WO2004089049A1 - 多層基板およびその製造方法 - Google Patents
多層基板およびその製造方法 Download PDFInfo
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- WO2004089049A1 WO2004089049A1 PCT/JP2004/004277 JP2004004277W WO2004089049A1 WO 2004089049 A1 WO2004089049 A1 WO 2004089049A1 JP 2004004277 W JP2004004277 W JP 2004004277W WO 2004089049 A1 WO2004089049 A1 WO 2004089049A1
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- H—ELECTRICITY
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- H01L23/00—Details of semiconductor or other solid state devices
- H01L23/58—Structural electrical arrangements for semiconductor devices not otherwise provided for, e.g. in combination with batteries
- H01L23/64—Impedance arrangements
- H01L23/642—Capacitive arrangements
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- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/46—Manufacturing multilayer circuits
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- H05K1/00—Printed circuits
- H05K1/16—Printed circuits incorporating printed electric components, e.g. printed resistor, capacitor, inductor
- H05K1/162—Printed circuits incorporating printed electric components, e.g. printed resistor, capacitor, inductor incorporating printed capacitors
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- H05K1/00—Printed circuits
- H05K1/16—Printed circuits incorporating printed electric components, e.g. printed resistor, capacitor, inductor
- H05K1/165—Printed circuits incorporating printed electric components, e.g. printed resistor, capacitor, inductor incorporating printed inductors
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- H01L2224/02—Bonding areas; Manufacturing methods related thereto
- H01L2224/04—Structure, shape, material or disposition of the bonding areas prior to the connecting process
- H01L2224/05—Structure, shape, material or disposition of the bonding areas prior to the connecting process of an individual bonding area
- H01L2224/0554—External layer
- H01L2224/0556—Disposition
- H01L2224/05568—Disposition the whole external layer protruding from the surface
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- H01L2224/02—Bonding areas; Manufacturing methods related thereto
- H01L2224/04—Structure, shape, material or disposition of the bonding areas prior to the connecting process
- H01L2224/05—Structure, shape, material or disposition of the bonding areas prior to the connecting process of an individual bonding area
- H01L2224/0554—External layer
- H01L2224/05573—Single external layer
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- H01L2224/10—Bump connectors; Manufacturing methods related thereto
- H01L2224/15—Structure, shape, material or disposition of the bump connectors after the connecting process
- H01L2224/16—Structure, shape, material or disposition of the bump connectors after the connecting process of an individual bump connector
- H01L2224/161—Disposition
- H01L2224/16151—Disposition the bump connector connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive
- H01L2224/16221—Disposition the bump connector connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked
- H01L2224/16225—Disposition the bump connector connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being non-metallic, e.g. insulating substrate with or without metallisation
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- H01L2224/26—Layer connectors, e.g. plate connectors, solder or adhesive layers; Manufacturing methods related thereto
- H01L2224/31—Structure, shape, material or disposition of the layer connectors after the connecting process
- H01L2224/32—Structure, shape, material or disposition of the layer connectors after the connecting process of an individual layer connector
- H01L2224/321—Disposition
- H01L2224/32151—Disposition the layer connector connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive
- H01L2224/32221—Disposition the layer connector connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked
- H01L2224/32225—Disposition the layer connector connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being non-metallic, e.g. insulating substrate with or without metallisation
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- H01L2224/73—Means for bonding being of different types provided for in two or more of groups H01L2224/10, H01L2224/18, H01L2224/26, H01L2224/34, H01L2224/42, H01L2224/50, H01L2224/63, H01L2224/71
- H01L2224/732—Location after the connecting process
- H01L2224/73201—Location after the connecting process on the same surface
- H01L2224/73203—Bump and layer connectors
- H01L2224/73204—Bump and layer connectors the bump connector being embedded into the layer connector
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- H01L2924/15—Details of package parts other than the semiconductor or other solid state devices to be connected
- H01L2924/151—Die mounting substrate
- H01L2924/153—Connection portion
- H01L2924/1531—Connection portion the connection portion being formed only on the surface of the substrate opposite to the die mounting surface
- H01L2924/15311—Connection portion the connection portion being formed only on the surface of the substrate opposite to the die mounting surface being a ball array, e.g. BGA
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- H01L2924/00—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
- H01L2924/19—Details of hybrid assemblies other than the semiconductor or other solid state devices to be connected
- H01L2924/1901—Structure
- H01L2924/19015—Structure including thin film passive components
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- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2201/00—Indexing scheme relating to printed circuits covered by H05K1/00
- H05K2201/01—Dielectrics
- H05K2201/0183—Dielectric layers
- H05K2201/0187—Dielectric layers with regions of different dielectrics in the same layer, e.g. in a printed capacitor for locally changing the dielectric properties
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- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2201/00—Indexing scheme relating to printed circuits covered by H05K1/00
- H05K2201/09—Shape and layout
- H05K2201/09209—Shape and layout details of conductors
- H05K2201/09654—Shape and layout details of conductors covering at least two types of conductors provided for in H05K2201/09218 - H05K2201/095
- H05K2201/09672—Superposed layout, i.e. in different planes
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- H05K2203/00—Indexing scheme relating to apparatus or processes for manufacturing printed circuits covered by H05K3/00
- H05K2203/05—Patterning and lithography; Masks; Details of resist
- H05K2203/0502—Patterning and lithography
- H05K2203/0537—Transfer of pre-fabricated insulating pattern
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- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/46—Manufacturing multilayer circuits
- H05K3/4611—Manufacturing multilayer circuits by laminating two or more circuit boards
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- H—ELECTRICITY
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- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/46—Manufacturing multilayer circuits
- H05K3/4644—Manufacturing multilayer circuits by building the multilayer layer by layer, i.e. build-up multilayer circuits
- H05K3/4652—Adding a circuit layer by laminating a metal foil or a preformed metal foil pattern
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49002—Electrical device making
- Y10T29/49117—Conductor or circuit manufacturing
- Y10T29/49124—On flat or curved insulated base, e.g., printed circuit, etc.
