GB1357335A - Hydrogen - Google Patents
HydrogenInfo
- Publication number
- GB1357335A GB1357335A GB3551370A GB3551370A GB1357335A GB 1357335 A GB1357335 A GB 1357335A GB 3551370 A GB3551370 A GB 3551370A GB 3551370 A GB3551370 A GB 3551370A GB 1357335 A GB1357335 A GB 1357335A
- Authority
- GB
- United Kingdom
- Prior art keywords
- catalyst
- guard
- hydrogen
- guard material
- shift
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910052739 hydrogen Inorganic materials 0.000 title abstract 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title abstract 3
- 239000001257 hydrogen Substances 0.000 title abstract 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 6
- 239000003054 catalyst Substances 0.000 abstract 5
- 239000000463 material Substances 0.000 abstract 5
- 239000007789 gas Substances 0.000 abstract 3
- 229910018072 Al 2 O 3 Inorganic materials 0.000 abstract 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 2
- 150000007514 bases Chemical class 0.000 abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 abstract 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- QPLDLSVMHZLSFG-UHFFFAOYSA-N CuO Inorganic materials [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 abstract 1
- 239000001273 butane Substances 0.000 abstract 1
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 abstract 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 abstract 1
- 150000002823 nitrates Chemical class 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- XLOMVQKBTHCTTD-UHFFFAOYSA-N zinc oxide Inorganic materials [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
- C10K3/02—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment
- C10K3/04—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment reducing the carbon monoxide content, e.g. water-gas shift [WGS]
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
- C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
- C01B3/16—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
- Hydrogen, Water And Hydrids (AREA)
Abstract
1357335 Hydrogen-rich gas IMPERIAL CHEMICAL INDUSTRIES Ltd 28 June 1971 [22 July 1970] 35513/70 Heading C5E Hydrogen is produced by reacting CO with steam at under 300 C. over a copper containing low temperature shift catalyst in discrete pieces characterized in that the catalyst is preceded by a bed of discrete pieces of a solid guard material that is more basic than ZnO or that such catalyst and such guard material are in admixture. The guard material may comprise a basic compound (e.g. an oxide, hydroxide or carbonate) supported on a carrier (e.g. alumina). The guard material may contain 0À3 to 0À6% by weight of the basic compound while the catalyst contains less than 0À25% by weight thereof. A hydrocarbon feedstock e.g. CH 4 , butane, naphtha or refinery gas may be reacted at 600 to 1000 C. to give a gas containing CO and H 2 which is cooled to shift inlet temperature and subjected to shift conversion over a catalyst as above which is protected by said guard bed. In the examples the guard materials are NaOH on Al 2 O 3 , a mixture of NaOH, ZnO, CuO and Al 2 O 3 or nitrates of Ba, Mn, Y or La on alumina.
Priority Applications (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB3551370A GB1357335A (en) | 1970-07-22 | 1970-07-22 | Hydrogen |
| IT752271A IT951922B (en) | 1970-07-22 | 1971-07-21 | TATALYTIC PROCESS FOR THE PRODUCTION OF HYDROGEN FROM CARBON OXIDE AND WATER VAPOR |
| CA118,813A CA945738A (en) | 1970-07-22 | 1971-07-21 | Process for producing hydrogen |
| FR7126778A FR2103196A5 (en) | 1970-07-22 | 1971-07-21 | |
| BE770356A BE770356A (en) | 1970-07-22 | 1971-07-22 | PROCESS FOR PRODUCING HYDROGEN |
| NL7110096A NL7110096A (en) | 1970-07-22 | 1971-07-22 | |
| DE19712136746 DE2136746A1 (en) | 1970-07-22 | 1971-07-22 | Process for the production of hydrogen |
| US316566A US3922337A (en) | 1970-07-22 | 1972-12-19 | Hydrogen |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB3551370A GB1357335A (en) | 1970-07-22 | 1970-07-22 | Hydrogen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1357335A true GB1357335A (en) | 1974-06-19 |
Family
ID=10378584
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3551370A Expired GB1357335A (en) | 1970-07-22 | 1970-07-22 | Hydrogen |
Country Status (7)
| Country | Link |
|---|---|
| BE (1) | BE770356A (en) |
| CA (1) | CA945738A (en) |
| DE (1) | DE2136746A1 (en) |
| FR (1) | FR2103196A5 (en) |
| GB (1) | GB1357335A (en) |
| IT (1) | IT951922B (en) |
