JP2015034987A - 気体環境中のフォトレジストをレーザ処理する方法 - Google Patents
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Abstract
【解決手段】a)トリメチルアルミニウムガス、四塩化チタンガス、及びジエチル亜鉛ガスからなる群から選択される少なくとも1つの第1の処理ガスに、フォトレジスト層を曝す工程、b)フォトレジスト層及び第1の処理ガスにレーザを照射し、第1の処理ガスをフォトレジスト層に注入させる工程であって、フォトレジスト層の表面は、+/−5℃の温度均一性を有する300℃から500℃の間の温度に上昇させられる工程、c)フォトレジスト層の周辺から、残余の第1の処理ガスを除去する工程、d)フォトレジスト層を、H2Oを含む第2の処理ガスに曝す工程、e)フォトレジスト層及び第2の処理ガスにレーザを照射し、H2Oをフォトレジスト層に注入させる工程とを含む方法。
【選択図】図3
Description
以降、本開示の様々な実施形態、および、添付の図面に示される複数の例について詳述する。可能な限り、同一または類似の部分の図では、同一または類似の参照番号および参照符号が用いられる。図面には決まった縮尺がなく、当業者であれば、図面は本発明の主要な部分を説明するために簡略化されていることに気づくであろう。
Claims (33)
- パターン化製品ウエハにおいて、表面を有するフォトレジスト層のエッチング耐性及び線境界粗さのうちの少なくとも一つを改善する方法であって、:
a)トリメチルアルミニウム(Al2(CH3)6)ガス、四塩化チタン(TiCl4)ガス、及びジエチル亜鉛((C2H5)2Zn)ガスからなる群から選択される少なくとも1つの第1の処理ガスに、フォトレジスト層を曝す工程と、;
b)前記フォトレジスト層及び前記第1の処理ガスにレーザを照射し、前記第1の処理ガスを前記フォトレジスト層に注入させる工程であって、前記フォトレジスト層の表面は、+/−5℃の温度均一性を有する300℃から500℃の間の温度に上昇させられる工程と、;
c)前記フォトレジスト層の周辺から、残余の第1の処理ガスを除去する工程と、;
d)前記フォトレジスト層を、H2Oを含む第2の処理ガスに曝す工程と、;
e)前記フォトレジスト層及び第2の処理ガスにレーザを照射し、前記H2Oを前記フォトレジスト層に注入させる工程であって、前記フォトレジスト層の表面は、+/−5℃の温度均一性を有する300℃から500℃の間の温度に上昇させられる工程と、
を含む方法。 - 前記レーザを照射することは、前記フォトレジスト層の表面上でレーザ光線を走査することを含む、請求項1に記載の方法。
- 前記走査することは、前記レーザ光線を動かすことか、前記パターン化製品ウエハを動かすことか、又は、前記レーザ光線及び前記パターン化製品ウエハの両方を動かすことかの何れかを含む、請求項2に記載の方法。
- 前記レーザ光線は、前記フォトレジスト層の表面で線画像を形成する、請求項2又は3に記載の方法。
- 前記線画像は、1ms≦τ≦100msの範囲の滞留時間τを有する、請求項4に記載の方法。
- 前記線画像は、0.2mm≦W≦2mmの範囲の幅W、及び、10mm≦L≦100mmの範囲の長さLを有する、請求項4又は5に記載の方法。
- 前記線画像は、20mm/s≦vs≦5,000mm/sの範囲の走査速度vsを有する、請求項4から6の何れか1項に記載の方法。
- 前記レーザ光線は、50ワット/cm2≦P≦150ワット/cm2の範囲の出力密度Pを有する、請求項2から7の何れか1項に記載の方法。
- 前記パターン化製品ウエハは、処理チャンバの内部に保持される、請求項1から8の何れか1項に記載の方法。
- 処理された前記パターン化製品ウエハをエッチングすることをさらに含む、請求項1から9の何れか1項に記載の方法。
