DE2714239A1 - Verfahren zur selektiven herstellung von p-dialkylbenzolen und katalysator zu dessen durchfuehrung - Google Patents

Verfahren zur selektiven herstellung von p-dialkylbenzolen und katalysator zu dessen durchfuehrung

Info

Publication number
DE2714239A1
DE2714239A1 DE19772714239 DE2714239A DE2714239A1 DE 2714239 A1 DE2714239 A1 DE 2714239A1 DE 19772714239 DE19772714239 DE 19772714239 DE 2714239 A DE2714239 A DE 2714239A DE 2714239 A1 DE2714239 A1 DE 2714239A1
Authority
DE
Germany
Prior art keywords
catalyst
zeolite
weight
xylene
silicone
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
DE19772714239
Other languages
German (de)
English (en)
Other versions
DE2714239C2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html
Inventor
Chin-Chiun Chu
Werner Otto Haag
David Harold Olson
Paul Gerhard Rodewald
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mobil Oil AS
Original Assignee
Mobil Oil AS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US05/672,194 external-priority patent/US4060568A/en
Priority claimed from US05/680,998 external-priority patent/US4011276A/en
Priority claimed from US05/726,091 external-priority patent/US4090981A/en
Application filed by Mobil Oil AS filed Critical Mobil Oil AS
Publication of DE2714239A1 publication Critical patent/DE2714239A1/de
Application granted granted Critical
Publication of DE2714239C2 publication Critical patent/DE2714239C2/de
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/08—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
    • C07C6/12—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
    • C07C6/123—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring of only one hydrocarbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/76—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/862—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
    • C07C2/864—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an alcohol
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C4/00—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/373—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation
    • C07C5/393—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation with cyclisation to an aromatic six-membered ring, e.g. dehydrogenation of n-hexane to benzene
    • C07C5/41—Catalytic processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/12—After treatment, characterised by the effect to be obtained to alter the outside of the crystallites, e.g. selectivation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/26—After treatment, characterised by the effect to be obtained to stabilize the total catalyst structure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/32—Reaction with silicon compounds, e.g. TEOS, siliconfluoride
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/34—Reaction with organic or organometallic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/36—Steaming
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
DE19772714239 1976-03-31 1977-03-30 Verfahren zur selektiven herstellung von p-dialkylbenzolen und katalysator zu dessen durchfuehrung Granted DE2714239A1 (de)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US05/672,194 US4060568A (en) 1976-03-31 1976-03-31 Silica-modified zeolite catalyst and conversion therewith
US05/680,998 US4011276A (en) 1976-04-28 1976-04-28 Disproportionation of toluene
US68587276A 1976-05-12 1976-05-12
US68586976A 1976-05-12 1976-05-12
US05/726,091 US4090981A (en) 1976-09-23 1976-09-23 Catalyst for selective production of para dialkyl substituted benzenes

Publications (2)

Publication Number Publication Date
DE2714239A1 true DE2714239A1 (de) 1977-10-20
DE2714239C2 DE2714239C2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) 1993-07-22

Family

ID=27542059

Family Applications (3)

Application Number Title Priority Date Filing Date
DE19772714239 Granted DE2714239A1 (de) 1976-03-31 1977-03-30 Verfahren zur selektiven herstellung von p-dialkylbenzolen und katalysator zu dessen durchfuehrung
DE2760481A Expired - Lifetime DE2760481C2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) 1976-03-31 1977-03-30
DE2760479A Expired - Lifetime DE2760479C2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) 1976-03-31 1977-03-30

Family Applications After (2)

Application Number Title Priority Date Filing Date
DE2760481A Expired - Lifetime DE2760481C2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) 1976-03-31 1977-03-30
DE2760479A Expired - Lifetime DE2760479C2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) 1976-03-31 1977-03-30

Country Status (12)