- Y10T29/49126—Assembling bases
Definitions
- the present invention relates to a multilayer substrate, an electronic component using the same, and a method for manufacturing the same, and more particularly, to a structure and a method for manufacturing a multilayer substrate in which a functional element such as a capacitor or an inductor is built in an organic resin substrate.
- an organic multilayer substrate generally disperses a functional material such as a dielectric ceramic powder or a magnetic powder in a resin base material including a glass cloth, and disposes an electrode or a metal thin film formed on the resin base material. It is configured by arranging a coil or the like and laminating the base materials with an insulating layer interposed therebetween.
- a method of incorporating a thin film material into a substrate a method of directly forming a thin film on an organic substrate by sputtering or the like and laminating the thin film is also performed.
- a method using the thick film method for example, a method using a metal foil with resin is known.
- Japanese Patent Application Laid-Open No. 2002-271038 discloses a substrate structure of this type in which a functional element layer is provided inside the substrate.
- a ceramic dielectric film formed by a thin film method generally has poor crystallinity, and thus has a problem in that sufficient electrical characteristics inherent in the material cannot be obtained. Therefore, in order to form a thin film having excellent crystallinity and excellent electric characteristics, it is necessary to heat the substrate (to about 500 to 600 ° C. or higher). However, the heating limit is about 200 ° C for ordinary resin substrates, and at most about 400 ° C even if polyimide with excellent heat resistance is used. With a substrate structure in which a thin film is directly formed, it has been difficult to produce a ceramic dielectric thin film having good electrical characteristics in terms of heat resistance.
- the surface of an organic resin substrate generally has unevenness on the order of several / m and has poor smoothness.
- a thin film having a thickness of about several tens of nm is formed on the surface (the surface of the resin substrate has a film thickness).
- the surface of the resin substrate has a film thickness.
- the invention described in Japanese Patent Application Laid-Open No. 2002-2713038 discloses a composite having different material regions on the same layer in order to reduce the size and thickness of a multilayer substrate having a built-in functional element.
- a multilayer substrate is disclosed.
- this substrate is formed by laminating sheets of different materials to form a block, and then slicing the block in a direction perpendicular to the direction of spread of each sheet to form a composite material layer.
- the layers need to be stacked. For this reason, the manufacturing process becomes complicated, and an adhesive layer must be interposed between each material region. Therefore, it cannot be said that the structure is still sufficient in terms of mounting density.
- both the functional material films are formed of an organic material (judgment)
- the bonding strength at the contact portion between the two material films is weak, and a gap is generated between the two film materials.
- the reliability of the substrate may be reduced. Disclosure of the invention
- an object of the present invention is to provide a highly reliable organic multilayer substrate capable of incorporating therein a functional element having excellent electrical characteristics at a high density and a method of manufacturing the same.
- a multilayer substrate is a multilayer substrate including a plurality of base materials laminated and including a plurality of types of functional elements inside the substrate. At least one of the base materials includes a plurality of types of functional material films including at least a functional material film and a second functional material film formed of a second functional material different from the first functional material film. A plurality of functional elements are formed on the same surface of one base material and the plurality of types of functional material films are formed.
- a method for manufacturing a multilayer substrate according to the present invention is a method for manufacturing a multilayer substrate including a plurality of types of functional elements inside a substrate, comprising: a first functional film; and a second functional film different from the first functional film. And disposing a plurality of types of functional films including at least a functional film on the same surface of the substrate.
- the mounting density of the substrate can be increased. Specifically, for example, a material having a low dielectric constant and a material having a high dielectric constant are disposed on the same surface of the core substrate, and an inductor is provided in a region where the low dielectric constant material is disposed, while a high dielectric constant material is disposed. A capacitor is formed in the arranged area.
- a dielectric material and a magnetic material, or arbitrary materials such as a piezoelectric material, a pyroelectric material, and a semiconductor material are appropriately arranged on the same surface of the substrate, and a desired functional element is built in the multilayer substrate.
- a desired functional element is built in the multilayer substrate.
- the functional element for example, a capacitor / inductor, a resistor, a varistor and other elements can be formed.
- Specific methods for disposing a functional material film on a substrate include a thin film method (for example, sputtering, vapor deposition, CVD, laser ablation, baking of a sol-gel forming film), and a thick film method (for example, a printing method, a doctor method). Forming a thick film of functional material by the blade method and transferring it) It is possible to apply both. According to the thin film method, a high-performance functional element having excellent electrical characteristics can be formed in a substrate. On the other hand, according to the thick film method that does not use a vacuum technique, the multilayer substrate according to the present invention can be manufactured with simple steps and at low cost.
