロエトキシ)フェニル]−3−(トリフルオロメチル)−1H−ピラゾール−4−カルボキサミド、(2.25)3−(ジフルオロメチル)−1−メチル−N−[2−(1,1,2,2−テトラフルオロエトキシ)フェニル]−1H−ピラゾール−4−カルボキサミド、(2.26)3−(ジフルオロメチル)−N−[4−フルオロ−2−(1,1,2,3,3,3−ヘキサフルオロプロポキシ)フェニル]−1−メチル−1H−ピラゾール−4−カルボキサミド、(2.27)N−[1−(2,4−ジクロロフェニル)−1−メトキシプロパン−2−イル]−3−(ジフルオロメチル)−1−メチル−1H−ピラゾール−4−カルボキサミド(1092400−95−7)、(2.28)5,8−ジフルオロ−N−[2−(2−フルオロ−4−{[4−(トリフルオロメチル)ピリジン−2−イル]オキシ}フェニル)エチル]キナゾリン−4−アミン(1210070−84−0)、(2.29)ベンゾビンジフルピル(benzovindiflupyr)、(2.30)N−[(1S,4R)−9−(ジクロロメチレン)−1,2,3,4−テトラヒドロ−1,4−メタノナフタレン−5−イル]−3−(ジフルオロメチル)−1−メチル−1H−ピラゾール−4−カルボキサミド、(2.31)N−[(1R,4S)−9−(ジクロロメチレン)−1,2,3,4−テトラヒドロ−1,4−メタノナフタレン−5−イル]−3−(ジフルオロメチル)−1−メチル−1H−ピラゾール−4−カルボキサミド、(2.32)3−(ジフルオロメチル)−1−メチル−N−(1,1,3−トリメチル−2,3−ジヒドロ−1H−インデン−4−イル)−1H−ピラゾール−4−カルボキサミド、(2.33)1,3,5−トリメチル−N−(1,1,3−トリメチル−2,3−ジヒドロ−1H−インデン−4−イル)−1H−ピラゾール−4−カルボキサミド、(2.34)1−メチル−3−(トリフルオロメチル)−N−(1,3,3−トリメチル−2,3−ジヒドロ−1H−インデン−4−イル)−1H−ピラゾール−4−カルボキサミド、(2.35)1−メチル−3−(トリフルオロメチル)−N−[(1S)−1,3,3−トリメチル−2,3−ジヒドロ−1H−インデン−4−イル]−1H−ピラゾール−4−カルボキサミド、(2.36)1−メチル−3−(トリフルオロメチル)−N−[(1R)−1,3,3−トリメチル−2,3−ジヒドロ−1H−インデン−4−イル]−1H−ピラゾール−4−カルボキサミド、(2.37)3−(ジフルオロメチル)−1−メチル−N−[(3S)−1,1,3−トリメチル−2,3−ジヒドロ−1H−インデン−4−イル]−1H−ピラゾール−4−カルボキサミド、(2.38)3−(ジフルオロメチル)−1−メチル−N−[(3R)−1,1,3−トリメチル−2,3−ジヒドロ−1H−インデン−4−イル]−1H−ピラゾール−4−カルボキサミド、(2.39)1,3,5−トリメチル−N−[(3R)−1,1,3−トリメチル−2,3−ジヒドロ−1H−インデン−4−イル]−1H−ピラゾール−4−カルボキサミド、(2.40)1,3,5−トリメチル−N−[(3S)−1,1,3−トリメチル−2,3−ジヒドロ−1H−インデン−4−イル]−1H−ピラゾール−4−カルボキサミド;
(3) 複合体IIIにおける呼吸鎖の阻害薬、例えば、(3.1)アメトクトラジン(865318−97−4)、(3.2)アミスルブロム(348635−87−0)、(3.3)アゾキシストロビン(131860−33−8)、(3.4)シアゾファミド(120116−88−3)、(3.5)クメトキシストロビン(coumethoxystrobin)(850881−30−0)、(3.6)クモキシストロビン(coumoxystrobin)(850881−70−8)、(3.7)ジモキシストロビン(141600−52−4)、(3.8)エネストロブリン(238410−11−2)、(3.9)ファモキサドン(131807−57−3)、(3.10)フェンアミドン(161326−34−7)、(3.11)フェノキシストロビン(fenoxystrobin)(918162−02−4)、(3.12)フルオキサストロビン(361377−29−9)、(3.13)クレソキシム−メチル(143390−89−0)、(3.14)メトミノストロビン(133408−50−1)、(3.15)オリサストロビン(189892−69−1)、(3.16)ピコキシストロビン(117428−22−5)、(3.17)ピラクロストロビン(175013−18−0)、(3.18)ピラメトストロビン(pyrametostrobin)(915410−70−7)、(3.19)ピラオキシストロビン(pyraoxystrobin)(862588−11−2)、(3.20)ピリベンカルブ(799247−52−2)、(3.21)トリクロピリカルブ(triclopyricarb)(902760−40−1)、(3.22)トリフロキシストロビン(141517−21−7)、(3.23)(2E)−2−(2−{[6−(3−クロロ−2−メチルフェノキシ)−5−フルオロピリミジン−4−イル]オキシ}フェニル)−2−(メトキシイミノ)−N−メチルエタンアミド、(3.24)(2E)−2−(メトキシイミノ)−N−メチル−2−(2−{[({(1E)−1−[3−(トリフルオロメチル)フェニル]エチリデン}アミノ)オキシ]メチル}フェニル)エタンアミド、(3.25)(2E)−2−(メトキシイミノ)−N−メチル−2−{2−[(E)−({1−[3−(トリフルオロメチル)フェニル]エトキシ}イミノ)メチル]フェニル}エタンアミド(158169−73−4)、(3.26)(2E)−2−{2−[({[(1E)−1−(3−{[(E)−1−フルオロ−2−フェニルエテニル]オキシ}フェニル)エチリデン]アミノ}オキシ)メチル]フェニル}−2−(メトキシイミノ)−N−メチルエタンアミド(326896−28−0)、(3.27)(2E)−2−{2−[({[(2E,3E)−4−(2,6−ジクロロフェニル)ブタ−3−エン−2−イリデン]アミノ}オキシ)メチル]フェニル}−2−(メトキシイミノ)−N−メチルエタンアミド、(3.28)2−クロロ−N−(1,1,3−トリメチル−2,3−ジヒドロ−1H−インデン−4−イル)ピリジン−3−カルボキサミド(119899−14−8)、(3.29)5−メトキシ−2−メチル−4−(2−{[({(1E)−1−[3−(トリフルオロメチル)フェニル]エチリデン}アミノ)オキシ]メチル}フェニル)−2,4−ジヒドロ−3H−1,2,4−トリアゾール−3−オン、(3.30)(2E)−2−{2−[({シクロプロピル[(4−メトキシフェニル)イミノ]メチル}スルファニル)メチル]フェニル}−3−メトキシプロパ−2−エン酸メチル(149601−03−6)、(3.31)N−(3−エチル−3,5,5−トリメチルシクロヘキシル)−3−(ホルミルアミノ)−2−ヒドロキシベンズアミド(226551−21−9)、(3.32)2−{2−[(2,5−ジメチルフェノキシ)メチル]フェニル}−2−メトキシ−N−メチルアセトアミド(173662−97−0)、(3.33)(2R)−2−{2−[(2,5−ジメチルフェノキシ)メチル]フェニル}−2−メトキシ−N−メチルアセトアミド(394657−24−0);
(4) 有糸分裂及び細胞分裂の阻害薬、例えば、(4.1)ベノミル(17804−35−2)、(4.2)カルベンダジム(10605−21−7)、(4.3)クロルフェナゾール(3574−96−7)、(4.4)ジエトフェンカルブ(87130−20−9)、(4.5)エタボキサム(162650−77−3)、(4.6)フルオピコリド(239110−15−7)、(4.7)フベリダゾール(3878−19−1)、(4.8)ペンシクロン(66063−05−6)、(4.9)チアベンダゾール(148−79−8)、(4.10)チオファネート−メチル(23564−05−8)、(4.11)チオファネート(23564−06−9)、(4.12)ゾキサミド(156052−68−5)、(4.13)5−クロロ−7−(4−メチルピペリジン−1−イル)−6−(2,4,6−トリフルオロフェニル)[1,2,4]トリアゾロ[1,5−a]ピリミジン(214706−53−3)、(4.14)3−クロロ−5−(6−クロロピリジン−3−イル)−6−メチル−4−(2,4,6−トリフルオロフェニル)ピリダジン(1002756−87−7);
(5) 多部位に作用し得る化合物、例えば、(5.1)ボルドー液(8011−63−0)、(5.2)カプタホール(2425−06−1)、(5.3)キャプタン(133−06−2)、(5.4)クロロタロニル(1897−45−6)、(5.5)水酸化銅(20427−59−2)、(5.6)ナフテン酸銅(1338−02−9)、(5.7)酸化銅(1317−39−1)、(5.8)塩基性塩化銅(1332−40−7)、(5.9)硫酸銅(2+)(7758−98−7)、(5.10)ジクロフルアニド(1085−98−9)、(5.11)ジチアノン(3347−22−6)、(5.12)ドジン(2439−10−3)、(5.13)ドジン遊離塩基、(5.14)ファーバム(14484−64−1)、(5.15)フルオロホルペット(719−96−0)、(5.16)ホルペット(133−07−3)、(5.17)グアザチン(108173−90−6)、(5.18)酢酸グアザチン、(5.19)イミノクタジン(13516−27−3)、(5.20)イミノクタジンアルベシル酸塩(169202−06−6)、(5.21)イミノクタジン三酢酸塩(57520−17−9)、(5.22)マンカッパー(53988−93−5)、(5.23)マンゼブ(8018−01−7)、(5.24)マンネブ(12427−38−2)、(5.25)メチラム(9006−42−2)、(5.26)メチラム亜鉛(metiram zinc)(9006−42−2)、(5.27)オキシン銅(10380−28−6)、(5.28)プロパミジン(propamidine)(104−32−5)、(5.29)プロピネブ(12071−83−9)、(5.30)硫黄及び硫黄剤、例えば、多硫化カルシウム(7704−34−9)、(5.31)チウラム(137−26−8)、(5.32)トリルフルアニド(731−27−1)、(5.33)ジネブ(12122−67−7)、(5.34)ジラム(137−30−4);
(6) 宿主の防御を誘発し得る化合物、例えば、(6.1)アシベンゾラル−S−メチル(135158−54−2)、(6.2)イソチアニル(224049−04−1)、(6.3)プロベナゾール(27605−76−1)、(6.4)チアジニル(223580−51−6);
(7) アミノ酸及び/又はタンパク質の生合成の阻害薬、例えば、(7.1)アンドプリム(andoprim)(23951−85−1)、(7.2)ブラストサイジン−S(2079−00−7)、(7.3)シプロジニル(121552−61−2)、(7.4)カスガマイシン(6980−18−3)、(7.5)カスガマイシン塩酸塩水和物(19408−46−9)、(7.6)メパニピリム(110235−47−7)、(7.7)ピリメタニル(53112−28−0)、(7.8)3−(5−フルオロ−3,3,4,4−テトラメチル−3,4−ジヒドロイソキノリン−1−イル)キノリン(861647−32−7);
(8) ATP産生の阻害薬、例えば、(8.1)酢酸トリフェニルスズ(900−95−8)、(8.2)塩化トリフェニルスズ(639−58−7)、(8.3)水酸化トリフェニルスズ(76−87−9)、(8.4)シルチオファム(175217−20−6);
(9) 細胞壁合成の阻害薬、例えば、(9.1)ベンチアバリカルブ(177406−68−7)、(9.2)ジメトモルフ(110488−70−5)、(9.3)フルモルフ(211867−47−9)、(9.4)イプロバリカルブ(140923−17−7)、(9.5)マンジプロパミド(374726−62−2)、(9.6)ポリオキシン(11113−80−7)、(9.7)ポリオキソリム(22976−86−9)、(9.8)バリダマイシンA(37248−47−8)、(9.9)バリフェナレート(283159−94−4;283159−90−0);
(10) 脂質及び膜の合成の阻害薬、例えば、(10.1)ビフェニル(92−52−4)、(10.2)クロロネブ(2675−77−6)、(10.3)ジクロラン(99−30−9)、(10.4)エジフェンホス(17109−49−8)、(10.5)エトリジアゾール(2593−15−9)、(10.6)ヨードカルブ(iodocarb)(55406−53−6)、(10.7)イプロベンホス(26087−47−8)、(10.8)イソプロチオラン(50512−35−1)、(10.9)プロパモカルブ(25606−41−1)、(10.10)プロパモカルブ塩酸塩(25606−41−1)、(10.11)プロチオカルブ(19622−08−3)、(10.12)ピラゾホス(13457−18−6)、(10.13)キントゼン(82−68−8)、(10.14)テクナゼン(117−18−0)、(10.15)トルクロホス−メチル(57018−04−9);
(11) メラニン生合成の阻害薬、例えば、(11.1)カルプロパミド(104030−54−8)、(11.2)ジクロシメット(139920−32−4)、(11.3)フェノキサニル(115852−48−7)、(11.4)フタリド(27355−22−2)、(11.5)ピロキロン(57369−32−1)、(11.6)トリシクラゾール(41814−78−2)、(11.7){3−メチル−1−[(4−メチルベンゾイル)アミノ]ブタン−2−イル}カルバミン酸2,2,2−トリフルオロエチル(851524−22−6);
(12) 核酸合成の阻害薬、例えば、(12.1)ベナラキシル(71626−11−4)、(12.2)ベナラキシル−M(キララキシル(kiralaxyl))(98243−83−5)、(12.3)ブピリメート(41483−43−6)、(12.4)クロジラコン(67932−85−8)、(12.5)ジメチリモール(5221−53−4)、(12.6)エチリモール(23947−60−6)、(12.7)フララキシル(57646−30−7)、(12.8)ヒメキサゾール(10004−44−1)、(12.9)メタラキシル(57837−19−1)、(12.10)メタラキシル−M(メフェノキサム)(70630−17−0)、(12.11)オフラセ(58810−48−3)、(12.12)オキサジキシル(77732−09−3)、(12.13)オキソリン酸(14698−29−4);
