ATE264336T1 - Verfahren zur herstellung von gruppe 14 verbrückten biscyclopentadienyl-liganden - Google Patents
Verfahren zur herstellung von gruppe 14 verbrückten biscyclopentadienyl-ligandenInfo
- Publication number
- ATE264336T1 ATE264336T1 AT01907166T AT01907166T ATE264336T1 AT E264336 T1 ATE264336 T1 AT E264336T1 AT 01907166 T AT01907166 T AT 01907166T AT 01907166 T AT01907166 T AT 01907166T AT E264336 T1 ATE264336 T1 AT E264336T1
- Authority
- AT
- Austria
- Prior art keywords
- ligands
- present
- bridged biscyclopentadienyl
- preparing group
- synthesis
- Prior art date
Links
- 239000003446 ligand Substances 0.000 title abstract 4
- 230000015572 biosynthetic process Effects 0.000 abstract 2
- 238000003786 synthesis reaction Methods 0.000 abstract 2
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Natural products C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 abstract 1
- 239000003153 chemical reaction reagent Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
- B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2282—Unsaturated compounds used as ligands
- B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0803—Compounds with Si-C or Si-Si linkages
- C07F7/081—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0803—Compounds with Si-C or Si-Si linkages
- C07F7/081—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te
- C07F7/0812—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te comprising a heterocyclic ring
- C07F7/0814—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te comprising a heterocyclic ring said ring is substituted at a C ring atom by Si
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0803—Compounds with Si-C or Si-Si linkages
- C07F7/0825—Preparations of compounds not comprising Si-Si or Si-cyano linkages
- C07F7/0827—Syntheses with formation of a Si-C bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/22—Tin compounds
- C07F7/2208—Compounds having tin linked only to carbon, hydrogen and/or halogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/30—Germanium compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
- C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
- C08F297/083—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins the monomers being ethylene or propylene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/08—Silica
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
- B01J2231/12—Olefin polymerisation or copolymerisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
- B01J2231/12—Olefin polymerisation or copolymerisation
- B01J2231/122—Cationic (co)polymerisation, e.g. single-site or Ziegler-Natta type
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/42—Tin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/48—Zirconium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/49—Hafnium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/122—Metal aryl or alkyl compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/165—Polymer immobilised coordination complexes, e.g. organometallic complexes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/14—Copolymers of propene
- C08L23/142—Copolymers of propene at least partially crystalline copolymers of propene with other olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US18101600P | 2000-02-08 | 2000-02-08 | |
US09/534,556 US6492465B1 (en) | 2000-02-08 | 2000-03-24 | Propylene impact copolymers |
US09/535,357 US6384142B1 (en) | 2000-02-08 | 2000-03-24 | Propylene impact copolymers |
PCT/US2001/004220 WO2001058913A1 (en) | 2000-02-08 | 2001-02-08 | Method of preparing group 14 bridged biscyclopentadienyl ligands |