- a thin film method for example, sputtering, vapor deposition, CVD, laser ablation, baking of a sol-gel forming film
- a thick film method for example, a printing method, a doctor method.
- the multilayer substrate according to the present invention is a multilayer substrate having at least one capacitor element layer inside the substrate, wherein the capacitor element layer is formed by a thin film method and has improved crystallinity by heat treatment. It is formed of a body ceramic layer and electrode films disposed on both sides of the dielectric ceramic layer, and is held by a substrate mainly composed of resin.
- the dielectric ceramic layer formed by the thin film method is heat-treated to increase the crystallinity, and the dielectric constant is improved.
- Form a substrate This makes it possible to form a high-permittivity ceramic layer in the substrate and to incorporate a high-capacity capacitor in the organic multilayer resin substrate.
- a dielectric ceramic layer is formed on a transfer substrate having heat resistance, as in a manufacturing method described later, and after heat-treating the organic resin, Transfer to the substrate.
- FIG. 1 is a horizontal cross-sectional view showing a multilayer substrate (a layer on which a heterogeneous material film is formed) according to the first embodiment of the present invention.
- FIG. 2 is a vertical sectional view showing the multilayer substrate according to the first embodiment.
- 3 (a) to 3 (o) are cross-sectional views sequentially showing the steps of manufacturing the multilayer substrate according to the first embodiment.
- FIG. 4 is a vertical sectional view showing a multilayer substrate according to the second embodiment of the present invention.
- FIG. 5 is an exploded vertical sectional view showing the multilayer substrate according to the second embodiment.
- 6 (a) to 6 (o) are cross-sectional views sequentially showing the steps of manufacturing the multilayer substrate according to the second embodiment.
- FIG. 7 shows a multilayer substrate (forming layer of a heterogeneous material film) according to the third embodiment of the present invention. It is a horizontal sectional view shown.
- FIG. 8 is a vertical sectional view showing the multilayer substrate according to the third embodiment.
- FIG. 9 is a horizontal cross-sectional view showing a multilayer substrate (layer of a different material film) according to the fourth embodiment of the present invention.
- FIG. 10 is a vertical sectional view showing the multilayer substrate according to the fourth embodiment.
- FIG. 11 is a horizontal sectional view showing a multilayer substrate (a first layer on which a heterogeneous material film is formed) according to the fifth embodiment of the present invention.
- FIG. 12 is a horizontal sectional view showing a multilayer substrate (a second layer on which a dissimilar material film is formed) according to the fifth embodiment.
- FIG. 13 is a vertical sectional view showing the multilayer substrate according to the fifth embodiment.
- FIGS. 14 (a) and (b) are cross-sectional views showing layers in which a heterogeneous material film is formed according to the present invention.
- FIGS. 15 (a) and 15 (b) are cross-sectional views showing the different material film forming layers when the different material films are formed in the same layer on the ceramic fired substrate.
- 15 (a) shows the state before firing
- 15 (b) shows the state after firing.
- FIGS. 16 (a) to 16 (k) are cross-sectional views sequentially showing the manufacturing steps in the method for manufacturing a multilayer substrate according to the sixth embodiment of the present invention.
- FIG. 17 is a cross-sectional view illustrating an example of the multilayer substrate according to the present invention.
- FIGS. 18 (a) to 18 (n) are cross-sectional views sequentially showing the steps of manufacturing a multilayer substrate according to one embodiment of the present invention.
- FIG. 19 (a) is a plan view showing one configuration example of the dielectric ceramic layer according to the present invention
- FIG. 19 (b) is a cross-sectional view.
- FIG. 20 (a) is a plan view showing another configuration example of the dielectric ceramic layer according to the present invention
- FIG. 20 (b) is a cross-sectional view.
- FIG. 21 is an X-ray diffraction chart of the BaTi03 thin film formed by sputtering immediately after sputtering (without heat treatment).
- FIG. 22 shows the Ba T i 03 thin film formed by sputtering and heat-treated at 300 ° C.
- FIG. 6 is an X-ray diffraction chart in the case.
- FIG. 23 is an X-ray diffraction chart when the BaTi03 thin film formed by sputtering is heat-treated at 500 ° C.
- FIG. 24 is an X-ray diffraction chart when the BaTi03 thin film formed by sputtering is heat-treated at 700 ° C.
- FIG. 25 is an X-ray diffraction chart of the BaTi03 sintered body. BEST MODE FOR CARRYING OUT THE INVENTION
- FIG. 1 and FIG. 2 show a multilayer substrate according to a first embodiment of the present invention.
- this multilayer substrate has thin films 11 and 12 made of different materials formed on the same plane inside the substrate, and different types of functional elements and high-capacitance capacitors 1 are formed by these thin films.
- 3 and inductor 14 are provided on the same layer in the substrate.
- a high dielectric material thin film 11 is formed of a material having a high dielectric constant as a first functional material film
- a low dielectric material film is formed of a material having a low dielectric constant as a second functional material film.
- a dielectric material thin film 12 was formed. Then, the conductors 15 and 15a patterned in a rectangular shape are provided on both surfaces of the high dielectric material thin film 11 to form a high capacity capacitor 13 (first functional element), while the low dielectric material is formed.
- Inductors 14 (second functional elements) were formed by providing conductors 17 and 17a patterned in a spiral shape on both surfaces of the thin film 12.
