JP2013533577A - マグネシウム電池用の電極材料 - Google Patents

マグネシウム電池用の電極材料 Download PDF

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JP2013533577A
JP2013533577A JP2013512213A JP2013512213A JP2013533577A JP 2013533577 A JP2013533577 A JP 2013533577A JP 2013512213 A JP2013512213 A JP 2013512213A JP 2013512213 A JP2013512213 A JP 2013512213A JP 2013533577 A JP2013533577 A JP 2013533577A
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compound
magnesium
spinel
group
mixtures
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JP2013533577A5 (enExample
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ドエ，ロバート，エリス
ミューラー，ティモシー，キース
シーダー，ガーブランド
バーカー，ジャーミー
パーソン，クリスティーン，アスローグ
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ペリオン テクノロジーズ インク．
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H01M4/46—Alloys based on magnesium or aluminium
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00—Phosphorus; Compounds thereof
    • C01B25/16—Oxyacids of phosphorus; Salts thereof
    • C01B25/26—Phosphates
    • C01B25/37—Phosphates of heavy metals
    • C01B25/372—Phosphates of heavy metals of titanium, vanadium, zirconium, niobium, hafnium or tantalum
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00—Phosphorus; Compounds thereof
    • C01B25/16—Oxyacids of phosphorus; Salts thereof
    • C01B25/26—Phosphates
    • C01B25/38—Condensed phosphates
    • C01B25/42—Pyrophosphates
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    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00—Phosphorus; Compounds thereof
    • C01B25/16—Oxyacids of phosphorus; Salts thereof
    • C01B25/26—Phosphates
    • C01B25/45—Phosphates containing plural metal, or metal and ammonium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G31/00—Compounds of vanadium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G37/00—Compounds of chromium
    • C01G37/006—Compounds containing chromium, with or without oxygen or hydrogen, and containing two or more other elements
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G45/00—Compounds of manganese
    • C01G45/12—Complex oxides containing manganese and at least one other metal element
    • C01G45/1221—Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof
    • C01G45/1235—Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof of the type (Mn2O4)2-, e.g. Li2Mn2O4 or Li2(MxMn2-x)O4
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G49/00—Compounds of iron
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/40—Complex oxides containing nickel and at least one other metal element
    • C01G53/66—Complex oxides containing nickel and at least one other metal element containing alkaline earth metals, e.g. SrNiO3 or SrNiO2
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/054—Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • H—ELECTRICITY
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    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H—ELECTRICITY
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    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/581—Chalcogenides or intercalation compounds thereof
    • H01M4/5815—Sulfides
    • H—ELECTRICITY
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    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
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    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
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    • C01P2002/20—Two-dimensional structures
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    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/30—Three-dimensional structures
    • C01P2002/32—Three-dimensional structures spinel-type (AB2O4)
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
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    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
    • H—ELECTRICITY
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    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/136—Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Geology (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Secondary Cells (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
JP2013512213A 2010-05-25 2011-05-25 マグネシウム電池用の電極材料 Pending JP2013533577A (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US34806810P 2010-05-25 2010-05-25
US61/348,068 2010-05-25
PCT/US2011/037951 WO2011150093A1 (en) 2010-05-25 2011-05-25 Electrode materials for magnesium batteries

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JP2013533577A true JP2013533577A (ja) 2013-08-22
JP2013533577A5 JP2013533577A5 (enExample) 2015-04-23

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US (2) US20120219856A1 (enExample)
EP (1) EP2577780B1 (enExample)
JP (1) JP2013533577A (enExample)
KR (1) KR20130119333A (enExample)
CN (1) CN103155235A (enExample)
CA (1) CA2799209A1 (enExample)
WO (1) WO2011150093A1 (enExample)

Cited By (13)

