ATE264336T1 - Verfahren zur herstellung von gruppe 14 verbrückten biscyclopentadienyl-liganden - Google Patents

Verfahren zur herstellung von gruppe 14 verbrückten biscyclopentadienyl-liganden

Info

Publication number
ATE264336T1
ATE264336T1 AT01907166T AT01907166T ATE264336T1 AT E264336 T1 ATE264336 T1 AT E264336T1 AT 01907166 T AT01907166 T AT 01907166T AT 01907166 T AT01907166 T AT 01907166T AT E264336 T1 ATE264336 T1 AT E264336T1
Authority
AT
Austria
Prior art keywords
ligands
present
bridged biscyclopentadienyl
preparing group
synthesis
Prior art date
Application number
AT01907166T
Other languages
English (en)
Inventor
Francis C Rix
Terry J Burkhardt
Robert T Li
William T Haygood Jr
Original Assignee
Exxonmobil Chem Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US09/535,357 external-priority patent/US6384142B1/en
Application filed by Exxonmobil Chem Patents Inc filed Critical Exxonmobil Chem Patents Inc
Application granted granted Critical
Publication of ATE264336T1 publication Critical patent/ATE264336T1/de

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/0803—Compounds with Si-C or Si-Si linkages
    • C07F7/081—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/0803—Compounds with Si-C or Si-Si linkages
    • C07F7/081—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te
    • C07F7/0812—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te comprising a heterocyclic ring
    • C07F7/0814—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te comprising a heterocyclic ring said ring is substituted at a C ring atom by Si
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/0803—Compounds with Si-C or Si-Si linkages
    • C07F7/0825—Preparations of compounds not comprising Si-Si or Si-cyano linkages
    • C07F7/0827—Syntheses with formation of a Si-C bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/22—Tin compounds
    • C07F7/2208—Compounds having tin linked only to carbon, hydrogen and/or halogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/30—Germanium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
    • C08F297/083—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins the monomers being ethylene or propylene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/12—Polypropene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/12—Olefin polymerisation or copolymerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/12—Olefin polymerisation or copolymerisation
    • B01J2231/122—Cationic (co)polymerisation, e.g. single-site or Ziegler-Natta type
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/42—Tin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/48—Zirconium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/49—Hafnium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/122—Metal aryl or alkyl compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/165—Polymer immobilised coordination complexes, e.g. organometallic complexes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/14—Copolymers of propene
    • C08L23/142—Copolymers of propene at least partially crystalline copolymers of propene with other olefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16—Ethylene-propylene or ethylene-propylene-diene copolymers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
AT01907166T 2000-02-08 2001-02-08 Verfahren zur herstellung von gruppe 14 verbrückten biscyclopentadienyl-liganden ATE264336T1 (de)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US18101600P 2000-02-08 2000-02-08
US09/535,357 US6384142B1 (en) 2000-02-08 2000-03-24 Propylene impact copolymers
US09/534,556 US6492465B1 (en) 2000-02-08 2000-03-24 Propylene impact copolymers
PCT/US2001/004220 WO2001058913A1 (en) 2000-02-08 2001-02-08 Method of preparing group 14 bridged biscyclopentadienyl ligands

Publications (1)

Publication Number Publication Date
ATE264336T1 true ATE264336T1 (de) 2004-04-15

Family

ID=27391352

Family Applications (2)

Application Number Title Priority Date Filing Date
AT04021067T ATE336529T1 (de) 2000-02-08 2001-02-08 Schlagzähe propylencopolymerisate
AT01907166T ATE264336T1 (de) 2000-02-08 2001-02-08 Verfahren zur herstellung von gruppe 14 verbrückten biscyclopentadienyl-liganden

Family Applications Before (1)

Application Number Title Priority Date Filing Date
AT04021067T ATE336529T1 (de) 2000-02-08 2001-02-08 Schlagzähe propylencopolymerisate

Country Status (10)