- Each of the high and low dielectric material films 11 and 12 is a thin film formed by using a thin film method such as sputtering, vapor deposition, CVD, laser ablation, or baking of a sol-gel forming film, and has a thickness of 5 m or less.
- a thin film method such as sputtering, vapor deposition, CVD, laser ablation, or baking of a sol-gel forming film
- the dielectric constant is about 1 to 50
- the dielectric loss tangent (tan S) is about 0.002 to 0.02.
- a dielectric constant of 3 to about L0000 and a ta ⁇ value of about 0.001 to 0.1 can be obtained.
- Specific materials that can be used to form the dielectric material thin films 11 and 12 include, for example, Barium titanate-based ceramics, titanium-barium-neodymium-based ceramics, titanium-barium-based tin-based ceramics, 10-canoresium-based ceramics, titanium dioxide ceramics, lead titanate-based ceramics, strontium titanate-based ceramics, calcium titanate-based ceramics, bismuth titanate-based ceramics, magnesium titanate-based ceramics, C a W_ ⁇ 4 ceramic, B a (Mg, Nb) 0 3 based ceramic, B a (Mg, T a ) 0 3 based ceramic, B a (C o , Mg, Nb) 0 3 based ceramic, B a (C o, Mg , T a) 0 3 based ceramic, and the like.
- the functional material film formed on the same plane may be a dielectric material film or a magnetic material (for example, Fe-Ni-Zn-based ceramics, Mn_Zn-based ferrite, Ni- -Zeta eta ferrite, Mn-Mg -Z n ferrite, B a system ferrite, S r ferrite, n i- C u- Z n ferrite, F e 2 0 3 or F e 3 0 4, etc. acid iron, F e or F e various magnetic alloys containing etc.)
- Ya piezoelectric material e.g. P b T I_ ⁇ 3-P b Z r 0 3, etc.
- pyroelectric e.g.
- a through-hole or a via hole (not shown) can be appropriately formed in order to make electrical connection between the layers provided with these elements and the like.
- Surface mounting components such as IC 1 and various chip components 2 can be mounted on the surface of the substrate, whereby a desired electronic component module can be formed.
- Various electronic components such as modules, isolators, DC-DC converters, and tuner units can be configured by the present invention.
- a transfer substrate 21 is prepared (FIG. 3 (a)), and a metal film 22 serving as a capacitor electrode conductor is formed on the surface of the transfer substrate 21 by a thin film method (FIG. 3). (b)).
- a SUS (stainless steel) substrate having a thickness of 0.1 mm is used, and a copper (Cu) and nickel (N i) film are formed on the surface of the substrate by sputtering in the order of 0.1 ⁇ .
- the metal film 22 is formed by stacking the layers so as to be thick.
- the transfer substrate 21 in addition to a SUS substrate, for example, a substrate made of silicon-alumina, zirconia, quartz, sapphire, magnesium oxide, zirconium oxide, or the like can be used, and an inorganic material having a heat resistance of 500 ° C or more can be used. It is desirable to use a substrate made of a base material.
- the metal film 22 in addition to copper and nickel, for example, titanium (Ti), gold (Au), silver (Ag), platinum (Pt), palladium (Pd), tungsten (W), Molybdenum (Mo) or an alloy containing at least one of these materials can be used, and various conductive materials having conductivity can be used.
- a method for forming the metal film 22 in addition to sputtering, it is possible to use evaporation, CVD, laser ablation, baking of a sol-gel film, plating, and other methods as described above.
- a dry method such as sputtering, vapor deposition, or CVD, which can form a smoother metal film. According to these dry film forming methods, unevenness such as an electrolytic metal foil does not occur. Particularly when forming a counter electrode of a capacitor, local electric field concentration is prevented from occurring, and the reliability of the substrate is improved. Can be done.
- a high dielectric material thin film 11 is formed as a first functional material film in a region on the metal film 22 where a capacitor is to be formed (FIG. 3 (c)).
- This thin film of high dielectric material 11 is formed by arranging a mask that covers the surface of the metal film other than the capacitor forming region and using a thin film method such as a sputtering method.
- a barium titanate thin film having a thickness of 0.3 / zm is formed on the metal film 22 by RF sputtering under a heating condition of 600 ° C., and the high dielectric material thin film 11 can be obtained.
- the thin film 11 can be subjected to a heat treatment to improve the crystallinity.
- the temperature of the heat treatment is preferably 400 ° C. or higher (for example, 500 ° C. to 900 ° C.), whereby a dielectric layer having a stable crystal structure and excellent dielectric properties can be formed.
- the crystal form is desirably a single crystal structure that can provide better dielectric properties, but may be a polycrystalline structure.
- the functional material film in the present invention is not necessarily limited to a film having a crystalline structure, and includes a film in an amorphous state.
- a low dielectric material thin film 12 is formed as a second functional material film in a region on the metal film 22 where an inductor is to be formed (FIG. 3D).
- the low dielectric material thin film 12 is formed by arranging a mask covering the surface of the metal film other than the area where the inductor is to be formed, and using a thin film method such as a sputtering method. For example, it is possible to form on the metal film 22 with a thin film of 0. 3 xm thickness of 600 ° C A 1 2 0 3 by sputtering under the heating conditions of the (alumina), a low dielectric material film 12 .
