JP2010515838A - セルロース基材用増白剤を含む洗濯ケア組成物 - Google Patents
セルロース基材用増白剤を含む洗濯ケア組成物 Download PDFInfo
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- JP2010515838A JP2010515838A JP2009545246A JP2009545246A JP2010515838A JP 2010515838 A JP2010515838 A JP 2010515838A JP 2009545246 A JP2009545246 A JP 2009545246A JP 2009545246 A JP2009545246 A JP 2009545246A JP 2010515838 A JP2010515838 A JP 2010515838A
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- FBDWCTWJJMORIU-UHFFFAOYSA-N magnesium;hexahydrate Chemical compound O.O.O.O.O.O.[Mg] FBDWCTWJJMORIU-UHFFFAOYSA-N 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 1
- 150000004682 monohydrates Chemical class 0.000 description 1
- KSKTVNNRMXUMIY-UHFFFAOYSA-N n,n-dimethylethanamine;hydrochloride Chemical compound Cl.CCN(C)C KSKTVNNRMXUMIY-UHFFFAOYSA-N 0.000 description 1
- FJDUDHYHRVPMJZ-UHFFFAOYSA-N nonan-1-amine Chemical class CCCCCCCCCN FJDUDHYHRVPMJZ-UHFFFAOYSA-N 0.000 description 1
- 125000002801 octanoyl group Chemical group C(CCCCCCC)(=O)* 0.000 description 1
- JPMIIZHYYWMHDT-UHFFFAOYSA-N octhilinone Chemical compound CCCCCCCCN1SC=CC1=O JPMIIZHYYWMHDT-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 239000003605 opacifier Substances 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 150000004967 organic peroxy acids Chemical class 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- 239000013618 particulate matter Substances 0.000 description 1
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- 229960003330 pentetic acid Drugs 0.000 description 1
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- 125000000864 peroxy group Chemical group O(O*)* 0.000 description 1
- CBSISAXGAQOTIL-UHFFFAOYSA-N phenyl 6-(decanoylamino)hexanoate Chemical compound CCCCCCCCCC(=O)NCCCCCC(=O)OC1=CC=CC=C1 CBSISAXGAQOTIL-UHFFFAOYSA-N 0.000 description 1
- ZRXJXIVOMZDPKQ-UHFFFAOYSA-N phenyl 6-(nonanoylamino)hexanoate Chemical compound CCCCCCCCC(=O)NCCCCCC(=O)OC1=CC=CC=C1 ZRXJXIVOMZDPKQ-UHFFFAOYSA-N 0.000 description 1
- ATDMVKHUQFOKCV-UHFFFAOYSA-N phenyl 6-(octanoylamino)hexanoate Chemical compound CCCCCCCC(=O)NCCCCCC(=O)OC1=CC=CC=C1 ATDMVKHUQFOKCV-UHFFFAOYSA-N 0.000 description 1