(13) シグナル伝達の阻害薬、例えば、(13.1)クロゾリネート(84332−86−5)、(13.2)フェンピクロニル(74738−17−3)、(13.3)フルジオキソニル(131341−86−1)、(13.4)イプロジオン(36734−19−7)、(13.5)プロシミドン(32809−16−8)、(13.6)キノキシフェン(124495−18−7)、(13.7)ビンクロゾリン(50471−44−8);
(14) 脱共役剤として作用し得る化合物、例えば、(14.1)ビナパクリル(485−31−4)、(14.2)ジノカップ(131−72−6)、(14.3)フェリムゾン(89269−64−7)、(14.4)フルアジナム(79622−59−6)、(14.5)メプチルジノカップ(131−72−6);
(15) さらなる化合物、例えば、(15.1)ベンチアゾール(21564−17−0)、(15.2)ベトキサジン(163269−30−5)、(15.3)カプシマイシン(capsimycin)(70694−08−5)、(15.4)カルボン(99−49−0)、(15.5)キノメチオネート(2439−01−2)、(15.6)ピリオフェノン(クラザフェノン(chlazafenone))(688046−61−9)、(15.7)クフラネブ(11096−18−7)、(15.8)シフルフェナミド(180409−60−3)、(15.9)シモキサニル(57966−95−7)、(15.10)シプロスルファミド(221667−31−8)、(15.11)ダゾメット(533−74−4)、(15.12)デバカルブ(62732−91−6)、(15.13)ジクロロフェン(97−23−4)、(15.14)ジクロメジン(62865−36−5)、(15.15)ジフェンゾコート(49866−87−7)、(15.16)ジフェンゾコートメチル硫酸塩(43222−48−6)、(15.17)ジフェニルアミン(122−39−4)、(15.18)エコメイト、(15.19)フェンピラザミン(473798−59−3)、(15.20)フルメトベル(154025−04−4)、(15.21)フルオルイミド(41205−21−4)、(15.22)フルスルファミド(106917−52−6)、(15.23)フルチアニル(304900−25−2)、(15.24)ホセチル−アルミニウム(39148−24−8)、(15.25)ホセチル−カルシウム、(15.26)ホセチル−ナトリウム(39148−16−8)、(15.27)ヘキサクロロベンゼン(118−74−1)、(15.28)イルママイシン(81604−73−1)、(15.29)メタスルホカルブ(66952−49−6)、(15.30)イソチオシアン酸メチル(556−61−6)、(15.31)メトラフェノン(220899−03−6)、(15.32)ミルディオマイシン(67527−71−3)、(15.33)ナタマイシン(7681−93−8)、(15.34)ジメチルジチオカルバミン酸ニッケル(15521−65−0)、(15.35)ニトロタル−イソプロピル(10552−74−6)、(15.36)オクチリノン(26530−20−1)、(15.37)オキサモカルブ(oxamocarb)(917242−12−7)、(15.38)オキシフェンチイン(oxyfenthiin)(34407−87−9)、(15.39)ペンタクロロフェノール及び塩(87−86−5)、(15.40)フェノトリン、(15.41)亜リン酸及びその塩(13598−36−2)、(15.42)プロパモカルブ−ホセチレート(propamocarb−fosetylate)、(15.43)プロパノシン−ナトリウム(propanosine−sodium)(88498−02−6)、(15.44)プロキナジド(189278−12−4)、(15.45)ピリモルフ(868390−90−3)、(15.45e)(2E)−3−(4−tert−ブチルフェニル)−3−(2−クロロピリジン−4−イル)−1−(モルホリン−4−イル)プロパ−2−エン−1−オン(1231776−28−5)、(15.45z)(2Z)−3−(4−tert−ブチルフェニル)−3−(2−クロロピリジン−4−イル)−1−(モルホリン−4−イル)プロパ−2−エン−1−オン(1231776−29−6)、(15.46)ピロールニトリン(1018−71−9)、(15.47)テブフロキン(376645−78−2)、(15.48)テクロフタラム(76280−91−6)、(15.49)トルニファニド(304911−98−6)、(15.50)トリアゾキシド(72459−58−6)、(15.51)トリクラミド(70193−21−4)、(15.52)ザリラミド(84527−51−5)、(15.53)(3S,6S,7R,8R)−8−ベンジル−3−[({3−[(イソブチリルオキシ)メトキシ]−4−メトキシピリジン−2−イル}カルボニル)アミノ]−6−メチル−4,9−ジオキソ−1,5−ジオキソナン−7−イル 2−メチルプロパノエート(517875−34−2)、(15.54)1−(4−{4−[(5R)−5−(2,6−ジフルオロフェニル)−4,5−ジヒドロ−1,2−オキサゾール−3−イル]−1,3−チアゾール−2−イル}ピペリジン−1−イル)−2−[5−メチル−3−(トリフルオロメチル)−1H−ピラゾール−1−イル]エタノン(1003319−79−6)、(15.55)1−(4−{4−[(5S)−5−(2,6−ジフルオロフェニル)−4,5−ジヒドロ−1,2−オキサゾール−3−イル]−1,3−チアゾール−2−イル}ピペリジン−1−イル)−2−[5−メチル−3−(トリフルオロメチル)−1H−ピラゾール−1−イル]エタノン(1003319−80−9)、(15.56)1−(4−{4−[5−(2,6−ジフルオロフェニル)−4,5−ジヒドロ−1,2−オキサゾール−3−イル]−1,3−チアゾール−2−イル}ピペリジン−1−イル)−2−[5−メチル−3−(トリフルオロメチル)−1H−ピラゾール−1−イル]エタノン(1003318−67−9)、(15.57)1−(4−メトキシフェノキシ)−3,3−ジメチルブタン−2−イル 1H−イミダゾール−1−カルボキシレート(111227−17−9)、(15.58)2,3,5,6−テトラクロロ−4−(メチルスルホニル)ピリジン(13108−52−6)、(15.59)2,3−ジブチル−6−クロロチエノ[2,3−d]ピリミジン−4(3H)−オン(221451−58−7)、(15.60)2,6−ジメチル−1H,5H−[1,4]ジチイノ[2,3−c:5,6−c’]ジピロール−1,3,5,7(2H,6H)−テトロン、(15.61)2−[5−メチル−3−(トリフルオロメチル)−1H−ピラゾール−1−イル]−1−(4−{4−[(5R)−5−フェニル−4,5−ジヒドロ−1,2−オキサゾール−3−イル]−1,3−チアゾール−2−イル}ピペリジン−1−イル)エタノン(1003316−53−7)、(15.62)2−[5−メチル−3−(トリフルオロメチル)−1H−ピラゾール−1−イル]−1−(4−{4−[(5S)−5−フェニル−4,5−ジヒドロ−1,2−オキサゾール−3−イル]−1,3−チアゾール−2−イル}ピペリジン−1−イル)エタノン(1003316−54−8)、(15.63)2−[5−メチル−3−(トリフルオロメチル)−1H−ピラゾール−1−イル]−1−{4−[4−(5−フェニル−4,5−ジヒドロ−1,2−オキサゾール−3−イル)−1,3−チアゾール−2−イル]ピペリジン−1−イル}エタノン(1003316−51−5)、(15.64)2−ブトキシ−6−ヨード−3−プロピル−4H−クロメン−4−オン、(15.65)2−クロロ−5−[2−クロロ−1−(2,6−ジフルオロ−4−メトキシフェニル)−4−メチル−1H−イミダゾール−5−イル]ピリジン、(15.66)2−フェニルフェノール及び塩(90−43−7)、(15.67)3−(4,4,5−トリフルオロ−3,3−ジメチル−3,4−ジヒドロイソキノリン−1−イル)キノリン(861647−85−0)、(15.68)3,4,5−トリクロロピリジン−2,6−ジカルボニトリル(17824−85−0)、(15.69)3−[5−(4−クロロフェニル)−2,3−ジメチル−1,2−オキサゾリジン−3−イル]ピリジン、(15.70)3−クロロ−5−(4−クロロフェニル)−4−(2,6−ジフルオロフェニル)−6−メチルピリダジン、(15.71)4−(4−クロロフェニル)−5−(2,6−ジフルオロフェニル)−3,6−ジメチルピリダジン、(15.72)5−アミノ−1,3,4−チアジアゾール−2−チオール、(15.73)5−クロロ−N’−フェニル−N’−(プロパ−2−イン−1−イル)チオフェン−2−スルホノヒドラジド(134−31−6)、(15.74)5−フルオロ−2−[(4−フルオロベンジル)オキシ]ピリミジン−4−アミン(1174376−11−4)、(15.75)5−フルオロ−2−[(4−メチルベンジル)オキシ]ピリミジン−4−アミン(1174376−25−0)、(15.76)5−メチル−6−オクチル[1,2,4]トリアゾロ[1,5−a]ピリミジン−7−アミン、(15.77)(2Z)−3−アミノ−2−シアノ−3−フェニルプロパ−2−エン酸エチル、(15.78)N’−(4−{[3−(4−クロロベンジル)−1,2,4−チアジアゾール−5−イル]オキシ}−2,5−ジメチルフェニル)−N−エチル−N−メチルイミドホルムアミド、(15.79)N−(4−クロロベンジル)−3−[3−メトキシ−4−(プロパ−2−イン−1−イルオキシ)フェニル]プロパンアミド、(15.80)N−[(4−クロロフェニル)(シアノ)メチル]−3−[3−メトキシ−4−(プロパ−2−イン−1−イルオキシ)フェニル]プロパンアミド、(15.81)N−[(5−ブロモ−3−クロロピリジン−2−イル)メチル]−2,4−ジクロロピリジン−3−カルボキサミド、(15.82)N−[1−(5−ブロモ−3−クロロピリジン−2−イル)エチル]−2,4−ジクロロピリジン−3−カルボキサミド、(15.83)N−[1−(5−ブロモ−3−クロロピリジン−2−イル)エチル]−2−フルオロ−4−ヨードピリジン−3−カルボキサミド、(15.84)N−{(E)−[(シクロプロピルメトキシ)イミノ][6−(ジフルオロメトキシ)−2,3−ジフルオロフェニル]メチル}−2−フェニルアセトアミド(221201−92−9)、(15.85)N−{(Z)−[(シクロプロピルメトキシ)イミノ][6−(ジフルオロメトキシ)−2,3−ジフルオロフェニル]メチル}−2−フェニルアセトアミド(221201−92−9)、(15.86)N’−{4−[(3−tert−ブチル−4−シアノ−1,2−チアゾール−5−イル)オキシ]−2−クロロ−5−メチルフェニル}−N−エチル−N−メチルイミドホルムアミド、(15.87)N−メチル−2−(1−{[5−メチル−3−(トリフルオロメチル)−1H−ピラゾール−1−イル]アセチル}ピペリジン−4−イル)−N−(1,2,3,4−テトラヒドロナフタレン−1−イル)−1,3−チアゾール−4−カルボキサミド(922514−49−6)、(15.88)N−メチル−2−(1−{[5−メチル−3−(トリフルオロメチル)−1H−ピラゾール−1−イル]アセチル}ピペリジン−4−イル)−N−[(1R)−1,2,3,4−テトラヒドロナフタレン−1−イル]−1,3−チアゾール−4−カルボキサミド(922514−07−6)、(15.89)N−メチル−2−(1−{[5−メチル−3−(トリフルオロメチル)−1H−ピラゾール−1−イル]アセチル}ピペリジン−4−イル)−N−[(1S)−1,2,3,4−テトラヒドロナフタレン−1−イル]−1,3−チアゾール−4−カルボキサミド(922514−48−5)、(15.90){6−[({[(1−メチル−1H−テトラゾール−5−イル)(フェニル)メチリデン]アミノ}オキシ)メチル]ピリジン−2−イル}カルバミン酸ペンチル、(15.91)フェナジン−1−カルボン酸、(15.92)キノリン−8−オール(134−31−6)、(15.93)キノリン−8−オールスルフェート(2:1)(134−31−6)、(15.94){6−[({[(1−メチル−1H−テトラゾール−5−イル)(フェニル)メチレン]アミノ}オキシ)メチル]ピリジン−2−イル}カルバミン酸tert−ブチル;
