DE69232297T2 - Katalysatorzusammensetzung - Google Patents

Katalysatorzusammensetzung

Info

Publication number
DE69232297T2
DE69232297T2 DE69232297T DE69232297T DE69232297T2 DE 69232297 T2 DE69232297 T2 DE 69232297T2 DE 69232297 T DE69232297 T DE 69232297T DE 69232297 T DE69232297 T DE 69232297T DE 69232297 T2 DE69232297 T2 DE 69232297T2
Authority
DE
Germany
Prior art keywords
groups
group
hydrogen atoms
complex
alkyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69232297T
Other languages
German (de)
English (en)
Other versions
DE69232297D1 (de
Inventor
Robert S. Cardwell
Brian W. Kolthammer
John C. Tracy
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Chemical Co
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=25222564&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=DE69232297(T2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Application granted granted Critical
Publication of DE69232297D1 publication Critical patent/DE69232297D1/de
Publication of DE69232297T2 publication Critical patent/DE69232297T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/14Monomers containing five or more carbon atoms
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
DE69232297T 1992-01-06 1992-12-01 Katalysatorzusammensetzung Expired - Lifetime DE69232297T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US81720292A 1992-01-06 1992-01-06

Publications (2)

Publication Number Publication Date
DE69232297D1 DE69232297D1 (de) 2002-01-24
DE69232297T2 true DE69232297T2 (de) 2002-08-14

Family

ID=25222564

Family Applications (2)

Application Number Title Priority Date Filing Date
DE69232297T Expired - Lifetime DE69232297T2 (de) 1992-01-06 1992-12-01 Katalysatorzusammensetzung
DE69224287T Expired - Lifetime DE69224287T2 (de) 1992-01-06 1992-12-01 Katalysatorzusammensetzung

Family Applications After (1)

Application Number Title Priority Date Filing Date
DE69224287T Expired - Lifetime DE69224287T2 (de) 1992-01-06 1992-12-01 Katalysatorzusammensetzung

Country Status (10)

Country Link
US (1) US5453410A (OSRAM)
EP (2) EP0802204B1 (OSRAM)
JP (1) JP3275078B2 (OSRAM)
KR (1) KR100262023B1 (OSRAM)
CA (1) CA2105555C (OSRAM)
DE (2) DE69232297T2 (OSRAM)
ES (2) ES2111656T3 (OSRAM)
FI (1) FI114641B (OSRAM)
TW (1) TW211018B (OSRAM)
WO (1) WO1993014132A1 (OSRAM)

