DE60022667T2 - Dentalmaterialien mit siliciumdioxid-nanoteilchen - Google Patents

Dentalmaterialien mit siliciumdioxid-nanoteilchen Download PDF

Info

Publication number
DE60022667T2
DE60022667T2 DE60022667T DE60022667T DE60022667T2 DE 60022667 T2 DE60022667 T2 DE 60022667T2 DE 60022667 T DE60022667 T DE 60022667T DE 60022667 T DE60022667 T DE 60022667T DE 60022667 T2 DE60022667 T2 DE 60022667T2
Authority
DE
Germany
Prior art keywords
nanoteiles
silicon dioxide
dental materials
dental
materials
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE60022667T
Other languages
German (de)
English (en)
Other versions
DE60022667D1 (de
Inventor
Xiaodong Zhang
U Kolb
A Hanggi
D Craig
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Innovative Properties Co
Original Assignee
3M Innovative Properties Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=23701047&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=DE60022667(T2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by 3M Innovative Properties Co filed Critical 3M Innovative Properties Co
Publication of DE60022667D1 publication Critical patent/DE60022667D1/de
Application granted granted Critical
Publication of DE60022667T2 publication Critical patent/DE60022667T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00—Preparations for dentistry
    • A61K6/20—Protective coatings for natural or artificial teeth, e.g. sealings, dye coatings or varnish
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00—Preparations for dentistry
    • A61K6/30—Compositions for temporarily or permanently fixing teeth or palates, e.g. primers for dental adhesives
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00—Preparations for dentistry
    • A61K6/70—Preparations for dentistry comprising inorganic additives
    • A61K6/71—Fillers
    • A61K6/76—Fillers comprising silicon-containing compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00—Preparations for dentistry
    • A61K6/80—Preparations for artificial teeth, for filling teeth or for capping teeth
    • A61K6/884—Preparations for artificial teeth, for filling teeth or for capping teeth comprising natural or synthetic resins
    • A61K6/887—Compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00—Preparations for dentistry
    • A61K6/80—Preparations for artificial teeth, for filling teeth or for capping teeth
    • A61K6/884—Preparations for artificial teeth, for filling teeth or for capping teeth comprising natural or synthetic resins
    • A61K6/891—Compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y10T428/259—Silicic material
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
    • Y10T428/2991—Coated
    • Y10T428/2993—Silicic or refractory material containing [e.g., tungsten oxide, glass, cement, etc.]
    • Y10T428/2995—Silane, siloxane or silicone coating
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
    • Y10T428/2991—Coated
    • Y10T428/2998—Coated including synthetic resin or polymer

Landscapes

  • Health & Medical Sciences (AREA)
  • Oral & Maxillofacial Surgery (AREA)
  • Epidemiology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Plastic & Reconstructive Surgery (AREA)
  • Nanotechnology (AREA)
  • Inorganic Chemistry (AREA)
  • Composite Materials (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Dental Preparations (AREA)
DE60022667T 1999-10-28 2000-02-25 Dentalmaterialien mit siliciumdioxid-nanoteilchen Expired - Lifetime DE60022667T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US42893799A 1999-10-28 1999-10-28
PCT/US2000/005089 WO2001030307A1 (en) 1999-10-28 2000-02-25 Dental materials with nano-sized silica particles

Publications (2)

Publication Number Publication Date
DE60022667D1 DE60022667D1 (de) 2005-10-20
DE60022667T2 true DE60022667T2 (de) 2006-06-14

Family

ID=23701047

Family Applications (2)

Application Number Title Priority Date Filing Date
DE60022667T Expired - Lifetime DE60022667T2 (de) 1999-10-28 2000-02-25 Dentalmaterialien mit siliciumdioxid-nanoteilchen
DE60042038T Expired - Lifetime DE60042038D1 (de) 1999-10-28 2000-02-25 Siliziumdioxid-Nanoteilchen in Form eines trockenen Pulvers

Family Applications After (1)

Application Number Title Priority Date Filing Date
DE60042038T Expired - Lifetime DE60042038D1 (de) 1999-10-28 2000-02-25 Siliziumdioxid-Nanoteilchen in Form eines trockenen Pulvers

Country Status (7)

Country Link
US (1) US6899948B2 (https=)
EP (2) EP1227781B9 (https=)
JP (2) JP4800535B2 (https=)
AU (1) AU3505400A (https=)
CA (1) CA2387215C (https=)
DE (2) DE60022667T2 (https=)
WO (1) WO2001030307A1 (https=)