Country Link
US (2) US6960676B2 (de)
EP (1) EP1263764B1 (de)
JP (1) JP2003522194A (de)
CN (1) CN1406241A (de)
AT (2) ATE336529T1 (de)
BR (1) BR0108195A (de)
CA (1) CA2398529A1 (de)
DE (2) DE60122396T2 (de)
ES (2) ES2230277T3 (de)
WO (1) WO2001058913A1 (de)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7157591B2 (en) * 2001-12-10 2007-01-02 Exxonmobie Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
EP1501843B1 (de) * 2002-04-23 2006-06-14 Dow Global Technologies Inc. Alkarylsubstituierte komplexe von gruppe-4-metallen, katalysatoren und verfahren zur polymerisierung von olefinen
US7285608B2 (en) * 2004-04-21 2007-10-23 Novolen Technology Holdings C.V. Metallocene ligands, metallocene compounds and metallocene catalysts, their synthesis and their use for the polymerization of olefins
KR101364329B1 (ko) * 2006-02-02 2014-02-18 바젤 폴리올레핀 게엠베하 프로필렌 용융 취입 수지, 이로부터 제조된 프로필렌 용융 취입 수지 섬유 및 부직포, 및 이의 제조 방법
RU2012105023A (ru) * 2009-07-14 2013-08-20 ДАУ ГЛОБАЛ ТЕКНОЛОДЖИЗ ЭлЭлСи Полипропиленовые ударопрочные сополимеры, имеющие высокие текучесть расплава и пластичность в испытании по изоду
US9266910B2 (en) 2013-10-29 2016-02-23 Exxonmobil Chemical Patents Inc. Asymmetric polypropylene catalysts
US9376559B2 (en) 2013-11-22 2016-06-28 Exxonmobil Chemical Patents Inc. Reverse staged impact copolymers
WO2023150480A1 (en) 2022-02-07 2023-08-10 Exxonmobil Chemical Patents Inc. C1 symmetric 5-ome-6-alkyl substituted metallocenes
CN116247301B (zh) * 2023-05-10 2023-08-11 合肥国轩高科动力能源有限公司 电解液及锂离子电池