(16) さらなる化合物、例えば、(16.1)1−メチル−3−(トリフルオロメチル)−N−[2’−(トリフルオロメチル)ビフェニル−2−イル]−1H−ピラゾール−4−カルボキサミド、(16.2)N−(4’−クロロビフェニル−2−イル)−3−(ジフルオロメチル)−1−メチル−1H−ピラゾール−4−カルボキサミド、(16.3)N−(2’,4’−ジクロロビフェニル−2−イル)−3−(ジフルオロメチル)−1−メチル−1H−ピラゾール−4−カルボキサミド、(16.4)3−(ジフルオロメチル)−1−メチル−N−[4’−(トリフルオロメチル)ビフェニル−2−イル]−1H−ピラゾール−4−カルボキサミド、(16.5)N−(2’,5’−ジフルオロビフェニル−2−イル)−1−メチル−3−(トリフルオロメチル)−1H−ピラゾール−4−カルボキサミド、(16.6)3−(ジフルオロメチル)−1−メチル−N−[4’−(プロパ−1−イン−1−イル)ビフェニル−2−イル]−1H−ピラゾール−4−カルボキサミド、(16.7)5−フルオロ−1,3−ジメチル−N−[4’−(プロパ−1−イン−1−イル)ビフェニル−2−イル]−1H−ピラゾール−4−カルボキサミド、(16.8)2−クロロ−N−[4’−(プロパ−1−イン−1−イル)ビフェニル−2−イル]ピリジン−3−カルボキサミド、(16.9)3−(ジフルオロメチル)−N−[4’−(3,3−ジメチルブタ−1−イン−1−イル)ビフェニル−2−イル]−1−メチル−1H−ピラゾール−4−カルボキサミド、(16.10)N−[4’−(3,3−ジメチルブタ−1−イン−1−イル)ビフェニル−2−イル]−5−フルオロ−1,3−ジメチル−1H−ピラゾール−4−カルボキサミド、(16.11)3−(ジフルオロメチル)−N−(4’−エチニルビフェニル−2−イル)−1−メチル−1H−ピラゾール−4−カルボキサミド、(16.12)N−(4’−エチニルビフェニル−2−イル)−5−フルオロ−1,3−ジメチル−1H−ピラゾール−4−カルボキサミド、(16.13)2−クロロ−N−(4’−エチニルビフェニル−2−イル)ピリジン−3−カルボキサミド、(16.14)2−クロロ−N−[4’−(3,3−ジメチルブタ−1−イン−1−イル)ビフェニル−2−イル]ピリジン−3−カルボキサミド、(16.15)4−(ジフルオロメチル)−2−メチル−N−[4’−(トリフルオロメチル)ビフェニル−2−イル]−1,3−チアゾール−5−カルボキサミド、(16.16)5−フルオロ−N−[4’−(3−ヒドロキシ−3−メチルブタ−1−イン−1−イル)ビフェニル−2−イル]−1,3−ジメチル−1H−ピラゾール−4−カルボキサミド、(16.17)2−クロロ−N−[4’−(3−ヒドロキシ−3−メチルブタ−1−イン−1−イル)ビフェニル−2−イル]ピリジン−3−カルボキサミド、(16.18)3−(ジフルオロメチル)−N−[4’−(3−メトキシ−3−メチルブタ−1−イン−1−イル)ビフェニル−2−イル]−1−メチル−1H−ピラゾール−4−カルボキサミド、(16.19)5−フルオロ−N−[4’−(3−メトキシ−3−メチルブタ−1−イン−1−イル)ビフェニル−2−イル]−1,3−ジメチル−1H−ピラゾール−4−カルボキサミド、(16.20)2−クロロ−N−[4’−(3−メトキシ−3−メチルブタ−1−イン−1−イル)ビフェニル−2−イル]ピリジン−3−カルボキサミド、(16.21)(5−ブロモ−2−メトキシ−4−メチルピリジン−3−イル)(2,3,4−トリメトキシ−6−メチルフェニル)メタノン、(16.22)N−[2−(4−{[3−(4−クロロフェニル)プロパ−2−イン−1−イル]オキシ}−3−メトキシフェニル)エチル]−N2−(メチルスルホニル)バリンアミド(220706−93−4)、(16.23)4−オキソ−4−[(2−フェニルエチル)アミノ]ブタン酸、(16.24)ブタ−3−イン−1−イル {6−[({[(Z)−(1−メチル−1H−テトラゾール−5−イル)(フェニル)メチレン]アミノ}オキシ)メチル]ピリジン−2−イル}カルバメート、(16.25)4−アミノ−5−フルオロピリミジン−2−オール(メソメリック形態:6−アミノ−5−フルオロピリミジン−2(1H)−オン)、(16.26)3,4,5−トリヒドロキシ安息香酸プロピル。
(2.1)ビキサフェン、(2.2)ボスカリド、(2.6)フルオピラム、(2.8)フルキサピロキサド、(2.11)イソピラザム(シン−エピマー性ラセミ化合物(1RS,4SR,9RS)とアンチ−エピマー性ラセミ化合物(1RS,4SR,9SR)の混合物)、(2.12)イソピラザム(アンチ−エピマー性ラセミ化合物 1RS,4SR,9SR)、(2.13)イソピラザム(アンチ−エピマー性エナンチオマー 1R,4S,9S)、(2.14)イソピラザム(アンチ−エピマー性エナンチオマー 1S,4R,9R)、(2.15)イソピラザム(シン−エピマー性ラセミ化合物 1RS,4SR,9RS)、(2.16)イソピラザム(シン−エピマー性エナンチオマー 1R,4S,9R)、(2.17)イソピラザム(シン−エピマー性エナンチオマー 1S,4R,9S)、(2.27)N−[1−(2,4−ジクロロフェニル)−1−メトキシプロパン−2−イル]−3−(ジフルオロメチル)−1−メチル−1H−ピラゾール−4−カルボキサミド、(2.29)N−[9−(ジクロロメチレン)−1,2,3,4−テトラヒドロ−1,4−メタノナフタレン−5−イル]−3−(ジフルオロメチル)−1−メチル−1H−ピラゾール−4−カルボキサミド、(3.1)アメトクトラジン、(3.2)アミスルブロム、(3.3)アゾキシストロビン、(3.4)シアゾファミド、(3.9)ファモキサドン、(3.10)フェンアミドン、(3.12)フルオキサストロビン、(3.16)ピコキシストロビン、(3.17)ピラクロストロビン、(3.22)トリフロキシストロビン、(4.6)フルオピコリド、(5.1)ボルドー液、(5.4)クロロタロニル、(5.5)水酸化銅、(5.7)酸化銅、(5.8)塩基性塩化銅、(5.9)硫酸銅(2+)、(5.16)ホルペット、(5.23)マンゼブ、(5.25)メチラム、(5.26)メチラム亜鉛、(5.29)プロピネブ、(5.30)硫黄及び硫黄剤、例えば、多硫化カルシウム、(7.7)ピリメタニル、(9.2)ジメトモルフ、(9.4)イプロバリカルブ、(9.5)マンジプロパミド、(10.9)プロパモカルブ、(10.10)プロパモカルブ塩酸塩、(12.9)メタラキシル、(12.10)メタラキシル−M(メフェノキサム)、(14.4)フルアジナム、(15.9)シモキサニル、(15.24)ホセチル−アルミニウム、(15.25)ホセチル−カルシウム、(15.26)ホセチル−ナトリウム、(15.41)亜リン酸及びその塩、(15.42)プロパモカルブ−ホセチレート、(15.54)1−(4−{4−[(5R)−5−(2,6−ジフルオロフェニル)−4,5−ジヒドロ−1,2−オキサゾール−3−イル]−1,3−チアゾール−2−イル}ピペリジン−1−イル)−2−[5−メチル−3−(トリフルオロメチル)−1H−ピラゾール−1−イル]エタノン、(15.55)1−(4−{4−[(5S)−5−(2,6−ジフルオロフェニル)−4,5−ジヒドロ−1,2−オキサゾール−3−イル]−1,3−チアゾール−2−イル}ピペリジン−1−イル)−2−[5−メチル−3−(トリフルオロメチル)−1H−ピラゾール−1−イル]エタノン、(15.56)1−(4−{4−[5−(2,6−ジフルオロフェニル)−4,5−ジヒドロ−1,2−オキサゾール−3−イル]−1,3−チアゾール−2−イル}ピペリジン−1−イル)−2−[5−メチル−3−(トリフルオロメチル)−1H−ピラゾール−1−イル]エタノン、(15.60)2,6−ジメチル−1H,5H−[1,4]ジチイノ[2,3−c:5,6−c’]ジピロール−1,3,5,7(2H,6H)−テトロン、(15.90){6−[({[(1−メチル−1H−テトラゾール−5−イル)(フェニル)メチリデン]アミノ}オキシ)メチル]ピリジン−2−イル}カルバミン酸ペンチル。
本発明は、さらに、本発明による活性化合物組合せを含んでいる、望ましくない微生物を駆除する(combating)/防除するための組成物にも関する。好ましくは、該組成物は、農業上適切な補助剤、溶媒、担体、界面活性剤又は増量剤を含んでいる殺菌剤組成物である。
本発明の活性成分又は組成物は、強力な殺微生物活性(microbicidal activity)を有しており、作物保護と材料物質(materials)の保護において、望ましくない微生物(例えば、菌類及び細菌類)を防除するために使用することができる
本発明は、さらに、望ましくない微生物を防除する方法にも関し、ここで、該方法は、本発明の活性成分を当該植物病原性菌類、植物病原性細菌類及び/又はそれらの生息環境に施用することを特徴とする。
・ 例えば以下のような、うどんこ病病原体に起因する病害: ブルメリア属各種(Blumeria species)、例えば、ブルメリア・グラミニス(Blumeria graminis); ポドスファエラ属各種(Podosphaera species)、例えば、ポドスファエラ・レウコトリカ(Podosphaera leucotricha); スファエロテカ属各種(Sphaerotheca species)、例えば、スファエロテカ・フリギネア(Sphaerotheca fuliginea); ウンシヌラ属各種(Uncinula species)、例えば、ウンシヌラ・ネカトル(Uncinula necator);
・ 例えば以下のような、さび病病原体に起因する病害: ギムノスポランギウム属各種(Gymnosporangium species)、例えば、ギムノスポランギウム・サビナエ(Gymnosporangium sabinae); ヘミレイア属各種(Hemileia species)、例えば、ヘミレイア・バスタトリクス(Hemileia vastatrix); ファコプソラ属各種(Phakopsora species)、例えば、ファコプソラ・パキリジ(Phakopsora pachyrhizi)及びファコプソラ・メイボミアエ(Phakopsora meibomiae); プッシニア属各種(Puccinia species)、例えば、プッシニア・レコンジテ(Puccinia recondite)、プッシニア・トリチシナ(P. triticina)、プッシニア・グラミニス(P. graminis)又はプッシニア・ストリイホルミス(P. striiformis); ウロミセス属各種(Uromyces species)、例えば、ウロミセス・アペンジクラツス(Uromyces appendiculatus);
・ 例えば以下のような、卵菌類(Oomycetes)の群の病原体に起因する病害: アルブゴ属各種(Albugo species)、例えば、アルブゴ・カンジダ(Albugo candida); ブレミア属各種(Bremia species)、例えば、ブレミア・ラクツカエ(Bremia lactucae); ペロノスポラ属各種(Peronospora species)、例えば、ペロノスポラ・ピシ(Peronospora pisi)又はペロノスポラ・ブラシカエ(P. brassicae); フィトフトラ属各種(Phytophthora species)、例えば、フィトフトラ・インフェスタンス(Phytophthora infestans); プラスモパラ属各種(Plasmopara species)、例えば、プラスモパラ・ビチコラ(Plasmopara viticola); プセウドペロノスポラ属各種(Pseudoperonospora species)、例えば、プセウドペロノスポラ・フムリ(Pseudoperonospora humuli)又はプセウドペロノスポラ・クベンシス(Pseudoperonospora cubensis); ピシウム属各種(Pythium species)、例えば、ピシウム・ウルチムム(Pythium ultimum);
・ 例えば以下のものに起因する、斑点病(leaf blotch disease)及び萎凋病(leaf wilt disease): アルテルナリア属各種(Alternaria species)、例えば、アルテルナリア・ソラニ(Alternaria solani); セルコスポラ属各種(Cercospora species)、例えば、セルコスポラ・ベチコラ(Cercospora beticola); クラジオスポリウム属各種(Cladiosporium species)、例えば、クラジオスポリウム・ククメリヌム(Cladiosporium cucumerinum); コクリオボルス属各種(Cochliobolus species)、例えば、コクリオボルス・サチブス(Cochliobolus sativus)(分生子形態:Drechslera, 同義語:Helminthosporium)、コクリオボルス・ミヤベアヌス(Cochliobolus miyabeanus); コレトトリクム属各種(Colletotrichum species)、例えば、コレトトリクム・リンデムタニウム(Colletotrichum lindemuthanium); シクロコニウム属各種(Cycloconium species)、例えば、シクロコニウム・オレアギヌム(Cycloconium oleaginum); ジアポルテ属各種(Diaporthe species)、例えば、ジアポルテ・シトリ(Diaporthe citri); エルシノエ属各種(Elsinoe species)、例えば、エルシノエ・ファウセッチイ(Elsinoe fawcettii); グロエオスポリウム属各種(Gloeosporium species)、例えば、グロエオスポリウム・ラエチコロル(Gloeosporium laeticolor); グロメレラ属各種(Glomerella species)、例えば、グロメレラ・シングラタ(Glomerella cingulata); グイグナルジア属各種(Guignardia species)、例えば、グイグナルジア・ビドウェリ(Guignardia bidwelli); レプトスファエリア属各種(Leptosphaeria species)、例えば、レプトスファエリア・マクランス(Leptosphaeria maculans)、レプトスファエリア・ノドルム(Leptosphaeria nodorum); マグナポルテ属各種(Magnaporthe species)、例えば、マグナポルテ・グリセア(Magnaporthe grisea); ミクロドキウム属各種(Microdochium species)、例えば、ミクロドキウム・ニバレ(Microdochium nivale); ミコスファエレラ属各種(Mycosphaerella species)、例えば、ミコスファエレラ・グラミニコラ(Mycosphaerella graminicola)、ミコスファエレラ・アラキジコラ(M. arachidicola)及びミコスファエレラ・フィジエンシス(M. fijiensis); ファエオスファエリア属各種(Phaeosphaeria species)、例えば、ファエオスファエリア・ノドルム(Phaeosphaeria nodorum); ピレノホラ属各種(Pyrenophora species)、例えば、ピレノホラ・テレス(Pyrenophora teres)、ピレノホラ・トリチシ・レペンチス(Pyrenophora tritici repentis); ラムラリア属各種(Ramularia species)、例えば、ラムラリア・コロ−シグニ(Ramularia collo−cygni)、ラムラリア・アレオラ(Ramularia areola); リンコスポリウム属各種(Rhynchosporium species)、例えば、リンコスポリウム・セカリス(Rhynchosporium secalis); セプトリア属各種(Septoria species)、例えば、セプトリア・アピイ(Septoria apii)、セプトリア・リコペルシイ(Septoria lycopersii); チフラ属各種(Typhula species)、例えば、チフラ・インカルナタ(Typhula incarnata); ベンツリア属各種(Venturia species)、例えば、ベンツリア・イナエクアリス(Venturia inaequalis);
