WO2017094576A1 - 植物病害防除組成物及び植物病害防除方法 - Google Patents
植物病害防除組成物及び植物病害防除方法 Download PDFInfo
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- WO2017094576A1 WO2017094576A1 PCT/JP2016/084739 JP2016084739W WO2017094576A1 WO 2017094576 A1 WO2017094576 A1 WO 2017094576A1 JP 2016084739 W JP2016084739 W JP 2016084739W WO 2017094576 A1 WO2017094576 A1 WO 2017094576A1
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- formula
- compound represented
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- disease control
- plant
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- ZQEIXNIJLIKNTD-UHFFFAOYSA-N CC(C(OC)=O)N(C(COC)=O)c1c(C)cccc1C Chemical compound CC(C(OC)=O)N(C(COC)=O)c1c(C)cccc1C ZQEIXNIJLIKNTD-UHFFFAOYSA-N 0.000 description 2
- 0 *c1cc(*)n[n]1CC(N(CC1)CCC1c1nc(C(C2)=NOC2c2c(*)cccc2*)c[s]1)=O Chemical compound *c1cc(*)n[n]1CC(N(CC1)CCC1c1nc(C(C2)=NOC2c2c(*)cccc2*)c[s]1)=O 0.000 description 1
Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
- A01P3/00—Fungicides
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
- A01N37/46—N-acyl derivatives
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01C—PLANTING; SOWING; FERTILISING
- A01C1/00—Apparatus, or methods of use thereof, for testing or treating seed, roots, or the like, prior to sowing or planting
- A01C1/06—Coating or dressing seed
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
- A01G7/00—Botany in general
- A01G7/06—Treatment of growing trees or plants, e.g. for preventing decay of wood, for tingeing flowers or wood, for prolonging the life of plants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
- A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
Definitions
- the present invention relates to a plant disease control composition and a plant disease control method.
- An object of the present invention is to provide a plant disease control composition and a plant disease control method having an excellent plant disease control effect.
- the present inventor has found that a compound represented by the following formula (1), a compound represented by the following formula (2), and the following formula (3) It has been found that a plant disease control composition containing a compound represented by the formula shows an excellent control effect against plant diseases. That is, the present invention is as follows.
- plant diseases can be controlled.
- the plant disease control composition of the present invention (hereinafter referred to as the present composition) comprises a compound represented by the formula (1) (hereinafter referred to as the present compound (1)) and a compound represented by the formula (2). (Hereinafter referred to as the present compound (2)) and a compound represented by the formula (3) (hereinafter referred to as the present compound (3)).
- This compound (1) is described in, for example, US Pat. No. 5,514,643, and is known by a general name of ethaboxam.
- This compound (1) can be obtained from a commercially available formulation, or can be manufactured by a well-known method.
- This compound (2) is described in, for example, US Pat. No. 4,317,916, and its racemate is known by a general name of metalaxyl. Further, the R form thereof is known by the general name of metalaxyl-M, and the compound (2) includes metalaxyl-M.
- This compound (2) can be obtained from a commercially available formulation, or can be manufactured by a well-known method.
- the compound (3) is a compound in which R 1 is a methyl group, R 2 is a trifluoromethyl group, and R 3 and R 4 are both fluorine atoms in the formula (3) (hereinafter referred to as the present compound). (Denoted as (3a)), or a compound in which R 1 and R 2 are both difluoromethyl groups, R 3 is a chlorine atom, and R 4 is a methanesulfonyloxy group in the formula (3) (hereinafter referred to as “3a”) , Referred to as the present compound (3b)).
- This compound (3a) is described in, for example, International Publication No. 2008/013622, and is known by a general name of oxathiapiproline.
- This compound (3a) can be obtained from a commercially available formulation, or can be manufactured by a well-known method.
- This compound (3b) is described in, for example, International Publication No. 2012/025557.
- This compound (3b) can be obtained from a commercially available formulation, or can be manufactured by a well-known method.
- the content ratio of the present compound (1), the present compound (2) and the present compound (3) is not particularly limited, but the present ratio is 100 parts by weight of the present compound (1).
- the compound (2) is usually 2 to 5000 parts by weight, preferably 10 to 1000 parts by weight
- the compound (3) is usually 2 to 5000 parts by weight, preferably 10 to 1000 parts by weight.
- the composition of the present invention may be a mixture of the present compound (1), the present compound (2) and the present compound (3), but usually the present compound (1), the present compound (2) and the present compound (3).
- an inert carrier such as a solid carrier and a liquid carrier, and if necessary, add a surfactant or other auxiliary agent for formulation, and oil, emulsion, flowable agent, wettable powder, granular water Those formulated into a powder, powder, granule, etc. are used.
- the total amount of the present compound (1), the present compound (2) and the present compound (3) in the composition of the present invention is usually 0.01 to 99% by weight, preferably 0.1 to 90% by weight, more preferably It is in the range of 0.5 to 70% by weight.
- solid carriers used in formulation examples include kaolin clay, attapulgite clay, bentonite, montmorillonite, acid clay, pyrophyllite, talc, diatomaceous earth, calcite, corn cob flour, walnut shell powder, etc.
- liquid carriers examples include xylene, toluene, methyl Aromatic hydrocarbons such as naphthalene, alcohols such as 2-propanol, ethylene glycol, propylene glycol and ethylene glycol monoethyl ether, ketones such as acetone, cyclohexanone and isophorone, vegetable oils such as soybean oil and cottonseed oil, petroleum fats Group hydrocarbons, Ethers, dimethyl sulfoxide, acetonitrile and water.
