HU189663B - Compositions containing 8-oxy-quinoline derivatives for diminishing phytotoxicity of herbicides and process for producing 8-oxy-quinoline derivatives - Google Patents
Compositions containing 8-oxy-quinoline derivatives for diminishing phytotoxicity of herbicides and process for producing 8-oxy-quinoline derivatives Download PDFInfo
- Publication number
- HU189663B HU189663B HU83533A HU53383A HU189663B HU 189663 B HU189663 B HU 189663B HU 83533 A HU83533 A HU 83533A HU 53383 A HU53383 A HU 53383A HU 189663 B HU189663 B HU 189663B
- Authority
- HU
- Hungary
- Prior art keywords
- hydrogen
- formula
- alkyl
- herbicide
- group
- Prior art date
Links
- 239000004009 herbicide Substances 0.000 title claims description 91
- 239000000203 mixture Substances 0.000 title claims description 83
- MCJGNVYPOGVAJF-UHFFFAOYSA-N quinolin-8-ol Chemical class C1=CN=C2C(O)=CC=CC2=C1 MCJGNVYPOGVAJF-UHFFFAOYSA-N 0.000 title claims description 14
- 238000000034 method Methods 0.000 title claims description 8
- 231100000674 Phytotoxicity Toxicity 0.000 title 1
- 230000003467 diminishing effect Effects 0.000 title 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 45
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 23
- 150000002367 halogens Chemical class 0.000 claims abstract description 23
- 125000006273 (C1-C3) alkyl group Chemical group 0.000 claims abstract 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 81
- 239000001257 hydrogen Substances 0.000 claims description 81
- 230000002363 herbicidal effect Effects 0.000 claims description 79
- 239000000729 antidote Substances 0.000 claims description 71
- -1 methoxy, ethoxy, n-propoxy Chemical group 0.000 claims description 61
- 150000001875 compounds Chemical class 0.000 claims description 57
- 239000004480 active ingredient Substances 0.000 claims description 35
- 125000000217 alkyl group Chemical group 0.000 claims description 34
- 150000002431 hydrogen Chemical class 0.000 claims description 34
- 239000000460 chlorine Chemical group 0.000 claims description 22
- 229910052801 chlorine Inorganic materials 0.000 claims description 22
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 21
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 21
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical group [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 19
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 13
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical group BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 13
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 12
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 12
- 229910052794 bromium Inorganic materials 0.000 claims description 12
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 12
- 238000002360 preparation method Methods 0.000 claims description 11
- 239000002202 Polyethylene glycol Substances 0.000 claims description 10
- 229920001223 polyethylene glycol Polymers 0.000 claims description 10
- 239000005995 Aluminium silicate Substances 0.000 claims description 9
- 235000012211 aluminium silicate Nutrition 0.000 claims description 9
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical group II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 claims description 9
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 9
- 125000003545 alkoxy group Chemical group 0.000 claims description 8
- 239000004202 carbamide Substances 0.000 claims description 8
- 125000001309 chloro group Chemical group Cl* 0.000 claims description 8
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 8
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 claims description 8
- 150000003839 salts Chemical class 0.000 claims description 8
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 claims description 8
- WEVYAHXRMPXWCK-UHFFFAOYSA-N acetonitrile Substances CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 claims description 7
- 239000002253 acid Chemical class 0.000 claims description 7