- FCJSHPDYVMKCHI-UHFFFAOYSA-N phenyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OC1=CC=CC=C1 FCJSHPDYVMKCHI-UHFFFAOYSA-N 0.000 description 1
- SIENSFABYFDZCL-UHFFFAOYSA-N phenyl decanoate Chemical compound CCCCCCCCCC(=O)OC1=CC=CC=C1 SIENSFABYFDZCL-UHFFFAOYSA-N 0.000 description 1
- ZPORCTAUIXXZAI-UHFFFAOYSA-N phenyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OC1=CC=CC=C1 ZPORCTAUIXXZAI-UHFFFAOYSA-N 0.000 description 1
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
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- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 229920001592 potato starch Polymers 0.000 description 1
- 150000004023 quaternary phosphonium compounds Chemical class 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 239000004627 regenerated cellulose Substances 0.000 description 1
- 230000015227 regulation of liquid surface tension Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000013557 residual solvent Substances 0.000 description 1
- 239000008165 rice bran oil Substances 0.000 description 1
- 235000005713 safflower oil Nutrition 0.000 description 1
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- 238000005464 sample preparation method Methods 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 229910021647 smectite Inorganic materials 0.000 description 1
- PFUVRDFDKPNGAV-UHFFFAOYSA-N sodium peroxide Chemical compound [Na+].[Na+].[O-][O-] PFUVRDFDKPNGAV-UHFFFAOYSA-N 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- UXIDHQPACNSJJP-UHFFFAOYSA-M sodium;2-[2-[2-[bis(carboxymethyl)amino]ethyl-(carboxymethyl)amino]ethyl-(carboxymethyl)amino]acetate Chemical compound [Na+].OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC([O-])=O UXIDHQPACNSJJP-UHFFFAOYSA-M 0.000 description 1
- HLWRUJAIJJEZDL-UHFFFAOYSA-M sodium;2-[2-[bis(carboxymethyl)amino]ethyl-(carboxymethyl)amino]acetate Chemical compound [Na+].OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC([O-])=O HLWRUJAIJJEZDL-UHFFFAOYSA-M 0.000 description 1
- MAZNCWGRSPCNGO-UHFFFAOYSA-M sodium;4-[6-(nonanoylamino)hexanoyloxy]benzenesulfonate Chemical compound [Na+].CCCCCCCCC(=O)NCCCCCC(=O)OC1=CC=C(S([O-])(=O)=O)C=C1 MAZNCWGRSPCNGO-UHFFFAOYSA-M 0.000 description 1