- Aromatic hydrocarbons such as naphthalene
- alcohols such as 2-propanol
- ethylene glycol propylene glycol and ethylene glycol monoethyl ether
- ketones such as acetone, cyclohexanone and isophorone
- vegetable oils such as soybean oil and cottonseed oil
- petroleum fats Group hydrocarbons Ethers, dimethyl sulfoxide, acetonitrile and water.
- surfactants include anionic interfaces such as alkyl sulfate esters, alkylaryl sulfonates, dialkyl sulfosuccinates, polyoxyethylene alkylaryl ether phosphate esters, lignin sulfonates, naphthalene sulfonate formaldehyde polycondensates, and the like.
- Nonionic surfactants such as activators and polyoxyethylene alkyl aryl ethers, polyoxyethylene alkyl polyoxypropylene block copolymers, sorbitan fatty acid esters, and cationic surfactants such as alkyltrimethylammonium salts.
- formulation adjuvants include, for example, water-soluble polymers such as polyvinyl alcohol and polyvinylpyrrolidone, gum arabic, alginic acid and its salts, polysaccharides such as CMC (carboxymethyl cellulose) and xanthan gum, aluminum magnesium silicate, alumina sol Inorganic substances such as preservatives, colorants and stabilizers such as PAP (isopropyl acid phosphate) and BHT.
- water-soluble polymers such as polyvinyl alcohol and polyvinylpyrrolidone
- gum arabic alginic acid and its salts
- polysaccharides such as CMC (carboxymethyl cellulose) and xanthan gum
- aluminum magnesium silicate such as aluminum magnesium silicate
- alumina sol Inorganic substances such as preservatives, colorants and stabilizers such as PAP (isopropyl acid phosphate) and BHT.
- PAP isopropyl acid phosphate
- composition of the present invention is a preparation obtained by formulating the present compound (1), the present compound (2) and the present compound (3) by the method described above, or a mixture obtained by mixing each of these preparations with water. It can also be prepared by mixing the liquids.
- composition of the present invention may further contain one or more other fungicides and / or insecticides and / or plant growth regulators.
- examples of the combination of compounds include the following combinations. However, ⁇ 1 in the following combinations represents N- (1,1,3-trimethylindan-4-yl) -1-methyl-3-difluoromethylpyrazole-4-carboxylic acid amide, racemic or enantiomer, R It includes a mixture of the enantiomer of the body and the enantiomer of the S form in any proportion.
- fludioxonil mandestrobin, clothianidin, ⁇ 1, ipconazole, metalaxyl, ethaboxam, oxathiapiproline and thiabendazole
- fludioxonil mandestrobin, clothianidin, ⁇ 1, ipconazole, metalaxyl-M, ethaboxam, oxathiapiproline and thiabendazole
- thiabendazole combinationFludioxonil, mandestrobin, clothianidin Combination of toluclophosmethyl, ipconazole, metalaxyl, ethaboxam, oxathiapiproline and thiabendazole, fludioxonil, mandestrobin, clothianidin, tolcrophosmethyl, ipconazole, metalaxyl-M, combination of ethaboxam, oxathiapiproline and thiabendazole, fludioxonil, mandesto Robin, clothianidin, tolcrofosmethyl, metconazole, metalaxyl, ethaboxam, oxathiapiproline and thiabendazole combinationFludioxonil, mande
- composition of the present invention is used to protect plants from diseases.
- Examples of plant diseases that can be exerted by the composition of the present invention include the following.
- Rice diseases rice blast (Magnaporthe grisea), sesame leaf blight (Cochliobolus miyabeanus), blight (Rhizoctonia solani), idiotic seedling (Gibberella fujikuruoi).
- Diseases of wheat powdery mildew (Erysiphe graminis), red mold (Fusarium graminearum, F. avenacerum, F. culmorum, Microdochium nivare), rust (Puccinia striformi.
- Ustilago nuda cloud disease (Rhynchosporium secalis), reticular disease (Pyrenophora teres), spot disease (Cochliobolus sativus), leafy leaf disease (Pyrenophora graminea), Rhizonia genus R. Diseases of corn: smut (Ustilago maydis), sesame leaf blight (Cochliobolus heterostrohus), leprosy (Gloeocercospora sorgi), southern rust (Puccinia polysora), gray leaf spot C Rhizotonia solani, and downy mildew of corn (Peronosclerosporia philippinensis).
- Pear Diseases Black Star Disease (Venturia nashicola, V. pirina), Black Spot Disease (Alternaria alternata Japan pearpathotype), Red Star Disease (Gymnosporangium haraeanum), Tomato Phartohum Peach disease: Monilinia fracticola, black scab (Cladosporium carpophilum), Phomopsis spoilage (Phomopsis spp.). Grape diseases: black scab (Elsinoe ampelina), late rot (Glomerella cinulata), powdery mildew (Uncinula apelopidais), black rot (Gikonivaladi) .
- Oyster diseases anthracnose (Gloeosporium kaki), leaf fall (Cercospora kaki, Mycosphaerella nawae).
- Diseases of cucurbits Anthracnose (Colletotrichum lagenarium), powdery mildew (Sphaerotheca fuliginea), vine blight (Mycosphaerella meloniis), pori (Fusarium oxysporum), por disease (fusarium oxysporum) ), Seedling blight (Pythium spp.).
- Diseases of tomato Alternaria solani, leaf mold (Cladosporium fulvum), plague (Phytophthora infestans).
- Pea disease powdery mildew (Erysiphe pisi), root rot (Fusarium solani F. sp. Pisi). Diseases of potato: Alternaria solani, Phytophthora infestans, Phytophthora erythro- septica, Spongospoa sra tersane ternean tsuterrananu. Strawberry disease: powdery mildew (Sphaerotheca humuli), anthracnose (Glomerella singulata).
