CA2673239A1 - Laundry care composition comprising a whitening agent having an azo-thiophene or triphenylmethane colorant moiety and a polyoxyalkylene moiety - Google Patents

Laundry care composition comprising a whitening agent having an azo-thiophene or triphenylmethane colorant moiety and a polyoxyalkylene moiety Download PDF

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Publication number
CA2673239A1
CA2673239A1 CA002673239A CA2673239A CA2673239A1 CA 2673239 A1 CA2673239 A1 CA 2673239A1 CA 002673239 A CA002673239 A CA 002673239A CA 2673239 A CA2673239 A CA 2673239A CA 2673239 A1 CA2673239 A1 CA 2673239A1
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CA
Canada
Prior art keywords
whitening agent
laundry care
care composition
nanometers
mixtures
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Granted
Application number
CA002673239A
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French (fr)
Other versions
CA2673239C (en
Inventor
Eugene Steven Sadlowski
Mark Robert Sivik
Michael David Cummings
Donna D'angelo Morrall
Kevin Lee Kott
Keith Homer Baker
Brian Joseph Loughnane
Michael A. Valenti
Laurent D. Kieken
Xiaoyong Michael Hong
Eduardo Torres
Dominick J. Valenti
Patrick D. Moore
Leonard J. Starks
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Procter and Gamble Co
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Individual
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Publication of CA2673239A1 publication Critical patent/CA2673239A1/en
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Publication of CA2673239C publication Critical patent/CA2673239C/en
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/40—Dyes ; Pigments
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/40—Dyes ; Pigments
    • C11D3/42—Brightening agents ; Blueing agents

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

This invention relates to laundry care compositions including but not limited to liquid and/or powder laundry detergent formulations and rinse added fabric softening (RAFS) compositions that comprise whitening agents for cellulosic substrates. The whitening agents are comprised of at least two components: at least one chromophore component and at least one polymeric component. Suitable chromophore components generally fluoresce blue, red, violet, or purple color when exposed to ultraviolet light, or they may absorb light to reflect these same shades. The whitening agents are further characterized by having a dispersion component value of the Hansen Solubility Parameter of less than or equal to about 17 MPaO.5.

Claims (16)

1. A laundry care composition comprising a laundry care ingredient and a whitening agent, said whitening agent comprising:
(a) at least one chromophore component that comprises a thiophene colorant, and (b) at least one polymeric component;
wherein the whitening agent is characterized by the following structure:
Wherein R1 and R2 can independently be selected from:
a) [(CH2CR'HO)x(CH2CR"HO)y H]
wherein R' is selected from the group consisting of H, CH3, CH2O(CH2CH2O)z H, and mixtures thereof; wherein R" is selected from the group consisting of H, CH2O(CH2CH2O)z H, and mixtures thereof; wherein x + y <= 5; wherein y >= 1; and wherein z = 0 to 5;
b) R1 = alkyl, aryl or aryl alkyl and R2 = [(CH2CR'HO)x(CH2CR"HO)y H]
wherein R' is selected from the group consisting of H, CH3, CH2O(CH2CH2O)z H, and mixtures thereof; wherein R" is selected from the group consisting of H, CH2O(CH2CH2O)z H, and mixtures thereof; wherein x + y <= 10; wherein y >= 1; and wherein z = 0 to 5;
c) R1 =[CH2CH2(OR3)CH2OR4] and R2 =[CH2CH2(O R3)CH2O R4]