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- 230000003595 spectral effect Effects 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 125000005156 substituted alkylene group Chemical group 0.000 description 1
- 125000005650 substituted phenylene group Chemical group 0.000 description 1
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- 238000005670 sulfation reaction Methods 0.000 description 1
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 1
- DIORMHZUUKOISG-UHFFFAOYSA-N sulfoformic acid Chemical compound OC(=O)S(O)(=O)=O DIORMHZUUKOISG-UHFFFAOYSA-N 0.000 description 1
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- 239000000375 suspending agent Substances 0.000 description 1
- 239000003784 tall oil Substances 0.000 description 1
- 108010038851 tannase Proteins 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- 150000004026 tertiary sulfonium compounds Chemical class 0.000 description 1
- 150000004685 tetrahydrates Chemical class 0.000 description 1
- ILJSQTXMGCGYMG-UHFFFAOYSA-N triacetic acid Chemical compound CC(=O)CC(=O)CC(O)=O ILJSQTXMGCGYMG-UHFFFAOYSA-N 0.000 description 1
- 125000004417 unsaturated alkyl group Chemical group 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- AQLJVWUFPCUVLO-UHFFFAOYSA-N urea hydrogen peroxide Chemical compound OO.NC(N)=O AQLJVWUFPCUVLO-UHFFFAOYSA-N 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
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Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
- C11D3/42—Brightening agents ; Blueing agents
Abstract
Description
a)[(CH2CR’HO)x(CH2CR”HO)yH]
(式中、R’はH、CH3、CH2O(CH2CH2O)zH及びこれらの混合物からなる群から選択され、R”はH、CH2O(CH2CH2O)zH及びこれらの混合物からなる群から選択され、x+y≦5であり、y≧1であり、z=0〜5である)、
b)R1=アルキル、アリール又はアリールアルキル、かつR2=[(CH2CR’HO)x(CH2CR”HO)yH]
(式中、R’はH、CH3、CH2O(CH2CH2O)zH及びこれらの混合物からなる群から選択され、R”はH、CH2O(CH2CH2O)zH及びこれらの混合物からなる群から選択され、x+y≦10であり、y≧1であり、z=0〜5である)、
c)R1=[CH2CH2(OR3)CH2OR4]、かつR2=[CH2CH2(OR3)CH2OR4]
(式中、R3はH、(CH2CH2O)zH及びこれらの混合物からなる群から選択され、z=0〜10であり、
R4は(C1〜C16)アルキル、アリール基及びこれらの混合物からなる群から選択される)並びに、
