CN1231431C - 取代的2,3－二氢－1－茚酮类化合物的制备方法 - Google Patents

取代的2,3－二氢－1－茚酮类化合物的制备方法 Download PDF

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CN1231431C
CN1231431C CNB98804739XA CN98804739A CN1231431C CN 1231431 C CN1231431 C CN 1231431C CN B98804739X A CNB98804739X A CN B98804739XA CN 98804739 A CN98804739 A CN 98804739A CN 1231431 C CN1231431 C CN 1231431C
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bihydrogen
indenone
methyl
group
indenyl
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CN1254328A (zh
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C·宾格尔
M·高雷斯
V·弗雷杰
A·温特
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Targor GmbH
Basell Polyolefine GmbH
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Targor GmbH
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    • C07C49/613—Unsaturated compounds containing a keto groups being part of a ring polycyclic
    • C07C49/617—Unsaturated compounds containing a keto groups being part of a ring polycyclic a keto group being part of a condensed ring system
    • C07C49/623—Unsaturated compounds containing a keto groups being part of a ring polycyclic a keto group being part of a condensed ring system having two rings
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  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Heterocyclic Compounds Containing Sulfur Atoms (AREA)
  • Furan Compounds (AREA)
  • Pyridine Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
CNB98804739XA 1997-03-07 1998-03-05 取代的2,3－二氢－1－茚酮类化合物的制备方法 Expired - Lifetime CN1231431C (zh)

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Application Number Priority Date Filing Date Title
DE19709402.3 1997-03-07
DE19709402 1997-03-07
DE19713546A DE19713546A1 (de) 1997-04-02 1997-04-02 Verfahren zur Herstellung substituierter Indanone
DE19713546.3 1997-04-02

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CNB2005101085205A Division CN100451024C (zh) 1997-03-07 1998-03-05 金属茂化合物和茚类化合物以及其应用
CN2005101089263A Division CN1762957B (zh) 1997-03-07 1998-03-05 2,3-二氢-1-茚酮类化合物以及其制备方法

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CN1254328A CN1254328A (zh) 2000-05-24
CN1231431C true CN1231431C (zh) 2005-12-14

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CNB98804739XA Expired - Lifetime CN1231431C (zh) 1997-03-07 1998-03-05 取代的2,3－二氢－1－茚酮类化合物的制备方法
CNB2005101085205A Expired - Lifetime CN100451024C (zh) 1997-03-07 1998-03-05 金属茂化合物和茚类化合物以及其应用
CN2005101089263A Expired - Lifetime CN1762957B (zh) 1997-03-07 1998-03-05 2,3-二氢-1-茚酮类化合物以及其制备方法

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CNB2005101085205A Expired - Lifetime CN100451024C (zh) 1997-03-07 1998-03-05 金属茂化合物和茚类化合物以及其应用
CN2005101089263A Expired - Lifetime CN1762957B (zh) 1997-03-07 1998-03-05 2,3-二氢-1-茚酮类化合物以及其制备方法

