EP3802521A1 - Benzoylpyrazoles bicycliques utilisés comme herbicide - Google Patents
Benzoylpyrazoles bicycliques utilisés comme herbicideInfo
- Publication number
- EP3802521A1 EP3802521A1 EP19728922.6A EP19728922A EP3802521A1 EP 3802521 A1 EP3802521 A1 EP 3802521A1 EP 19728922 A EP19728922 A EP 19728922A EP 3802521 A1 EP3802521 A1 EP 3802521A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- alkyl
- plants
- compounds
- event
- hydrogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
- C07D405/02—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings
- C07D405/06—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings linked by a carbon chain containing only aliphatic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D409/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
- C07D409/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings
- C07D409/06—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings linked by a carbon chain containing only aliphatic carbon atoms
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D411/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having oxygen and sulfur atoms as the only ring hetero atoms
- C07D411/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having oxygen and sulfur atoms as the only ring hetero atoms containing two hetero rings
- C07D411/06—Heterocyclic compounds containing two or more hetero rings, at least one ring having oxygen and sulfur atoms as the only ring hetero atoms containing two hetero rings linked by a carbon chain containing only aliphatic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D417/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00
- C07D417/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings
- C07D417/06—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings linked by a carbon chain containing only aliphatic carbon atoms
Definitions
- the invention relates to the technical field of herbicides, in particular that of herbicides for the selective control of weeds and weeds in crops.
- WO 97/08164 A1 and JPH10130267 describe, inter alia. substituted benzoylpyrazoles, which are fused in the 2,3-position, or 3,4-position of the benzoyl radical.
- An object of the present invention is therefore to provide compounds with herbicidal activity, which are highly effective even at relatively low rates of use against economically important harmful plants and preferably with good efficacy against harmful plants can be selectively used in crops and preferably show a good compatibility with crops.
- these herbicidal compounds should be particularly effective and efficient against a broad spectrum of grass weeds, and preferably additionally have good activity against many weeds.
- the present invention therefore relates to compounds of the general formula (I) and their agrochemically acceptable salts, in which the symbols and indices follow
- A is (CH 2 ) n ,
- X 1 , X 2 independently of one another in each case denote O or S (O) n ,
- R is halogen- (C 1 -C 6 ) -alkyl
- R a , R b independently of one another are each hydrogen, fluorine, (C 1 -C 6 ) -alkyl, halogen
- R a and R b together with the carbon atom to which they are attached form a carbonyl or a thiocarbonyl group
- R pl is hydrogen, (C 1 -C 4 ) -alkylcarbonyloxy- (C 1 -C 4 ) -alkyl, (C 1 -C 4 ) -alkoxycarbonyloxy- (C 1 -C 4 ) -alkyl, (C 1 -C 6 -alkylsulfonyl, (C 1 -C 4 ) -alkoxy- (C 1 -C 6 ) -alkylsulfonyl, or in each case by n identical or different radicals from the group consisting of halogen, (C 1 -C 4 ) -alkyl and (C 1 -C 4 ) Alkoxy-substituted phenylsulfonyl, thiophenyl-2-sulfonyl, benzoyl, benzoyl- (C 1 -C 6 ) -alkyl or benzyl,
- R p2 is (C 1 -C 4 ) -alkyl
- R p3 represents hydrogen, (Ci-C 4) alkyl, (Ci-C 4) -haloalkyl, (CN-Cx) cycloalkyl, (Ci- C4) alkyl- (C 3 -C 8) cycloalkyl or (C 3 -C 6 ) -halocycloalkyl, n means 0, 1 or 2.
- the compounds of formula (I) can form salts. Salt formation can be effected by the action of a base on those compounds of the formula (I) which carry an acidic hydrogen atom.
- suitable bases are organic amines, such as trialkylamines, morpholine, piperidine or pyridine, and ammonium, alkali metal or alkaline earth metal hydroxides, carbonates and bicarbonates, in particular sodium and potassium hydroxide, sodium and potassium carbonate and sodium and
- Potassium bicarbonate are compounds in which the acidic hydrogen is represented by a for the agriculture suitable cation is replaced, for example, metal salts, in particular
- Alkali metal salts or alkaline earth metal salts especially sodium and potassium salts, or ammonium salts, salts with organic amines or quaternary (quaternary) ammonium salts, for example with cations of the formula [NRR'R "R"'] +, wherein R to R'"are each independently one another may be an organic radical, in particular alkyl, aryl, aralkyl or alkylaryl, also suitable are alkylsulfonium and alkylsulfoxonium salts, such as (C 1 -C 4 ) -trialkylsulfonium and (C 1 -C 4 ) -trialkylsulfoxonium salts.
- the compounds of formula (I) may be prepared by addition of a suitable inorganic or organic acid such as, for example, mineral acids such as HCl, HBr, H 2 SO 4, H 3 PO 4 or HNO 3, or organic acids, e.g. Carboxylic acids, such as formic acid, acetic acid, propionic acid, oxalic acid, lactic acid or salicylic acid, or sulfonic acids, such as p-toluenesulfonic acid, to a basic group, e.g. Amino, alkylamino, dialkylamino, piperidino, morpholino or pyridino, salts. These salts then contain the conjugate base of the acid as an anion.
- a suitable inorganic or organic acid such as, for example, mineral acids such as HCl, HBr, H 2 SO 4, H 3 PO 4 or HNO 3, or organic acids, e.g. Carboxylic acids, such as formic acid, acetic acid, prop
- Suitable substituents which are in deprotonated form e.g. Sulfonic acids or carboxylic acids, may form internal salts with their turn protonatable groups, such as amino groups.
- Alkyl is saturated, straight-chain or branched hydrocarbon radicals with the number of carbon atoms given in each case, for example C 1 -C 6 -alkyl, such as methyl, ethyl, propyl, 1-methylethyl, butyl, 1-methyl-propyl, 2-methylpropyl, 1, 1 -Dimethylethyl, pentyl, 1-methylbutyl, 2-methylbutyl, 3-methylbutyl, 2,2-dimethylpropyl, 1-ethylpropyl, hexyl, 1,1-dimethylpropyl, 1,2-di-methylphenyl, 1-methylpentyl, 2 Methylpentyl, 3-methylpentyl, 4-methylpentyl, 1,1-dimethylbutyl,
- Alkyl substituted by halogen means straight-chain or branched alkyl groups, in which groups some or all of the hydrogen atoms may be replaced by halogen atoms, e.g. C 1 -C 2 -haloalkyl, such as chloromethyl, bromomethyl, dichloromethyl, trichloromethyl, fluoromethyl, difluoromethyl, trifluoromethyl, chlorofluoromethyl, dichlorofluoromethyl, chlorodifluoromethyl, 1-chloroethyl, 1-bromoethyl, 1-fluoroethyl, 2-fluoroethyl, 2,2-difluoroethyl, 2, 2,2-trifluoroethyl, 2-chloro-2-fluoroethyl, 2-chloro, 2-difluoroethyl, 2,2-dichloro-2-fluoroethyl, 2,2,2-trichloroethyl, pentafluoroeth
- Cycloalkyl means a carbocyclic, saturated ring system preferably having 3-8 ring C atoms, eg cyclopropyl, cyclobutyl, cyclopentyl or cyclohexyl.
- cycloalkyl cyclic systems are included with substituents, wherein substituents having a double bond on the cycloalkyl, z.
- substituents having a double bond on the cycloalkyl, z As an alkylidene group such as methylidene, are included.
- polycyclic aliphatic systems such as, for example, bicyclo [IIO] butan-1-yl, bicyclo [llO] butan-2-yl,
- spirocyclic aliphatic systems are also included, such as spiro [2.2] pent-1-yl, spiro [2.3] hex-1-yl and spiro [2.3] hex-4-yl, 3-spiro [2.3] hex-5-yl.
- Alkoxy means saturated, straight or branched alkoxy radicals with the respectively specified number of carbon atoms, for example C I -C ⁇ - alkoxy such as methoxy, ethoxy, propoxy, 1 -Methylethoxy, butoxy, propoxy-methyl-1, 2-methylpropoxy, 1, 1 -Dimethylethoxy, pentoxy, 1-methylbutoxy, 2-methylbutoxy, 3-methylbutoxy, 2,2-dimethylpropoxy, 1-ethylpropoxy, hexoxy, 1,1-dimethylpropoxy, 1,2-dimethylpropoxy, 1-methylpentoxy, 2-methylpentoxy , 3-methylpentoxy, 4-methylpentoxy, 1, 1-dimethylbutoxy, 1, 2-dimethylbutoxy, 1,3-dimethylbutoxy, 2,2-dimethylbutoxy, 2,3-dimethylbutoxy, 3,3-dimethylbutoxy, 1-ethylbutoxy, 2 Ethyl butoxy, 1,1,2-trimethylpropoxy,
- halogen alkoxy means straight-chain or branched alkoxy having the number of carbon atoms indicated in each case, wherein in these groups partially or completely the
- Hydrogen atoms may be replaced by halogen atoms as mentioned above, e.g. C1-C2-halogenoalkoxy such as chloromethoxy, bromomethoxy, dichloromethoxy, trichloromethoxy, fluoromethoxy, difluoromethoxy, trifluoromethoxy, chlorofluoromethoxy, dichlorofluoromethoxy, chlorodifluoromethoxy, 1-chloroethoxy, 1-bromoethoxy, 1-fluoroethoxy, 2-fluoroethoxy, 2,2-difluoroethoxy, 2,2,2-trifluoroethoxy, 2-chloro-2-fluoroethoxy, 2-chloro-1, 2-difluoroethoxy, 2,2-dichloro-2-fluoroethoxy, 2,2,2-trichloroethoxy, pentafluoroethoxy and 1, 1,1-trifluoroprop-2-oxy.
- C1-C2-halogenoalkoxy
- halogen means fluorine, chlorine, bromine or iodine.
- halogen means a fluorine, chlorine, bromine or iodine atom.
- Stereoisomers are present. For example, if one or more asymmetrically substituted carbon atoms and / or sulfoxides are present, enantiomers and diastereomers may occur.
- Stereoisomers can be prepared from the mixtures obtained in the preparation of conventional
- stereoisomers can be selectively prepared by using stereoselective reactions using optically active starting materials and / or auxiliaries.
- the invention also relates to all stereoisomers and mixtures thereof which are of the formula (1), but are not specifically defined. However, for the sake of simplicity, the following is always used Compounds of formula (I) spoken, although both the pure compounds and optionally also mixtures with different proportions of isomeric compounds are meant.
- A is (CFb) n ,
- X 1 , X 2 independently of one another are each O or S (O) n ,
- R is halogen (Ci-C3) -alkyl
- R a , R b are each independently hydrogen, fluoro (C 1 -C 6 ) -alkyl, halogen
- R a and R b together with the carbon atom to which they are attached form a carbonyl or a thiocarbonyl group
- R p l is hydrogen
- R p2 is (Ci-C i) -alkyl
- R p3 is hydrogen, (Ci-C i) -alkyl, (Ci-C4) -haloalkyl or cyclopropyl, n is 0, 1 or 2.
- X 1, X 2 are each independently O or S (O) n ,
- R is trifluoromethyl, difluoromethyl or pentafluoroethyl, each independently of one another denote hydrogen, fluorine, methyl, ethyl,
- Trifluoromethyl difluoromethyl, methoxy, ethoxy, or
- R a and R b together with the carbon atom to which they are attached form a carbonyl or a thiocarbonyl group
- R p l is hydrogen
- R p2 is (Ci-C i) -alkyl
- R p3 is hydrogen, (Ci-C i) -alkyl, (Ci-C i) -haloalkyl or cyclopropyl, n means 0, 1 or 2.
- compounds of the general formula (I) are encompassed by the present invention, in which, for example, the substituent X 1 has a preferred meaning and the substituents A, X 2 , R, R a , R b , R 1 , R 2 , R pI , R p2 , R p3 and the index n have the general meaning or the substituent R has a preferred meaning, the substituent R a has a particularly preferred meaning and the remaining substituents one have general meaning.
- L is halogen or R 3 0,
- R 3 is hydrogen or (C 1 -C 6 ) -alkyl
- X 1 ⁇ 2 independently of one another in each case denote O or S (O) n ,
- R is halogen- (C 1 -C 6 ) -alkyl
- R a , R b independently of one another are each hydrogen, fluorine, (C 1 -C 6 ) -alkyl, halogeno (C 1 -C 6 ) -alkyl, (C 1 -C 8) -alkyloxy, (C 1 -Cr,) - Alkylthio, cyano, or
- Collections of compounds of formula (I) and / or their salts, which may be synthesized following the above reactions, may also be prepared in a parallelized manner, which may be done in a manual, partially automated or fully automated manner. It is possible, for example, to automate the reaction procedure, the work-up or the purification of the products or intermediates. Overall, this is understood to mean a procedure as described, for example, by D. Tiebes in Combinatorial Chemistry - Synthesis, Analysis, Screening (publisher Günther Jung), Verlag Wiley 1999, on pages 1 to 34.
- the present invention therefore also provides a method for controlling
- Plant cultures in which one or more compounds of the invention (s) on the plants eg harmful plants such as mono- or dicotyledonous weeds or undesirable crops
- the seed eg grains, seeds or vegetative propagules such as tubers or sprouts with buds
- the area on the plants grow eg the acreage
- the compounds according to the invention can be applied, for example, in pre-sowing (optionally also by incorporation into the soil), pre-emergence or postemergence process.
- some representatives of the monocotyledonous and dicotyledonous weed flora can be mentioned, which can be controlled by the compounds according to the invention, without the intention of limiting them to certain species.
- the compounds according to the invention are applied to the surface of the earth before germination, either the emergence of the weed seedlings is completely prevented or the weeds grow up to the cotyledon stage stage, but then stop their growth.
- the compounds according to the invention can have selectivities in useful cultures and can also be used as nonselective herbicides.
- the active compounds can also be used for controlling harmful plants in crops of known or yet to be developed genetically modified plants.
- the transgenic plants are usually characterized by particular advantageous properties, for example by resistance to certain active ingredients used in the agricultural industry, especially certain herbicides,
- Plant diseases or pathogens of plant diseases such as certain insects or microorganisms such as fungi, bacteria or viruses.
- Other special properties concern, for example, the crop in terms of quantity, quality, shelf life, composition and special ingredients.
- transgenic plants with increased starch content or altered quality of the starch or those with other fatty acid composition of Emteguts are known.
- Further special properties are in a tolerance or resistance to abiotic stressors such as heat, cold, drought, salt and ultraviolet radiation.
- the compounds of the formula (I) can be used as herbicides in crops which are resistant to the phytotoxic effects of the herbicides or have been made genetically resistant.
- new plants with altered properties can be generated by genetic engineering techniques (see, for example, EP 0221044, EP 0131624).
- genetic modifications of crop plants have been described for the purpose of modifying the starch synthesized in the plants (eg WO 92/011376 A, WO 92/014827 A, WO 91/019806 A), transgenic crop plants which are resistant to certain glufosinate-type herbicides (US Pat. see eg EP 0242236 A, EP 0242246 A) or glyphosate (WO 92/000377 A) or the sulfonylureas (EP 0257993 A, US 5,013,659) or against combinations or
- herbicides by "gene stacking" resistant, such as transgenic crops z.
- transgenic crops z For example, corn or soybean with the trade name or designation Optimum TM GAT TM (Glyphosate ALS Tolerant).
- Transgenic crops such as cotton, with the ability to produce Bacillus thuringiensis toxins (Bt toxins), which make the plants resistant to certain pests (EP 0142924 A, EP 0193259 A).
- Bacillus thuringiensis toxins Bacillus thuringiensis toxins
- transgenic crops characterized by higher yields or better quality transgenic crops characterized by a combination of e.g. the o. g. characterize new properties ("gene stacking")
- nucleic acid molecules can be introduced into plasmids that allow mutagenesis or sequence alteration by recombination of DNA sequences.
- base exchanges can be made, partial sequences removed or natural or synthetic sequences added.
- adapters or linkers can be attached to the fragments, see eg Sambrook et al., 1989, Molecular Cloning, A Laboratory Manual, 2nd Ed. Cold Spring Harbor Laboratory Press, Cold Spring Harbor, NY; or Winnacker "Genes and Clones", VCH Weinheim 2nd edition 1996
- the production of plant cells having a reduced activity of a gene product can be achieved, for example, by the expression of at least one corresponding antisense RNA, a sense RNA to obtain a cosuppression effect, or the expression of at least one appropriately engineered ribozyme which specifically cleaves transcripts of the above gene product.
- DNA molecules may be used which comprise the entire coding sequence of a gene product, including any flanking sequences that may be present, as well as DNA molecules which comprise only parts of the coding sequence, which parts must be long enough to be present in the cells to cause an antisense effect. It is also possible to use DNA sequences which have a high degree of homology to the coding sequences of a gene product, but are not completely identical.
- the synthesized protein may be located in any compartment of the plant cell.
- the coding region is linked to DNA sequences which ensure localization in a particular compartment.
- sequences are known to those skilled in the art (see, for example, Braun et al., EMBO J. 11 (1992), 3219-3227; Wolter et al., Proc. Natl. Acad., U.S.A. 85 (1988), 846-850; Sonnewald et al., Plant J. 1 (1991), 95-106).
- the expression of the nucleic acid molecules can also take place in the organelles of the plant cells.
- the transgenic plant cells can be regenerated to whole plants by known techniques.
- the transgenic plants can in principle be plants of any one
- Plant species ie, both monocotyledonous and dicotyledonous plants.
- the compounds (I) according to the invention can be used in transgenic cultures which are resistant to growth substances, such as 2,4-D, dicamba or herbicides, the essential plant enzymes, for example acetolactate synthases (ALS), EPSP synthases, glutamine synthases (GS) or hydroxyphenylpyruvate Dioxygenases (HPPD) inhibit or are resistant to herbicides from the group of sulfonylureas, the glyphosate, glufosinate or benzoylisoxazole and analogous drugs, or against any combination of these drugs, resistant.
- the essential plant enzymes for example acetolactate synthases (ALS), EPSP synthases, glutamine synthases (GS) or hydroxyphenylpyruvate Dioxygenases (HPPD) inhibit or are resistant to herbicides from the group of sulfonylureas, the glyphosate, glufosinate or benzoylisoxazole and analogous drugs
- the compounds according to the invention can particularly preferably be used in transgenic crop plants which are resistant to a combination of glyphosates and glufosinates, glyphosates and sulfonylureas or imidazolinones. Most preferably, the compounds of the invention in transgenic crops such. As corn or soybean with the trade name or the name OptimumTM GATTM (Glyphosate ALS Tolerant) can be used.
- the invention therefore also relates to the use of the compounds of the formula (I) according to the invention as herbicides for controlling harmful plants in transgenic crop plants.
- the compounds of the invention can be used in the form of Spritzpulvem, emulsifiable concentrates, sprayable solutions, dusts or granules in the usual preparations.
- the invention therefore also relates to herbicidal and plant growth-regulating agents which contain the compounds according to the invention.
- the compounds according to the invention can be formulated in various ways, depending on which biological and / or chemical-physical parameters are predetermined. As
- Formulation options are, for example: wettable powders (WP), water-soluble powders (SP), water-soluble concentrates, emulsifiable concentrates (EC), emulsions (EW), such as oil-in-water and water-in-oil emulsions, sprayable solutions, Suspension concentrates (SC), oil- or water-based dispersions, oil-miscible solutions, capsule suspensions (CS), dusts (DP), mordants, granules for litter and soil application, granules (GR) in the form of micro, spray, elevator and adsorption granules, water-dispersible granules (WG), water-soluble Granules (SG), ULV formulations, microcapsules and waxes.
- WP wettable powders
- SP water-soluble powders
- EC emulsifiable concentrates
- EW emulsions
- SC Suspension concentrates
- SC oil- or water-based dispersions
- auxiliaries such as inert materials, surfactants, solvents and other additives are also known and are described, for example, in: Watkins, "Handbook of Insecticides Dust Diluents and Carriers", 2nd ed., Darland Books, Caldwell N.J., H.v. Olphen,
- Producing growth regulators e.g. in the form of a ready-made formulation or as a tank mix.