d)R1及びR2はスチレンオキシド、グリシジルメチルエーテル、イソブチルグリシジルエーテル、イソプロピルグリシジルエーテル、t−ブチルグリシジルエーテル、2−エチルヘキシルグリシジルエーテル及びグリシジルヘキサデシルエーテルのアミノ付加生成物、から独立して選択することができ、さらに、1〜10個のアルキレンオキシド単位を付加するもの、から独立して選択することができる。
δ2=δd 2+δp 2+δh 2。(1)
に従う分散力(d)、分子双極子力(p)及び水素結合力(h)の組み合わせであるという事実から引き出されている。
ジクロロ−5,12−ジメチル−1,5,8,12−テトラアザビシクロ[6.6.2]ヘキサデカンマンガン(II)
ジクロロ−5,12−ジエチル−1,5,8,12−テトラアザビシクロ[6.6.2]ヘキサデカンマンガン(II)
ジアクオ−5,12−ジメチル−1,5,8,12−テトラアザビシクロ[6.6.2]ヘキサデカンマンガン(II)
ヘキサフルオロホスフェート
ジアクオ−5,12−ジエチル−1,5,8,12−テトラアザビシクロ[6.6.2]ヘキサデカンマンガン(II)ヘキサフルオロホスフェート
アクオ−ヒドロキシ−5,12−ジメチル−1,5,8,12−テトラアザビシクロ[6.6.2]ヘキサデカン
マンガン(III)ヘキサフルオロホスフェート
ジアクオ−5,12−ジメチル−1,5,8,12−テトラアザビシクロ[6.6.2]ヘキサデカンマンガン(II)
テトラフルオロボレート
ジクロロ−5,12−ジメチル−1,5,8,12−テトラアザビシクロ[6.6.2]ヘキサデカン
マンガン(III)ヘキサフルオロホスフェート
ジクロロ−5,12−ジエチル−1,5,8,12−テトラアザビシクロ[6.6.2]ヘキサデカンマンガン(III)
ヘキサフルオロホスフェート
ジクロロ−5,12−ジ−n−ブチル−1,5,8,12−テトラアザビシクロ[6.6.2]ヘキサデカン
マンガン(II)
ジクロロ−5,12−ジベンジル−1,5,8,12−テトラアザビシクロ[6.6.2]ヘキサデカンマンガン(II)
ジクロロ−5−n−ブチル−12−メチル−1,5,8,12−テトラアザ−ビシクロ[6.6.2]ヘキサデカン
マンガン(II)
ジクロロ−5−n−オクチル−12−メチル−1,5,8,12−テトラアザ−ビシクロ[6.6.2]ヘキサデカン
マンガン(II)
ジクロロ−5−n−ブチル−12−メチル−1,5,8,12−テトラアザ−ビシクロ[6.6.2]ヘキサデカン
マンガン(II)
のいずれかにより非限定的に明示される。
(i)ペルオキシ安息香酸及び環置換ペルオキシ安息香酸、例えば、ペルオキシ−a−ナフトエ酸、モノペルオキシフタル酸(マグネシウム塩六水和物)及びo−カルボキシベンズアミドペルオキシヘキサノン酸(ナトリウム塩)、
(ii)脂肪族、置換脂肪族及びアリールアルキルモノペルオキシ酸、例えば、ペルオキシラウリン酸、ペルオキシステアリン酸、N−ノナノイルアミノペルオキシカプロン酸(NAPCA)、N,N−(3−オクチルスクシノイル)アミノペルオキシカプロン酸(SAPA)及びN,N−フタロイルアミノペルオキシカプロン酸(PAP)、
(iii)アミドペルオキシ酸、例えば、ペルオキシコハク酸(NAPSA)又はペルオキシアジピン酸(NAPAA)のいずれかのモノノニルアミドのようなアルキル及びアリールペルオキシ酸、が挙げられる。
(i)1,12−ジペルオキシドデカン二酸、
(ii)1,9−ジペルオキシアゼライン酸、
(iii)ジペルオキシブラシル酸、ジペルオキシセバシン酸及びジペルオキシイソフタル酸、
(iv)2−デシルジペルオキシブタン−1,4−二酸、
(v)4,4’−スルホニルビスペルオキシ安息香酸次のようなアルキルジペルオキシ酸及びアリールジペルオキシ酸、が挙げられる。
別の具体的な実施形態では、本発明の増白剤は、布地ケア組成物に包含されてもよい。布地ケア組成物は、少なくとも1種の増白剤及びすすぎ時添加布地柔軟化組成物(「RAFS」、すすぎ時添加コンディショニング組成物としても既知)からなってもよい。典型的なすすぎ時添加柔軟化組成物の例は、米国特許仮出願第60/687582号(2004年10月8日出願)に見出すことができる。本発明のすすぎ時添加布地柔軟化組成物は(a)布地柔軟化活性剤及び(b)チアゾリウム染料を含んでもよい。すすぎ時添加布地柔軟化組成物は、約1重量%〜約90重量%のFSA、より好ましくは約5重量%〜約50重量%のFSAを含んでもよい。増白剤は、すすぎ時添加布地柔軟化組成物中に約0.5ppb〜約50ppm、より好ましくは約0.5ppm〜約30ppmの量で存在してもよい。
{R4−m−N+−[(CH2)n−Y−R1]m}X−
