GB1159035A - Methanol Synthesis. - Google Patents

Methanol Synthesis.

Info

Publication number
GB1159035A
GB1159035A GB41002/65A GB4100265A GB1159035A GB 1159035 A GB1159035 A GB 1159035A GB 41002/65 A GB41002/65 A GB 41002/65A GB 4100265 A GB4100265 A GB 4100265A GB 1159035 A GB1159035 A GB 1159035A
Authority
GB
United Kingdom
Prior art keywords
oxides
catalyst
zinc
copper
metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB41002/65A
Inventor
John Thomas Gallagher
John Mitchell Kidd
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB41002/65A priority Critical patent/GB1159035A/en
Priority to AT774166A priority patent/AT281777B/en
Priority to NO66164328A priority patent/NO124160B/no
Priority to DE1568864A priority patent/DE1568864C3/en
Priority to BE685706D priority patent/BE685706A/xx
Priority to ES0330359A priority patent/ES330359A1/en
Priority to FR73470A priority patent/FR1489682A/en
Publication of GB1159035A publication Critical patent/GB1159035A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • C07C29/154—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing copper, silver, gold, or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/1512—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by reaction conditions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/1516—Multisteps
    • C07C29/1518—Multisteps one step being the formation of initial mixture of carbon oxides and hydrogen for synthesis
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

1,159,035. Methanol synthesis. IMPERIAL CHEMICAL INDUSTRIES Ltd. 26 July, 1966 [18 Aug., 1965; 27 Sept., 1965], Nos. 35368/65 and 41002/65. Heading C2C. Methanol is prepared by reacting carbon monoxide or carbon dioxide or both with hydrogen at a pressure in the range 10 to 150 atmospheres and a temperature in the range 160‹ to 300‹ C. in the presence of a catalyst containing the oxides of copper and zinc and at least one difficultly reducible oxide of at least one other metal from Groups II to IV of the Periodic Table, removing methanol from the reaction mixture and recycling unconverted reactants to the catalyst. The term " oxides " as applied to the catalyst composition is defined as the reduction product of the initial mixture of metal oxides under the conditions of the synthesis process. The catalyst preferably contains at least 20% (by metal atoms) of copper, less than 70% zinc and 4 to 20% of the other metal oxide or oxides, e.g. alumina, magnesia, titania, zirconia, ceria or thoria. The feed gas for the process preferably contains 1-20% by volume of carbon dioxide and up to 10 times the stoichiometric concentration of hydrogen required to react with all the carbon oxides present and may be prepared in a primary hydrocarbonsteam reforming process. The process is exemplified using a catalyst comprising the oxides of copper, zinc and aluminium.
GB41002/65A 1965-08-18 1965-09-27 Methanol Synthesis. Expired GB1159035A (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
GB41002/65A GB1159035A (en) 1965-08-18 1965-09-27 Methanol Synthesis.
AT774166A AT281777B (en) 1965-08-18 1966-08-12 Process for the synthesis of methanol
NO66164328A NO124160B (en) 1965-08-18 1966-08-16
DE1568864A DE1568864C3 (en) 1965-08-18 1966-08-16 Process for the synthesis of methanol
BE685706D BE685706A (en) 1965-08-18 1966-08-18
ES0330359A ES330359A1 (en) 1965-08-18 1966-08-18 Methanol synthesis procedure. (Machine-translation by Google Translate, not legally binding)
FR73470A FR1489682A (en) 1965-08-18 1966-08-18 Methanol synthesis process

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB3536865 1965-08-18
GB41002/65A GB1159035A (en) 1965-08-18 1965-09-27 Methanol Synthesis.

Publications (1)

Publication Number Publication Date
GB1159035A true GB1159035A (en) 1969-07-23

Family

ID=26262693

Family Applications (1)

Application Number Title Priority Date Filing Date
GB41002/65A Expired GB1159035A (en) 1965-08-18 1965-09-27 Methanol Synthesis.

