WO2009031445A1 - プロピレンの製造方法 - Google Patents

プロピレンの製造方法 Download PDF

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Publication number
WO2009031445A1
WO2009031445A1 PCT/JP2008/065319 JP2008065319W WO2009031445A1 WO 2009031445 A1 WO2009031445 A1 WO 2009031445A1 JP 2008065319 W JP2008065319 W JP 2008065319W WO 2009031445 A1 WO2009031445 A1 WO 2009031445A1
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WIPO (PCT)
Prior art keywords
zeolite
raw material
material containing
pore
hydrocarbon raw
Prior art date
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PCT/JP2008/065319
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English (en)
French (fr)
Inventor
Haruyuki Minoura
Yoshikazu Takamatsu
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Asahi Kasei Chemicals Corporation
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Publication date
Application filed by Asahi Kasei Chemicals Corporation filed Critical Asahi Kasei Chemicals Corporation
Priority to US12/676,118 priority Critical patent/US9079168B2/en
Priority to KR1020107004871A priority patent/KR101169144B1/ko
Priority to EP08828928A priority patent/EP2184268A4/en
Priority to CN200880023549A priority patent/CN101687726A/zh
Priority to JP2009531196A priority patent/JP5116043B2/ja
Publication of WO2009031445A1 publication Critical patent/WO2009031445A1/ja

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/44—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/10—Heat treatment in the presence of water, e.g. steam
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/30—Ion-exchange
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond
    • C07C6/04—Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/36—Steaming
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

　本発明の目的は、効率よく安定に、高濃度のエチレンを含有する炭化水素原料からプロピレンを製造する方法を提供する。本発明は、５０質量％を超えるエチレンを含有する炭化水素原料を、下記（１）～（３）を満たすゼオライト含有触媒と接触転化させてプロピレンを製造する方法を開示する。 （１）５～６．５Åの細孔径を有する中間細孔径ゼオライトを含有し、 （２）該中間細孔径ゼオライトのＳｉＯ２／Ａｌ２Ｏ３モル比が、２０～３００の範囲であり （３）アンモニア昇温脱離スペクトルにおける高温脱離量から求められる酸量（ＴＰＤ酸量）が、２０～３５０μｍｏｌ／ｇ－ゼオライトである。
PCT/JP2008/065319 2007-09-06 2008-08-27 プロピレンの製造方法 WO2009031445A1 (ja)

Priority Applications (5)

Application Number Priority Date Filing Date Title
US12/676,118 US9079168B2 (en) 2007-09-06 2008-08-27 Process for producing propylene
KR1020107004871A KR101169144B1 (ko) 2007-09-06 2008-08-27 프로필렌의 제조 방법
EP08828928A EP2184268A4 (en) 2007-09-06 2008-08-27 PROCESS FOR THE PRODUCTION OF PROPYLENE
CN200880023549A CN101687726A (zh) 2007-09-06 2008-08-27 丙烯的制造方法
JP2009531196A JP5116043B2 (ja) 2007-09-06 2008-08-27 プロピレンの製造方法

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007231400 2007-09-06
JP2007-231400 2007-09-06

Publications (1)

Publication Number Publication Date
WO2009031445A1 true WO2009031445A1 (ja) 2009-03-12

Family

ID=40428766

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/065319 WO2009031445A1 (ja) 2007-09-06 2008-08-27 プロピレンの製造方法

Country Status (8)

Country Link
US (1) US9079168B2 (ja)
EP (1) EP2184268A4 (ja)
JP (1) JP5116043B2 (ja)
KR (1) KR101169144B1 (ja)
CN (2) CN105037067A (ja)
MY (1) MY156919A (ja)
TW (1) TW200918487A (ja)
WO (1) WO2009031445A1 (ja)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010101121A1 (ja) * 2009-03-02 2010-09-10 旭化成ケミカルズ株式会社 プロピレンの製造方法
JP2011079819A (ja) * 2009-09-14 2011-04-21 Mitsubishi Chemicals Corp プロピレンの製造方法
JP2011079818A (ja) * 2009-09-14 2011-04-21 Mitsubishi Chemicals Corp プロピレンの製造方法
JP2011078962A (ja) * 2009-08-11 2011-04-21 Mitsubishi Chemicals Corp 触媒の再生方法
JP2018145085A (ja) * 2017-03-03 2018-09-20 東ソー株式会社 ゼオライトおよびその製造方法
JP2018153769A (ja) * 2017-03-21 2018-10-04 東ソー株式会社 金属含有ゼオライト
WO2024162258A1 (ja) * 2023-01-30 2024-08-08 旭化成株式会社 エタノールの変換方法、ゼオライト含有触媒、ゼオライト含有触媒の製造方法、及び炭化水素等の製造方法