Country Link
JP (3) JPS52120292A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
BE (1) BE852865A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
CS (1) CS218565B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
DE (3) DE2714239A1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
FR (1) FR2357303A1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
GB (1) GB1574523A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
IT (1) IT1075368B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
NL (1) NL187424C (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
NO (1) NO149492C (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
NZ (1) NZ183608A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
PL (1) PL115528B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
SE (1) SE438606B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2826865A1 (de) * 1977-06-23 1979-01-18 Mobil Oil Corp Verfahren zur aethylierung von monoalkylbenzolen
DE2829756A1 (de) * 1977-07-29 1979-02-15 Mobil Oil Corp Verfahren zur aethylierung von monoalkylbenzolen
DE2906267A1 (de) * 1978-02-20 1979-08-30 Shell Int Research Verfahren zum katalytischen cracken von kohlenwasserstoffoelen und katalysator zur durchfuehrung des verfahrens
DE2947710A1 (de) * 1978-11-29 1980-06-12 Shell Int Research Verfahren zum katalytischen kracken von kohlenwasserstoffoelen und katalysator zur durchfuehrung des verfahrens
JPS6061034A (ja) * 1983-08-19 1985-04-08 モ−ビル　オイル　コ−ポレ−ション コークス含有触媒の製造方法及び該触媒を使用するトルエンの選択的不均化反応
EP0134076A3 (en) * 1983-08-19 1985-10-16 Mobil Oil Corporation A process for preparing a coked zeolite catalyst and a process for the selective disproportionation of toluene using said catalyst
FR2566389A1 (fr) * 1984-06-25 1985-12-27 Res Assoc Utiliz Light Oil Procede de production d'un 1,4-dialkylbenzene
EP0289691A1 (en) * 1987-04-08 1988-11-09 Taiwan Styrene Monomer Corporation A process for synthesizing high purity p-dialkyl benzene from monoalkyl benzene by using silicon-modified catalystSi-HZSM-5
DE19538799A1 (de) * 1995-10-18 1997-04-24 Sued Chemie Ag Wabenförmiger Katalysatorträger
EP0457853B1 (en) * 1989-12-13 1997-08-06 Mobil Oil Corporation A process for the catalytic conversion of a c9+ aromatics feed