- combination partners for the compounds according to the invention in mixture formulations or in the tank mix are known active compounds which are based on inhibition of, for example, acetolactate synthase, acetyl-CoA carboxylase, cellulose synthase, enolpyruvylshikimate-3-phosphate synthase, glutamine synthetase, p-hydroxyphenylpyruvate dioxygenase, phytoene desaturase,
- Photosystem I, photosystem II or protoporphyrinogen oxidase can be used, as e.g. from Weed Research 26 (1986) 441-445 or "The Pesticide Manual", 16 th edition, The British Crop Protection Council and the Royal Soc. of Chemistry, 2006 and cited therein.
- herbicidal mixture partners examples include:
- prosulfocarb prosulfuron, pyraclonil, pyraflufen, pyraflufen-ethyl, pyrasulfotole, pyrazolynate ( pyrazolates), pyrazosulfuron, pyrazosulfuron-ethyl, pyrazoxyfen, pyribambenz, pyribambenz-isopropyl, pyribambenz-propyl, pyribenzoxim, pyributicarb, pyridafol, pyridate, pyriftalid, pyriminobac, pyriminobac-methyl, pyr
- plant growth regulators as possible mixing partners are:
- Safeners which are used in combination with the compounds of the formula (I) according to the invention and, if appropriate, in combinations with further active compounds, such as, for example, Insecticides, acaricides, herbicides, fungicides as listed above, are preferably selected from the group consisting of:
- R A 1 is halogen, (C 1 -C 4 ) alkyl, (C 1 -C 4 ) alkoxy, nitro or (C 1 -C 4 ) haloalkyl;
- WA is an unsubstituted or substituted divalent heterocyclic radical selected from the group consisting of the monounsaturated or aromatic five-membered heterocycles having 1 to 3 hetero ring atoms from the group N and O, where at least one N atom and at most one O atom are present in the ring, preferably one Remainder of the group (WA 1 ) to (WA 4 ),
- n A is 0 or 1;
- RA 2 is ORA 3 , SRA 3 or NRA 3 RA 4 or a saturated or unsaturated 3- to 7-membered one
- Heterocycle having at least one N atom and up to 3 heteroatoms, preferably from the group O and S, which is connected via the N atom to the carbonyl group in (S1) and unsubstituted or by radicals from the group (Ci-C i) Alkyl, (Ci-C i) alkoxy or optionally substituted phenyl, preferably a radical of the formula OR A 3 , NHR A 4 or N (CH 3) 2, in particular the formula
- R A 3 is hydrogen or an unsubstituted or substituted aliphatic hydrocarbon radical, preferably having a total of 1 to 18 C atoms;
- RA 4 is hydrogen, (C 1 -C 6 ) alkyl, (C 1 -C 6 ) alkoxy or substituted or unsubstituted phenyl;
- RA 5 is H, (C 1 -C 8 ) alkyl, (C 1 -C 8 ) haloalkyl, (C 1 -C 4 ) alkoxy (C 1 -C 8 ) alkyl, cyano or COOR A 9 , where RA 9 is hydrogen, C 8) alkyl, (Ci-C 8) haloalkyl, (Ci-C 4) alkoxy (Ci-C alkyl 4), (Ci-C 6) hydroxyalkyl, (C3-Ci2) -cycloalkyl or tri- (Ci-C 4 ) -alkyl-silyl;
- RA 6 , RA 7 , RA 8 are identical or different hydrogen, (Ci-C 8 ) alkyl, (Ci-C 8 ) haloalkyl, (C3- Ci2) cycloalkyl or substituted or unsubstituted phenyl; preferably: a) compounds of the type of dichlorophenylpyrazoline-3-carboxylic acid (Sl a ), preferably compounds such as 1- (2,4-dichlorophenyl) -5- (ethoxycarbonyl) -5-methyl-2-pyrazoline-3-carboxylic acid,
- RB 1 is halogen, (Ci-C i) alkyl, (Ci-C i) alkoxy, nitro or (Ci-C4) haloalkyl; ne is a natural number of 0 to 5, preferably 0 to 3;
- R B 2 is OR B 3 , SR B 3 or NR B 3 R B 4 or a saturated or unsaturated 3- to 7-membered heterocycle having at least one N atom and up to 3
- Heteroatoms preferably from the group O and S, which is connected via the N-atom with the carbonyl group in (S2) and unsubstituted or by radicals from the group (Ci-C i) alkyl, (Ci-C i) alkoxy or optionally substituted phenyl, preferably a radical of the formula OR B 3 , NHR B 4 or N (CH 3) 2, in particular of the formula OR B 3 ;
- R B 3 is hydrogen or an unsubstituted or substituted aliphatic hydrocarbon radical, preferably having a total of 1 to 18 C atoms;
- RB 4 is hydrogen, (C 1 -C 6 ) alkyl, (C 1 -C 6 ) alkoxy or substituted or unsubstituted phenyl;
- T B is a (Ci or C2) alkanediyl chain which is unsubstituted or substituted by one or two (Ci-C i) alkyl radicals or by [(Ci-C3) alkoxy] carbonyl; preferably: a) compounds of the 8-quinolinoxyacetic acid type (S2 a ), preferably
- Rc 1 is (Ci-C 4) alkyl, (Ci-C 4) haloalkyl, (C 2 -C 4) alkenyl, (C 2 -C 4) haloalkenyl, (C 3 -C 7) cycloalkyl, preferably dichloromethyl;
- Rc 2, rc 3 are identical or different hydrogen, (Ci-C 4) alkyl, (C2-C4) alkenyl, (C2-C4) alkynyl, (Ci C 4) haloalkyl, (C2-C4) haloalkenyl alkyl, alkyl, (Ci-C4) alkylcarbamoyl (Ci-C 4) (C2-C 4) Alkenylcarbamoyl- (Ci-C 4) alkyl, (Ci-C 4) alkoxy (Ci-C 4), dioxolanyl (Ci-C 4 ) alkyl, thiazolyl, furyl, furylalkyl, thienyl, piperidyl, substituted or unsubstituted phenyl, or Rc 2 and Rc 3 together form a substituted or unsubstituted heterocyclic ring, preferably an oxazolidine,
- R-29148 (3-dichloroacetyl-2,2,5-trimethyl-1,3-oxazolidine) from Stauffer (S3-2),
- R-28725" (3-dichloroacetyl-2,2, -dimethyl-1,3-oxazolidine) from Stauffer (S3-3),
- Benoxacor (4-dichloroacetyl-3,4-dihydro-3-methyl-2H-1,4-benzoxazine) (S3-4),
- PPG-1292 N-allyl-N - [(1,3-dioxolan-2-yl) -methyl] -dichloroacetamide
- TI-35 (1-dichloroacetyl-azepane) from TRI-Chemical RT (S3-8),
- a D is S0 2 -NR D 3 -C0 or C0-NR D 3 -S0 2
- XD is CH or N
- RD 1 is CO-NR D 5 RD 6 or NHCO-RD 7 ;
- RD 2 is halogen, (Ci-C 4) haloalkyl, (Ci-C 4) haloalkoxy, nitro, (Ci-C 4) alkyl, (Ci-C 4) alkoxy, (Ci C 4) alkylsulfonyl, (Ci- C 4 ) alkoxycarbonyl or (C 1 -C 4 ) alkylcarbonyl;
- R D 3 is hydrogen, (Ci-C 4) alkyl, (C 2 -C 4) alkenyl or (C 2 -C 4) alkynyl;
- RD 4 is halogen, nitro, (Ci-C 4) alkyl, (Ci-C 4) haloalkyl, (Ci-C 4) haloalkoxy, (C 3 -C 6) cycloalkyl, phenyl, (Ci-C 4) alkoxy, cyano, (Ci-C 4) alkylthio, (Ci-C 4) alkylsulfinyl, (Ci-C 4) alkylsulfonyl, (Ci C 4) alkoxycarbonyl or (Ci-C 4) alkylcarbonyl;
- RD 5 is hydrogen, (C 1 -C 6 ) alkyl, (C 3 -C 6 ) cycloalkyl, (C 2 -C 6 ) alkenyl, (C 2 -C 6 ) alkynyl, (C 5 -C 6 ) cycloalkenyl, phenyl or 3- to 6-membered heterocyclyl containing V D heteroatoms from the group consisting of nitrogen, oxygen and sulfur, wherein the latter seven radicals by V D
- RD 6 is hydrogen, (Ci-C 6 ) alkyl, (C 2 -Cr,) alkynyl or (C 2 -C 6 ) alkynyl, where the three last-mentioned radicals are represented by V D radicals from the group halogen, hydroxy, C 4 ) alkyl, (C 1 -C 4 ) al
- RD 5 and RD 6 together with the nitrogen atom carrying them form a pyrrolidinyl or piperidinyl radical;
- RD 7 is hydrogen, (Ci-C 4) alkylamino, di (Ci-C 4) alkylamino, (Ci-C 6) alkyl, (C 3 -C 6) cycloalkyl, where the 2 last-mentioned radicals by V D substituents from the group halogen, (Ci-C i) alkoxy, (Ci- C 6 ) haloalkoxy and (Ci-C4) alkylthio and in the case of cyclic radicals also (Ci-C i) alkyl and
- haloalkyl are substituted; n D is 0, 1 or 2; m D is 1 or 2;
- V D is 0, 1, 2 or 3; Of these, preference is given to compounds of the N-acylsulfonamide type, for example of the following formula (S4 a ), which are, for example, B. are known from WO-A-97/45016 wherein
- RD 7 (Ci-C 6 ) alkyl, (C3-C6) cycloalkyl, where the 2 latter radicals by V D substituents selected from the group consisting of halogen, (Ci-C4) alkoxy, (Ci-C 6 ) haloalkoxy and (Ci-C4 ) Alkylthio and in the case of cyclic radicals are also (Ci-C4) alkyl and (Ci-C4) haloalkyl substituted;
- RD 4 is halogen, (C 1 -C 4 ) alkyl, (C 1 -C 4 ) alkoxy, CF 3; m D 1 or 2;
- V D is 0, 1, 2 or 3; such as
- Acylsulfamoylbenzoeklareamide for example, the following formula (S4 b ), for example, are known from WO-A-99/16744,
- compounds of the type of N-Acylsulfamoylphenylhamstoffe of the formula (S4 C), for example, are known from EP-A-365484
- R D 8 and R D 9 independently of one another are hydrogen, (C 1 -C 6 ) -alkyl, (C 3 -C 9 ) -cycloalkyl, (C 3 -C 6 ) -alkenyl, (C 3 -C 6 ) -alkynyl,
- R D 4 is halogen, (C 1 -C 4 ) alkyl, (C 1 -C 4 ) alkoxy, CF 3 m D 1 or 2; for example, 1- [4- (N-2-methoxybenzoylsulfamoyl) phenyl] -3-methylurea,
- N-phenylsulfonylterephthalamides of the formula (S4 d ) which are known, for example, from CN 101838227,
- R D 4 is halogen, (C 1 -C 4 ) alkyl, (C 1 -C 4 ) alkoxy, CF 3; m D 1 or 2; RD 5 is hydrogen, (C 1 -C 6 ) alkyl, (C 3 -C 6 ) cycloalkyl, (C 2 -C 6 ) alkenyl, (C 2 -C 6 ) alkynyl, (C 5 -C 6 ) cycloalkenyl.
- Carboxylic acid derivatives (S5) e.g.
- Dihydroxybenzoic acid 4-hydroxysalicylic acid, 4-fluorosalicyclic acid, 2-hydroxycinnamic acid, 2,4-dichlorocinnamic acid, as described in WO-A-2004/084631, WO-A-2005/015994, WO-A-2005/016001.
- RE 1 , RE 2 are each independently halogen, (Ci-C4) alkyl, (Ci-C i) alkoxy, (Ci-C i) haloalkyl,
- a E is COOR E 3 or COSR E 4 RE 3 , RE 4 are each independently hydrogen, (C 1 -C 4 ) alkyl, (C 2 -C 6) alkenyl,
- Methyl diphenylmethoxyacetate (CAS No. 41858-19-9) (S7-1).
- RF 2 is hydrogen or (Ci-C4) alkyl
- RF 3 is hydrogen, (C 1 -C 5 -alkyl, (C 2 -C 4) -alkenyl, (C 2 -C 4) -alkynyl, or aryl, where each of the abovementioned C-containing radicals is unsubstituted or consists of one or more, preferably up to three, identical or different radicals the group consisting of halogen and alkoxy, or their salts, preferably compounds wherein
- n F is an integer from 0 to 2
- RF 1 halogen (C 1 -C 4) alkyl, (C 1 -C 4) haloalkyl, (C 1 -C 4) alkoxy, (C 1 -C 4) haloalkoxy,
- RF 2 is hydrogen or (Ci-C4) alkyl
- RF 3 is hydrogen, (C 1 -C 6) alkyl, (C 2 -C 4) alkenyl, (C 2 -C 4) alkynyl, or aryl, where each of the aforementioned C-containing radicals is unsubstituted or substituted by one or more, preferably up to three, identical or different Radicals from the group consisting of halogen and alkoxy is substituted, mean or their salts.
- Y G , Z G independently of one another O or S, no an integer from 0 to 4,
- RG 2 (C 1 -C 6 ) alkyl, (C 2 -C 6 ) alkenyl, (C 3 -C 6 ) cycloalkyl, aryl; Benzyl, halobenzyl, R G 3 is hydrogen or (Ci-C 6 ) alkyl.
- Sl 1 active substances of the type of oxyimino compounds (Sl 1), which are known as seed dressings, such as. B.
- Oxabetrinil ((Z) -l, 3-dioxolan-2-ylmethoxyimino (phenyl) acetonitrile) (Sl II), which is known as a seed safener for millet against damage by metolachlor
- Fluofenim (l- (4-) Chlorophenyl) -2,2,2-trifluoro-1-ethanone-O- (1,3-dioxolan-2-ylmethyl) -oxime) (S1-2), which has been known as seed-etch safener for millet against damage by metolachlor is and
- Cyometrinil or “CGA-43089” ((Z) -cyanomethoxyimino (phenyl) acetonitrile) (Sl l-3), which is known as a seed dressing safener for millet against damage from metolachlor.
- S12 active substances from the class of isothiochromanones (S12), such as, for example, methyl [(3-oxo-1H-2] benzothiopyran-4 (3H) -ylidene) methoxy] acetate (CAS Reg. No. 205121-04-6) (S12-1) and related compounds of WO-A-1998/13361.
- S12 isothiochromanones
- Naphthalene anhydride (l, 8-naphthalenedicarboxylic anhydride) (S13-1), which is known as a seed safener for corn against damage by thiocarbamate herbicides.
- MG 191 (CAS Reg. No. 96420-72-3) (2-dichloromethyl-2-methyl-1,3-dioxolane) (S13-5) from Nitrokemia, which is known as safener for corn, " MG 838 "(CAS Reg. No. 133993-74-5)
- Mephenate (4-chlorophenyl methylcarbamate) (S13-9). S14) active substances, in addition to a herbicidal activity against harmful plants and safener
- NK 049 (3,3'-dimethyl-4-methoxy-benzophenone), which is known as safener for rice against damage of some herbicides
- CSB l-bromo-4- (chloromethylsulfonyl) benzene
- RH 1 is a (Ci-C 6 ) haloalkyl radical
- RH 2 is hydrogen or halogen
- RH 3 , RH 4 are each independently hydrogen, (Ci-Ci 6 ) alkyl, (C 2 -C 16) alkenyl or
- (C4-C6) cycloalkenyl fused on one side of the ring with a 4 to 6-membered saturated or unsaturated carbocyclic ring, each of the latter 4 radicals being unsubstituted or substituted by one or more of halogen, hydroxy, cyano, (C 1 -C 4) alkyl, (C 1 -C 4) haloalkyl, (C 1 -C 4) alkoxy, (C 1 -C 4) haloalkoxy, (C 1 -C 4) -alkylthio, (C 1 -C 4) -alkylamino, and di [(C 1 -C 4) -alkyl ] -amino, [(C 1 -C 4) alkoxy] carbonyl,
- R is H 3 (C 1 -C 4) alkoxy, (C 2 -C 4) alkenyloxy, (C 2 -C 6) alkynyloxy or (C 2 -C 4) haloalkoxy and RH 4 is hydrogen or (Ci-C i) -alkyl or
- RH 3 and RH 4 together with the directly attached N atom form a four- to eight-membered one
- heterocyclic ring which, in addition to the N atom, may also contain further hetero ring atoms, preferably up to two further hetero ring atoms from the group consisting of N, O and S, and which may be unsubstituted or substituted by one or more radicals from the group consisting of halogen, cyano, nitro, C i) alkyl, (Ci-C i) haloalkyl, (Ci-C4) alkoxy, (Ci-C4) haloalkoxy and (Ci-C4) alkylthio is substituted means.
- Particularly preferred safeners are mefenpyr-diethyl, cyprosulfamide, isoxadifen-ethyl, cloquintocetmexyl and dichloromide.
- Injectable powders are preparations which are uniformly dispersible in water and contain surfactants of the ionic and / or nonionic type (wetting agents, dispersants) in addition to the active ingredient except a diluent or inert substance.
- surfactants of the ionic and / or nonionic type (wetting agents, dispersants) in addition to the active ingredient except a diluent or inert substance.
- the herbicidal active compounds are finely ground, for example, in customary apparatus such as hammer mills, blower mills and air-jet mills and mixed simultaneously or subsequently with the formulation auxiliaries.
- Emulsifiable concentrates are prepared by dissolving the active ingredient in an organic solvent such as butanol, cyclohexanone, dimethylformamide, xylene or higher-boiling aromatics or hydrocarbons or mixtures of organic solvents with the addition of one or more ionic and / or nonionic surfactants (emulsifiers).
- organic solvent such as butanol, cyclohexanone, dimethylformamide, xylene or higher-boiling aromatics or hydrocarbons or mixtures of organic solvents with the addition of one or more ionic and / or nonionic surfactants (emulsifiers).
- emulsifiers which may be used are: alkylarylsulfonic acid calcium salts, such as Ca-dodecylbenzenesulfonate or nonionic emulsifiers such as fatty acid polyglycol ester,
- Alkylaryl polyglycol ethers fatty alcohol polyglycol ethers, propylene oxide-ethylene oxide condensation products, alkyl polyethers, sorbitan esters such as e.g. Sorbitan fatty acid esters or polyoxethylenesorbitan esters such as e.g. Polyoxyethylenesorbitan fatty acid ester.
- Dusts are obtained by milling the active ingredient with finely divided solids, e.g.
- Talc natural clays such as kaolin, bentonite and pyrophyllite, or diatomaceous earth.
- Suspension concentrates may be water or oil based. They can be prepared, for example, by wet milling using commercially available bead mills and, if appropriate, addition of surfactants, as described, for example, in US Pat. are already listed above for the other formulation types.
- Emulsions e.g. Oil-in-water emulsions (EW), for example, by means of stirrers,
- Solvents and optionally surfactants such as e.g. above in the other formulation types are already listed, produce.
- Granules can either be prepared by spraying the active ingredient onto adsorptive, granulated inert material or by applying active substance concentrates by means of
- Adhesives e.g. Polyvinyl alcohol, polyacrylic acid sodium or mineral oils, on the
- Water dispersible granules are generally prepared by the usual methods such as spray drying, fluidized bed granulation, plate granulation, high speed mixing and extrusion without solid inert material.
- the agrochemical preparations generally contain from 0.1 to 99% by weight, in particular from 0.1 to 95% by weight, of compounds according to the invention.
- the active ingredient concentration is for example about 10 to 90% wt .-%, the remainder to 100 wt .-% consists of conventional formulation components.
- the active ingredient concentration may be about 1 to 90%, preferably 5 to 80% by weight.
- Dusty formulations contain 1 to 30 wt .-% of active ingredient, preferably usually 5 to 20 wt .-% of active ingredient, sprayable solutions contain about 0.05 to 80%, preferably 2 to 50 wt .-% active ingredient.
- the active ingredient content depends, in part, on whether the active compound is liquid or solid and which granulating aids, fillers, etc. are used.
- the content of active ingredient is, for example, between 1 and 95% by weight, preferably between 10 and 80% by weight.
- the active substance formulations mentioned optionally contain the customary adhesion, wetting, dispersing, emulsifying, penetrating, preserving, antifreeze and solvent, fillers, carriers and dyes, antifoams, evaporation inhibitors and the pH and the Viscosity-influencing agent.