Publications (1)
Publication Number | Publication Date |
---|---|
ATE264336T1 true ATE264336T1 (de) | 2004-04-15 |
Family
ID=27391352
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AT04021067T ATE336529T1 (de) | 2000-02-08 | 2001-02-08 | Schlagzähe propylencopolymerisate |
AT01907166T ATE264336T1 (de) | 2000-02-08 | 2001-02-08 | Verfahren zur herstellung von gruppe 14 verbrückten biscyclopentadienyl-liganden |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AT04021067T ATE336529T1 (de) | 2000-02-08 | 2001-02-08 | Schlagzähe propylencopolymerisate |
Country Status (10)
Country | Link |
---|---|
US (2) | US6960676B2 (de) |
EP (1) | EP1263764B1 (de) |
JP (1) | JP2003522194A (de) |
CN (1) | CN1406241A (de) |
AT (2) | ATE336529T1 (de) |
BR (1) | BR0108195A (de) |
CA (1) | CA2398529A1 (de) |
DE (2) | DE60102805T2 (de) |
ES (2) | ES2230277T3 (de) |
WO (1) | WO2001058913A1 (de) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7157591B2 (en) * | 2001-12-10 | 2007-01-02 | Exxonmobie Chemical Patents Inc. | Metallocenes and catalyst compositions derived therefrom |
CA2483326C (en) * | 2002-04-23 | 2011-01-04 | Dow Global Technologies Inc. | Alkaryl-substituted group 4 metal complexes, catalysts and olefin polymerization process |
US7285608B2 (en) * | 2004-04-21 | 2007-10-23 | Novolen Technology Holdings C.V. | Metallocene ligands, metallocene compounds and metallocene catalysts, their synthesis and their use for the polymerization of olefins |
EP1979384A2 (de) * | 2006-02-02 | 2008-10-15 | Basell Polyolefine GmbH | Propylenschmelzblasharze, propylenschmelzblasharzfasern und daraus hergestellter vliesstoff und herstellungsverfahren dafür |
WO2011008589A1 (en) * | 2009-07-14 | 2011-01-20 | Dow Global Technologies Inc. | Polypropylene impact copolymers having high melt flow and izod ductility |
US9266910B2 (en) | 2013-10-29 | 2016-02-23 | Exxonmobil Chemical Patents Inc. | Asymmetric polypropylene catalysts |
US9376559B2 (en) | 2013-11-22 | 2016-06-28 | Exxonmobil Chemical Patents Inc. | Reverse staged impact copolymers |
WO2023150480A1 (en) | 2022-02-07 | 2023-08-10 | Exxonmobil Chemical Patents Inc. | C1 symmetric 5-ome-6-alkyl substituted metallocenes |
CN116247301B (zh) * | 2023-05-10 | 2023-08-11 | 合肥国轩高科动力能源有限公司 | 电解液及锂离子电池 |
Family Cites Families (55)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3244752A1 (de) | 1982-12-03 | 1984-06-07 | Hoechst Ag, 6230 Frankfurt | Verfahren zur herstellung von fettsaeurenitrilen und glycerin aus glyceriden, insbesondere aus natuerlichen fetten und oelen |
DE3639857A1 (de) * | 1986-11-21 | 1988-06-01 | Hoechst Ag | Verfahren zur herstellung von fettsaeurenitrilen und glycerin aus glyceriden |
EP0284708B1 (de) | 1987-04-03 | 1996-01-31 | Fina Technology, Inc. | Metallocen-katalysatorsysteme für die Polymersation von Olefinen, mit einer Silizium-Hydrocarbyl-Brücke. |
US5017714A (en) * | 1988-03-21 | 1991-05-21 | Exxon Chemical Patents Inc. | Silicon-bridged transition metal compounds |
US5120867A (en) * | 1988-03-21 | 1992-06-09 | Welborn Jr Howard C | Silicon-bridged transition metal compounds |
US5382631A (en) | 1988-09-30 | 1995-01-17 | Exxon Chemical Patents Inc. | Linear ethylene interpolymer blends of interpolymers having narrow molecular weight and composition distributions |
DE3844282A1 (de) * | 1988-12-30 | 1990-07-05 | Hoechst Ag | Bisindenyl-derivat und verfahren zu seiner herstellung |
DE3916555A1 (de) | 1989-05-20 | 1990-11-22 | Hoechst Ag | Verfahren zur herstellung von ethylenpolymeren |