Country Status (6)

Country Link
AT (1) AT281777B (en)
BE (1) BE685706A (en)
DE (1) DE1568864C3 (en)
ES (1) ES330359A1 (en)
GB (1) GB1159035A (en)
NO (1) NO124160B (en)

Cited By (42)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4107089A (en) * 1977-03-14 1978-08-15 Petr Grigorievich Bondar Catalyst for the synthesis of methanol and method for preparing same
EP0005492A2 (en) * 1978-05-15 1979-11-28 The Standard Oil Company Preparation of alcohols from synthesis gas
US4203915A (en) * 1976-01-29 1980-05-20 Metallgesellschaft Process of producing methanol
EP0011404A1 (en) * 1978-11-10 1980-05-28 Imperial Chemical Industries Plc Integrated process for synthesis of methanol and of ammonia
US4219492A (en) * 1978-04-18 1980-08-26 Toyo Engineering Corporation Process for manufacturing methanol
FR2448385A1 (en) * 1979-02-10 1980-09-05 Mitsubishi Gas Chemical Co CATALYSTS BASED ON COPPER, ZINC AND ALUMINUM OXIDES, THEIR PREPARATION AND THEIR USE IN THE SYNTHESIS OF METHANOL
US4226795A (en) * 1979-05-04 1980-10-07 E. I. Du Pont De Nemours And Company Purge gas in methanol synthesis
US4279781A (en) * 1979-10-09 1981-07-21 United Catalysts Inc. Catalyst for the synthesis of methanol
JPS5738568B1 (en) * 1970-03-20 1982-08-16
US4386017A (en) * 1979-11-12 1983-05-31 Mitsubishi Gas Chemical Company Preparation of improved catalyst composition
US4529738A (en) * 1980-11-25 1985-07-16 Institut Francais Du Petrole Process for operating highly exothermic reactions
US4540713A (en) * 1978-05-15 1985-09-10 The Standard Oil Company Preparation of alcohols from synthesis gas
US4559207A (en) * 1971-10-27 1985-12-17 Metallgesellschaft Ag Reactor for producing methanol and process
US4593015A (en) * 1978-05-15 1986-06-03 The Standard Oil Company Catalyst for the preparation of alcohols from synthesis gas
US4609678A (en) * 1978-05-15 1986-09-02 The Standard Oil Company Preparation of alcohols from synthesis gas
US4668656A (en) * 1978-05-15 1987-05-26 The Standard Oil Company Catalyst for the preparation of alcohols from synthesis gas
US4762817A (en) * 1986-11-03 1988-08-09 Union Carbide Corporation Aldehyde hydrogenation catalyst
US4788175A (en) * 1985-08-30 1988-11-29 Imperial Chemical Industries Plc Catalyst
US4876402A (en) * 1986-11-03 1989-10-24 Union Carbide Chemicals And Plastics Company Inc. Improved aldehyde hydrogenation process
US4935395A (en) * 1986-12-19 1990-06-19 Associated Universities, Inc. Homogeneous catalyst formulations for methanol production
US4943551A (en) * 1985-11-08 1990-07-24 Union Carbide Chemicals And Plastics Company, Inc. Catalyst for synthesis of mixtures of methanol and higher alcohols
US5079267A (en) * 1989-09-16 1992-01-07 Xytel Technologies Partnership Methanol production
US5254596A (en) * 1992-09-15 1993-10-19 Eastman Kodak Company Process for the manufacture of methanol and dimethyl ether
US5254520A (en) * 1990-09-18 1993-10-19 Csir Catalyst for the synthesis of methanol
US5266281A (en) * 1989-09-16 1993-11-30 Xytel Technologies Partnership Catalytic reactor
US5302569A (en) * 1991-08-17 1994-04-12 Hoechst Aktiengesellschaft Copper/zinc oxide/aluminum oxide-containing catalysts
US5455281A (en) * 1992-12-07 1995-10-03 Haldor Topsoe A/S Method of cooling a synthesis gas in a catalytic reactor
US5631302A (en) * 1994-05-10 1997-05-20 Metallgesellschaft Aktiengesellschaft Process of producing methanol
EP0868943A2 (en) * 1997-03-31 1998-10-07 Director-General Of The Agency Of Industrial Science And Technology Copper, zinc and aluminium based catalyst for methanol synthesis and reforming
EP2305379A2 (en) * 2008-07-24 2011-04-06 Hyundai Heavy Industries Co., Ltd. Catalyst for synthesizing methanol from synthesis gas and preparation method thereof
EP2399894A2 (en) 2006-05-30 2011-12-28 Starchem Technologies, Inc. Methanol production process and system
DE112010002562T5 (en) 2009-06-17 2012-09-13 Johnson Matthey Plc Methanol synthesis process
DE102011086451A1 (en) 2011-11-16 2013-05-16 Süd-Chemie Ip Gmbh & Co. Kg METHANOL SYNTHESIS CATALYST BASED ON COPPER, ZINC AND ALUMINUM
EP2628538A1 (en) 2012-02-17 2013-08-21 Total Raffinage Chimie Process for manufacturing a methanol synthesis catalyst
US20130296620A1 (en) * 2012-05-03 2013-11-07 Exxonmobil Chemical Patents Inc. Hydrocarbon Conversion Process
CN102307835B (en) * 2008-12-08 2013-12-04 现代重工业株式会社 Methanol synthesis method using synthesis gas generated by a mixed reforming of natural gas and carbon dioxide
US9492809B2 (en) 2009-06-17 2016-11-15 Johnson Matthey Plc Carbon oxides conversion process
EP2492008A4 (en) * 2009-10-23 2017-03-15 Mitsubishi Gas Chemical Company, Inc. Methanol synthesis catalyst
US10668450B2 (en) 2016-01-07 2020-06-02 Total Raffinage Chimie Supported indium oxide catalyst and process for methanol synthesis using the same
US10676416B2 (en) 2016-01-07 2020-06-09 Total Raffinage Chimie Process for methanol synthesis using an indium oxide based catalyst
WO2022106313A1 (en) 2020-11-17 2022-05-27 Totalenergies Onetech Process for methanol synthesis from co2-rich syngas
ES2914350A1 (en) * 2020-12-09 2022-06-09 Blueplasma Power S L Device and process to produce dimethyl carbonate (Machine-translation by Google Translate, not legally binding)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3448161A (en) * 1968-02-12 1969-06-03 Dow Chemical Co Alkylation process
BE743652A (en) * 1968-12-26 1970-05-28
DE2846614C3 (en) * 1978-10-26 1982-05-19 Basf Ag, 6700 Ludwigshafen Process for the production of methanol
IT1148864B (en) * 1980-05-16 1986-12-03 Snam Progetti PROCESS FOR THE PRODUCTION OF A MIXTURE OF METHANOL AND HIGHER ALCOHOLS FUEL DEGREE
IT1140947B (en) * 1980-05-16 1986-10-10 Snam Progetti PROCESS FOR THE PRODUCTION OF A MIXTURE OF METHANOL AND HIGHER ALCOHOL "FUEL DEGREE"
EP0117944B1 (en) * 1982-12-13 1990-06-20 Imperial Chemical Industries Plc Methanol synthesis and catalyst therefor
DE3318855A1 (en) * 1983-05-25 1984-11-29 Basf Ag, 6700 Ludwigshafen METHOD FOR PRODUCING METHANOL
DE3403492A1 (en) * 1984-02-02 1985-08-08 Metallgesellschaft Ag, 6000 Frankfurt METHOD FOR PRODUCING A MIXTURE OF METHANOL AND HIGHER ALCOHOLS
DE102013225724A1 (en) 2013-12-12 2015-06-18 Evonik Industries Ag Purification of liquid hydrocarbon streams by means of a copper-containing sorbent
EP3023131A1 (en) 2014-11-18 2016-05-25 Evonik Degussa GmbH Two stage fine desulphurisation of olefin mixtures
SG10201604013RA (en) 2015-05-28 2016-12-29 Evonik Degussa Gmbh Hydrogen-assisted adsorption of sulphur compounds from olefin mixtures