- the formulations present in commercial form are optionally diluted in a customary manner, e.g. for Spritzpulvem, emulsifiable concentrates, dispersions and water-dispersible granules by means of water. Dust-like preparations, soil or
- Spreading granulates and sprayable solutions are usually no longer diluted with other inert substances before use.
- the type of herbicide used u.a. varies the required application rate of the compounds of formula (1). It can vary within wide limits, e.g. between 0.001 and 1.0 kg / ha or more of active substance, but is preferably between 0.005 and 750 g / ha.
- Carrier means a natural or synthetic, organic or inorganic substance, with which the active ingredients for better applicability, v.a. for application to plants or
- the carrier which may be solid or liquid, is generally inert and should be useful in agriculture.
- Suitable solid or liquid carriers are: for example, ammonium salts and ground natural minerals, such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth and ground synthetic minerals, such as fumed silica, alumina and natural or synthetic silicates, resins, waxes, solid fertilizers, water, alcohols, especially butanol, organic solvents, mineral and vegetable oils and derivatives thereof. Mixtures of such
- Suitable solid carriers for granules are: e.g. Cracked and fractionated natural rocks such as calcite, marble, pumice, sepiolite, dolomite and synthetic granules of inorganic and organic flours and granules of organic material such as sawdust, coconut shells, corn cobs and tobacco stems.
- Suitable liquefied gaseous diluents or carriers are those liquids which are gaseous at normal temperature and under normal pressure, e.g. Aerosol propellants, such as halogenated hydrocarbons, as well as butane, propane, nitrogen and carbon dioxide.
- Aerosol propellants such as halogenated hydrocarbons, as well as butane, propane, nitrogen and carbon dioxide.
- Adhesives such as carboxymethyl cellulose, natural and synthetic powdery, granular or latex polymers, such as gum arabic, can be used in the formulations.
- Other additives may be mineral and vegetable oils
- Suitable liquid solvents are essentially: aromatics such as xylene, toluene or alkylnaphthalenes, chlorinated aromatics or chlorinated aliphatic hydrocarbons such as chlorobenzenes, chloroethylenes or dichloromethane, aliphatic hydrocarbons such as cyclohexane or paraffins, e.g. Petroleum fractions, mineral and vegetable oils,
- Alcohols such as butanol or glycol and their ethers and esters, ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents such as dimethylformamide and dimethyl sulfoxide, and water.
- the agents of the invention may additionally contain other ingredients, e.g.
- Surfactants include emulsifying and / or foaming agents, dispersants or wetting agents with ionic or nonionic
- Naphthalene sulphonic acid polycondensates of ethylene oxide with fatty alcohols or with fatty amines, substituted phenols (preferably alkylphenols or arylphenols), salts of sulphosuccinic esters, taurine derivatives (preferably alkyl taurates), phosphoric acid esters of polyethoxylated alcohols or phenols, fatty acid esters of polyols, and derivatives of the compounds containing sulphates , Sulphonates and phosphates, for example alkylarylpolyglycol ethers, alkylsulphonates, alkyl sulphates, arylsulphonates, protein hydrolysates, lignin sulphite liquors and methylcellulose.
- the presence of a surfactant is necessary when one of the active ingredients and / or one of the inert carriers is not soluble in water and when applied in water.
- the proportion of surface-active substances is between 5 and 40 percent by weight of the agent according to the invention.
- Dyes such as inorganic pigments such as iron oxide, titanium oxide, ferrocyan blue and organic dyes such as alizarin, azo and metal phthalocyanine dyes and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc can be used.
- additional components may also be included, e.g. protective colloids, binders, adhesives, thickeners, thixotropic substances, penetration promoters, stabilizers,
- the active ingredients can be combined with any solid or liquid additive commonly used for formulation purposes.
- the agents and formulations according to the invention contain between 0.05 and 99% by weight, 0.01 and 98% by weight, preferably between 0.1 and 95% by weight, particularly preferably between 0.5 and 90%. % Active ingredient, most preferably between 10 and 70 weight percent.
- the active compounds or compositions according to the invention can be used as such or as a function of their respective physical and / or chemical properties in the form of their formulations or the use forms prepared therefrom, such as aerosols, capsule suspensions, cold mist concentrates, hot mist concentrates, encapsulated granules, fine granules, flowable concentrates for the
- Seed treatment ready-to-use solutions, dustable powders, emulsifiable concentrates, oil-in-water emulsions, water-in-oil emulsions, macrogranules, microgranules, oil-dispersible powders, oil-miscible flowable concentrates, oil-miscible liquids, foams, pastes, Pesticide-coated seeds, suspension concentrates, suspension-emulsion concentrates, soluble concentrates, suspensions, wettable powders, soluble powders, dusts and granules, water-soluble granules or tablets, water-soluble powders for seed treatment, wettable powders, active substance-impregnated natural and synthetic substances and Feinstverkapselitch in polymeric materials and in coating compositions for seeds, as well as ULV cold and warm mist formulations are used.
- the formulations mentioned can be prepared in a manner known per se, e.g. by mixing the active ingredients with at least one customary diluent, solvent or diluent, emulsifier, dispersing and / or binding or fixing agent, wetting agent, water repellent, optionally siccatives and UV stabilizers and optionally dyes and pigments, antifoams, Preservatives, secondary thickeners, adhesives, gibberellins and other processing aids.
- compositions according to the invention comprise not only formulations which are already ready for use and which can be applied to the plant or the seed with a suitable apparatus, but also commercial concentrates which have to be diluted with water before use.
- the active compounds according to the invention can be used as such or in their (commercially available) formulations and in the formulations prepared from these formulations in admixture with other (known) active ingredients, such as insecticides, attractants, sterilants, bactericides, acaricides, nema- ticides, fungicides, growth regulators, herbicides, fertilizers, safeners or semiochemicals.
- the treatment according to the invention of the plants and plant parts with the active ingredients or agents is carried out directly or by acting on their environment, habitat or storage space according to the usual treatment methods, e.g. by dipping, spraying, spraying, sprinkling, evaporating, atomizing, atomizing, sprinkling, foaming, brushing, spreading, drenching, drip irrigation and propagating material, in particular for seeds by dry pickling, wet pickling, slurry pickling, encrusting, single or multilayer coating, etc. It is also possible to apply the active ingredients by the ultra-low-volume method or to inject the active ingredient preparation or the active ingredient itself into the soil.
- transgenic seed As also described below, the treatment of transgenic seed with the erfindungsge MAESSEN agents or agents is of particular importance.
- This relates to the seed of plants containing at least one heterologous gene which allows expression of a polypeptide or protein having insecticidal properties.
- the heterologous gene in transgenic seed may e.g. come from microorganisms of the species Bacillus, Rhizobium, Pseudomonas, Serratia, Trichoderma, Clavibacter, Glomus or Gliocladium.
- this heterologous gene is derived from Bacillus sp., Wherein the gene product has an activity against the European corn borer and / or Western Com Rootworm.
- the heterologous gene is from Bacillus thuringiensis.
- the agent according to the invention is applied to the seed alone or in a suitable formulation.
- the seed is treated in a condition that is so stable that no damage occurs during the treatment.
- the treatment of the seed can be done at any time between harvesting and sowing.
- seed may be used which has been harvested, cleaned and dried to a moisture content below 15% by weight.
- seed may also be used which, after drying, e.g. treated with water and then dried again.
- agents according to the invention can be applied directly, ie without further
- Suitable formulations and methods for seed treatment are known to those skilled in the art and are described, for example, in the following documents: US 4,272,417 A, US 4,245,432 A, US 4,808,430, US 5,876,739, US 2003/0176428 A1, WO 2002/080675 A1, WO 2002/028186 A2.
- the active compounds according to the invention can be converted into the customary seed dressing formulations, such as solutions, emulsions, suspensions, powders, foams, slurries or other seed coating compositions, as well as ULV formulations.
- formulations are prepared in a known manner by mixing the active ingredients with conventional additives, such as conventional extenders and solution or
- Diluents dyes, wetting agents, dispersants, emulsifiers, defoamers, preservatives, secondary thickeners, adhesives, gibberellins and also water.
- Dyes which may be present in the seed dressing formulations which can be used according to the invention are all dyes customary for such purposes. Both water-insoluble pigments and water-soluble dyes are useful in this case. Examples which may be mentioned under the names rhodamine B, C.I. Pigment Red 112 and C.I. Solvent Red 1 known dyes.
- Suitable wetting agents which may be present in the seed dressing formulations which can be used according to the invention are all wetting-promoting substances customary for the formulation of agrochemical active compounds. Preference is given to using alkylnaphthalene sulfonates, such as diisopropyl or diisobutyl naphthalene sulfonates.
- dispersing agents and / or emulsifiers which may be present in the pickling formulations which can be used according to the invention, all are used for the formulation of agrochemicals
- Nonionic, anionic and cationic dispersants are nonionic or anionic dispersants or mixtures of nonionic or anionic dispersants.
- Particularly suitable nonionic dispersants are, in particular, ethylene oxide-propylene oxide, block polymers, alkylphenol polyglycol ethers and tristryrylphenol polyglycol ethers and their phosphated or sulfated derivatives.
- Suitable anionic dispersants are in particular lignosulfonates, polyacrylic acid salts and arylsulfonate-formaldehyde condensates.
- Defoamers which may be present in the seed-dressing formulations which can be used according to the invention are all foam-inhibiting substances customary for the formulation of agrochemical active compounds.
- Preferably usable are silicone defoamers and magnesium stearate.
- all substances which can be used for such purposes in agrochemicals can be present in the pickling formulations which can be used according to the invention. Examples include dichlorophen and Benzylalkoholhemiformal.
- Suitable secondary thickeners which may be present in the seed dressing formulations which can be used according to the invention are all substances which can be used for such purposes in agrochemicals. Preference is given to cellulose derivatives, acrylic acid derivatives, xanthan, modified clays and finely divided silica.
- Suitable adhesives which may be present in the seed dressing formulations which can be used according to the invention are all customary binders which can be used in pickling agents.
- Preferably mentioned are polyvinylpyrrolidone, polyvinyl acetate, polyvinyl alcohol and Tylose.
- the seed dressing formulations which can be used according to the invention can be used either directly or after prior dilution with water for the treatment of seed of various kinds, including seed of transgenic plants. In this case, additional synergistic effects may occur in interaction with the substances formed by expression.
- the seed dressing formulations which can be used according to the invention or the preparations prepared therefrom by the addition of water
- all mixing devices customarily usable for the dressing can be considered. Specifically, in the pickling procedure, the seed is placed in a mixer which adds either desired amount of seed dressing formulations either as such or after prior dilution with water and mixes until evenly distributed the formulation on the seed. If necessary, followed by a drying process.
- the active compounds according to the invention are suitable for good plant tolerance, more favorable
- plants which can be treated according to the invention the following main crops are mentioned: maize, soybean, cotton, Brassica oilseeds such as Brassica napus (eg canola), Brassica rapa, B. juncea (eg (field) mustard) and Brassica carinata, rice, Wheat sugar beet, cane,
- Brassica oilseeds such as Brassica napus (eg canola), Brassica rapa, B. juncea (eg (field) mustard) and Brassica carinata, rice, Wheat sugar beet, cane,
- Rosaceae sp. Oats, rye, barley, millet, triticale, flax, wine and various fruits and vegetables of various botanical taxa such as Rosaceae sp.
- pomes such as apple and pear, but also stone fruits such as apricots, cherries, almonds and peaches and soft fruits such Strawberries
- Ribesioidae sp. Juglandaceae sp.
- Betulaceae sp. Anacardiaceae sp., Fagaceae sp., Moraceae sp., Oleaceae sp., Actinidaceae sp., Lauraceae sp., Musaceae sp.
- pomes such as apple and pear, but also stone fruits such as apricots, cherries, almonds and peaches and soft fruits such Strawberries
- Ribesioidae sp. Juglandaceae sp.
- Rubiaceae sp. for example, coffee
- Theaceae sp. Sterculiceae sp.
- Rutaceae sp. for example, lemons, organs and grapefruit
- Solanaceae sp. for example, tomatoes, potatoes, peppers, eggplants
- Liliaceae sp. Compositae sp.
- lettuce, artichoke and chicory - including root chicory, endive or common chicory for example, Umbelliferae sp. (for example, carrots, parsley, celery and celeriac),
- Cucurbitaceae sp. for example cucumber - including gherkin, squash, watermelon, gourd and melons
- Alliaceae sp. for example, leek and onion
- Leguminosae sp. e.g., peanuts, peas, and beans - such as barley bean and field bean
- Chenopodiaceae sp. for example, Swiss chard, fodder beet, spinach, beetroot
- Malvaceae for example okra
- asparagaceae for example asparagus
- plants and their parts can be treated.
- wild-type or plant species obtained by conventional biological breeding methods such as crossing or protoplast fusion
- plant cultivars and their parts are treated.
- transgenic plants and plant cultivars obtained by genetic engineering if appropriate in combination with conventional methods (Genetically Modified Organisms), and parts thereof are treated.
- the term "parts” or “parts of plants” or “plant parts” has been explained above. It is particularly preferred according to the invention to treat plants of the respective commercially available or in use plant cultivars. Plant varieties are plants with new ones
- the treatment method of the invention may be used in the treatment of genetically modified organisms (GMOs), e.g. Plants (such as crops and trees) or seeds.
- GMOs genetically modified organisms
- Genetically modified plants are plants in which a heterologous gene has been stably integrated into the genome.
- heterologous gene essentially means a gene which is provided or assembled outside the plant or plant cell and which, when incorporated into the cell nucleatoma, the chloropiastic genome or the
- Mitochondrial genome that confers new or improved agronomic or other traits to the transformed plant by expressing a protein or polypeptide of interest or that it has another gene present in the plant or other genes present in the plant Plant, downregulated or switched off (eg by antisense technology, cosuppression technology, RNA interference technology (RNAi technology) or microRNA technology (miRNA technology)).
- RNAi technology RNA interference technology
- miRNA technology microRNA technology
- the active compound combinations according to the invention can also exert a strengthening effect on plants. They are therefore suitable for mobilizing the plant defense system against attack by unwanted microorganisms. This may optionally be one of the reasons for the increased efficacy of the combinations of the invention, e.g. against mushrooms.
- Plant strengthening (resistance inducing) substances in the present context should also mean those substances or substance combinations capable of stimulating the plant defense system so that the treated plants, when subsequently inoculated with undesirable microorganisms, have a considerable degree of resistance to these microorganisms In the present case, phytopathogenic fungi, bacteria and viruses are understood to mean undesirable microorganisms.
- the substances according to the invention can therefore be employed for the protection of plants against attack by the above-mentioned pathogens within a certain period of time after the treatment.
- the period of time over which a protective effect is achieved generally extends from 1 to 10 days, preferably 1 to 7 days, after the treatment of the plants with the active substances.
- Plants and plant varieties which are preferably treated according to the invention include all plants which have genetic material conferring on these plants particularly advantageous, useful features (whether obtained by breeding and / or biotechnology).
- Plants and plant varieties which are also preferably treated according to the invention are resistant to one or more biotic stress factors, ie these plants have improved Defense against animal and microbial pests such as nematodes, insects, mites, phytopathogenic fungi, bacteria, viruses and / or viroids.
- Examples of nematode or insect resistant plants are e.g. in U.S. Patent Application Nos. 11 / 765,491, 11 / 765,494, 10 / 926,819, 10 / 782,020, 12 / 032,479, 10 / 783,417, 10 / 782,096, 11 / 657,964, 12 / 192,904, 11 / 396,808, 12 / 166,253, 12 / 166,239, 12 / 166,124, 12 / 166,209, 11 / 762,886, 12 / 364,335, 11 / 763,947, 12 / 252,453, 12 / 209,354, 12 / 491,396, 12 / 497,221, 12 / 644,632, 12 / 646,004, 12 / 701,058 , 12 / 718,059, 12 / 721,595, 12 / 638,591 and in WO 11/002992
- Examples of plant resistance to other pathogen species are e.g. in WO 13/050410, WO 2013127988, WO 2013135726, WO 2015036378, WO 2015036469, WO 2015177206.
- Plants and plant varieties which can also be treated according to the invention are those plants which are resistant to one or more abiotic stress factors.
- Abiotic stress conditions may be e.g. Drought, cold and heat conditions, osmotic stress, waterlogging, increased soil salinity, increased exposure to minerals, ozone conditions, high light conditions, limited availability of nitrogen nutrients, limited availability of phosphorous nutrients or avoidance of shade.
- Plants and plant varieties which can also be treated according to the invention are those plants which are characterized by increased yield properties.
- An increased yield can in these plants z. B. based on improved plant physiology, improved plant growth and improved plant development, such as water efficiency, water retention efficiency, improved nitrogen utilization, increased carbon assimilation, improved photosynthesis, increased germination and accelerated Abreife.
- the yield may also be influenced by improved plant architecture (under stress and non-stress conditions), including early flowering, control of flowering for hybrid seed production, seedling vigor,
- Other yield-related traits include seed composition such as
- Carbohydrate content, protein content, oil content and oil composition Carbohydrate content, nutritional value, reduction of nontoxic compounds, improved processability and improved shelf life.
- Plants which can be treated according to the invention are hybrid plants which already express the properties of the heterosis or of the hybrid effect, which is generally higher Yield, higher vigor, better health and better resistance to biotic and abiotic stress factors. Such plants are typically produced by crossing an inbred male sterile parental line (the female crossover partner) with another inbred male fertile parent line (the male crossover partner).
- Hybrid seed is typically harvested from the male sterile plants and sold to growers. Pollen sterile plants can sometimes (for example in corn) by delaving, d. H. mechanical removal of male reproductive organs (or male flowers) are produced; however, it is more common for male sterility to be due to genetic determinants in the plant genome, and in particular when the desired seed to be harvested from the hybrid plants is the seed, it is usually ensured that the pollen fertility in
- Hybrid plants is restored. This can be accomplished by ensuring that the male crossing partners possess appropriate fertility restorer genes capable of restoring pollen fertility in hybrid plants containing the genetic determinants responsible for male sterility.
- Genetic determinants of pollen sterility may be localized in the cytoplasm. Examples of cytoplasmic male sterility (CMS) have been described e.g. for Brassica species (WO 92/05251, WO 95/09910, WO 98/27806, WO 05/002324, WO 06/021972 and US 6,229,072).
- CMS cytoplasmic male sterility
- genetic determinants of male sterility may also be localized in the cell nucleus. Pollen sterile plants can also be obtained using plant biotechnology methods such as genetic engineering.
- a particularly convenient means of producing male-sterile plants is described in WO 89/10396, e.g. a ribonuclease such as a Bamase is selectively expressed in the tapetum cells in the stamens. Fertility can then be restorated by expression of a ribonuclease inhibitor such as barstar in the tapetum cells (e.g., WO91 / 02069).
- a ribonuclease inhibitor such as barstar in the tapetum cells (e.g., WO91 / 02069).
- Other plants containing male sterility genes and fertility restorative genes, as well as systems for hybrid seed production are e.g. in WO 2014170387 and WO 2014195152.
- Plants or plant varieties obtained by methods of plant biotechnology, such as genetic engineering which can be treated according to the invention are also herbicide-tolerant plants, i. Plants tolerant to one or more given herbicides. Such plants can be obtained either by genetic transformation or by selection of plants containing a mutation conferring such herbicide tolerance.
- Herbicide-resistant plants are, for example, glyphosate-tolerant plants, ie plants which have been rendered tolerant to the herbicide glyphosate or its salts.
- Plants can be rendered glyphosate-tolerant in several ways.
- glyphosate-tolerant plants can be obtained by transforming the plant with a gene encoding the enzyme 5-enolpyruvylshikimate-3-phosphate synthase (EPSPS).
- EPSPS 5-enolpyruvylshikimate-3-phosphate synthase
- Examples of such EPSPS genes are the AroA gene (mutant CT7) of the bacterium Salmonella typhimurium (Science 1983, 221, 370-371), the CP4 gene of the bacterium Agrobacterium sp.
- Glyphosate-tolerant plants can also be obtained by expressing a gene coding for a glyphosate oxidoreductase enzyme as described in US 5,776,760 and US 5,463,175.
- Glyphosate-tolerant plants can also be obtained by expressing a gene encoding a glyphosate acetyltransferase enzyme as described in e.g. WO 02/036782, WO 03/092360, WO 05/012515 and WO 07/024782.