を含む化合物を包含し、式中、各R置換基は水素、短鎖C1〜C6、好ましくはC1〜C3アルキル又はヒドロキシアルキル基、例えば、メチル(最も好ましい)、エチル、プロピル、ヒドロキシエチルなど、ポリ(C2〜3アルコキシ)、好ましくはポリエトキシ、基、ベンジル又はこれらの混合物のいずれかであり、各mは2又は3であり、各nは1〜約4、好ましくは2であり、各Yは−O−(O)C−、−C(O)−O−、−NR−C(O)−又は−C(O)−NR−であり、各Yは同じであっても又は異なってもよく、各R1中の炭素の合計(Yが−O−(O)C−又は−NR−C(O)−のときはプラス1)は、C12〜C22、好ましくはC14〜C20であり、各R1はヒドロカルビル又は置換ヒドロカルビル基であり、R1は、不飽和又は飽和及び分枝鎖又は直鎖であってよく、好ましくは直鎖であり、各R1は同じであっても又は異なってもよく、好ましくはこれらは同じであり、X−はいずれかの柔軟剤適合性アニオン、好ましくは塩化物イオン、臭化物イオン、メチル硫酸イオン、エチル硫酸イオン、硫酸イオン、リン酸イオン又は硝酸イオンであり、より好ましくは塩化物イオン又はメチル硫酸イオンとすることができ、より好ましくは塩化物イオン又はメチル硫酸イオンである。好ましいDQA化合物は、典型的には、MDEA(メチルジエタノールアミン)及びTEA(トリエタノールアミン)などのアルカノールアミン類を脂肪酸と反応させることによって製造される。典型的にこのような反応から得られるいくつかの材料には、N,N−ジ(アシル−オキシエチル)−N,N−ジメチルアンモニウムクロリド又はN,N−ジ(アシル−オキシエチル)−N,N−メチルヒドロキシエチルアンモニウムメチルサルフェートが挙げられ、アシル基は、動物性脂肪、不飽和及び多不飽和の脂肪酸、例えば、タロウ、硬化タロウ、オレイン酸及び/又は部分硬化脂肪酸から誘導され、植物油類及び/又は部分硬化植物油、例えば、キャノーラ油、ベニバナ油、ピーナッツ油、ヒマワリ油、コーン油、大豆油、トール油、米糠油、パーム油などからも誘導される。
[R4−m−N(+)−R1 m]A−
を含むDTTMACとして認定された化合物を含み、式中、各mは2又は3であり、各R1はC6〜C22、好ましくはC14〜C20の(しかし、約C12未満であるのは1つ以下であり、他は少なくとも約16である)ヒドロカルビル又は置換ヒドロカルビル置換基、好ましくはC10〜C20アルキル又はアルケニル(「アルキレン」と称されることもある、多不飽和アルキルを包含する不飽和アルキル)、最も好ましくはC12〜C18アルキル又はアルケニルで、分枝又は非分枝である。1つの実施形態では、FSAのヨウ素価(IV)は約1〜70であり、各RはH又は短鎖C1〜C6、好ましくはC1〜C3アルキル又はヒドロキシアルキル基、例えばメチル(最も好ましい)、エチル、プロピル及びヒドロキシエチルなど、ベンジル又は(R2O)2〜4Hであり、各R2はC1〜6アルキレン基であり、A−は柔軟剤適合性アニオン、好ましくはクロライド、ブロマイド、メチルサルフェート、エチルサルフェート、サルフェート、ホスフェート又はニトレートであり、より好ましくはクロライド又はメチルサルフェートである。
本発明の目的には必須ではないが、以下に例示される洗濯ケア成分の非限定的なリストは、洗濯ケア組成物における使用に好適であり、例えば、性能を補助若しくは向上させるために、洗浄する基材の処理のために又は香料、着色剤及び染料などを用いる場合のように組成物の審美性を改変するために、本発明の特定の実施形態に望ましくは組み込んでもよい。このような成分がいずれかの特定の実施形態に関して先に列挙された成分に追加されることが理解される。このような補助剤の総量は、洗濯ケア組成物の約0.1重量%〜約50重量%又は更には約1重量%〜約30重量%の範囲であってよい。
A.試料調製
3グラムの粉末状洗濯洗剤(AATCC粉末洗濯洗剤)及び500mLの室温の水を含有する溶液に0.5グラムの増白剤(セルロース基材の重量に基づいて0.1重量%)を加えることにより、各試料を調製する。等量の色単位を保障するために吸光度について各着色剤荷重を補正する。次に、配合物を50グラムのセルロース粉末(アルドリッチ(Aldrich)から入手可能)と組み合わせて、この混合物を10分間にわたって撹拌する。次に、混合物を濾過して、液体からセルロース粒子を分離し、セルロース粒子を風乾させておく。前述したように、グレタグ・マクベス・カラー・アイ(Gretag Macbeth Color Eye)7000A分光分析装置を使用して、色に関してセルロース粒子と液体の両方を測定する。
白色度指数(「WI」)は、色測定の3つの構成要素−色相、彩度及び明度−を包含すると共に標準白色値の指標にもなる式により計算される色の適性評価である。いくつかの白色度式を使用してセルロース系基材の白色度を測定することができる。2つの一般的な式が、ガンツ白色度指数(Ganz Whiteness Index)及びCIE白色度(CIE Whiteness)である。ガンツ白色度指数は次式により表わされる:WI=(D×Y)+(P×x)+(Q×y)+C、式中、Y、x及びyは比色分析値であり、D、P、Q及びCは、式パラメータである。CIE白色度は次式により表わされる:WI=Y−(800×x)−(1700×y)+813.7、式中、Y、x及びyは比色分析値である。更なる情報が、ロルフ・グリーサー(Rolf Griesser)(チバガイギー社(Ciba-Geigy Ltd))「白色度及び色味(Whiteness and Tint)」(1993年6月)という刊行物から入手できる。