Families Citing this family (240)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030134035A1 (en) * 1997-03-20 2003-07-17 Unisearch Limited, A.C.N. 000 263 025 Hydrophobic films
AU3505400A (en) 1999-10-28 2001-05-08 3M Innovative Properties Company Dental materials with nano-sized silica particles
US6730156B1 (en) * 1999-10-28 2004-05-04 3M Innovative Properties Company Clustered particle dental fillers
US6537563B2 (en) * 2000-05-11 2003-03-25 Jeneric/Pentron, Inc. Dental acid etchant composition and method of use
US7709029B2 (en) * 2001-01-24 2010-05-04 Ada Foundation Calcium-containing restoration materials
US6890968B2 (en) 2001-05-16 2005-05-10 Kerr Corporation Prepolymerized filler in dental restorative composite
US6593395B2 (en) 2001-05-16 2003-07-15 Kerr Corporation Dental composition containing discrete nanoparticles
JP5329734B2 (ja) 2001-08-15 2013-10-30 スリーエム イノベイティブ プロパティズ カンパニー 硬化性自己支持形構造および方法
EP1425352B1 (en) 2001-09-11 2005-01-12 3M Innovative Properties Company Smudge resistant nanocomposite hardcoats and methods for making same
FR2833484B1 (fr) * 2001-12-18 2004-12-10 Rhodia Chimie Sa Composition dentaire a base de solution de silice colloidale en phase continue silicone
US7393882B2 (en) 2002-01-31 2008-07-01 3M Innovative Properties Company Dental pastes, dental articles, and methods
US7008229B2 (en) 2002-04-12 2006-03-07 3M Innovative Properties Company Stainless steel dental crowns with a polyester/epoxy coating
US6773261B2 (en) 2002-06-28 2004-08-10 3M Innovative Properties Company Processes for forming dental materials
US7134875B2 (en) 2002-06-28 2006-11-14 3M Innovative Properties Company Processes for forming dental materials and device
US7091259B2 (en) 2002-07-03 2006-08-15 3M Innovative Properties Company Dental fillers, pastes, and compositions prepared therefrom
US20040206932A1 (en) 2002-12-30 2004-10-21 Abuelyaman Ahmed S. Compositions including polymerizable bisphosphonic acids and methods
US7396862B2 (en) * 2003-02-06 2008-07-08 Weimer Alan W Dental composite filler particles
TWI236374B (en) * 2003-02-13 2005-07-21 Univ Nat Taiwan Light curable epoxy nano composite for dental restorative material
US7084182B2 (en) * 2003-03-13 2006-08-01 Tokuyama Corporation Photopolymerization initiator
US7282195B2 (en) * 2003-04-10 2007-10-16 Macdougald Ian T Flavored sealants
KR100708882B1 (ko) 2003-04-15 2007-04-17 (주) 보람케메탈 흄드 실리카를 이용한 나노 실리카 결정 분말의 제조방법
US7235118B2 (en) * 2003-04-16 2007-06-26 National Research Council Of Canada Process for agglomeration and densification of nanometer sized particles
US20040241609A1 (en) * 2003-05-08 2004-12-02 Weitao Jia Method of manufacturing high strength dental restorations
US7998375B2 (en) * 2003-05-08 2011-08-16 Pentron Clinical Technologies, Llc Method of manufacturing high strength dental restorations
JP5570091B2 (ja) * 2003-05-13 2014-08-13 デンツプライ インターナショナル インコーポレーテッド 歯科用接着剤組成物および方法
DE60305025T2 (de) 2003-07-14 2006-10-12 3M Espe Ag Klebstoffzusammensetzung mit verringerter Polarität nach der Polymerisation
EP1502570A1 (de) * 2003-08-01 2005-02-02 Nanosolutions GmbH Röntgenopakes Dentalmaterial mit oberflächenmodifizierten Nanopartikeln
US7632098B2 (en) 2003-08-12 2009-12-15 3M Innovative Properties Company Self-adhesive dental compositions and methods
US7250452B2 (en) 2003-09-26 2007-07-31 3M Innovative Properties Company Dental compositions and methods with arylsulfinate salts
US7026367B2 (en) 2003-09-26 2006-04-11 3M Innovative Properties Company Photoiniators having triarylsulfonium and arylsulfinate ions
US7030169B2 (en) 2003-09-26 2006-04-18 3M Innovative Properties Company Arylsulfinate salts in initiator systems for polymeric reactions
US7064152B2 (en) 2003-09-26 2006-06-20 3M Innovative Properties Company Arylsulfinate salts in photoinitiator systems for polymerization reactions
US7189768B2 (en) * 2003-11-25 2007-03-13 3M Innovative Properties Company Solution containing surface-modified nanoparticles
US20050132928A1 (en) * 2003-12-22 2005-06-23 Culp Terry L. Dental composites placement techniques for direct restorations
DE102005002845A1 (de) * 2004-02-18 2005-09-15 Heraeus Kulzer Gmbh Dispersionen nanoskaliger, nicht-agglomerierter Teilchen zum Einsatz in Dentalmaterialien
US20060004121A1 (en) * 2004-03-10 2006-01-05 Xingzhe Ding Polymer-brush modified fillers for composites
KR100858373B1 (ko) * 2004-04-15 2008-09-17 덴토피트 에이/에스 치과용 충전재의 초음파 경화방법
EP1737415B1 (en) * 2004-04-15 2008-05-07 Dentofit A/S Ultrasonic curing of dental filling materials
NZ550000A (en) * 2004-04-15 2009-06-26 Dentofit As Ultrasonic curing of dental filling materials
US7090721B2 (en) 2004-05-17 2006-08-15 3M Innovative Properties Company Use of nanoparticles to adjust refractive index of dental compositions
US7156911B2 (en) 2004-05-17 2007-01-02 3M Innovative Properties Company Dental compositions containing nanofillers and related methods
US7649029B2 (en) * 2004-05-17 2010-01-19 3M Innovative Properties Company Dental compositions containing nanozirconia fillers
US7090722B2 (en) 2004-05-17 2006-08-15 3M Innovative Properties Company Acid-reactive dental fillers, compositions, and methods
DE102004025030A1 (de) * 2004-05-18 2005-12-15 S&C Polymer Silicon- und Composite-Spezialitäten GmbH Nano-Apatit-Füllstoffe enthaltende härtbare Restaurationsmaterialien
US8465284B2 (en) 2004-07-08 2013-06-18 3M Innovative Properties Company Dental methods, compositions, and kits including acid-sensitive dyes
CN101018536A (zh) * 2004-07-14 2007-08-15 3M埃斯佩股份公司 含环氧官能可聚合化合物的牙科组合物
EP1765262B1 (en) 2004-07-14 2009-03-04 3M Espe AG Dental composition containing unsaturated halogenated aryl alkyl ether components
DE602004029510D1 (de) 2004-07-14 2010-11-18 3M Espe Ag Dentalzusammensetzung mit einer epoxy-funktionalen carbosilan-verbindung
AU2005275246B2 (en) 2004-07-14 2011-10-06 3M Deutschland Gmbh Dental compositions containing carbosilane monomers
JP4879894B2 (ja) 2004-07-14 2012-02-22 スリーエム イノベイティブ プロパティズ カンパニー カルボシランポリマーを含有する歯科用組成物
US20060035997A1 (en) 2004-08-10 2006-02-16 Orlowski Jan A Curable acrylate polymer compositions featuring improved flexural characteristics
EP1784155B1 (en) 2004-08-11 2011-09-28 3M Innovative Properties Company Self-adhesive compositions including a plurality of acidic compounds
FR2874498B1 (fr) * 2004-08-31 2006-11-24 Coste Bruno Clunet Element d'obturation et d'ancrage dentaire prefabrique en materiau composite radio opaque et translucide
EP2062561B1 (en) * 2004-10-14 2016-06-15 DENTSPLY International Inc. One-component self-etching adhesive
CA2587556A1 (en) 2004-11-16 2006-05-26 3M Innovative Properties Company Dental fillers including a phosphorus containing surface treatment, and compositions and methods thereof
KR101240883B1 (ko) 2004-11-16 2013-03-07 쓰리엠 이노베이티브 프로퍼티즈 컴파니 카제이네이트를 포함하는 치과용 충전제, 방법, 조성물
US8957126B2 (en) 2004-11-16 2015-02-17 3M Innovative Properties Company Dental compositions with calcium phosphorus releasing glass
EP1819313B1 (en) 2004-11-16 2010-12-29 3M Innovative Properties Company Dental fillers and compositions including phosphate salts
CN102512329A (zh) 2005-05-09 2012-06-27 3M创新有限公司 含有杂化单体的牙科组合物
US20060270752A1 (en) * 2005-05-26 2006-11-30 Ada Foundation Dental releasing materials
US20070123604A1 (en) * 2005-05-26 2007-05-31 Ada Foundation Dental releasing materials
EP1909742B1 (en) 2005-08-05 2010-07-14 3M Espe AG Dental compositions containing a surface-modified filler
DE102005041014A1 (de) * 2005-08-29 2007-03-01 Heraeus Kulzer Gmbh Lichthärtendes, selbstätzendes Nanopartikel enthaltendes Einkomponenten-Dentaladhäsiv
US7855242B2 (en) * 2005-09-01 2010-12-21 Pentron Clinical Technologies Llc Dental resin composition, method of manufacture, and method of use thereof
WO2007028159A2 (en) * 2005-09-02 2007-03-08 Dentsply International Inc. Dental sealant compositions containing nanometer- sized silica
US7495054B2 (en) 2005-09-19 2009-02-24 3M Innovative Properties Company Curable compositions containing dithiane monomers
BRPI0520560B8 (pt) * 2005-09-22 2023-03-07 Micerium Spa material dentário
EP1787627A1 (en) 2005-11-17 2007-05-23 3M Innovative Properties Company Anti-microbial dental impression material
US7776940B2 (en) 2005-12-20 2010-08-17 3M Innovative Properties Company Methods for reducing bond strengths, dental compositions, and the use thereof
US7658870B2 (en) * 2005-12-20 2010-02-09 University Of Hawaii Polymer matrix composites with nano-scale reinforcements
US8026296B2 (en) 2005-12-20 2011-09-27 3M Innovative Properties Company Dental compositions including a thermally labile component, and the use thereof
US7896650B2 (en) 2005-12-20 2011-03-01 3M Innovative Properties Company Dental compositions including radiation-to-heat converters, and the use thereof
DE102005061965A1 (de) * 2005-12-23 2007-07-05 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Oxidische Agglomeratpartikel, Verfahren zur Herstellung von Nanokompositen sowie deren Verwendung
US20080306168A1 (en) * 2005-12-29 2008-12-11 Craig Bradley D Dental Compositions with a Water Scavenger
WO2007079070A1 (en) 2005-12-29 2007-07-12 3M Innovative Properties Company Dental compositions and initiator systems with polycyclic aromatic component
US8071662B2 (en) 2005-12-29 2011-12-06 3M Innovative Properties Company Dental compositions with surface-treated filler for shelf stability
US7556743B2 (en) * 2006-03-06 2009-07-07 Southwest Research Institute Nanocomposites and methods for synthesis and use thereof
EP1849449A1 (en) * 2006-04-26 2007-10-31 3M Innovative Properties Company Filler containing composition and process for production and use thereof
JP2007314773A (ja) * 2006-04-28 2007-12-06 Mitsubishi Chemicals Corp 高屈折率粒子含有樹脂組成物
EP1881010B1 (en) 2006-05-31 2010-08-11 3M Innovative Properties Company Polymerizable compositions containing salts of barbituric acid derivatives