Families Citing this family (288)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NZ235032A (en) 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
US6025448A (en) 1989-08-31 2000-02-15 The Dow Chemical Company Gas phase polymerization of olefins
US6294625B1 (en) 1990-03-20 2001-09-25 Exxonmobil Chemical Patents Inc. Catalyst system of enhanced productivity and its use in polymerization process
US5801113A (en) * 1990-06-22 1998-09-01 Exxon Chemical Patents, Inc. Polymerization catalyst systems, their production and use
US6538080B1 (en) 1990-07-03 2003-03-25 Bp Chemicals Limited Gas phase polymerization of olefins
US6545088B1 (en) 1991-12-30 2003-04-08 Dow Global Technologies Inc. Metallocene-catalyzed process for the manufacture of EP and EPDM polymers
JP2888639B2 (ja) * 1992-04-20 1999-05-10 エクソン・ケミカル・パテンツ・インク エチレン/分枝鎖オレフィンのコポリマー
CA2146344A1 (en) * 1992-10-05 1994-04-14 Gregory George Hlatky Catalyst system of enhanced productivity and its use in polymerization process
HU225374B1 (en) * 1993-01-29 2006-10-28 Dow Global Technologies Inc Process for producing ethylene/alfa-olefin interpolymer composition
WO1994029356A1 (en) * 1993-06-15 1994-12-22 Idemitsu Kosan Co., Ltd. Process for producing olefin polymer and catalyst for olefin polymerization
CZ289538B6 (cs) * 1993-06-24 2002-02-13 The Dow Chemical Company Kovový komplex, katalytická kompozice jej obsahující, její pouľití a způsob přípravy tohoto komplexu
JP3216748B2 (ja) 1993-07-23 2001-10-09 出光興産株式会社 芳香族ビニル化合物重合体組成物の製造触媒及びそれを用いた芳香族ビニル化合物重合体組成物の製造方法
JP3180523B2 (ja) 1993-09-13 2001-06-25 出光興産株式会社 スチレン系重合体製造用触媒の選択方法
GB9319340D0 (en) * 1993-09-17 1993-11-03 Exxon Chemical Patents Inc Olefin polymersisation process
BE1007614A3 (nl) * 1993-10-11 1995-08-22 Dsm Nv Werkwijze voor de polymerisatie van een olefine in aanwezigheid van een katalysator gevormd uit halogeenmetalloceen.
US5643847A (en) * 1994-08-03 1997-07-01 Exxon Chemical Patents Inc. Supported ionic catalyst composition
US6143686A (en) * 1994-08-03 2000-11-07 Exxon Chemical Patents, Inc. Supported ionic catalyst compositions
PL318432A1 (en) * 1994-08-03 1997-06-09 Exxon Chemical Patents Inc Ionic supported catalyst composition
EP0708117B1 (en) * 1994-10-03 1999-08-11 Sumitomo Chemical Company Limited Process for producing copolymer rubber
US6506866B2 (en) * 1994-11-17 2003-01-14 Dow Global Technologies Inc. Ethylene copolymer compositions
US7153909B2 (en) * 1994-11-17 2006-12-26 Dow Global Technologies Inc. High density ethylene homopolymers and blend compositions
US5962714A (en) * 1995-10-02 1999-10-05 Mccullough; Laughlin Gerard Monocyclopentadienyl transition metal catalyst and olefin polymerization process
ID16442A (id) * 1996-01-22 1997-10-02 Dow Chemical Co Polimer etilena berat molekul ultra rendah
US6225426B1 (en) 1996-04-10 2001-05-01 Uniroyal Chemical Company, Inc. Process for producing polyolefin elastomer employing a metallocene catalyst
JPH09309926A (ja) * 1996-05-17 1997-12-02 Dow Chem Co:The エチレン共重合体の製造方法
US5811379A (en) * 1996-06-17 1998-09-22 Exxon Chemical Patents Inc. Polymers derived from olefins useful as lubricant and fuel oil additives, processes for preparation of such polymers and additives and use thereof (PT-1267)
US6066603A (en) * 1996-06-17 2000-05-23 Exxon Chemical Patents Inc. Polar monomer containing copolymers derived from olefins useful as lubricant and useful as lubricant and fuel oil additivies process for preparation of such copolymers and additives and use thereof
KR100466733B1 (ko) * 1996-07-23 2005-01-24 다우 글로벌 테크놀로지스 인크. 13족 화합물을 포함하는 올레핀 중합 촉매 조성물
US5849823A (en) * 1996-09-04 1998-12-15 The Dow Chemical Company Homogeneously branched ethylene α-olefin interpolymer compositions for use in gasket applications
US6271322B1 (en) 1996-10-02 2001-08-07 Mccullough Laughlin Gerard Monocyclopentadienyl transition metal catalyst and olefin polymerization process
CA2271861C (en) * 1996-11-15 2007-09-04 Montell Technology Company B.V. Heterocyclic metallocenes and polymerization catalysts
US6812289B2 (en) 1996-12-12 2004-11-02 Dow Global Technologies Inc. Cast stretch film of interpolymer compositions
CN1249734A (zh) 1997-01-08 2000-04-05 赫尔克里士公司 用于制备烃树脂的氟化固体酸催化剂
FI971565A7 (fi) 1997-04-14 1998-10-15 Borealis As Olefiinien polymerointiin tarkoitettujen katalysaattorisysteemien substituoituja metalloseeniyhdisteitä, niiden välituotteet ja valmistusmenetelmä
US5777120A (en) * 1997-03-14 1998-07-07 University Of Iowa Research Foundation Cationic aluminum alkyl complexes incorporating amidinate ligands as polymerization catalysts
US6228794B1 (en) 1997-03-14 2001-05-08 University Of Iowa Research Foundation Cationic group 13 complexes incorporating bidentate ligands as polymerization catalysts
AR012582A1 (es) 1997-04-14 2000-11-08 Dow Global Technologies Inc Composiciones polimericas de elongacion mejorada y formulaciones adhesivas de fusion en caliente que incluyen dicha composicion
US6228795B1 (en) 1997-06-05 2001-05-08 Exxon Chemical Patents, Inc. Polymeric supported catalysts
US6172015B1 (en) 1997-07-21 2001-01-09 Exxon Chemical Patents, Inc Polar monomer containing copolymers derived from olefins useful as lubricant and fuel oil additives, processes for preparation of such copolymers and additives and use thereof
CN1130418C (zh) 1997-08-08 2003-12-10 陶氏化学公司 适合用作地面、墙面或天花板覆盖材料的片材、其制备方法和用于制备该片材的中间体
WO1999009096A1 (en) 1997-08-15 1999-02-25 The Dow Chemical Company Films produced from substantially linear homogeneous olefin polymer compositions
AU9118498A (en) 1997-08-27 1999-03-16 Dow Chemical Company, The Elastomers with improved processability
US6696379B1 (en) 1997-09-19 2004-02-24 The Dow Chemical Company Supported modified alumoxane catalyst activator
DE19757524A1 (de) 1997-12-23 1999-06-24 Bayer Ag eta-Komplex-Verbindungen
EP1068377A1 (en) 1998-03-11 2001-01-17 The Dow Chemical Company Fibers made from alpha-olefin/vinyl or vinylidene aromatic and/or hindered cycloaliphatic or aliphatic vinyl or vinylidene interpolymers
AR018359A1 (es) * 1998-05-18 2001-11-14 Dow Global Technologies Inc Articulo resistente al calor , configurado, irradiado y reticulado, libre de un agente de reticulacion de silano
US6245868B1 (en) 1998-05-29 2001-06-12 Univation Technologies Catalyst delivery method, a catalyst feeder and their use in a polymerization process
BR9911158A (pt) 1998-06-12 2001-04-03 Univation Tech Llc Processos de polimerização de olefinas usando complexos ativados ácido-base de lewis
BR9911836A (pt) 1998-06-12 2001-10-16 Avery Dennison Corp Película termoplástica de multicamadas, método para corte de sinal e película de delineamento eletrônico