・ 例えば以下のものに起因する、根及び茎の病害: コルチシウム属各種(Corticium species)、例えば、コルチシウム・グラミネアルム(Corticium graminearum); フサリウム属各種(Fusarium species)、例えば、フサリウム・オキシスポルム(Fusarium oxysporum); ガエウマンノミセス属各種(Gaeumannomyces species)、例えば、ガエウマンノミセス・グラミニス(Gaeumannomyces graminis); リゾクトニア属各種(Rhizoctonia species)、例えば、リゾクトニア・ソラニ(Rhizoctonia solani); サロクラジウム(Sarocladium)病、これは、例えば、サロクラジウム・オリザエ(Sarocladium oryzae)に起因する; スクレロチウム(Sclerotium)病、これは、例えば、スクレロチウム・オリザエ(Sclerotium oryzae)に起因する; タペシア属各種(Tapesia species)、例えば、タペシア・アクホルミス(Tapesia acuformis); チエラビオプシス属各種(Thielaviopsis species)、例えば、チエラビオプシス・バシコラ(Thielaviopsis basicola);
・ 例えば以下のものに起因する、穂の病害(ear and panicle disease)(トウモロコシの穂軸を包含する): アルテルナリア属各種(Alternaria species)、例えば、アルテルナリア属種(Alternaria spp.); アスペルギルス属各種(Aspergillus species)、例えば、アスペルギルス・フラブス(Aspergillus flavus); クラドスポリウム属各種(Cladosporium species)、例えば、クラドスポリウム・クラドスポリオイデス(Cladosporium cladosporioides); クラビセプス属各種(Claviceps species)、例えば、クラビセプス・プルプレア(Claviceps purpurea); フサリウム属各種(Fusarium species)、例えば、フサリウム・クルモルム(Fusarium culmorum); ジベレラ属各種(Gibberella species)、例えば、ジベレラ・ゼアエ(Gibberella zeae); モノグラフェラ属各種(Monographella species)、例えば、モノグラフェラ・ニバリス(Monographella nivalis); セプトリア属各種(Septoria species)、例えば、セプトリア・ノドルム(Septoria nodorum);
・ 例えば以下のものなどの、黒穂病菌類(smut fungi)に起因する病害: スファセロテカ属各種(Sphacelotheca species)、例えば、スファセロテカ・レイリアナ(Sphacelotheca reiliana); チレチア属各種(Tilletia species)、例えば、チレチア・カリエス(Tilletia caries)、チレチア・コントロベルサ(T. controversa); ウロシスチス属各種(Urocystis species)、例えば、ウロシスチス・オクルタ(Urocystis occulta); ウスチラゴ属各種(Ustilago species)、例えば、ウスチラゴ・ヌダ(Ustilago nuda)、ウスチラゴ・ヌダ・トリチシ(U. nuda tritici);
・ 例えば以下のものに起因する、果実の腐敗(fruit rot): アスペルギルス属各種(Aspergillus species)、例えば、アスペルギルス・フラブス(Aspergillus flavus); ボトリチス属各種(Botrytis species)、例えば、ボトリチス・シネレア(Botrytis cinerea); ペニシリウム属各種(Penicillium species)、例えば、ペニシリウム・エキスパンスム(Penicillium expansum)及びペニシリウム・プルプロゲヌム(P. purpurogenum); スクレロチニア属各種(Sclerotinia species)、例えば、スクレロチニア・スクレロチオルム(Sclerotinia sclerotiorum); ベルチシリウム属各種(Verticilium species)、例えば、ベルチシリウム・アルボアトルム(Verticilium alboatrum);
・ 例えば以下のものに起因する、種子及び土壌が媒介する腐朽性、黴性、萎凋性、腐敗性及び苗立ち枯れ性の病害(seed and soilborne decay, mould, wilt, rot and damping−off disease): アルテルナリア属各種(Alternaria species)、例えば、アルテルナリア・ブラシシコラ(Alternaria brassicicola)に起因する; アファノミセス属各種(Aphanomyces species)、例えば、アファノミセス・エウテイケス(Aphanomyces euteiches)に起因する; アスコキタ属各種(Ascochyta species)、例えば、アスコキタ・レンチス(Ascochyta lentis)に起因する; アスペルギルス属各種(Aspergillus species)、例えば、アスペルギルス・フラブス(Aspergillus flavus)に起因する; クラドスポリウム属各種(Cladosporium species)、例えば、クラドスポリウム・ヘルバルム(Cladosporium herbarum)に起因する; コクリオボルス属各種(Cochliobolus species)、例えば、コクリオボルス・サチブス(Cochliobolus sativus)に起因する;(分生子形態:Drechslera、Bipolaris 異名:Helminthosporium); コレトトリクム属各種(Colletotrichum species)、例えば、コレトトリクム・ココデス(Colletotrichum coccodes)に起因する; フサリウム属各種(Fusarium species)、例えば、フサリウム・クルモルム(Fusarium culmorum)に起因する; ジベレラ属各種(Gibberella species)、例えば、ジベレラ・ゼアエ(Gibberella zeae)に起因する; マクロホミナ属各種(Macrophomina species)、例えば、マクロホミナ・ファセオリナ(Macrophomina phaseolina)に起因する; モノグラフェラ属各種(Monographella species)、例えば、モノグラフェラ・ニバリス(Monographella nivalis)に起因する; ペニシリウム属各種(Penicillium species)、例えば、ペニシリウム・エキスパンスム(Penicillium expansum)に起因する; ホマ属各種(Phoma species)、例えば、ホマ・リンガム(Phoma lingam)に起因する; ホモプシス属各種(Phomopsis species)、例えば、ホモプシス・ソジャエ(Phomopsis sojae)に起因する; フィトフトラ属各種(Phytophthora species)、例えば、フィトフトラ・カクトルム(Phytophthora cactorum)に起因する; ピレノホラ属各種(Pyrenophora species)、例えば、ピレノホラ・グラミネア(Pyrenophora graminea)に起因する; ピリクラリア属各種(Pyricularia species)、例えば、ピリクラリア・オリザエ(Pyricularia oryzae)に起因する; ピシウム属各種(Pythium species)、例えば、ピシウム・ウルチムム(Pythium ultimum)に起因する; リゾクトニア属各種(Rhizoctonia species)、例えば、リゾクトニア・ソラニ(Rhizoctonia solani)に起因する; リゾプス属各種(Rhizopus species)、例えば、リゾプス・オリザエ(Rhizopus oryzae)に起因する; スクレロチウム属各種(Sclerotium species)、例えば、スクレロチウム・ロルフシイ(Sclerotium rolfsii)に起因する; セプトリア属各種(Septoria species)、例えば、セプトリア・ノドルム(Septoria nodorum)に起因する; チフラ属各種(Typhula species)、例えば、チフラ・インカルナタ(Typhula incarnata)に起因する; ベルチシリウム属各種(Verticillium species)、例えば、ベルチシリウム・ダーリアエ(Verticillium dahliae)に起因する;
・ 例えば以下のものに起因する、癌性病害(cancer)、こぶ(gall)及び天狗巣病(witches’ broom): 例えば、ネクトリア属各種(Nectria species)、例えば、ネクトリア・ガリゲナ(Nectria galligena);
・ 例えば以下のものに起因する、萎凋病(wilt disease): モニリニア属各種(Monilinia species): 例えば、モニリニア・ラキサ(Monilinia laxa);
・ 例えば以下のものに起因する、葉水泡性病害又は縮葉病(leaf blister or leaf curl disease): 例えば、エキソバシジウム属各種(Exobasidium species)、例えば、エキソバシジウム・ベキサンス(Exobasidium vexans); タフリナ属各種(Taphrina species)、例えば、タフリナ・デホルマンス(Taphrina deformans);
・ 例えば以下のものに起因する、木本植物の衰退性病害(decline disease of wooden plant): エスカ(Esca)病、これは、例えば、ファエオモニエラ・クラミドスポラ(Phaemoniella clamydospora)、ファエオアクレモニウム・アレオフィルム(Phaeoacremonium aleophilum)及びフォミチポリア・メジテラネア(Fomitiporia mediterranea)に起因する;ユーティパダイバック病(Eutypa dyeback)、これは、例えば、ユーティパ・ラタ(Eutypa lata)に起因する; ガノデルマ(Ganoderma)病、これは、例えば、ガノデルマ・ボニネンセ(Ganoderma boninense)に起因する;リジドポルス(Rigidoporus)病、これは、例えば、リジドポルス・リグノスス(Rigidoporus lignosus)に起因する;
・ 例えば以下のものに起因する、花及び種子の病害: ボトリチス属各種(Botrytis species)、例えば、ボトリチス・シネレア(Botrytis cinerea);
・ 例えば以下のものに起因する、植物塊茎の病害: リゾクトニア属各種(Rhizoctonia species)、例えば、リゾクトニア・ソラニ(Rhizoctonia solani); ヘルミントスポリウム属各種(Helminthosporium species)、例えば、ヘルミントスポリウム・ソラニ(Helminthosporium solani);
・ 例えば以下のものに起因する、根瘤病(club root): プラスモジオホラ属各種(Plasmodiophora species)、例えば、プラスモジオホラ・ブラシカエ(Plamodiophora brassicae);
・ 例えば以下のものなどの、細菌性病原体に起因する病害: キサントモナス属各種(Xanthomonas species)、例えば、キサントモナス・カムペストリス pv.オリザエ(Xanthomonas campestris pv. oryzae); シュードモナス属各種(Pseudomonas species)、例えば、シュードモナス・シリンガエ pv.ラクリマンス(Pseudomonas syringae pv. lachrymans); エルウィニア属各種(Erwinia species)、例えば、エルウィニア・アミロボラ(Erwinia amylovora)。
・ 例えば以下のものに起因する、葉、茎、鞘及び種子の菌類病:
アルテルナリア斑点病(alternaria leaf spot)(Alternaria spec. atrans tenuissima)、炭疽病(Colletotrichum gloeosporoides dematium var. truncatum)、褐紋病(brown spot)(Septoria glycines)、紫斑病(cercospora leaf spot and blight)(Cercospora kikuchii)、コアネホラ葉枯病(choanephora leaf blight)(Choanephora infundibulifera trispora(Syn.))、ダクツリオホラ斑点病(dactuliophora leaf spot)(Dactuliophora glycines)、べと病(Peronospora manshurica)、ドレクスレラ胴枯病(drechslera blight)(Drechslera glycini)、斑点病(frogeye leaf spot)(Cercospora sojina)、そばかす病(leptosphaerulina leaf spot)(Leptosphaerulina trifolii)、灰星病(phyllostica leaf spot)(Phyllosticta sojaecola)、黒点病(pod and stem blight)(Phomopsis sojae)、うどんこ病(Microsphaera diffusa)、ピレノカエタ斑点病(pyrenochaeta leaf spot)(Pyrenochaeta glycines)、葉腐病(rhizoctonia aerial, foliage, and web blight)(Rhizoctonia solani)、さび病(Phakopsora pachyrhizi, Phakopsora meibomiae)、黒とう病(Sphaceloma glycines)、ステムフィリウム葉枯病(stemphylium leaf blight)(Stemphylium botryosum)、褐色輪紋病(Corynespora cassiicola);
・ 例えば以下のものに起因する、根及び茎基部の菌類病:
黒根腐病(Calonectria crotalariae)、炭腐病(Macrophomina phaseolina)、赤かび病(fusarium blight or wilt, root rot, and pod and collar rot)(Fusarium oxysporum、Fusarium orthoceras、Fusarium semitectum、Fusarium equiseti)、ミコレプトジスクス根腐病(mycoleptodiscus root rot)(Mycoleptodiscus terrestris)、根腐病(neocosmospora)(Neocosmospora vasinfecta)、黒点病(Diaporthe phaseolorum)、茎腐爛病(stem canker)(Diaporthe phaseolorum var. caulivora)、茎疫病(phytophthora rot)(Phytophthora megasperma)、落葉病(brown stem rot)(Phialophora gregata)、根茎腐敗病(pythium rot)(Pythium aphanidermatum、Pythium irregulare、Pythium debaryanum、Pythium myriotylum、Pythium ultimum)、リゾクトニア根腐病(rhizoctonia root rot, stem decay, and damping−off)(Rhizoctonia solani)、菌核病(sclerotinia stem decay)(Sclerotinia sclerotiorum)、スクレロチニアサウザンブライト病(sclerotinia southern blight)(Sclerotinia rolfsii)、チエラビオプシス根腐病(thielaviopsis root rot)(Thielaviopsis basicola)。
以下のものにおけるアルブゴ属種(Albugo spp.)(白さび病):観賞植物、野菜作物(例えば、A.candida)及びヒマワリ(例えば、A.tragopogonis); 以下のものにおけるアルテルナリア属種(Alternaria spp.)(黒斑病、黒星病):野菜類、ナタネ(例えば、A.brassicola、又は、A.brassicae)、テンサイ(例えば、A.tenuis)、果実、イネ、ダイズ、及び、さらに、ジャガイモ(例えば、A.solani、又は、A.alternata)及びトマト(例えば、A.solani、又は、A.alternata)、並びに、以下のものにおけるアルテルナリア属種(Alternaria spp.)(黒頭病):コムギ; 以下のものにおけるアワノミセス属種(Aphanomyces spp.):テンサイ及び野菜類; 以下のものにおけるアスコキタ属種(Ascochyta spp.):禾穀類及び野菜類、例えば、コムギにおけるA.tritici(アスコキタ黒葉枯れ病)及びオオムギにおけるA.hordei; 以下のものにおけるビポラリス及びドレクスレラ属種(Bipolaris and Drechslera spp.)(テレオモルフ:コクリオボルス属種(Cochliobolus spp.))、例えば、トウモロコシにおける斑点病(D.maydis and B.zeicola)、例えば、禾穀類におけるふ枯病(B.sorokiniana)、及び、例えば、イネ及び芝生にけるB.oryzae; 以下のものにおけるブルメリア・グラミニス(Blumeria(旧名:Erysiphe)graminis)(うどんこ病):禾穀類(例えば、コムギ又はオオムギ); 以下のものにおけるボトリオスファエリア属種(Botryosphaeria spp.)(「スラック(Slack)ブドウ蔓割病」):ブドウの木(例えば、B.obtusa); 以下のものにおけるボトリチス・シネレア(Botrytis cinerea)(テレオモルフ:Botryotinia fuckeliana:灰色かび病、灰星病):小果樹及び仁果(特に、イチゴ)、野菜類(特に、レタス、ニンジン、セルリアック及びキャベツ)、ナタネ、花、ブドウの木、森林作物及びコムギ(穂のかび(ear mold)); 以下のものにおけるブレミア・ラクツカエ(Bremia lactucae)(べと病):レタス; 以下のものにおけるセラトシスチス属種(Ceratocystis(同義語.Ophiostoma)spp.)(青変菌):落葉樹及び針葉樹、例えば、ニレにおけるC.ulmi(ニレ立ち枯れ病); 以下のものにおけるセルコスポラ属種(Cercospora spp.)(セルコスポラ斑点病):トウモロコシ(例えば、C.zeae−maydis)、イネ、テンサイ(例えば、C.beticola)、サトウキビ、野菜類、コーヒー、ダイズ(例えば、C.sojina、又は、C.kikuchil)、及び、イネ; 以下のものにおけるクラドスポリウム属種(Cladosporium spp.):トマト(例えば、C.fulvum:トマト葉かび病)、及び、禾穀類、例えば、コムギにおけるC.herbarum(穂腐れ); 以下のものにおけるクラビセプス・プルプレア(Claviceps purpurea)(麦角):禾穀類; 以下のものにおけるコクリオボルス属種(Cochliobolus(アナモルフ:Helminthosporium、又は、Bipolaris)spp.)(斑点病):トウモロコシ(例えば、C.carbonum)、禾穀類(例えば、C.sativus、アナモルフ:B.sorokiniana:ふ枯病)、及び、イネ(例えば、C.miyabeanus、アナモルフ:H.oryzae); 以下のものにおけるコレトトリクム属種(Colletotrichum(テレオモルフ:Glomerella)spp.)(炭疽病):ワタ(例えば、C.gossypii)、トウモロコシ(例えば、C.graminicola:茎腐病及び炭疽病)、小果樹、ジャガイモ(例えば、C.coccodes:萎縮病)、インゲンマメ(例えば、C.lindemuthianum)、及び、ダイズ(例えば、C.truncatum); 以下のものにおけるコルチシウム属種(Corticium spp.)、例えば、イネにおけるC.sasakii(紋枯病); 以下のものにおけるコリネスポラ・カッシイコラ(Corynespora cassiicola)(斑点病):ダイズ、及び、観賞植物; 以下のものにおけるシクロコニウム属種(Cycloconium spp.)、例えば、オリーブにおけるC.oleaginum; 以下のものにおけるシリンドロカルポン属種(Cylindrocarpon spp.)(例えば、ブドウの木における果樹癌又は黒足病、テレオモルフ:Nectria、又は、Neonectria spp.):果実の木、ブドウの木(例えば、C.liriodendn;テレオモルフ:Neonectria liriodendri、黒足病)、及び、多くの種類の鑑賞樹; 以下のものにおけるデマトホラ・ネカトリクス(Dematophora(テレオモルフ:Rosellinia)necatrix)(根/茎腐れ):ダイズ; 以下のものにおけるジアポルテ属種(Diaporthe spp.)、例えば、ダイズにおけるD.phaseolorum(茎病害); 以下のものにおけるドレクスレラ属種(Drechslera(同義語 Helminthosporium、テレオモルフ:Pyrenophora)spp.):トウモロコシ、禾穀類、例えば、オオムギ(例えば、D.teres、網斑病)、並びに、コムギ(例えば、D.tritici−repentis:DTR斑点病)、イネ、及び、芝生; 以下のものにおけるエスカ病(Esca disease)(ブドウの枝枯れ、アポプレキシア(apoplexia)):ブドウの木、これは、以下のものに起因する:ホルミチポリア・プンクタタ(Formitiporia(同義語 Phellinus)punctata)、ホルミチポリア・メジテラネア(F mediterranea)、ファエオモニエラ・クラミドスポラ(Phaeomoniella chlamydospora)(旧名 Phaeoacremonium chlamydosporum)、ファエオアクレモニウム・アレオフィルム(Phaeoacremonium aleophilum)及び/又はボトリオスファエリア・オブツタ(Botryosphaeria obtusa); 以下のものにおけるエルシノエ属種(Elsinoe spp.):仁果(E.pyri)、及び、小果樹(E.veneta:anthracnosis)、及び、さらに、ブドウの木(E.ampelina:anthracnosis); 以下のものにおけるエンチロマ・オリザエ(Entyloma oryzae)(葉黒穂病):イネ; 以下のものにおけるエピコックム属種(Epicoccum spp.)(黒頭病):コムギ; 以下のものにおけるエリシフェ属種(Erysiphe spp.)(うどんこ病):テンサイ(E.betae)、野菜類(例えば、E.pisi)、例えば、キュウリ種(例えば、E.cichoracearum)、及び、キャベツ種、例えば、ナタネ(例えば、E.cruciferarum); 以下のものにおけるユーティパ・ファタ(Eutypa fata)(ユーティパ癌又は枝枯れ、アナモルフ:Cytosporina lata、同義語 Libertella blepharis):果樹、ブドウの木、及び、多くの種類の鑑賞樹; 以下のものにおけるエキスセロヒルム属種(Exserohilum(syn.Helminthosporium)spp.):トウモロコシ(例えば、E.turcicum); 以下のものにおけるフサリウム属種(Fusarium(テレオモルフ:Gibberella)spp.)(立ち枯れ病、根及び茎腐れ病):種々の植物、例えば、禾穀類(例えば、コムギ又はオオムギ)におけるF.graminearum又はF.culmorum(根腐れ及び葉先白斑病)、トマトにおけるF.oxysporum、ダイズにおけるF.solani、及び、トウモロコシにおけるF.verticillioides; 以下のものにおけるガエウマンノミセス・グラミニス(Gaeumannomyces graminis(立枯れ病)):禾穀類(例えば、コムギ又はオオムギ)、及び、トウモロコシ; 以下のものにおけるジベレラ属種(Gibberella spp.):禾穀類(例えば、G.zeae)、及び、イネ(例えば、G.fujikuroi:馬鹿苗病); 以下のものにおけるグロメレラ・シングラタ(Glomerella cingulata):ブドウの木、仁果、及び、別の植物、並びに、ワタにおけるG.gossypii;イネにおけるグラインスタイニング複合菌; 以下のものにおけるグイグナルジア・ビドウェリイ(Guignardia bidwellii)(黒斑病):ブドウの木; 以下のものにおけるギムノスポランギウム属種(Gymnosporangium spp.):バラ科、及び、ジュニパー、例えば、ナシにおけるG.sabinae(ナシさび病); 以下のものにおけるヘルミントスポリウム属種(Helminthosporium spp.)(同義語 Drechslera、テレオモルフ:Cochliobolus):トウモロコシ、禾穀類、及び、イネ; 以下のものにおけるヘミレイア属種(Hemileia spp.)、例えば、コーヒーにおけるH.vastatrix(コーヒー葉さび病); 以下のものにおけるイサリオプシス・クラビスポラ(Isariopsis clavispora)(同義語 Cladosporium vitis):ブドウの木; 以下のものにおけるマクロホミナ・ファセオリア(Macrophomina phaseolina)(同義語 phaseoli)(根腐れ/茎腐れ):ダイズ、及び、ワタ; 以下のものにおけるミクロドキウム・ニバレ(Microdochium(同義語 Fusarium)nivale)(紅色雪腐病):禾穀類(例えば、コムギ又はオオムギ); 以下のものにおけるミクロスファエラ・ジフサ(Microsphaera diffusa)(うどんこ病):ダイズ; 以下のものにおけるモニリニア属種(Monilinia spp.)、例えば、果実及び別のバラ科におけるM.laxa.M.fructicola、及び、M.fructigena(花及び枝枯れ病); 以下のものにおけるミコスファエレラ属種(Mycosphaerella spp.):禾穀類、バナナ、小果樹及びラッカセイ、例えば、コムギにおけるM.graminicola(アナモルフ:Septoria tritici、セプトリア葉枯病))、又は、バナナにおけるM.fijiensis(シガトカ病); 以下のものにおけるペロノスポラ属種(Peronospora spp.)(べと病):キャベツ(例えば、P.brassicae)、ナタネ(例えば、P.parasitica)、球根植物(例えば、P.destructor)、タバコ(P.tabacina)、及び、ダイズ(例えば、P.manshurica); 以下のものにおけるファコプソラ・パキリジ(Phakopsora pachyrhizi)及びファコプソラ・メイボミアエ(P.meibomiae)(ダイズさび病):ダイズ; 以下のものにおけるフィアロホラ属種(Phialophora spp.)、例えば、ブドウの木(例えば、P.tracheiphila、及び、P.tetraspora)、及び、ダイズ(例えば、P.gregata:茎の病害); 以下のものにおけるホマ・リンガム(Phoma lingam)(根及び茎腐れ病):ナタネ及びキャベツ、並びに、テンサイにおけるP.betae(斑点病); 以下のものにおけるホモプシス属種(Phomopsis spp