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Families Citing this family (143)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE69831139T2 (de) * 1997-03-07 2006-06-01 Basell Polyolefine Gmbh Verfahren zur herstellung substituierter indanone, die substituierte indanone und daraus hergestelle metallocene
DE19806918A1 (de) 1998-02-19 1999-08-26 Aventis Res & Tech Gmbh & Co Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen
US7053160B1 (en) 1998-11-25 2006-05-30 Basell Polyolefine Gmbh Metallocene monohalogenides
JP2002530416A (ja) 1998-11-25 2002-09-17 バーゼル、ポリオレフィン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング モノアリールオキシ−アンサ−メタロセン
EP1548037A3 (de) 1999-12-23 2007-09-12 Basell Polyolefine GmbH Random-Propylen-Ethylencopolymere
KR100743010B1 (ko) * 1999-12-23 2007-07-27 바젤 폴리올레핀 게엠베하 전이 금속 화합물, 리간드계, 촉매계와 올레핀의 중합 및공중합에 사용되는 이의 용도
US6384142B1 (en) 2000-02-08 2002-05-07 Exxonmobil Chemical Patents Inc. Propylene impact copolymers
ATE264336T1 (de) 2000-02-08 2004-04-15 Exxonmobil Chem Patents Inc Verfahren zur herstellung von gruppe 14 verbrückten biscyclopentadienyl-liganden
US6376407B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376413B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380122B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376408B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380331B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380123B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376412B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380330B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376627B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US7122498B2 (en) 2000-06-30 2006-10-17 Exxonmobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
US6380124B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380120B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6870016B1 (en) 2000-06-30 2005-03-22 Exxonmobil Chemical Patents Inc. Polymerization process and polymer composition
US6399723B1 (en) 2000-06-30 2002-06-04 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380121B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376409B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6414095B1 (en) 2000-06-30 2002-07-02 Exxon Mobil Chemical Patents Inc. Metallocene compositions
US6380334B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376411B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376410B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
DE50105968D1 (de) 2000-08-29 2005-05-25 Basell Polyolefine Gmbh VERFAHREN ZUR HERSTELLUNG VON AlKYLVERBRÜCKTEN LIGANDSYSTEMEN UND ÜBERGANGSMETALLVERBINDUNGEN
EP1446429B1 (en) * 2001-06-12 2009-10-07 Basell Polyolefine GmbH Process for the polymerization of 1-butene
EP1397371B1 (en) 2001-06-22 2006-03-22 Basell Polyolefine GmbH Metallocenes and their use in catalyst systems for producing olefin polymers
JP2005522406A (ja) * 2001-06-29 2005-07-28 エクソンモービル・ケミカル・パテンツ・インク メタロセン及び該メタロセン由来の触媒組成物
US7019157B2 (en) * 2001-08-06 2006-03-28 Chisso Corporation Metallocene compounds, production process for olefin polymers using catalysts containing them and olefin polymers produced by the production process
US7157591B2 (en) * 2001-12-10 2007-01-02 Exxonmobie Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
DE10214938A1 (de) * 2002-04-04 2003-10-16 Merck Patent Gmbh Fluorierte Indene und 1,7-Dihydroindacene mit negativem delta epsilon
US20060089253A1 (en) 2002-08-13 2006-04-27 Shahram Mihan Monocyclopentadienyl complexes
ATE445651T1 (de) * 2002-09-06 2009-10-15 Basell Polyolefine Gmbh Verfahren zur copolymerisation von ethylen
US8008412B2 (en) 2002-09-20 2011-08-30 Exxonmobil Chemical Patents Inc. Polymer production at supersolution conditions
AU2003273400A1 (en) 2002-10-10 2004-05-04 Basell Polyolefine Gmbh Process for the copolymerization of ethylene
