WO2010011101A3 - 합성가스로부터 메탄올 합성용 촉매 및 이의 제조방법 - Google Patents

합성가스로부터 메탄올 합성용 촉매 및 이의 제조방법 Download PDF

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WO2010011101A3
WO2010011101A3 PCT/KR2009/004128 KR2009004128W WO2010011101A3 WO 2010011101 A3 WO2010011101 A3 WO 2010011101A3 KR 2009004128 W KR2009004128 W KR 2009004128W WO 2010011101 A3 WO2010011101 A3 WO 2010011101A3
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catalyst
methanol
synthesis gas
preparation
synthesizing methanol
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PCT/KR2009/004128
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English (en)
French (fr)
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WO2010011101A2 (ko
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강석환
배종욱
전기원
민계식
송석용
정삼헌
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현대중공업 주식회사
한국화학연구원
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Priority to JP2011519994A priority Critical patent/JP5303033B2/ja
Priority to AU2009274701A priority patent/AU2009274701B2/en
Priority to CN200980128951.4A priority patent/CN102105222B/zh
Priority to US13/055,496 priority patent/US8623927B2/en
Priority to EP09800582A priority patent/EP2305379A4/en
Publication of WO2010011101A2 publication Critical patent/WO2010011101A2/ko
Publication of WO2010011101A3 publication Critical patent/WO2010011101A3/ko

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of rare earths
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/036—Precipitation; Co-precipitation to form a gel or a cogel
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/22—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
    • C01B3/24—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons
    • C01B3/26—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons using catalysts
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • C07C29/154—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing copper, silver, gold, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • C07C29/156—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof
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    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
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  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
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  • Dispersion Chemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)

Abstract

본 발명은 합성가스로부터 메탄올 합성용 촉매 및 이의 제조방법에 관한 것으로서, 더욱 상세하게는 CuO, ZnO 및 Al2O3를 일정비로 함유한 Cu-Zn-Al계 산화물 또는 CuO, ZnO, Al2O3 및 ZrO2 일정비로 함유한 Cu-Zn-Al-Zr계 산화물과, 졸-겔법에 의해 제조된 세륨-지르코늄산화물 지지체로 구성되는 신규 촉매계로, 종래의 Cu-Zn-Al계 단독으로 사용된 메탄올 합성용 촉매와 비교하여 부산물의 생성이 억제되어 메탄올로의 수율이 향상되어, 메탄올로의 수율 증가에 따른 메탄올 정제 효율 및 카본전환 효율을 크게 향상시킬 수 있는 합성가스로부터 메탄올 합성용 촉매 및 이의 제조방법에 관한 것이다.
PCT/KR2009/004128 2008-07-24 2009-07-24 합성가스로부터 메탄올 합성용 촉매 및 이의 제조방법 WO2010011101A2 (ko)

Priority Applications (5)

Application Number Priority Date Filing Date Title
JP2011519994A JP5303033B2 (ja) 2008-07-24 2009-07-24 合成ガスからのメタノール合成用触媒およびその製造方法
AU2009274701A AU2009274701B2 (en) 2008-07-24 2009-07-24 Catalyst for synthesizing methanol from synthesis gas and preparation method thereof
CN200980128951.4A CN102105222B (zh) 2008-07-24 2009-07-24 用于从合成气合成甲醇的催化剂及其制备方法
US13/055,496 US8623927B2 (en) 2008-07-24 2009-07-24 Catalyst for synthesizing methanol from synthesis gas and preparation method thereof
EP09800582A EP2305379A4 (en) 2008-07-24 2009-07-24 CATALYST FOR SYNTHESIS OF METHANOL FROM A SYNTHESIS GAS AND PREPARATION METHOD THEREOF

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR20080072286 2008-07-24
KR10-2008-0072286 2008-07-24

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WO2010011101A2 WO2010011101A2 (ko) 2010-01-28
WO2010011101A3 true WO2010011101A3 (ko) 2010-05-14

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Country Link
US (1) US8623927B2 (ko)
EP (1) EP2305379A4 (ko)
JP (1) JP5303033B2 (ko)
KR (1) KR101085038B1 (ko)
CN (1) CN102105222B (ko)
AU (1) AU2009274701B2 (ko)
WO (1) WO2010011101A2 (ko)

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WO2024029584A1 (ja) * 2022-08-04 2024-02-08 三井金属鉱業株式会社 複合酸化物、メタノール製造用触媒及び複合酸化物の製造方法
CN116037132B (zh) * 2022-12-28 2024-05-24 鄂尔多斯市瀚博科技有限公司 一种用于co2加氢制备甲醇的催化剂及其制备方法和应用
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AU2009274701B2 (en) 2012-12-06
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