CN101516319B (zh) 2006-09-13 2015-11-25 3M创新有限公司 包含有机凝胶因子的牙科用组合物、产品及方法
US7498197B2 (en) * 2006-09-13 2009-03-03 Delphi Technologies, Inc. Silica nanoparticles thermoset resin compositions
US8202502B2 (en) * 2006-09-15 2012-06-19 Cabot Corporation Method of preparing hydrophobic silica
US8435474B2 (en) * 2006-09-15 2013-05-07 Cabot Corporation Surface-treated metal oxide particles
US8455165B2 (en) * 2006-09-15 2013-06-04 Cabot Corporation Cyclic-treated metal oxide
US20080070146A1 (en) 2006-09-15 2008-03-20 Cabot Corporation Hydrophobic-treated metal oxide
US20080096150A1 (en) 2006-10-23 2008-04-24 3M Innovative Properties Company Dental articles, methods, and kits including a compressible material
US9539065B2 (en) 2006-10-23 2017-01-10 3M Innovative Properties Company Assemblies, methods, and kits including a compressible material
DE102006054879B4 (de) * 2006-11-20 2008-09-11 Heraeus Kulzer Gmbh Polymerisierbares Dentalmaterial auf der Basis von Methylmethacrylaten, geeignet zur Herstellung von Prothesenkunststoff
JP5507256B2 (ja) 2006-12-13 2014-05-28 スリーエム イノベイティブ プロパティズ カンパニー 酸性成分及び光退色性染料を有する歯科用組成物の使用方法
WO2008082929A2 (en) 2006-12-28 2008-07-10 3M Innovative Properties Company Adhesive composition for hard tissue
EP2114351B1 (en) * 2006-12-28 2016-07-13 3M Innovative Properties Company Dental compositions with natural tooth fluorescence
JP5512280B2 (ja) * 2006-12-28 2014-06-04 スリーエム イノベイティブ プロパティズ カンパニー 歯科充填剤及び方法
FR2911494B1 (fr) 2007-01-19 2009-04-10 Rech S Tech Dentaires R T D Sa Element prothetique dentaire radio-opaque
EP2119425B1 (en) * 2007-02-08 2019-06-12 Kuraray Noritake Dental Inc. Dental composition
US20080214689A1 (en) * 2007-03-02 2008-09-04 Cheng-Chien Yang Manufacturing method and foaming manufacturing method of polymethyl methacrylate/silica composite material
WO2008140800A2 (en) 2007-05-11 2008-11-20 Dentsply International Inc. Dental compositions for coating restorations and tooth surfaces
US20080286724A1 (en) 2007-05-18 2008-11-20 Ormco Corporation Orthodontic adhesives
US8735463B2 (en) 2007-05-31 2014-05-27 Creighton University Self-healing dental composites and related methods
EP2008636A1 (en) * 2007-06-29 2008-12-31 3M Innovative Properties Company Dental composition containing a polyfunctional (meth)acrylate comprising urethane, urea or amide groups, method of production and use thereof
EP2025381A1 (de) * 2007-07-30 2009-02-18 Nanoresins AG Verfahren zum Entfernen basischer oder saurer Verbindungen aus einer lösungsmittelhaltigen Metalloxiddispersion insbesondere Kieselsäure
EP2042486A1 (en) * 2007-09-26 2009-04-01 3M Innovative Properties Company Methacrylate Based Monomers containing a Urethane Linkage, Process for Production and Use thereof
EP2203144A2 (en) 2007-10-01 2010-07-07 3M Innovative Properties Company Orthodontic composition with polymeric fillers
JP5461415B2 (ja) 2007-11-01 2014-04-02 スリーエム イノベイティブ プロパティズ カンパニー 歯科用組成物及び色安定アミン電子供与体を有する開始剤系
WO2009075977A1 (en) 2007-12-13 2009-06-18 3M Innovative Properties Company Orthodontic article having partially hardened composition and method of its use and manufacture
EP2072028A1 (de) 2007-12-21 2009-06-24 Ernst Mühlbauer GmbH & Co.KG Stumpfaufbaumaterial
EP2133063A1 (en) 2008-06-10 2009-12-16 3M Innovative Properties Company Initiator system with biphenylene derivates, method of production and use thereof
EP2133064A1 (en) 2008-06-10 2009-12-16 3M Innovative Properties Company Initiator system containing a diarylalkylamine derivate, hardenable composition and use thereof
WO2009152404A1 (en) * 2008-06-12 2009-12-17 3M Innovative Properties Company Methods of compounding nanoparticles with a resin
EP2153812B1 (de) * 2008-08-13 2014-11-26 Mühlbauer Technology GmbH Röntgenopaker Infiltrant
BRPI0913521A2 (pt) * 2008-09-04 2015-10-13 3M Innovative Properties Co composição dental endurecível e artigo dental
US20100068523A1 (en) * 2008-09-16 2010-03-18 Aveka, Incorporated Surface modification of and dispersion of particles
BRPI0914427C8 (pt) 2008-10-15 2018-07-24 3M Innovative Properties Co composição dental endurecível
CN102224106A (zh) * 2008-10-15 2011-10-19 3M创新有限公司 具有氧化锆和二氧化硅纳米粒子的填料和复合材料
BRPI0914464A2 (pt) * 2008-10-22 2015-10-27 3M Innovative Properties Co "composição dentária endurecível, artigos dentários e monômero bifenil di(met)acrilato"
MX2011005567A (es) * 2008-11-25 2012-01-25 Procter & Gamble Composiciones para el cuidado bucal con estetica mejorada y silicio fundido.
US8551457B2 (en) 2008-11-25 2013-10-08 The Procter & Gamble Company Oral care compositions comprising spherical fused silica
JP5855943B2 (ja) 2008-12-19 2016-02-09 スリーエム イノベイティブ プロパティズ カンパニー ナノカルサイト複合材料
US20100189663A1 (en) * 2009-01-24 2010-07-29 Gallis Karl W Mouth rinse compositions including chemically modified silica or silicate materials for sustained delivery to tooth surfaces
DE102009006173A1 (de) * 2009-01-26 2010-07-29 Ernst Mühlbauer Gmbh & Co. Kg Dentalmaterial
ES2464495T3 (es) 2009-07-30 2014-06-03 3M Innovative Properties Company Tobera y método para hacer la misma
JP5800812B2 (ja) 2009-08-28 2015-10-28 スリーエム イノベイティブ プロパティズ カンパニー 重合性イオン液体混合物を含む組成物及び物品並びに硬化方法
US8742047B2 (en) 2009-08-28 2014-06-03 3M Innovative Properties Company Polymerizable ionic liquid comprising multifunctional cation and antistatic coatings
US9783681B2 (en) 2009-10-21 2017-10-10 3M Innovative Properties Company Solventless functionalization, milling, and compounding process with reactive diluents
CN102656221B (zh) 2009-12-17 2015-03-25 3M创新有限公司 高镁表面浓度的纳米方解石复合材料
EP2513214A1 (en) 2009-12-17 2012-10-24 3M Innovative Properties Company Nanocalcite and vinyl ester composites
EP2515827A2 (en) 2009-12-22 2012-10-31 3M Innovative Properties Company Curable dental compositions and articles comprising polymerizable ionic liquids
RU2557961C2 (ru) 2009-12-22 2015-07-27 3М Инновейтив Пропертиз Компани Стоматологические композиции, заготовки для стоматологического протезирования и способы
US20110206749A1 (en) * 2010-02-19 2011-08-25 J.M. Huber Corporation Silica materials for reducing oral malador
US20110236444A1 (en) * 2010-03-25 2011-09-29 Darsillo Michael S Antimicrobial Silica Composites
EP2552380B1 (en) 2010-03-31 2019-04-24 3M Innovative Properties Company Polymerizable isocyanurate monomers and dental compositions
WO2011133331A1 (en) 2010-04-20 2011-10-27 3M Innovative Properties Company Pressure sensitive adhesives containing reactive, surface-modified nanoparticles
WO2011133228A2 (en) 2010-04-23 2011-10-27 Pixelligent Technologies, Llc Synthesis, capping and dispersion of nanocrystals
RU2565414C2 (ru) 2010-05-25 2015-10-20 3М Инновейтив Пропертиз Компани Метод обработки поверхности частиц неорганического оксида, твердеющие стоматологические композиты, частицы с обработанной поверхностью и соединения для обработки поверхности
EP2401998A1 (en) 2010-07-02 2012-01-04 3M Innovative Properties Company Dental composition, kit of parts and use thereof
EP2412361A1 (en) 2010-07-29 2012-02-01 3M Innovative Properties Company Kit of parts, method of producing and use thereof
WO2012027091A1 (en) 2010-08-11 2012-03-01 3M Innovative Properties Company Dental articles including a ceramic and microparticle coating and method of making the same
WO2012021442A1 (en) 2010-08-11 2012-02-16 3M Innovative Properties Company Coated dental crows and method of making the same
EP2603159A1 (en) 2010-08-11 2013-06-19 3M Innovative Properties Company Aesthetic and abrasion resistant coated dental articles and methods of making the same
US20130130203A1 (en) 2010-08-11 2013-05-23 3M Innovative Properties Company Polymer coated dental articles and method of making the same
EP2616476A2 (en) 2010-09-15 2013-07-24 3M Innovative Properties Company Substituted saccharide compounds and dental compositions
EP2436366B1 (de) 2010-09-30 2015-07-29 VOCO GmbH Kompositmaterial umfassend ein Monomer mit einem polyalicyclischen Strukturelement als Versiegelungsmaterial
EP2436364B1 (de) 2010-09-30 2017-05-31 VOCO GmbH Lackzusammensetzung umfassend ein Monomer mit einem polyalicyclischen Strukturelement
EP3190083B1 (en) 2010-10-27 2020-08-26 Pixelligent Technologies, LLC Synthesis, capping and dispersion of nanocrystals
JP5824061B2 (ja) * 2010-10-27 2015-11-25 スリーエム イノベイティブ プロパティズ カンパニー 半結晶性樹脂とナノクラスター充填剤とを含む歯科用組成物
CN103281986B (zh) 2010-12-30 2016-08-17 3M创新有限公司 包括可压缩材料的可粘合牙科用组件和方法
EP2481390A1 (en) 2011-01-31 2012-08-01 3M Innovative Properties Company Dental composition, method of producing and use thereof
CA2826443A1 (en) 2011-02-02 2012-08-09 3M Innovative Properties Company Nozzle and method of making same
EP2675422B1 (en) 2011-02-15 2020-09-30 3M Innovative Properties Company Dental compositions comprising ethylenically unsaturated addition-fragmentation agent
WO2012112321A2 (en) 2011-02-15 2012-08-23 3M Innovative Properties Company Dental compositions comprising mixture of isocyanurate monomer and tricyclodecane monomer
EP2688508A1 (en) 2011-03-24 2014-01-29 3M Innovative Properties Company Dental adhesive comprising a coated polymeric component
US8431626B2 (en) 2011-05-18 2013-04-30 3M Innovative Properties Company Disulfide monomers comprising ethylenically unsaturated norbornyl groups suitable for dental compositions
US8455565B2 (en) 2011-05-18 2013-06-04 3M Innovative Properties Company Disulfide monomers comprising ethylenically unsaturated groups suitable for dental compositions
EP2726049B1 (en) 2011-06-29 2022-08-17 3M Innovative Properties Company Dental compositions comprising a fatty mono(meth)acrylate
US9173820B2 (en) 2011-08-11 2015-11-03 3M Innovative Properties Company Dental composition, method of producing and use thereof
WO2013028397A2 (en) 2011-08-23 2013-02-28 3M Innovative Properties Company Dental compositions comprising addition-fragmentation agents
EP2578200B1 (de) 2011-10-04 2018-03-28 VOCO GmbH Zusammensetzungen zum Infiltrieren und/oder Versiegeln von Zahnhartsubstanz und entsprechende Verfahren