Cited By (59)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5738568B1 (en) * 1970-03-20 1982-08-16
US4559207A (en) * 1971-10-27 1985-12-17 Metallgesellschaft Ag Reactor for producing methanol and process
US4203915A (en) * 1976-01-29 1980-05-20 Metallgesellschaft Process of producing methanol
US4107089A (en) * 1977-03-14 1978-08-15 Petr Grigorievich Bondar Catalyst for the synthesis of methanol and method for preparing same
US4219492A (en) * 1978-04-18 1980-08-26 Toyo Engineering Corporation Process for manufacturing methanol
US4540713A (en) * 1978-05-15 1985-09-10 The Standard Oil Company Preparation of alcohols from synthesis gas
US4668656A (en) * 1978-05-15 1987-05-26 The Standard Oil Company Catalyst for the preparation of alcohols from synthesis gas
US4609678A (en) * 1978-05-15 1986-09-02 The Standard Oil Company Preparation of alcohols from synthesis gas
US4593015A (en) * 1978-05-15 1986-06-03 The Standard Oil Company Catalyst for the preparation of alcohols from synthesis gas
EP0005492A3 (en) * 1978-05-15 1979-12-12 The Standard Oil Company Preparation of alcohols from synthesis gas
EP0005492A2 (en) * 1978-05-15 1979-11-28 The Standard Oil Company Preparation of alcohols from synthesis gas
EP0011404A1 (en) * 1978-11-10 1980-05-28 Imperial Chemical Industries Plc Integrated process for synthesis of methanol and of ammonia
US4367206A (en) 1978-11-10 1983-01-04 Imperial Chemical Industries Limited Method for producing methanol and ammonia
FR2448385A1 (en) * 1979-02-10 1980-09-05 Mitsubishi Gas Chemical Co CATALYSTS BASED ON COPPER, ZINC AND ALUMINUM OXIDES, THEIR PREPARATION AND THEIR USE IN THE SYNTHESIS OF METHANOL
US4305842A (en) 1979-02-10 1981-12-15 Mitsubishi Gas Chemical Company, Inc. Preparation of improved catalyst composition
US4226795A (en) * 1979-05-04 1980-10-07 E. I. Du Pont De Nemours And Company Purge gas in methanol synthesis
US4279781A (en) * 1979-10-09 1981-07-21 United Catalysts Inc. Catalyst for the synthesis of methanol
US4386017A (en) * 1979-11-12 1983-05-31 Mitsubishi Gas Chemical Company Preparation of improved catalyst composition
US4529738A (en) * 1980-11-25 1985-07-16 Institut Francais Du Petrole Process for operating highly exothermic reactions
US4788175A (en) * 1985-08-30 1988-11-29 Imperial Chemical Industries Plc Catalyst
US4943551A (en) * 1985-11-08 1990-07-24 Union Carbide Chemicals And Plastics Company, Inc. Catalyst for synthesis of mixtures of methanol and higher alcohols
US4762817A (en) * 1986-11-03 1988-08-09 Union Carbide Corporation Aldehyde hydrogenation catalyst
US4876402A (en) * 1986-11-03 1989-10-24 Union Carbide Chemicals And Plastics Company Inc. Improved aldehyde hydrogenation process
US4935395A (en) * 1986-12-19 1990-06-19 Associated Universities, Inc. Homogeneous catalyst formulations for methanol production
US5079267A (en) * 1989-09-16 1992-01-07 Xytel Technologies Partnership Methanol production
US5266281A (en) * 1989-09-16 1993-11-30 Xytel Technologies Partnership Catalytic reactor
US5254520A (en) * 1990-09-18 1993-10-19 Csir Catalyst for the synthesis of methanol
US5302569A (en) * 1991-08-17 1994-04-12 Hoechst Aktiengesellschaft Copper/zinc oxide/aluminum oxide-containing catalysts
US5254596A (en) * 1992-09-15 1993-10-19 Eastman Kodak Company Process for the manufacture of methanol and dimethyl ether
US5455281A (en) * 1992-12-07 1995-10-03 Haldor Topsoe A/S Method of cooling a synthesis gas in a catalytic reactor
US5631302A (en) * 1994-05-10 1997-05-20 Metallgesellschaft Aktiengesellschaft Process of producing methanol
EP0868943A2 (en) * 1997-03-31 1998-10-07 Director-General Of The Agency Of Industrial Science And Technology Copper, zinc and aluminium based catalyst for methanol synthesis and reforming