- the low dielectric material film 12 prior to the formation of the low dielectric material film, order to secure insulation, for example it is deposited on the metal film 12 with a thickness of 0.5 by sputtering S I_ ⁇ 2, low dielectric thereon
- the body material thin film 12 may be formed.
- the metal film 22 a for forming the electrodes and Ingukuta capacitor is formed by a thin film method such as sputtering (FIG. 3 (e)).
- the metal film 22a is patterned by etching (FIG. 3 ( ⁇ )) to form a rectangular pattern serving as a capacitor electrode and a spiral pattern serving as an inductor. It should be noted that both wet etching and dry etching can be applied to the puttering.
- the transfer substrate 21 is inverted, and the pre-predator (organic resin substrate in the stage state) 23 is pressed and heated while being pressed to transfer (FIG. 3 (g)). )), After the pre-predator 23 is cured, the transfer substrate 21 is peeled off (FIG. 3 (h)).
- the pre-predator 23 is pressed and heated while being pressed to transfer (FIG. 3 (g)).
- the transfer substrate 21 is peeled off (FIG. 3 (h)).
- a pre-preda it is also possible to transfer by pressing against a cured resin substrate via another adhesive film.
- the organic resin substrate (predder) to be transferred preferably has low water absorption in order to enhance the reliability of the substrate.
- thermoplastic resins and thermosetting resins can be used, such as epoxy resins, phenolic resins, vinyl benzyl ether compounds, bismaleimidoidiazine resins, polyolefin resins, polyimides, polyesters, and polyphenylene oxides.
- epoxy resins such as epoxy resins, phenolic resins, vinyl benzyl ether compounds, bismaleimidoidiazine resins, polyolefin resins, polyimides, polyesters, and polyphenylene oxides.
- Polyphenylene sulfide, liquid crystal polymer, fluororesin, etc., and those containing one or more of these can be used.
- metal foils 24, 25 with resin are pressed and attached to both surfaces of the substrate (FIG. 3 (j)).
- the surface copper foil 24a is etched to form a hole for laser via formation (Fig. 3 (k)), and a laser beam is applied to this to form a hole in the resin portion 24b of the metal foil 24 with resin.
- the metal film 27 is provided is subjected to electroless plated and electrolytic plated to form a via hole 28 (FIG. 3 (m)) 0
- steps (8) to (10) (FIG. 3 (j) to FIG. 3 (.)) Generally known as a build-up method are repeated, whereby the present embodiment shown in FIG. A multilayer substrate can be formed.
- the other substrate to be laminated in the laminating step may have a single film material on the same surface as shown in FIG.
- a plurality of substrates provided with the dissimilar material films may be laminated on the same surface formed in the step of).
- the functional film formed on the same surface for example, a material having a low dielectric constant and a material having a high dielectric constant are arranged to form an inductor and a capacitor on the same surface, or a piezoelectric material (for example, PbT i 0 3 - PZ r 0 3, etc.) or a pyroelectric material (e.g.
- FIGS. 4 and 5 show a multilayer substrate according to a second embodiment of the present invention.
- this multilayer board is provided on one side with a core board 31 provided with dissimilar material films 11 and 12 on one side and a conductor pattern 32 for bare chip mounting on the other side.
- This is a four-layer multilayer board that is integrated with another board 35 having a line pattern 36 and a ground pattern 37 and a land pattern 38 on the other side with a pre-predator 39 interposed therebetween.
- the bare chip 7 can be flip-chip mounted.
- the core substrate 31 having a different material film has a high dielectric material thin film 11 (first functional material film) and a low dielectric material thin film 12 (second functional material) on one surface (lower surface). These thin films 11 and 12 form a high-capacity capacitor 13 in the high-dielectric material thin film portion, and a low-capacitance capacitor 4 3 and inductor 1 in the low-dielectric material thin film portion. Form 4.
- the thinner dielectric is used for the low-capacitance (low-permittivity) capacitor 43, considering thinning as the highest priority.
- a conductor pattern 32 for bare mounting with a narrow pitch is formed on the other surface (upper surface) of the core substrate 31, a conductor pattern 32 for bare mounting with a narrow pitch is formed.
- a transfer substrate 21 is prepared (FIG. 6 (a)), and the transfer substrate 21 is prepared.
- a metal film 22 serving as a capacitor electrode or an inductor conductor is formed on the surface by a thin film method (FIG. 6 (b)).
- the transfer substrate 21 for example, a stainless steel substrate having good heat resistance is used, and a film of copper (Cu) and a film of titanium (Ti) are formed in this order on the surface of the substrate by sputtering.
- various other materials can be used as in the first embodiment. .
- a high dielectric material thin film 11 is formed on the film in a region where a high-capacitance capacitor is to be formed (FIG. 6C).
- This film formation is performed by covering the surface of the metal film other than the high-capacitance capacitor formation region with a mask and using a thin film method such as sputtering. After film formation, heat treatment may be performed to improve the crystallinity of the thin film 11.
- the low dielectric material thin film 12 is formed on the metal film 22 in a region where the inductor and the low capacitance capacitor are to be formed (FIG. 6D).
- This film formation is performed by a thin film method such as sputtering by covering the surface of the metal film other than the inductor / low-capacitance capacitor formation region with a mask, similarly to the formation of the thin film 11.