US6437090B1 (en) * 1998-06-17 2002-08-20 Kabushiki Kaisha Toshiba Curing catalyst, resin composition, resin-sealed semiconductor device and coating material
US6329312B1 (en) 1998-06-19 2001-12-11 Phillips Petroleum Company Metallocycle metallocenes and their use
ES2283125T3 (es) * 1998-07-16 2007-10-16 Univation Technologies Llc Cocatalizadores de acidos de lewis basados en aluminio para polimerizacion de olefinas.
EP1104426B1 (en) 1998-08-11 2002-08-14 The Dow Chemical Company Catalyst activator composition
US6187940B1 (en) 1998-08-17 2001-02-13 The Dow Chemical Company Three coordinate aluminum catalyst activator composition
US6248914B1 (en) 1998-08-18 2001-06-19 The Dow Chemical Company Metalloid salt catalyst/activators
AU6254099A (en) 1998-09-16 2000-04-03 Dow Chemical Company, The Functionalized catalyst supports and supported catalyst systems
WO2000015642A1 (en) 1998-09-16 2000-03-23 The Dow Chemical Company Dinuclear fluoroaryl aluminum alkyl complexes
WO2000018808A1 (en) 1998-09-30 2000-04-06 Exxon Chemical Patents Inc. Cationic group 3 catalyst system
US6521793B1 (en) 1998-10-08 2003-02-18 Symyx Technologies, Inc. Catalyst ligands, catalytic metal complexes and processes using same
US6225427B1 (en) 1998-10-15 2001-05-01 Uniroyal Chemical Company, Inc. Olefin polymerization process employing metallocene catalyst provided by cocatalyst activation of a metallocene procatalyst
US6486088B1 (en) 1998-10-23 2002-11-26 Exxonmobil Chemical Patents Inc. High activity carbenium-activated polymerization catalysts
US6340651B1 (en) 1999-04-26 2002-01-22 Phillips Petroleum Company Multicyclic metallocycle metallocenes and their use
US6369176B1 (en) 1999-08-19 2002-04-09 Dupont Dow Elastomers Llc Process for preparing in a single reactor polymer blends having a broad molecular weight distribution
US6476164B1 (en) 1999-10-22 2002-11-05 Exxonmobil Chemical Patents Inc. Carbenium cationic complexes suitable for polymerization catalysts
US6475946B1 (en) 1999-10-22 2002-11-05 Exxonmobil Chemical Patents Inc. Olefin polymerization catalysis with aryl substituted carbenium cationic complexes
US6673735B1 (en) 1999-11-24 2004-01-06 Dow Global Technologies Inc. Preparation of catalyst compositions
US6489480B2 (en) 1999-12-09 2002-12-03 Exxonmobil Chemical Patents Inc. Group-15 cationic compounds for olefin polymerization catalysts
US6822057B2 (en) 1999-12-09 2004-11-23 Exxon Mobil Chemical Patents Inc. Olefin polymerization catalysts derived from Group-15 cationic compounds and processes using them
ES2239631T3 (es) 1999-12-10 2005-10-01 Exxonmobil Chemical Patents Inc. Polimeros compolimerizados de propileno y dieno.
US6977287B2 (en) 1999-12-10 2005-12-20 Exxonmobil Chemical Patents Inc. Propylene diene copolymers
US6809168B2 (en) 1999-12-10 2004-10-26 Exxonmobil Chemical Patents Inc. Articles formed from propylene diene copolymers
US6281306B1 (en) 1999-12-16 2001-08-28 Univation Technologies, Llc Method of polymerization
WO2001046273A1 (en) 1999-12-20 2001-06-28 Exxon Chemical Patents Inc. Processes for the preparation polyolefin resins using supported ionic catalysts
US7067603B1 (en) 1999-12-22 2006-06-27 Exxonmobil Chemical Patents Inc. Adhesive alpha-olefin inter-polymers
WO2001046277A2 (en) 1999-12-22 2001-06-28 Exxonmobil Chemical Patents, Inc. Polypropylene-based adhesive compositions
US20020013224A1 (en) * 2000-02-08 2002-01-31 Diamond Gary M. Catalysts, metal complexes, compositions and arrays containing erbium
US6809209B2 (en) 2000-04-07 2004-10-26 Exxonmobil Chemical Patents Inc. Nitrogen-containing group-13 anionic compounds for olefin polymerization
US6448424B1 (en) * 2000-05-01 2002-09-10 Solvay Polyolefins Europe-Belgium (Société Anonyme) Tetrahydrofluorenyl containing group 4 metallocenes useful as catalysts for the polymerization of olefins, process for their preparation and use of said metallocenes for the polymerization of olefins
US7078164B1 (en) 2000-06-19 2006-07-18 Symyx Technologies, Inc. High throughput screen for identifying polymerization catalysts from potential catalysts
US6858767B1 (en) 2000-08-11 2005-02-22 Uniroyal Chemical Company, Inc. Process for producing liquid polyalphaolefin polymer, metallocene catalyst therefor, the resulting polymer and lubricant containing same
US6559230B2 (en) 2000-09-29 2003-05-06 Dupont Dow Elastomers L.L.C. Thermosetting ethylene/alpha-olefin composition and safety glass interlayer film made from the composition
US6943133B2 (en) * 2000-10-20 2005-09-13 Univation Technologies, Llc Diene functionalized catalyst supports and supported catalyst compositions
EP1334139A2 (en) 2000-11-07 2003-08-13 Symyx Technologies, Inc. Substituted pyridyl amine ligands, complexes and catalysts therefrom. processes for producing polyolefins therewith
US6538082B2 (en) * 2000-12-05 2003-03-25 Solvay Polyolefins Europe-Belgium Asymmetric silicon-bridged metallocenes useful as catalysts in the polymerization of α-olefins, process for their preparation and use of said metallocenes for the polymerization of α-olefins
WO2002053374A1 (en) 2001-01-02 2002-07-11 Dow Global Technologies Inc. Peelable seal and method of making and using same
WO2003000740A2 (en) 2001-06-20 2003-01-03 Exxonmobil Chemical Patents Inc. Polyolefins made by catalyst comprising a noncoordinating anion and articles comprising them
EP1425345A1 (en) 2001-06-22 2004-06-09 Exxonmobil Chemical Patents Inc. Metallocene-produced very low density polyethylenes or linear lowdensity polyethylenes as impact modifiers
MXPA04001928A (es) * 2001-08-31 2004-07-23 Dow Global Technologies Inc Material de polietileno multimodal.
US7122689B2 (en) 2001-11-06 2006-10-17 Symyx Technologies, Inc. Titanium substituted pyridyl amine complexes, catalysts and processes for polymerizing ethylene and stryene
US6794514B2 (en) * 2002-04-12 2004-09-21 Symyx Technologies, Inc. Ethylene-styrene copolymers and phenol-triazole type complexes, catalysts, and processes for polymerizing
US7060848B2 (en) * 2002-04-24 2006-06-13 Symyx Technologies, Inc. Bridged bi-aromatic catalysts, complexes, and methods of using the same
ATE492552T1 (de) * 2002-04-24 2011-01-15 Symyx Solutions Inc Verbrückte bi-aromatische liganden, komplexe, katalysatoren, verfahren zur polymerisierung und entstehende polymere
US7091292B2 (en) * 2002-04-24 2006-08-15 Symyx Technologies, Inc. Bridged bi-aromatic catalysts, complexes, and methods of using the same
CN100484975C (zh) 2002-07-31 2009-05-06 埃克森美孚化学专利公司 硅烷可交联的聚乙烯