US9359689B2 (en) 2011-10-26 2016-06-07 Pixelligent Technologies, Llc Synthesis, capping and dispersion of nanocrystals
CN104053627B (zh) 2011-11-02 2018-06-01 3M创新有限公司 制造喷嘴的方法
CN104114142B (zh) 2011-12-01 2016-12-21 3M创新有限公司 单组分自粘合牙科组合物、其制备和使用方法
EP2604247A1 (en) * 2011-12-15 2013-06-19 Dentsply DeTrey GmbH Composite filler particles and process for the preparation thereof
US8999371B2 (en) 2012-03-19 2015-04-07 Arges Imaging, Inc. Contrast pattern application for three-dimensional imaging
US9381140B2 (en) 2012-08-31 2016-07-05 Kettenbach Gmbh & Co. Kg Radically polymerisable dental material, cured product and usage
US8986003B2 (en) 2012-09-13 2015-03-24 Orthoaccel Technologies, Inc. Pearlescent white aligners
AU2013337356B2 (en) 2012-11-05 2016-12-08 The Procter & Gamble Company Heat treated precipitated silica
JP6351608B2 (ja) 2012-11-12 2018-07-04 スリーエム イノベイティブ プロパティズ カンパニー 付加開裂剤を含む歯科用組成物
WO2014099317A1 (en) 2012-12-17 2014-06-26 3M Innovative Properties Company Addition-fragmentation oligomers
CN105051007B (zh) 2013-03-20 2020-03-13 3M创新有限公司 高折射率加成-断裂剂
EP2986269A1 (en) 2013-04-15 2016-02-24 3M Innovative Properties Company Dental composition containing high refractive index monomers
DE102013007894A1 (de) 2013-05-08 2014-11-13 Heraeus Kulzer Gmbh Langlebiges Dentalmaterial mit verbesserten transparenten Eigenschaften
BR112016000433B1 (pt) 2013-07-08 2020-12-08 3M Innovative Properties Company composição dental endurecível contendo uma mistura de nanopartículas aglomeradas e agregadas
EP3046962B1 (en) 2013-09-20 2018-05-23 3M Innovative Properties Company Trithiocarbonate-containing addition-fragmentation agents
CN105705112B (zh) 2013-10-04 2018-02-27 3M创新有限公司 牙科研磨坯料、牙科修复体以及形成牙科研磨坯料的方法
CN105683257B (zh) 2013-10-16 2018-02-13 3M创新有限公司 包含烯丙基二硫化物的加成‑断裂低聚物
WO2015126862A1 (en) 2014-02-18 2015-08-27 3M Innovative Properties Company Dental composition and use thereof
US9730864B2 (en) 2014-02-18 2017-08-15 3M Innovative Properties Company Addition-fragmentation oligomers having high refractive index groups
DE102014107518A1 (de) * 2014-05-28 2015-12-03 Heraeus Kulzer Gmbh Reaktiver Mikro-Applikator mit Metall enthaltenden Additiven zur Verwendung mit dental Adhäsiven
JP2017522418A (ja) 2014-06-27 2017-08-10 コーニング インコーポレイテッド エポキシ／オキセタン化合物、エポキシ官能化シルセスキオキサンおよびエポキシ官能化ナノ粒子に基づく、ガラス向けｕｖ硬化性コーティング組成物
RU2683315C2 (ru) 2014-07-10 2019-03-28 3М Инновейтив Пропертиз Компани Двухкомпонентный самоклеящийся стоматологический состав, способ его изготовления и применения
US10709529B2 (en) * 2014-07-31 2020-07-14 3M Innovative Properties Company Kit of parts containing dental mill blank colouring solution
DE102014013807A1 (de) * 2014-09-23 2016-03-24 Dph Dental Partner Holding Gmbh Verfahren zur Präparation von dentalen Werkstücken mit reflektierenden Oberflächen
WO2016060845A1 (en) 2014-10-14 2016-04-21 3M Innovative Properties Company Dental articles and methods of using same
US10350297B2 (en) 2014-10-31 2019-07-16 3M Innovative Properties Company Dental materials and methods
WO2016069290A1 (en) 2014-10-31 2016-05-06 3M Innovative Properties Company Dental materials and methods
US10479848B2 (en) 2015-02-20 2019-11-19 3M Innovative Properties Company Addition-fragmentation oligomers
JP6659716B2 (ja) 2015-03-05 2020-03-04 スリーエム イノベイティブ プロパティズ カンパニー セラミック繊維を有する複合材料
KR101746793B1 (ko) 2015-07-22 2017-06-14 주식회사 쿠보텍 금속 산화물을 함유하는 치과용 시멘트
DE102015012793A1 (de) * 2015-10-05 2017-04-06 Birgit Stührenberg Dentale Kompetenz GmbH & Co. KG Verblendelement zur Abdeckung einer Zahnoberfläche, Verfahren zur Herstellung des Verblendelements und Schichtaufbau mit dem Verblendelement
WO2017078883A1 (en) 2015-11-06 2017-05-11 3M Innovative Properties Company Redox polymerizable composition with photolabile transition metal complexes
CN108348404B (zh) 2015-11-06 2021-06-08 3M创新有限公司 利用光不稳定过渡金属络合物的氧化还原可聚合牙科用组合物
WO2017095704A1 (en) 2015-12-03 2017-06-08 3M Innovative Properties Company Redox polymerizable composition with photolabile reducing agents
WO2017100231A1 (en) 2015-12-08 2017-06-15 3M Innovative Properties Company Two-component self-adhesive dental composition, storage stable initiator system, and use thereof
EP3411006A1 (en) 2016-02-05 2018-12-12 3M Innovative Properties Company Dental compositions comprising nanoparticles providing a refractive index differential between polymerizable resin and filler
CN119587186A (zh) 2016-03-07 2025-03-11 舒万诺知识产权公司 预成形复合牙冠、其生产方法和用途
US11208562B2 (en) 2016-03-25 2021-12-28 Nippon Shokubai Co., Ltd. Zirconium oxide nanoparticles
KR20190022777A (ko) 2016-06-30 2019-03-06 쓰리엠 이노베이티브 프로퍼티즈 컴파니 고점성 성분을 포함하는 인쇄가능 조성물 및 그로부터 3d 물품을 생성하는 방법
EP3507011B1 (en) * 2016-09-02 2024-06-26 3M Innovative Properties Company Shaped gel articles and sintered articles prepared therefrom
WO2018048777A1 (en) 2016-09-06 2018-03-15 3M Innovative Properties Company Methods of improving dental restoration margins and articles
US10968197B2 (en) 2016-10-20 2021-04-06 3M Innovative Properties Company Photoinitiators with protected carbonyl group
JP7245775B2 (ja) 2016-12-01 2023-03-24 スリーエム イノベイティブ プロパティズ カンパニー 生体担体材料に使用するのに好適な無機シェル内に封入された塩基性コア材料
JP6793241B2 (ja) * 2017-02-27 2020-12-02 株式会社ジーシー 歯科用硬化性組成物
CN110678160B (zh) 2017-05-15 2022-12-30 3M创新有限公司 牙科用粘合剂组合物，其制备和用途
EP3624754A1 (en) 2017-05-18 2020-03-25 3M Innovative Properties Company Glass ionomer compositions and methods including water-miscible, silane-treated, nano-sized silica particles
CN110785158B (zh) 2017-06-14 2023-06-13 3M创新有限公司 用于制备牙科复合冠的可固化组合物和制备方法
US11553996B2 (en) 2017-09-11 2023-01-17 3M Innovative Properties Company Radiation curable compositions and composite articles made using an additive manufacturing process
CN111093559B (zh) * 2017-09-26 2022-07-12 可乐丽则武齿科株式会社 牙科用研磨坯料和其制造方法
CN111315341B (zh) 2017-11-08 2021-06-04 3M创新有限公司 具有高e-模量的牙科用组合物
EP3706708B1 (en) 2017-11-08 2022-01-12 3M Innovative Properties Company Radiopaque dental composition
CN111433268B (zh) 2017-11-29 2022-07-05 康宁股份有限公司 高度负载的无机填充的水性树脂体系
WO2019123260A2 (en) 2017-12-19 2019-06-27 3M Innovative Properties Company Multi-part composition having staged viscosity prior to hardening
WO2019123263A2 (en) 2017-12-21 2019-06-27 3M Innovative Properties Company Inorganic dental fillers including a silane treated surface
US11912860B2 (en) 2018-03-29 2024-02-27 Corning Incorporated Highly loaded inorganic filled organic resin systems
US12070514B2 (en) 2018-05-02 2024-08-27 Solventum Intellectual Properties Company One-part dental adhesive composition for fixing dental composite materials
US12102499B2 (en) 2018-06-06 2024-10-01 Solventum Intellectual Properties Company Two-part dental sealant, method of applying with a syringe device, and kit
EP3801360A1 (en) 2018-06-06 2021-04-14 3M Innovative Properties Company Hardenable dental compositions comprising basic core material encapsulated in an inorganic shell and dispensing devices therewith
CN111295175A (zh) 2018-08-08 2020-06-16 株式会社Gc 牙科用固化性组合物
CN112673035B (zh) 2018-09-14 2024-04-19 舒万诺知识产权公司 包含陶瓷纤维和纳米团簇的复合材料、牙科产品、套件盒及其制备和使用方法
US11642199B2 (en) 2018-09-24 2023-05-09 3M Innovative Properties Company Dental appliance with cosmetic therapeutic aqueous solution
EP3864002B1 (en) 2018-10-09 2023-12-27 3M Innovative Properties Company Addition-fragmentation agent with pendent amine groups
WO2020100041A1 (en) 2018-11-14 2020-05-22 3M Innovative Properties Company Storage stable two-component dual cure dental composition
KR102198371B1 (ko) * 2019-10-18 2021-01-05 연세대학교 산학협력단 치과용 조성물 및 이를 포함하는 치과 교정술 장치 제조 방법
US12590211B2 (en) 2019-11-27 2026-03-31 Corning Incorporated Compositions and methods of making a green body or a printed article using the same
US12209172B2 (en) 2020-04-08 2025-01-28 3M Innovative Properties Company Curable compositions and methods of using the same
US12466908B2 (en) 2020-04-08 2025-11-11 3M Innovative Properties Company Curable compositions and methods of using the same
US11404289B2 (en) * 2020-08-31 2022-08-02 Micron Technology, Inc. Semiconductor device assembly with graded modulus underfill and associated methods and systems
JP2023547191A (ja) 2020-10-28 2023-11-09 スリーエム イノベイティブ プロパティズ カンパニー 光重合性組成物を処理するための方法及びシステム
US12404419B2 (en) 2020-11-05 2025-09-02 3M Innovative Properties Company Imide addition-fragmentation agents
WO2022112886A1 (en) 2020-11-25 2022-06-02 3M Innovative Properties Company Curable dental compositions and uses thereof
EP4271322A1 (en) 2020-12-30 2023-11-08 3M Innovative Properties Company Bondable orthodontic assemblies and methods for bonding
EP4308571A1 (en) 2021-03-17 2024-01-24 3M Innovative Properties Company Polymerizable 4,4'-spirobi[chromane]-2,2'-diones and curable compositions including the same
US20240199919A1 (en) 2021-04-19 2024-06-20 3M Innovative Properties Company Adhesive layer for flexographic plate mounting tape
EP4444809A1 (en) 2021-12-06 2024-10-16 3M Innovative Properties Company Adhesives comprising cyclic imide addition-fragmentation and adhesion agents
WO2023105315A1 (en) 2021-12-06 2023-06-15 3M Innovative Properties Company Dental compositions
JP2023151496A (ja) 2022-03-31 2023-10-16 株式会社ジーシー 処理シリカ分散単量体組成物の製造方法
EP4514304B1 (en) 2022-04-26 2026-03-25 Solventum Intellectual Properties Company Dental composition containing a resorcinol or catechol moiety containing component and use thereof
DE102022116932A1 (de) * 2022-07-07 2024-01-18 Voco Gmbh Herstellung von dentalen Fräsrohlingen
WO2024018305A1 (en) 2022-07-21 2024-01-25 3M Innovative Properties Company Curable composition for producing transparent orthodontic attachments
CN120187382A (zh) 2022-11-25 2025-06-20 舒万诺知识产权公司 在处理患者口腔中的牙齿状况的方法中使用的可固化组合物
JP2025540069A (ja) 2022-12-06 2025-12-11 ソルベンタム インテレクチュアル プロパティズ カンパニー 表面処理された充填剤、このような充填剤を含有する歯科用組成物、その製造方法及び使用
WO2026078464A1 (en) 2024-10-08 2026-04-16 Solventum Intellectual Properties Company Multi-part medical composition and use thereof