AU2003280396A1 (en) 2002-10-22 2004-05-13 Basell Polyolefine Gmbh Preparation of substituted indenes
EP1567560B1 (en) * 2002-12-06 2011-01-19 Basell Polyolefine GmbH Organometallic transition metal compound, biscyclopentadienyl ligand system, catalyst system and process for preparing polyolefins
JP2006511607A (ja) * 2002-12-20 2006-04-06 バーゼル、ポリオレフィン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング モノシクロペンタジエニル錯体
DE602004019647D1 (de) * 2003-05-28 2009-04-09 Basell Polyolefine Gmbh Bisindenyl-zirconium-komplexe zur olefinpolymerisation
DE10358082A1 (de) 2003-12-10 2005-07-14 Basell Polyolefine Gmbh Organübergangsmetallverbindung, Bscyclopentadienyligandsystem, Katalysatorsystem und Hertellung von Polyolefinen
JP2007523955A (ja) 2004-02-25 2007-08-23 ラ ホヤ ファーマシューティカル カンパニー 疾患の治療のためのアミンおよびアミド
EP1735354A1 (en) * 2004-04-16 2006-12-27 Exxonmobil Chemical Company Inc. Heterocyclic substituted metallocene compounds for olefin polymerization
DE102004020524A1 (de) 2004-04-26 2005-11-10 Basell Polyolefine Gmbh Polyethylen und Katalysatorzusammensetzung zu dessen Herstellung
JP4897670B2 (ja) * 2004-05-04 2012-03-14 バーゼル・ポリオレフィン・ゲーエムベーハー アタクチック１−ブテンポリマー類の製造方法
CN101076621A (zh) * 2004-12-13 2007-11-21 巴塞尔聚烯烃意大利有限责任公司 聚烯烃组合物、纤维以及非织造织物
US7446216B2 (en) * 2004-12-16 2008-11-04 Exxonmobil Chemical Patents Inc. Halogen substituted metallocene compounds for olefin polymerization
WO2006082176A1 (en) 2005-02-03 2006-08-10 Basell Polyolefine Gmbh Process for producing thermoformed articles
BRPI0611557B1 (pt) * 2005-03-18 2017-03-28 Basell Polyolefine Gmbh compostos metalocenos bis-indenila em ponte com simetria c2, sistema catalítico dessa classe de compostos e processo de polimerização de a-olefinas com a referida classe de compostos
EP1858934B1 (en) 2005-03-18 2013-04-24 Basell Polyolefine GmbH Metallocene compounds
CN101146836B (zh) 2005-03-23 2011-06-08 巴塞尔聚烯烃股份有限公司 烯烃聚合方法
JP2008534705A (ja) 2005-03-23 2008-08-28 バーゼル・ポリオレフィン・ゲーエムベーハー オレフィン類の重合法
JP2008540714A (ja) * 2005-05-03 2008-11-20 バーゼル・ポリオレフィン・ゲーエムベーハー α−オレフィンの重合方法
ATE515533T1 (de) 2005-05-11 2011-07-15 Basell Poliolefine Srl Polymerisationsverfahren zur herstellung von polyolefinblends
US7550544B2 (en) 2005-12-14 2009-06-23 Exxonmobil Chemical Patents Inc. Halogen substituted metallocene compounds for olefin polymerization
US7538168B2 (en) 2005-12-14 2009-05-26 Exxonmobil Chemical Patents Inc. Halogen substituted metallocene compounds for olefin polymerization
US7868197B2 (en) 2005-12-14 2011-01-11 Exxonmobil Chemical Patents Inc. Halogen substituted heteroatom-containing metallocene compounds for olefin polymerization
US7910783B2 (en) 2005-12-14 2011-03-22 Exxonmobil Chemical Patents Inc. Preparation of substituted bridged indenyl and related ligands
US7667064B2 (en) * 2005-12-14 2010-02-23 Exxonmobil Chemical Patents Inc. Halogen substituted metallocene compounds for olefin polymerization
US7763562B2 (en) * 2005-12-14 2010-07-27 Exxonmobil Chemical Patents Inc. Heteroatom bridged metallocene compounds for olefin polymerization
DE102005061326A1 (de) * 2005-12-20 2007-06-21 Basell Polyolefine Gmbh Verfahren zur Herstellung von Metallocenen aus recycelten, substituierten Cyclopentadienylderivaten
DE102006001959A1 (de) * 2006-01-13 2007-07-19 Basell Polyolefine Gmbh Verfahren zur Herstellung von unsymmetrischen Bis(imino)verbindungen
ATE526337T1 (de) * 2006-03-17 2011-10-15 Basell Polyolefine Gmbh Metallocenverbindungen
US7834205B2 (en) 2006-04-12 2010-11-16 Basell Polyolifine GmbH Metallocene compounds
EP1847555A1 (en) * 2006-04-18 2007-10-24 Borealis Technology Oy Multi-branched Polypropylene
US8785575B2 (en) 2006-04-21 2014-07-22 Basell Polyolefine Gmbh Process for the preparation of ethylene propylene copolymers