wherein R3 is selected from the group consisting of H, (CH2CH2O)z H, and mixtures thereof; and wherein z = 0 to 10;
wherein R4 is selected from the group consisting of (C1-C16)alkyl , aryl groups, and mixtures thereof; and d) wherein R1 and R2 can independently be selected from the amino addition product of styrene oxide, glycidyl methyl ether, isobutyl glycidyl ether, isopropylglycidyl ether, t-butyl glycidyl ether, 2-ethylhexylgycidyl ether, and glycidylhexadecyl ether, followed by the addition of from 1 to 10 alkylene oxide units.
2. The laundry care composition of claim 1, wherein the whitening agent comprises a polyoxyalkylene chain having from 2 to 20 repeating units.
3. A laundry care composition according to any preceding claim, wherein the whitening agent comprises at least two hydroxyl groups, preferably said least two hydroxyl groups are primary hydroxyl moieties.
4. A laundry care composition according to any preceding claim, wherein the whitening agent comprises an alkoxylated thiophene polymeric colorant.
5. A laundry care composition according to any preceding claim, wherein the whitening agent possesses a dispersion component value of the Hansen Solubility Parameter of less than or equal to 17 MPa0.5, preferably from 12 to 17 MPa0.5.
6. The laundry care composition of any of claims 1 to 4, wherein the whitening agent's chromophore exhibits an absorbance spectrum in water of from 520 nanometers to nanometers.
7. The laundry care composition of any of claims 1 to 4, wherein the whitening agent's chromophore exhibits an emission spectrum in water of from 400 nanometers to 480 nanometers.
8. A laundry care composition comprising a laundry care ingredient and a whitening agent, said whitening agent comprising:

(a) at least one chromophore component that comprises a thiophene or triphenylmethane colorant, and (b) at least one polymeric component; wherein the whitening agent possesses a dispersion component value of the Hansen Solubility Parameter of less than or equal to 17 MPa0.5, preferably from 12 to 17 MPa0.5.
9. The laundry care composition of claim 8, wherein the whitening agent comprises a polyoxyalkylene chain having from 2 to 20 repeating units.
10. A laundry care composition according to any preceding claim, wherein the whitening agent comprises at least two hydroxyl groups, preferably said least two hydroxyl groups are primary hydroxyl moieties.
11. A laundry care composition according to any preceding claim, wherein the whitening agent comprises an alkoxylated triphenylmethane polymeric colorant.
12. A laundry care composition according to any preceding claim, wherein the whitening agent comprises an alkoxylated thiophene polymeric colorant.
13. A laundry care composition according to any of claims 8 to 12, wherein the whitening agent's chromophore exhibits an absorbance spectrum in water of from 520 nanometers to 640 nanometers.
14. A laundry care composition according to any of claims 8 to 12, wherein the whitening agent's chromophore exhibits an emission spectrum in water of from 400 nanometers to 480 nanometers.
15. A laundry care composition comprising a laundry care ingredient and a whitening agent, said whitening agent comprising:
(a) at least one chromophore component that comprises a thiophene colorant, and (b) at least one polymeric component;
wherein the whitening agent is characterized by the following structure:

wherein R' is selected from the group consisting of H, CH3, CH2O(CH2CH2O)z H, and mixtures thereof; wherein R" is selected from the group consisting of H, CH2O(CH2CH2O)z H, and mixtures thereof; wherein x + y <= 5; wherein y >= 1; and wherein z = 0 to 5.
16. The laundry care composition of claim 15, wherein the whitening agent comprises a polyoxyalkylene chain having from 2 to 20 repeating units, preferably from 4 to 6 repeating units.
CA2673239A 2007-01-19 2007-01-19 Laundry care composition comprising a whitening agent having an azo-thiophene or triphenylmethane colorant moiety and a polyoxyalkylene moiety Active CA2673239C (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/IB2007/050192 WO2008087497A1 (en) 2007-01-19 2007-01-19 Laundry care composition comprising a whitening agent for cellulosic substrates

Publications (2)

Publication Number Publication Date
CA2673239A1 true CA2673239A1 (en) 2008-07-24
CA2673239C CA2673239C (en) 2012-07-24

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CA2673239A Active CA2673239C (en) 2007-01-19 2007-01-19 Laundry care composition comprising a whitening agent having an azo-thiophene or triphenylmethane colorant moiety and a polyoxyalkylene moiety

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EP (2) EP2192169B1 (en)
JP (1) JP5122583B2 (en)
CN (1) CN101583704B (en)
AT (2) ATE486927T1 (en)
BR (1) BRPI0720944B1 (en)
CA (1) CA2673239C (en)
DE (1) DE602007010350D1 (en)
ES (2) ES2386873T3 (en)
MX (1) MX2009007746A (en)
PL (2) PL2104729T3 (en)
WO (1) WO2008087497A1 (en)

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