.):ヒマワリ、ブドウの木(例えば、P.viticola:つる割病)、及び、ダイズ(例えば、茎癌腫/茎胴枯れ病:P.phaseoli、テレオモルフ:Diaporthe phaseolorum); 以下のものにおけるフィソデルマ・マイジス(Physoderma maydis)(褐斑病):トウモロコシ; 以下のものにおけるフィトフトラ属種(Phytophthora spp.)(立ち枯れ病、根、葉、茎及び果実腐れ病):種々の植物、例えば、ピーマン及びキュウリ種(例えば、P.capsici)、ダイズ(例えば、P.megasperma、同義語 P.sojae)、ジャガイモ及びトマト(例えば、P.infestans.;葉枯れ病及び褐色腐敗病)、及び、落葉樹(例えば、P.ramorum;オーク突然死(sudden oak death)); 以下のものにおけるプラスモジオホラ・ブラシカエ(Plasmodiophora brassicae)(根こぶ病):キャベツ、ナタネ、ラディッシュ、及び、別の植物; 以下のものにおけるプラスモパラ属種(Plasmopara spp.)、例えば、ブドウの木におけるP.viticola(ブドウのツユカビ類、べと病)、及び、ヒマワリにおけるP.halstedii; 以下のものにおけるポドスファエラ属種(Podosphaera spp.)(うどんこ病):バラ科、ホップ、仁果実、及び、小果樹、例えば、リンゴにおけるP.leucotrich; 以下のものにおけるポリミキサ属種(Polymyxa spp.)、例えば、禾穀類、例えば、オオムギ及びコムギ(P.graminis)、及び、テンサイ(P.betae)、並びに、それによって感染するウイルス病; 以下のものにおけるプセウドセルコスポレラ・ヘルポトリコイデス(Pseudocercosporella herpotrichoides)(眼紋病/褐変症、テレオモルフ:Tapesia yallundae):禾穀類.例えば、コムギ又はオオムギ; 以下のものにおけるプセウドペロノスポラ(Pseudoperonospora)(べと病):種々の植物、例えば、キュウリ種におけるP.cubensis、又は、ホップにおけるP.humili; 以下のものにおけるプセウドペジクラ・トラケイフィラ(Pseudopezicula tracheiphila)(角斑葉枯病、アナモルフ Phialophora):ブドウの木; 以下のものにおけるプッシニア属種(Puccinia spp.)(さび病):種々の植物、例えば、禾穀類(例えば、コムギ、オオムギ又はライムギ)におけるP.triticina(小麦の赤錆病)、P.striiformis(黄さび病)、P.hordei(小さび病)、P.graminis(黒さび病)若しくはP.recondita(ライ麦の褐さび病)、サトウキビにおけるP.kuehnii、及び、例えば、アスパラガス(例えば、P.asparagi); 以下のものにおけるピレノホラ・トリチシ−レペンチス(Pyrenophora(アナモルフ:Drechslera)tritici−repentis)(コムギ葉枯れ病):コムギ、又は、オオムギにおけるP.teres(網斑病); 以下のものにおけるピリクラリア属種(Pyricularia spp.)、例えば、イネにおけるP.oryzae(テレオモルフ:Magnaporthe grisea.イネいもち病)、及び、芝生及び禾穀類におけるP.grisea; 以下のものにおけるピシウム属種(Pythium spp.)(立ち枯れ病):芝生、イネ、トウモロコシ、コムギ、ワタ、ナタネ、ヒマワリ、テンサイ、野菜類、及び、別の植物(例えば、P.ultimum、又は、P.aphanidermatum); 以下のものにおけるラムラリア属種(Ramularia spp.)、例えば、オオムギにおけるR.collo−cygni(ラムラリア葉及び芝生の斑点病/生理的斑点病)、及び、テンサイにおけるR.beticola; 以下のものにおけるリゾクトニア属種(Rhizoctonia spp.):ワタ、イネ、ジャガイモ、芝生、トウモロコシ、ナタネ、ジャガイモ、テンサイ、野菜類、及び、別の種々の植物、例えば、ダイズにおけるR.solani(根腐病及び茎腐病)、イネにおけるR.solani(紋枯病)、又は、コムギ若しくはオオムギにおけるR.cerealis(株腐病); 以下のものにおけるリゾプス・ストロニフェル(Rhizopus stolonifer)(軟腐病):イチゴ、ニンジン、キャベツ、ブドウの木、及び、トマト; 以下のものにおけるリンコスポリウム・セカリス(Rhynchosporium secalis)(斑点病):オオムギ、ライムギ、及び、ライコムギ; 以下のものにおけるサロクラジウム・オリザエ(Sarocladium oryzae)及びサロクラジウム・アテヌアツム(S.attenuatum)(葉しょう腐敗病):イネ; 以下のものにおけるスクレロチニア属種(Sclerotinia spp.)(茎又は白色腐れ病):野菜、及び、畑作物、例えば、ナタネ、ヒマワリ(例えば、Sclerotinia sclerotiorum)、及び、ダイズ(例えば、S.rolfsii); 以下のものにおけるセプトリア属種(Septoria spp.):種々の植物、例えば、ダイズにおけるS.glycines(斑点病)、コムギにおけるS.tritici(セプトリア葉枯病)、及び、禾穀類におけるS.(同義語 Stagonospora)nodorum(葉枯病及びふ枯病); 以下のものにおけるウンシヌラ・ネカトル(Uncinula(同義語 Erysiphe)necator)(うどんこ病、アナモルフ:Oidium tuckeri):ブドウの木; 以下のものにおけるセトスファエリア属種(Setospaeria spp.)(斑点病):トウモロコシ(例えば、S.turcicum、同義語 Helminthosporium turcicum)、及び、芝生; 以下のものにおけるスファセロテカ属種(Sphacelotheca spp.)(黒穂病):トウモロコシ(例えば、S.reiliana:穀粒黒穂病)、アワ、及び、サトウキビ; 以下のものにおけるスファエロテカ・フリギネア(Sphaerotheca fuliginea)(うどんこ病):キュウリ種; 以下のものにおけるスポンゴスポラ・スブテラネア(Spongospora subterranea)(粉状瘡痂病(powdery scab)):ジャガイモ、及び、それによって感染するウイルス病; 以下のものにおけるスタゴノスポラ属種(Stagonospora spp.):禾穀類、例えば、コムギにおけるS.nodorum(葉枯病及びふ枯病、テレオモルフ:Leptosphaeria[同義語 Phaeosphaeria]nodorum); 以下のものにおけるシンキトリウム・エンドビオチクム(Synchytrium endobioticum):ジャガイモ(ジャガイモこぶ病); 以下のものにおけるタフリナ属種(Taphrina spp.)、例えば、モモにおけるT.deformans(縮葉病)、及び、プラムにおけるT.pruni(袋実病(plum−pocket disease)); 以下のものにおけるチエラビオプシス属種(Thielaviopsis spp.)(黒根腐病):タバコ、仁果、野菜作物、ダイズ、及び、ワタ、例えば、T.basicola(同義語 Chalara elegans); 以下のものにおけるチレチア属種(Tilletia spp.)(黒穂病又はなまぐさ黒穂病):禾穀類、例えば、コムギにおけるT.tritici(同義語 T.caries、小麦黒穂病)及びT.controversa(萎縮腥黒穂病); 以下のものにおけるチフラ・インカルナタ(Typhula incarnata)(雪腐小粒菌核病(gray snow mold)):オオムギ、又は、コムギ; 以下のものにおけるウロシスチス属種(Urocystis spp.)、例えば、ライムギにおけるU.occulta(茎葉黒奴病(flag smut)); 以下のものにおけるウロミセス属種(Uromyces spp.)(さび病):野菜植物、例えば、インゲンマメ(例えば、U.appendiculatus、同義語 U.phaseolI)、及び、テンサイ(例えば、U.betae); 以下のものにおけるウスチラゴ属す(Ustilago spp.)(裸黒穂病):禾穀類(例えば、U.nuda、及び、U.avaenae)、トウモロコシ(例えば、U.maydis:トウモロコシ黒穂病)、及び、サトウキビ; 以下のものにおけるベンツリア属種(Venturia spp.)(瘡痂病):リンゴ(例えば、V.inaequalis)、及び、モモ;及び、以下のものにおけるベルチシリウム属種(Verticillium spp.)(葉及び苗条立ち枯れ病):種々の植物、例えば、果樹及び鑑賞樹、ブドウの木、小果樹、野菜及び畑作物、例えば、イチゴ、ナタネ、ジャガイモ及びトマトにおけるV.dahliae。
場合によっては、本発明の組成物は、特定の濃度又は特定の施用量において、除草剤、薬害軽減剤、成長調節剤若しくは植物の特性を改善する作用剤としても使用し得るか、又は、殺微生物剤(microbicide)として、例えば、殺菌剤(fungicide)、抗真菌剤(antimycotic)、殺細菌剤若しくは殺ウイルス剤(これは、ウイロイドに対する組成物も包含する)としても使用し得るか、又は、MLO(マイコプラズマ様生物)及びRLO(リケッチア様生物)に対する組成物としても使用し得る。適切な場合には、それらは、別の活性成分を合成するための中間体又は前駆物質としても使用することができる。
本発明による活性組合せは、さらにまた、植物において強力な強化効果(strengthening effect)も示し得る。従って、該活性組合せは、望ましくない微生物による攻撃に対して植物の防御を動員させるために使用することができる。
サイズ分布に関する改善された加工性(穀粒、果実など)、均一な成熟(riping)、穀粒水分、より良好な製粉、より良好なアルコール発酵、より良好な醸造、増大されたジュース収穫量、収穫性(harvestability)、消化性、沈降価、落下数(falling number)、莢安定性、貯蔵安定性、繊維の改善された長さ/強度/一様性、サイレージで飼育された動物のミルク及び/又は肉の品質における増強、料理及びフライに対する適応;
さらに、以下のものも包含する:
果実/穀粒の改善された品質、サイズ分布(穀粒、果実など)、増大された貯蔵寿命(storage/shelf−life)、堅さ/柔らかさ、風味(芳香、テクスチャーなど)、等級(サイズ、形状、液果の数など)、1果房あたりの液果/果実の数、クリスプ性、鮮度、ワックスによる被覆、生理障害の頻度、色などに関する、市場性;
さらに、以下のものも包含する:
増大された所望成分、例えば、タンパク質含有量、脂肪酸、オイル含有量、オイルの質、アミノ酸組成、糖質含有量、酸含有量(pH)、糖質/酸比(Brix)、ポリフェノール、デンプン含有量、栄養価、グルテン含有量/指数、エネルギー含量、風味など;
及び、さらに、以下のものも包含する:
低減された望ましくない成分、例えば、より少ないマイコトキシン、より少ないアフラトキシン、ゲオスミンレベル、フェノール性香気、ラッカーゼ(lacchase)、ポリフェノールオキシダーゼ及びペルオキシダーゼ、硝酸塩(nitrate)含有量など。
遅延された老化、これは、植物生理学における改善〔これは、例えば、より長い登熟相(これは、より多い収穫量をもたらす)、植物の葉が緑色を呈しているより長い持続期間において、明瞭に示される〕を包含し、及び、従って、色(緑化)、含水量、乾燥度などを包含する。従って、本発明に関連して、該活性化合物組合せの本発明による特定の施用によって緑色の葉の領域の持続期間を延長させる〔これは、植物の成熟(老化)を遅延させる〕ことが可能であるということが分かった。農業従事者にとっての主な有利点は、より長い登熟相であり、これは、より多い収穫量をもたらす。収穫時期におけるより大きなフレキシビリティーに基づいた、農業従事者に対する有利点も存在している。
本発明は、さらに、種子を処理する方法も包含する。