Family Cites Families (55)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3244752A1 (de) * 1982-12-03 1984-06-07 Hoechst Ag, 6230 Frankfurt Verfahren zur herstellung von fettsaeurenitrilen und glycerin aus glyceriden, insbesondere aus natuerlichen fetten und oelen
DE3639857A1 (de) * 1986-11-21 1988-06-01 Hoechst Ag Verfahren zur herstellung von fettsaeurenitrilen und glycerin aus glyceriden
DE3751694T2 (de) 1987-04-03 1996-08-01 Fina Technology Metallocen-katalysatorsysteme für die Polymersation von Olefinen, mit einer Silizium-Hydrocarbyl-Brücke.
US5120867A (en) 1988-03-21 1992-06-09 Welborn Jr Howard C Silicon-bridged transition metal compounds
US5017714A (en) 1988-03-21 1991-05-21 Exxon Chemical Patents Inc. Silicon-bridged transition metal compounds
US5382631A (en) 1988-09-30 1995-01-17 Exxon Chemical Patents Inc. Linear ethylene interpolymer blends of interpolymers having narrow molecular weight and composition distributions
DE3844282A1 (de) * 1988-12-30 1990-07-05 Hoechst Ag Bisindenyl-derivat und verfahren zu seiner herstellung
DE3916555A1 (de) 1989-05-20 1990-11-22 Hoechst Ag Verfahren zur herstellung von ethylenpolymeren
US5191042A (en) 1989-09-06 1993-03-02 Exxon Chemical Patents Inc. Process for preparing alpha-olefin copolymers having a narrow MWD and broad compositional distribution
US5258464A (en) 1990-01-29 1993-11-02 Shell Oil Company Impact copolymer compositions
US5118757A (en) 1990-03-26 1992-06-02 Shell Oil Company Polymer production
US5166268A (en) 1990-04-12 1992-11-24 Union Carbide Chemicals & Plastics Technology Corporation Process for cold forming propylene copolymers
US5362782A (en) 1990-05-14 1994-11-08 Shell Oil Company Polymer compositions
US5250631A (en) 1990-06-13 1993-10-05 Shell Oil Company Polymer compositions
ES2091273T3 (es) 1990-11-12 1996-11-01 Hoechst Ag Procedimiento para la preparacion de un polimero olefinico de alto peso molecular.
ES2071888T3 (es) 1990-11-12 1995-07-01 Hoechst Ag Bisindenilmetalocenos sustituidos en posicion 2, procedimiento para su preparacion y su utilizacion como catalizadores en la polimerizacion de olefinas.
DE4104931A1 (de) 1991-02-18 1992-08-20 Hoechst Ag Verfahren zur herstellung substituierter indene
US5347026A (en) * 1993-06-11 1994-09-13 Phillips Petroleum Company Fluorene compounds and methods for making
US5401817A (en) * 1991-05-09 1995-03-28 Phillips Petroleum Company Olefin polymerization using silyl-bridged metallocenes
US5631335A (en) * 1991-05-09 1997-05-20 Phillips Petroleum Company Process of polymerizing olefins using diphenylsilyl or dimethyl tin bridged 1-methyl fluorenyl metallocenes
DE4130429A1 (de) 1991-09-13 1993-03-18 Basf Ag Verfahren zur herstellung von mehrphasigen blockcopolymerisaten auf der basis von alk-1-enen
EP0537686B1 (de) 1991-10-15 2005-01-12 Basell Polyolefine GmbH Verfahren zur Herstellung eines Olefinpolymers unter Verwendung von Metallocenen mit speziell substituierten Indenylliganden
US5830821A (en) 1991-11-30 1998-11-03 Targor Gmbh Process for olefin preparation using metallocenes having benzo-fused indenyl derivatives as ligands
TW318184B (de) 1991-11-30 1997-10-21 Hoechst Ag
ATE150037T1 (de) * 1992-05-26 1997-03-15 Hoechst Ag Verfahren zur herstellung von polyolefinwachsen
TW294669B (de) 1992-06-27 1997-01-01 Hoechst Ag
ES2128371T3 (es) 1992-08-15 1999-05-16 Targor Gmbh Procedimiento para la obtencion de poliolefinas.
CA2125247C (en) 1993-06-07 2001-02-20 Daisuke Fukuoka Transition metal compound, olefin polymerization catalyst component comprising said compound, olefin polymerization catalyst containing said catalyst component, process for olefinpolymerization using said catalyst , propylene homopolymer, propylene copolymer and propylene elastomer
DE69413651T2 (de) 1993-06-30 1999-04-08 Mitsui Chemicals, Inc., Tokio/Tokyo Polypropylenzusammensetzung
TW354792B (en) 1993-08-13 1999-03-21 Mitsui Petrochemical Ind Olefin polymerization catalyst and process for preparing polypropylene and propylene block copolymer
US5486585A (en) 1993-08-26 1996-01-23 Exxon Chemical Patents Inc. Amidosilyldiyl bridged catalysts and method of polymerization using said catalysts.
DE4344689A1 (de) 1993-12-27 1995-06-29 Hoechst Ag Metallocenverbindung
DE4344688A1 (de) 1993-12-27 1995-06-29 Hoechst Ag Metallocenverbindung
DE69506821T2 (de) 1994-04-11 1999-06-10 Mitsui Chemicals, Inc., Tokio/Tokyo Verfahren zur herstellung einer propylen-polymerzusammensetzung und propylen-polymerzusammensetzung
JP3357186B2 (ja) 1994-07-14 2002-12-16 三菱化学株式会社 プロピレンブロック共重合体の製造法
EP0763553B1 (de) 1995-02-07 1999-05-06 Mitsui Chemicals, Inc. Verfahren zur herstellung von polyolefin
US5674630A (en) 1995-05-08 1997-10-07 Union Carbide Chemicals & Plastics Technology Corporation Polymer compositions and cast films
SG64939A1 (en) 1995-07-17 2002-02-19 Mitsui Chemicals Inc Olefin polymerization catalyst, process for preparing olefin polymer, and olefin polymer
JP3506563B2 (ja) * 1995-07-17 2004-03-15 三井化学株式会社 オレフィン重合用触媒、オレフィン重合体の製造方法およびオレフィン重合体
US5708101A (en) 1995-08-17 1998-01-13 California Institute Of Technology Stereospecific olefin polymerization catalysts
JPH09151294A (ja) 1995-09-29 1997-06-10 Mitsubishi Chem Corp タルク含有プロピレン系樹脂組成物
DE19544828A1 (de) 1995-12-01 1997-06-05 Hoechst Ag Hochmolekulare Copolymere
US5712344A (en) 1996-01-04 1998-01-27 Union Carbide Chemicals & Plastics Technology Corporation Modified polypropylene impact copolymer compositions
JPH09208881A (ja) 1996-02-07 1997-08-12 Mitsubishi Chem Corp 塗装用プロピレン系樹脂組成物
SG67392A1 (en) 1996-05-27 1999-09-21 Sumitomo Chemical Co Propylene/ethylene-alpha-olefin block copolymer and process for producing the same
JP3320619B2 (ja) 1996-10-02 2002-09-03 三井化学株式会社 新規メタロセン化合物とそれを用いたオレフィンまたはジエンの重合方法
AU1211197A (en) 1997-01-10 1998-08-03 Chisso Corporation Propylene/ethylene copolymer, process for the production thereof, and molded articles thereof
EP0985674B1 (de) 1997-01-21 2003-04-23 Mitsubishi Chemical Corporation Organische verbindungen enthaltend silizium oder germanium, übergangsmetallkomplexe, katalysatoren für alpha-olefin polymerisation und verfahren zur herstellung von alpha-olefinpolymeren
US6492539B1 (en) 1997-03-07 2002-12-10 Basell Polypropylen Gmbh Preparation of preparing substituted indanones
US6303696B1 (en) 1997-04-11 2001-10-16 Chisso Corporation Propylene (co)polymer composition using metallocene catalyst
DE19739946A1 (de) 1997-09-11 1999-03-18 Targor Gmbh Verfahren zur Herstellung von Metallocenen
US5942587A (en) 1997-11-21 1999-08-24 Exxon Chemical Patents Inc. Ethylene polymers with a norbornene comonomer for LLDPE like resins of improved toughness and processibility for film production
DE69928185T2 (de) 1998-01-30 2006-07-20 Boulder Scientific Co., Mead Synthese von n-silylierten verbindungen
EP0962474B1 (de) 1998-06-04 2004-04-07 Japan Polychem Corporation Propylenblockcopolymer und Harzzusammensetzung
US6384142B1 (en) * 2000-02-08 2002-05-07 Exxonmobil Chemical Patents Inc. Propylene impact copolymers