- Tea diseases net blast (Exobasidium reticulatum), white scab (Elsinoe leucospila), ring spot disease (Pestarotropis spe.), Anthracnose (Colletotrichum theae-sinensis).
- Tobacco disease Alternaria longipes, powdery mildew (Erysiphe cichoracearum), anthracnose (Colletotrichum tabacum), downy mildew (Peronospora tabacina), epidemic (Phytophyti. Rapeseed diseases: Sclerotinia sclerotiorum, Rhizoctonia solani, Rhizoctonia solani. Cotton disease: Rhizotonia solani caused by Rhizoctonia spp.
- Sugar beet disease brown spot disease (Cercospora beticola), leaf rot (Rhizoctonia solani), root rot (Rhizoctonia solani), black root disease (Aphanomyces cochlioides). Rose diseases: black spot (Diplocarpon rosae), powdery mildew (Sphaerotheca pannosa), downy mildew (Peronospora sparsa). Diseases of chrysanthemum and asteraceae vegetables: downy mildew (Bremia lactucae), brown spot disease (Septoria chrysanthemi-indici), white rust (Puccinia horiana). Diseases of various plants: diseases caused by Pythium spp.
- Aspergillus genus Penicillium genus, Fusarium genus, Gibberella genus, Trichoderma genus, Thielaviopsis genus, Rhizopus genus, Mucor genus, Corticium genus, Poma genus, Rhizoctonia genus Disease. Viral diseases of various plants mediated by Polymixa genus or Olpidium genus.
- diseases that are expected to have high efficacy include, specifically, wheat, barley, corn, rice, sorghum, soybean, cotton, rapeseed, cucumber, sunflower, sugar beet, and shiba piscium.
- Seedling blight and root rot (Phythium debarianum, Pythium graminicola, Pythium irregulare, Pythium ultimum), sugar beet (Aphanomyces cochlioides), and Phytophthora phytophytophytophylla , Sunflower downy mildew (Plasmopara halstedii), potato plague (Phytophthora) infestans), corn downy mildew (Peronosclerospora philippinensis), and the like.
- the plant disease control method of the present invention (hereinafter referred to as the present invention control method) is an application of an effective amount of the present compound (1), the present compound (2) and the present compound (3) to the plant or the soil where the plant is cultivated.
- the process of carrying out is included.
- Plants to be applied include plant foliage, plant seeds, plant bulbs and the like.
- the bulb means a bulb, a bulb, a rhizome, a tuber, a tuberous root and a root bearing body.
- the present compound (1), the present compound (2) and the present compound (3) may be applied separately at the same time, but usually the present composition is applied in an effective amount from the viewpoint of ease of application. Is done. Examples of application forms include foliage treatment, soil treatment, root treatment, and seed treatment.
- the composition of the present invention can be used as a seed treatment agent.
- foliage treatment a method of applying to the surface of the plant being cultivated by foliage spray and trunk spray is mentioned.
- the soil treatment include soil application, soil mixing, and chemical irrigation into the soil.
- the root treatment include a method of immersing the whole plant or the root in a chemical solution, and a method of adhering a preparation formulated using a solid carrier to the root of the plant.
- Seed treatment includes treating the seed or bulb of the plant to be protected from plant diseases with the composition of the present invention.
- a spray treatment in which the suspension of the composition of the present invention is atomized and sprayed onto the seed surface or bulb surface, the solution of which is dissolved in a solvent, a wettable powder, an emulsion, or a flowable agent.
- a smearing process in which the composition of the present invention with water added thereto is applied to seeds or bulbs, a dipping process in which seeds are immersed in an aqueous dispersion of the composition of the present invention for a certain period of time, a film coating process and a pellet coating process. It is done.
- the application amount of the present compound (1), the present compound (2) and the present compound (3) is the type of plant to be applied, the type and degree of occurrence of the plant disease to be controlled, the formulation form, the application It can be changed according to the time, weather conditions, etc., but when applied to the plant foliage or the soil where the plant is cultivated, the total application amount of the present compound (1), the present compound (2) and the present compound (3) (hereinafter, The amount of the active ingredient) is usually 1 to 5000 g, preferably 2 to 500 g per 10,000 m 2 .
- Emulsions, wettable powders, flowables and the like are usually treated by spraying a chemical obtained by mixing with water.
- the concentration of the active ingredient in the chemical solution is usually 0.0001 to 3% by weight, preferably 0.0005 to 1% by weight. Powders, granules, etc. are usually processed as they are.
- the amount of the active ingredient when treating seeds is usually 0.001 to 10 g, preferably 0.01 to 3 g, per 1 kg of seeds.
- the seed treatment is performed on seeds that have not been sown. An unseeded seed means a seed at an arbitrary time point until seeding.
- seeds treated with the present compound (1), the present compound (2), and the present compound (3) can be obtained by treating the seed.
- the seed retains an effective amount of the present compound (1), the present compound (2) and the present compound (3). Therefore, the seed or the plant grown from the seed is protected from disease.
- the control method of the present invention is carried out in cultivated lands such as fields, paddy fields, lawns, orchards, or non-agricultural lands.
- cultivated lands such as fields, paddy fields, lawns, orchards, or non-agricultural lands.
- plants to which the present control method can be applied include the following plants.
- Agricultural crops corn, rice, wheat, barley, rye, oat, sorghum, cotton, soybean, peanut, buckwheat, sugar beet, rapeseed, sunflower, sugarcane, tobacco, etc.