- Glyphosate-tolerant plants may also be obtained by culturing plants containing the naturally occurring mutations of the above mentioned genes, e.g.
- Plants expressing glyphosate tolerance-mediating EPSPS genes are e.g. in U.S. Patent Application Nos. 11 / 517,991, 10 / 739,610, 12 / 139,408, 12 / 352,532, 11 / 312,866, 11 / 315,678, 12 / 421,292, 11 / 400,598, 11 / 651,752, 11 / 681,285, 11 / 605,824, 12 / 468,205, 11 / 760,570, 11 / 762,526, 11 / 769,327, 11 / 769,255, 11/943801 or 12 / 362,774.
- Plants containing other glyphosate tolerance-mediating genes, such as decarboxylase genes, are e.g. in U.S. Patent Application Nos. 11 / 588,811, 11 / 185,342, 12 / 364,724, 11 / 185,560 or 12 / 423,926.
- herbicide resistant plants are e.g. Plants tolerant to herbicides which inhibit the enzyme glutamine synthase, such as bialaphos, phosphinothricin or glufosinate. Such plants can be obtained by expressing an enzyme that detoxifies the herbicide or using a mutant of the enzyme glutamine synthase
- Such an effective detoxifying enzyme is e.g. an enzyme encoding a phosphinothricin acetyltransferase (such as the bar or pat protein from Streptomyces species). Plants expressing an exogenous phosphinothricin acetyltransferase are known e.g. in U.S. Patents 5,561,236; 5,648,477; 5,646,024;
- HPPD hydroxyphenylpyruvate dioxygenase
- HPPD is an enzyme that catalyzes the reaction in which para-hydroxyphenylpyruvate (HPP) is converted to homogentisate.
- Plants tolerant to HPPD inhibitors may be treated with a gene encoding a naturally occurring resistant HPPD enzyme or a gene encoding a mutant or chimeric HPPD enzyme as described in WO 96/38567, WO 99/24585, WO 99/24586,
- Tolerance to HPPD inhibitors can also be achieved by transforming plants with genes encoding such enzymes that inhibit the formation of homogentisate
- Allow inhibition of the native HPPD enzyme by the HPPD inhibitor Such plants and genes are described in WO 99/34008 and WO 02/36787.
- the tolerance of plants to HPPD inhibitors can also be improved by transforming plants in addition to a gene coding for an HPPD-tolerant enzyme with a gene coding for an enzyme with prephenate dehydrogenase (PDH) activity as described in WO 04/024928.
- plants can be made more tolerant of HPPD inhibitor herbicides by adding to their genome a gene encoding an enzyme which is useful for metabolizing or degrading HPPD inhibitors, such as those described in WO 07/103567 and WO 08/150473 shown CYP450 enzymes.
- ALS inhibitors include e.g. Sulfonylurea, imidazolinone, triazolopyrimidines, pyrimidinyloxy (thio) benzoates and / or sulfonylaminocarbonyltriazolinone herbicides.
- ALS also known as acetoxy-hydroxy acid synthase, AHAS
- AHAS acetoxy-hydroxy acid synthase
- the preparation of sulfonylurea tolerant plants and imidazolinone tolerant plants is described in U.S. Patents 5,605,011; 5,013,659; 5,141,870; 5,767,361; 5,731,180; 5,304,732; 4,761,373;
- Sulfonylurea and imidazolinone tolerant plants are also useful in e.g. WO 07/024782, WO
- plants which are tolerant to imidazolinone and / or sulfonylurea may be obtained by induced mutagenesis, selection in cell cultures in the presence of the herbicide or by mutagenesis, e.g. for the soybean in US 5,084,082, for rice in WO 97/41218, for the sugar beet in US 5,773,702 and WO 99/057965, for salad in US 5,198,599 or for the sunflower in WO 01/065922.
- Plants tolerant of 2,4-D or dicamba are e.g. in US6153401.
- Plants or plant varieties obtained by plant biotechnology methods such as genetic engineering which can also be treated according to the invention are insect-resistant transgenic plants, ie plants which have been made resistant to attack by certain target insects. Such plants can be obtained by genetic transformation or by selection of plants containing a mutation conferring such insect resistance.
- insect-resistant transgenic plant includes any plant containing at least one transgene comprising a coding sequence encoding:
- an insecticidal crystal protein from Bacillus thuringiensis or an insecticidal portion thereof such as the insecticidal crystal proteins described by Crickmore et al (Microbiology and Molecular Biology Reviews 1998, 62, 807-813), by Crickmore et al. (2005) in the Bacillus thuringiensis toxin nomenclature, online at:
- insecticidal parts thereof e.g. Cry protein class proteins CrylAb, CrylAc, CrylB, CrylC, CrylD, CrylF, Cry2Ab, Cry3Aa or Cry3Bb, or insecticidal portions thereof (e.g., EP-A
- a crystal protein from Bacillus thuringiensis or a part thereof which is insecticidal in the presence of a second, different crystal protein than Bacillus thuringiensis or a part thereof, such as the binary toxin selected from the crystal proteins Cry34 and Cry35 (Nat. Biotechnol., 2001, 19 , 668-72, Applied Environment Microbiol., 2006, 71, 1765-1774), or the binary toxin consisting of the CrylA or CrylF protein and the Cry2Aa or Cry2Ab or Cry2Ae protein (US patent application Ser 12 / 214,022 and EP-A 2 300 618); or
- a hybrid insecticidal protein comprising parts of different Bacillus thuringiensis insecticidal crystal proteins, e.g. a hybrid of the proteins of 1) above or a hybrid of the proteins of 2) above, e.g. The protein CrylA.105 produced by the corn event MON89034 (WO 07/027777); or
- VIPs vegetative insecticidal proteins
- a secreted protein from Bacillus thuringiensis or Bacillus cereus which is insecticidal in the presence of a second secreted protein from Bacillus thuringiensis or B. cereus, such as the binary toxin consisting of the proteins VIP1A and VIP2A (WO 94/21795) or
- a hybrid insecticidal protein comprising parts of various secreted proteins of Bacillus thuringiensis or Bacillus cereus, such as a hybrid of the proteins of 1) above or a hybrid of the proteins of 2) above; or
- a secreted protein from Bacillus thuringiensis or Bacillus cereus which is insecticidal in the presence of a crystal protein from Bacillus thuringiensis, such as the binary toxin consisting of VIP3 and CrylA or CrylF (US patent applications 61/126083 and 61/195019), or the binary toxin consisting of the protein VIP3 and the proteins Cry2Aa or Cry2Ab or Cry2Ae (US patent application 12 / 214,022 and EP-A 2 300 618); or
- a protein according to 9) above in which some, in particular 1 to 10, amino acids have been replaced by another amino acid, in order to achieve a higher insecticidal activity against a target insect species, and / or to broaden the spectrum of the affected target insect species, and or because of changes introduced into the coding DNA during cloning or transformation (preserving the coding for an insecticidal protein).
- insect-resistant transgenic plants in the present context include any plant comprising a combination of genes coding for the proteins of any of the above-mentioned classes 1 to 10.
- an insect-resistant plant contains more than one transgene encoding a protein of any one of the above classes 1 to 10 in order to extend the spectrum of target insect species involved when using different proteins targeting different target insect species, or to increase the development of resistance of the insects to the plants by using various proteins, the are insecticidal for the same target insect species, but have a different mode of action, such as binding to different receptor binding sites in the insect.
- An "insect-resistant transgenic plant” as used herein further includes any plant containing at least one transgene which comprises a sequence which upon expression produces a double-stranded RNA which, when ingested by a plant pest insect, inhibits the growth of that pest insect, e.g. in WO 07/080126, WO 06/129204, WO 07/074405, WO 07/080127 and WO 07/035650.
- Plants or plant varieties obtained by methods of plant biotechnology, such as genetic engineering), which can also be treated according to the invention, are tolerant to abiotic stressors. Such plants can be obtained by genetic transformation or by selection of plants containing a mutation conferring such stress resistance. Particularly useful plants with stress tolerance include the following:
- Plants or plant cultivars obtained by plant biotechnology methods such as genetic engineering which can also be treated according to the invention have an altered quantity, quality and / or storability of the enceary product and / or altered properties of certain components of the enceary product; such as:
- Amylose / amylopectin ratio the degree of branching, the average chain length, the distribution of the side chains, the viscosity behavior, the gel strength, the starch grain size and / or starch comorphology in comparison to the synthesized starch in wild-type plant cells or plants is changed, so that this modified starch is better suited for certain applications.
- These transgenic plants which synthesize a modified starch are described, for example, in EP-A 0 571 427, WO 95/04826, EP-A 0 719 338, WO 96/15248,
- WO 03/33540 WO 04/078983, WO 01/19975, WO 95/26407, WO 96/34968, WO 98/20145, WO 99/12950, WO 99/66050, WO 99/53072, US 6,734,341, WO 00 / 11192, WO 98/22604,
- WO 98/32326 WO 01/98509, WO 01/98509, WO 05/002359, US 5,824,790, US 6,013,861, WO 94/04693, WO 94/09144, WO 94/11520, WO 95/35026, WO 97/20936 WO 10/012796, WO 10/003701, WO13 / 053729, WO13 / 053730.
- Polyfructose in particular of the inulin and levan type, produce, as described in EP-A 0 663 956, WO 96/01904, WO 96/21023, WO 98/39460 and WO 99/24593, plants which contain alpha-1,4 Produce glucans, as described in WO 95/31553, US 2002031826, US 6,284,479,
- Transgenic plants or hybrid plants such as onions with characteristics such as 'high soluble solids content', 'low pungency' (LP) and / or 'long storage' (LS), as described in US patent applications 12 / 020,360 is described.
- Plants or plant varieties are plants such as cotton plants with altered fiber properties. Such plants can be obtained by genetic transformation or by selection of plants containing a mutation conferring such altered fiber properties; These include: a) plants such as cotton plants containing an altered form of cellulose synthase genes as described in WO 98/00549; b) plants, such as cotton plants, which contain an altered form of rsw2 or rsw3 homologous nucleic acids, as described in WO 04/053219; c) plants such as cotton plants with an increased expression of the sucrose phosphate synthase, as described in WO 01/17333; d) plants such as cotton plants with an increased expression of sucrose synthase, as described in WO 02/45485; e) plants, such as cotton plants, where the timing of the passage control of the
- Plasmodesms is changed at the base of the fiber cell, z.
- plants such as cotton plants with altered reactivity fibers, e.g. by
- N-acetylglucosamine transferase gene including nodC
- chitin synthase genes as described in WO 06/136351, WO 2011/089021, WO 2011/089021,
- Plants or plant varieties are plants such as oilseed rape or related brassiciferous plants with altered oil composition properties. Such plants can be obtained by genetic transformation or by selection of plants containing a mutation conferring such altered oil properties; These include: a) plants such as rape plants producing oil of high oleic acid content as described, for example, in US 5,969,169, US 5,840,946, US 6,323,392, US 6,063,947 or WO 2014006158, WO 2014006159, WO 2014006162; b) plants such as oilseed rape plants which produce low linolenic acid oil as described in US 6,270,828, US 6,169,190 or US 5,965,755, WO 2011/060946; c) plants such as oilseed rape plants, the oil with a low saturated fatty acid content
- Plants or plant varieties (which can be obtained by plant biotechnology methods, such as genetic engineering), which can also be treated according to the invention, are plants such as rape or related ⁇ / m r / plants with altered seed dispersal properties. Such plants can be obtained by genetic transformation or by selection of plants containing a mutation conferring such altered seed dispersal properties; These include rape plants with delayed or reduced seed scattering, as described in US Patent Application 61 / 135,230, WO 09/068313 and WO 10/006732.
- Plants or plant varieties which can be obtained by plant biotechnology methods such as genetic engineering
- plants which can also be treated according to the invention are plants such as tobacco plants with altered post-translational protein modification patterns, as described e.g. in WO 10/121818 and WO 10/145846.
- Transgenic crops that can be treated according to the invention are preferably plants that have transformation events or a combination of
- Event 531 / PV-GHBK04 Cotton, Insect Control, described in WO 2002/040677
- Event 1143-14A cotton, insect control, not deposited, described in WO 06/128569
- Event 1143-51B cotton, insect control, not deposited, described in WO 06/128570
- Event 1445 cotton, herbicide tolerance, unpublished, described in US-A 2002-120964 or WO 02/034946
- Event 17053 rice, herbicide tolerance, deposited as PTA-9843 described in WO 10/117737
- Event 17314 (Rice, herbicide tolerance, deposited as PTA-9844, described in WO 10/117735)
- Event 281-24-236 cotton,
- Event 40416 (corn, insect control - herbicide tolerance, deposited as ATCC PTA-11508 described in WO 11/075593); Event 43A47 (corn, insect control - herbicide tolerance deposited as ATCC PTA-I 1509 described in WO 11/075595); Event 5307 (corn, insect control deposited as ATCC PTA-9561 described in WO 10/077816); Event ASR-368 [Straussgras (bent grass), herbicide tolerance deposited as ATCC PTA-4816 described in US-A 2006-162007 or WO 04/053062]; Event B16 (corn, herbicide tolerance, not deposited, described in US-A 2003-126634); Event BPS-CV127-9 (Soybean, herbicide tolerance, deposited as NCIMB No.
- Event BLR1 Rape plants, recultivation of male sterility, deposited as NCIMB 41193, described in WO 2005/074671
- event CE43-67B cotton, insect control, deposited as DSM ACC2724 described in US-A 2009-217423 or WO 06/128573
- Event CE44- 69D cotton, insect control, not deposited, described in US-A 2010-0024077
- Event CE44-69D cotton, insect control, not deposited, described in WO 06/128571
- Event CE46-02A cotton, insect control, not deposited, described in WO 06/128572
- Event COT102 cotton, insect control, not deposited, described in US-A 2006-130175 or WO 04/039986
- Event COT202 cotton, insect control, not deposited, described in US-A 2007-067868 or WO 05/054479
- Event COT203 cotton, insect control, not deposited,
- Event DP-098140-6 Maize, herbicide tolerance, deposited as ATCC PTA-8296, described in US-A 2009-137395 or WO 08/112019
- Event DP-305423-1 Soybean, quality feature, not deposited, described in US-A 2008-312082 or WO 08/054747
- Event DP-32138-1 miize, hybrid system deposited as ATCC PTA-9158 described in US-A 2009-0210970 or WO
- Event DP-356043-5 Soybean, herbicide tolerance, deposited as ATCC PTA-8287, described in US-A 2010-0184079 or WO 08/002872
- Event EE-1 eggplant, insect control, not deposited, described in WO 07/091277
- Event FI117 corn, herbicide tolerance deposited as ATCC 209031 described in US-A 2006-059581 or WO 98/044140
- Event FG72 (soybean, herbicide tolerance, deposited as PTA-1 1041 described in WO 2011/063413),
- Event GA21 corn, herbicide tolerance deposited as ATCC 209033 described in US-A 2005-086719 or WO
- Event GG25 corn, herbicide tolerance deposited as ATCC 209032 described in US-A 2005-188434 or WO 98/044140
- Event GHB119 cotton, insect control - herbicide tolerance, deposited as ATCC PTA-8398 described in WO 08/151780
- Event GHB614 cotton, herbicide tolerance, deposited as ATCC PTA-6878 described in US-A 2010-050282 or WO 07/017186
- Event GJ11 corn, herbicide tolerance deposited as ATCC 209030 described in US-A 2005-188434 or WO 98/044140
- Event GM RZ13 sugar beet, virus resistance deposited as NCIMB-41601 described in WO 10/076212
- Event H7-1 sigar beet, herbicide tolerance, deposited as NCIMB 41158 or NCIMB 41159 described in US-A 2004-172669 or WO 04/074492
- Event JOPLIN1 (wheat, fungal resistance, not deposited
- MON87460 (maize, stress tolerance, deposited as ATCC PTA-8910 described in WO 09/111263 or US-A 2011-0138504); Event MON87701 (Soybean, insect control deposited as ATCC PTA-8194 described in US-A 2009-130071 or WO 09/064652); Event MON87705 (soybean, quality feature - herbicide tolerance, deposited as ATCC PTA-9241, described in US-A 2010-0080887 or WO 10/037016); Event MON87708 (Soybean, herbicide tolerance, deposited as ATCC PTA-9670, described in WO 11/034704); Event MON87712 (Soybean, Yield, deposited as ATCC PTA-10296 described in WO 12/051199); Event MON87754 (soybean, quality feature, deposited as ATCC PTA-9385, described in WO 10/024976); Event MON87769 (soybean, quality feature deposited
- Event MSI 1 (oilseed rape, pollination control - herbicide tolerance deposited as ATCC PTA-850 or PTA-2485 described in WO 01/031042); Event MS8 (rape, pollination control - herbicide tolerance deposited as ATCC PTA-730 described in WO 01/041558 or US-A 2003- 188 347); Event NK603 (corn, herbicide tolerance deposited as ATCC PTA-2478 described in US-A 2007-292854); Event PE-7 (rice, insect control, not deposited, described in WO 08/114282); Event RF3 (Rape, Pollination Control - Herbicide Tolerance, deposited as ATCC PTA-730 described in WO 01/041558 or US-A 2003-188347); Event RT73 (rape, herbicide tolerance, not deposited, described in WO 02/036831 or US-A 2008-070260); Event SYHT0H2 / SYN-00H2-5 (soybean, herbicide tolerance deposited
- Event VIP1034 (corn, insect control - herbicide tolerance, deposited as ATCC PTA-3925 described in WO 03/052073); Event 32316 (corn, insect control - herbicide tolerance, deposited as PTA-I 1507 described in WO 11/084632); Event 4114 (corn, insect control - herbicide tolerance deposited as PTA-I 1506 described in WO 11/084621); Event EE-GM3 / FG72 (soybean, herbicide tolerance, ATCC accession number PTA-l 1041, WO 2011 / 063413A2); Event DAS-68416-4 (Soybean, herbicide tolerance, ATCC accession number PTA-10442, WO02 / 066360A1); Event DAS-68416-4 (Soybean, herbicide tolerance, ATCC accession number PTA-10442, WO02 / 066360A1); Event DAS-68416-4 (Soybean, herbicide tolerance, ATCC accession number PTA-10442, WO /
- Event DP-040416-8 Maize, Insect Control, ATCC accession number PTA-1 1508, WO 2011 / 075593A1; Event DP-043A47-3 (Maize, Insect Control, ATCC Accession Number PTA-11509, WO 2011 / 075595A1), Event DP-004114-3 (Maize, Insect Control, ATCC accession number PTA-1 1506, WO 2011/084621 A1); Event DP-032316-8 (corn, insect control, ATCC
- Herbicide tolerance ATCC accession number PTA-10955, WO 2011 / 153186A1; Event DAS-21606-3 (Soybean, herbicide tolerance, ATCC accession number PTA-1 1028, WO 2012 / 033794A2); Event MON-87712-4 (Soybean plant, quality feature, ATCC accession number PTA-10296, WO 2012 / 051199A2); Event DAS-44406-6 (soybean, stacked herbicide tolerance, ATCC accession number PTA-l 1336, WO 2012 / 075426A1); Event DAS-14536-7 (soybean, stacked herbicide tolerance, ATCC accession number PTA-l 1335, WO 2012 / 075429A1); Event SYN-000H2-5 (soybean, stacked herbicide tolerance, ATCC Accession Number PTA-1226, WO 2012 / 082548A2); Event DP-061061-7 (rape plant,
- Herbicide tolerance ATCC accession number PTA-l 1336, WO 2012075426A2); Event 8291.45.36.2 (soybean, stacked herbicide tolerance, ATCC accession number PTA-l 1335, WO 2012075429A2); Event SYHT0H2 (soybean, ATCC accession number PTA-1 1226, WO 2012 / 082548A2); Event MON88701 (cotton, ATCC accession number PTA-I 1754, WO 2012 / 134808A1); Event KK179-2 (Alfalfa, ATCC accession number PTA-l 1833, W02013003558A1); Event pDAB8264.42.32.1 (Soybean, stacked herbicide tolerance, ATCC accession number PTA-l 1993, WO 2013010094A1); Event MZDT09Y (maize, ATCC accession number PTA-13025, WO 2013012775A1); Event KK179-2 (Alfalfa,
- Herbicide tolerance ATCC accession number PTA-12006, WO2013016527A1
- Event HCEM485 corn, herbicide tolerance, ATCC accession number PTA-12014, W02013025400A1
- Event pDAB4468.18.07.1 cotton, herbicide tolerance, ATCC accession number PTA-12456, WO2013112525A2
- Event pDAB4468.19.10.3 cotton, herbicide tolerance, ATCC accession number PTA-12457
- Example 1-44 Synthesis of 7- (5-hydroxy-1-ethyl-pyrazole-3-carbonyl) -4- (trifluoromethyl) -1,3-benzoxathiolane
- the NMR data of disclosed examples are listed either in classical form (d values, number of H atoms, multiplet splitting) or as so-called NMR peak lists.