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NZ183608A (en) * 1976-03-31 1978-12-18 Mobil Oil Corp Aluminosilicate zeolite catalyst for selectine production of para-diakyl substituted benzenes
US4086287A (en) * 1976-07-19 1978-04-25 Mobil Oil Corporation Selective ethylation of mono alkyl benzenes
AU538578B2 (en) * 1979-01-31 1984-08-23 Mobil Oil Corp. Zeolite catalyst containing gp za or gp8 metal and its use to convert hydrocarbons
US4274982A (en) * 1979-10-12 1981-06-23 Mobil Oil Corporation Method for maintaining para-selectivity of modified zeolite catalyst
US4357264A (en) 1980-03-10 1982-11-02 Mobil Oil Corporation Alkaline earth metal modified zeolite catalysts
US4288647A (en) * 1980-03-10 1981-09-08 Mobil Oil Corporation Shape selective reactions with alkaline earth-modified zeolite catalysts
US4278827A (en) * 1980-04-07 1981-07-14 Mobil Oil Corporation Shape selective reactions with zeolite catalyst modified with group IVB metal
EP0040463B1 (en) * 1980-05-19 1984-09-05 Mobil Oil Corporation Shape selective reactions with zeolite catalyst modified with iron and/or cobalt
JPS57108023A (en) * 1980-12-26 1982-07-05 Toa Nenryo Kogyo Kk Oligomerization catalyst for isobutene
US4431527A (en) * 1981-11-13 1984-02-14 Standard Oil Company (Indiana) Process for hydrogen treating high nitrogen content hydrocarbon feeds
JPS5931718A (ja) * 1982-08-17 1984-02-20 Toray Ind Inc パラジアルキルベンゼンの選択的製造法
JPS59107921A (ja) * 1982-12-10 1984-06-22 Idemitsu Kosan Co Ltd ｐ―キシレンの製造方法
JPS61221137A (ja) * 1985-03-28 1986-10-01 Teijin Yuka Kk Ｐ−キシレンの製造法
JPS6263528A (ja) * 1985-09-17 1987-03-20 Teijin Yuka Kk Ｐ−キシレンの製造法
JPS62115088A (ja) * 1985-11-13 1987-05-26 Res Assoc Util Of Light Oil 芳香族炭化水素の製造方法
US4902841A (en) * 1987-03-11 1990-02-20 Nippon Petrochemicals Company, Ltd. Method for producing electrical insulating oil composition
US4851604A (en) * 1987-09-02 1989-07-25 Mobil Oil Corp. Toluene disproportionation
JPH0788319B2 (ja) * 1987-09-09 1995-09-27 日本石油化学株式会社 ｍ−ベンジルトルエンの製造方法
JPH0810566B2 (ja) * 1988-03-09 1996-01-31 日本石油化学株式会社 改良された留分からなる電気絶縁油
AU614691B2 (en) * 1989-03-22 1991-09-05 Matsushita Refrigeration Company Expanded heat-insulating material
US5448005A (en) * 1994-04-04 1995-09-05 Mobil Oil Corporation Crystallization of paraxlene from high purity paraxylene feeds
JP3427507B2 (ja) * 1994-09-12 2003-07-22 東レ株式会社 パラジアルキルベンゼンの製造用触媒及びその製造法及びパラキシレンを製造する方法
US6316683B1 (en) * 1999-06-07 2001-11-13 Exxonmobil Chemical Patents Inc. Protecting catalytic activity of a SAPO molecular sieve
US6709570B1 (en) * 1999-09-27 2004-03-23 Shell Oil Company Method for preparing a catalyst
US7049260B2 (en) 2003-06-03 2006-05-23 Chevron Phillips Chemical Company Lp Selective para-xylene production via methylation of toluene with methanol in the presence of modified HZSM-5 catalyst
CN1902147B (zh) * 2003-12-31 2010-08-25 埃克森美孚化学专利公司 芳族化合物的烷基化方法
JP5294928B2 (ja) * 2009-03-06 2013-09-18 三井化学株式会社 芳香族炭化水素の製造方法およびその製造方法に使用される触媒

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DE1916243A1 (de) * 1968-03-29 1970-02-12 Union Carbide Corp Katalysator fuer die Isomerisierung von Xylolgemischen,seine Herstellung und Verwendung
US3658696A (en) * 1969-06-17 1972-04-25 Texaco Inc Selected adsorption with a silanized crystalline alumino-silicate
US3682996A (en) 1970-02-24 1972-08-08 Mobil Oil Corp Zeolite esters
DE2213109A1 (de) * 1971-03-18 1972-09-21 Mobil Oil Corp Kristalline Zeolithe und Verfahren zu ihrer Herstellung
US3698157A (en) * 1971-06-01 1972-10-17 Mobil Oil Corp Separation of mixtures with modified zeolites
US3702886A (en) * 1969-10-10 1972-11-14 Mobil Oil Corp Crystalline zeolite zsm-5 and method of preparing the same
US3890218A (en) * 1974-03-29 1975-06-17 Mobil Oil Corp Upgrading aliphatic naphthas to higher octane gasoline
US3894104A (en) * 1973-08-09 1975-07-08 Mobil Oil Corp Aromatization of hetero-atom substituted hydrocarbons
DE2518097A1 (de) * 1974-04-24 1975-11-13 Mobil Oil Corp Verfahren zur herstellung von kohlenwasserstoffen
DE2542230A1 (de) * 1974-09-23 1976-04-01 Mobil Oil Corp Phosphor enthaltender katalysator und verfahren zu seiner herstellung
US3980586A (en) * 1974-08-28 1976-09-14 Mobil Oil Corporation Modified solid catalyst materials
DE2624097A1 (de) * 1975-05-29 1976-12-09 Mobil Oil Corp Verfahren zur alkylierung von aromatischen kohlenwasserstoffen
US4086262A (en) * 1976-09-20 1978-04-25 Mobil Oil Corporation Conversion of synthesis gas to hydrocarbon mixtures
DE2321399C2 (de) * 1972-04-28 1982-09-16 Mobil Oil Corp., 10017 New York, N.Y. Verfahren zur Alkylierung von aromatischen Kohlenwasserstoffen