* Cited by examiner, † Cited by third party
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JP2014143194A (ja) * 2012-12-26 2014-08-07 Showa Denko Kk マグネシウムイオン二次電池用正極活物質及びその製造方法並びにマグネシウムイオン二次電池
KR20150052369A (ko) * 2013-10-29 2015-05-14 삼성전자주식회사 마그네슘 전지용 전극 활물질, 이를 포함하는 전극 및 마그네슘 전지, 및 마그네슘 전지용 전극 활물질의 제조방법
JP2015153697A (ja) * 2014-02-18 2015-08-24 本田技研工業株式会社 正極活物質
JP2016096024A (ja) * 2014-11-14 2016-05-26 国立大学法人京都大学 二次電池
WO2017119208A1 (ja) * 2016-01-06 2017-07-13 国立研究開発法人産業技術総合研究所 二次電池用正極活物質及びその製造方法、並びに、二次電池
WO2017119494A1 (ja) * 2016-01-06 2017-07-13 国立研究開発法人産業技術総合研究所 マグネシウム化合物、二次電池用正極活物質、及び二次電池、並びにマグネシウム化合物の製造方法
JP2018078219A (ja) * 2016-11-10 2018-05-17 国立研究開発法人物質・材料研究機構 ｐ型熱電半導体、その製造方法及びそれを用いた熱電発電素子
KR20190097161A (ko) * 2016-12-15 2019-08-20 하이드로-퀘벡 탄소의 첨가에 의한 무-탄소 올리바인의 탈리튬화
JP2020024899A (ja) * 2018-05-09 2020-02-13 パナソニックＩｐマネジメント株式会社 固体電解質およびそれを用いたマグネシウム二次電池
WO2021024661A1 (ja) * 2019-08-07 2021-02-11 パナソニックＩｐマネジメント株式会社 正極活物質、及び、電池
US11081698B2 (en) 2018-04-23 2021-08-03 Panasonic Intellectual Property Management Co., Ltd. Cathode active material containing boron and carbon, and magnesium secondary battery using the same
JPWO2021166280A1 (enExample) * 2020-02-21 2021-08-26
JP2022133679A (ja) * 2021-03-02 2022-09-14 株式会社豊田中央研究所 プロトン伝導体及び電気化学デバイス