Family Cites Families (184)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2801185A (en) † 1952-05-16 1957-07-30 Du Pont Silica hydrosol powder
US2948628A (en) * 1955-08-02 1960-08-09 Horizons Inc Method of making ceramic dielectric
US2984628A (en) 1956-11-29 1961-05-16 Du Pont Concentrated zirconia and hafnia aquasols and their preparation
US3018262A (en) 1957-05-01 1962-01-23 Shell Oil Co Curing polyepoxides with certain metal salts of inorganic acids
US3179623A (en) 1959-01-30 1965-04-20 Rafael L Bowen Method of preparing a monomer having phenoxy and methacrylate groups linked by hydroxy glyceryl groups
US3066112A (en) 1959-01-30 1962-11-27 Rafael L Bowen Dental filling material comprising vinyl silane treated fused silica and a binder consisting of the reaction product of bis phenol and glycidyl acrylate
NL128404C (https=) 1959-12-24
US3442817A (en) 1966-04-15 1969-05-06 Du Pont Preparation of zirconia and hafnia sols
US3514252A (en) 1967-07-07 1970-05-26 Grace W R & Co Process for the preparation of stabilized zirconia powders
US3860556A (en) 1968-03-15 1975-01-14 Minnesota Mining & Mfg Low water absorption dental restorative
CA878004A (en) 1968-06-14 1971-08-10 Johnson And Johnson Dental filling package
US3539533A (en) 1968-06-14 1970-11-10 Johnson & Johnson Dental filling material
US3708296A (en) 1968-08-20 1973-01-02 American Can Co Photopolymerization of epoxy monomers
US3709706A (en) 1969-05-16 1973-01-09 Minnesota Mining & Mfg Refractory fibers and other articles of zirconia and silica mixtures
US3629187A (en) 1969-06-25 1971-12-21 Dentsply Int Inc Dental compositions containing adduct of 2 2' - propane bis 3-(4-phenoxy)-1 2-hydroxy propane - 1 - methacrylate and isocyanate
US3709866A (en) 1970-06-01 1973-01-09 Dentsply Int Inc Photopolymerizable dental products
US3766132A (en) 1971-02-12 1973-10-16 Lee Pharmaceuticals Diacrylate esters of low viscosity and the use thereof as binders in dental restorative compositions
US3751399A (en) 1971-05-24 1973-08-07 Lee Pharmaceuticals Polyacrylate resin compositions
GB1408265A (en) 1971-10-18 1975-10-01 Ici Ltd Photopolymerisable composition
US3729313A (en) 1971-12-06 1973-04-24 Minnesota Mining & Mfg Novel photosensitive systems comprising diaryliodonium compounds and their use
US3808006A (en) 1971-12-06 1974-04-30 Minnesota Mining & Mfg Photosensitive material containing a diaryliodium compound, a sensitizer and a color former
US3741769A (en) 1972-10-24 1973-06-26 Minnesota Mining & Mfg Novel photosensitive polymerizable systems and their use
DE2406557C3 (de) 1974-02-12 1981-02-19 Kulzer & Co Gmbh, 6380 Bad Homburg Hydroxyl-Gruppen enthaltende Diester von Acrylsäuren und diese enthaltendes Zahnfüllungsmaterial
US4115346A (en) 1974-02-12 1978-09-19 Kulzer & Co. Gmbh Hydroxy group containing diesters of acrylic acids and their use in dental material
AU497960B2 (en) 1974-04-11 1979-01-25 Minnesota Mining And Manufacturing Company Photopolymerizable compositions
GB1512982A (en) 1974-05-02 1978-06-01 Gen Electric Salts
US4250311A (en) 1974-05-02 1981-02-10 General Electric Company P, As, and Sb hexafluoride onium salts as photoinitiators
US4027073A (en) * 1974-06-25 1977-05-31 Dow Corning Corporation Pigment-free coating compositions
GB1569021A (en) 1976-03-17 1980-06-11 Kuraray Co Adhesive cementing agents containing partial phosphonic orphosphonic acid esters
US4150012A (en) 1977-01-21 1979-04-17 Minnesota Mining And Manufacturing Company Discernible dental sealant
JPS587561B2 (ja) 1977-06-17 1983-02-10 株式会社神戸製鋼所 塵芥等の管路輸送システムにおける輸送管路への塵芥等の供給方法
US4292029A (en) 1978-05-15 1981-09-29 University Of Michigan Hydrophobic composite restorative materials and their use in tooth treatment
US4387240A (en) 1978-06-02 1983-06-07 Minnesota Mining And Manufacturing Company Oligomeric methacryl substituted alkylsiloxanes
US4216288A (en) 1978-09-08 1980-08-05 General Electric Company Heat curable cationically polymerizable compositions and method of curing same with onium salts and reducing agents
DE2850917A1 (de) 1978-11-24 1980-06-04 Bayer Ag Dentalwerkstoffe auf basis von organischen kunststoffen in pastoeser form
EP0013491B1 (en) 1979-01-05 1982-10-20 Imperial Chemical Industries Plc Dispersions of siliceous solids in liquid organic media
US4327014A (en) 1979-04-11 1982-04-27 Kanebo Ltd. Resin-forming material, implant material and compositions for restorative material suitable for medical or dental use
US4250053A (en) 1979-05-21 1981-02-10 Minnesota Mining And Manufacturing Company Sensitized aromatic iodonium or aromatic sulfonium salt photoinitiator systems
US4389497A (en) * 1979-11-22 1983-06-21 Espe Fabrik Parmazeutischer Praparate Gmbh Use of agglomerates of silicic acid as fillers in dental materials
US4379695A (en) 1980-06-02 1983-04-12 Scientific Pharmaceuticals, Inc. Dental material comprising dimethyacrylate adducts of glycidyl methacrylate with diesters of bis(hydroxymethyl) tricyclo[5.2.1.02,6 ]decane and dicarboxylic acids
US4348462A (en) † 1980-07-11 1982-09-07 General Electric Company Abrasion resistant ultraviolet light curable hard coating compositions
JPS5828878B2 (ja) 1980-08-20 1983-06-18 三金工業株式会社 環状ピロ燐酸エステル誘導体
JPS5774369A (en) 1980-10-28 1982-05-10 Mitsui Petrochem Ind Ltd Coating composition
EP0060911B1 (de) 1981-03-24 1985-06-19 Blendax-Werke R. Schneider GmbH & Co. Dentales Füllungsmaterial
US4491508A (en) 1981-06-01 1985-01-01 General Electric Company Method of preparing curable coating composition from alcohol, colloidal silica, silylacrylate and multiacrylate monomer
JPS5879818A (ja) 1981-11-05 1983-05-13 Etsuro Kato 結晶質ジルコニアのコロイドゾル及びその製造方法
JPS58135131A (ja) 1982-02-02 1983-08-11 Etsuro Kato ジルコニア系微粉末の製造方法
US4512743A (en) 1982-02-05 1985-04-23 Johnson & Johnson Dental Products Company Method for masking discoloration on teeth
EP0094914B1 (de) 1982-05-19 1986-09-24 Ciba-Geigy Ag Photopolymerisation mittels organometallischer Salze
EP0094915B1 (de) 1982-05-19 1987-01-21 Ciba-Geigy Ag Härtbare, Metallocenkomplexe enthaltende Zusammensetzungen, daraus erhältliche aktivierte Vorstufen und deren Verwendung
US5089536A (en) 1982-11-22 1992-02-18 Minnesota Mining And Manufacturing Company Energy polmerizable compositions containing organometallic initiators
JPS59107969A (ja) 1982-12-08 1984-06-22 加藤　悦朗 ジルコニア系固溶体単結晶超微粒子の分散したゾルおよび製造方法
DE3316851A1 (de) 1983-05-07 1984-11-08 Bayer Ag, 5090 Leverkusen Polymerisierbare dentalmassen und hieraus hergestellte dentalformkoerper
US5073476A (en) 1983-05-18 1991-12-17 Ciba-Geigy Corporation Curable composition and the use thereof
US4545924A (en) 1983-06-13 1985-10-08 Owens-Corning Fiberglas Corporation Production of a magnesium chloride gel system useful in ceramics and fiber production
US4442240A (en) 1983-07-14 1984-04-10 Bisco, Inc. Dental filling materials
US4612138A (en) 1983-08-04 1986-09-16 Nalco Chemical Company Stable acidic and alkaline metal oxide sols
JPS60103033A (ja) 1983-11-01 1985-06-07 Chichibu Cement Co Ltd ジルコニア系超微粉末の製造方法
DE3341888A1 (de) 1983-11-19 1985-05-30 Bayer Ag, 5090 Leverkusen Anorganisch-organische fuellstoffe, verfahren zu deren herstellung sowie deren verwendung in polymerisierbaren massen
DE3342601C1 (de) 1983-11-25 1985-03-14 Blendax-Werke R. Schneider Gmbh & Co, 6500 Mainz Verwendung von bromierten aromatischen Diacrylsaeure- bzw. Dimethacrylsaeureestern in dentalen Fuellungsmaterialien
JPS60137827A (ja) 1983-12-23 1985-07-22 Shin Etsu Chem Co Ltd ジルコニア微粉末の製造方法