- the NMR data of selected examples are noted in the form of NMR peak lists, with the d value in ppm and then the signal intensity separated by a space for each signal peak.
- the d-value signal intensity-number pairs of different signal peaks are listed separated by semicolons.
- the peak list of an example therefore has the form: di (intensity ⁇ ; 6 2 (intensity 2 );.; D; (intensity ⁇ ;;; d h (intensity)
- the intensity of sharp signals correlates with the height of the signals in a printed example of an NMR spectrum in cm and shows the true ratios of the signal intensities. For broad signals, multiple peaks or the center of the signal and their relative intensity can be shown compared to the most intense signal in the spectrum.
- tetramethylsilane is used and / or the chemical shift of the solvent, especially in the case of spectra measured in DMSO. Therefore, the tetramethylsilane peak may occur in NMR peaks, but it does not have to.
- the lists of the H NMR Pcaks are similar to the classical H NMR expressions and thus usually contain all the peaks that are listed in a classical NMR interpretation.
- An expert calculating the peaks of the target compounds by known methods can isolate the peaks of the target compounds as needed, using additional intensity filters if necessary. This isolation would be similar to peak picking in the classical 1H NMR interpretation.
- a dust is obtained by mixing 10 parts by weight of a compound of formula (I) and 90% by weight of talc as inert and comminuting in a hammer mill.
- a wettable powder readily dispersible in water is obtained by reacting 25 parts by weight of a compound of formula (I), 64 parts by weight of kaolin-containing quartz as inert material, 10 parts by weight of lignosulfonic acid potassium and 1 part by weight of oleoylmethyltaurine sodium as wetting agent
- Dispersant mixed and ground in a pin mill.
- a water-dispersible dispersion concentrate is obtained by adding 20 parts by weight of a compound of formula (I), 6 parts by weight of alkylphenol polyglycol ether (®Triton X 207), 3 parts by weight of isotridecanol polyglycol ether (8 EO) and 71 parts by weight paraffinic mineral oil (boiling range, for example, about 255 to about 277 ° C) and milled in a ball mill to a fineness of less than 5 microns.
- a compound of formula (I) 6 parts by weight of alkylphenol polyglycol ether (®Triton X 207), 3 parts by weight of isotridecanol polyglycol ether (8 EO) and 71 parts by weight paraffinic mineral oil (boiling range, for example, about 255 to about 277 ° C) and milled in a ball mill to a fineness of less than 5 microns.
- An emulsifiable concentrate is obtained from 15 parts by weight of a compound of the formula (I), 75 parts by weight of cyclohexanone as solvent and 10 parts by weight of ethoxylated nonylphenol as emulsifier.
- a water-dispersible granule is obtained by
- a water-dispersible granule is also obtained by
- ABUTH Abutilon theophrasti
- CYPES Cyperus esculentus
- ECHCG Echinochloa crus-galli
- VERPE Veronica persica
- VIOTR Viola tricolor
- Seeds of monocotyledonous or dicotyledonous weeds and crops are laid out in plastic or organic plant pots and covered with soil.
- the compounds according to the invention formulated in the form of wettable powders (WP) or as emulsion concentrates (EC) are then applied to the surface of the cover soil as an aqueous suspension or emulsion with the addition of 0.5% of additive at a water application rate of 600 l / ha.
- WP wettable powders
- EC emulsion concentrates
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- Agronomy & Crop Science (AREA)
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Abstract
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Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2003A (en) | 1841-03-12 | Improvement in horizontal windivhlls | ||
US188347A (en) | 1877-03-13 | Improvement in lamp-burners | ||
US2036008A (en) | 1934-11-07 | 1936-03-31 | White Martin Henry | Plug fuse |
US3247908A (en) | 1962-08-27 | 1966-04-26 | Robook Nicolay Nikolaevich | Adjustable blades hydraulic turbine runner |
US4272417A (en) | 1979-05-22 | 1981-06-09 | Cargill, Incorporated | Stable protective seed coating |
US4245432A (en) | 1979-07-25 | 1981-01-20 | Eastman Kodak Company | Seed coatings |
MA19709A1 (fr) | 1982-02-17 | 1983-10-01 | Ciba Geigy Ag | Application de derives de quinoleine a la protection des plantes cultivees . |
EP0094349B1 (fr) | 1982-05-07 | 1994-04-06 | Ciba-Geigy Ag | Utilisation de dérivés de quinoléine pour protéger des plantes cultivées |
WO1984002919A1 (fr) | 1983-01-17 | 1984-08-02 | Monsanto Co | Plasmides de transformation de cellules vegetales |
BR8404834A (pt) | 1983-09-26 | 1985-08-13 | Agrigenetics Res Ass | Metodo para modificar geneticamente uma celula vegetal |
JPS6087254A (ja) | 1983-10-19 | 1985-05-16 | Japan Carlit Co Ltd:The | 新規尿素化合物及びそれを含有する除草剤 |
US5304732A (en) | 1984-03-06 | 1994-04-19 | Mgi Pharma, Inc. | Herbicide resistance in plants |
US5331107A (en) | 1984-03-06 | 1994-07-19 | Mgi Pharma, Inc. | Herbicide resistance in plants |
US4761373A (en) | 1984-03-06 | 1988-08-02 | Molecular Genetics, Inc. | Herbicide resistance in plants |
DE3525205A1 (de) | 1984-09-11 | 1986-03-20 | Hoechst Ag, 6230 Frankfurt | Pflanzenschuetzende mittel auf basis von 1,2,4-triazolderivaten sowie neue derivate des 1,2,4-triazols |
BR8600161A (pt) | 1985-01-18 | 1986-09-23 | Plant Genetic Systems Nv | Gene quimerico,vetores de plasmidio hibrido,intermediario,processo para controlar insetos em agricultura ou horticultura,composicao inseticida,processo para transformar celulas de plantas para expressar uma toxina de polipeptideo produzida por bacillus thuringiensis,planta,semente de planta,cultura de celulas e plasmidio |
DE3680212D1 (de) | 1985-02-14 | 1991-08-22 | Ciba Geigy Ag | Verwendung von chinolinderivaten zum schuetzen von kulturpflanzen. |
DE3686633T2 (de) | 1985-10-25 | 1993-04-15 | David Matthew Bisaro | Pflanzenvektoren. |
ES2018274T5 (es) | 1986-03-11 | 1996-12-16 | Plant Genetic Systems Nv | Celulas vegetales resistentes a los inhibidores de glutamina sintetasa, preparadas por ingenieria genetica. |
EP0305398B1 (fr) | 1986-05-01 | 1991-09-25 | Honeywell Inc. | Agencement d'interconnexion de plusieurs circuits integres |
US5273894A (en) | 1986-08-23 | 1993-12-28 | Hoechst Aktiengesellschaft | Phosphinothricin-resistance gene, and its use |
US5276268A (en) | 1986-08-23 | 1994-01-04 | Hoechst Aktiengesellschaft | Phosphinothricin-resistance gene, and its use |
US5637489A (en) | 1986-08-23 | 1997-06-10 | Hoechst Aktiengesellschaft | Phosphinothricin-resistance gene, and its use |
US5013659A (en) | 1987-07-27 | 1991-05-07 | E. I. Du Pont De Nemours And Company | Nucleic acid fragment encoding herbicide resistant plant acetolactate synthase |
IL83348A (en) | 1986-08-26 | 1995-12-08 | Du Pont | Nucleic acid fragment encoding herbicide resistant plant acetolactate synthase |
US5378824A (en) | 1986-08-26 | 1995-01-03 | E. I. Du Pont De Nemours And Company | Nucleic acid fragment encoding herbicide resistant plant acetolactate synthase |
US5605011A (en) | 1986-08-26 | 1997-02-25 | E. I. Du Pont De Nemours And Company | Nucleic acid fragment encoding herbicide resistant plant acetolactate synthase |
DE3629890A1 (de) | 1986-08-29 | 1988-03-10 | Schering Ag | Mikroorganismen und plasmide fuer die 2,4-dichlorphenoxyessigsaeure (2,4-d)-monooxigenase - bildung und verfahren zur herstellung dieser plasmide und staemme |
DE3633840A1 (de) | 1986-10-04 | 1988-04-14 | Hoechst Ag | Phenylpyrazolcarbonsaeurederivate, ihre herstellung und verwendung als pflanzenwachstumsregulatoren und safener |
EP0268554B1 (fr) | 1986-10-22 | 1991-12-27 | Ciba-Geigy Ag | Dérivés d'acide diphényl-1,5-pyrazol-3-carbonique pour la protection de plantes de culture |
US4808430A (en) | 1987-02-27 | 1989-02-28 | Yazaki Corporation | Method of applying gel coating to plant seeds |
DE3733017A1 (de) | 1987-09-30 | 1989-04-13 | Bayer Ag | Stilbensynthase-gen |
US5638637A (en) | 1987-12-31 | 1997-06-17 | Pioneer Hi-Bred International, Inc. | Production of improved rapeseed exhibiting an enhanced oleic acid content |
DE3808896A1 (de) | 1988-03-17 | 1989-09-28 | Hoechst Ag | Pflanzenschuetzende mittel auf basis von pyrazolcarbonsaeurederivaten |
GB8810120D0 (en) | 1988-04-28 | 1988-06-02 | Plant Genetic Systems Nv | Transgenic nuclear male sterile plants |
DE3817192A1 (de) | 1988-05-20 | 1989-11-30 | Hoechst Ag | 1,2,4-triazolderivate enthaltende pflanzenschuetzende mittel sowie neue derivate des 1,2,4-triazols |
US5084082A (en) | 1988-09-22 | 1992-01-28 | E. I. Du Pont De Nemours And Company | Soybean plants with dominant selectable trait for herbicide resistance |
EP0365484B1 (fr) | 1988-10-20 | 1993-01-07 | Ciba-Geigy Ag | Sulfamoylphénylurées |
US6013861A (en) | 1989-05-26 | 2000-01-11 | Zeneca Limited | Plants and processes for obtaining them |
DE69034268D1 (de) | 1989-08-10 | 2011-03-03 | Bayer Bioscience Nv | Pflanzen mit modifizierten Blüten |
DE3939010A1 (de) | 1989-11-25 | 1991-05-29 | Hoechst Ag | Isoxazoline, verfahren zu ihrer herstellung und ihre verwendung als pflanzenschuetzende mittel |
DE3939503A1 (de) | 1989-11-30 | 1991-06-06 | Hoechst Ag | Neue pyrazoline zum schutz von kulturpflanzen gegenueber herbiziden |
US5739082A (en) | 1990-02-02 | 1998-04-14 | Hoechst Schering Agrevo Gmbh | Method of improving the yield of herbicide-resistant crop plants |
US5908810A (en) | 1990-02-02 | 1999-06-01 | Hoechst Schering Agrevo Gmbh | Method of improving the growth of crop plants which are resistant to glutamine synthetase inhibitors |
WO1991013972A1 (fr) | 1990-03-16 | 1991-09-19 | Calgene, Inc. | Desaturases de plantes - compositions et emplois |
AU639319B2 (en) | 1990-04-04 | 1993-07-22 | Pioneer Hi-Bred International, Inc. | Production of improved rapeseed exhibiting a reduced saturated fatty acid content |
US5198599A (en) | 1990-06-05 | 1993-03-30 | Idaho Resarch Foundation, Inc. | Sulfonylurea herbicide resistance in plants |
WO1991019806A1 (fr) | 1990-06-18 | 1991-12-26 | Monsanto Company | Plantes a teneur en amidon augmentee |
AU655197B2 (en) | 1990-06-25 | 1994-12-08 | Monsanto Technology Llc | Glyphosate tolerant plants |
DE4107396A1 (de) | 1990-06-29 | 1992-01-02 | Bayer Ag | Stilbensynthase-gene aus weinrebe |
US6395966B1 (en) | 1990-08-09 | 2002-05-28 | Dekalb Genetics Corp. | Fertile transgenic maize plants containing a gene encoding the pat protein |
FR2667078B1 (fr) | 1990-09-21 | 1994-09-16 | Agronomique Inst Nat Rech | Sequence d'adn conferant une sterilite male cytoplasmique, genome mitochondrial, mitochondrie et plante contenant cette sequence, et procede de preparation d'hybrides. |
EP0492366B1 (fr) | 1990-12-21 | 1997-03-26 | Hoechst Schering AgrEvo GmbH | Nouveaux dérivés de chloro-5-quinoline-8-acide oxyalkanecarboniques, procédé pour leur préparation et leur utilisation comme antidote d'herbicides |
SE467358B (sv) | 1990-12-21 | 1992-07-06 | Amylogene Hb | Genteknisk foeraendring av potatis foer bildning av staerkelse av amylopektintyp |
DE4104782B4 (de) | 1991-02-13 | 2006-05-11 | Bayer Cropscience Gmbh | Neue Plasmide, enthaltend DNA-Sequenzen, die Veränderungen der Karbohydratkonzentration und Karbohydratzusammensetzung in Pflanzen hervorrufen, sowie Pflanzen und Pflanzenzellen enthaltend dieses Plasmide |
US5731180A (en) | 1991-07-31 | 1998-03-24 | American Cyanamid Company | Imidazolinone resistant AHAS mutants |
US6270828B1 (en) | 1993-11-12 | 2001-08-07 | Cargrill Incorporated | Canola variety producing a seed with reduced glucosinolates and linolenic acid yielding an oil with low sulfur, improved sensory characteristics and increased oxidative stability |
TW259690B (fr) | 1992-08-01 | 1995-10-11 | Hoechst Ag | |
DE4227061A1 (de) | 1992-08-12 | 1994-02-17 | Inst Genbiologische Forschung | DNA-Sequenzen, die in der Pflanze die Bildung von Polyfructanen (Lävanen) hervorrufen, Plasmide enthaltend diese Sequenzen sowie Verfahren zur Herstellung transgener Pflanzen |
GB9218185D0 (en) | 1992-08-26 | 1992-10-14 | Ici Plc | Novel plants and processes for obtaining them |
DK0664835T3 (da) | 1992-10-14 | 2004-09-27 | Syngenta Ltd | Nye planter og fremgangsmåde til opnåelse af dem |
GB9223454D0 (en) | 1992-11-09 | 1992-12-23 | Ici Plc | Novel plants and processes for obtaining them |
EP1471145A2 (fr) | 1993-03-25 | 2004-10-27 | Syngenta Participations AG | Souches et protéines pesticides |
JP3527242B2 (ja) | 1993-04-27 | 2004-05-17 | カージル,インコーポレーテッド | 食用の非水素化カノラ油 |
WO1995004826A1 (fr) | 1993-08-09 | 1995-02-16 | Institut Für Genbiologische Forschung Berlin Gmbh | Enzymes de deramification et sequences d'adn les codant, utilisables dans la modification du degre de ramification de l'amidon amylopectinique dans des plantes |
DE4330960C2 (de) | 1993-09-09 | 2002-06-20 | Aventis Cropscience Gmbh | Kombination von DNA-Sequenzen, die in Pflanzenzellen und Pflanzen die Bildung hochgradig amylosehaltiger Stärke ermöglichen, Verfahren zur Herstellung dieser Pflanzen und die daraus erhaltbare modifizierte Stärke |
DE4331448A1 (de) | 1993-09-16 | 1995-03-23 | Hoechst Schering Agrevo Gmbh | Substituierte Isoxazoline, Verfahren zu deren Herstellung, diese enthaltende Mittel und deren Verwendung als Safener |
WO1995009910A1 (fr) | 1993-10-01 | 1995-04-13 | Mitsubishi Corporation | Gene identifiant un cytoplasme vegetal sterile et procede pour preparer un vegetal hybride a l'aide de celui-ci |
AU692791B2 (en) | 1993-10-12 | 1998-06-18 | Agrigenetics, Inc. | Brassica napus variety AG019 |
KR960705938A (ko) | 1993-11-09 | 1996-11-08 | 미리암 디. 메코너헤이 | 유전자 전환된 프럭탄 축적 작물 및 그의 제조 방법(Transgenic Fructan Accumulating Crops and Method for Their Production) |
AU688006B2 (en) | 1994-03-25 | 1998-03-05 | Brunob Ii B.V. | Method for producing altered starch from potato plants |
DE69535543T2 (de) | 1994-05-18 | 2008-04-30 | Bayer Bioscience Gmbh | Für enzyme, die die fähigkeit besitzen lineare alpha 1,4-glucane in pflanzen, pilzen und mikroorganismen zu synthesieren, kodierende dna sequenzen |
CA2190761A1 (fr) | 1994-06-21 | 1995-12-28 | Peter Lewis Keeling | Nouvelles plantes et leur procede d'obtention |
US5824790A (en) | 1994-06-21 | 1998-10-20 | Zeneca Limited | Modification of starch synthesis in plants |
NL1000064C1 (nl) | 1994-07-08 | 1996-01-08 | Stichting Scheikundig Onderzoe | Produktie van oligosacchariden in transgene planten. |
DE4441408A1 (de) | 1994-11-10 | 1996-05-15 | Inst Genbiologische Forschung | DNA-Sequenzen aus Solanum tuberosum kodierend Enzyme, die an der Stärkesynthese beteiligt sind, Plasmide, Bakterien, Pflanzenzellen und transgene Pflanzen enhaltend diese Sequenzen |
DE4447387A1 (de) | 1994-12-22 | 1996-06-27 | Inst Genbiologische Forschung | Debranching-Enzyme aus Pflanzen und DNA-Sequenzen kodierend diese Enzyme |
JP3840259B2 (ja) | 1995-01-06 | 2006-11-01 | プラント リサーチ インターナショナル ベスローテン フェンノートシャップ | 炭水化物ポリマー合成酵素をコードするdna配列及びトランスジェニック植物を製造するための方法 |
DE19509695A1 (de) | 1995-03-08 | 1996-09-12 | Inst Genbiologische Forschung | Verfahren zur Herstellung einer modifizieren Stärke in Pflanzen, sowie die aus den Pflanzen isolierbare modifizierte Stärke |
US5853973A (en) | 1995-04-20 | 1998-12-29 | American Cyanamid Company | Structure based designed herbicide resistant products |
BR9604993B1 (pt) | 1995-04-20 | 2009-05-05 | dna mutante codificando uma proteìna ahas mutante de sìntese de ácido acetohidróxi e proteìnas ahas mutantes. | |
WO1996034968A2 (fr) | 1995-05-05 | 1996-11-07 | National Starch And Chemical Investment Holding Corporation | Ameliorations apportees a une composition a base d'amidon de plante |
FR2734842B1 (fr) | 1995-06-02 | 1998-02-27 | Rhone Poulenc Agrochimie | Sequence adn d'un gene de l'hydroxy-phenyl pyruvate dioxygenase et obtention de plantes contenant un gene de l'hydroxy-phenyl pyruvate dioxygenase, tolerantes a certains herbicides |
US6284479B1 (en) | 1995-06-07 | 2001-09-04 | Pioneer Hi-Bred International, Inc. | Substitutes for modified starch and latexes in paper manufacture |