US5191042A (en) * | 1989-09-06 | 1993-03-02 | Exxon Chemical Patents Inc. | Process for preparing alpha-olefin copolymers having a narrow MWD and broad compositional distribution |
US5258464A (en) | 1990-01-29 | 1993-11-02 | Shell Oil Company | Impact copolymer compositions |
US5118757A (en) | 1990-03-26 | 1992-06-02 | Shell Oil Company | Polymer production |
US5166268A (en) | 1990-04-12 | 1992-11-24 | Union Carbide Chemicals & Plastics Technology Corporation | Process for cold forming propylene copolymers |
US5362782A (en) | 1990-05-14 | 1994-11-08 | Shell Oil Company | Polymer compositions |
US5250631A (en) | 1990-06-13 | 1993-10-05 | Shell Oil Company | Polymer compositions |
EP0485823B1 (de) | 1990-11-12 | 1995-03-08 | Hoechst Aktiengesellschaft | 2-Substituierte Bisindenylmetallocene, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren bei der Olefinpolymerisation |
EP0485822B1 (de) | 1990-11-12 | 1996-07-03 | Hoechst Aktiengesellschaft | Verfahren zur Herstellung eines hochmolekularen Olefinpolymers |
DE4104931A1 (de) * | 1991-02-18 | 1992-08-20 | Hoechst Ag | Verfahren zur herstellung substituierter indene |
US5631335A (en) | 1991-05-09 | 1997-05-20 | Phillips Petroleum Company | Process of polymerizing olefins using diphenylsilyl or dimethyl tin bridged 1-methyl fluorenyl metallocenes |
US5347026A (en) * | 1993-06-11 | 1994-09-13 | Phillips Petroleum Company | Fluorene compounds and methods for making |
US5401817A (en) * | 1991-05-09 | 1995-03-28 | Phillips Petroleum Company | Olefin polymerization using silyl-bridged metallocenes |
DE4130429A1 (de) | 1991-09-13 | 1993-03-18 | Basf Ag | Verfahren zur herstellung von mehrphasigen blockcopolymerisaten auf der basis von alk-1-enen |
DE59210001D1 (de) * | 1991-10-15 | 2005-02-17 | Basell Polyolefine Gmbh | Verfahren zur Herstellung eines Olefinpolymers unter Verwendung von Metallocenen mit speziell substituierten Indenylliganden |
US5830821A (en) | 1991-11-30 | 1998-11-03 | Targor Gmbh | Process for olefin preparation using metallocenes having benzo-fused indenyl derivatives as ligands |
TW318184B (de) * | 1991-11-30 | 1997-10-21 | Hoechst Ag | |
EP0571882B1 (de) * | 1992-05-26 | 1997-03-12 | Hoechst Aktiengesellschaft | Verfahren zur Herstellung von Polyolefinwachsen |
TW294669B (de) | 1992-06-27 | 1997-01-01 | Hoechst Ag | |
ES2128371T3 (es) * | 1992-08-15 | 1999-05-16 | Targor Gmbh | Procedimiento para la obtencion de poliolefinas. |
CA2125247C (en) | 1993-06-07 | 2001-02-20 | Daisuke Fukuoka | Transition metal compound, olefin polymerization catalyst component comprising said compound, olefin polymerization catalyst containing said catalyst component, process for olefinpolymerization using said catalyst , propylene homopolymer, propylene copolymer and propylene elastomer |
US5591795A (en) | 1993-06-30 | 1997-01-07 | Mitsui Petrochemical Industries, Ltd. | Polypropylene composition |
TW354792B (en) | 1993-08-13 | 1999-03-21 | Mitsui Petrochemical Ind | Olefin polymerization catalyst and process for preparing polypropylene and propylene block copolymer |
US5486585A (en) * | 1993-08-26 | 1996-01-23 | Exxon Chemical Patents Inc. | Amidosilyldiyl bridged catalysts and method of polymerization using said catalysts. |
DE4344688A1 (de) * | 1993-12-27 | 1995-06-29 | Hoechst Ag | Metallocenverbindung |
DE4344689A1 (de) * | 1993-12-27 | 1995-06-29 | Hoechst Ag | Metallocenverbindung |
EP0704462B1 (de) | 1994-04-11 | 1998-12-23 | Mitsui Chemicals, Inc. | Verfahren zur herstellung einer propylen-polymerzusammensetzung und propylen-polymerzusammensetzung |
JP3357186B2 (ja) | 1994-07-14 | 2002-12-16 | 三菱化学株式会社 | プロピレンブロック共重合体の製造法 |