さらに、本発明の処理によって、収穫物並びにその収穫作物から作られる食料及び飼料におけるマイコトキシンの含有量を低減させることが可能である。マイコトキシンとしては、限定するものではないが、特に、以下のものを挙げることができる:デオキシニバレノール(DON)、ニバレノール、15−Ac−DON、3−Ac−DON、T2−トキシン、HT2−トキシン、フモニシン類、ゼアラレノン、モニリホルミン、フザリン、ジアセトキシシルペノール(DAS)、ベアウベリシン(beauvericin)、エンニアチン、フサロプロリフェリン(fusaroproliferin)、フサレノール(fusarenol)、オクラトキシン類、パツリン、エルゴットアルカロイド類及びアフラトキシン類〔これらは、例えば、以下の菌類によって産生され得る:とりわけ、フサリウム属各種(Fusarium spec.)、例えば、フサリウム・アクミナツム(F. acuminatum)、フサリウム・アシアチクム(F. asiaticum)、フサリウム・アベナセウム(F. avenaceum)、フサリウム・クロオクウェレンセ(F. crookwellense)、フサリウム・クルモルム(F. culmorum)、フサリウム・グラミネアルム(F. graminearum)(ジベレラ・ゼアエ(Gibberella zeae))、フサリウム・エクイセチ(F. equiseti)、フサリウム・フジコロイ(F. fujikoroi)、フサリウム・ムサルム(F. musarum)、フサリウム・オキシスポルム(F. oxysporum)、フサリウム・プロリフェラツム(F. proliferatum)、フサリウム・ポアエ(F. poae)、フサリウム・プセウドグラミネアルム(F. pseudograminearum)、フサリウム・サムブシヌム(F. sambucinum)、フサリウム・シルピ(F. scirpi)、フサリウム・セミテクツム(F. semitectum)、フサリウム・ソラニ(F. solani)、フサリウム・スポロトリコイデス(F. sporotrichoides)、フサリウム・ラングセチアエ(F. langsethiae)、フサリウム・スブグルチナンス(F. subglutinans)、フサリウム・トリシンクツム(F. tricinctum)、フサリウム・ベルチシリオイデス(F. verticillioides)など、及び、さらに、アスペルギルス属各種(Aspergillus spec.)、例えば、アスペルギルス・フラブス(A. flavus)、アスペルギルス・パラシチクス(A. parasiticus)、アスペルギルス・ノミウス(A. nomius)、アスペルギルス・オクラセウス(A. ochraceus)、アスペルギルス・クラバツス(A. clavatus)、アスペルギルス・テレウス(A. terreus)、アスペルギルス・ベルシコロル(A. versicolor)、ペニシリウム属各種(Penicillium spec.)、例えば、ペニシリウム・ベルコスム(P. verrucosum)、ペニシリウム・ビリジカツム(P. viridicatum)、ペニシリウム・シトリヌム(P. citrinum)、ペニシリウム・エキスパンスム(P. expansum)、ペニシリウム・クラビホルメ(P. claviforme)、ペニシリウム・ロクエホルチ(P. roqueforti)、クラビセプス属各種(Claviceps spec.)、例えば、クラビセプス・プルプレア(C. purpurea)、クラビセプス・フシホルミス(C. fusiformis)、クラビセプス・パスパリ(C. paspali)、クラビセプス・アフリカナ(C. africana)、スタキボトリス属各種(Stachybotrys spec.)など〕。
本発明の組成物は、材料物質の保護において、望ましくない微生物(例えば、菌類及び昆虫類)による攻撃及び破壊に対して工業材料を保護するするために用いることもできる。
さらに、本発明の組合せは、極めて優れた抗真菌活性も有している。それらは、極めて広い抗真菌活性スペクトルを有しており、特に、皮膚糸状菌、並びに、酵母菌、カビ及び二相性真菌類に対して〔例えば、カンジダ属各種(Candida species)、例えば、カンジダ・アルビカンス(C.albicans)、カンジダ・グラブラタ(C.glabrata)に対して〕、並びに、エピデルモフィトン・フロコスム(Epidermophyton floccosum)、アスペルギルス属各種(Aspergillus species)、例えば、アスペルギルス・ニゲル(A.niger)及びアスペルギルス・フミガツス(A.fumigatus)、トリコフィトン属各種(Trichophyton species)、例えば、トリコフィトン・メンタグロフィテス(T.mentagrophytes)、ミクロスポロン属各種(Microsporon species)、例えば、ミクロスポロン・カニス(M.canis)及びミクロスポロン・アウドウイニイ(M.audouinii)などに対して、極めて広い抗真菌活性スペクトルを有している。これら菌類のリストは、包含される真菌スペクトルを決して限定するものではなく、単に例示な性質のものである。
上記で既に述べたように、本発明に従って、全ての植物及びそれらの部分を処理することができる。好ましい実施形態では、野生の植物種及び植物品種、又は、交雑若しくはプロトプラスト融合のような慣習的な生物学的育種法により得られた植物種及び植物品種、並びに、それらの部分を処理する。好ましいさらなる実施形態では、適切な場合には慣習的な方法と組み合わせた遺伝子工学的方法により得られたトランスジェニック植物及び植物品種(遺伝子組換え生物)及びそれらの部分を処理する。用語「部分(parts)」又は「植物の部分(parts of plants)」又は「植物の部分(plant parts)」については、既に上記で説明した。さらに好ましくは、市販されているか又は使用されている植物品種の植物を、本発明に従って処理する。植物品種は、慣習的な育種又は突然変異誘発又は組換えDNA技術によって得られた、新しい特性(「形質」)を有する植物を意味するものと理解される。これらは、品種、変種、生物型又は遺伝子型であることができる。
(1) バシルス・ツリンギエンシス(Bacillus thuringiensis)に由来する殺虫性結晶タンパク質又はその殺虫活性を示す一部分、例えば、クリックモアら「Crickmore et al. (1998, Microbiology and Molecular Biology Reviews, 62:807−813」によって記載され、クリックモアら「Crickmore et al. (2005)」によって、オンライン「http://www.lifesci.sussex.ac.uk/Home/Neil_Crickmore/Bt/」上で「バシルス・ツリンギエンシス(Bacillus thuringiensis)毒素命名法」において更新された殺虫性結晶タンパク質又はその殺虫活性を示す一部分、例えば、Cryタンパク質類(Cry1Ab、Cry1Ac、Cry1B、Cry1C、Cry1D、Cry1F、Cry2Ab、Cry3Aa、又は、Cry3Bb)のタンパク質若しくはその殺虫活性を示す一部分(例えば、EP−A 1999141、及び、WO 2007/107302)、又は、例えば米国特許出願第12/249,016に記載されている合成遺伝子によってコードされているタンパク質;又は、
(2) バシルス・ツリンギエンシス(Bacillus thuringiensis)に由来する第2の別の結晶タンパク質又はその一部分の存在下において殺虫活性を示す、バシルス・ツリンギエンシス(Bacillus thuringiensis)に由来する結晶タンパク質又はその一部分、例えば、Cry34結晶タンパク質とCry35結晶タンパク質で構成されているバイナリートキシン(Nat. Biotechnol. 2001, 19, 668−72; Applied Environm. Microbiol. 2006, 71, 1765−1774)、又は、Cry1A若しくはCry1Fタンパク質とCry2Aa若しくはCry2Ab若しくはCry2Aeタンパク質で構成されているバイナリートキシン(米国特許出願第12/214,022号、及び、EP−A 2300618);又は、
(3) バシルス・ツリンギエンシス(Bacillus thuringiensis)に由来する種々の殺虫性結晶タンパク質の一部分を含んでいる殺虫性ハイブリッドタンパク質、例えば、上記(1)のタンパク質のハイブリッド、又は、上記(2)のタンパク質のハイブリッド、例えば、トウモロコシイベントMON89034で産生されるCry1A.105タンパク質(WO 2007/027777);又は、
(4) 上記(1)〜(3)のいずれか1つのタンパク質において、標的昆虫種に対するさらに強い殺虫活性を得るために、及び/又は、影響を受ける標的昆虫種の範囲を拡大するために、及び/又は、クローニング若しくは形質転換に際してコード化DNA中に導入された変化に起因して、幾つかのアミノ酸(特に、1〜10のアミノ酸)が別のアミノ酸で置き換えられていているもの、例えば、トウモロコシイベントMON863若しくはMON88017におけるCry3Bb1タンパク質又はトウモロコシイベントMIR604におけるCry3Aタンパク質;又は、
(5) バシルス・ツリンギエンシス(Bacillus thuringiensis)又はバシルス・セレウス(Bacillus cereus)に由来する殺虫性分泌タンパク質又はその殺虫活性を示す一部分、例えば、「http://www.lifesci.sussex.ac.uk/home/Neil_Crickmore/Bt/vip.html」において挙げられている栄養生長期殺虫性タンパク質(vegetative insecticidal protein)(VIP)、例えば、VIP3Aaタンパク質類のタンパク質;又は、
(6) バシルス・ツリンギエンシス(Bacillus thuringiensis)又はバシルス・セレウス(Bacillus cereus)に由来する第2の分泌タンパク質の存在下において殺虫活性を示す、バシルス・ツリンギエンシス(Bacillus thuringiensis)又はバシルス・セレウス(Bacillus cereus)に由来する分泌タンパク質、例えば、VIP1Aタンパク質とVIP2Aタンパク質で構成されているバイナリートキシン(WO 94/21795);又は、
(7) バシルス・ツリンギエンシス(Bacillus thuringiensis)又はバシルス・セレウス(Bacillus cereus)に由来する種々の分泌タンパク質の一部分を含んでいる殺虫性ハイブリッドタンパク質、例えば、上記(1)のタンパク質のハイブリッド、又は、上記(2)のタンパク質のハイブリッド;又は、
(8) 上記(5)〜(7)のいずれか1つのタンパク質において、標的昆虫種に対するさらに強い殺虫活性を得るために、及び/又は、影響を受ける標的昆虫種の範囲を拡大するために、及び/又は、クローニング若しくは形質転換に際してコード化DNA中に導入された変化(それでも、まだ、殺虫性タンパク質をコードしている)に起因して、幾つかのアミノ酸(特に、1〜10のアミノ酸)が別のアミノ酸で置き換えられていているもの、例えば、ワタイベントCOT102におけるVIP3Aaタンパク質;又は、
(9) バシルス・ツリンギエンシス(Bacillus thuringiensis)に由来する結晶タンパク質の存在下において殺虫活性を示す、バシルス・ツリンギエンシス(Bacillus thuringiensis)又はバシルス・セレウス(Bacillus cereus)に由来する分泌タンパク質、例えば、VIP3とCry1A若しくはCry1Fで構成されているバイナリートキシン(米国特許出願第61/126083号、及び、米国特許出願第61/195019号)、又は、VIP3タンパク質とCry2Aaタンパク質若しくはCry2Abタンパク質若しくはCry2Aeタンパク質で構成されているバイナリートキシン(米国特許出願第12/214,022号、及び、EP−A 2300618);又は、
(10) 上記(9)のタンパク質において、標的昆虫種に対するさらに強い殺虫活性を得るために、及び/又は、影響を受ける標的昆虫種の範囲を拡大するために、及び/又は、クローニング若しくは形質転換に際してコード化DNA中に導入された変化(それでも、まだ、殺虫性タンパク質をコードしている)に起因して、幾つかのアミノ酸(特に、1〜10のアミノ酸)が別のアミノ酸で置き換えられていているもの。
(1) 植物細胞内又は植物内におけるポリ(ADP−リボース)ポリメラーゼ(PARP)遺伝子の発現及び/又は活性を低減させることが可能な導入遺伝子を含んでいる植物(WO 00/04173、WO /2006/045633、EP−A 1807519又はEP−A 2018431に記述されている);
(2) 植物又は植物細胞のPARGコード化遺伝子の発現及び/又は活性を低減させることが可能なストレス耐性を強化する導入遺伝子を含んでいる植物(例えば、WO 2004/090140などに記述されている);
(3) ニコチンアミダーゼ、ニコチン酸ホスホリボシルトランスフェラーゼ、ニコチン酸モノヌクレオチドアデニルトランスフェラーゼ、ニコチンアミドアデニンジヌクレオチドシンテターゼ又はニコチンアミドホスホリボシルトランスフェラーゼを包含するニコチンアミドアデニンジヌクレオチドサルベージ合成経路の植物機能性酵素(plant−functional enzyme)をコードするストレス耐性を強化する導入遺伝子を含んでいる植物(例えば、EP−A 1794306、WO 2006/133827、WO 2007/107326、EP−A 1999263又はWO 2007/107326などに記述されている)。