US5712107A (en) | 1995-06-07 | 1998-01-27 | Pioneer Hi-Bred International, Inc. | Substitutes for modified starch and latexes in paper manufacture |
GB9513881D0 (en) | 1995-07-07 | 1995-09-06 | Zeneca Ltd | Improved plants |
FR2736926B1 (fr) | 1995-07-19 | 1997-08-22 | Rhone Poulenc Agrochimie | 5-enol pyruvylshikimate-3-phosphate synthase mutee, gene codant pour cette proteine et plantes transformees contenant ce gene |
WO1997008164A1 (fr) | 1995-08-25 | 1997-03-06 | E.I. Du Pont De Nemours And Company | Herbicides bicycliques |
PT1435205E (pt) | 1995-09-19 | 2010-02-04 | Bayer Bioscience Gmbh | Plantas que sintetizam um amido modificado, processo para a sua produção e amido modificado |
GB9524938D0 (en) | 1995-12-06 | 1996-02-07 | Zeneca Ltd | Modification of starch synthesis in plants |
DE19601365A1 (de) | 1996-01-16 | 1997-07-17 | Planttec Biotechnologie Gmbh | Nucleinsäuremoleküle aus Pflanzen codierend Enzyme, die an der Stärkesynthese beteiligt sind |
DE19608918A1 (de) | 1996-03-07 | 1997-09-11 | Planttec Biotechnologie Gmbh | Nucleinsäuremoleküle, die neue Debranching-Enzyme aus Mais codieren |
US5773704A (en) | 1996-04-29 | 1998-06-30 | Board Of Supervisors Of Louisiana State University And Agricultural And Mechanical College | Herbicide resistant rice |
DE19618125A1 (de) | 1996-05-06 | 1997-11-13 | Planttec Biotechnologie Gmbh | Nucleinsäuremoleküle, die neue Debranching-Enzyme aus Kartoffel codieren |
DE19619918A1 (de) | 1996-05-17 | 1997-11-20 | Planttec Biotechnologie Gmbh | Nucleinsäuremoleküle codierend lösliche Stärkesynthasen aus Mais |
DE19621522A1 (de) | 1996-05-29 | 1997-12-04 | Hoechst Schering Agrevo Gmbh | Neue N-Acylsulfonamide, neue Mischungen aus Herbiziden und Antidots und deren Verwendung |
IL127246A0 (en) | 1996-05-29 | 1999-09-22 | Hoechst Schering Agrevo Gmbh | Nucleic acid molecules encoding enzymes from wheat which are involved in starch synthesis |
CA2257623C (fr) | 1996-06-12 | 2003-02-11 | Pioneer Hi-Bred International, Inc. | Substituts de l'amidon modifie utilises dans la fabrication du papier |
WO1997047806A1 (fr) | 1996-06-12 | 1997-12-18 | Pioneer Hi-Bred International, Inc. | Substituts de l'amidon modifie utilises dans la fabrication du papier |
AU729286B2 (en) | 1996-06-12 | 2001-02-01 | Pioneer Hi-Bred International, Inc. | Substitutes for modified starch in paper manufacture |
US5876739A (en) | 1996-06-13 | 1999-03-02 | Novartis Ag | Insecticidal seed coating |
AUPO069996A0 (en) | 1996-06-27 | 1996-07-18 | Australian National University, The | Manipulation of plant cellulose |
US5850026A (en) | 1996-07-03 | 1998-12-15 | Cargill, Incorporated | Canola oil having increased oleic acid and decreased linolenic acid content |
US5773702A (en) | 1996-07-17 | 1998-06-30 | Board Of Trustees Operating Michigan State University | Imidazolinone herbicide resistant sugar beet plants |
AU4778097A (en) | 1996-09-26 | 1998-04-17 | Novartis Ag | Herbicidal composition |
JPH10130267A (ja) | 1996-11-01 | 1998-05-19 | Idemitsu Kosan Co Ltd | ピラゾール誘導体およびそれを用いた除草剤 |
GB9623095D0 (en) | 1996-11-05 | 1997-01-08 | Nat Starch Chem Invest | Improvements in or relating to starch content of plants |
US6232529B1 (en) | 1996-11-20 | 2001-05-15 | Pioneer Hi-Bred International, Inc. | Methods of producing high-oil seed by modification of starch levels |
DE19653176A1 (de) | 1996-12-19 | 1998-06-25 | Planttec Biotechnologie Gmbh | Neue Nucleinsäuremoleküle aus Mais und ihre Verwendung zur Herstellung einer modifizierten Stärke |
DE19652961A1 (de) | 1996-12-19 | 1998-06-25 | Hoechst Schering Agrevo Gmbh | Neue 2-Fluoracrylsäurederivate, neue Mischungen aus Herbiziden und Antidots und deren Verwendung |
CA2193938A1 (fr) | 1996-12-24 | 1998-06-24 | David G. Charne | Oleagineux du genre brassica renfermant un gene restaurateur de la fertilite ameliore encodant la sterilite male cytoplasmique ogura |
US5981840A (en) | 1997-01-24 | 1999-11-09 | Pioneer Hi-Bred International, Inc. | Methods for agrobacterium-mediated transformation |
DE19708774A1 (de) | 1997-03-04 | 1998-09-17 | Max Planck Gesellschaft | Nucleinsäuremoleküle codierend Enzyme die Fructosylpolymeraseaktivität besitzen |
US6071856A (en) | 1997-03-04 | 2000-06-06 | Zeneca Limited | Herbicidal compositions for acetochlor in rice |
DE19709775A1 (de) | 1997-03-10 | 1998-09-17 | Planttec Biotechnologie Gmbh | Nucleinsäuremoleküle codierend Stärkephosphorylase aus Mais |
AU6882298A (en) | 1997-04-03 | 1998-10-22 | Dekalb Genetics Corporation | Glyphosate resistant maize lines |
DE19727410A1 (de) | 1997-06-27 | 1999-01-07 | Hoechst Schering Agrevo Gmbh | 3-(5-Tetrazolylcarbonyl)-2-chinolone und diese enthaltende nutzpflanzenschützende Mittel |
GB9718863D0 (en) | 1997-09-06 | 1997-11-12 | Nat Starch Chem Invest | Improvements in or relating to stability of plant starches |
DE19742951A1 (de) | 1997-09-29 | 1999-04-15 | Hoechst Schering Agrevo Gmbh | Acylsulfamoylbenzoesäureamide, diese enthaltende nutzpflanzenschützende Mittel und Verfahren zu ihrer Herstellung |
DE19749122A1 (de) | 1997-11-06 | 1999-06-10 | Max Planck Gesellschaft | Nucleinsäuremoleküle codierend Enzyme, die Fructosyltransferaseaktivität besitzen |
FR2770854B1 (fr) | 1997-11-07 | 2001-11-30 | Rhone Poulenc Agrochimie | Sequence adn d'un gene de l'hydroxy-phenyl pyruvate dioxygenase et obtention de plantes contenant un tel gene, tolerantes aux herbicides |
GB9724586D0 (en) * | 1997-11-20 | 1998-01-21 | Rhone Poulenc Agriculture | New herbicides |
FR2772789B1 (fr) | 1997-12-24 | 2000-11-24 | Rhone Poulenc Agrochimie | Procede de preparation enzymatique d'homogentisate |
EP1068333A1 (fr) | 1998-04-09 | 2001-01-17 | E.I. Du Pont De Nemours And Company | Homologues de la proteine r1 de phosphorylation de l'amidon |
DE19820608A1 (de) | 1998-05-08 | 1999-11-11 | Hoechst Schering Agrevo Gmbh | Nucleinsäuremoleküle codierend Enzyme aus Weizen, die an der Stärkesynthese beteiligt sind |
DE19820607A1 (de) | 1998-05-08 | 1999-11-11 | Hoechst Schering Agrevo Gmbh | Nucleinsäuremoleküle codierend Enzyme aus Weizen, die an der Stärkesynthese beteiligt sind |
JP4494634B2 (ja) | 1998-05-13 | 2010-06-30 | バイエル バイオサイエンス ゲーエムベーハー | プラスチドadp/atp転移因子の改変された活性を有するトランスジェニック植物 |
DE19821614A1 (de) | 1998-05-14 | 1999-11-18 | Hoechst Schering Agrevo Gmbh | Sulfonylharnstoff-tolerante Zuckerrübenmutanten |
CA2331300C (fr) | 1998-06-15 | 2009-01-27 | National Starch And Chemical Investment Holding Corporation | Ameliorations apportees a des plantes et a des produits vegetaux |
US6693185B2 (en) | 1998-07-17 | 2004-02-17 | Bayer Bioscience N.V. | Methods and means to modulate programmed cell death in eukaryotic cells |
DE19836097A1 (de) | 1998-07-31 | 2000-02-03 | Hoechst Schering Agrevo Gmbh | Nukleinsäuremoleküle kodierend für eine alpha-Glukosidase, Pflanzen, die eine modifizierte Stärke synthetisieren, Verfahren zur Herstellung der Pflanzen, ihre Verwendung sowie die modifizierte Stärke |
DE19836099A1 (de) | 1998-07-31 | 2000-02-03 | Hoechst Schering Agrevo Gmbh | Nukleinsäuremoleküle kodierend für eine ß-Amylase, Pflanzen, die eine modifizierte Stärke synthetisieren, Verfahren zur Herstellung der Pflanzen, ihre Verwendung sowie die modifizierte Stärke |
DE19836098A1 (de) | 1998-07-31 | 2000-02-03 | Hoechst Schering Agrevo Gmbh | Pflanzen, die eine modifizierte Stärke synthetisieren, Verfahren zur Herstellung der Pflanzen, ihre Verwendung sowie die modifizierte Stärke |
AU6018399A (en) | 1998-08-25 | 2000-03-14 | Pioneer Hi-Bred International, Inc. | Plant glutamine: fructose-6-phosphate amidotransferase nucleic acids |
CA2342124A1 (fr) | 1998-09-02 | 2000-03-16 | Planttec Biotechnologie Gmbh | Molecules d'acide nucleique codant une amylosucrase |
DE19924342A1 (de) | 1999-05-27 | 2000-11-30 | Planttec Biotechnologie Gmbh | Genetisch modifizierte Pflanzenzellen und Pflanzen mit erhöhter Aktivität eines Amylosucraseproteins und eines Verzweigungsenzyms |
PL347223A1 (en) | 1998-10-09 | 2002-03-25 | Planttec Biotechnologie Gmbh | Nucleic acid molecules which code a branching enzyme from bacteria of the genus neisseria, and a method for producing α-1,6-branched α-1,4-glucans |
US6333449B1 (en) | 1998-11-03 | 2001-12-25 | Plant Genetic Systems, N.V. | Glufosinate tolerant rice |
WO2000026356A1 (fr) | 1998-11-03 | 2000-05-11 | Aventis Cropscience N. V. | Riz tolerant au glufosinate |
AU773808B2 (en) | 1998-11-09 | 2004-06-10 | Bayer Cropscience Aktiengesellschaft | Nucleic acid molecules from rice and their use for the production of modified starch |
US6503904B2 (en) | 1998-11-16 | 2003-01-07 | Syngenta Crop Protection, Inc. | Pesticidal composition for seed treatment |
US6531648B1 (en) | 1998-12-17 | 2003-03-11 | Syngenta Participations Ag | Grain processing method and transgenic plants useful therein |
DE19905069A1 (de) | 1999-02-08 | 2000-08-10 | Planttec Biotechnologie Gmbh | Nucleinsäuremoleküle codierend Alternansucrase |
US6323392B1 (en) | 1999-03-01 | 2001-11-27 | Pioneer Hi-Bred International, Inc. | Formation of brassica napus F1 hybrid seeds which exhibit a highly elevated oleic acid content and a reduced linolenic acid content in the endogenously formed oil of the seeds |
HUP0201013A2 (en) | 1999-04-29 | 2002-07-29 | Syngenta Ltd | Herbicide resistant plants |
JP2003523173A (ja) | 1999-04-29 | 2003-08-05 | シンジェンタ リミテッド | 除草剤耐性植物 |
DE19926771A1 (de) | 1999-06-11 | 2000-12-14 | Aventis Cropscience Gmbh | Nukleinsäuremoleküle aus Weizen, transgene Pflanzenzellen und Pflanzen und deren Verwendung für die Herstellung modifizierter Stärke |
DE19937348A1 (de) | 1999-08-11 | 2001-02-22 | Aventis Cropscience Gmbh | Nukleinsäuremoleküle aus Pflanzen codierend Enzyme, die an der Stärkesynthese beteiligt sind |
DE19937643A1 (de) | 1999-08-12 | 2001-02-22 | Aventis Cropscience Gmbh | Transgene Zellen und Pflanzen mit veränderter Aktivität des GBSSI- und des BE-Proteins |
AU7647000A (en) | 1999-08-20 | 2001-03-19 | Basf Plant Science Gmbh | Increasing the polysaccharide content in plants |
US6423886B1 (en) | 1999-09-02 | 2002-07-23 | Pioneer Hi-Bred International, Inc. | Starch synthase polynucleotides and their use in the production of new starches |
US6472588B1 (en) | 1999-09-10 | 2002-10-29 | Texas Tech University | Transgenic cotton plants with altered fiber characteristics transformed with a sucrose phosphate synthase nucleic acid |
GB9921830D0 (en) | 1999-09-15 | 1999-11-17 | Nat Starch Chem Invest | Plants having reduced activity in two or more starch-modifying enzymes |
AR025996A1 (es) | 1999-10-07 | 2002-12-26 | Valigen Us Inc | Plantas no transgenicas resistentes a los herbicidas. |
US6509516B1 (en) | 1999-10-29 | 2003-01-21 | Plant Genetic Systems N.V. | Male-sterile brassica plants and methods for producing same |
US6506963B1 (en) | 1999-12-08 | 2003-01-14 | Plant Genetic Systems, N.V. | Hybrid winter oilseed rape and methods for producing same |
US6395485B1 (en) | 2000-01-11 | 2002-05-28 | Aventis Cropscience N.V. | Methods and kits for identifying elite event GAT-ZM1 in biological samples |
CA2401093A1 (fr) | 2000-03-09 | 2001-09-13 | Monsanto Technology Llc | Procedes permettant de rendre des plantes tolerantes au glyphosate et compositions associees |
WO2001065922A2 (fr) | 2000-03-09 | 2001-09-13 | E. I. Du Pont De Nemours And Company | Tournesols tolerants a la sulfonyluree |
US6768044B1 (en) | 2000-05-10 | 2004-07-27 | Bayer Cropscience Sa | Chimeric hydroxyl-phenyl pyruvate dioxygenase, DNA sequence and method for obtaining plants containing such a gene, with herbicide tolerance |
BRPI0100752B1 (pt) | 2000-06-22 | 2015-10-13 | Monsanto Co | moléculas e pares de moléculas de dna, processos para detectar molécula de dna e para criar um traço tolerante a glifosato em plantas de milho, bem como kit de detecção de dna |
US6713259B2 (en) | 2000-09-13 | 2004-03-30 | Monsanto Technology Llc | Corn event MON810 and compositions and methods for detection thereof |
JP2004528808A (ja) | 2000-09-29 | 2004-09-24 | シンジェンタ リミテッド | 除草剤抵抗性植物 |
US6660690B2 (en) | 2000-10-06 | 2003-12-09 | Monsanto Technology, L.L.C. | Seed treatment with combinations of insecticides |
US6734340B2 (en) | 2000-10-23 | 2004-05-11 | Bayer Cropscience Gmbh | Monocotyledon plant cells and plants which synthesise modified starch |
AR031027A1 (es) | 2000-10-23 | 2003-09-03 | Syngenta Participations Ag | Composiciones agroquimicas |
AU2002215363B2 (en) | 2000-10-25 | 2006-10-12 | Monsanto Technology Llc | Cotton event PV-GHGT07(1445) and compositions and methods for detection thereof |
CA2425956C (fr) | 2000-10-30 | 2014-12-23 | Maxygen, Inc. | Nouveaux genes glyphosate n-acetyltransferase (gat) |
ATE509110T1 (de) | 2000-10-30 | 2011-05-15 | Monsanto Technology Llc | Canola event pv-bngt(rt73), zusammensetzungen und verfahren zum nachweis davon |
FR2815969B1 (fr) | 2000-10-30 | 2004-12-10 | Aventis Cropscience Sa | Plantes tolerantes aux herbicides par contournement de voie metabolique |
AU2004260931B9 (en) | 2003-04-29 | 2012-01-19 | E.I. Du Pont De Nemours And Company | Novel glyphosate-N-acetyltransferase (GAT) genes |
AR035215A1 (es) | 2000-11-20 | 2004-05-05 | Monsanto Technology Llc | Polinucleotido aislado, primer y segundo polinucleotido cebador, metodo para detectar el suceso vegetal de algodon 531, molecula de polinucleotido aislado obtenida por dicho metodo, equipo de deteccion de acido nucleico y metodo para determinar la cigosidad del genoma de una planta de algodon. |
WO2002044407A2 (fr) | 2000-11-30 | 2002-06-06 | Ses Europe N.V. | Séquence des flancs de t227-1 |
ES2400699T3 (es) | 2000-12-07 | 2013-04-11 | Syngenta Limited | HIDROXI-FENIL PIRUVATO DIOXIGENASAS (HPPD) derivadas de plantas y resistentes frenta a herbicidas tricetónicos, y plantas transgénicas que contienen DIOXIGENASAS |
WO2002045485A1 (fr) | 2000-12-08 | 2002-06-13 | Commonwealth Scienctific And Industrial Research Organisation | Modification de l'expression genetique de la sucrose synthase dans le tissu vegetal et ses applications |
US20020134012A1 (en) | 2001-03-21 | 2002-09-26 | Monsanto Technology, L.L.C. | Method of controlling the release of agricultural active ingredients from treated plant seeds |
AU2002338233A1 (en) | 2001-03-30 | 2002-10-15 | Basf Plant Science Gmbh | Glucan chain length domains |
EG26529A (en) | 2001-06-11 | 2014-01-27 | مونسانتو تكنولوجى ل ل سى | Prefixes for detection of DNA molecule in cotton plant MON15985 which gives resistance to damage caused by insect of squamous lepidoptera |
CA2465884A1 (fr) | 2001-06-12 | 2002-12-19 | Bayer Cropscience Gmbh | Plantes transgeniques synthetisant de l'amidon riche en amylose |
US6818807B2 (en) | 2001-08-06 | 2004-11-16 | Bayer Bioscience N.V. | Herbicide tolerant cotton plants having event EE-GH1 |
AU2002322435A1 (en) | 2001-08-09 | 2003-02-24 | Cibus Genetics | Non-transgenic herbicide resistant plants |
WO2003033540A2 (fr) | 2001-10-17 | 2003-04-24 | Basf Plant Science Gmbh | Amidon |
AU2002361696A1 (en) | 2001-12-17 | 2003-06-30 | Syngenta Participations Ag | Novel corn event |
DE10208132A1 (de) | 2002-02-26 | 2003-09-11 | Planttec Biotechnologie Gmbh | Verfahren zur Herstellung von Maispflanzen mit erhöhtem Blattstärkegehalt und deren Verwendung zur Herstellung von Maissilage |
AU2003234328A1 (en) | 2002-04-30 | 2003-11-17 | Pioneer Hi-Bred International, Inc. | Novel glyphosate-n-acetyltransferase (gat) genes |
UA87808C2 (ru) | 2002-07-29 | 2009-08-25 | Монсанто Текнолоджи, Ллс | Зерновые растения pv-zmir13 (mon863) и композиции и способы их обнаружения |
FR2844142B1 (fr) | 2002-09-11 | 2007-08-17 | Bayer Cropscience Sa | Plantes transformees a biosynthese de prenylquinones amelioree |
US20040142353A1 (en) | 2002-10-29 | 2004-07-22 | Cheung Wing Y. | Compositions and methods for identifying plants having increased tolerance to imidazolinone herbicides |
GB0225129D0 (en) | 2002-10-29 | 2002-12-11 | Syngenta Participations Ag | Improvements in or relating to organic compounds |