CA2187204C (en) | 1995-02-07 | 2002-09-10 | Kenji Sugimura | Process for preparing olefin polymer |
US5674630A (en) | 1995-05-08 | 1997-10-07 | Union Carbide Chemicals & Plastics Technology Corporation | Polymer compositions and cast films |
JP3506563B2 (ja) * | 1995-07-17 | 2004-03-15 | 三井化学株式会社 | オレフィン重合用触媒、オレフィン重合体の製造方法およびオレフィン重合体 |
SG64939A1 (en) * | 1995-07-17 | 2002-02-19 | Mitsui Chemicals Inc | Olefin polymerization catalyst, process for preparing olefin polymer, and olefin polymer |
US5708101A (en) * | 1995-08-17 | 1998-01-13 | California Institute Of Technology | Stereospecific olefin polymerization catalysts |
JPH09151294A (ja) | 1995-09-29 | 1997-06-10 | Mitsubishi Chem Corp | タルク含有プロピレン系樹脂組成物 |
DE19544828A1 (de) | 1995-12-01 | 1997-06-05 | Hoechst Ag | Hochmolekulare Copolymere |
US5712344A (en) | 1996-01-04 | 1998-01-27 | Union Carbide Chemicals & Plastics Technology Corporation | Modified polypropylene impact copolymer compositions |
JPH09208881A (ja) | 1996-02-07 | 1997-08-12 | Mitsubishi Chem Corp | 塗装用プロピレン系樹脂組成物 |
SG67392A1 (en) | 1996-05-27 | 1999-09-21 | Sumitomo Chemical Co | Propylene/ethylene-alpha-olefin block copolymer and process for producing the same |
JP3320619B2 (ja) | 1996-10-02 | 2002-09-03 | 三井化学株式会社 | 新規メタロセン化合物とそれを用いたオレフィンまたはジエンの重合方法 |
US6156856A (en) | 1997-01-10 | 2000-12-05 | Chisso Corporation | Propylene-ethylene copolymers processes for the production thereof and molded articles made therefrom |
US6255515B1 (en) | 1997-01-21 | 2001-07-03 | Mitsubishi Chemical Corporation | Processes for producing silicon- or germanium-containing organic compound, transition metal complex, catalyst for polymerization of α-olefin and α-olefin polymer |
KR100624632B1 (ko) | 1997-03-07 | 2006-09-15 | 타고르 게엠베하 | 메탈로센 및 그의 제조 방법 |
US6303696B1 (en) | 1997-04-11 | 2001-10-16 | Chisso Corporation | Propylene (co)polymer composition using metallocene catalyst |
DE19739946A1 (de) | 1997-09-11 | 1999-03-18 | Targor Gmbh | Verfahren zur Herstellung von Metallocenen |
US5942587A (en) | 1997-11-21 | 1999-08-24 | Exxon Chemical Patents Inc. | Ethylene polymers with a norbornene comonomer for LLDPE like resins of improved toughness and processibility for film production |
DE69928185T2 (de) | 1998-01-30 | 2006-07-20 | Boulder Scientific Co., Mead | Synthese von n-silylierten verbindungen |
EP0962474B1 (de) | 1998-06-04 | 2004-04-07 | Japan Polychem Corporation | Propylenblockcopolymer und Harzzusammensetzung |
US6492465B1 (en) * | 2000-02-08 | 2002-12-10 | Exxonmobil Chemical Patents, Inc. | Propylene impact copolymers |
-
2001
- 2001-02-08 CN CN01805790A patent/CN1406241A/zh active Pending
- 2001-02-08 AT AT04021067T patent/ATE336529T1/de not_active IP Right Cessation
- 2001-02-08 BR BR0108195-0A patent/BR0108195A/pt not_active IP Right Cessation
- 2001-02-08 JP JP2001558062A patent/JP2003522194A/ja active Pending
- 2001-02-08 DE DE60102805T patent/DE60102805T2/de not_active Expired - Lifetime
- 2001-02-08 CA CA002398529A patent/CA2398529A1/en not_active Abandoned
- 2001-02-08 ES ES01910477T patent/ES2230277T3/es not_active Expired - Lifetime
- 2001-02-08 ES ES01907166T patent/ES2215879T3/es not_active Expired - Lifetime
- 2001-02-08 US US10/203,017 patent/US6960676B2/en not_active Expired - Lifetime
- 2001-02-08 WO PCT/US2001/004220 patent/WO2001058913A1/en active IP Right Grant
- 2001-02-08 DE DE60122396T patent/DE60122396T2/de not_active Expired - Lifetime
- 2001-02-08 AT AT01907166T patent/ATE264336T1/de not_active IP Right Cessation
- 2001-02-08 EP EP01907166A patent/EP1263764B1/de not_active Expired - Lifetime