CN100503708C (zh) 2002-09-05 2009-06-24 埃克森美孚化学专利公司 收缩薄膜
CA2493274A1 (en) 2002-09-05 2004-03-18 Exxonmobil Chemical Patents Inc. Stretch film
US6846884B2 (en) * 2002-09-27 2005-01-25 Union Carbide Chemicals & Plastics Technology Corporation Control of resin properties
WO2005108442A1 (en) 2002-10-15 2005-11-17 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
US7223822B2 (en) 2002-10-15 2007-05-29 Exxonmobil Chemical Patents Inc. Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom
DE60333224D1 (de) * 2002-12-13 2010-08-12 Dow Global Technologies Inc Olefinpolymerisationskatalysatorzusammensetzung, gruppe 13-amid derivate enthaltend
JP4090389B2 (ja) * 2003-06-10 2008-05-28 株式会社日立製作所 核磁気共鳴装置
CA2557870A1 (en) 2004-03-17 2005-09-29 Dow Global Technologies Inc. Catalyst composition comprising shuttling agent for higher olefin multi-block copolymer formation
ES2342895T3 (es) 2004-03-17 2010-07-16 Dow Global Technologies Inc. Composicion catalitica que comprende agente de transferencia para la formacion de copolimero de multiples bloques de etileno.
MXPA06010485A (es) 2004-03-17 2006-12-19 Dow Global Technologies Inc Composicion catalizadora que comprende agente de enlace para la formacion de copolimeros de etileno.
GB0411742D0 (en) 2004-05-26 2004-06-30 Exxonmobil Chem Patents Inc Transition metal compounds for olefin polymerization and oligomerization
EP3009459B1 (en) * 2004-06-16 2017-08-02 Dow Global Technologies LLC Olefin polymerization process using a modifier
KR101195320B1 (ko) * 2004-08-09 2012-10-29 다우 글로벌 테크놀로지스 엘엘씨 중합체를 제조하기 위한 지지된비스(하이드록시아릴아릴옥시) 촉매
US7256296B2 (en) * 2004-09-22 2007-08-14 Symyx Technologies, Inc. Heterocycle-amine ligands, compositions, complexes, and catalysts
EP1794196A2 (en) * 2004-09-22 2007-06-13 Symyx Technologies, Inc. Heterocycle-amine ligands, compositions, complexes, and catalysts, and methods of making and using the same
WO2006049699A1 (en) 2004-10-29 2006-05-11 Exxonmobil Chemical Patents Inc Catalyst compound containing divalent tridentate ligand
US7705157B2 (en) * 2004-12-16 2010-04-27 Symyx Solutions, Inc. Phenol-heterocyclic ligands, metal complexes, and their uses as catalysts
ATE502093T1 (de) 2004-12-21 2011-04-15 Dow Global Technologies Inc Klebstoffzusammensetzung auf polypropylenbasis
EP2894176B1 (en) * 2005-03-17 2022-06-01 Dow Global Technologies LLC Catalyst composition comprising shuttling agent for regio-irregular multi-block copolymer formation
US9410009B2 (en) 2005-03-17 2016-08-09 Dow Global Technologies Llc Catalyst composition comprising shuttling agent for tactic/ atactic multi-block copolymer formation
WO2006101596A1 (en) 2005-03-17 2006-09-28 Dow Global Technologies Inc. Catalyst composition comprising shuttling agent for tactic/ atactic multi-block copolymer formation
MY148274A (en) * 2005-07-08 2013-03-29 Dow Global Technologies Inc Layered film compositions, packages prepared therefrom, and methods of use
CA2622720A1 (en) 2005-09-15 2007-03-29 Dow Global Technologies Inc. Catalytic olefin block copolymers via polymerizable shuttling agent
WO2007035493A2 (en) * 2005-09-15 2007-03-29 Dow Global Technologies Inc. Control of polymer architecture and molecular weight distribution via multi-centered shuttling agent
US8153243B2 (en) 2005-12-09 2012-04-10 Dow Global Technologies Llc Interpolymers suitable for multilayer films
EP1963347B1 (en) 2005-12-14 2011-10-19 ExxonMobil Chemical Patents Inc. Halogen substituted metallocene compounds for olefin polymerization
AU2006329980A1 (en) 2005-12-16 2007-07-05 Dow Global Technologies Inc. Polydentate heteroatom ligand containing metal complexes, catalysts and methods of making and using the same
EP1803747A1 (en) 2005-12-30 2007-07-04 Borealis Technology Oy Surface-modified polymerization catalysts for the preparation of low-gel polyolefin films
WO2007078134A1 (en) * 2005-12-30 2007-07-12 Lg Chem. Ltd. Transition metal complexes and preparation methods thereof
KR100874032B1 (ko) * 2006-02-01 2008-12-17 주식회사 엘지화학 전이 금속 화합물을 포함하는 촉매 조성물 및 이를 이용한올레핀 중합
WO2007130277A1 (en) 2006-05-05 2007-11-15 Exxonmobil Chemical Patents Inc. Linear low density polymer blends and articles made therefrom
BRPI0711018A8 (pt) * 2006-05-17 2017-09-19 Dow Global Technologies Inc Processo para a polimerização de etileno e uma ou mais alfa-olefinas ou diolefinas c-3-30, processo para a polimerização de etileno e uma ou mais alfa-olefinas c3-8 usando um complexo de zircônio e um cocatalizador de ativação e copolímero de etileno e uma ou mais alfa-olefinas c3-8
US7601255B2 (en) 2006-09-06 2009-10-13 Chemtura Corporation Process for removal of residual catalyst components
US8071699B2 (en) 2006-09-21 2011-12-06 Union Carbide Chemicals & Plastics Technology Llc Methods of controlling properties in multimodal systems
BRPI0808314B1 (pt) * 2007-03-07 2019-04-09 Dow Global Technologies Inc. Complexo metálico suportado e processo de polimerização por adição.
ITMI20070878A1 (it) 2007-05-02 2008-11-03 Dow Global Technologies Inc Processo per la polimerizzazine di polimeri tattici con l'uso di catalizzatori chirali
ITMI20070877A1 (it) 2007-05-02 2008-11-03 Dow Global Technologies Inc Processo per la produzione di copolimeri a blocchi multipli con l'utilizzo di solventi polari
US8281332B2 (en) * 2007-05-02 2012-10-02 Google Inc. Animated video overlays
TW200932762A (en) 2007-10-22 2009-08-01 Univation Tech Llc Polyethylene compositions having improved properties
ES2435568T3 (es) * 2007-11-19 2013-12-20 Dow Global Technologies Llc Copolímeros de propileno-alfa-olefina con ramificación de cadena larga
EP2112173A1 (en) 2008-04-16 2009-10-28 ExxonMobil Chemical Patents Inc. Catalyst compounds and use thereof
US20090286944A1 (en) * 2008-05-15 2009-11-19 Symyx Technologies, Inc. Select phenol-heterocycle ligands, metal complexes formed therefrom, and their uses as catalysts
BRPI0922454A2 (pt) 2008-12-18 2018-05-22 Univation Tech Llc método para tratamento de leito de semente para uma reação de polimerização
EP2757113A2 (en) 2009-03-06 2014-07-23 Dow Global Technologies LLC Catalysts, processes for making catalysts, processes for making polyolefin compositions and polyolefin compositions
WO2011016992A2 (en) 2009-07-29 2011-02-10 Dow Global Technologies Inc. Polymeric chain transfer/shuttling agents
EP2459598B1 (en) 2009-07-29 2017-10-18 Dow Global Technologies LLC Dual- or multi-headed chain shuttling agents and their use for the preparation of block copolymers
US8067652B2 (en) 2009-08-13 2011-11-29 Chemtura Corporation Processes for controlling the viscosity of polyalphaolefins