US20040110443A1 (en) | 2002-12-05 | 2004-06-10 | Pelham Matthew C. | Abrasive webs and methods of making the same |
EP1567000A4 (fr) | 2002-12-05 | 2007-09-05 | Monsanto Technology Llc | Evenement associe a l'agrostide asr-368 et compositions et procedes de detection de la presence de celle-ci |
US7714186B2 (en) | 2002-12-19 | 2010-05-11 | Bayer Cropscience Ag | Plant cells and plants which synthesize a starch with an increased final viscosity |
WO2004072235A2 (fr) | 2003-02-12 | 2004-08-26 | Monsanto Technology Llc | Evenement mon 88913 de plant de coton et procedes de detection correspondants |
US7335816B2 (en) | 2003-02-28 | 2008-02-26 | Kws Saat Ag | Glyphosate tolerant sugar beet |
PT1597373E (pt) | 2003-02-20 | 2012-09-27 | Kws Saat Ag | Beterraba açucareira tolerante a glifosato |
US20060162021A1 (en) | 2003-03-07 | 2006-07-20 | Basf Plant Science Gmbh | Enhanced amylose production in plants |
MXPA05010296A (es) | 2003-03-26 | 2005-11-17 | Bayer Cropscience Gmbh | Utilizacion de compuestos hidroxilicos aromaticos como antidotos. |
EP1616013B1 (fr) | 2003-04-09 | 2011-07-27 | Bayer BioScience N.V. | Procedes et elements destines a augmenter la tolerance de plantes par rapport a des conditions de stress |
EP1620571B1 (fr) | 2003-05-02 | 2015-07-01 | Dow AgroSciences LLC | Mais tc1507 et procedes de detection de celui-ci |
CA2526480A1 (fr) | 2003-05-22 | 2005-01-13 | Syngenta Participations Ag | Amidon modifie, ses utilisations, ses procedes de production |
US9382526B2 (en) | 2003-05-28 | 2016-07-05 | Basf Aktiengesellschaft | Wheat plants having increased tolerance to imidazolinone herbicides |
EP1493328A1 (fr) | 2003-07-04 | 2005-01-05 | Institut National De La Recherche Agronomique | Production des lignées B. napus double zéro restauratrices avec une bonne qualité agronomique |
US7547819B2 (en) | 2003-07-31 | 2009-06-16 | Toyo Boseki Kabushiki Kaisha | Plant producing hyaluronic acid |
DE10335726A1 (de) | 2003-08-05 | 2005-03-03 | Bayer Cropscience Gmbh | Verwendung von Hydroxyaromaten als Safener |
DE10335725A1 (de) | 2003-08-05 | 2005-03-03 | Bayer Cropscience Gmbh | Safener auf Basis aromatisch-aliphatischer Carbonsäuredarivate |
EP1692285B1 (fr) | 2003-08-15 | 2012-04-11 | Commonwealth Scientific and Industrial Research Organisation | Procedes et moyens d'alteration des caracteristiques des fibres dans des plantes produisant des fibres |
EP2982240B1 (fr) | 2003-08-29 | 2019-07-31 | Instituto Nacional de Tecnologia Agropecuaria | Plants de riz présentant une tolérance accrue aux herbicides d'imidazolinone |
EP1687417B9 (fr) | 2003-09-30 | 2011-03-30 | Bayer CropScience AG | Vegetaux ayant une activite reduite de l'enzyme de ramification de classe 3 |
AR046090A1 (es) | 2003-09-30 | 2005-11-23 | Bayer Cropscience Gmbh | Plantas con actividad aumentada de una enzima de ramificacion de la clase 3 |
WO2005054480A2 (fr) | 2003-12-01 | 2005-06-16 | Syngenta Participations Ag | Plants de coton resistant aux insectes et procedes de detection de ces derniers |
CN1886513A (zh) | 2003-12-01 | 2006-12-27 | 先正达公司 | 昆虫抗性棉花植株及对其进行探测的方法 |
US7157281B2 (en) | 2003-12-11 | 2007-01-02 | Monsanto Technology Llc | High lysine maize compositions and event LY038 maize plants |
WO2005059103A2 (fr) | 2003-12-15 | 2005-06-30 | Monsanto Technology Llc | Plant de mais mon88017, compositions et procedes de detection associes |
GB0402106D0 (en) | 2004-01-30 | 2004-03-03 | Syngenta Participations Ag | Improved fertility restoration for ogura cytoplasmic male sterile brassica and method |
ATE541042T1 (de) | 2004-03-05 | 2012-01-15 | Bayer Cropscience Ag | Pflanzen mit reduzierter aktivität des stärkephosphorylierenden enzyms phosphoglucan- wasser-dikinase |
AR048026A1 (es) | 2004-03-05 | 2006-03-22 | Bayer Cropscience Gmbh | Procedimientos para la identificacion de proteinas con actividad enzimatica fosforiladora de almidon |
AR048024A1 (es) | 2004-03-05 | 2006-03-22 | Bayer Cropscience Gmbh | Plantas con actividad aumentada de distintas enzimas fosforilantes del almidon |
AR048025A1 (es) | 2004-03-05 | 2006-03-22 | Bayer Cropscience Gmbh | Plantas con actividad aumentada de una enzima fosforilante del almidon |
US7432082B2 (en) | 2004-03-22 | 2008-10-07 | Basf Ag | Methods and compositions for analyzing AHASL genes |
CN102260668B (zh) | 2004-03-25 | 2016-08-10 | 辛根塔参与股份公司 | 玉米事件mir604 |
EP2333082B1 (fr) | 2004-03-26 | 2015-01-07 | Dow AgroSciences LLC | Lignées de coton transgéniques Cry1F et Cry1AC et leur identification spécifique à l'événement |
DE102004023332A1 (de) | 2004-05-12 | 2006-01-19 | Bayer Cropscience Gmbh | Chinoxalin-2-on-derivate, diese enthaltende nutzpflanzenschützende Mittel und Verfahren zu ihrer Herstellung und deren Verwendung |
AU2005262525A1 (en) | 2004-06-16 | 2006-01-19 | Basf Plant Science Gmbh | Polynucleotides encoding mature AHASL proteins for creating imidazolinone-tolerant plants |
DE102004029763A1 (de) | 2004-06-21 | 2006-01-05 | Bayer Cropscience Gmbh | Pflanzen, die Amylopektin-Stärke mit neuen Eigenschaften herstellen |
TR200900517T2 (tr) | 2004-07-30 | 2009-03-23 | Basf Agrochemical Products B.V. | Herbisitlere dayanıklı ayçiçeği bitkileri herbisitlere dayanıklı asetohidroksiasit sintaz geniş altünite proteinlerini kodla yan polinükleotidler ve kullanma metotları. |
JP2008508884A (ja) | 2004-08-04 | 2008-03-27 | ビーエーエスエフ プラント サイエンス ゲーエムベーハー | 単子葉植物ahassの配列および使用方法 |
WO2006018319A1 (fr) | 2004-08-18 | 2006-02-23 | Bayer Cropscience Gmbh | Vegetaux a activite plastidique accrue de l'enzyme r3 de phosphorylation de l'amidon |
US8030548B2 (en) | 2004-08-26 | 2011-10-04 | Dhara Vegetable Oil And Foods Company Limited | Cytoplasmic male sterility system for Brassica species and its use for hybrid seed production in indian oilseed mustard Brassica juncea |
SI1805312T1 (sl) | 2004-09-23 | 2009-12-31 | Bayer Cropscience Ag | Postopki in sredstva za izdelavo hialuronana |
US7851675B2 (en) | 2004-09-24 | 2010-12-14 | Bayer Bioscience N.V. | Stress resistant plants |
AU2005292090B2 (en) | 2004-09-29 | 2011-02-03 | Corteva Agriscience Llc | Corn event DAS-59122-7 and methods for detection thereof |
MX2007005166A (es) | 2004-10-29 | 2007-06-26 | Bayer Bioscience Nv | Plantas de algodon tolerantes a la agresion. |
AR051690A1 (es) | 2004-12-01 | 2007-01-31 | Basf Agrochemical Products Bv | Mutacion implicada en el aumento de la tolerancia a los herbicidas imidazolinona en las plantas |
EP1672075A1 (fr) | 2004-12-17 | 2006-06-21 | Bayer CropScience GmbH | Plantes transformées exprimant un dextrane sucrase et synthétisant un amidon modifie |
EP1679374A1 (fr) | 2005-01-10 | 2006-07-12 | Bayer CropScience GmbH | Plantes transformées exprimant un mutane sucrase et synthétisant un amidon modifie |
EP1868426B1 (fr) | 2005-03-16 | 2018-02-21 | Syngenta Participations AG | Mais 3272 et procedes pour le detecter |
JP2006304779A (ja) | 2005-03-30 | 2006-11-09 | Toyobo Co Ltd | ヘキソサミン高生産植物 |
EP1707632A1 (fr) | 2005-04-01 | 2006-10-04 | Bayer CropScience GmbH | Amidon de pomme de terre cireux phosphorylé |
CA2603944C (fr) | 2005-04-08 | 2015-06-23 | Bayer Bioscience N.V. | Evenement elite a2704-12 comprenant l'integration du gene phosphinothri cine acetyltransferase dans le soya et procedes et trousses permettant d'identifier cet evenement dans des prelevements biologiques |
EP1710315A1 (fr) | 2005-04-08 | 2006-10-11 | Bayer CropScience GmbH | Amidon à forte teneur en phosphate |
PT1871901E (pt) | 2005-04-11 | 2011-09-29 | Bayer Bioscience Nv | Acontecimento elite a5547-127 e processos e kits para identificar um tal acontecimento em amostras biológicas |
AP2693A (en) | 2005-05-27 | 2013-07-16 | Monsanto Technology Llc | Soybean event MON89788 and methods for detection thereof |
JP5832062B2 (ja) | 2005-05-31 | 2015-12-16 | デフヘン・ナムローゼ・フェンノートシャップDEVGEN nv | 昆虫及びクモの防除のためのRNAi |
BRPI0611508A2 (pt) | 2005-06-02 | 2010-09-14 | Syngenta Participations Ag | algodão inseticida ce44-69d |
WO2006128568A2 (fr) | 2005-06-02 | 2006-12-07 | Syngenta Participations Ag | Coton insecticide t342-142 |
WO2006128569A2 (fr) | 2005-06-02 | 2006-12-07 | Syngenta Participations Ag | Coton insecticide 1143-14a |
WO2006128570A1 (fr) | 2005-06-02 | 2006-12-07 | Syngenta Participations Ag | Coton insecticide 1143-51b |
WO2006128572A1 (fr) | 2005-06-02 | 2006-12-07 | Syngenta Participations Ag | Coton insecticide ce46-02a |
BRPI0611504A2 (pt) | 2005-06-02 | 2010-09-08 | Syngenta Participations Ag | algodão inseticida ce43-67b |
ES2331022T3 (es) | 2005-06-15 | 2009-12-18 | Bayer Bioscience N.V. | Metodos para aumentar la resistencia de las plantas a condiciones hipoxicas. |
AU2006261276B2 (en) | 2005-06-24 | 2011-09-22 | Bayer Cropscience Nv. | Methods for altering the reactivity of plant cell walls |
AR054174A1 (es) | 2005-07-22 | 2007-06-06 | Bayer Cropscience Gmbh | Sobreexpresion de sintasa de almidon en vegetales |
EP1922409B1 (fr) | 2005-08-08 | 2017-11-08 | Bayer CropScience NV | Cotonniers tolérants aux herbicides et leurs procédés d'identification |
WO2007023719A1 (fr) | 2005-08-22 | 2007-03-01 | Kumiai Chemical Industry Co., Ltd. | Agent servant à réduire l'attaque chimique et composition herbicide produisant une attaque chimique réduite |
AR055128A1 (es) | 2005-08-24 | 2007-08-08 | Du Pont | Metodos y composiciones para la expresion de un polinucleotido de interes |
WO2007023764A1 (fr) | 2005-08-26 | 2007-03-01 | Kumiai Chemical Industry Co., Ltd. | Agent servant à réduire les effets nocifs d’un herbicide et composition d’herbicide ayant des effets nocifs réduits |
KR101156893B1 (ko) | 2005-08-31 | 2012-06-21 | 몬산토 테크놀로지 엘엘씨 | 살충 단백질을 암호화하는 뉴클레오티드 서열들 |
AU2006329563B2 (en) | 2005-09-16 | 2014-02-20 | Devgen Nv | dsRNA as insect control agent |
EP3508582B1 (fr) | 2005-09-16 | 2021-01-13 | Monsanto Technology LLC | Procédés de contrôle génétique d'infestation d'insectes dans des plantes et compositions correspondantes |
CA2624496A1 (fr) | 2005-10-05 | 2007-04-12 | Bayer Cropscience Ag | Plantes a production accrue de hyaluronane ii |
CA2624973C (fr) | 2005-10-05 | 2016-01-19 | Bayer Cropscience Ag | Production de hyaluronan a partir de plantes transgeniques pour la synthase de l'hyaluronan, la glutamine fructose-6-phosphate amidotransferase et la deshydrogenase de glucose de diphosphate d'uridine |
PL1951878T3 (pl) | 2005-10-05 | 2015-07-31 | Bayer Ip Gmbh | Rośliny o zwiększonym wytwarzaniu hialuronianu |
WO2011066360A1 (fr) | 2009-11-24 | 2011-06-03 | Dow Agrosciences Llc | Détection de l'événement 416 du soja aad-12 |
CA2627795C (fr) | 2006-01-12 | 2019-01-22 | Devgen N.V. | Procedes destines a lutter contre des parasites au moyen d'arni |
EP1971687A2 (fr) | 2006-01-12 | 2008-09-24 | Devgen NV | L'arn a double brin pour la lutte contre les insectes |
CN101421404A (zh) | 2006-02-10 | 2009-04-29 | 马哈拉施特拉杂交种子有限公司 | 表达cry1ac基因的转基因茄子(solanum melongena) |
US20070214515A1 (en) | 2006-03-09 | 2007-09-13 | E.I.Du Pont De Nemours And Company | Polynucleotide encoding a maize herbicide resistance gene and methods for use |
WO2007107302A2 (fr) | 2006-03-21 | 2007-09-27 | Bayer Bioscience N.V. | Nouveaux gènes codant pour des protéines à action insecticide |
MX2008012058A (es) | 2006-03-21 | 2008-10-03 | Bayer Bioscience Nv | Plantas resistes al estres. |
WO2007131699A2 (fr) | 2006-05-12 | 2007-11-22 | Bayer Bioscience N.V. | Nouvelles molécules de micro-arn liées au stress et leurs utilisations |
EP2021476B1 (fr) | 2006-05-26 | 2014-07-09 | Monsanto Technology, LLC | Plant et semence de maïs correspondant au produit transgénique mon89034, procédés de détection et utilisation associés |
AP2726A (en) | 2006-06-03 | 2013-08-31 | Syngenta Participations Ag | Corn event MIR 162 |
US7951995B2 (en) | 2006-06-28 | 2011-05-31 | Pioneer Hi-Bred International, Inc. | Soybean event 3560.4.3.5 and compositions and methods for the identification and detection thereof |
EP1887079A1 (fr) | 2006-08-09 | 2008-02-13 | Bayer CropScience AG | Plante genetiquement modifié pour synthetiser d'amidon avec un pouvoir de gonfler elevé |
US7928295B2 (en) | 2006-08-24 | 2011-04-19 | Bayer Bioscience N.V. | Herbicide tolerant rice plants and methods for identifying same |
US20080064032A1 (en) | 2006-09-13 | 2008-03-13 | Syngenta Participations Ag | Polynucleotides and uses thereof |
US7928296B2 (en) | 2006-10-30 | 2011-04-19 | Pioneer Hi-Bred International, Inc. | Maize event DP-098140-6 and compositions and methods for the identification and/or detection thereof |
US7897846B2 (en) | 2006-10-30 | 2011-03-01 | Pioneer Hi-Bred Int'l, Inc. | Maize event DP-098140-6 and compositions and methods for the identification and/or detection thereof |
BR122017006111B8 (pt) | 2006-10-31 | 2022-12-06 | Du Pont | Métodos para controlar ervas daninhas |
AR064558A1 (es) | 2006-12-29 | 2009-04-08 | Bayer Cropscience Sa | Proceso para la modificacion de las propiedades termicas y de digestion de almidones de maiz y harinas de maiz |
AR064557A1 (es) | 2006-12-29 | 2009-04-08 | Bayer Cropscience Ag | Almidon de maiz y harinas y alimentos de maiz que comprenden este almidon de maiz |
EP1950303A1 (fr) | 2007-01-26 | 2008-07-30 | Bayer CropScience AG | Plantes génétiquement modifiées synthétisant un amidon à teneur réduite en amylose et à capacité de gonflement augmentée |
WO2008114282A2 (fr) | 2007-03-19 | 2008-09-25 | Maharashtra Hybrid Seeds Company Limited | Riz transgénique (oryza sativa) comprenant l'événement pe-7 et son procédé de détection |
CN103773863A (zh) | 2007-04-05 | 2014-05-07 | 拜尔作物科学公司 | 抗虫棉花植物及其鉴定方法 |
EP1987717A1 (fr) | 2007-04-30 | 2008-11-05 | Bayer CropScience AG | Pyridinecarboxamide, agent phytoprotecteur la comportant, son procédé de fabrication et son utilisation |
EP1987718A1 (fr) | 2007-04-30 | 2008-11-05 | Bayer CropScience AG | Utilisation de pyridine-2-oxy-3-carbonamides en tant que phytoprotecteur |
BRPI0812785A2 (pt) | 2007-05-30 | 2014-10-07 | Syngenta Participations Ag | Genes de citocromo p450 que conferem resistência à herbicida |
DE102007026875A1 (de) | 2007-06-11 | 2008-12-24 | Bayer Cropscience Ag | 3-Cyclopropyl-4-(3-thiobenzoyl)pyrazole und ihre Verwendung als Herbizide |
EP2615173B1 (fr) | 2007-06-11 | 2020-09-16 | Basf Agricultural Solutions Seed Us Llc | Cotonniers résistants aux insectes et procédés d'identification associés |
JP5300225B2 (ja) | 2007-08-03 | 2013-09-25 | バイエル・クロップサイエンス・アーゲー | 除草剤トリアゾリルピリジンケトン類 |
CN101861392B (zh) | 2007-11-15 | 2016-01-20 | 孟山都技术公司 | 对应于转基因事件mon87701的大豆植物和种子及其检测方法 |
ES2543425T3 (es) | 2007-11-28 | 2015-08-19 | Bayer Cropscience Nv | Planta de Brassica que comprende un alelo INDEHISCENT mutante |
WO2009100188A2 (fr) | 2008-02-08 | 2009-08-13 | Dow Agrosciences Llc | Procédés de détection de l’événement de maïs das-59132 |
BRPI0908831A2 (pt) | 2008-02-14 | 2015-08-04 | Pioneer Hi Bred Int | Métodos para identificar o evento e6611.32.1.38 em amostra biológica, para detectar a presença do evento e6611.32.1.38 ou a progênie deste em uma amostra biológica, para detectar a presença de dna correspondente ao evento e6611.32.1.38 em uma amostra, para selecionar sementes com a presença do evento e6611.32.1.38, molécula de dna isolada, sequência de nucleotídeos de primer de dna, par de sequências de dna isoladas, planta, célula, tecido, semente transgênicos ou partes destes contendo dna. |
CA2712445C (fr) | 2008-02-15 | 2018-11-06 | Monsanto Technology Llc | Plante de soja et graine correspondant a l'evenement transgenique mon87769 et leurs procedes de detection |
MX341747B (es) | 2008-02-29 | 2016-08-31 | Monsanto Technology Llc | Evento de maiz mon87460 y composiciones y metodos para detectarlo. |
CN101998993A (zh) | 2008-04-14 | 2011-03-30 | 拜耳生物科学股份有限公司 | 新的突变羟基苯基丙酮酸双加氧酶,dna序列和耐受hppd抑制剂除草剂的植物分离 |
MX349774B (es) | 2008-05-26 | 2017-08-10 | Bayer Cropscience Nv | Metodos y medios para modificar la resistencia de las fibras en plantas que producen fibras. |
BRPI0914615A2 (pt) | 2008-06-13 | 2016-09-06 | Bayer Bioscience Nv | administração de resistência de inseto de lagarta em plantas transgênicas |