- 工程a)から工程e)は、30秒から120秒の間のウエハ処理時間で、ウエハ全体に対して行われる、請求項1から10の何れか1項に記載の方法。
- 工程a)から工程e)は、1回以上繰り返され、各工程e)の後に、フォトレジスト層の周辺から前記第2の処理ガスを除去する工程を追加する、請求項1から11の何れか1項に記載の方法。
- 前記製品ウエハは、処理チャンバの内部に存在し、前記フォトレジスト層の周辺から前記第1の処理ガスを除去することは、前記処理チャンバ内部から前記第1の処理ガスを排出することと、前記処理チャンバ内部を不活性ガスでパージすることのうちの少なくとも一つを含む、請求項1から12の何れか1項に記載の方法。
- 処理チャンバの内部にあり、表面を有するパターン化フォトレジスト層を有する製品ウエハを処理する方法であり、エッチング耐性及び線境界粗さのうちの少なくとも一つを改善する方法であって、:
a)第1の分子処理ガスに、パターン化フォトレジスト層の表面を曝す工程と、;
b)前記パターン化フォトレジスト層の表面にレーザ光線を走査し、前記パターン化フォトレジスト層に第1の分子処理ガスの分子を注入させる工程であって、前記パターン化フォトレジスト層の表面は、+/−5℃の温度均一性を有する300℃から500℃の間の温度に上昇させられる工程と、;
c)前記処理チャンバの内部から、残余の第1の分子処理ガスを除去する工程と、;
d)前記パターン化フォトレジスト層を第2の分子処理ガスに曝し、該第2の分子処理ガスに対して工程b)を繰り返す工程と、;を含み、
前記第1の分子処理ガスは、トリメチルアルミニウム(Al2(CH3)6)ガス、四塩化チタン(TiCl4)ガス、ジエチル亜鉛((C2H5)2Zn)ガスからなる群から選択される少なくとも一つであり、前記第2の分子処理ガスは、H2Oを含む、方法。 - 前記レーザ光線は、パターン化フォトレジスト層の表面で線画像を形成し、該線画像は、1ms≦τ≦100msの範囲の滞留時間τを有する、請求項14に記載の方法。
- 前記線画像は、0.2mm≦W≦2mmの範囲の幅W、及び、10mm≦L≦100mmの範囲の長さLを有する、請求項15に記載の方法。
- 前記線画像は、20mm/s≦vs≦5,000mm/sの範囲の走査速度vsを有する、請求項15又は16に記載の方法。
- 前記レーザ光線は、50ワット/cm2≦P≦150ワット/cm2の範囲の出力密度Pを有する、請求項14から17の何れか1項に記載の方法。
- 処理された前記パターン化製品ウエハをエッチングすることをさらに含む、請求項14から18の何れか1項に記載の方法。
- 工程a)から工程d)は、30秒から120秒の間のウエハ処理時間で、ウエハ全体に対して行われる、請求項14から19の何れか1項に記載の方法。
- 前記処理チャンバの内部から前記第1の分子処理ガスを除去することは、前記処理チャンバ内部から前記第1の分子処理ガスを排出することと、前記処理チャンバ内部を不活性ガスでパージすることのうちの少なくとも一つを含む、請求項14から20の何れか1項に記載の方法。
- 処理チャンバの内部に存在し、表面を有するパターン化フォトレジスト層を有する製品ウエハを処理する方法であり、エッチング耐性及び線境界粗さのうちの少なくとも一つを改善する方法であって、:
a)第1及び第2の分子処理ガスを連続して前記処理チャンバの内部に導入し、前記第1又は第2の分子処理ガスを、他方の第1又は第2の分子処理ガスが導入される前に、前記処理チャンバの内部から除去することを含む工程と、;
b)前記第1及び第2の分子ガスそれぞれについて、前記パターン化フォトレジスト層の表面をレーザ走査し、前記パターン化フォトレジスト層に前記第1及び第2の分子ガスを連続的に注入させる工程と、;
c)工程a)及び工程b)を複数回繰り返す工程と、を含み、