US4544359A (en) 1984-01-13 1985-10-01 Pentron Corporation Dental restorative material
DE3403040A1 (de) 1984-01-30 1985-08-08 Blendax-Werke R. Schneider Gmbh & Co, 6500 Mainz Dentales fuellungsmaterial
JPS60176920A (ja) 1984-02-21 1985-09-11 Etsuro Kato ジルコニア系単結晶超微粒子の分散したゾルおよび製造方法
US4503169A (en) 1984-04-19 1985-03-05 Minnesota Mining And Manufacturing Company Radiopaque, low visual opacity dental composites containing non-vitreous microparticles
JPS60255622A (ja) 1984-05-30 1985-12-17 Toyo Soda Mfg Co Ltd 焼結性に優れたジルコニア系微粉末の製造方法
US5177120A (en) 1984-07-31 1993-01-05 Dentsply Research & Development Corp. Chain extended urethane diacrylate and dental impression formation
US5137448A (en) 1984-07-31 1992-08-11 Dentsply Research & Development Corp. Dental impression method with photocuring of impression material in light transmissive tray
US4547531A (en) 1984-08-02 1985-10-15 Pentron Corporation Two component (paste-paste) self-curing dental restorative material
GR852068B (https=) 1984-08-30 1985-12-24 Johnson & Johnson Dental Prod
US4746685A (en) 1984-08-31 1988-05-24 Nippon Oil And Fats Co., Ltd. Light curable dental composition
DE3443221A1 (de) 1984-11-27 1986-06-05 ESPE Fabrik pharmazeutischer Präparate GmbH, 8031 Seefeld Bisacylphosphinoxide, ihre herstellung und verwendung
US4661540A (en) 1984-12-06 1987-04-28 Berger, Jenson & Nicholson Limited Water reducible coating compositions
EP0184467A3 (en) 1984-12-06 1988-06-08 Berger, Jenson and Nicholson Limited Water reducible coating compositions
DE3502594A1 (de) 1985-01-26 1986-07-31 Etablissement Dentaire Ivoclar, Schaan Roentgenopaker dentalwerkstoff
US4642126A (en) 1985-02-11 1987-02-10 Norton Company Coated abrasives with rapidly curable adhesives and controllable curvature
US4619817A (en) 1985-03-27 1986-10-28 Battelle Memorial Institute Hydrothermal method for producing stabilized zirconia
US5276068A (en) 1985-03-29 1994-01-04 Jeneric/Pentron, Inc. Dental resin materials
JPS61227917A (ja) 1985-04-03 1986-10-11 Nippon Shokubai Kagaku Kogyo Co Ltd ジルコニア系球形微粒子粉末の製造方法
JPS61270217A (ja) 1985-05-23 1986-11-29 Denki Kagaku Kogyo Kk 結晶質酸化ジルコニウム微粉末の製法
US4652274A (en) 1985-08-07 1987-03-24 Minnesota Mining And Manufacturing Company Coated abrasive product having radiation curable binder
JPS6265932A (ja) 1985-09-13 1987-03-25 Nippon Mining Co Ltd 高強度ジルコニア微粉末の製造方法
JPS6291421A (ja) 1985-10-18 1987-04-25 Tokyo Inst Of Technol 酸化ジルコニウム微粒子の製造方法
US4772530A (en) 1986-05-06 1988-09-20 The Mead Corporation Photosensitive materials containing ionic dye compounds as initiators
US4772511A (en) 1985-11-22 1988-09-20 Minnesota Mining And Manufacturing Company Transparent non-vitreous zirconia microspheres
JPH0764563B2 (ja) 1985-11-27 1995-07-12 悦朗 加藤 結晶質ジルコニアの微粉末及びその製造方法
JPH0651568B2 (ja) 1985-11-29 1994-07-06 電気化学工業株式会社 酸化ジルコニウム系微粉末の製法
JPH0729771B2 (ja) 1986-01-14 1995-04-05 悦朗 加藤 単斜ジルコニア超微結晶の高分散ゾルまたはゲルおよび製造方法
JPS62212224A (ja) 1986-03-14 1987-09-18 Taiyo Yuden Co Ltd ジルコニア系固溶体結晶質微粉末の製造方法
JPS62226815A (ja) 1986-03-27 1987-10-05 Nippon Shokubai Kagaku Kogyo Co Ltd ジルコニア系コロイドゾルの製造方法
JPS62260718A (ja) 1986-05-06 1987-11-13 Shigeyuki Somiya 水熱法による高純度ジルコニア−アルミナ系超微粉末の製造方法
JPS632809A (ja) 1986-06-19 1988-01-07 Nippon Shokubai Kagaku Kogyo Co Ltd 高純度ジルコニアゾルの製造方法
US4719091A (en) 1986-07-01 1988-01-12 Corning Glass Works Preparation of mono-sized zirconia powders by forced hydrolysis
US4778671A (en) 1986-07-14 1988-10-18 Corning Glass Works Preparation of unagglomerated metal oxide particles with uniform particle size
EP0262579B1 (en) 1986-09-27 1992-04-01 Nissan Chemical Industries Ltd. Process for manufacturing fine zirconium oxide powder
DE3642290C1 (de) 1986-12-11 1987-07-02 Dentaire Ivoclar Ets Verfahren zur Verbesserung der Haftung von Kunststoffen auf Metallen
US4874450A (en) 1987-01-29 1989-10-17 The Mead Corporation Laminating transparent or translucent materials using ionic dye-counter ion complexes
DE3863940D1 (de) 1987-02-25 1991-09-05 Nippon Catalytic Chem Ind Verfahren zur erzeugung sehr kleiner, anorganischer, kugelfoermiger teilchen.
CA1323949C (en) 1987-04-02 1993-11-02 Michael C. Palazzotto Ternary photoinitiator system for addition polymerization
US4781940A (en) * 1987-06-26 1988-11-01 Johnson & Johnson Consumer Products, Inc. Method for producing filler for microfilled dental composite material
US4792577A (en) 1987-07-16 1988-12-20 Johnson & Johnson Consumer Products, Inc. Stain-resistant no-mix orthodontic adhesive
US4886624A (en) 1987-08-19 1989-12-12 Rhone-Poulenc, Inc. Colloidal alcohol-dispersible association complexes of ceric dioxide and a hydroxyphenyl carboxylic acid
US4859716A (en) 1987-11-06 1989-08-22 Den-Mat Corporation Microfilled dental composite and method for making it
JPH0346407Y2 (https=) 1988-02-08 1991-10-01
FR2629071B1 (fr) 1988-03-22 1991-03-15 Produits Refractaires Oxyde de zirconium reactif et sa preparation
US4885332A (en) 1988-04-11 1989-12-05 Minnesota Mining And Manufacturing Company Photocurable abrasion resistant coatings comprising silicon dioxide dispersions
US4985340A (en) 1988-06-01 1991-01-15 Minnesota Mining And Manufacturing Company Energy curable compositions: two component curing agents
US5234870A (en) 1988-07-21 1993-08-10 Nippon Shokubai Kagaku Kogyo Co., Ltd. Zirconia sol and method for production thereof
US4954414A (en) 1988-11-08 1990-09-04 The Mead Corporation Photosensitive composition containing a transition metal coordination complex cation and a borate anion and photosensitive materials employing the same
JPH0667816B2 (ja) 1988-11-11 1994-08-31 株式会社クラレ 歯科用修復材
US5275759A (en) 1989-02-10 1994-01-04 Nippon Shokubai Kagaku Kogyo Co., Ltd. Zirconia sol, method for production thereof, porous ceramic-producing slurry, and porous ceramic product obtained by use thereof
US5248706A (en) 1989-04-22 1993-09-28 Degussa Aktiengesellschaft Process for preparing a pasty dental material which is an organopolysiloxane filler combined with a polymerizable bonding agent
US5219899A (en) 1989-04-22 1993-06-15 Degussa Aktiengesellschaft Pasty dental material which is an organopolysilane filler combined with a polymerizable bonding agent
DE3913250A1 (de) 1989-04-22 1990-10-25 Degussa Dentalmaterial (ii)
US5013585A (en) * 1989-06-13 1991-05-07 Shin-Etsu Chemical Co., Ltd. Method for the preparation of surface-modified silica particles
US5057393A (en) 1989-07-10 1991-10-15 The Mead Corporation Dye branched-alkyl borate photoinitiators
JPH0717820Y2 (ja) 1989-08-18 1995-04-26 国産電機株式会社 内燃機関安全装置
US5126394A (en) 1989-10-18 1992-06-30 Dow Corning Corporation Radiation curable abrasion resistant coatings from colloidal silica and acrylate monomer
US5190583A (en) 1989-12-04 1993-03-02 Transfer-Electric Gesellschaft Fur Aqueous coating composition and the use thereof for coating to be protected from light, especially ultraviolet radiation
EP0434334B1 (en) 1989-12-21 1994-02-02 Minnesota Mining And Manufacturing Company Dental compositions, a method of making shaped dental articals via photoiniferter polymerization of the dental compositions, and shaped dental articles produced thereby
US5037579A (en) 1990-02-12 1991-08-06 Nalco Chemical Company Hydrothermal process for producing zirconia sol
US5124417A (en) 1990-02-12 1992-06-23 Minnesota Mining And Manufacturing Company Initiators for cationic polymerization
US5084586A (en) 1990-02-12 1992-01-28 Minnesota Mining And Manufacturing Company Novel initiators for cationic polymerization