EP0868943A3 (en) * 1997-03-31 1999-03-31 Director-General Of The Agency Of Industrial Science And Technology Copper, zinc and aluminium based catalyst for methanol synthesis and reforming
EP2404888A2 (en) 2006-05-30 2012-01-11 Starchem Technologies, Inc. Methanol production process
EP2399894A2 (en) 2006-05-30 2011-12-28 Starchem Technologies, Inc. Methanol production process and system
CN102105222A (en) * 2008-07-24 2011-06-22 现代重工业株式会社 Catalyst for synthesizing methanol from synthesis gas and preparation method thereof
JP2011528617A (en) * 2008-07-24 2011-11-24 ヒュンダイ ヘビー インダストリーズ カンパニー リミテッド Methanol synthesis catalyst from synthesis gas and method for producing the same
US8623927B2 (en) 2008-07-24 2014-01-07 Hyundai Heavy Industries Co., Ltd. Catalyst for synthesizing methanol from synthesis gas and preparation method thereof
EP2305379A4 (en) * 2008-07-24 2012-04-11 Hyun Dai Heavy Ind Co Ltd Catalyst for synthesizing methanol from synthesis gas and preparation method thereof
CN102105222B (en) * 2008-07-24 2014-07-09 现代重工业株式会社 Catalyst for synthesizing methanol from synthesis gas and preparation method thereof
AU2009274701B2 (en) * 2008-07-24 2012-12-06 Hyundai Heavy Industries Co., Ltd. Catalyst for synthesizing methanol from synthesis gas and preparation method thereof
EP2305379A2 (en) * 2008-07-24 2011-04-06 Hyundai Heavy Industries Co., Ltd. Catalyst for synthesizing methanol from synthesis gas and preparation method thereof
US8729141B2 (en) 2008-12-08 2014-05-20 Hyundai Heavy Industries Co., Ltd. Method for methanol synthesis using synthesis gas generated by combined reforming of natural gas with carbon dioxide
CN102307835B (en) * 2008-12-08 2013-12-04 现代重工业株式会社 Methanol synthesis method using synthesis gas generated by a mixed reforming of natural gas and carbon dioxide
US8957117B2 (en) 2009-06-17 2015-02-17 Johnson Matthey Plc Methanol synthesis process
US9492809B2 (en) 2009-06-17 2016-11-15 Johnson Matthey Plc Carbon oxides conversion process
DE112010002562T5 (en) 2009-06-17 2012-09-13 Johnson Matthey Plc Methanol synthesis process
EP2492008A4 (en) * 2009-10-23 2017-03-15 Mitsubishi Gas Chemical Company, Inc. Methanol synthesis catalyst
WO2013072197A1 (en) 2011-11-16 2013-05-23 Süd-Chemie Ip Gmbh & Co. Kg Methanol synthesis catalyst on the basis of copper, zinc and aluminum
DE102011086451A1 (en) 2011-11-16 2013-05-16 Süd-Chemie Ip Gmbh & Co. Kg METHANOL SYNTHESIS CATALYST BASED ON COPPER, ZINC AND ALUMINUM
WO2013120711A1 (en) 2012-02-17 2013-08-22 Total Raffinage Chimie Process for manufacturing a methanol synthesis catalyst
EP2628538A1 (en) 2012-02-17 2013-08-21 Total Raffinage Chimie Process for manufacturing a methanol synthesis catalyst
US20130296620A1 (en) * 2012-05-03 2013-11-07 Exxonmobil Chemical Patents Inc. Hydrocarbon Conversion Process
WO2013165655A1 (en) 2012-05-03 2013-11-07 Exxonmobil Chemical Patents Inc. Hydrocarbon conversion process
US9505676B2 (en) * 2012-05-03 2016-11-29 Exxonmobil Chemical Patents Inc. Hydrocarbon conversion process
US10668450B2 (en) 2016-01-07 2020-06-02 Total Raffinage Chimie Supported indium oxide catalyst and process for methanol synthesis using the same
US10676416B2 (en) 2016-01-07 2020-06-09 Total Raffinage Chimie Process for methanol synthesis using an indium oxide based catalyst
WO2022106313A1 (en) 2020-11-17 2022-05-27 Totalenergies Onetech Process for methanol synthesis from co2-rich syngas
ES2914350A1 (en) * 2020-12-09 2022-06-09 Blueplasma Power S L Device and process to produce dimethyl carbonate (Machine-translation by Google Translate, not legally binding)