- a metal film 22a is formed on these thin films 11 and 12 by a thin film method such as sputtering (FIG. 6 (e)).
- the metal film 22a is formed by laminating 1 111 and 11 in this order.
- the metal film 22a is patterned by etching (FIG. 6 (f)) to form a capacitor electrode and an inductor.
- a transfer substrate 21a is separately prepared (FIG. 6 (g)).
- a metal film 32 is formed on the surface of the transfer substrate by a thin film method (FIG. 6 (h)).
- the transfer substrate 21a for example, a stainless steel substrate having good heat resistance is used, and Cu and Ti films are formed in this order on the substrate surface 21a by a thin film method such as sputtering.
- a conductor pattern 32 for P mounting is formed.
- the transfer for forming the conductor pattern 32 for mounting the bare chip is performed.
- the substrate 21 a and the transfer substrate 21 (FIG. 6 (f)) formed by patterning the metal film 22a are arranged so that the pattern forming surfaces face each other, and these transfer substrates 21 1 and 21
- the pre-predator 40 is interposed between a and a (FIG. 6 ( ⁇ )), and the substrates 21 and 2 la are heated and pressed against the upper and lower surfaces of the pre-predder 40 (FIG. 6 (k)).
- a resist 55 is applied to the conductor forming surface for bare chip mounting to protect the fine pattern 32 (Fig. 6 (m)). Patterning is performed on the first formed metal film 22 (FIG. 6B) covering the surfaces of,. More specifically, the counter electrode and the inductor of the capacitor are formed in alignment with the capacitor electrode and the inductor (conductor 22a) formed by the patterning (FIG. 6 (f)), respectively (FIG. n)).
- the substrates are laminated using the substrate 31 as a core substrate. That is, the other board 35 having the wiring pattern 36, the ground pattern 37, and the land pattern 38 on each of the front and back surfaces is separately prepared (see FIG. 5), and the board 35 is completed.
- the above-mentioned core substrate 31 is integrated with a pre-predator 39 interposed therebetween. Further, a bare chip 7 is flip-chip mounted on the fine pattern conductor 32 on the surface of the core substrate 31.
- the transfer method using the transfer method, patterning at a very narrow pitch is possible. This is because the transfer method allows a full additive method to be applied by making the transfer substrate conductive (for example, using a stainless steel substrate). Therefore, it is not necessary to use electroless plating or soft etching, and very fine and highly accurate patterning can be performed.
- the board Ji putter jung is required. This is because large-scale bare chips have a large number of terminals and those terminals are arranged at a narrow pitch. According to the multilayer substrate according to the present embodiment having the fine conductor pattern, it is possible to mount such a large-scale bare chip.
- FIG. 7 and 8 show a multilayer substrate according to a third embodiment of the present invention.
- two kinds of different material films high-dielectric material thin film and low-dielectric material thin film
- a magnetic material thin film and a magnetic material thin film 6 1 third functional material film
- a conductor 15 patterned in a rectangular shape and a conductor 17 patterned in a spiral shape are arranged adjacent to the high dielectric material thin film 11 and the low dielectric material thin film 12, Similarly to the above embodiment, a high-capacity capacitor 13 (first functional element) and an inductor 14 (second functional element) are formed. Further, in this embodiment, a conductor 17 patterned in a spiral shape is disposed on both surfaces of the magnetic material thin film 61 to form an impedance 65 (third functional element), and both surfaces of the semiconductor thin film 62 are formed.
- a varistor 66 (fourth functional element) was formed by disposing a conductor 15 patterned in a rectangular shape.
- Examples of the material for forming the magnetic material thin film 61 include the above-mentioned Fe-Ni-Zn-based ceramics, Mn-Zn-based ferrite, Ni- ⁇ -based ferrite, and Mn-Mg-Zn system ferrite, B a ferrite, S r ferrite, n i- C u- Z n based ferrite, F e 2 ⁇ 3 and F e 3 ⁇ 4 etc. Sani ⁇ , the F e or F e, It is possible to use various magnetic alloys and the like. Further, as a material for forming the semiconductor thin film 6 2, eg if B a T i 0 3 or the like can be used.
- the ground electrode 3, the wiring 4, the capacitor 5, and other functional elements can be formed on layers other than the layer on which the heterogeneous functional material film is arranged.
- Various surface mount components 1 and 2 can be mounted in the same manner as in the first embodiment. Further, the specific manufacturing method (step) of the multilayer substrate according to the present embodiment and the fourth and fifth embodiments described later is the same as the multilayer substrate according to the first embodiment. Description is omitted.
- FIG. 9 and FIG. 10 show a multilayer substrate according to a fourth embodiment of the present invention.
- this multilayer substrate has a plurality of layers in which different material films are arranged on the same surface.
- the layer in which the dissimilar material film is disposed is one layer.
- the dissimilar material film forming layer may be two layers, or three or more layers are provided. It is also possible.
- Each of the different material film forming layers is made of a high dielectric material thin film as in the third embodiment.
- FIGS. 9 and 10 and FIGS. 11 to 13 the same or corresponding parts as those in the above-described embodiments (FIGS. 1 to 8) are denoted by the same reference numerals, and redundant description is omitted. I do.
- FIGS. 11 to 13 show a multilayer substrate according to a fifth embodiment of the present invention.
- this multilayer substrate is provided with two layers in which different kinds of material films are arranged, as in the fourth embodiment.