-
2005
- 2005-07-13 US US11/181,004 patent/US7081543B2/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
CA2398529A1 (en) | 2001-08-16 |
ATE336529T1 (de) | 2006-09-15 |
DE60102805D1 (de) | 2004-05-19 |
ES2230277T3 (es) | 2005-05-01 |
US7081543B2 (en) | 2006-07-25 |
DE60122396D1 (de) | 2006-09-28 |
WO2001058913A1 (en) | 2001-08-16 |
CN1406241A (zh) | 2003-03-26 |
US20050250956A1 (en) | 2005-11-10 |
BR0108195A (pt) | 2003-02-25 |
ES2215879T3 (es) | 2004-10-16 |
US6960676B2 (en) | 2005-11-01 |
JP2003522194A (ja) | 2003-07-22 |
US20030220190A1 (en) | 2003-11-27 |
EP1263764B1 (de) | 2004-04-14 |
DE60122396T2 (de) | 2007-09-06 |
DE60102805T2 (de) | 2005-04-21 |
EP1263764A1 (de) | 2002-12-11 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
DE59107926D1 (de) | Metallocene mit Liganden aus 2-substituierten Indenylderivaten, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren | |
DE602005010084D1 (de) | Verbesserte synthese von ansa-metallocenen und stammliganden davon in hoher ausbeute | |
TR200100006T2 (tr) | Bir katalizör terkibi, ve bunu hazırlamak ve bir polimerizasyon işleminde kullanmak için yöntemler | |
DE59104869D1 (de) | 2-Substituierte Bisindenylmetallocene, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren bei der Olefinpolymerisation. | |
MX9501383A (es) | Metalocenos que contienen fluorenilo para utilizarse en polimerizacion de olefinas. | |
EP1188763A3 (de) | Metallocenverbindung und ihre Verwendung in Olefin-Polymerisation | |
BR0016725A (pt) | Sistema catalisador, uso do mesmo, e, processo para preparar poliolefinas | |
ATE304556T1 (de) | Verfahren zur herstellung von amorphen alpha- olefinpolymeren, diese enthaltende zusammensetzungen und verfahren zur herstellung von verbrückten liganden | |
ATE264336T1 (de) | Verfahren zur herstellung von gruppe 14 verbrückten biscyclopentadienyl-liganden | |
ATE395314T1 (de) | Katalytisches hydrierungsverfahren | |
ATE222913T1 (de) | Integriertes verfahren zur herstellung von dien- komplexen | |
DE59108612D1 (de) | Metallocene mit bicyclischen Cyclopentadienderivaten als Liganden, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren | |
DE69101841T2 (de) | Verfahren zur herstellung von mikroteilchen aus metallocenen. | |
DE59509924D1 (de) | Verfahren zur Herstellung von verbrückten Halbsandwichkomplexen | |
IT1299068B1 (it) | Legandi fosforati chirali e loro complessi organometallici, utili come catalizzatori in sintesi stereoselettive | |
DE60236196D1 (de) | Katalysatorsystem aus einer mischung von katalysatorbestandteilen zur herstellung einer polyolefinmischung | |
ATE330962T1 (de) | Phosphonite, ihre verwendung als ligand in übergangsmetall komplexen und verfahren zur herstellung von nitrilen | |
TW200517180A (en) | Use of azeotropically dried nickel (II) halides | |
DE60132242D1 (de) | Phosphonitliganden, katalysatorzusammensetzungen und dessen verwendung in hydroformylierungsprozess | |
DK1047669T3 (da) | Perfluor-N-alkylsulfonsyrederivater | |
RU95116655A (ru) | Способ получения металлоценов с мостичными связями | |
DE69709883T2 (de) | Chirale ferrocene | |
DE69836496D1 (de) | Verfahren zur herstellung von beta-(1,3)-d-glukan aus pilzen | |
ATE276321T1 (de) | Pigmentkonzentrate und verfahren zu ihrer herstellung | |
ATE318829T1 (de) | Liganden mit wenigstens einem fluorosilizium- substituenten zur herstellung von metallocenen |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
UEP | Publication of translation of european patent specification |
Ref document number: 1263764 Country of ref document: EP |
|
REN | Ceased due to non-payment of the annual fee |