前記第1の分子ガスは、トリメチルアルミニウム(Al2(CH3)6)、四塩化チタン(TiCl4)、及びジエチル亜鉛((C2H5)2Zn)からなる群から選択される少なくとも一つであり、前記第2の分子ガスは、水蒸気を含む、方法。 - 前記レーザ走査は、線画像を形成するレーザ光線を使用して行われ、該線画像は、1ms≦τ≦100msの範囲の滞留時間τを有する、請求項22に記載の方法。
- 前記線画像は、0.2mm≦W≦2mmの範囲の幅W、及び、10mm≦L≦100mmの範囲の長さLを有する、請求項23に記載の方法。
- 前記線画像は、20mm/s≦vs≦5,000mm/sの範囲の走査速度vsを有する、請求項23または24に記載の方法。
- 前記レーザ光線は、50ワット/cm2≦P≦150ワット/cm2の範囲の出力密度Pを有する、請求項23から25の何れか1項に方法。
- 前記処理チャンバの内部から前記第1又は第2の分子処理ガスを除去することは、i)前記処理チャンバ内部から前記第1又は第2の分子処理ガスを排出すること、及び、ii)前記処理チャンバ内部を不活性ガスでパージすることの少なくとも一つを含む、請求項22から26の何れか1項に記載の方法。
- 処理チャンバの内部に存在し、表面を有するパターン化フォトレジスト層を有する製品ウエハを処理する方法であり、エッチング耐性及び線境界粗さのうちの少なくとも一つを改善する方法であって、:
a)分子を含む第1の処理ガスに、パターン化フォトレジスト層の表面を曝す工程であって、前記第1の処理ガス分子は、トリメチルアルミニウム(Al2(CH3)6)ガス、四塩化チタン(TiCl4)ガス、及びジエチル亜鉛((C2H5)2Zn)ガスからなる分子の群から選択される少なくとも一つである工程と、;
b)前記パターン化フォトレジスト層の表面をレーザ光線で走査し、前記前記パターン化フォトレジスト層に前記第1の処理ガスの分子を注入させる工程であって、前記パターン化フォトレジスト層の表面は、+/−5℃の温度均一性を有する300℃から500℃の間の温度に上昇させられる工程と、
を含む方法。 - 工程b)の後に、:
c)前記処理チャンバの内部から、前記第1の処理ガスを除去する工程と、;
d)前記パターン化フォトレジスト層を、H2O分子を含む第2の処理ガスに曝す工程と、;
e)前記パターン化フォトレジスト層の表面にレーザ光線を走査し、前記H2O分子を前記パターン化フォトレジスト層に注入させる工程と、
をさらに含む、請求項28に記載の方法。 - 前記処理チャンバの内部から前記第1の分子処理ガスを除去することは、i)前記処理チャンバ内部から前記第1又は第2の分子処理ガスを排出すること、及び、ii)前記処理チャンバ内部を不活性ガスでパージすることの少なくとも一つを含む、請求項29に記載の方法。
- レーザ光線の走査は、1ms≦τ≦100msの範囲の滞留時間τを有する線画像を形成する、請求項28から30の何れか1項に記載の方法。
- 前記線画像は、0.2mm≦W≦2mmの範囲の幅W、10mm≦L≦100mmの範囲の長さL、20mm/s≦vs≦5,000mm/sの範囲の走査速度vs、及び、50ワット/cm2≦P≦150ワット/cm2の範囲の出力密度Pを有する、請求項31に記載の方法。
- 工程a)から工程b)は、30秒から120秒の間のウエハ処理時間で、製品ウエハ全体に対して行われる、請求項28から32の何れか1項に記載の方法。
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SG10201406175TA (en) | 2015-03-30 |
US20150041431A1 (en) | 2015-02-12 |
US8986562B2 (en) | 2015-03-24 |
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