CA2777230C (en) 2009-10-19 2015-12-22 Sasol Technology (Pty) Limited Oligomerisation of olefinic compounds with reduced polymer formation
BR112012015365A2 (pt) 2009-12-23 2020-09-15 Invista Technologies S.A.R.L. artigo e método para preparar um pano
WO2011087692A2 (en) 2009-12-23 2011-07-21 Invista Technologies S.A R.L. Stretch articles including polyolefin elastic fiber
WO2011087695A2 (en) 2009-12-23 2011-07-21 Invista Technologies S.A R.L. Polyolefin elastic fiber
EP2516703B1 (en) 2009-12-23 2020-04-29 Invista Technologies S.à.r.l. Elastic fiber containing an anti-tack additive
WO2011079042A2 (en) 2009-12-24 2011-06-30 Exxonmobil Chemical Patents Inc. Process for producing novel synthetic basestocks
WO2011087731A1 (en) 2010-01-14 2011-07-21 Exxonmobil Chemical Patents Inc. Processes and apparatus for continuous solution polymerization
ES2672893T3 (es) 2010-01-14 2018-06-18 Exxonmobil Chemical Patents Inc. Procesos y aparato para polimerización continua en disolución
WO2011087729A2 (en) 2010-01-14 2011-07-21 Exxonmobil Chemical Patents Inc. Processes and apparatus for polymer finishing and packaging
US8058461B2 (en) 2010-03-01 2011-11-15 Exxonmobil Chemical Patents Inc. Mono-indenyl transition metal compounds and polymerization therewith
EP2591020B1 (en) 2010-07-06 2015-09-09 Ticona GmbH Process for producing high molecular weight polyethylene
US20130071663A1 (en) 2010-07-06 2013-03-21 Ticona Gmbh Ultra-high molecular weight polyethylene, its production and use
BR112012032745A2 (pt) 2010-07-06 2016-11-08 Ticona Gmbh processo para produção de polietileno de alto peso molecular
BR112012032623A2 (pt) 2010-07-06 2016-11-22 Ticona Gmbh "processo para produção de polietileno de alto peso molecular"
WO2012006230A1 (en) 2010-07-06 2012-01-12 Ticona Gmbh Process for producing high molecular weight polyethylene
CN102958960A (zh) 2010-07-06 2013-03-06 提克纳有限公司 成形的高分子量聚乙烯制品、其产生和用途
CN102959144A (zh) 2010-07-06 2013-03-06 提克纳有限公司 高分子量聚乙烯纤维和膜、它们的生产和用途
CN103298843B (zh) 2010-11-30 2015-08-19 尤尼威蒂恩技术有限责任公司 具有改进的流动特征的催化剂组合物及其制造和使用方法
RU2587080C2 (ru) 2010-11-30 2016-06-10 Юнивейшн Текнолоджиз, Ллк Способы полимеризации олефинов с использованием экстрагированных карбоксилатов металлов
US8893725B2 (en) 2011-01-28 2014-11-25 R. J. Reynolds Tobacco Company Polymeric materials derived from tobacco
BR112013029135B1 (pt) 2011-05-13 2020-12-15 Univation Technologies, Llc Composição e processo de polimerização
US8658556B2 (en) 2011-06-08 2014-02-25 Exxonmobil Chemical Patents Inc. Catalyst systems comprising multiple non-coordinating anion activators and methods for polymerization therewith
EP2718012B1 (en) 2011-06-08 2016-04-27 ExxonMobil Chemical Patents Inc. Catalyst systems comprising multiple non-coordinating anion activators and methods for polymerization therewith
WO2013048848A2 (en) 2011-09-30 2013-04-04 Exxonmobil Chemical Patents Inc. Dynamic modulation of metallocene catalysts
US8841379B2 (en) 2011-11-07 2014-09-23 E I Du Pont De Nemours And Company Method to form an aqueous dispersion of an ionomer-polyolefin blend
JP2015504935A (ja) 2011-12-19 2015-02-16 ティコナ ゲゼルシャフト ミット ベシュレンクテル ハフツング 高分子量ポリエチレンの製造方法
CN104781628B (zh) 2012-11-12 2017-07-07 尤尼威蒂恩技术有限责任公司 用于气相聚合方法的再循环气体冷却器系统
EP2935297B1 (en) 2012-12-21 2019-03-20 ExxonMobil Chemical Patents Inc. Bridged metallocene compounds, catalyst systems and processes for polymerization therewith
KR102214265B1 (ko) 2013-01-14 2021-02-10 유니베이션 테크놀로지즈, 엘엘씨 증가된 생산성을 갖는 촉매 시스템의 제조 방법
BR112015018250B1 (pt) 2013-01-30 2021-02-23 Univation Technologies, Llc processo para produzir uma composição catalisadora e processo de polimerização
US9458260B2 (en) 2013-07-17 2016-10-04 Exxonmobil Chemical Patents Inc. Process using substituted metallocene catalysts and products therefrom
EP3022233B1 (en) 2013-07-17 2019-05-01 ExxonMobil Chemical Patents Inc. Cyclopropyl substituted metallocene catalysts
US8916659B1 (en) 2013-10-31 2014-12-23 Exxonmobil Chemical Patents Inc. Process and apparatus for continuous solution polymerization
WO2015073157A1 (en) 2013-11-15 2015-05-21 Exxonmobil Chemical Patents Inc. Process to produce polymers from pyridyldiamido transition metal complexes and use thereof
US9676885B2 (en) 2014-04-02 2017-06-13 Univation Technologies, Llc Continuity compositions and methods of making and using the same
SG11201700372SA (en) 2014-07-24 2017-02-27 Dow Global Technologies Llc Bis-biphenylphenoxy catalysts for polymerization of low molecular weight ethylene-based polymers
EP3229944A1 (en) 2014-12-12 2017-10-18 ExxonMobil Research and Engineering Company Membrane fabrication methods using organosilica materials and uses thereof
WO2016094843A2 (en) 2014-12-12 2016-06-16 Exxonmobil Chemical Patents Inc. Olefin polymerization catalyst system comprising mesoporous organosilica support
WO2016094861A1 (en) 2014-12-12 2016-06-16 Exxonmobil Chemical Patents Inc. Olefin polymerization catalyst system comprising mesoporous organosilica support
WO2016094870A1 (en) 2014-12-12 2016-06-16 Exxonmobil Chemical Patents Inc. Olefin polymerization catalyst system comprising mesoporous organosilica support
WO2016094866A1 (en) 2014-12-12 2016-06-16 Exxonmobil Chemical Patents Inc. Olefin polymerization catalyst system comprising mesoporous organosilica support
BR112017019133B1 (pt) 2015-03-10 2021-11-23 Univation Technologies, Llc Método para produzir uma composição de catalisador suportado para polimerização de olefina
EP3285923B1 (en) 2015-04-20 2019-07-17 Univation Technologies, LLC Bridged bi-aromatic ligands and olefin polymerization catalysts prepared therefrom
EP3286230B1 (en) 2015-04-20 2023-03-08 ExxonMobil Chemical Patents Inc. Supported catalyst systems and processes for use thereof
BR112017022494A2 (pt) 2015-04-20 2018-07-17 Univation Tech Llc ligandos biaromáticos em ponte e compostos de metais de transição preparados a partir dos mesmos
US10533063B2 (en) 2015-04-20 2020-01-14 Exxonmobil Chemical Patents Inc. Supported catalyst systems and processes for use thereof
BR112017023052B1 (pt) 2015-04-27 2022-05-10 Univation Technologies, Llc Composição de catalisador de polimerização de poliolefina suportada e método para a produção de composição de catalisador de polimerização de olefina suportada
WO2016195824A1 (en) 2015-05-29 2016-12-08 Exxonmobil Chemical Patents Inc. Polymerization process using bridged metallocene compounds supported on organoaluminum treated layered silicate supports
US10570219B2 (en) 2015-06-05 2020-02-25 Exxonmobil Chemical Patents Inc. Production of heterophasic polymers in gas or slurry phase