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims description 7
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 6
- 239000000654 additive Substances 0.000 claims description 6
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 6
- 125000001246 bromo group Chemical group Br* 0.000 claims description 6
- 125000005843 halogen group Chemical group 0.000 claims description 6
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 6
- 239000000546 pharmaceutical excipient Substances 0.000 claims description 6
- 125000000714 pyrimidinyl group Chemical group 0.000 claims description 6
- 239000000377 silicon dioxide Substances 0.000 claims description 6
- WYYFNMXLUUHRAU-UHFFFAOYSA-N 2-phenoxy-2-pyridin-2-yloxypropanoic acid Chemical compound C=1C=CC=NC=1OC(C(O)=O)(C)OC1=CC=CC=C1 WYYFNMXLUUHRAU-UHFFFAOYSA-N 0.000 claims description 5
- GXJQFSNHEKKWLN-UHFFFAOYSA-N 7h-quinolin-8-one Chemical class C1=CN=C2C(=O)CC=CC2=C1 GXJQFSNHEKKWLN-UHFFFAOYSA-N 0.000 claims description 5
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical class ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 claims description 5
- XBDQKXXYIPTUBI-UHFFFAOYSA-N Propionic acid Substances CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims description 5
- 125000003282 alkyl amino group Chemical group 0.000 claims description 5
- SFZULDYEOVSIKM-UHFFFAOYSA-N chembl321317 Chemical group C1=CC(C(=N)NO)=CC=C1C1=CC=C(C=2C=CC(=CC=2)C(=N)NO)O1 SFZULDYEOVSIKM-UHFFFAOYSA-N 0.000 claims description 5
- 125000004218 chloromethyl group Chemical group [H]C([H])(Cl)* 0.000 claims description 5
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 5
- 125000006656 (C2-C4) alkenyl group Chemical group 0.000 claims description 4
- 125000005913 (C3-C6) cycloalkyl group Chemical group 0.000 claims description 4
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 4
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 claims description 4
- 239000003995 emulsifying agent Substances 0.000 claims description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 4
- 125000003718 tetrahydrofuranyl group Chemical group 0.000 claims description 4
- 239000008096 xylene Substances 0.000 claims description 4
- 125000000304 alkynyl group Chemical group 0.000 claims description 3
- 229960000892 attapulgite Drugs 0.000 claims description 3
- 239000003085 diluting agent Substances 0.000 claims description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- 229910052625 palygorskite Inorganic materials 0.000 claims description 3
- 239000000080 wetting agent Substances 0.000 claims description 3
- 150000003920 1,2,4-triazines Chemical class 0.000 claims description 2
- RWRVMJNSJBXFHV-UHFFFAOYSA-N 2-(5-chloro-7-iodoquinolin-8-yl)oxyacetonitrile Chemical compound C1=CC=C2C(Cl)=CC(I)=C(OCC#N)C2=N1 RWRVMJNSJBXFHV-UHFFFAOYSA-N 0.000 claims description 2
- 125000001340 2-chloroethyl group Chemical group [H]C([H])(Cl)C([H])([H])* 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 2
- 230000000996 additive effect Effects 0.000 claims description 2
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical class C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 claims description 2
- 125000005059 halophenyl group Chemical group 0.000 claims description 2
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims description 2
- 125000003170 phenylsulfonyl group Chemical group C1(=CC=CC=C1)S(=O)(=O)* 0.000 claims description 2
- 125000001544 thienyl group Chemical group 0.000 claims description 2
- TWWNLDITIRCJDN-UHFFFAOYSA-N 1,2-bis(2-methylpropyl)naphthalene;sodium Chemical compound [Na].C1=CC=CC2=C(CC(C)C)C(CC(C)C)=CC=C21 TWWNLDITIRCJDN-UHFFFAOYSA-N 0.000 claims 1
- GVNKDIIUOKNRIO-UHFFFAOYSA-N 2-(5-chloroquinolin-8-yl)oxyacetonitrile Chemical compound C1=CC=C2C(Cl)=CC=C(OCC#N)C2=N1 GVNKDIIUOKNRIO-UHFFFAOYSA-N 0.000 claims 1
- 125000004974 2-butenyl group Chemical group C(C=CC)* 0.000 claims 1