US8742042B2 (en) * 2006-04-21 2014-06-03 Basell Polyolefine Gmbh Process for the preparation of ethylene copolymers
US8242237B2 (en) 2006-12-20 2012-08-14 Exxonmobil Chemical Patents Inc. Phase separator and monomer recycle for supercritical polymerization process
DE102007017903A1 (de) * 2007-04-13 2008-10-16 Basell Polyolefine Gmbh Polyethylen und Katalysatorzusammensetzung und Verfahren zu dessen Herstellung
WO2008150572A1 (en) 2007-06-04 2008-12-11 Exxonmobil Chemical Patents Inc. Super-solution homogeneous propylene polymerization
EP2220101B1 (en) * 2007-12-18 2018-09-19 Basell Polyolefine GmbH Transition metal compounds
US7812104B2 (en) * 2008-01-18 2010-10-12 Exxonmobil Chemical Patents Inc. Production of propylene-based polymers
US8318875B2 (en) 2008-01-18 2012-11-27 Exxonmobil Chemical Patents Inc. Super-solution homogeneous propylene polymerization and polypropylenes made therefrom
CN102060680A (zh) * 2009-11-12 2011-05-18 上海药明康德新药开发有限公司 一种合成二甲基茚酮及其衍生物的方法
ES2424958T3 (es) 2009-11-13 2013-10-10 Borealis Ag Proceso para polimerización de olefinas
EP2499169B1 (en) 2009-11-13 2014-04-02 Borealis AG Process for recovering a transition metal compound
EP2322568B1 (en) 2009-11-13 2013-05-15 Borealis AG Process for producing an olefin polymerization catalyst
WO2011058089A1 (en) 2009-11-13 2011-05-19 Borealis Ag Process for producing a polymerization catalyst
EP2330136B1 (en) 2009-12-07 2013-08-28 Borealis AG Process for the preparation of an unsupported, solid metallocene catalyst system and its use in polymerization of olefins
ES2813282T3 (es) 2011-03-02 2021-03-23 Borealis Ag Conjunto de reactor de alto rendimiento para la polimerización de olefinas
PT2495038T (pt) 2011-03-02 2020-11-06 Borealis Ag Conjunto de reator flexível para polimerização de olefinas
ES2605429T3 (es) 2011-06-15 2017-03-14 Borealis Ag Mezcla del reactor in situ de un polipropileno nucleado catalizado por Ziegler-Natta y un polipropileno catalizado por metaloceno
EP2729529B1 (en) 2011-07-08 2016-04-27 Borealis AG Heterophasic copolymers
EP2890490B1 (en) 2012-08-29 2020-05-06 Borealis AG Reactor assembly and method for polymerization of olefins
EP2745927A1 (en) 2012-12-21 2014-06-25 Borealis AG Fluidized bed reactor with internal moving bed reaction unit
EP2745926A1 (en) 2012-12-21 2014-06-25 Borealis AG Gas phase polymerization and reactor assembly comprising a fluidized bed reactor and an external moving bed reactor
WO2015022127A1 (en) 2013-08-14 2015-02-19 Borealis Ag Propylene composition with improved impact resistance at low temperature
MX2016001930A (es) 2013-08-21 2016-05-26 Borealis Ag Composicion de poliolefina de alto flujo con alta rigidez y tenacidad.
US9890275B2 (en) 2013-08-21 2018-02-13 Borealis Ag High flow polyolefin composition with high stiffness and toughness
PT2853563T (pt) 2013-09-27 2016-07-14 Borealis Ag Filmes adequados para processamento de bopp a partir de polímeros com xs elevada e tm elevado
EP2860031B1 (en) 2013-10-11 2016-03-30 Borealis AG Machine direction oriented film for labels
EP2865713B1 (en) 2013-10-24 2016-04-20 Borealis AG Blow molded article based on bimodal random copolymer
EP3060589B9 (en) 2013-10-24 2018-04-18 Borealis AG Low melting pp homopolymer with high content of regioerrors and high molecular weight
US9670293B2 (en) 2013-10-29 2017-06-06 Borealis Ag Solid single site catalysts with high polymerisation activity
US9751962B2 (en) 2013-11-22 2017-09-05 Borealis Ag Low emission propylene homopolymer with high melt flow
CN105793298B (zh) 2013-12-04 2019-06-28 博里利斯股份公司 用于熔喷纤维的不含邻苯二甲酸酯的pp均聚物
KR101873134B1 (ko) 2013-12-18 2018-06-29 보레알리스 아게 향상된 강성/인성 균형을 가진 bopp 필름
US9944665B2 (en) 2013-12-19 2018-04-17 Exxonmobil Chemical Patents Inc. Bridged bis(indenyl) transitional metal complexes, production, and use thereof