- Vegetables Eggplant vegetables (eggplant, tomatoes, peppers, peppers, potatoes, etc.), cucurbits vegetables (cucumbers, pumpkins, zucchini, watermelon, melon, squash, etc.), cruciferous vegetables (radish, turnip, horseradish, kohlrabi, Chinese cabbage) , Cabbage, mustard, broccoli, cauliflower, etc.), asteraceae vegetables (burdock, garlic, artichoke, lettuce, etc.), liliaceae vegetables (leek, onion, garlic, asparagus), celery family vegetables (carrot, parsley, celery, USA) Bowfish, etc.), red crustacean vegetables (spinach, chard, etc.), perilla vegetables (perilla, mint, basil, etc.), strawberries, sweet potatoes, yam, taros, etc.
- Trees other than fruit trees Cha, mulberry, flowering trees, yellow-breasted, roadside trees (ash, birch, dogwood, eucalyptus, ginkgo, lilac, maple, oak, poplar, poppy, redwood, fu, platanus, zelkova, black beet, black mink, tsuga, nezu , Pine, spruce, yew) etc.
- the plant includes a genetically modified plant.
- Formulation Example 1 Add 15 parts of ethaboxam, 5 parts of metalaxyl and 15 parts of oxathiapiproline to a mixture of 4 parts of sodium lauryl sulfate, 2 parts of calcium lignin sulfonate, 20 parts of synthetic silicon hydroxide fine powder and 39 parts of diatomaceous earth and stir well. Mix to obtain wettable powder.
- Formulation Example 2 Add 15 parts of ethaboxam, 5 parts of metalaxyl and 15 parts of this compound (3b) to a mixture of 4 parts of sodium lauryl sulfate, 2 parts of calcium lignin sulfonate, 20 parts of synthetic silicon hydroxide fine powder and 39 parts of diatomaceous earth. Stir and mix to obtain a wettable powder.
- Formulation Example 3 A powder is obtained by thoroughly pulverizing and mixing 1.5 parts of ethaboxam, 0.5 parts of metalaxyl, 2 parts of oxathiapiproline, 86 parts of kaolin clay and 10 parts of talc.
- Formulation Example 4 A powder is obtained by thoroughly pulverizing and mixing 1.5 parts of ethaboxam, 0.5 parts of metalaxyl, 2 parts of this compound (3b), 86 parts of kaolin clay and 10 parts of talc.
- Formulation Example 5 8 parts of ethaboxam, 2.5 parts of metalaxyl, 10 parts of oxathiapiproline, 30 parts of a mixture containing polyoxyethylene alkyl ether sulfate ammonium salt and white carbon in a weight ratio of 1: 1 and 49.5 parts of water are mixed.
- the flowable agent is obtained by fine pulverization by a wet pulverization method.
- Seed treatment example 1 Water is added to 4 g of the formulation obtained by the method described in Formulation Example 1 to make a total volume of 40 ml, and this is applied to 10 kg of dried corn seeds using a rotary seed treatment machine (seed treater, manufactured by Hege11 Wintersteiger). As a result, treated seeds are obtained.
- Seed treatment example 2 Water is added to 99.6 g of the preparation obtained by the method described in Preparation Example 2 to make a total volume of 50 ml, and this is smeared on 10 kg of dried soybean seeds using a rotary seed treatment machine (Seed Treater, manufactured by Hege11 Wintersteiger). Treated seeds are obtained by treatment.
- a rotary seed treatment machine Seed Treater, manufactured by Hege11 Wintersteiger.
- Seed treatment example 3 Water is added to 9.4 g of the preparation obtained by the method described in Preparation Example 5 to make a total volume of 50 ml, and this is applied to 10 kg of dried wheat seeds using a rotary seed treatment machine (Seed Treater, manufactured by Hege11 Wintersteiger). Treated seeds are obtained by treatment.
- a rotary seed treatment machine Seed Treater, manufactured by Hege11 Wintersteiger.
- Test example 1 An acetone solution of the compound was prepared so that the treatment amount of the compound when treated on the seeds was the numerical value shown in Table 1. After putting 10 g of soybean (Hatayutaka) seeds and 80 ⁇ l of the acetone solution in a plastic container, capping and shaking, the seeds taken out from the container were allowed to stand overnight to obtain treated seeds. A plastic pot was filled with culture soil, the treated seeds were sown, and the soil was covered with a culture soil mixed with seeds of shiba infected with Pythium irregulare. After irrigation, it was grown at 15 ° C. for 5 days, and then grown at 25 ° C. for 10 days. This is the treatment area.
- soybeans were grown in the same manner as in the treatment group except that the seed was not treated with the drug. Let this be an untreated zone.
- the disease severity of each plant in the treated group and the untreated group was calculated according to the following “Formula 1”.
- the control value was calculated using the following “Formula 2”.
- "Formula 1" Incidence degree (number of non-emergence seeds and number of diseased seedlings) ⁇ 100 / (total seeding number)
- "Formula 2" Control value 100 ⁇ (AB) / A
- B Disease severity of treated plant Table 1 shows the results.
- Test example 2 An acetone solution of the compound was prepared so that the treatment amount of the compound when the seed was treated was the numerical value shown in Table 2. After putting 10 g of soybean seeds and 80 ⁇ l of the acetone solution in a plastic container, capping and shaking the seeds, the seeds taken out from the container were allowed to stand overnight to obtain treated seeds. A plastic pot was filled with culture soil, the treated seeds were sown, and the soil was covered with culture soil mixed with shiba seeds infected with Pythium ultimum. After irrigation, it was grown at 15 ° C. for 5 days, and then grown at 25 ° C. for 10 days. This is the treatment area. In addition, soybeans were grown in the same manner as in the treatment group except that the seed was not treated with the drug. Let this be an untreated zone. The disease severity of each plant in the treated group and the untreated group was calculated according to “Formula 1”. The control value was calculated using “Formula 2”. The results are shown in Table 2.
- plant diseases can be controlled.