- NEURYOYRKPFLKH-UHFFFAOYSA-N 2-chloro-1-isocyanato-4-(trifluoromethyl)benzene Chemical group FC(F)(F)C1=CC=C(N=C=O)C(Cl)=C1 NEURYOYRKPFLKH-UHFFFAOYSA-N 0.000 claims 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims 1
- 125000004183 alkoxy alkyl group Chemical group 0.000 claims 1
- 125000002668 chloroacetyl group Chemical group ClCC(=O)* 0.000 claims 1
- AOGJNTZGPKXOFM-UHFFFAOYSA-L disodium 1,2-bis(2-methylpropyl)naphthalene sulfate Chemical compound S(=O)(=O)([O-])[O-].C(C(C)C)C1=C(C2=CC=CC=C2C=C1)CC(C)C.[Na+].[Na+] AOGJNTZGPKXOFM-UHFFFAOYSA-L 0.000 claims 1
- 239000000945 filler Substances 0.000 claims 1
- 125000001153 fluoro group Chemical group F* 0.000 claims 1
- 125000002346 iodo group Chemical group I* 0.000 claims 1
- FOXFZRUHNHCZPX-UHFFFAOYSA-N metribuzin Chemical compound CSC1=NN=C(C(C)(C)C)C(=O)N1N FOXFZRUHNHCZPX-UHFFFAOYSA-N 0.000 claims 1
- 125000002004 n-butylamino group Chemical group [H]N(*)C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims 1
- 229910052938 sodium sulfate Inorganic materials 0.000 claims 1
- 235000011152 sodium sulphate Nutrition 0.000 claims 1
- 229910021653 sulphate ion Inorganic materials 0.000 claims 1
- 239000003053 toxin Substances 0.000 claims 1
- 231100000765 toxin Toxicity 0.000 claims 1
- 244000038559 crop plants Species 0.000 abstract description 5
- 125000006274 (C1-C3)alkoxy group Chemical group 0.000 abstract 1
- 125000000449 nitro group Chemical class [O-][N+](*)=O 0.000 abstract 1
- 241000196324 Embryophyta Species 0.000 description 39
- 239000000843 powder Substances 0.000 description 27
- 230000001681 protective effect Effects 0.000 description 26
- 239000007921 spray Substances 0.000 description 22
- 238000009472 formulation Methods 0.000 description 21
- 239000002689 soil Substances 0.000 description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 18
- 229920003023 plastic Polymers 0.000 description 13
- 239000004033 plastic Substances 0.000 description 13
- 241000209140 Triticum Species 0.000 description 12
- 235000021307 Triticum Nutrition 0.000 description 12
- 239000000243 solution Substances 0.000 description 12
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 10
- 239000013543 active substance Substances 0.000 description 10
- 239000000839 emulsion Substances 0.000 description 10
- 238000011282 treatment Methods 0.000 description 10
- 239000011521 glass Substances 0.000 description 9
- 239000004094 surface-active agent Substances 0.000 description 9
- 239000004927 clay Substances 0.000 description 8
- 239000012141 concentrate Substances 0.000 description 8
- 235000008504 concentrate Nutrition 0.000 description 8
- 235000014113 dietary fatty acids Nutrition 0.000 description 8
- 239000000194 fatty acid Substances 0.000 description 8
- 229930195729 fatty acid Natural products 0.000 description 8
- 239000008187 granular material Substances 0.000 description 8
- 241000209219 Hordeum Species 0.000 description 7
- 235000007340 Hordeum vulgare Nutrition 0.000 description 7
- 241000209094 Oryza Species 0.000 description 7
- 235000007164 Oryza sativa Nutrition 0.000 description 7
- 238000002156 mixing Methods 0.000 description 7
- 235000009566 rice Nutrition 0.000 description 7
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 6
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 6
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 6
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 6
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- 240000008042 Zea mays Species 0.000 description 5
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 5
- 239000000969 carrier Substances 0.000 description 5
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 5
- 238000010899 nucleation Methods 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 238000009331 sowing Methods 0.000 description 5
- WTDHULULXKLSOZ-UHFFFAOYSA-N Hydroxylamine hydrochloride Chemical compound Cl.ON WTDHULULXKLSOZ-UHFFFAOYSA-N 0.000 description 4