US10227427B2 (en) 2014-01-17 2019-03-12 Borealis Ag Process for preparing propylene/1-butene copolymers
ES2767498T3 (es) 2014-02-06 2020-06-17 Borealis Ag Copolímeros de impacto transparentes y suaves
ES2827285T3 (es) 2014-02-06 2021-05-20 Borealis Ag Copolímeros blandos con alta resistencia al impacto
EP2907841A1 (en) 2014-02-14 2015-08-19 Borealis AG Polypropylene composite
ES2659731T3 (es) 2014-05-20 2018-03-19 Borealis Ag Composición de polipropileno para aplicaciones en interiores de automóviles
EP2995631A1 (en) 2014-09-12 2016-03-16 Borealis AG Process for producing graft copolymers on polyolefin backbone
US9873007B2 (en) * 2014-11-03 2018-01-23 Abdulrahman A. Al-Hebshi Fire extinguishing system
EP3023450B1 (en) 2014-11-21 2017-07-19 Borealis AG Process for producing pellets of soft copolymers
KR102384765B1 (ko) * 2014-11-26 2022-04-07 스미또모 가가꾸 가부시키가이샤 화합물의 제조 방법
ES2790649T3 (es) 2014-12-08 2020-10-28 Borealis Ag Procedimiento para producir gránulos de copolímeros de propileno
EP3124567A1 (en) 2015-07-30 2017-02-01 Borealis AG Polypropylene based hot-melt adhesive composition
EP3178853B1 (en) 2015-12-07 2018-07-25 Borealis AG Process for polymerising alpha-olefin monomers
CN105585566B (zh) * 2016-03-09 2017-12-29 河南师范大学 一种茚酮并咪唑并吡啶类化合物的合成方法
EP3241611B1 (en) 2016-05-02 2020-03-04 Borealis AG A process for feeding a polymerisation catalyst
EP3243622B1 (en) 2016-05-13 2020-09-09 Borealis AG Process for hydraulic conveying of polyolefin pellets
CN109328200B (zh) 2016-06-23 2022-08-19 博里利斯股份公司 催化剂失活的方法
WO2018091653A1 (en) 2016-11-18 2018-05-24 Borealis Ag Catalyst
JP7037562B2 (ja) 2016-11-18 2022-03-16 ボレアリス エージー 触媒
EP3555148B1 (en) 2016-12-15 2023-04-05 Borealis AG Catalyst system for producing polyethylene copolymers in a high temperature solution polymerization process
KR102543361B1 (ko) 2016-12-15 2023-06-13 보레알리스 아게 고온 용액 중합 공정으로 폴리에틸렌 공중합체를 제조하기 위한 새로운 촉매 시스템
WO2018122134A1 (en) 2016-12-29 2018-07-05 Borealis Ag Catalysts
US11214631B2 (en) 2017-11-14 2022-01-04 Exxonmobil Chemical Patents Inc. (Di)silicon bridged metallocenes that produce polyethylene with broad molecular weight distribution and high molecular weight
CN108329197A (zh) * 2017-12-18 2018-07-27 滨海康杰化学有限公司 一种茚酮类化合物的制备方法
CN111757896B (zh) 2017-12-21 2023-10-13 博里利斯股份公司 制备固体催化剂的方法
JP2021508756A (ja) 2017-12-28 2021-03-11 ボレアリス エージー 触媒及びその調製
KR20200133264A (ko) 2018-03-19 2020-11-26 보레알리스 아게 올레핀 중합용 촉매
EP3814388A1 (en) 2018-06-28 2021-05-05 Borealis AG Catalysts
EP3608364A1 (en) 2018-08-06 2020-02-12 Borealis AG Multimodal propylene random copolymer based composition suitable as hot melt adhesive composition
US20210277290A1 (en) 2018-08-06 2021-09-09 Borealis Ag Propylene random copolymer based hot melt adhesive composition
WO2020109452A1 (en) 2018-11-30 2020-06-04 Borealis Ag Washing process
CN111333494B (zh) * 2019-12-10 2023-07-11 武汉海昕药物研究有限公司 6-甲氧基-1-萘满酮的合成方法
CN111187295A (zh) * 2020-01-09 2020-05-22 山东清河化工科技有限公司 一种c2对称结构的硅桥联茂金属配合物及其应用
CN111205175A (zh) * 2020-03-17 2020-05-29 京博农化科技有限公司 一种提高5-氯-1-茚酮收率的合成方法
CN112538093B (zh) * 2020-12-18 2022-07-22 河南荣峰光电科技有限公司 一种光引发剂的制备方法
US11859041B2 (en) * 2021-08-16 2024-01-02 Chevron Phillips Chemical Company Lp Modulating co-monomer selectivity using non-covalent dispersion interactions in group 4 olefin polymerization catalysts
EP4144435A1 (en) 2021-09-01 2023-03-08 Borealis AG Gas phase polymerization process with improved gas recycling
CN114316103B (zh) * 2021-12-03 2023-05-26 国家能源集团宁夏煤业有限责任公司 聚丙烯及其制备方法
CN114316111B (zh) * 2021-12-03 2023-06-20 国家能源集团宁夏煤业有限责任公司 共聚α-烯烃及其制备方法
CN114560761B (zh) * 2022-01-29 2023-02-24 南京林业大学 一种水相中一次性合成2,3-二取代的茚酮衍生物的方法
CN115232175A (zh) * 2022-08-17 2022-10-25 山东清河化工科技有限公司 一种含氟准c2对称硅桥联茂金属配合物及其应用
CN115974664A (zh) * 2023-01-18 2023-04-18 合肥工业大学 一种5-氯-1-茚酮的合成方法
CN116497231B (zh) * 2023-06-21 2024-01-05 核工业理化工程研究院 一种四（三氟膦）镍制备镍的方法