Abstract
Description
即ち、本発明は以下の通りである。
〔1〕 下記式(1)
で示される化合物、
下記式(2)
で示される化合物及び
下記式(3)
〔式中、R1、R2、R3及びR4の組合せは、
R1がメチル基であり、R2がトリフルオロメチル基であり、R3及びR4がいずれもフッ素原子である組合せ、又は、R1及びR2がいずれもジフルオロメチル基であり、R3が塩素原子であり、R4がメタンスルホニルオキシ基である組合せを表す。〕で示される化合物を含有する植物病害防除組成物。
〔2〕 前記式(1)で示される化合物と前記式(2)で示される化合物との重量比が、1:0.02~1:50である〔1〕記載の植物病害防除組成物。
〔3〕 前記式(1)で示される化合物と前記式(3)で示される化合物との重量比が、1:0.02~1:50である〔1〕又は〔2〕記載の植物病害防除組成物。
〔4〕 前記式(3)で示される化合物が、当該式(3)において、R1がメチル基であり、R2がトリフルオロメチル基であり、R3及びR4がいずれもフッ素原子である化合物である〔1〕~〔3〕いずれか一項記載の植物病害防除組成物。
〔5〕 下記式(1)
で示される化合物、
下記式(2)
で示される化合物及び
下記式(3)
〔式中、R1、R2、R3及びR4の組合せは、
R1がメチル基であり、R2がトリフルオロメチル基であり、R3及びR4がいずれもフッ素原子である組合せ、又は、R1及びR2がいずれもジフルオロメチル基であり、R3が塩素原子であり、R4がメタンスルホニルオキシ基である組合せを表す。〕で示される化合物の有効量を、植物又は植物を栽培する土壌に施用する工程を含む植物病害防除方法。
〔6〕 下記式(1)
で示される化合物、
下記式(2)
で示される化合物及び
下記式(3)
〔式中、R1、R2、R3及びR4の組合せは、
R1がメチル基であり、R2がトリフルオロメチル基であり、R3及びR4がいずれもフッ素原子である組合せ、又は、R1及びR2がいずれもジフルオロメチル基であり、R3が塩素原子であり、R4がメタンスルホニルオキシ基である組合せを表す。〕で示される化合物を含有する種子処理剤。
〔7〕 下記式(1)
で示される化合物、
下記式(2)
で示される化合物及び
下記式(3)
〔式中、R1、R2、R3及びR4の組合せは、
R1がメチル基であり、R2がトリフルオロメチル基であり、R3及びR4がいずれもフッ素原子である組合せ、又は、R1及びR2がいずれもジフルオロメチル基であり、R3が塩素原子であり、R4がメタンスルホニルオキシ基である組合せを表す。〕で示される化合物で処理されてなる種子。
本発明組成物における、本化合物(1)、本化合物(2)及び本化合物(3)の合計量は、通常0.01~99重量%、好ましくは0.1~90重量%、さらに好ましくは0.5~70重量%の範囲である。
・フルジオキソニル、マンデストロビン、クロチアニジン、α1、イプコナゾール、メタラキシル、エタボキサム、オキサチアピプロリン及びチアベンダゾールの組合せ
・フルジオキソニル、マンデストロビン、クロチアニジン、α1、イプコナゾール、メタラキシル-M、エタボキサム、オキサチアピプロリン及びチアベンダゾールの組合せ
・フルジオキソニル、マンデストロビン、クロチアニジン、α1、メトコナゾール、メタラキシル、エタボキサム、オキサチアピプロリン及びチアベンダゾールの組合せ
・フルジオキソニル、マンデストロビン、クロチアニジン、α1、メトコナゾール、メタラキシル-M、エタボキサム、オキサチアピプロリン及びチアベンダゾールの組合せ
・フルジオキソニル、マンデストロビン、クロチアニジン、トルクロホスメチル、イプコナゾール、メタラキシル、エタボキサム、オキサチアピプロリン及びチアベンダゾールの組合せ
・フルジオキソニル、マンデストロビン、クロチアニジン、トルクロホスメチル、イプコナゾール、メタラキシル-M、エタボキサム、オキサチアピプロリン及びチアベンダゾールの組合せ
・フルジオキソニル、マンデストロビン、クロチアニジン、トルクロホスメチル、メトコナゾール、メタラキシル、エタボキサム、オキサチアピプロリン及びチアベンダゾールの組合せ
・フルジオキソニル、マンデストロビン、クロチアニジン、トルクロホスメチル、メトコナゾール、メタラキシル-M、エタボキサム、オキサチアピプロリン及びチアベンダゾールの組合せ
・フルジオキソニル、マンデストロビン、チアメトキサム、α1、イプコナゾール、メタラキシル、エタボキサム、オキサチアピプロリン及びチアベンダゾールの組合せ
・フルジオキソニル、マンデストロビン、チアメトキサム、α1、イプコナゾール、メタラキシル-M、エタボキサム、オキサチアピプロリン及びチアベンダゾールの組合せ
・フルジオキソニル、マンデストロビン、チアメトキサム、α1、メトコナゾール、メタラキシル、エタボキサム、オキサチアピプロリン及びチアベンダゾールの組合せ
・フルジオキソニル、マンデストロビン、チアメトキサム、α1、メトコナゾール、メタラキシル-M、エタボキサム、オキサチアピプロリン及びチアベンダゾールの組合せ
・フルジオキソニル、マンデストロビン、チアメトキサム、トルクロホスメチル、イプコナゾール、メタラキシル、エタボキサム、オキサチアピプロリン及びチアベンダゾールの組合せ
・フルジオキソニル、マンデストロビン、チアメトキサム、トルクロホスメチル、イプコナゾール、メタラキシル-M、エタボキサム、オキサチアピプロリン及びチアベンダゾールの組合せ
・フルジオキソニル、マンデストロビン、チアメトキサム、トルクロホスメチル、メトコナゾール、メタラキシル、エタボキサム、オキサチアピプロリン及びチアベンダゾールの組合せ
・フルジオキソニル、マンデストロビン、チアメトキサム、トルクロホスメチル、メトコナゾール、メタラキシル-M、エタボキサム、オキサチアピプロリン及びチアベンダゾールの組合せ
イネの病害:いもち病(Magnaporthe grisea)、ごま葉枯病(Cochliobolus miyabeanus)、紋枯病(Rhizoctonia solani)、馬鹿苗病(Gibberella fujikuroi)。