マテリアル・スタジオ分子モデリング(Material Studio molecular modeling)ソフトウェア(アクセルリス社(Accelrys, Inc.)から入手可能)により、本発明の増白剤それぞれの平均的な構造を導出する。半経験的普遍力場(semi-empirical Universal forcefield)及び電荷平衡法(Qeq)電荷配置システムを使用するフォーサイト(Forcite)モジュールにより、各構造の形状を最適化する。平均N=N結合距離1.25オングストロームと対比して、ジアゾ着色剤のN=N結合は約1.270〜1.275オングストロームと計算される。これらの値は、ガウシアン(Gaussian)98ソフトウェアパッケージ及びB3LYP/6−311G法によりジフェニルジアゾ染料について計算されている、ジャン−ナ リュウ(Liu, Jun-na)ら(ジャン−ナ リュウ(Liu, Jun-na)、ジ−ロン チェン(Chen, Zhi-rong)及びシェン−フェン ユアン(Yuan, Shen-feng)「浙江大学学報科学版(Journal of Zhejiang University Science)」(6B(6)、2005年、584〜589頁)により報告されているもの、即ち、約1.3オングストロームよりもわずかに短い。
試験1:CIELabのb*値及びガンツ(Ganz)白色度指数により測定される白色度試験
CIELabのb*値及びガンツ(Ganz)白色度指数(「ガンツWI」)値を測定するために、実施例1〜17を白色度について試験する。試験結果を表3に示す。より低い(より負の)CIELabのb*値及び、より高いガンツWI値は、処理済セルロース粒子によって、より大きな青味付け又は増白効果が発現していることを示す。
CIELabのb*値及びハンセン溶解度パラメータの分散項値を測定するために、実施例1〜17を試験する。実施例1〜14がバイオレットチオフェン発色団を含有する一方で、実施例15〜17がトリフェニルメタン着色剤を含有することに留意されたい。ハンセン溶解度パラメータの分散項値のみを測定するために、実施例18〜25を試験する。
b_青味付け=0.9704×δd−22.468 (2)
試験3:ハンセン溶解度パラメータの分散項値に基づくCIELabのb*値の予測
ハンセン溶解度パラメータの分散項値に基づくモデルをトレーニングするために、実施例1〜10及び15〜17をまず使用する。1回のすすぎサイクル後に得られる分散項値を利用する下記の等式3を使用して、これらの実施例についてCIELabのb*値を計算する:
b_青味付け=1.0014×δd−23.02 (3)
この等式は等式2に非常に似ており、全ての実施例を使用して引き出されている。等式3により表されているモデルは、実施例11〜14についても有効である。等式3を使用して、実施例11〜14の分子のCIELabのb*値について、これらの分子を合成して増白効果を試験する前に予測を得る。等式3から得られるCIELabのb*予測値を、グレタグ・マクベス・カラー・アイ(Gretag Macbeth Color Eye)7000A分光分析装置から先に得られている測定値と比較する。b*測定色値とb*予測色値との間の百分率差も求める。
配合物1a〜1l:液体洗剤配合物
表6A及び6Bは、本発明の増白剤を少なくとも1種包含する液体洗剤配合物の例を提供する。表6A中に配合物1a〜1fとして及び、表6Bに1g〜1lとして、配合物を示す。
1 ジエチレントリアミン五酢酸、ナトリウム塩
2 ジエチレントリアミンペンタキス(pentakis)メチレンホスホン酸、ナトリウム塩
3 エチレンジアミン四酢酸、ナトリウム塩
4 配合色調節のために使用される非色味づけ染料(non-tinting dye)
5 ポリビニルアルコールフィルム中に単位用量としてパッケージされたコンパクト配合物
6 10を超える色相効率及び30〜85%の洗浄除去率を有するアルコキシル化アントラキノン着色剤
7 10を超える色相効率及び30〜85%の洗浄除去率を有するアルコキシル化チオフェン着色剤
8 10を超える色相効率及び30〜85%の洗浄除去率を有するアルコキシル化トリフェニルメタン着色剤
9 アキュゾール(Acusol)OP301
配合物2a〜2e:粒状洗剤配合物
表7は、本発明の増白剤を少なくとも1種包含する粉状洗剤配合物の例を提供する。表7中に配合物2a〜2eとして配合物を示す。
配合物3a〜3d:液体布地ケア組成物
表8は、本発明の増白剤を少なくとも1種包含する液体布地ケア組成物の例を提供する。表8中に配合物3a〜3dとして組成物を示す。
