KR20130119333A - 마그네슘 배터리를 위한 전극 물질 - Google Patents

마그네슘 배터리를 위한 전극 물질 Download PDF

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KR20130119333A
KR20130119333A KR1020127033606A KR20127033606A KR20130119333A KR 20130119333 A KR20130119333 A KR 20130119333A KR 1020127033606 A KR1020127033606 A KR 1020127033606A KR 20127033606 A KR20127033606 A KR 20127033606A KR 20130119333 A KR20130119333 A KR 20130119333A
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compound
magnesium
spinel
mixtures
group
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로버트 엘리스 도
티모시 케이트 뮐러
거브랜드 세더
제레미 바커
크리스틴 아슬라우그 퍼쓴
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펠리온 테크놀로지스 인크.
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H01M4/46—Alloys based on magnesium or aluminium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00—Phosphorus; Compounds thereof
    • C01B25/16—Oxyacids of phosphorus; Salts thereof
    • C01B25/26—Phosphates
    • C01B25/37—Phosphates of heavy metals
    • C01B25/372—Phosphates of heavy metals of titanium, vanadium, zirconium, niobium, hafnium or tantalum
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00—Phosphorus; Compounds thereof
    • C01B25/16—Oxyacids of phosphorus; Salts thereof
    • C01B25/26—Phosphates
    • C01B25/38—Condensed phosphates
    • C01B25/42—Pyrophosphates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00—Phosphorus; Compounds thereof
    • C01B25/16—Oxyacids of phosphorus; Salts thereof
    • C01B25/26—Phosphates
    • C01B25/45—Phosphates containing plural metal, or metal and ammonium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G31/00—Compounds of vanadium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G37/00—Compounds of chromium
    • C01G37/006—Compounds containing chromium, with or without oxygen or hydrogen, and containing two or more other elements
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G45/00—Compounds of manganese
    • C01G45/12—Complex oxides containing manganese and at least one other metal element
    • C01G45/1221—Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof
    • C01G45/1235—Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof of the type (Mn2O4)2-, e.g. Li2Mn2O4 or Li2(MxMn2-x)O4
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G49/00—Compounds of iron
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/40—Complex oxides containing nickel and at least one other metal element
    • C01G53/66—Complex oxides containing nickel and at least one other metal element containing alkaline earth metals, e.g. SrNiO3 or SrNiO2
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/054—Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
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    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • H—ELECTRICITY
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    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/581—Chalcogenides or intercalation compounds thereof
    • H01M4/5815—Sulfides
    • H—ELECTRICITY
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    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
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    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
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    • C01P2002/20—Two-dimensional structures
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    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/30—Three-dimensional structures
    • C01P2002/32—Three-dimensional structures spinel-type (AB2O4)
    • C—CHEMISTRY; METALLURGY
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    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
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    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/136—Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Secondary Cells (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
KR1020127033606A 2010-05-25 2011-05-25 마그네슘 배터리를 위한 전극 물질 Ceased KR20130119333A (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US34806810P 2010-05-25 2010-05-25
US61/348,068 2010-05-25
PCT/US2011/037951 WO2011150093A1 (en) 2010-05-25 2011-05-25 Electrode materials for magnesium batteries

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KR20130119333A true KR20130119333A (ko) 2013-10-31

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US (2) US20120219856A1 (enExample)
EP (1) EP2577780B1 (enExample)
JP (1) JP2013533577A (enExample)
KR (1) KR20130119333A (enExample)
CN (1) CN103155235A (enExample)
CA (1) CA2799209A1 (enExample)
WO (1) WO2011150093A1 (enExample)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20170003308A (ko) * 2015-06-30 2017-01-09 주식회사 엘지화학 마그네슘 전지용 전극 활물질, 이의 제조 방법, 이를 포함하는 전극, 및 상기 전극을 포함하는 마그네슘 전지
KR20170003310A (ko) * 2015-06-30 2017-01-09 주식회사 엘지화학 마그네슘 전지용 전극 활물질, 이의 제조 방법, 이를 포함하는 전극, 및 상기 전극을 포함하는 마그네슘 전지
KR20170003306A (ko) * 2015-06-30 2017-01-09 주식회사 엘지화학 마그네슘 전지용 전극 활물질, 이의 제조 방법, 이를 포함하는 전극, 및 상기 전극을 포함하는 마그네슘 전지
KR20210002416A (ko) * 2019-04-11 2021-01-08 광주과학기술원 마그네슘 이온 이차전지용 양극 활물질 및 상기 양극을 포함하는 이차전지

Families Citing this family (81)