- 125000003342 alkenyl group Chemical group 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 235000019441 ethanol Nutrition 0.000 description 4
- AEXITZJSLGALNH-UHFFFAOYSA-N n'-hydroxyethanimidamide Chemical compound CC(N)=NO AEXITZJSLGALNH-UHFFFAOYSA-N 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- BVWGQYAEICASDT-UHFFFAOYSA-N 2-(5,7-dichloro-2-methylquinolin-8-yl)oxyacetonitrile Chemical compound ClC1=CC(Cl)=C(OCC#N)C2=NC(C)=CC=C21 BVWGQYAEICASDT-UHFFFAOYSA-N 0.000 description 3
- IGFHQQFPSIBGKE-UHFFFAOYSA-N 4-nonylphenol Chemical compound CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 3
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 244000062793 Sorghum vulgare Species 0.000 description 3
- 235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 description 3
- 150000001340 alkali metals Chemical class 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000003240 coconut oil Substances 0.000 description 3
- 235000019864 coconut oil Nutrition 0.000 description 3
- 238000007865 diluting Methods 0.000 description 3
- 238000010790 dilution Methods 0.000 description 3
- 239000012895 dilution Substances 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- 229910052731 fluorine Inorganic materials 0.000 description 3
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- 230000012447 hatching Effects 0.000 description 3
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- 239000007788 liquid Substances 0.000 description 3
- 235000009973 maize Nutrition 0.000 description 3
- 125000001160 methoxycarbonyl group Chemical group [H]C([H])([H])OC(*)=O 0.000 description 3
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- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 2
- VBUKZGDLQYERMU-UHFFFAOYSA-N 1-(2-chlorophenyl)sulfonyl-1-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)urea Chemical compound COC1=NC(C)=NC(N(C(N)=O)S(=O)(=O)C=2C(=CC=CC=2)Cl)=N1 VBUKZGDLQYERMU-UHFFFAOYSA-N 0.000 description 2
- 125000006017 1-propenyl group Chemical group 0.000 description 2
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical group COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 2
- XWSRLDYVUAOERK-UHFFFAOYSA-N 2-quinolin-8-yloxyacetonitrile Chemical compound C1=CN=C2C(OCC#N)=CC=CC2=C1 XWSRLDYVUAOERK-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
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- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 description 2
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- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 239000011630 iodine Substances 0.000 description 2
- 125000000555 isopropenyl group Chemical group [H]\C([H])=C(\*)C([H])([H])[H] 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- XNRPKYTXWNJHGR-UHFFFAOYSA-N n'-hydroxy-2-quinolin-8-yloxyethanimidamide Chemical compound C1=CN=C2C(OCC(N)=NO)=CC=CC2=C1 XNRPKYTXWNJHGR-UHFFFAOYSA-N 0.000 description 2
- 150000002825 nitriles Chemical class 0.000 description 2
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- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 2
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- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 description 2
- 239000004546 suspension concentrate Substances 0.000 description 2
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Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
- C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
- C07D401/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/32—Ingredients for reducing the noxious effect of the active substances to organisms other than pests, e.g. toxicity reducing compositions, self-destructing compositions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D215/00—Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems
- C07D215/02—Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen atoms or carbon atoms directly attached to the ring nitrogen atom
- C07D215/16—Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen atoms or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D215/20—Oxygen atoms