b 25%〜95%のアミロース及び0.02〜0.09の置換度を含有し、かつ50〜84の値を有する水流動性として測定される粘度を有する、普通のメイズスターチ又はポテトスターチをベースにするカチオンデンプン。
c 米国特許第5,574,179号、第15欄、1〜5行目に記載の式を有する、エチレンオキサイドとテレフタレートとのコポリマーであって、式中、各Xはメチルであり、各nは40であり、uは4であり、各R1は本質的に1,4−フェニレン部分であり、各R2は、本質的にエチレン、1,2−プロピレン部分又はそれらの混合物である。
d ジエチレントリアミン五酢酸。
e ローム・アンド・ハース社(Rohm and Haas Co.)から入手可能なカトン(KATHON)(登録商標)CG。
f DC2310の商標名でダウ・コーニング社(Dow Corning Corp.)から入手可能なシリコーン消泡剤。
g チバ・スペシャルティ・ケミカルズ(Ciba Specialty Chemicals)から入手可能な4,4’−ビス−(2−スルホスチリル)ビフェニル二ナトリウム。
h アクゾ・ノベル(Akzo Nobel)から入手可能なココメチルエトキシル化[15]アンモニウムクロライド。
a)[(CH2CR’HO)x(CH2CR”HO)yH]
(式中、R’は、H、CH3、CH2O(CH2CH2O)zH及びこれらの混合物からなる群から選択され、R”はH、CH2O(CH2CH2O)zH及びこれらの混合物からなる群から選択され、x+y≦5であり、y≧1であり、z=0〜5である)、
b)R1=アルキル、アリール又はアリールアルキル及び、R2=[(CH2CR’HO)x(CH2CR”HO)yH]
(式中、R’は、H、CH3、CH2O(CH2CH2O)zH及びこれらの混合物からなる群から選択され、R”はH、CH2O(CH2CH2O)zH及びこれらの混合物からなる群から選択され、x+y≦10であり、y≧1であり、z=0〜5である)、
c)R1=[CH2CH2(OR3)CH2OR4]及び、R2=[CH2CH2(OR3)CH2OR4]
(式中、R3は、H、(CH2CH2O)zH及びこれらの混合物からなる群から選択され、z=0〜10であり、
R4は、(C1〜C16)アルキル、アリール基及びこれらの混合物からなる群から選択される)並びに
d)R1及びR2は、スチレンオキシド、グリシジルメチルエーテル、イソブチルグリシジルエーテル、イソプロピルグリシジルエーテル、t−ブチルグリシジルエーテル、2−エチルヘキシルグリシジルエーテル及びグリシジルヘキサデシルエーテルのアミノ付加生成物、から独立して選択することができ、さらに、1〜10個のアルキレンオキシド単位を付加するもの、から独立して選択することができる。
Claims (16)
- 洗濯ケア成分及び増白剤を含む洗濯ケア組成物であって、前記増白剤が
(a)チオフェン着色剤を含む少なくとも1種の発色団成分と、
(b)少なくとも1種のポリマー性成分と、を含み、
前記増白剤が以下の構造:
a)[(CH2CR’HO)x(CH2CR”HO)yH]
(式中、R’はH、CH3、CH2O(CH2CH2O)zH及びこれらの混合物からなる群から選択され、R”はH、CH2O(CH2CH2O)zH及びこれらの混合物からなる群から選択され、x+y≦5であり、y≧1であり、z=0〜5である)、
b)R1=アルキル、アリール又はアリールアルキル、かつR2=[(CH2CR’HO)x(CH2CR”HO)yH]
(式中、R’はH、CH3、CH2O(CH2CH2O)zH及びこれらの混合物からなる群から選択され、R”はH、CH2O(CH2CH2O)zH及びこれらの混合物からなる群から選択され、x+y≦10であり、y≧1であり、z=0〜5である)、
c)R1=[CH2CH2(OR3)CH2OR4]、かつR2=[CH2CH2(OR3)CH2OR4]
(式中、R3はH、(CH2CH2O)zH及びこれらの混合物からなる群から選択され、z=0〜10であり、
R4は(C1〜C16)アルキル、アリール基及びこれらの混合物からなる群から選択される)並びに
d)R1及びR2はスチレンオキシド、グリシジルメチルエーテル、イソブチルグリシジルエーテル、イソプロピルグリシジルエーテル、t−ブチルグリシジルエーテル、2−エチルヘキシルグリシジルエーテル及びグリシジルヘキサデシルエーテルのアミノ付加生成物から独立して選択することができ、さらに、1〜10個のアルキレンオキシド単位を付加するもの、から独立して選択することができる、洗濯ケア組成物。 - 前記増白剤が2〜20個の繰返し単位を有するポリオキシアルキレン鎖を含む、請求項1に記載の洗濯ケア組成物。
- 前記増白剤が少なくとも2個のヒドロキシル基を含み、好ましくは前記少なくとも2個のヒドロキシル基が第一級ヒドロキシル部分である、請求項1又は2に記載の洗濯ケア組成物。