- the first of these layers (FIG. 1)
- each functional material film is formed by the thin film method, and for the second layer (Fig. 12), the thick film method is used.
- the second layer Fig. 12
- the thick film method is used.
- the first layer is provided with a high-dielectric thin film 11 and a semiconductor thin film 62, and a conductor patterned in a rectangular shape on both surfaces of the thin films 11 and 62.
- the plurality of high-capacitance capacitors 13 and the plurality of varistors 66 are respectively formed by disposing 15.
- the second layer is provided with a thick film made of a resistor material and a thick film 71 of a resistor material, and a thick film made of a magnetic material and a thick film 61a of a magnetic material.
- a conductor 15 patterned in a rectangular shape for a resistor and a conductor 17 patterned in a spiral shape for an impedance are arranged for resistance. 7 2 and the impeder 65 are formed respectively.
- a transfer method using a conventionally known PET film can be used. Specifically, a magnetic material powder or a resistor powder is mixed with a resin material to form a composite material, and the composite material is applied on a silicon-treated PET film by a doctor blade method. Then, the film is attached to a resin substrate, heated and pressed for a predetermined time, and then the film is peeled off to perform transfer. In the transfer, the thick film can be transferred and formed in a desired region by masking the resin base material.
- the multilayer substrate according to the present embodiment described above by disposing a plurality of different functional material films on the same layer surface in the substrate, it is possible to incorporate a desired functional element in the substrate at high density. Become.
- functional materials having excellent crystallinity and excellent electrical properties such as dielectric materials, magnetic materials, piezoelectric materials, and pyroelectric materials, can be formed on an organic substrate, and it is difficult to realize in a conventional organic substrate.
- the electrical characteristics can be realized in the multilayer substrate.
- different types of material films can be formed on the same plane in combination with a thick film method that can be easily thinned at low cost, the manufacturing cost of a multilayer substrate can be reduced. You.
- a crack 94 is formed at the boundary portion 94 between the different material films 91 and 92 as shown in FIG. Since 96 does not occur, there is no risk of impairing the reliability of the substrate.
- the plurality of types of functional material films may be formed of an inorganic material.
- the thickness of the film it is preferable that the thickness of the film be 5 ⁇ or less.
- the film thickness is desirably 5 ⁇ or less in order to form a high-capacity capacitor.
- the thickness of the film is preferably not less than 0. This is for ensuring the withstand voltage of the thin film.
- the plurality of types of functional material films may be thin films formed on a transfer substrate by a thin film method and then transferred to the base material.
- the film can be formed once on a transfer substrate that can withstand a high-temperature heat treatment, and this can be heat-treated to improve the crystallinity. It is also possible to form a functional material film having excellent electrical characteristics on an organic resin substrate and a functional element using the film.
- At least one of the plurality of types of functional material films is heat-treated to have crystallinity.
- the heat treatment temperature is, for example, 500 ° C. to 900 ° C.
- the heat treatment temperature is, for example, 500 ° C. to 900 ° C.
- the plurality of types of functional material films are formed of, for example, a dielectric material, a magnetic material, a piezoelectric material, a pyroelectric material, and a semiconductor material.
- the plurality of types of functional material films are formed of a composite material in which a functional powder is mixed and dispersed in a resin.
- Such a functional powder is, for example, any one of a dielectric material, a magnetic material, a piezoelectric material, a pyroelectric material, and a semiconductor material.
- the base material on which a plurality of types of functional material films are arranged is a base material mainly composed of resin.
- substrate mainly composed of resin refers to various inorganic materials (for example, dielectric materials, magnetic materials, piezoelectric materials, pyroelectric materials, semiconductor materials, etc.) in addition to substrates composed of only resin materials.
- at least one substrate provided with the plurality of types of functional elements is laminated and integrated with another substrate with a bonding material (including a pre-preda and an adhesive sheet) interposed therebetween. In some cases. .
- an electronic component according to the present invention is obtained by mounting a surface mount component on at least one surface of any one of the multilayer substrates.
- FIGS. 16 (a) to 16 (k) show a method for manufacturing a multilayer substrate according to the second embodiment of the present invention.
- a heterogeneous material film (a magnetic film and a dielectric film) is provided on the same layer inside the multilayer substrate by using a thick film method, and thereby, a heterogeneous functional element (an in-beader and a capacitor) is formed. They are formed in the same plane.
- a transfer substrate 15 1 is prepared (FIG. 16 (a)), and a dry film 152 is adhered to the surface of the transfer substrate 51 (FIG. 16 (b)).
- the film 152 is patterned by lithography using a mask to form a resist pattern 153 (see FIG. 16 (c)).
- a 0.1 mm thick SUS 304 tension annealed material whose surface has been passivated is cut into a size of 10 Omm in length and 100 mm in width to prepare a transfer substrate 51 and a thickness of 29 m
- the spiral pattern (line and space was set to 30 / zm 30 ⁇ ) for the invida, and the conte, over the entire area of 90 mm in length and 90 mm in width of the film 152.
- a plurality of rectangular patterns (each rectangular pattern is 4.5 mm long and 3.2 mm wide) for a sensor electrode are formed as a resist pattern 153.
- the surface of the transfer substrate 151 on which the resist pattern 153 is formed is subjected to, for example, bright copper sulfate plating to form a metal conductor 155 (FIG. 16D).