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101298871B1 (ko) * 2011-02-24 2013-08-21 롯데케미칼 주식회사 에틸렌 및 프로필렌 제조방법
US20160107119A1 (en) * 2014-10-16 2016-04-21 Battelle Memorial Institute CATALYSTS FOR ENHANCED REDUCTION OF NOx GASES AND PROCESSES FOR MAKING AND USING SAME
CN105037068B (zh) * 2015-06-26 2017-03-08 中石化炼化工程（集团）股份有限公司 一种丙烯的制备方法及设备
CN110283032B (zh) * 2018-03-19 2021-03-02 中国科学院大连化学物理研究所 一种乙烯直接转化制备丙烯的方法

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US4527001A (en) 1983-11-15 1985-07-02 Union Carbide Corporation Small olefin interconversions
JP2001031979A (ja) * 1999-06-16 2001-02-06 Fina Res Sa オレフィン類の製造
JP2006335729A (ja) * 2005-06-03 2006-12-14 Mitsubishi Chemicals Corp プロピレンの製造方法
JP2006335730A (ja) 2005-06-03 2006-12-14 Mitsubishi Chemicals Corp プロピレンの製造方法
JP2007231400A (ja) 2006-03-03 2007-09-13 Mitsubishi Heavy Ind Ltd 真空処理システム及びベント方法

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US5019357A (en) * 1987-11-10 1991-05-28 Mobil Oil Corporation Reactor system for upgrading light olefins in staged reactors
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JPH06346063A (ja) 1993-06-04 1994-12-20 Asahi Chem Ind Co Ltd 軽質炭化水素の接触変換法
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JP5330635B2 (ja) * 2006-01-20 2013-10-30 豊田通商株式会社 プロピレンの製造方法、触媒の再生方法、固体酸触媒

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JP2007231400A (ja) 2006-03-03 2007-09-13 Mitsubishi Heavy Ind Ltd 真空処理システム及びベント方法

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See also references of EP2184268A4

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010101121A1 (ja) * 2009-03-02 2010-09-10 旭化成ケミカルズ株式会社 プロピレンの製造方法
US8450551B2 (en) 2009-03-02 2013-05-28 Asahi Kasei Chemicals Corporation Method for producing propylene
JP2011078962A (ja) * 2009-08-11 2011-04-21 Mitsubishi Chemicals Corp 触媒の再生方法
JP2011079819A (ja) * 2009-09-14 2011-04-21 Mitsubishi Chemicals Corp プロピレンの製造方法
JP2011079818A (ja) * 2009-09-14 2011-04-21 Mitsubishi Chemicals Corp プロピレンの製造方法
JP2018145085A (ja) * 2017-03-03 2018-09-20 東ソー株式会社 ゼオライトおよびその製造方法
JP7119397B2 (ja) 2017-03-03 2022-08-17 東ソー株式会社 ゼオライトおよびその製造方法
JP2018153769A (ja) * 2017-03-21 2018-10-04 東ソー株式会社 金属含有ゼオライト
WO2024162258A1 (ja) * 2023-01-30 2024-08-08 旭化成株式会社 エタノールの変換方法、ゼオライト含有触媒、ゼオライト含有触媒の製造方法、及び炭化水素等の製造方法

Also Published As

Publication number Publication date
KR20100038469A (ko) 2010-04-14
JPWO2009031445A1 (ja) 2010-12-09
EP2184268A1 (en) 2010-05-12
MY156919A (en) 2016-04-15
US20100204532A1 (en) 2010-08-12
EP2184268A4 (en) 2012-01-25
CN101687726A (zh) 2010-03-31
CN105037067A (zh) 2015-11-11
TWI365865B (ja) 2012-06-11
US9079168B2 (en) 2015-07-14
JP5116043B2 (ja) 2013-01-09
TW200918487A (en) 2009-05-01
KR101169144B1 (ko) 2012-07-30

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