コムギの病害:うどんこ病(Erysiphe graminis)、赤かび病(Fusarium graminearum,F.avenacerum,F.culmorum,Microdochium nivale)、さび病(Puccinia striiformis,P.graminis,P.recondita)、紅色雪腐病(Micronectriella nivale)、雪腐小粒菌核病(Typhula spp.)、裸黒穂病(Ustilago tritici)、なまぐさ黒穂病(Tilletia caries)、眼紋病(Pseudocercosporella herpotrichoides)、葉枯病(Mycosphaerella graminicola)、ふ枯病(Stagonospora nodorum)、黄斑病(Pyrenophora tritici‐repentis)。
オオムギの病害:うどんこ病(Erysiphe graminis)、赤かび病(Fusarium graminearum,F.avenacerum,F.culmorum,Microdochium nivale)、さび病(Puccinia striiformis,P.graminis,P.hordei)、裸黒穂病(Ustilago nuda)、雲形病(Rhynchosporium secalis)、網斑病(Pyrenophora teres)、斑点病(Cochliobolus sativus)、斑葉病(Pyrenophora graminea)、リゾクトニア属菌による苗立枯病(Rhizoctonia solani)。
トウモロコシの病害:黒穂病(Ustilago maydis)、ごま葉枯病(Cochliobolus heterostrophus)、ひょう紋病(Gloeocercospora sorghi)、南方さび病(Puccinia polysora)、グレイリーフスポット病(Cercospora zeae‐maydis)、リゾクトニア属菌による苗立枯病(Rhizoctonia solani)、トウモロコシのべと病(Peronosclerospora philippinensis)。
リンゴの病害:モニリア病(Monilinia mali)、腐らん病(Valsa ceratosperma)、うどんこ病(Podosphaera leucotricha)、斑点落葉病(Alternaria alternata apple pathotype)、黒星病(Venturia inaequalis)、炭そ病(Colletotrichum acutatum)、疫病(Phytophtora cactorum)、褐斑病(Diplocarpon mali)、輪紋病(Botryosphaeria berengeriana)、紫紋羽病(Helicobasidium mompa)。
ナシの病害:黒星病(Venturia nashicola,V.pirina)、黒斑病(Alternaria alternata Japanese pear pathotype)、赤星病(Gymnosporangium haraeanum)、疫病(Phytophtora cactorum)。
モモの病害:灰星病(Monilinia fructicola)、黒星病(Cladosporium carpophilum)、フォモプシス腐敗病(Phomopsis spp.)。
ブドウの病害:黒とう病(Elsinoe ampelina)、晩腐病(Glomerella cingulata)、うどんこ病(Uncinula necator)、さび病(Phakopsora ampelopsidis)、ブラックロット病(Guignardia bidwellii)、べと病(Plasmopara viticola)。
カキの病害:炭そ病(Gloeosporium kaki)、落葉病(Cercospora kaki,Mycosphaerella nawae)。
ウリ類の病害:炭そ病(Colletotrichum lagenarium)、うどんこ病(Sphaerotheca fuliginea)、つる枯病(Mycosphaerella melonis)、つる割病(Fusarium oxysporum)、べと病(Pseudoperonospora cubensis)、疫病(Phytophthora spp.)、苗立枯病(Pythium spp.)。
トマトの病害:輪紋病(Alternaria solani)、葉かび病(Cladosporium fulvum)、疫病(Phytophthora infestans)。
ナスの病害:褐紋病(Phomopsis vexans)、うどんこ病(Erysiphe cichoracearum)。
アブラナ科野菜の病害:黒斑病(Alternaria japonica)、白斑病(Cercosporella brassicae)、根こぶ病(Plasmodiophora brassicae)、べと病(Peronospora parasitica)。
ネギの病害:さび病(Puccinia allii)、べと病(Peronospora destructor)。
インゲンの病害:炭そ病(Colletotrichum lindemthianum)。
ラッカセイの病害:黒渋病(Cercospora personata)、褐斑病(Cercospora arachidicola)、白絹病(Sclerotium rolfsii)。
エンドウの病害:うどんこ病(Erysiphe pisi)、根腐病(Fusarium solani F.sp.pisi)。
ジャガイモの病害:夏疫病(Alternaria solani)、疫病(Phytophthora infestans)、緋色腐敗病(Phytophthora erythroseptica)、粉状そうか病(Spongospora subterranean F.sp.subterranea)、黒あざ病(Rhizoctonia solani)。