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US2722504A (en) * 1950-12-04 1955-11-01 Union Oil Co Silicone coated catalyst and use thereof
US3417157A (en) * 1967-12-28 1968-12-17 Universal Oil Prod Co Transalkylation of toluene and catalyst therefor
US3651162A (en) * 1969-02-27 1972-03-21 Standard Oil Co Isomerization and disproportionation of alkyl aromatics
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Cited By (10)

* Cited by examiner, † Cited by third party
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DE2826865A1 (de) * 1977-06-23 1979-01-18 Mobil Oil Corp Verfahren zur aethylierung von monoalkylbenzolen
DE2829756A1 (de) * 1977-07-29 1979-02-15 Mobil Oil Corp Verfahren zur aethylierung von monoalkylbenzolen
DE2906267A1 (de) * 1978-02-20 1979-08-30 Shell Int Research Verfahren zum katalytischen cracken von kohlenwasserstoffoelen und katalysator zur durchfuehrung des verfahrens
DE2947710A1 (de) * 1978-11-29 1980-06-12 Shell Int Research Verfahren zum katalytischen kracken von kohlenwasserstoffoelen und katalysator zur durchfuehrung des verfahrens
JPS6061034A (ja) * 1983-08-19 1985-04-08 モ−ビル　オイル　コ−ポレ−ション コークス含有触媒の製造方法及び該触媒を使用するトルエンの選択的不均化反応
EP0134076A3 (en) * 1983-08-19 1985-10-16 Mobil Oil Corporation A process for preparing a coked zeolite catalyst and a process for the selective disproportionation of toluene using said catalyst
FR2566389A1 (fr) * 1984-06-25 1985-12-27 Res Assoc Utiliz Light Oil Procede de production d'un 1,4-dialkylbenzene
EP0289691A1 (en) * 1987-04-08 1988-11-09 Taiwan Styrene Monomer Corporation A process for synthesizing high purity p-dialkyl benzene from monoalkyl benzene by using silicon-modified catalystSi-HZSM-5
EP0457853B1 (en) * 1989-12-13 1997-08-06 Mobil Oil Corporation A process for the catalytic conversion of a c9+ aromatics feed
DE19538799A1 (de) * 1995-10-18 1997-04-24 Sued Chemie Ag Wabenförmiger Katalysatorträger

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SE7703593L (sv) 1977-10-01
NL187424B (nl) 1991-05-01
NL187424C (nl) 1991-10-01
SE438606B (sv) 1985-04-29
FR2357303B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) 1984-06-01
PL115528B1 (en) 1981-04-30
NO771085L (no) 1977-10-03
JPH0567613B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) 1993-09-27
GB1574523A (en) 1980-09-10
IT1075368B (it) 1985-04-22
JPH01199920A (ja) 1989-08-11
DE2760479C2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) 1993-08-12
NO149492B (no) 1984-01-23
DE2760481C2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) 1993-07-15
DE2714239C2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) 1993-07-22
NL7703484A (nl) 1977-10-04
BE852865A (fr) 1977-09-26
NZ183608A (en) 1978-12-18
FR2357303A1 (fr) 1978-02-03
CS218565B2 (en) 1983-02-25
JPS52120292A (en) 1977-10-08
JPS6247854B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) 1987-10-09
NO149492C (no) 1984-05-09

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