WO2016196334A1 (en) 2015-06-05 2016-12-08 Exxonmobil Chemical Patents Inc. Single reactor production of polymers in gas or slurry phase
EP3317288A4 (en) 2015-06-30 2019-03-13 ExxonMobil Chemical Patents Inc. TRANSITION METAL COMPLEXES OF TRIDENTATE DIANIONIC CNN LIGANDS, MANUFACTURE AND USE THEREOF
BR112018005199B1 (pt) 2015-09-30 2020-12-15 Dow Global Technologies Llc Processo para a preparação de uma composição, composição e processo para polimerização de pelo menos um monômero polimerizável por adição para formar uma composição de polímero
WO2017058384A1 (en) 2015-10-02 2017-04-06 Exxonmobil Chemical Patents Inc. Asymmetric fluorenyl-substituted salan catalysts
WO2017069854A1 (en) 2015-10-22 2017-04-27 Exxonmobil Chemical Patents Inc. Catalysts for the formation of multimodal polymers
CN108290975B (zh) 2015-10-23 2021-04-06 埃克森美孚化学专利公司 利用茂金属催化剂体系生产具有内部不饱和结构的聚烯烃
US9803037B1 (en) 2016-05-03 2017-10-31 Exxonmobil Chemical Patents Inc. Tetrahydro-as-indacenyl catalyst composition, catalyst system, and processes for use thereof
WO2017204830A1 (en) 2016-05-27 2017-11-30 Exxonmobil Chemical Patents, Inc. Metallocene catalyst compositions and polymerization process therewith
WO2018022263A1 (en) 2016-07-29 2018-02-01 Exxonmobil Chemical Patents Inc. Polymerization processes using high molecular weight polyhydric quenching agents
WO2018022249A1 (en) 2016-07-29 2018-02-01 Exxonmobil Chemical Patents Inc. Heterocyclic amido transition metal complexes, production and use thereof
WO2018044395A1 (en) 2016-08-31 2018-03-08 Exxonmobil Chemical Patents Inc. Spiral heat exchanger as a preheater in polymer devolatilization processes
JP7096236B2 (ja) 2016-09-30 2022-07-05 ダウ グローバル テクノロジーズ エルエルシー チェーンシャトリングに有用なマルチヘッドまたはデュアルヘッド組成物、およびそれを調製するプロセス
JP7123040B2 (ja) 2016-09-30 2022-08-22 ダウ グローバル テクノロジーズ エルエルシー 連鎖シャトリングに有用な多頭または二頭組成物の調製方法
JP7029448B2 (ja) 2016-09-30 2022-03-03 ダウ グローバル テクノロジーズ エルエルシー チェーンシャトリングに有用な封鎖されたマルチまたはデュアルヘッド組成物、およびそれを調製するプロセス
WO2018067289A1 (en) 2016-10-05 2018-04-12 Exxonmobil Chemical Patents Inc. Sterically hindered metallocenes, synthesis and use
WO2018075243A1 (en) 2016-10-19 2018-04-26 Exxonmobil Chemical Patents Inc. Supported catalyst systems and methods of using same
WO2018129230A1 (en) 2017-01-06 2018-07-12 Univation Technologies, Llc Synthesis of benzylanilinyl phenyl phenol ligands
CA3049113A1 (en) 2017-01-06 2018-07-12 Univation Technologies, Llc Synthesis of benzyloxyphenoxy phenol ligands
SG11201907497PA (en) 2017-02-20 2019-09-27 Exxonmobil Chemical Patents Inc Supported catalyst systems and processes for use thereof
WO2018151904A1 (en) 2017-02-20 2018-08-23 Exxonmobil Chemical Patents Inc. Group 4 catalyst compounds and process for use thereof
CN110325561B (zh) 2017-02-20 2022-10-14 埃克森美孚化学专利公司 第4族催化剂化合物及其使用方法
WO2018151790A1 (en) 2017-02-20 2018-08-23 Exxonmobil Chemical Patents Inc. Hafnocene catalyst compounds and process for use thereof
US11046796B2 (en) 2017-08-04 2021-06-29 Exxonmobil Chemical Patents Inc. Films made from polyethylene compositions and processes for making same
SG11202000942TA (en) 2017-08-04 2020-02-27 Exxonmobil Chemical Patents Inc Mixed catalysts with unbridged hafnocenes with -ch2-sime3 moieties
EP3661981B1 (en) 2017-08-04 2025-09-17 ExxonMobil Chemical Patents Inc. Polyethylene compositions and films prepared therefrom
WO2019099250A1 (en) 2017-11-14 2019-05-23 Exxonmobil Chemical Patents Inc. (di)silicon bridged metallocenes that produce polyethylene broad molecular weight distribution and molecular weight
WO2019108327A1 (en) 2017-12-01 2019-06-06 Exxonmobil Chemical Patents Inc. Films comprising polyethylene composition
KR102405495B1 (ko) 2017-12-01 2022-06-08 엑손모빌 케미칼 패턴츠 인코포레이티드 촉매계 및 이를 사용하기 위한 중합 방법
US11028196B2 (en) 2017-12-22 2021-06-08 Exxonmobil Chemical Patents Inc. Polyolefin compositions
EP3749707A1 (en) 2018-02-05 2020-12-16 ExxonMobil Chemical Patents Inc. Enhanced processability of lldpe by addition of ultra-high molecular weight high density polyethylene
WO2019156968A1 (en) 2018-02-07 2019-08-15 Exxonmobil Chemical Patents Inc. Supported catalysts systems and polymerization processes for using the same
WO2019160710A1 (en) 2018-02-19 2019-08-22 Exxonmobil Chemical Patents Inc. Catalysts, catalyst systems, and methods for using the same
US11578155B2 (en) 2018-03-08 2023-02-14 Exxonmobil Chemical Patents Inc. Ethylene-propylene linear copolymers as viscosity modifiers
US11479625B2 (en) 2018-03-08 2022-10-25 Exxonmobil Chemical Patents Inc. Ethylene-propylene branched copolymers as viscosity modifiers with enhanced fuel economy
CN111902435B (zh) 2018-03-19 2024-07-19 埃克森美孚化学专利公司 弹性体丙烯-α-烯烃-二烯三元共聚物组合物
EP3802644B1 (en) 2018-06-04 2024-09-04 ExxonMobil Chemical Patents Inc. Metallocenes with si-si bridges
US11787881B2 (en) 2018-06-19 2023-10-17 Exxonmobil Chemical Patents Inc. Polyethylene compositions and films prepared therefrom
EP3841188A1 (en) 2018-08-22 2021-06-30 ExxonMobil Research and Engineering Company Manufacturing a base stock from ethanol
US10815439B2 (en) 2018-08-22 2020-10-27 Exxonmobil Research And Engineering Company Manufacturing hydrocarbons
US12006423B2 (en) 2018-08-29 2024-06-11 ExxonMobil Engineering & Technology Company Methods of making polymer compositions with enhanced elasticity by employing VTP and HMP catalyst systems in parallel processes
WO2020060745A1 (en) 2018-09-19 2020-03-26 Exxonmobil Chemical Patents Inc. Devolatilization processes
WO2020069086A2 (en) 2018-09-27 2020-04-02 Exxonmobil Chemical Patents Inc. C1,c2-bridged ligands and catalysts
WO2020140067A1 (en) 2018-12-28 2020-07-02 Dow Global Technologies Llc Curable compositions comprising unsaturated polyolefins
CA3125275A1 (en) 2018-12-28 2020-07-02 Dow Global Technologies Llc Curable compositions comprising unsaturated polyolefins
CN113412264B (zh) 2018-12-28 2024-06-25 陶氏环球技术有限责任公司 有机金属链转移剂
US12275810B2 (en) 2018-12-28 2025-04-15 Dow Global Technologies Llc Telechelic polyolefins and processes for preparing the same
WO2020140061A1 (en) 2018-12-28 2020-07-02 Dow Global Technologies Llc Curable compositions comprising telechelic polyolefins
US12202920B2 (en) 2019-01-08 2025-01-21 ExxonMobil Engineering & Technology Company Olefin polymerization processes featuring in situ blending of an oil extension
WO2020167399A1 (en) 2019-02-11 2020-08-20 Exxonmobil Chemical Patents Inc. Biphasic polymerization processes and ethylene-based polyolefins therefrom
US11180580B2 (en) 2019-03-29 2021-11-23 Exxonmobil Chemical Patents Inc. Benzazole and pseudoindole diamido transition metal complexes and use thereof in olefin polymerization