* Cited by examiner, † Cited by third party
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US9466853B2 (en) 2010-09-30 2016-10-11 Ut-Battelle, Llc High energy density aluminum battery
KR102014983B1 (ko) * 2011-11-18 2019-08-28 삼성전자주식회사 양극 및 이를 채용한 리튬 전지
WO2013122783A1 (en) 2012-02-16 2013-08-22 3M Innovative Properties Company Electrochemical magnesium cell and method of making same
US9177721B2 (en) 2012-03-14 2015-11-03 Rutgers, The State University Of New Jersey Electrochemical devices and methods of fabrication
US9293790B2 (en) * 2012-03-20 2016-03-22 Pellion Technologies, Inc. High voltage rechargeable magnesium batteries having a non-aqueous electrolyte
US9172111B2 (en) * 2012-03-29 2015-10-27 Pellion Technologies, Inc. Layered materials with improved magnesium intercalation for rechargeable magnesium ion cells
US8673493B2 (en) * 2012-05-29 2014-03-18 Toyota Motor Engineering & Manufacturing North America, Inc. Indium-tin binary anodes for rechargeable magnesium-ion batteries
US8647770B2 (en) * 2012-05-30 2014-02-11 Toyota Motor Engineering & Manufacturing North America, Inc. Bismuth-tin binary anodes for rechargeable magnesium-ion batteries
KR101948549B1 (ko) * 2012-06-22 2019-02-15 에스케이이노베이션 주식회사 이차전지용 양극 활물질
KR101460641B1 (ko) 2012-07-19 2014-11-20 전자부품연구원 마그네슘 이차전지용 양극활물질 및 이의 제조방법
WO2014017461A1 (ja) * 2012-07-25 2014-01-30 国立大学法人京都大学 マグネシウム化合物、その製造方法、正極活物質、正極、及びマグネシウムイオン二次電池
JP6241996B2 (ja) * 2012-12-26 2017-12-06 昭和電工株式会社 マグネシウムイオン二次電池用正極活物質及びその製造方法並びにマグネシウムイオン二次電池
US9246170B2 (en) 2013-03-27 2016-01-26 Toyota Motor Engineering & Manufacturing North America, Inc. MgMn2O4 with a crystal structure analogue to CaFe2O4, CaMn2O4, or CaTi2O4 as rechargeable magnesium battery cathode
US20140302354A1 (en) * 2013-04-08 2014-10-09 Battelle Memorial Institute Electrodes for Magnesium Energy Storage Devices
KR101645406B1 (ko) * 2013-07-29 2016-08-04 전자부품연구원 Nasicon 구조 바나듐 인산화물의 마그네슘 이차전지용 양극 재료
US9887419B2 (en) 2013-08-26 2018-02-06 Samsung Electronics Co., Ltd. Active material, method of preparing the active material electrode including the active material, and secondary battery including the electrode
US10044038B2 (en) 2013-09-03 2018-08-07 Ut-Battelle, Llc Nitride- and oxide-modified electrode compositions and their methods of making
KR102156318B1 (ko) 2013-09-23 2020-09-16 삼성전자주식회사 양극활물질, 및 이를 포함하는 양극 및 마그네슘이차전지
KR102144996B1 (ko) 2013-09-30 2020-08-18 삼성전자주식회사 양극활물질, 및 이를 포함하는 양극 및 나트륨이차전지
CN104577088A (zh) * 2013-10-16 2015-04-29 中国科学院物理研究所 二次电池电极材料钼酸锂
KR102196363B1 (ko) * 2013-10-29 2020-12-30 삼성전자주식회사 마그네슘 전지용 전극 활물질, 이를 포함하는 전극 및 마그네슘 전지, 및 마그네슘 전지용 전극 활물질의 제조방법
US9461306B2 (en) * 2013-11-13 2016-10-04 Toyota Motor Engineering & Manufacturing North America, Inc. Vanadium oxide based amorphous cathode materials for rechargeable magnesium battery
KR102156319B1 (ko) 2013-11-21 2020-09-15 삼성전자주식회사 전해액, 이의 제조방법 및 상기 전해액을 포함하는 마그네슘 전지
KR102395787B1 (ko) * 2014-01-28 2022-05-09 춘셍 왕 다전자 수계 전지
JP6081393B2 (ja) * 2014-02-18 2017-02-15 本田技研工業株式会社 正極活物質
JP5966028B2 (ja) * 2014-03-19 2016-08-10 本田技研工業株式会社 非水電解質二次電池用正極材料
US9711793B2 (en) 2014-04-24 2017-07-18 Toyota Motor Engineering & Manufacturing North America, Inc. Vanadium oxysulfide based cathode materials for rechargeable battery
US10069138B2 (en) 2014-04-24 2018-09-04 Toyota Motor Engineering & Manufacturing North America, Inc. Vanadium oxysulfide based cathode materials for rechargeable battery
KR102188078B1 (ko) 2014-05-13 2020-12-07 삼성전자주식회사 비리튬 이차전지용 음극 활물질, 그 제조방법, 이를 포함하는 비리튬 이차전지용 음극 및 비리튬 이차전지
CN104143623B (zh) * 2014-07-09 2017-01-04 宁波职业技术学院 一种镁离子电池正极材料及其制备方法
CN104118855B (zh) * 2014-07-14 2016-03-02 中国科学院青海盐湖研究所 一种Mg0.5+y(Co0.5yV0.5yTi1-y)2(PO4)3镁电池正极材料及其制备方法
CN104108696B (zh) * 2014-07-14 2016-02-03 中国科学院青海盐湖研究所 一种Mg0．5+y(Ni0．5yV0．5yTi1-y)2(PO4)3镁电池正极材料及其制备方法
CN104124432B (zh) * 2014-07-14 2016-08-24 中国科学院青海盐湖研究所 一种Mg0.5+y(Co0.5yV0.5yTi1-y)2(PO4)3镁电池正极材料及其制备方法
CN104118856B (zh) * 2014-07-14 2016-01-06 中国科学院青海盐湖研究所 一种Mg0.5+y(Co0.5yV0.5yTi1-y)2(PO4)3镁电池正极材料及其制备方法
CN104124433B (zh) * 2014-07-14 2016-06-15 中国科学院青海盐湖研究所 一种Mg0．5+y(Co0．5yV0．5yTi1-y)2(PO4)3镁电池正极材料及其制备方法
CN104112859B (zh) * 2014-07-14 2016-05-18 中国科学院青海盐湖研究所 一种Mg0．5+y(Ni0．5yV0．5yTi1-y)2(PO4)3镁电池正极材料及其制备方法
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