(1) 野生型の植物細胞又は植物において合成された澱粉と比較して、その物理化学的特性〔特に、アミロース含有量若しくはアミロース/アミロペクチン比、枝分かれ度、平均鎖長、側鎖分布、粘性挙動、ゲル化強度(gelling strength)、澱粉粒径及び/又は澱粉粒子形態〕が変えられていて、特定の用途により適した変性澱粉を合成するトランスジェニック植物。変性澱粉を合成する該トランスジェニック植物は、例えば、EP−A 0571427、WO 95/04826、EP−A 0719338、WO 96/15248、WO 96/19581、WO 96/27674、WO 97/11188、WO 97/26362、WO 97/32985、WO 97/42328、WO 97/44472、WO 97/45545、WO 98/27212、WO 98/40503、WO 99/58688、WO 99/58690、WO 99/58654、WO 00/08184、WO 00/08185、WO 00/08175、WO 00/28052、WO 00/77229、WO 01/12782、WO 01/12826、WO 02/101059、WO 03/071860、WO 04/056999、WO 05/030942、WO 2005/030941、WO 2005/095632、WO 2005/095617、WO 2005/095619、WO 2005/095618、WO 2005/123927、WO 2006/018319、WO 2006/103107、WO 2006/108702、WO 2007/009823、WO 00/22140、WO 2006/063862、WO 2006/072603、WO 02/034923、WO 2008/017518、WO 2008/080630、WO 2008/080631、EP 07090007.1、WO 2008/090008、WO 01/14569、WO 02/79410、WO 03/33540、WO 2004/078983、WO 01/19975、WO 95/26407、WO 96/34968、WO 98/20145、WO 99/12950、WO 99/66050、WO 99/53072、US 6,734,341、WO 00/11192、WO 98/22604、WO 98/32326、WO 01/98509、WO 01/98509、WO 2005/002359、US 5,824,790、US 6,013,861、WO 94/04693、WO 94/09144、WO 94/11520、WO 95/35026、WO 97/20936、WO 2010/012796、WO 2010/003701に開示されている;
(2) 非澱粉炭水化物ポリマーを合成するか又は遺伝子組換えがなされていない野生型植物と比較して改変された特性を有する非澱粉炭水化物ポリマーを合成するトランスジェニック植物。その例は、ポリフルクトース(特に、イヌリン型及びレバン型のポリフルクトース)を産生する植物(EP−A 0663956、WO 96/01904、WO 96/21023、WO 98/39460及びWO 99/24593に開示されている)、α−1,4−グルカン類を産生する植物(WO 95/31553、US 2002031826、US 6,284,479、US 5,712,107、WO 97/47806、WO 97/47807、WO 97/47808及びWO 00/14249に開示されている)、α−1,6−分枝 α−1,4−グルカン類を産生する植物(WO 00/73422に開示されている)、及び、アルテルナンを産生する植物(WO 00/47727、WO 00/73422、EP 06077301.7、US 5,908,975及びEP−A 0728213などに開示されている)である;
(3) ヒアルロナンを産生するトランスジェニック植物(例えば、WO 2006/032538、WO 2007/039314、WO 2007/039315、WO 2007/039316、JP−A 2006−304779及びWO 2005/012529などに開示されている)。
(a) 改変された形態のセルロースシンターゼ遺伝子を含んでいる植物(例えば、ワタ植物)(WO 98/00549に記述されている);
(b) 改変された形態のrsw2相同核酸又はrsw3相同核酸を含んでいる植物(例えば、ワタ植物)(WO 2004/053219に記述されている);
(c) スクロースリン酸シンターゼの発現が増大している植物(例えば、ワタ植物)(WO 01/17333に記述されている);
(d) スクロースシンターゼの発現が増大している植物(例えば、ワタ植物)(WO 02/45485に記述されている);
(e) 繊維細胞に基づいた原形質連絡のゲーティングのタイミングが(例えば、繊維選択的β−1,3−グルカナーゼのダウンレギュレーションを介して)改変されている植物(例えば、ワタ植物)(WO 2005/017157に記述されているか、又は、WO 2009/143995に記述されている);
(f) 反応性が(例えば、nodCを包含するN−アセチルグルコサミントランスフェラーゼ遺伝子の発現及びキチンシンターゼ遺伝子の発現を介して)改変されている繊維を有する植物(例えば、ワタ植物)(WO 2006/136351に記述されている)。
(a) オレイン酸含有量が高いオイルを産生する植物(例えば、ナタネ植物)(例えば、US 5,969,169、US 5,840,946、US 6,323,392又はUS 6,063,947などに記載されている);
(b) リノレン酸含有量が低いオイルを産生する植物(例えば、ナタネ植物)(US 6,270,828、US 6,169,190又はUS 5,965,755に記載されている);
(c) 飽和脂肪酸のレベルが低いオイルを産生する植物(例えば、ナタネ植物)(例えば、US 5,434,283又は米国特許出願第12/668303号などに記載されている)。
− 申請: 当該申請の識別番号。形質転換イベントについての技術的な記述は、APHISから(例えば、APHISのウェブサイトにおいて、該申請番号を参照することによって)入手可能な個々の申請書類の中に見いだすことができる。それらの記述は、参照によって本明細書中に組み入れる。
、WO01/041558又はUS−A 2003−188347に記載されている);イベントRT73(ナタネ、除草剤耐性、寄託されていない、WO02/036831又はUS−A 2008−070260に記載されている);イベントT227−1(テンサイ、除草剤耐性、寄託されていない、WO02/44407又はUS−A 2009−265817に記載されている);イベントT25(トウモロコシ、除草剤耐性、寄託されていない、US−A 2001−029014又はWO01/051654に記載されている);イベントT304−40(ワタ、昆虫防除−除草剤耐性、ATCC PTA−8171として寄託されている、US−A 2010−077501又はWO2008/122406に記載されている);イベントT342−142(ワタ、昆虫防除、寄託されていない、WO2006/128568に記載されている);イベントTC1507(トウモロコシ、昆虫防除−除草剤耐性、寄託されていない、US−A 2005−039226又はWO2004/099447に記載されている);イベントVIP1034(トウモロコシ、昆虫防除−除草剤耐性、ATCC PTA−3925として寄託されている、WO03/052073に記載されている)、イベント32316(トウモロコシ、昆虫防除−除草剤耐性、PTA−11507として寄託されている、WO2011/084632に記載されている)、イベント4114(トウモロコシ、昆虫防除−除草剤耐性、PTA−11506として寄託されている、WO2011/084621に記載されている)。
本発明の組合せを殺菌剤として使用する場合、その施用量は、施用の種類に応じて、比較的広い範囲内で変えることができる。本発明の活性成分の施用量は、以下のとおりである:
・ 植物の部分、例えば、葉を処理する場合: 0.1〜10000g/ha、好ましくは、10〜1000g/ha、さらに好ましくは、10〜800g/ha、さらに一層好ましくは、50〜300g/ha(潅水又は滴下によって施用する場合、特に、ロックウール又はパーライトなどの不活性底土を用いる場合には、上記施用量はさらに低減させることができる);
・ 種子を処理する場合: 種子100kg当たり2〜200g、好ましくは、種子100kg当たり3〜150g、さらに好ましくは、種子100kg当たり2.5〜25g、さらに一層好ましくは、種子100kg当たり2.5〜12.5g;
・ 土壌を処理する場合: 0.1〜10000g/ha、好ましくは、1〜5000g/ha。
Xは、活性化合物Aがm(ppm)(又は、g/ha)の施用量で施用されたときの効力であり;
Yは、活性化合物Bがn(ppm)(又は、g/ha)の施用量で施用されたときの効力であり;
Eは、活性化合物A及び活性化合物Bが、それぞれ、m及びn(ppm)(又は、g/ha)の施用量で施用されたときの効力である;
とした場合、
アルテルナリア(Alternaria)試験(トマト)/予防
溶媒: 24.5重量部のアセトン
24.5重量部のジメチルアセトアミド
乳化剤: 1重量部のアルキルアリールポリグリコールエーテル
活性化合物の適切な調製物を調製するために、1重量部の活性化合物を上記量の溶媒及び乳化剤と混合し、得られた濃厚物を水で希釈して、所望の濃度とする。
フィトフトラ(Phytophthora)試験(トマト)/予防
溶媒: 24.5重量部のアセトン
24.5重量部のジメチルアセトアミド
乳化剤: 1重量部のアルキルアリールポリグリコールエーテル
活性化合物の適切な調製物を調製するために、1重量部の活性化合物を上記量の溶媒及び乳化剤と混合し、得られた濃厚物を水で希釈して、所望の濃度とする。
スファエロテカ(Sphaerotheca)試験(キュウリ)/予防
溶媒: 24.5重量部のアセトン
24.5重量部のジメチルアセトアミド
乳化剤: 1重量部のアルキルアリールポリグリコールエーテル
活性化合物の適切な調製物を調製するために、1重量部の活性化合物を上記量の溶媒及び乳化剤と混合し、得られた濃厚物を水で希釈して、所望の濃度とする。
ベンツリア(Venturia)試験(リンゴ)/予防
溶媒: 24.5重量部のアセトン
24.5重量部のジメチルアセトアミド
乳化剤: 1重量部のアルキルアリールポリグリコールエーテル
活性化合物の適切な調製物を調製するために、1重量部の活性化合物を上記量の溶媒及び乳化剤と混合し、得られた濃厚物を水で希釈して、所望の濃度とする。
Claims (10)
- 組合せであって、
(A) 式(I)
で表される少なくとも1種類のチアゾリルイソオキサゾリン又はその農薬的に許容される塩;
及び、
(B) 以下の群、
(1) エルゴステロール合成の阻害薬、
(2) 複合体I又はIIにおける呼吸鎖の阻害薬、
(3) 複合体IIIにおける呼吸鎖の阻害薬、
(4) 有糸分裂及び細胞分裂の阻害薬、
(5) 多部位に作用し得る化合物、
(6) 宿主の防御を誘発し得る化合物、
(7) アミノ酸及び/又はタンパク質の生合成の阻害薬、
(8) ATP産生の阻害薬、
(9) 細胞壁合成の阻害薬、
(10) 脂質及び膜の合成の阻害薬、
(11) メラニン生合成の阻害薬、
(12) 核酸合成の阻害薬、
(13) シグナル伝達の阻害薬、
(14) 脱共役剤として作用し得る化合物、
(15) 別の殺菌剤、
から選択される少なくとも1種類のさらなる活性化合物;
を含んでいる、前記組合せ。 - (I−1) 2−{3−[2−(1−{[3,5−ビス(ジフルオロメチル)−1H−ピラゾール−1−イル]アセチル}ピペリジン−4−イル)−1,3−チアゾール−4−イル]−4,5−ジヒドロ−1,2−オキサゾール−5−イル}フェニル メタンスルホネート;
(I−2) 2−{3−[2−(1−{[3,5−ビス(ジフルオロメチル)−1H−ピラゾール−1−イル]アセチル}ピペリジン−4−イル)−1,3−チアゾール−4−イル]−4,5−ジヒドロ−1,2−オキサゾール−5−イル}−6−フルオロフェニル メタンスルホネート;
(I−3) 2−{3−[2−(1−{[3,5−ビス(ジフルオロメチル)−1H−ピラゾール−1−イル]アセチル}ピペリジン−4−イル)−1,3−チアゾール−4−イル]−4,5−ジヒドロ−1,2−オキサゾール−5−イル}−3−クロロフェニル メタンスルホネート;
(I−4) 2−{3−[2−(1−{[3,5−ビス(ジフルオロメチル)−1H−ピラゾール−1−イル]アセチル}ピペリジン−4−イル)−1,3−チアゾール−4−イル]−4,5−ジヒドロ−1,2−オキサゾール−5−イル}−5−メチルフェニル メタンスルホネート;
(I−5) 2−{3−[2−(1−{[3,5−ビス(ジフルオロメチル)−1H−ピラゾール−1−イル]アセチル}ピペリジン−4−イル)−1,3−チアゾール−4−イル]−4,5−ジヒドロ−1,2−オキサゾール−5−イル}−5−クロロフェニル メタンスルホネート;
(I−6) 2−{3−[2−(1−{[3,5−ビス(ジフルオロメチル)−1H−ピラゾール−1−イル]アセチル}ピペリジン−4−イル)−1,3−チアゾール−4−イル]−4,5−ジヒドロ−1,2−オキサゾール−5−イル}−4−メチルフェニル メタンスルホネート;
(I−7) 2−{3−[2−(1−{[3,5−ビス(ジフルオロメチル)−1H−ピラゾール−1−イル]アセチル}ピペリジン−4−イル)−1,3−チアゾール−4−イル]−4,5−ジヒドロ−1,2−オキサゾール−5−イル}−4−クロロフェニル メタンスルホネート;
(I−8) 2−{3−[2−(1−{[3,5−ビス(ジフルオロメチル)−1H−ピラゾール−1−イル]アセチル}ピペリジン−4−イル)−1,3−チアゾール−4−イル]−4,5−ジヒドロ−1,2−オキサゾール−5−イル}−6−クロロフェニル メタンスルホネート;
からなる群から選択される式(I)で表される少なくとも1種類の化合物を含んでいる、請求項1に記載の組合せ。 - 有害な植物病原性菌類を防除する方法であって、請求項1又は2に記載の混合物を当該有害な植物病原性菌類及び/又はそれらの生息環境に施用することを特徴とする、前記方法。
- 有害な植物病原性菌類を防除するための組成物であって、増量剤及び/又は界面活性剤に加えて請求項1又は2に記載の少なくとも1種類の混合物を含んでいることを特徴とする、前記組成物。
- 殺虫剤、誘引剤、不妊剤、殺細菌剤、殺ダニ剤、殺線虫剤、殺菌剤、成長調節剤、除草剤、肥料、薬害軽減剤及び情報化学物質からなる群から選択される少なくとも1種類のさらなる活性成分を含んでいる、請求項4に記載の組成物。
- 有害な植物病原性菌類を防除するための、請求項1又は2に記載の混合物の使用。
- 植物成長調節剤としての、請求項1又は2に記載の混合物の使用。
- 有害な植物病原性菌類を防除するための組成物を製造する方法であって、請求項1又は2に記載の混合物を増量剤及び/又は界面活性剤と混合させることを特徴とする、前記方法。
- トランスジェニック植物を処理するための、請求項1に記載の混合物の化合物の使用。
- 種子及びトランスジェニック植物の種子を処理するための、請求項1に記載の混合物の化合物の使用。
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