US5055372A (en) 1990-04-23 1991-10-08 The Mead Corporation Photohardenable composition containing borate salts and ketone initiators
US5332779A (en) 1990-06-04 1994-07-26 Kawasaki Steel Corporation Polymerizable silica sol, adamantane derivative for use in the sol and cured resin prepared using the same
DE9103321U1 (de) 1991-03-19 1992-08-27 Thera Patent GmbH & Co KG Gesellschaft für industrielle Schutzrechte, 8031 Seefeld Transparentversiegelter Dentalkunststoffkörper
US5332429A (en) 1991-05-31 1994-07-26 Minnesota Mining And Manufacturing Company Method for treating fluoroaluminosilicate glass
DE4123946A1 (de) 1991-07-19 1993-01-28 Degussa Dentalmaterial mit alumoorganopolysiloxan-fuellstoff
JP2732968B2 (ja) * 1991-09-06 1998-03-30 鐘紡株式会社 歯科用充填組成物
FR2681534B1 (fr) 1991-09-20 1995-01-27 Rhone Poulenc Chimie Solutions collouidales concentrees de particules monocristallines non agregees d'oxydes de metaux, leur procede de preparation et leur application a l'obtention de films.
DE4133621A1 (de) 1991-10-10 1993-04-22 Inst Neue Mat Gemein Gmbh Nanoskalige teilchen enthaltende kompositmaterialien, verfahren zu deren herstellung und deren verwendung fuer optische elemente
FR2689876B1 (fr) 1992-04-08 1994-09-02 Hoechst France Dispersions silico-acryliques, leur procédé d'obtention, leur application en stéréophotolithographie et procédé de préparation d'objets en résine.
DE4212633A1 (de) 1992-04-15 1993-10-21 Inst Neue Mat Gemein Gmbh Verfahren zur Herstellung oberflächenmodifizierter nanoskaliger keramischer Pulver
WO1993023333A1 (en) 1992-05-20 1993-11-25 E.I. Du Pont De Nemours And Company Process for making inorganic gels
JPH06191827A (ja) 1992-09-04 1994-07-12 Ohara Inc シリカ球状単分散粒子の製造方法
US5502087A (en) 1993-06-23 1996-03-26 Dentsply Research & Development Corp. Dental composition, prosthesis, and method for making dental prosthesis
US5460701A (en) 1993-07-27 1995-10-24 Nanophase Technologies Corporation Method of making nanostructured materials
CN1082934C (zh) * 1994-04-11 2002-04-17 宇部日东化成株式会社 交联树脂包覆二氧化硅微粒及其制造方法
JP3859737B2 (ja) 1994-04-25 2006-12-20 三菱レイヨン株式会社 歯科用複合材料
JP3437881B2 (ja) 1994-05-12 2003-08-18 三菱レイヨン株式会社 硬化性組成物、複合充填材、及び歯科用修復材料
TW343961B (en) 1994-06-17 1998-11-01 Nissan Chemical Ind Ltd Aqueous zirconia sol and method of preparing same
DE4422118A1 (de) 1994-06-24 1996-01-04 Merck Patent Gmbh Präparationen von monodispersen kugelförmigen Oxidpartikeln
JP3214982B2 (ja) * 1994-07-04 2001-10-02 株式会社トクヤマ 無機組成物
US5856373A (en) 1994-10-31 1999-01-05 Minnesota Mining And Manufacturing Company Dental visible light curable epoxy system with enhanced depth of cure
JP3542425B2 (ja) 1994-11-17 2004-07-14 キヤノン株式会社 インクジェット記録用水系分散インク、これを用いるインクジェット記録方法、インクカートリッジ、記録ユニットおよび記録装置
DE19508586C2 (de) 1995-03-13 1997-07-10 Degussa Polymerisierbarer Dentalwerkstoff
CN1083400C (zh) 1995-03-15 2002-04-24 霍亚株式会社 金属氧化物析出物的制造方法
US5698483A (en) 1995-03-17 1997-12-16 Institute Of Gas Technology Process for preparing nanosized powder
DE19515820A1 (de) 1995-04-29 1996-10-31 Inst Neue Mat Gemein Gmbh Verfahren zur Herstellung schwach agglomerierter nanoskaliger Teilchen
US5648407A (en) 1995-05-16 1997-07-15 Minnesota Mining And Manufacturing Company Curable resin sols and fiber-reinforced composites derived therefrom
WO1997015526A1 (en) 1995-10-27 1997-05-01 E.I. Du Pont De Nemours And Company Hydrothermal process for making ultrafine metal oxide powders
DE19540623A1 (de) 1995-10-31 1997-05-07 Inst Neue Mat Gemein Gmbh Verfahren zur Herstellung von Kompositmaterialien mit hohem Grenzflächenanteil und dadurch erhältliche Kompositmaterialien
US5820978A (en) * 1995-11-09 1998-10-13 Minnesota Mining And Manufacturing Company Durability improved colloidal silica coating
US5886069A (en) 1995-11-13 1999-03-23 E. I. Du Pont De Nemours And Company Titanium dioxide particles having substantially discrete inorganic particles dispersed on their surfaces
JP3495171B2 (ja) * 1996-01-25 2004-02-09 サンメディカル株式会社 歯科用充填組成物
CH691970A5 (de) 1996-03-04 2001-12-14 Ciba Sc Holding Ag Alkylphenylbisacylphosphinoxide und Photoinitiatormischungen.
ES2202511T3 (es) * 1996-04-22 2004-04-01 Merck Patent Gmbh Particulas de sio2 recubiertas.
DE19617931C5 (de) 1996-04-26 2010-07-22 Ivoclar Vivadent Ag Verwendung eines gefüllten und polymerisierbaren Materials als Dentalmaterial
US5942559A (en) * 1996-08-26 1999-08-24 Ivoclar Ag Dental light-curing opaquer
ATE267575T1 (de) * 1996-08-26 2004-06-15 Ivoclar Vivadent Ag Dentaler lichthärtender opaker
EP0880349A4 (en) 1996-09-27 2005-04-13 Southwest Res Inst COMPOSITIONS AND METHODS BASED ON METAL OXIDES
US6030914A (en) 1996-11-12 2000-02-29 Tosoh Corporation Zirconia fine powder and method for its production
JP4086338B2 (ja) 1996-12-06 2008-05-14 株式会社松風 歯科用弾性修復材料並びにそれを用いた歯科補綴材料の作製方法
US5760126A (en) 1996-12-20 1998-06-02 Minnesota Mining And Manufacturing Company Aqueous fluorochemical compositions and abrasion-resistant coatings therefrom
US6025406A (en) 1997-04-11 2000-02-15 3M Innovative Properties Company Ternary photoinitiator system for curing of epoxy resins
EP0981570B1 (de) * 1997-05-23 2002-10-16 Bayer Ag Organosilan-oligomere
US5879715A (en) 1997-09-02 1999-03-09 Ceramem Corporation Process and system for production of inorganic nanoparticles
US5985168A (en) 1997-09-29 1999-11-16 University Of Pittsburgh Of The Commonwealth System Of Higher Education Magnetorheological fluid
BR9806297A (pt) 1997-10-03 2000-03-14 Dentsply Int Inc Material dental, carga , agente de ligação dental, e, verniz dental.
US6693143B2 (en) * 1997-10-03 2004-02-17 Dentsply Detrey Gmbh Dental materials having a nanoscale filler
DE19806572B4 (de) 1998-02-17 2007-01-25 3M Espe Ag Adhäsive Befestigung von dentalen Füllungsmaterialien
US6121344A (en) 1998-06-19 2000-09-19 Kerr Corporation Optimum particle sized hybrid composite
US6030606A (en) 1998-06-22 2000-02-29 3M Innovative Properties Company Dental restoratives comprising Bis-EMA6
US6210790B1 (en) * 1998-07-15 2001-04-03 Rensselaer Polytechnic Institute Glass-like composites comprising a surface-modified colloidal silica and method of making thereof
DE69926048T2 (de) 1998-07-20 2006-05-18 Dentsply International Inc. Transluzentes verschleißfestes Zahnschmelzmaterial und Verfahren
US6051672A (en) * 1998-08-24 2000-04-18 Dow Corning Corporation Method for making hydrophobic non-aggregated colloidal silica
US6306926B1 (en) * 1998-10-07 2001-10-23 3M Innovative Properties Company Radiopaque cationically polymerizable compositions comprising a radiopacifying filler, and method for polymerizing same
US6098906A (en) * 1998-12-04 2000-08-08 Kerr Corporation Vibratory mill and method of use for low contamination grinding
US6417246B1 (en) 1999-09-21 2002-07-09 Jenerica/Pentron Incorporated Dental composite materials
AU3505400A (en) 1999-10-28 2001-05-08 3M Innovative Properties Company Dental materials with nano-sized silica particles
US6572693B1 (en) * 1999-10-28 2003-06-03 3M Innovative Properties Company Aesthetic dental materials
US6376590B2 (en) 1999-10-28 2002-04-23 3M Innovative Properties Company Zirconia sol, process of making and composite material
US6387981B1 (en) 1999-10-28 2002-05-14 3M Innovative Properties Company Radiopaque dental materials with nano-sized particles
US6586483B2 (en) * 2001-01-08 2003-07-01 3M Innovative Properties Company Foam including surface-modified nanoparticles