- C07D215/24—Oxygen atoms attached in position 8
- C07D215/26—Alcohols; Ethers thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D215/00—Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems
- C07D215/02—Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen atoms or carbon atoms directly attached to the ring nitrogen atom
- C07D215/16—Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen atoms or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D215/20—Oxygen atoms
- C07D215/24—Oxygen atoms attached in position 8
- C07D215/26—Alcohols; Ethers thereof
- C07D215/28—Alcohols; Ethers thereof with halogen atoms or nitro radicals in positions 5, 6 or 7
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D407/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having oxygen atoms as the only ring hetero atoms, not provided for by group C07D405/00
- C07D407/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having oxygen atoms as the only ring hetero atoms, not provided for by group C07D405/00 containing two hetero rings
- C07D407/12—Heterocyclic compounds containing two or more hetero rings, at least one ring having oxygen atoms as the only ring hetero atoms, not provided for by group C07D405/00 containing two hetero rings linked by a chain containing hetero atoms as chain links
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D409/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
- C07D409/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings
- C07D409/12—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
Landscapes
- Organic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Agronomy & Crop Science (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Plural Heterocyclic Compounds (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH98082 | 1982-02-17 |
Publications (1)
Publication Number | Publication Date |
---|---|
HU189663B true HU189663B (en) | 1986-07-28 |
Family
ID=4199670
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
HU83533A HU189663B (en) | 1982-02-17 | 1983-02-16 | Compositions containing 8-oxy-quinoline derivatives for diminishing phytotoxicity of herbicides and process for producing 8-oxy-quinoline derivatives |
Country Status (26)
Country | Link |
---|---|
US (7) | US4623727A (en, 2012) |
EP (1) | EP0086750B1 (en, 2012) |
JP (1) | JPS58152802A (en, 2012) |
KR (1) | KR900009009B1 (en, 2012) |
AR (1) | AR240932A1 (en, 2012) |
AT (1) | ATE28116T1 (en, 2012) |
AU (1) | AU563387B2 (en, 2012) |
BR (1) | BR8300750A (en, 2012) |
CA (1) | CA1197846A (en, 2012) |
CS (1) | CS246058B2 (en, 2012) |
DD (2) | DD218888A5 (en, 2012) |
DE (1) | DE3372319D1 (en, 2012) |
DK (1) | DK162367C (en, 2012) |
ES (1) | ES519851A0 (en, 2012) |
GB (1) | GB2121403B (en, 2012) |
GR (1) | GR79561B (en, 2012) |
HU (1) | HU189663B (en, 2012) |
IL (1) | IL67915A0 (en, 2012) |
MA (1) | MA19709A1 (en, 2012) |
NZ (1) | NZ203301A (en, 2012) |
PH (1) | PH22043A (en, 2012) |
PL (1) | PL142523B1 (en, 2012) |
PT (1) | PT76244B (en, 2012) |
TR (1) | TR21433A (en, 2012) |
ZA (1) | ZA831041B (en, 2012) |
ZW (1) | ZW4283A1 (en, 2012) |
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Publication number | Priority date | Publication date | Assignee | Title |
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US3056790A (en) | 1960-01-08 | 1962-10-02 | Wisconsin Alumni Res Found | 8-ro-2-quinoline acrylic acid and lower alkyl esters thereof |
US3133810A (en) * | 1961-04-19 | 1964-05-19 | Monsanto Chemicals | Herbicidal compositions |
CH408006A (de) | 1962-05-11 | 1966-02-28 | Geigy Ag J R | Verfahren zur Herstellung von Chinolyl-(8)-oxyessigsäurederivaten |
CH408007A (de) * | 1962-05-11 | 1966-02-28 | Geigy Ag J R | Verfahren zur Herstellung neuer Derivate der Chinolyl-(8)-oxy-essigsäure |
US3592920A (en) * | 1968-07-22 | 1971-07-13 | Stauffer Chemical Co | Method of controlling bacteria and fungi with certain oxime esters |