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US9466853B2 (en) 2010-09-30 2016-10-11 Ut-Battelle, Llc High energy density aluminum battery
KR102014983B1 (ko) * 2011-11-18 2019-08-28 삼성전자주식회사 양극 및 이를 채용한 리튬 전지
JP6188729B2 (ja) 2012-02-16 2017-08-30 スリーエム イノベイティブ プロパティズ カンパニー 電気化学マグネシウム電池
US9177721B2 (en) 2012-03-14 2015-11-03 Rutgers, The State University Of New Jersey Electrochemical devices and methods of fabrication
EP2828919B1 (en) * 2012-03-20 2017-05-24 Pellion Technologies, Inc. Non-aqueous electrolyte for high voltage rechargeable magnesium batteries
US9240612B2 (en) * 2012-03-29 2016-01-19 Pellion Technologies, Inc. Layered materials with improved magnesium intercalation for rechargeable magnesium ion cells
US8673493B2 (en) * 2012-05-29 2014-03-18 Toyota Motor Engineering & Manufacturing North America, Inc. Indium-tin binary anodes for rechargeable magnesium-ion batteries
US8647770B2 (en) * 2012-05-30 2014-02-11 Toyota Motor Engineering & Manufacturing North America, Inc. Bismuth-tin binary anodes for rechargeable magnesium-ion batteries
KR101948549B1 (ko) * 2012-06-22 2019-02-15 에스케이이노베이션 주식회사 이차전지용 양극 활물질
KR101460641B1 (ko) 2012-07-19 2014-11-20 전자부품연구원 마그네슘 이차전지용 양극활물질 및 이의 제조방법
JPWO2014017461A1 (ja) * 2012-07-25 2016-07-11 国立大学法人京都大学 マグネシウム化合物、その製造方法、正極活物質、正極、及びマグネシウムイオン二次電池
US9246170B2 (en) * 2013-03-27 2016-01-26 Toyota Motor Engineering & Manufacturing North America, Inc. MgMn2O4 with a crystal structure analogue to CaFe2O4, CaMn2O4, or CaTi2O4 as rechargeable magnesium battery cathode
US20140302354A1 (en) * 2013-04-08 2014-10-09 Battelle Memorial Institute Electrodes for Magnesium Energy Storage Devices
KR101645406B1 (ko) * 2013-07-29 2016-08-04 전자부품연구원 Nasicon 구조 바나듐 인산화물의 마그네슘 이차전지용 양극 재료
US9887419B2 (en) 2013-08-26 2018-02-06 Samsung Electronics Co., Ltd. Active material, method of preparing the active material electrode including the active material, and secondary battery including the electrode
US10044038B2 (en) * 2013-09-03 2018-08-07 Ut-Battelle, Llc Nitride- and oxide-modified electrode compositions and their methods of making
KR102156318B1 (ko) 2013-09-23 2020-09-16 삼성전자주식회사 양극활물질, 및 이를 포함하는 양극 및 마그네슘이차전지
KR102144996B1 (ko) 2013-09-30 2020-08-18 삼성전자주식회사 양극활물질, 및 이를 포함하는 양극 및 나트륨이차전지
CN104577088A (zh) * 2013-10-16 2015-04-29 中国科学院物理研究所 二次电池电极材料钼酸锂
US9461306B2 (en) * 2013-11-13 2016-10-04 Toyota Motor Engineering & Manufacturing North America, Inc. Vanadium oxide based amorphous cathode materials for rechargeable magnesium battery
KR102156319B1 (ko) 2013-11-21 2020-09-15 삼성전자주식회사 전해액, 이의 제조방법 및 상기 전해액을 포함하는 마그네슘 전지
KR102763310B1 (ko) * 2014-01-28 2025-02-07 춘셍 왕 다전자 수계 전지
JP5966028B2 (ja) * 2014-03-19 2016-08-10 本田技研工業株式会社 非水電解質二次電池用正極材料
US10069138B2 (en) 2014-04-24 2018-09-04 Toyota Motor Engineering & Manufacturing North America, Inc. Vanadium oxysulfide based cathode materials for rechargeable battery
US9711793B2 (en) 2014-04-24 2017-07-18 Toyota Motor Engineering & Manufacturing North America, Inc. Vanadium oxysulfide based cathode materials for rechargeable battery
KR102188078B1 (ko) 2014-05-13 2020-12-07 삼성전자주식회사 비리튬 이차전지용 음극 활물질, 그 제조방법, 이를 포함하는 비리튬 이차전지용 음극 및 비리튬 이차전지
CN104143623B (zh) * 2014-07-09 2017-01-04 宁波职业技术学院 一种镁离子电池正极材料及其制备方法
CN104108696B (zh) * 2014-07-14 2016-02-03 中国科学院青海盐湖研究所 一种Mg0．5+y(Ni0．5yV0．5yTi1-y)2(PO4)3镁电池正极材料及其制备方法
CN104124433B (zh) * 2014-07-14 2016-06-15 中国科学院青海盐湖研究所 一种Mg0．5+y(Co0．5yV0．5yTi1-y)2(PO4)3镁电池正极材料及其制备方法
CN104108695B (zh) * 2014-07-14 2016-06-15 中国科学院青海盐湖研究所 一种Mg0．5+y(Ni0．5yV0．5yTi1-y)2(PO4)3镁电池正极材料及其制备方法
CN104118855B (zh) * 2014-07-14 2016-03-02 中国科学院青海盐湖研究所 一种Mg0.5+y(Co0.5yV0.5yTi1-y)2(PO4)3镁电池正极材料及其制备方法
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