Also Published As

Publication number Publication date
DE60022667D1 (de) 2005-10-20
AU3505400A (en) 2001-05-08
EP1227781B1 (en) 2005-09-14
EP1227781B9 (en) 2006-03-08
JP2003512407A (ja) 2003-04-02
EP1586294B1 (en) 2009-04-15
JP2011178807A (ja) 2011-09-15
CA2387215A1 (en) 2001-05-03
DE60042038D1 (de) 2009-05-28
US20020156152A1 (en) 2002-10-24
EP1227781A1 (en) 2002-08-07
CA2387215C (en) 2010-02-09
US6899948B2 (en) 2005-05-31
JP4800535B2 (ja) 2011-10-26
JP5255092B2 (ja) 2013-08-07
EP1586294B2 (en) 2016-02-17
EP1586294A1 (en) 2005-10-19
WO2001030307A1 (en) 2001-05-03

Similar Documents

Publication Publication Date Title
DE60022667T2 (de) Dentalmaterialien mit siliciumdioxid-nanoteilchen
DE60027590D1 (de) Ästhetische dentalmaterialien
EE05169B1 (et) Asendatud oksasolidinoonid ja nende kasutamine
DE60032858D1 (de) Dentales Füllungsmaterial
DK1308108T3 (da) Tandbörste
DE60025791D1 (de) Ellipsometer
DE60009127T2 (de) Zahnbürste
DE60010041D1 (de) Zahnbürste
DE10084428T1 (de) Zahnbürste
DE60043058D1 (de) Dentalwerkstoffe
DE60007530D1 (de) Oral wirksame androgene
DE50009595D1 (de) Zahnbürste
DE50006709D1 (de) Zahnbürste
ID30397A (id) Larutan oral prukaloprida
DE50004814D1 (de) Optoelektronischer drehwinkelsensor
NO20022102L (no) Skumbart solbeskyttelsesmiddel
DK199900279U3 (da) Cementbeholder
FI4490U1 (fi) Hoitoliivi
FI19991655L (fi) Hammasharja
FR2796837B3 (fr) Tetine-bague monomatiere
SE9900663D0 (sv) Kork
FI4183U1 (fi) Patja
FIU990281U0 (fi) Patja
FI4235U1 (fi) Hammaslääkärin 2-puolinen peili
CA85567S (fr) Bouteille

Legal Events

Date Code Title Description
8364 No opposition during term of opposition