- 前記増白剤がアルコキシル化チオフェンポリマー性着色剤を含む、請求項1〜3のいずれか一項に記載の洗濯ケア組成物。
- 前記増白剤が17MPa0.5以下、好ましくは12〜17MPa0.5のハンセン溶解度パラメータの分散項値を有する、請求項1〜4のいずれか一項に記載の洗濯ケア組成物。
- 前記増白剤の発色団が水中で520ナノメートル〜640ナノメートルの吸光スペクトルを示す、請求項1〜4のいずれか一項に記載の洗濯ケア組成物。
- 前記増白剤の発色団が水中で400ナノメートル〜480ナノメートルの発光スペクトルを示す、請求項1〜4のいずれか一項に記載の洗濯ケア組成物。
- 洗濯ケア成分及び増白剤を含む洗濯ケア組成物であって、前記増白剤が
(a)チオフェン又はトリフェニルメタン着色剤を含む少なくとも1種の発色団成分と、
(b)少なくとも1種のポリマー性成分と、を含み、前記増白剤が17MPa0.5以下、好ましくは12〜17MPa0.5のハンセン溶解度パラメータの分散項値を有する、洗濯ケア組成物。 - 前記増白剤が2〜20個の繰返し単位を有するポリオキシアルキレン鎖を含む、請求項8に記載の洗濯ケア組成物。
- 前記増白剤が少なくとも2個のヒドロキシル基を含み、好ましくは前記少なくとも2個のヒドロキシル基が第一級ヒドロキシル部分である、請求項1〜9のいずれか一項に記載の洗濯ケア組成物。
- 前記増白剤がアルコキシル化トリフェニルメタンポリマー性着色剤を含む、請求項1〜10のいずれか一項に記載の洗濯ケア組成物。
- 前記増白剤がアルコキシル化チオフェンポリマー性着色剤を含む、請求項1〜11のいずれか一項に記載の洗濯ケア組成物。
- 前記増白剤の発色団が水中で520ナノメートル〜640ナノメートルの吸光スペクトルを示す、請求項8〜12のいずれか一項に記載の洗濯ケア組成物。
- 前記増白剤の発色団が水中で400ナノメートル〜480ナノメートルの発光スペクトルを示す、請求項8〜12のいずれか一項に記載の洗濯ケア組成物。
- 前記増白剤が2〜20個の繰返し単位、好ましくは4〜6個の繰返し単位を有するポリオキシアルキレン鎖を含む、請求項15に記載の洗濯ケア組成物。
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JP2015500888A (ja) * | 2011-06-03 | 2015-01-08 | ミリケン・アンド・カンパニーMilliken & Company | チオフェンアゾカルボキシレート色素、およびこれらを含有する洗濯ケア組成物 |
JP2015513576A (ja) * | 2012-02-13 | 2015-05-14 | ミリケン・アンド・カンパニーMilliken & Company | 染料を含有する洗濯ケア組成物 |
JP2016530392A (ja) * | 2013-09-18 | 2016-09-29 | ザ プロクター アンド ギャンブル カンパニー | チオフェンアゾカルボキシレート染料を含有する洗濯ケア組成物 |
JP2016536433A (ja) * | 2013-09-18 | 2016-11-24 | ザ プロクター アンド ギャンブル カンパニー | カルボキシレート染料を含む洗濯ケア組成物 |
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CN101583704B (zh) | 2013-05-15 |
ES2355763T3 (es) | 2011-03-30 |
EP2192169B1 (en) | 2012-05-09 |
ATE486927T1 (de) | 2010-11-15 |
DE602007010350D1 (de) | 2010-12-16 |
CN101583704A (zh) | 2009-11-18 |
EP2104729A1 (en) | 2009-09-30 |
PL2192169T3 (pl) | 2012-10-31 |
BRPI0720944A2 (pt) | 2013-03-26 |
CA2673239A1 (en) | 2008-07-24 |
ES2386873T3 (es) | 2012-09-04 |
EP2104729B1 (en) | 2010-11-03 |
WO2008087497A1 (en) | 2008-07-24 |
BRPI0720944B1 (pt) | 2017-05-30 |
JP5122583B2 (ja) | 2013-01-16 |
PL2104729T3 (pl) | 2011-04-29 |
ATE557080T1 (de) | 2012-05-15 |
EP2192169A1 (en) | 2010-06-02 |
MX2009007746A (es) | 2009-07-27 |
CA2673239C (en) | 2012-07-24 |
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