EP2143797A1 (fr) | 2008-07-10 | 2010-01-13 | Bayer CropScience AG | Amidon de blé ainsi que farines de blé et aliments contenant cet amidon de blé/cette farine de blé |
CA2730859C (fr) | 2008-07-17 | 2023-01-24 | Bayer Bioscience N.V. | Plante brassica comprenant un allele indehiscent mutant |
BRPI0911744A2 (pt) | 2008-08-01 | 2015-08-18 | Bayer Bioscience Nv | "método para aumentar a produção de biomassa e/ou a produção de sementes e/ou a fixação de carbono em plantas de arroz, planta de arroz, transgênico, semente de arroz, grão de arroz, farinha e produto alimentício" |
US9078406B2 (en) | 2008-08-29 | 2015-07-14 | Monsanto Technology Llc | Soybean plant and seed corresponding to transgenic event MON87754 and methods for detection thereof |
MX356687B (es) | 2008-09-29 | 2018-06-07 | Monsanto Technology Llc | Evento transgénico de frijol de soya mon87705 y métodos para detección del mismo. |
MX2011006292A (es) | 2008-12-16 | 2011-06-27 | Syngenta Participations Ag | Evento 5307 del maiz. |
WO2010076212A1 (fr) | 2008-12-19 | 2010-07-08 | Syngenta Participations Ag | Événement de betterave sucrière transgénique gm rz13 |
CN104789649A (zh) | 2009-01-07 | 2015-07-22 | 巴斯夫农化产品有限公司 | 大豆事件127和与其相关的方法 |
US20110203528A1 (en) | 2009-01-08 | 2011-08-25 | Doskocil Manufacturing Company, Inc. | Pet housing enclosure |
CN102448288B (zh) | 2009-03-30 | 2015-07-15 | 孟山都技术公司 | 转基因水稻事件17314及其使用方法 |
WO2010117737A1 (fr) | 2009-03-30 | 2010-10-14 | Monsanto Technology Llc | Evénement de riz transgénique 17053 et ses procédés d'utilisation |
AU2010241154A1 (en) | 2009-04-22 | 2011-10-27 | Bayer Bioscience N.V. | Production of multi-antennary N-glycan structures in plants |
JP5925677B2 (ja) | 2009-06-15 | 2016-06-01 | アイコン・ジェネティクス・ゲーエムベーハー | キシロシルトランスフェラーゼ活性の欠損したベンサミアナタバコ(Nicotianabenthamiana)植物 |
JP2012531216A (ja) | 2009-07-01 | 2012-12-10 | バイエル・クロップサイエンス・エヌ・ヴェー | グリホサート耐性が増強された植物を得るための方法および手段 |
ES2609332T3 (es) | 2009-07-02 | 2017-04-19 | Athenix Corporation | Gen pesticida AXMI-205 y métodos para su uso |
KR101746545B1 (ko) | 2009-07-29 | 2017-06-13 | 바이엘 인텔렉쳐 프로퍼티 게엠베하 | 4-벤조일피라졸 및 제초제로서의 그의 용도 |
MX354219B (es) | 2009-07-31 | 2018-02-19 | Athenix Corp | Familia de genes plaguicidas axmi-192 y metodos para su uso. |
CN102573452B (zh) | 2009-08-19 | 2015-07-22 | 陶氏益农公司 | Aad-1事件das-40278-9、相关的转基因玉米品系及其事件特异性鉴定 |
CN107779520A (zh) | 2009-09-17 | 2018-03-09 | 孟山都技术公司 | 大豆转基因事件mon 87708及其使用方法 |
SI2501804T1 (sl) | 2009-11-20 | 2016-09-30 | Bayer Cropscience Nv | Rastline Brassice, ki vsebujejo mutirane FAD3 alele |
WO2011063413A2 (fr) | 2009-11-23 | 2011-05-26 | Bayer Bioscience N.V. | Plantes de soja tolérant un herbicide et leurs procédés d'identification |
BR112012012404B1 (pt) | 2009-11-23 | 2019-03-06 | Monsanto Technology Llc | "molécula de dna reconbinante de amplicon, sonda de dna, par de moléculas de dna mètodo para detectar a presença de uma molècula de dna e kit de detecçao de dna". |
CA2781375C (fr) | 2009-11-24 | 2020-05-05 | Dow Agrosciences Llc | Evenement 416 de la transformation aad-12, lignees de soja transgeniques associees, et leur identification specifique a l'evenement |
US8581046B2 (en) | 2010-11-24 | 2013-11-12 | Pioneer Hi-Bred International, Inc. | Brassica gat event DP-073496-4 and compositions and methods for the identification and/or detection thereof |
US20110154525A1 (en) | 2009-12-17 | 2011-06-23 | Pioneer Hi-Bred International, Inc. | Maize event DP-040416-8 and methods for detection thereof |
WO2011075595A1 (fr) | 2009-12-17 | 2011-06-23 | Pioneer Hi-Bred International, Inc. | Maïs dp-043a47-3 et procédés de détection associés |
US20110154524A1 (en) | 2009-12-17 | 2011-06-23 | Pioneer Hi-Bred International, Inc. | Maize event DP-032316-8 and methods for detection thereof |
PL2512226T3 (pl) | 2009-12-17 | 2019-10-31 | Pioneer Hi Bred Int | Modyfikacja DP-004114-3 kukurydzy i sposoby jej wykrywania |
EA201290546A1 (ru) | 2009-12-22 | 2013-05-30 | Байер Кропсайенс Нв | Устойчивые к гербицидам растения |
CA2785225C (fr) | 2009-12-23 | 2019-01-22 | Bayer Intellectual Property Gmbh | Plantes tolerantes aux herbicides inhibiteurs de hppd. |
ES2668198T3 (es) | 2009-12-23 | 2018-05-17 | Bayer Intellectual Property Gmbh | Plantas tolerantes a herbicidas inhibidores de HPPD |
EA201290560A1 (ru) | 2009-12-23 | 2014-05-30 | Байер Интеллектуэль Проперти Гмбх | Растения, устойчивые к гербицидам - ингибиторам hppd |
BR112012015697A2 (pt) | 2009-12-23 | 2015-08-25 | Bayer Intelectual Property Gmbh | Plantas tolerantes a herbicidas inibidores de hppd. |
AR079972A1 (es) | 2009-12-23 | 2012-03-07 | Bayer Cropscience Ag | Plantas tolerantes a herbicidas inhibidores de las hppd |
CN102770544B (zh) | 2010-01-25 | 2015-04-15 | 拜尔作物科学公司 | 制备包含几丁质的植物细胞壁的方法 |
WO2011095528A1 (fr) | 2010-02-04 | 2011-08-11 | Bayer Cropscience Ag | Procédé d'accroissement de la fixation de carbone photosynthétique faisant appel à une protéine de fusion multi sous-unitaire de type glycolate déshydrogénase |
CN102892886A (zh) | 2010-02-18 | 2013-01-23 | 阿森尼克斯公司 | AXMI218、AXMI219、AXMI220、AXMI226、AXMI227、AXMI228、AXMI229、AXMI230、和AXMI231δ-内毒素基因以及它们的使用方法 |
EP2536267B1 (fr) | 2010-02-18 | 2015-07-22 | Athenix Corp. | Gènes de delta-endotoxine axmi221z, axmi222z, axmi223z, axmi224z, et axmi225z et leurs procédés d'utilisation |
CN101838227A (zh) | 2010-04-30 | 2010-09-22 | 孙德群 | 一种苯甲酰胺类除草剂的安全剂 |
NZ603506A (en) | 2010-06-04 | 2013-11-29 | Monsanto Technology Llc | Transgenic brassica event mon 88302 and methods of use thereof |
WO2012033794A2 (fr) | 2010-09-08 | 2012-03-15 | Dow Agrosciences Llc | Événement 1606 d'aad-12 et lignées de soja transgénique associées |
WO2012051199A2 (fr) | 2010-10-12 | 2012-04-19 | Monsanto Technology Llc | Plante et semence de soja correspondant à l'événement transgénique mon87712 et procédé pour les détecter |
BR112013010278B1 (pt) | 2010-10-27 | 2020-12-29 | Ceres, Inc | método para produzir uma planta, método para modular a composição de biomassa em uma planta, ácido nucleico isolado e método para alterar a composição de biomassa em uma planta |
WO2012071039A1 (fr) | 2010-11-24 | 2012-05-31 | Pioner Hi-Bred International, Inc. | Événement dp-061061-7 de brassica gat et compositions et procédés pour l'identifier et/ou le détecter |
WO2012074868A2 (fr) | 2010-12-03 | 2012-06-07 | Ms Technologies, Llc | Expression optimisée de molécules d'acide nucléique codant pour la résistance au glyphosate dans cellules végétales |
CA2819684C (fr) | 2010-12-03 | 2024-05-07 | Dow Agrosciences Llc | Evenement 8264.44.06.1 de tolerance aux herbicides empile, lignees de soja transgeniques apparentees, et sa detection |
WO2012075429A1 (fr) | 2010-12-03 | 2012-06-07 | Dow Agrosciences Llc | Événement 8291.45.36.2 de tolérance aux herbicides empilé, lignées de soja transgéniques apparentées, et sa détection |
TWI667347B (zh) | 2010-12-15 | 2019-08-01 | 瑞士商先正達合夥公司 | 大豆品種syht0h2及偵測其之組合物及方法 |
US9695440B2 (en) | 2011-03-30 | 2017-07-04 | Athenix Corp. | AXMI232, AXMI233, and AXMI249 toxin genes and methods for their use |
US9321814B2 (en) | 2011-03-30 | 2016-04-26 | Athenix Corp. | AXMI238 toxin gene and methods for its use |
CN103597079B (zh) | 2011-03-30 | 2017-04-05 | 孟山都技术公司 | 棉花转基因事件mon88701及其使用方法 |
CA2832197A1 (fr) | 2011-05-04 | 2012-11-08 | Bayer Intellectual Property Gmbh | Mutants de b. napus tolerants a un herbicide inhibiteur de l'als |
CA2840630C (fr) | 2011-06-30 | 2021-11-30 | Monsanto Technology Llc | Plante et graine de luzerne correspondant a l'evenement transgenique kk 179-2 et procedes pour la detection de celui-ci |
EP2731419A4 (fr) | 2011-07-13 | 2015-04-29 | Dow Agrosciences Llc | Événement 8264.42.32.1 « empilé » de tolérance aux herbicides, lignées de soja transgénique associées et détection dudit événément |
WO2013012643A1 (fr) | 2011-07-15 | 2013-01-24 | Syngenta Participations Ag | Polynucléotides codant pour la tréhalose-6-phosphate phosphatase et procédés d'utilisation de ceux-ci |
BR102012019434B1 (pt) | 2011-07-26 | 2021-11-09 | Dow Agrosciences Llc | Métodos de controle de pestes, de insetos, molécula e sequência de dna diagnóstica para o evento de soja 9582.814.19.1 |
CA2842833A1 (fr) | 2011-07-28 | 2013-01-31 | Genective | Evenement de mais tolerant au glyphosate vco-o1981-5 et kit et procede pour detecter celui-ci |
US8759618B2 (en) | 2011-08-17 | 2014-06-24 | Stine Seed Farm, Inc. | Maize event HCEM485, compositions and methods for detecting and use thereof |
BR112014003919A2 (pt) | 2011-08-22 | 2017-03-14 | Bayer Cropscience Ag | métodos e meios para modificar um genoma de planta |
AU2012320554B2 (en) | 2011-10-04 | 2017-11-09 | Bayer Intellectual Property Gmbh | RNAi for the control of fungi and oomycetes by inhibiting saccharopine dehydrogenase gene |
WO2013053730A1 (fr) | 2011-10-12 | 2013-04-18 | Bayer Cropscience Ag | Plantes ayant une activité réduite d'une enzyme de déphosphorylation de l'amidon |
CA2851563A1 (fr) | 2011-10-12 | 2013-04-18 | Bayer Cropscience Ag | Plantes ayant une activite diminuee d'une enzyme de dephosphorylation de l'amidon |
AR089251A1 (es) | 2011-12-22 | 2014-08-06 | Bayer Ip Gmbh | Plantas tolerantes a herbicidas inhibidores de hppd |
WO2013092551A1 (fr) | 2011-12-22 | 2013-06-27 | Bayer Intellectual Property Gmbh | Plantes tolérantes à des herbicides inhibiteurs de hppd |
AR089784A1 (es) | 2012-01-23 | 2014-09-17 | Dow Agrosciences Llc | EVENTO DE ALGODON RESISTENTE A HERBICIDA pDAB4468.18.07.1 |
BR102013001773A2 (pt) | 2012-01-23 | 2015-09-08 | Dow Agrosciences Llc | evento de algodão pdab4468.19.10.3 tolerante a herbicidas |
EP2814316B1 (fr) | 2012-02-13 | 2021-04-07 | Nunhems B.V. | Plantes de pastèque triploïde avec une forme de croissance "bush" |
CA2865571A1 (fr) | 2012-02-29 | 2013-09-06 | Bayer Cropscience Nv | Mutants de b. napus tolerants aux herbicides inhibiteurs d'als |
WO2013127988A1 (fr) | 2012-03-02 | 2013-09-06 | Nunhems B.V. | Plantes du genre capsicum résistant au tswv |
CA2866239C (fr) | 2012-03-08 | 2020-07-28 | Athenix Corp. | Gene axmi335 de la toxine de bacillus thuringiensis et procedes pour son utilisation |
UY34663A (es) | 2012-03-08 | 2013-10-31 | Athenix Corp | Acido nucleico y proteina recombinante del gen de la endotoxina axmi345, vectores, células, composiciones y métodos para proteger plantas |
EA030642B1 (ru) | 2012-03-16 | 2018-09-28 | Нунхемс Б.В. | РАСТЕНИЯ ТОМАТА С ФЕНОТИПОМ intense И УСТОЙЧИВОСТЬЮ К TYLCV |
MX2014012339A (es) | 2012-04-17 | 2015-01-19 | Nunhems Bv | Plantas de solanum lycopersicum que tienen modificaciones no transgenicas en el gen rin. |
CN103998610B (zh) | 2012-06-29 | 2020-03-17 | 阿森尼克斯公司 | Axmi277线虫毒素及其使用方法 |
US9873886B2 (en) | 2012-07-06 | 2018-01-23 | Bayer Cropscience Nv | Brassica ROD1 gene sequences and uses thereof |
WO2014006159A1 (fr) | 2012-07-06 | 2014-01-09 | Bayer Cropscience Nv | Séquences de gènes rod1 provenant du soja et leurs utilisations |
EA201590164A1 (ru) | 2012-07-06 | 2015-05-29 | Байер Кропсайенс Нв | Растения brassica с модифицированным составом масла семян |
US9758793B2 (en) | 2012-08-30 | 2017-09-12 | Athenix Corp. | AXMI-234 and AXMI-235 delta-endotoxin genes and methods for their use |
US10793872B2 (en) | 2012-09-14 | 2020-10-06 | BASF Agricultural Solutions Seed US LLC | HPPD variants and methods of use |
EP2900817B1 (fr) | 2012-09-28 | 2021-11-10 | Nunhems B.V. | Plants de solanum lycopersicum présentant des modifications non transgéniques dans le gène acs4 |
AU2013349743B2 (en) | 2012-11-21 | 2019-11-14 | Nunhems B.V. | Solanum lycopersicum plants having non-transgenic alterations in the acs2 gene |
ES2786507T3 (es) | 2012-12-12 | 2020-10-13 | Nunhems Bv | Plantas de melón con resistencia al virus asociado al amarilleamiento del melón (MYaV) |
RS57806B2 (sr) | 2012-12-13 | 2022-07-29 | Bayer Cropscience Ag | Upotreba als inhibitora herbicida za kontrolu neželjene vegetacije kod beta vulgaris biljaka tolerantnih na als inhibitore herbicida |
US9440917B2 (en) | 2012-12-14 | 2016-09-13 | Bayer Cropscience Ag | Method for producing 4-haloalkyl-3-mercapto-substituted 2-hydroxy-benzoic acid derivatives |
EA032350B1 (ru) | 2013-01-31 | 2019-05-31 | Нунхемс Б.В. | Растения solanum lycopersicum, имеющие розовые плоды |
CA2901160C (fr) | 2013-02-13 | 2023-08-22 | Athenix Corp. | Utilisation d'axmi184 pour la lutte contre des larves nuisibles aux racines |
AU2014225732B2 (en) | 2013-03-07 | 2020-03-19 | BASF Agricultural Solutions Seed US LLC | Toxin genes and methods for their use |
AU2014247081B2 (en) | 2013-04-05 | 2020-04-16 | BASF Agricultural Solutions Seed US LLC | Brassica plants comprising mutant DA1 alleles |
WO2014170387A1 (fr) | 2013-04-19 | 2014-10-23 | Bayer Cropscience Nv | Plantes hybrides brassica et leurs procédés de production |
CA2914096A1 (fr) | 2013-06-04 | 2014-12-11 | Bayer Cropscience Nv | Procede de production ameliore de semences hybrides |
US20160160232A1 (en) | 2013-07-12 | 2016-06-09 | Bayer Cropscience Lp | Als inhibitor herbicide tolerant mutant plants |
US9862967B2 (en) | 2013-08-09 | 2018-01-09 | Athenix Corp. | AXMI281 toxin gene and methods for its use |
AR097292A1 (es) | 2013-08-09 | 2016-03-02 | Monsanto Technology Llc | Toxina pesticida activa contra insectos coleópteros y/o hemípteros |
AR097280A1 (es) | 2013-08-09 | 2016-03-02 | Athenix Corp | Gen de la toxina axmi422 y sus métodos de empleo |
UY35696A (es) | 2013-08-09 | 2015-03-27 | Athenix Corp | ?molécula de adn recombinante que comprende al gen de toxina axmi440, vector, célula huésped, plantas, composiciones y métodos relacionados?. |
EP3036331B1 (fr) | 2013-08-21 | 2021-06-16 | BASF Agricultural Solutions Seed US LLC | Plantes mutantes tolérantes aux herbicides inhibiteurs d'als |
AU2013399918A1 (en) | 2013-09-04 | 2016-03-03 | Bayer Cropscience Nv | Plants with increased growth over expressing a mitochondrial glycine decarboxylase complex subunit |
WO2015036378A1 (fr) | 2013-09-13 | 2015-03-19 | Nunhems B.V. | Épinards résistants au mildiou |
EP3043634A1 (fr) | 2013-09-13 | 2016-07-20 | Nunhems B.V. | Plantes d'épinard résistant au mildiou |
WO2015040098A1 (fr) | 2013-09-18 | 2015-03-26 | Nunhems B.V. | Plantes ayant un phénotype de fruit intense |
MX2016003405A (es) | 2013-09-24 | 2016-10-28 | Bayer Cropscience Nv | Hetero-transglicosilasa novedosa y usos de la misma. |
CN105764343B (zh) | 2013-11-25 | 2020-04-17 | 拜耳作物科学有限合伙公司 | 使用axmi-011控制半翅目昆虫 |
EP3076783A1 (fr) | 2013-12-02 | 2016-10-12 | Bayer CropScience NV | Plantes mutantes tolérantes aux herbicides inhibiteurs d'als |
CN111560385B (zh) | 2013-12-09 | 2023-11-28 | 巴斯夫农业解决方案种子美国有限责任公司 | Axmi477、axmi482、axmi486和axmi525毒素基因及使用方法 |
WO2015117265A1 (fr) | 2014-02-07 | 2015-08-13 | Tsinghua University | Longs arn non codants pour la modulation efficace de l'utilisation de phosphate dans les plantes |
BR112016020709A2 (pt) | 2014-03-11 | 2017-10-10 | Bayer Cropscience Ag | variantes de hppd e métodos de uso |
MX2016011745A (es) | 2014-03-11 | 2017-09-01 | Bayer Cropscience Lp | Variantes de hppd y metodos de uso. |
AU2015233552A1 (en) | 2014-03-21 | 2016-09-29 | Bayer Cropscience Nv | Cotton fibers with increased glucosamine content |
US10362742B2 (en) | 2014-05-22 | 2019-07-30 | Nunhems B.V. | Melon plants with whitefly resistance |
-
2019
- 2019-05-29 BR BR112020024615-8A patent/BR112020024615A2/pt not_active IP Right Cessation
- 2019-05-29 WO PCT/EP2019/064008 patent/WO2019233863A1/fr unknown
- 2019-05-29 CN CN201980049886.XA patent/CN112513033A/zh active Pending
- 2019-05-29 JP JP2020567481A patent/JP2021525774A/ja active Pending
- 2019-05-29 EP EP19728922.6A patent/EP3802521A1/fr not_active Withdrawn
- 2019-05-29 US US15/734,496 patent/US20210323950A1/en not_active Abandoned
- 2019-06-04 AR ARP190101501A patent/AR114912A1/es unknown
Also Published As
Publication number | Publication date |
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CN112513033A (zh) | 2021-03-16 |
WO2019233863A1 (fr) | 2019-12-12 |
US20210323950A1 (en) | 2021-10-21 |
JP2021525774A (ja) | 2021-09-27 |
AR114912A1 (es) | 2020-10-28 |
BR112020024615A2 (pt) | 2021-03-02 |
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