イチゴの病害:うどんこ病(Sphaerotheca humuli)、炭そ病(Glomerella cingulata)。
チャの病害:網もち病(Exobasidium reticulatum)、白星病(Elsinoe leucospila)、輪斑病(Pestalotiopsis spp.)、炭そ病(Colletotrichum theae‐sinensis)。
タバコの病害:赤星病(Alternaria longipes)、うどんこ病(Erysiphe cichoracearum)、炭そ病(Colletotrichum tabacum)、べと病(Peronospora tabacina)、疫病(Phytophthora nicotianae)。
ナタネの病害:菌核病(Sclerotinia sclerotiorum)、リゾクトニア属菌による苗立枯病(Rhizoctonia solani)。
ワタの病害:リゾクトニア属菌による苗立枯病(Rhizoctonia solani)。
テンサイの病害:褐斑病(Cercospora beticola)、葉腐病(Rhizoctonia solani)、根腐病(Rhizoctonia solani)、黒根病(Aphanomyces cochlioides)。
バラの病害:黒星病(Diplocarpon rosae)、うどんこ病(Sphaerotheca pannosa)、べと病(Peronospora sparsa)。
キク及びキク科野菜の病害:べと病(Bremia lactucae)、褐斑病(Septoria chrysanthemi‐indici)、白さび病(Puccinia horiana)。
種々の植物の病害:ピシウム属菌によって引き起こされる病害(Pythium debarianum,Pythium graminicola,Pythium irregulare,Pythium ultimum)、灰色かび病(Botrytis cinerea)、菌核病(Sclerotinia sclerotiorum)、白絹病(Sclerotium rolfsii)。
ダイコンの病害:黒斑病(Alternaria brassicicola)。
シバの病害:ダラースポット病(Sclerotinia homeocarpa)、ブラウンパッチ病及びラージパッチ病(Rhizoctonia solani)。
バナナの病害:シガトカ病(Mycosphaerella fijiensis,Mycosphaerella musicola)。
ヒマワリの病害:べと病(Plasmopara halstedii)。
Aspergillus属、Penicillium属、Fusarium属、Gibberella属、Tricoderma属、Thielaviopsis属、Rhizopus属、Mucor属、Corticium属、Phoma属、Rhizoctonia属、及びDiplodia属菌等によって引き起こされる、各種植物の種子病害又は生育初期の病害。
Polymixa属又はOlpidium属等によって媒介される各種植物のウイルス病。
本化合物(1)、本化合物(2)及び本化合物(3)は各々同時期に別々に施用してもよいが、通常は施用の簡便性の観点から、本発明組成物が有効量で施用される。施用の形態としては、例えば、茎葉処理、土壌処理、根部処理及び種子処理が挙げられる。種子処理においては、本発明組成物を種子処理剤として用いることができる。
茎葉処理としては、茎葉散布及び樹幹散布により、栽培されている植物の表面に施用する方法が挙げられる。土壌処理としては、土壌散布、土壌混和及び土壌への薬液潅注が挙げられる。根部処理としては、薬液に植物の全体又は根部を浸漬する方法、固体担体を用いて製剤化したものを植物の根部に付着させる方法が挙げられる。
種子処理としては、植物病害から保護しようとする植物の種子又は球根への本発明組成物の処理が挙げられる。詳しくは、例えば本発明組成物の懸濁液を霧状にして種子表面若しくは球根表面に吹きつける吹きつけ処理、その形態が溶剤に溶解した溶液、水和剤、乳剤若しくはフロアブル剤であり、必要に応じ水が加えられた本発明組成物を、種子又は球根に塗布する塗沫処理、本発明組成物の水分散液に一定時間種子を浸漬する浸漬処理、フィルムコート処理及びペレットコート処理が挙げられる。
乳剤、水和剤、フロアブル剤等は通常水と混合して得られる薬液を散布することにより処理する。該薬液における本有効成分量の濃度は通常0.0001~3重量%、好ましくは0.0005~1重量%である。粉剤、粒剤等は通常そのまま処理する。
種子へ処理する場合の本有効成分量は、種子1kgあたり、通常0.001~10g、好ましくは0.01~3gである。種子への処理は、播種されていない種子に対して施される。播種されていない種子とは、播種されるまでの任意の時点の種子を意味する。
上記で説明したように、種子への処理を施すことにより、本化合物(1)、本化合物(2)及び本化合物(3)で処理されてなる種子を得ることができる。該種子は、本化合物(1)、本化合物(2)及び本化合物(3)の有効量を保持している。そのため、該種子又は該種子より生長した植物体は病害から保護される。
農作物;トウモロコシ、イネ、コムギ、オオムギ、ライムギ、エンバク、ソルガム、ワタ、ダイズ、ピーナッツ、ソバ、テンサイ、ナタネ、ヒマワリ、サトウキビ、タバコ等、
野菜;ナス科野菜(ナス、トマト、ピーマン、トウガラシ、ジャガイモ等)、ウリ科野菜(キュウリ、カボチャ、ズッキーニ、スイカ、メロン、スカッシュ等)、アブラナ科野菜(ダイコン、カブ、セイヨウワサビ、コールラビ、ハクサイ、キャベツ、カラシナ、ブロッコリー、カリフラワー等)、キク科野菜(ゴボウ、シュンギク、アーティチョーク、レタス等)、ユリ科野菜(ネギ、タマネギ、ニンニク、アスパラガス)、セリ科野菜(ニンジン、パセリ、セロリ、アメリカボウフウ等)、アカザ科野菜(ホウレンソウ、フダンソウ等)、シソ科野菜(シソ、ミント、バジル等)、イチゴ、サツマイモ、ヤマノイモ、サトイモ等、