Also Published As

Publication number Publication date
BR0108195A (pt) 2003-02-25
EP1263764B1 (de) 2004-04-14
DE60102805D1 (de) 2004-05-19
US20050250956A1 (en) 2005-11-10
DE60122396T2 (de) 2007-09-06
ATE336529T1 (de) 2006-09-15
US6960676B2 (en) 2005-11-01
EP1263764A1 (de) 2002-12-11
WO2001058913A1 (en) 2001-08-16
CA2398529A1 (en) 2001-08-16
ES2215879T3 (es) 2004-10-16
CN1406241A (zh) 2003-03-26
JP2003522194A (ja) 2003-07-22
ES2230277T3 (es) 2005-05-01
DE60102805T2 (de) 2005-04-21
DE60122396D1 (de) 2006-09-28
US20030220190A1 (en) 2003-11-27
US7081543B2 (en) 2006-07-25

Similar Documents

Publication Publication Date Title
DE59107926D1 (de) Metallocene mit Liganden aus 2-substituierten Indenylderivaten, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren
DE50115621D1 (de) Adamantylgruppen enthaltende phosphanliganden, deren herstellung und ihre verwendung in katalytischen reaktionen
DE602005010084D1 (de) Verbesserte synthese von ansa-metallocenen und stammliganden davon in hoher ausbeute
TR200100006T2 (tr) Bir katalizör terkibi, ve bunu hazırlamak ve bir polimerizasyon işleminde kullanmak için yöntemler
DE59104869D1 (de) 2-Substituierte Bisindenylmetallocene, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren bei der Olefinpolymerisation.
EP1188763A3 (de) Metallocenverbindung und ihre Verwendung in Olefin-Polymerisation
Aldridge et al. The coordination chemistry of boryl and borate substituted cyclopentadienyl ligands
ATE304556T1 (de) Verfahren zur herstellung von amorphen alpha- olefinpolymeren, diese enthaltende zusammensetzungen und verfahren zur herstellung von verbrückten liganden
DE59902501D1 (de) Liganden und komplexe zur enantioselektiven hydrierung
BR0016725A (pt) Sistema catalisador, uso do mesmo, e, processo para preparar poliolefinas
EP0967015A3 (de) Verwendung von Ferrocenylliganden zur katalytischen enantioselektiven Hydrierung
DE60102805T2 (de) VERFAHREN ZUR HERSTELLUNG VON GRUPPE 14 VERBRüCKTEN BISCYCLOPENTADIENYL-LIGANDEN
ATE395314T1 (de) Katalytisches hydrierungsverfahren
DE59108612D1 (de) Metallocene mit bicyclischen Cyclopentadienderivaten als Liganden, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren
IT1299068B1 (it) Legandi fosforati chirali e loro complessi organometallici, utili come catalizzatori in sintesi stereoselettive
DE59905420D1 (de) Valeraldehyd und Verfahren zu seiner Herstellung
DE60236196D1 (de) Katalysatorsystem aus einer mischung von katalysatorbestandteilen zur herstellung einer polyolefinmischung
TW200517180A (en) Use of azeotropically dried nickel (II) halides
BG106019A (en) INHIBITORS OF LFA-1 BINDING TO ICAMs AND USES THEREOF
DE60132242D1 (de) Phosphonitliganden, katalysatorzusammensetzungen und dessen verwendung in hydroformylierungsprozess
DE59509485D1 (de) Verfahren zur Herstellung verbrückter Metallocene
RU95116655A (ru) Способ получения металлоценов с мостичными связями
DE69709883D1 (de) Chirale ferrocene
DE69836496D1 (de) Verfahren zur herstellung von beta-(1,3)-d-glukan aus pilzen
DE69832645D1 (de) Tetrakis(fluoraryl)-borat/Etherkomplexe und Verfahren zu deren Herstellung

Legal Events

Date Code Title Description
UEP Publication of translation of european patent specification

Ref document number: 1263764

Country of ref document: EP

REN Ceased due to non-payment of the annual fee