IL37642A0 (en) * | 1970-09-10 | 1971-11-29 | Ciba Geigy Ag | Di-and tetrahydroquinolyl carbamates,their manufacture and their use as pesticides |
JPS4737540U (en, 2012) * | 1971-05-22 | 1972-12-26 | ||
DE2601548C2 (de) * | 1976-01-16 | 1984-01-26 | Hoechst Ag, 6230 Frankfurt | 2-[4-(2'-Chlor-4'-bromphenoxy)-phenoxy]-propionsäure und Derivate sowie diese enthaltende herbizide Mittel |
DE2617804C2 (de) * | 1976-04-23 | 1985-01-24 | Hoechst Ag, 6230 Frankfurt | 2-(4-Phenoxy phenoxy)-propionsäurederivate und ihre Verwendung als Herbizide |
JPS53130427A (en) * | 1977-04-18 | 1978-11-14 | Sumitomo Chem Co Ltd | Plant growth regulator |
DE2961917D1 (en) * | 1978-01-18 | 1982-03-11 | Ciba Geigy Ag | Herbicidal active unsaturated esters of 4- (3',5'-dihalogenpyridyl-(2')-oxy)-alpha-phenoxy propionic acids, process for their preparation, herbicidal compositions containing them and their use |
DE2930450A1 (de) * | 1979-07-26 | 1981-02-19 | Bayer Ag | N-( alpha -chlorpropionyl)-1,2,3,4- tetrahydro-iso-chinolin, verfahren zu dessen herstellung und dessen verwendung als gegenmittel zum schutz von kulturpflanzen vor schaedigungen durch herbizide |
DE2930451A1 (de) * | 1979-07-26 | 1981-02-19 | Bayer Ag | N-( alpha -chlorpropionyl)-1,2,3,4- tetrahydro-chinaldin, verfahren zu dessen herstellung und dessen verwendung als gegenmittel zum schutz von kulturpflanzen vor schaedigungen durch herbizide |
DE3000076A1 (de) * | 1980-01-03 | 1981-09-03 | Hoechst Ag, 6000 Frankfurt | Wachstumsfoerdernde und pflanzenschuetzende mittel |
MA19709A1 (fr) * | 1982-02-17 | 1983-10-01 | Ciba Geigy Ag | Application de derives de quinoleine a la protection des plantes cultivees . |
US4497651A (en) * | 1982-02-17 | 1985-02-05 | Basf Aktiengesellschaft | Dichloroquinoline derivatives for use as herbicides |
-
1983
- 1983-02-10 MA MA19927A patent/MA19709A1/fr unknown
- 1983-02-11 EP EP83810059A patent/EP0086750B1/de not_active Expired
- 1983-02-11 DE DE8383810059T patent/DE3372319D1/de not_active Expired
- 1983-02-11 GB GB08303882A patent/GB2121403B/en not_active Expired
- 1983-02-11 AT AT83810059T patent/ATE28116T1/de not_active IP Right Cessation
- 1983-02-11 US US06/465,740 patent/US4623727A/en not_active Expired - Fee Related
- 1983-02-11 BR BR8300750A patent/BR8300750A/pt unknown
- 1983-02-14 PH PH28512A patent/PH22043A/en unknown
- 1983-02-15 GR GR70505A patent/GR79561B/el unknown
- 1983-02-15 DD DD83261822A patent/DD218888A5/de unknown
- 1983-02-15 IL IL67915A patent/IL67915A0/xx not_active IP Right Cessation
- 1983-02-15 DD DD83247958A patent/DD208066A5/de unknown
- 1983-02-15 PL PL1983240582A patent/PL142523B1/pl unknown
- 1983-02-15 ZW ZW42/83A patent/ZW4283A1/xx unknown
- 1983-02-15 AR AR292129A patent/AR240932A1/es active
- 1983-02-16 AU AU11463/83A patent/AU563387B2/en not_active Ceased
- 1983-02-16 HU HU83533A patent/HU189663B/hu unknown
- 1983-02-16 ES ES519851A patent/ES519851A0/es active Granted
- 1983-02-16 CA CA000421728A patent/CA1197846A/en not_active Expired
- 1983-02-16 PT PT76244A patent/PT76244B/pt unknown
- 1983-02-16 ZA ZA831041A patent/ZA831041B/xx unknown
- 1983-02-16 TR TR21433A patent/TR21433A/xx unknown
- 1983-02-16 NZ NZ203301A patent/NZ203301A/en unknown
- 1983-02-16 DK DK067583A patent/DK162367C/da not_active IP Right Cessation
- 1983-02-17 KR KR1019830000638A patent/KR900009009B1/ko not_active Expired
- 1983-02-17 CS CS831078A patent/CS246058B2/cs unknown
- 1983-02-17 JP JP58025472A patent/JPS58152802A/ja active Granted
-
1986
- 1986-08-11 US US06/895,569 patent/US4758264A/en not_active Expired - Fee Related
- 1986-09-29 US US06/912,858 patent/US4785105A/en not_active Expired - Fee Related
- 1986-09-29 US US06/912,851 patent/US4822884A/en not_active Expired - Fee Related
- 1986-09-29 US US06/912,857 patent/US4785106A/en not_active Expired - Fee Related
-
1988
- 1988-05-13 US US07/193,617 patent/US4851033A/en not_active Expired - Fee Related
- 1988-11-28 US US07/277,530 patent/US5045107A/en not_active Expired - Fee Related
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