花卉、
観葉植物、
シバ、
果樹;仁果類(リンゴ、セイヨウナシ、ニホンナシ、カリン、マルメロ等)、核果類(モモ、スモモ、ネクタリン、ウメ、オウトウ、アンズ、プルーン等)、カンキツ類(ウンシュウミカン、オレンジ、レモン、ライム、グレープフルーツ等)、堅果類(クリ、クルミ、ハシバミ、アーモンド、ピスタチオ、カシューナッツ、マカダミアナッツ等)、液果類(ブルーベリー、クランベリー、ブラックベリー、ラズベリー等)、ブドウ、カキ、オリーブ、ビワ、バナナ、コーヒー、ナツメヤシ、ココヤシ等、
果樹以外の樹;チャ、クワ、花木、ナンヨウアブラギリ、街路樹(トネリコ、カバノキ、ハナミズキ、ユーカリ、イチョウ、ライラック、カエデ、カシ、ポプラ、ハナズオウ、フウ、プラタナス、ケヤキ、クロベ、モミノキ、ツガ、ネズ、マツ、トウヒ、イチイ)等。
上記のうち、特にトウモロコシ、イネ、コムギ、オオムギ、ソルガム、ワタ、ダイズ、テンサイ、ナタネ、シバ、ジャガイモの栽培において、本発明防除方法を適用することが好ましい。
エタボキサム15部、メタラキシル5部及びオキサチアピプロリン15部を、ラウリル硫酸ナトリウム4部、リグニンスルホン酸カルシウム2部、合成含水酸化珪素微粉末20部及び珪藻土39部を混合した中に加え、よく攪拌混合して水和剤を得る。
エタボキサム15部、メタラキシル5部及び本化合物(3b)15部を、ラウリル硫酸ナトリウム4部、リグニンスルホン酸カルシウム2部、合成含水酸化珪素微粉末20部及び珪藻土39部を混合した中に加え、よく攪拌混合して水和剤を得る。
エタボキサム1.5部、メタラキシル0.5部、オキサチアピプロリン2部、カオリンクレー86部及びタルク10部をよく粉砕混合することにより粉剤を得る。
エタボキサム1.5部、メタラキシル0.5部、本化合物(3b)2部、カオリンクレー86部及びタルク10部をよく粉砕混合することにより粉剤を得る。
エタボキサム8部、メタラキシル2.5部、オキサチアピプロリン10部、ポリオキシエチレンアルキルエーテルサルフェートアンモニウム塩とホワイトカーボンとを1:1の重量比で含む混合物30部及び水49.5部を混合し、湿式粉砕法で微粉砕することにより、フロアブル剤を得る。
エタボキサム8部、メタラキシル2.5部、本化合物(3b)10部、ポリオキシエチレンアルキルエーテルサルフェートアンモニウム塩とホワイトカーボンとを1:1の重量比で含む混合物30部及び水49.5部を混合し、湿式粉砕法で微粉砕することにより、フロアブル剤を得る。
製剤例1に記載の方法で得られる製剤4gに水を加えて全量40mlとし、これを、回転式種子処理機(種子トリーター、Hege11 Wintersteiger社製)を用いてトウモロコシ乾燥種子10kgに塗沫処理することにより、処理種子を得る。
製剤例2に記載の方法で得られる製剤99.6gに水を加えて全量50mlとし、これを、回転式種子処理機(種子トリーター、Hege11 Wintersteiger社製)を用いてダイズ乾燥種子10kgに塗沫処理することにより、処理種子を得る。
製剤例5に記載の方法で得られる製剤9.4gに水を加えて全量50mlとし、これを、回転式種子処理機(種子トリーター、Hege11 Wintersteiger社製)を用いてコムギ乾燥種子10kgに塗沫処理することにより、処理種子を得る。
種子へ処理したときの化合物の処理量が表1に記載の数値になるように、化合物のアセトン溶液を調製した。プラスチック容器にダイズ(ハタユタカ)の種子10g及び該アセトン溶液80μlを入れ、蓋をして振り混ぜた後、該容器から取り出した種子を一晩静置することにより、処理種子を得た。プラスチックポットに培養土を詰め、該処理種子を播種し、苗立枯病菌(Pythium irregulare)を感染させたシバの種子を混合した培養土で覆土した。潅水したのち15℃で5日間生育させ、その後25℃で10日間生育させた。これを処理区とする。
また、種子へ薬剤を処理しなかったこと以外は、処理区と同様にダイズを生育させた。これを無処理区とする。
下記「式1」により処理区及び無処理区のそれぞれの植物の発病度を算出した。防除価は、下記「式2」を用いて算出した。
「式1」
発病度=(不出芽種子数及び発病苗数)×100/(総播種数)
「式2」
防除価=100×(A-B)/A
A:無処理区の植物の発病度
B:処理区の植物の発病度
結果を表1に示す。
種子へ処理したときの化合物の処理量が表2に記載の数値になるように、化合物のアセトン溶液を調製した。プラスチック容器にダイズ(ハタユタカ)の種子10g及び該アセトン溶液80μlを入れ、蓋をして振り混ぜた後、該容器から取り出した種子を一晩静置することにより処理種子を得た。プラスチックポットに培養土を詰め、該処理種子を播種し、苗立枯病菌(Pythium ultimum)を感染させたシバの種子を混合した培養土で覆土した。潅水したのち15℃で5日間生育させ、その後25℃で10日間生育させた。これを処理区とする。
また、種子へ薬剤を処理しなかったこと以外は、処理区と同様にダイズを生育させた。これを無処理区とする。
前記「式1」により処理区及び無処理区のそれぞれの植物の発病度を算出した。防除価は、前記「式2」を用いて算出した。
結果を表2に示す。
Claims (7)
- 前記式(1)で示される化合物と前記式(2)で示される化合物との重量比が、1:0.02~1:50である請求項1記載の植物病害防除組成物。
- 前記式(1)で示される化合物と前記式(3)で示される化合物との重量比が、1:0.02~1:50である請求項1又は2記載の植物病害防除組成物。
- 前記式(3)で示される化合物が、当該式(3)において、R1がメチル基であり、R2がトリフルオロメチル基であり、R3及びR4がいずれもフッ素原子である化合物である請求項1~3いずれか一項記載の植物病害防除組成物。
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