| NL (1) | NL7110096A (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2390377A1 (en) * | 1977-05-09 | 1978-12-08 | Ici Ltd | PROCESS FOR OBTAINING CARBON DIOXIDE AND HYDROGEN FROM CARBON MONO-OXIDE AND WATER VAPOR |
| WO2001017674A1 (en) * | 1999-09-06 | 2001-03-15 | Imperial Chemical Industries Plc | Guard bed containing lead compounds upstream of a bed of copper-containing catalyst to prevent its contamination by chlorine and sulphur contaminants |
| WO2002066156A1 (en) * | 2001-02-20 | 2002-08-29 | Johnson Matthey Plc | A combination of a guard bed and a catalyst bed |
| WO2004014546A1 (en) * | 2002-08-13 | 2004-02-19 | Johnson Matthey Plc | Combination of a guard bed and a copper-containing catalyst bed |
| CN101531568B (en) * | 2009-04-13 | 2011-12-07 | 烟台万华聚氨酯股份有限公司 | Method for synthesizing 1,6-hexamethylene glycol by using dimethyl adipate gas phase and hydrogen |
| WO2017072479A1 (en) * | 2015-10-29 | 2017-05-04 | Johnson Matthey Public Limited Company | Water gas shift process |
| US10807866B2 (en) | 2015-10-29 | 2020-10-20 | Johnson Matthey Public Limited Company | Water-gas shift catalyst |
| US11014811B2 (en) | 2015-10-29 | 2021-05-25 | Johnson Matthey Public Limited Company | Water gas shift process |
| EP4155287A1 (en) | 2021-09-23 | 2023-03-29 | Clariant International Ltd | Reactor and method for methanol synthesis |
-
1970
- 1970-07-22 GB GB3551370A patent/GB1357335A/en not_active Expired
-
1971
- 1971-07-21 FR FR7126778A patent/FR2103196A5/fr not_active Expired
- 1971-07-21 IT IT752271A patent/IT951922B/en active
- 1971-07-21 CA CA118,813A patent/CA945738A/en not_active Expired
- 1971-07-22 BE BE770356A patent/BE770356A/en unknown
- 1971-07-22 DE DE19712136746 patent/DE2136746A1/en active Pending
- 1971-07-22 NL NL7110096A patent/NL7110096A/xx unknown
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2390377A1 (en) * | 1977-05-09 | 1978-12-08 | Ici Ltd | PROCESS FOR OBTAINING CARBON DIOXIDE AND HYDROGEN FROM CARBON MONO-OXIDE AND WATER VAPOR |
| WO2001017674A1 (en) * | 1999-09-06 | 2001-03-15 | Imperial Chemical Industries Plc | Guard bed containing lead compounds upstream of a bed of copper-containing catalyst to prevent its contamination by chlorine and sulphur contaminants |
| US7501112B2 (en) | 1999-09-06 | 2009-03-10 | Johnson Matthey Plc | Guard bed containing lead compounds upstream of a bed of copper-containing catalyst to prevent its contamination by chlorine and sulphur contaminants |
| US7098167B2 (en) | 1999-09-06 | 2006-08-29 | Johnson Matthey Plc | Guard bed containing lead compounds upstream of a bed of copper-containing catalyst to prevent its contamination by chlorine and sulphur contaminants |
| AU2002225185B2 (en) * | 2001-02-20 | 2005-10-27 | Johnson Matthey Plc | A combination of a guard bed and a catalyst bed |
| US7087550B2 (en) * | 2001-02-20 | 2006-08-08 | Johnson Matthey Plc | Combination of a guard bed and a catalyst bed |
| WO2002066156A1 (en) * | 2001-02-20 | 2002-08-29 | Johnson Matthey Plc | A combination of a guard bed and a catalyst bed |
| WO2004014546A1 (en) * | 2002-08-13 | 2004-02-19 | Johnson Matthey Plc | Combination of a guard bed and a copper-containing catalyst bed |
| US7148178B2 (en) | 2002-08-13 | 2006-12-12 | Johnson Matthey Plc | Combination of a guard bed and a copper-containing catalyst bed |
| CN101531568B (en) * | 2009-04-13 | 2011-12-07 | 烟台万华聚氨酯股份有限公司 | Method for synthesizing 1,6-hexamethylene glycol by using dimethyl adipate gas phase and hydrogen |
| WO2017072479A1 (en) * | 2015-10-29 | 2017-05-04 | Johnson Matthey Public Limited Company | Water gas shift process |
| US10494255B2 (en) | 2015-10-29 | 2019-12-03 | Johnson Matthey Public Limited Company | Water gas shift process |
| US10807866B2 (en) | 2015-10-29 | 2020-10-20 | Johnson Matthey Public Limited Company | Water-gas shift catalyst |
| US11014811B2 (en) | 2015-10-29 | 2021-05-25 | Johnson Matthey Public Limited Company | Water gas shift process |
| EP4155287A1 (en) | 2021-09-23 | 2023-03-29 | Clariant International Ltd | Reactor and method for methanol synthesis |
| WO2023046685A1 (en) | 2021-09-23 | 2023-03-30 | Clariant International Ltd. | Reactor and method for synthesizing methanol |
Also Published As
| Publication number | Publication date |
|---|---|
| CA945738A (en) | 1974-04-23 |
| IT951922B (en) | 1973-07-10 |
| NL7110096A (en) | 1972-01-25 |
| BE770356A (en) | 1972-01-24 |
| FR2103196A5 (en) | 1972-04-07 |
| DE2136746A1 (en) | 1972-04-06 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PLNP | Patent lapsed through nonpayment of renewal fees |