Also Published As

Publication number Publication date
BE685706A (en) 1967-02-20
DE1568864A1 (en) 1970-07-16
NO124160B (en) 1972-03-13
AT281777B (en) 1970-06-10
DE1568864C3 (en) 1979-12-20
ES330359A1 (en) 1967-09-01
DE1568864B2 (en) 1973-08-23

Similar Documents

Publication Publication Date Title
GB1159035A (en) Methanol Synthesis.
US5041405A (en) Lithium/magnesium oxide catalyst and method of making
EP0230769B1 (en) Oxidation of methane over heterogeneous catalysts
GB2064525A (en) Preparation of dimethyl carbonate
GB1505254A (en) Catalyst and process for preparing methane rich gas
US3689575A (en) Methanol synthesis
ES370950A1 (en) Process for conducting exothermic chemical reaction in heterogeneous gas-liquid mixtures
MY113720A (en) Process for the preparation of hydrogen and carbon monoxide containing mixtures
Evans et al. Hydrogenolysis of alkyl formates over a copper chromite catalyst
GB1477392A (en) Process for making ethylene glycol
US2006981A (en) Production of hydrocyanic acid
GB1508868A (en) Catalytic oxidation process
GB1129597A (en) Production of hydrogen
GB1306863A (en) Production of acetic acid
GB1010871A (en) Water-gas conversion and catalysts therefor
GB1286970A (en) Low temperature methanol synthesis catalyst precursor
US3758417A (en) Copper zinc didymium oxide containing catelysts
GB1440413A (en) Process for producing butyraldehydes
GB1357335A (en) Hydrogen
GB1475358A (en) Process for preparing chlorinated hydrocarbons
US3636156A (en) Process for the direct production of ketones from olefins
GB1181437A (en) Process for the preparation of 2,3,5-trimethyl phenol.
IL25539A (en) Process for the catalytic production of hydrogen cyanide
US3709919A (en) Production of methanol
GB1262479A (en) Methanol production

Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PE Patent expired