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE791201A (fr) 1971-11-12 1973-05-10 Merck & Co Inc Indanyloxytetrazoles
US3929872A (en) * 1973-10-12 1975-12-30 Merck & Co Inc Indanacetic acid compounds
NL7907742A (nl) * 1979-10-19 1981-04-22 Zaltbommel Chem Fab Werkwijze voor het bereiden van kobalt-(iii)-acetyl- acetonaat.
TW294669B (US06492539-20021210-C00015.png) * 1992-06-27 1997-01-01 Hoechst Ag
DE59301869D1 (de) 1992-09-09 1996-04-18 Hoechst Ag Verfahren zur Herstellung von aromatisch substituierten Olefinen aus Chloraromaten
EP1070729B1 (en) * 1993-06-07 2011-09-28 Mitsui Chemicals, Inc. Transition metal compound, olefin polymerization catalyst component comprising said compound, olefin polymerization catalyst containing said component, process for olefin polymerization using said catalyst, propylene homopolymer, propylene copolymer and propylene elastomer
JPH07286005A (ja) * 1993-06-07 1995-10-31 Mitsui Petrochem Ind Ltd 新規な遷移金属化合物および該遷移金属化合物からなるオレフィン重合用触媒成分、該オレフィン重合用触媒成分を含むオレフィン重合用触媒ならびにオレフィンの重合方法
JP3423378B2 (ja) * 1993-11-12 2003-07-07 三井化学株式会社 新規な遷移金属化合物および該遷移金属化合物からなるオレフィン重合用触媒成分、該オレフィン重合用触媒成分を含むオレフィン重合用触媒ならびにオレフィンの重合方法
DE4423061C1 (de) 1994-07-01 1996-01-18 Hoechst Ag Verfahren zur Herstellung von Biphenylen mit Palladacyclen als Katalysatoren
US5489712A (en) * 1994-11-04 1996-02-06 Hoechst Celanese Corporation Process for preparing cyclic ketones
DE19515444C1 (de) * 1995-04-27 1996-11-14 Hoechst Ag Verfahren zur Herstellung von aromatischen Acetylenen mit Palladazyklen als Katalysatoren
DE19517851A1 (de) * 1995-05-16 1996-11-21 Hoechst Ag Organometallverbindung
JP3512521B2 (ja) * 1995-05-29 2004-03-29 三井化学株式会社 変性プロピレン系エラストマー
DE69831139T2 (de) * 1997-03-07 2006-06-01 Basell Polyolefine Gmbh Verfahren zur herstellung substituierter indanone, die substituierte indanone und daraus hergestelle metallocene
DE19757563A1 (de) * 1997-03-07 1999-07-08 Targor Gmbh Geträgertes Katalysatorsystem, Verfahren zur Herstellung und seine Verwendung zur Polymerisation von Olefinen

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KR100624632B1 (ko) 2006-09-15
ES2247681T3 (es) 2006-03-01
JP2001519779A (ja) 2001-10-23
KR100553633B1 (ko) 2006-02-22
US6963017B2 (en) 2005-11-08
CN1762957B (zh) 2010-05-12
US6492539B1 (en) 2002-12-10
JP5105413B2 (ja) 2012-12-26
ZA981913B (en) 1999-09-06
EP0968158A1 (en) 2000-01-05
KR20050098018A (ko) 2005-10-10
ZA981912B (en) 1999-09-06
CN1254328A (zh) 2000-05-24
CN1763060A (zh) 2006-04-26

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