US12305028B2 (en) 2019-07-17 2025-05-20 ExxonMobil Engineering & Technology Company High propylene content EP having low glass transition temperatures
US12338257B2 (en) 2019-08-02 2025-06-24 Exxonmobil Chemical Patents Inc. Metallocenes and methods thereof
CN114450336B (zh) 2019-08-05 2024-01-09 埃克森美孚化学专利公司 用于改进橡胶粘着性的丙烯-α-烯烃-二烯三元共聚物添加剂
CN114929761A (zh) 2019-08-22 2022-08-19 埃克森美孚化学专利公司 用c1对称的茂金属催化剂生产的全同立构的丙烯均聚物和共聚物
US20220289882A1 (en) 2019-08-27 2022-09-15 Chevron Oronite Company Llc Ethylene copolymers and use as viscosity modifiers
US11649256B2 (en) 2019-10-11 2023-05-16 Exxonmobil Chemical Patents Inc. Catalysts for olefin polymerization
KR20220114592A (ko) 2019-12-11 2022-08-17 엑손모빌 케미칼 패턴츠 인코포레이티드 저 방향족 함량을 갖는 폴리올레핀
US11718635B2 (en) 2019-12-16 2023-08-08 Exxonmobil Chemical Patents Inc. Iron bis(imino) aryl catalysts and methods thereof
CN115151581A (zh) 2019-12-17 2022-10-04 埃克森美孚化学专利公司 制备具有长链支化的高密度聚乙烯的溶液聚合方法
EP4110834B1 (en) 2020-02-24 2024-04-03 ExxonMobil Chemical Patents Inc. Ansa-bis(inden-2-yl) catalysts for producing vinylidene-terminated polyalphaolefins
WO2021173362A1 (en) 2020-02-24 2021-09-02 Exxonmobil Chemical Patents Inc. Lewis base catalysts and methods thereof
US11760814B2 (en) 2020-03-03 2023-09-19 Exxonmobil Chemical Patents Inc. 1,5 diazabicyclooctane ligand systems and methods therewith
WO2021188361A1 (en) 2020-03-20 2021-09-23 Exxonmobil Chemical Patents Inc. Linear alpha-olefin copolymers and impact copolymers thereof
US12410273B2 (en) 2020-03-30 2025-09-09 Exxonmobil Chemical Patents Inc. Comb-block copolymers and methods thereof
WO2021222016A2 (en) 2020-05-01 2021-11-04 Exxonmobil Chemical Patents Inc. Linear low density polyethylene for film applications
WO2021222280A2 (en) 2020-05-01 2021-11-04 Exxonmobil Chemical Patents Inc. Linear low density polyethylene for film applications
US20230242745A1 (en) 2020-06-03 2023-08-03 Exxonmobil Chemical Patents Inc Process for Production of Thermoplastic Vulcanizates using Supported Catalyst Systems and Compositions Made Therefrom
WO2021257264A1 (en) 2020-06-16 2021-12-23 Exxonmobil Chemical Patents Inc. Metallocene catalysts for producing vinyl-terminated polyalphaolefins and methods associated therewith
WO2021262842A1 (en) 2020-06-26 2021-12-30 Exxonmobil Chemical Patents Inc. COPOLYMERS OF ETHYLENE, α-OLEFIN, NON-CONJUGATED DIENE, AND ARYL-SUBSTITUTED CYCLOALKENE, METHODS TO PRODUCE, BLENDS, AND ARTICLES THEREFROM
WO2021262838A1 (en) 2020-06-26 2021-12-30 Exxonmobil Chemical Patents Inc. Copolymers composed of ethylene, a-olefin, non-conjugated diene, and substituted styrene and articles therefrom
CN116490528B (zh) 2020-08-13 2025-07-25 埃克森美孚化学专利公司 使用过渡金属双(酚盐)催化剂配合物得到的含有环状物的聚合物组合物及其制备方法
WO2022072180A1 (en) 2020-09-30 2022-04-07 Exxonmobil Chemical Patents Inc. Bis(heterocyclic-olate) lewis base catalysts and methods thereof
EP4225816A1 (en) 2020-10-08 2023-08-16 ExxonMobil Chemical Patents Inc. Supported catalyst systems and processes for use thereof
WO2022087121A1 (en) 2020-10-22 2022-04-28 Exxonmobil Chemical Patents Inc. Multidentate lewis base catalysts and methods for use thereof
US11919981B2 (en) 2020-10-22 2024-03-05 Exxonmobil Chemical Patents Inc. Monocyclopentadienyl pyridyl hydroxyl amine catalyst compounds and systems for olefin polymerization
US11814460B2 (en) 2020-10-22 2023-11-14 Exxonmobil Chemical Patents Inc. Pyridyl hydroxyl amine catalyst compounds and systems for Olefin Polymerization
US20230406967A1 (en) 2020-10-28 2023-12-21 Exxonmobil Chemical Patents Inc. Non-Aromatic Hydrocarbon Soluble Olefin Polymerization Catalysts and Use Thereof
US12195563B2 (en) 2020-12-29 2025-01-14 Exxonmobil Chemical Patents Inc. Polyolefin-based ionomers and production thereof
US20240084056A1 (en) 2020-12-29 2024-03-14 Exxonmobil Chemical Patents Inc. Polyolefin-Based Ionomers and Production Thereof
US12503529B2 (en) 2021-02-26 2025-12-23 Exxonmobil Chemical Patents Inc. Polymers of 4-substituted hexadiene and processes for production thereof
JP2024518830A (ja) 2021-05-14 2024-05-07 エクソンモービル ケミカル パテンツ,インコーポレイティド 粘度調整剤としてのエチレン-プロピレン分岐コポリマー
CN117377703A (zh) 2021-05-24 2024-01-09 埃克森美孚化学专利公司 两相聚合方法
EP4396246A1 (en) 2021-09-02 2024-07-10 ExxonMobil Chemical Patents Inc. C1 symmetric metallocene catalysts tailored for production of vinyl-terminated polypropylene oligomers and macromonomers
WO2023044215A1 (en) 2021-09-14 2023-03-23 Exxonmobil Chemical Patents Inc. Catalyst feeder and processes thereof
EP4437014A1 (en) 2021-11-23 2024-10-02 ExxonMobil Chemical Patents Inc. Plants and processes for forming polymers
KR20240161816A (ko) 2022-03-14 2024-11-12 엑손모빌 케미칼 패턴츠 인코포레이티드 금속 함유 비스(이미노) 과치환된(per-substituted) 아릴 화합물 및 이의 방법
EP4493567A1 (en) 2022-03-14 2025-01-22 ExxonMobil Chemical Patents Inc. Metal bis(imino) aryl compounds and methods thereof
WO2023250268A1 (en) 2022-06-24 2023-12-28 Exxonmobil Chemical Patents Inc. Constrained geometry metal-ligand complexes and use thereof in olefin polymerization
WO2024072545A1 (en) 2022-09-29 2024-04-04 Exxonmobil Chemical Patents Inc. Foamable branched polypropylene compositions and foamed products produced therefrom
WO2024167619A1 (en) 2023-02-08 2024-08-15 ExxonMobil Technology and Engineering Company Catalysts for copolymerizations
EP4665774A1 (en) 2023-02-14 2025-12-24 ExxonMobil Technology and Engineering Company Metallocene catalyst compounds having ferrocenyl substituents
WO2025080492A1 (en) 2023-10-13 2025-04-17 ExxonMobil Technology and Engineering Company Metallocene catalyst compounds for producing polyolefins
WO2025117277A1 (en) 2023-12-01 2025-06-05 ExxonMobil Technology and Engineering Company Metallocene catalyst compounds for producing polyolefins
WO2025117354A1 (en) 2023-12-01 2025-06-05 ExxonMobil Technology and Engineering Company Methods for producing impact copolymers using c1 symmetric metallocene catalysts
WO2025117379A1 (en) 2023-12-01 2025-06-05 ExxonMobil Technology and Engineering Company Formation of branched polypropylenes using dianionic complexes having eight-membered chelate rings
WO2025117332A1 (en) 2023-12-01 2025-06-05 ExxonMobil Technology and Engineering Company Methods for producing impact copolymers using dianionic complexes containing eight-membered chelate rings
WO2026024926A1 (en) 2024-07-25 2026-01-29 ExxonMobil Technology and Engineering Company Metallocene catalyst compounds for producing polyolefins
WO2026024944A1 (en) 2024-07-25 2026-01-29 ExxonMobil Technology and Engineering Company Metallocene catalyst compounds for producing polyolefins

