WO2010143783A3 - Iron-based catalyst for fischer-tropsch synthesis and preparation method thereof - Google Patents

Iron-based catalyst for fischer-tropsch synthesis and preparation method thereof Download PDF

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Publication number
WO2010143783A3
WO2010143783A3 PCT/KR2009/005553 KR2009005553W WO2010143783A3 WO 2010143783 A3 WO2010143783 A3 WO 2010143783A3 KR 2009005553 W KR2009005553 W KR 2009005553W WO 2010143783 A3 WO2010143783 A3 WO 2010143783A3
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WO
WIPO (PCT)
Prior art keywords
iron
fischer
preparation
tropsch synthesis
based catalyst
Prior art date
Application number
PCT/KR2009/005553
Other languages
French (fr)
Other versions
WO2010143783A2 (en
Inventor
Suk Hwan Kang
Jong Wook Bae
Suk Jin Lee
Yun Jo Lee
Ki Won Jun
Original Assignee
Korea Research Institute Of Chemical Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Korea Research Institute Of Chemical Technology filed Critical Korea Research Institute Of Chemical Technology
Publication of WO2010143783A2 publication Critical patent/WO2010143783A2/en
Publication of WO2010143783A3 publication Critical patent/WO2010143783A3/en

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/036—Precipitation; Co-precipitation to form a gel or a cogel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of rare earths
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/745—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B01J23/8892—Manganese
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Disclosed herein are an iron-based catalyst for Fischer- Tropsch synthesis (FTS) and a preparation method thereof. More specifically, disclosed are a novel catalyst wherein iron as a main catalytic component, one promoter metal selected from the group consisting of copper, manganese and cobalt, and if necessary, potassium, are incorporated as active components into a cerium-zirconium oxide prepared using a sol-gel process, and a preparation method thereof. When the iron-based catalyst is applied in Fischer- Tropsch synthesis reactions using synthetic gas, it can ensure stable catalytic activity for a long period of time while having the excellent effects of showing a high conversion of carbon monoxide and a low selectivity for main byproduct methane and increasing the yield of high-boiling-point hydrocarbons and C2-C4 light hydrocarbons.
PCT/KR2009/005553 2009-06-12 2009-09-29 Iron-based catalyst for fischer-tropsch synthesis and preparation method thereof WO2010143783A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR10-2009-0052473 2009-06-12
KR1020090052473A KR101026536B1 (en) 2009-06-12 2009-06-12 Fe-based catalyst for the reaction of Fischer-Tropsch synthesis and preparation method thereof

Publications (2)

Publication Number Publication Date
WO2010143783A2 WO2010143783A2 (en) 2010-12-16
WO2010143783A3 true WO2010143783A3 (en) 2011-03-31

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KR (1) KR101026536B1 (en)
WO (1) WO2010143783A2 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
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CN108940302A (en) * 2018-07-19 2018-12-07 南京工业大学 Composite metal oxide catalyst and preparation method and application thereof
CN112973778B (en) * 2021-02-05 2022-03-22 浙江大学 Iron-zirconium bimetal supported catalyst and preparation method and application thereof

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EP2318131B1 (en) * 2009-09-04 2015-08-12 Korea Research Institute of Chemical Technology Catalyst for direct production of light olefins and preparation method thereof
KR101386629B1 (en) 2012-03-27 2014-04-18 국방과학연구소 Granule-Type Catalyst Composition, Preparation Method Thereof and Preparation Method of Liquid Hydrocarbon using the same
CN105377422B (en) 2013-03-28 2018-09-21 新加坡科技研究局 Methanation catalyst
CN103230810B (en) * 2013-04-25 2015-11-04 武汉凯迪工程技术研究总院有限公司 The fischer-tropsch synthetic catalyst of preparation of low carbon olefines by synthetic gas, modified molecular screen carrier and preparation method
SG2013050877A (en) 2013-06-28 2015-01-29 Agency Science Tech & Res Methanation catalyst
CN105555922A (en) * 2013-07-31 2016-05-04 沙特基础工业公司 A process for the production of olefins through fischer-tropsch based synthesis
CN105518111A (en) * 2013-07-31 2016-04-20 沙特基础工业公司 A process for the production of olefins through fischer-tropsch based synthesis
US9695365B2 (en) * 2013-07-31 2017-07-04 Saudi Basic Industries Corporation Process for the production of olefins through FT based synthesis
KR101469183B1 (en) * 2013-08-23 2014-12-10 한국화학연구원 method of prepering supported catalyst
CN105080561B (en) * 2014-05-05 2017-08-22 中国石油化工股份有限公司 A kind of load-type iron-based catalyst and preparation method thereof
KR20160092547A (en) 2015-01-27 2016-08-05 한국기술교육대학교 산학협력단 Mixed support catalyst for fischer-tropsch synthesis and it used liquid hydrocarbon fabrication method
CN106311269B (en) * 2015-07-03 2019-02-15 中国科学院大连化学物理研究所 Ferrum-based catalyst, preparation method and the application of sol-gel combustion method preparation
KR102155594B1 (en) * 2019-05-23 2020-09-14 에코팩쳐(주) Method for preparing oxidation catalyst for high temperature using excess impregnation method
US11193072B2 (en) 2019-12-03 2021-12-07 Saudi Arabian Oil Company Processing facility to form hydrogen and petrochemicals
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CN113426474B (en) * 2021-05-27 2022-05-03 浙江大学衢州研究院 Boric acid modified iron-zirconium shape-selective catalyst and preparation method and application thereof
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CN108940302A (en) * 2018-07-19 2018-12-07 南京工业大学 Composite metal oxide catalyst and preparation method and application thereof
CN112973778B (en) * 2021-02-05 2022-03-22 浙江大学 Iron-zirconium bimetal supported catalyst and preparation method and application thereof

Also Published As

Publication number Publication date
WO2010143783A2 (en) 2010-12-16
KR101026536B1 (en) 2011-04-01
KR20100133766A (en) 2010-12-22

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