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NZ235032A (en) * 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
US5026798A (en) * 1989-09-13 1991-06-25 Exxon Chemical Patents Inc. Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system
US5064802A (en) * 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
US5077367A (en) * 1989-09-29 1991-12-31 The Dow Chemical Company Crystalline syndiotactic copolymers from arylcyclobutene functional monomers and vinyl aromatic monomers
ES2086397T5 (es) * 1989-10-30 2005-07-16 Fina Technology, Inc. Adicion de alkiloaluminio para un catalizador metaloceno mejorado.
CA2085581C (en) * 1990-06-22 2002-07-30 Joann Marie Canich Aluminum-free monocyclopentadienyl metallocene catalysts for olefin polymerization
DE69107006T2 (de) * 1990-10-17 1995-09-21 Idemitsu Kosan Co Verfahren zur Herstellung von Oligomeren auf Basis von Propylen.
EP0513380B2 (en) * 1990-11-30 2011-02-23 Idemitsu Kosan Company Limited Process for producing olefinic polymer

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EP0802204A2 (en) 1997-10-22
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DE69224287D1 (de) 1998-03-05
KR100262023B1 (ko) 2000-07-15
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TW211018B (OSRAM) 1993-08-11
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EP0574561A1 (en) 1993-12-22
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DE69224287T2 (de) 1998-08-27
EP0802204B1 (en) 2001-12-12
DE69232297D1 (de) 2002-01-24
ES2165562T3 (es) 2002-03-16
ES2111656T3 (es) 1998-03-16
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CA2105555A1 (en) 1993-07-07

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