- the composition of the plating solution for the copper sulfate plating may be, for example, 200 gZl of copper sulfate pentahydrate and 100 gZl of sulfuric acid.
- the resist 153 is removed (FIG. 16E).
- the resist 153 is removed by heating a 5% solution of sodium hydroxide to 50 ° C. and spraying the surface of the transfer substrate 151 on the pattern forming side at a pressure of 1.5 kgZc in 2. It is possible.
- the surface of the conductor is blackened with, for example, a mixed solution of sodium hypochlorite and sodium hydroxide, and the substrate 151 is dried at 100 ° C. for 30 minutes in a convection oven.
- the transfer substrate 151 is turned over, and this is vacuum-pressed onto the pre-predator 156 to perform transfer (FIG. 16). After that, the transfer substrate 151 is peeled off, and the conductor is patterned.
- the core substrate 157 is formed (FIG. 16 (g)). It should be noted that at least another core substrate 157 on which the conductor is patterned is prepared for use in a bonding step (FIG. 16 (j)) described later.
- the resin substrate (core substrate) 156 of the transfer destination it is possible to use various materials similar to those described in the first embodiment. — As an example, a pre-preda containing a cloth having a thickness of 100 m can be used as the resin substrate 156.
- a composite material in which various functional powders are mixed and dispersed with a resin material as a functional material is prepared.
- a magnetic material powder for example, Fe—Ni-Z11-based ceramics
- the composite material is applied to the PET film by the doctor blade method so that the thickness becomes, for example, 10 m.
- a dielectric composite material is formed by mixing a dielectric powder (for example, Ba—Ti—Nd-based ceramics) with the resin material, for example, by 40% (by volume).
- This composite material is applied on a PET film by a doctor blade method so that the thickness becomes, for example, 10 / xm.
- it is desirable that such PET film is previously subjected to a silicon treatment in order to enhance the releasability in the following transfer step (FIGS. 16 (1!) To 16 (i)).
- the resin material It is preferable that the resin used for the core substrate is mainly used.
- the dielectric powder for forming the dielectric composite material it is possible to use the power of Ba—Ti—Nd-based ceramics and the various ceramic materials described in the first embodiment.
- the magnetic powder for forming the magnetic composite material include, in addition to Fe—Ni- ⁇ ⁇ ⁇ -based ceramics, ⁇ — ⁇ -based ferrites ⁇ N i— i ⁇ -based ferrites, N i— Z n ferrite, Mn- Mg- Z n ferrite, B a system off Eraito, S r ferrite, n i-Cu- Zn ferrite or F e 2 0 3 or F e 3 0 4 iron oxide, such as, , Fe, and various magnetic alloys including Fe can be used.
- the magnetic film 161 can be transferred as the first functional film to the first region on the surface of the core substrate where the magnetic layer is to be formed (FIG. 16 (h)).
- the dielectric film 162 can be transferred as the second functional film to the second region on the surface of the core substrate where the dielectric layer is to be formed (FIG. 16 (i)).
- the order of transfer of the magnetic film 161 and the dielectric film 162 may be reversed.
- the material of the functional film formed on Koa substrate other dielectric materials Ya magnetics material previously described, the piezoelectric material (e.g. P b T i 0 3 -P b Z r 0 3 or the like resin mixed and dispersed composite material) or pyroelectric material to material (e.g., PBT i 0 3 or the like mixed dispersed composite resin material), a semiconductor material (e.g., B a T i 0 3 or the like is mixed into a resin material (Dispersed composite material)
- Other materials can also be used, and various functional films can be formed with these materials.
- three or more types of materials (functional films) can be formed in different areas in the same plane.
- the magnetic film 161 and the dielectric film 162 perform the function of a pre-predator, and the two substrates 157, 157a are bonded.
- the substrates 157 and 157a are overlapped, the magnetic film 161 and the dielectric film 162 are sandwiched between the conductor forming surfaces of the substrates 157 and 157a. Positioning is performed so that a counter electrode of the capacitor can be formed by the metal conductors 15 5 and 15 55 a disposed on the portion where the dielectric film 16 2 is formed.
- a plurality of substrates 158 bonded in this manner are prepared, and these are laminated with a pre-predeer 166 (or an adhesive sheet) interposed therebetween and pressed to form a multilayer substrate (FIG. 1). 6 (k)).
- the substrate to be laminated at this time is not limited to the substrate 158 according to the present embodiment having different (multiple types) functional films, but may be a substrate 159 having a single type functional film 165. Any number of these substrates may be appropriately combined to form various multilayer substrates.
- the thick film method is used in the second embodiment, and the thin film method is used in the first embodiment.
- the film formation is performed by combining the thick film method and the thin film method. It is also possible to do.
- the first functional film formed on the same surface can be formed by a thin film method, and the second functional film can be formed by a thick film method.
- a pre-preda or an adhesive sheet may be interposed in the thin film portion.
- a plurality of different functional material films are arranged on the same surface in the substrate, and a desired functional element having excellent electrical characteristics can be embedded in the substrate at a high density. I can do it.
- an inorganic thin film material that originally requires film formation at a high temperature 500 to 900 C
- each substrate constituent material can be pressed at a time (see FIG. 1). 6 (j), Fig. 16 (k)), it is possible to manufacture a laminated substrate with a small number of steps and low cost.
- the manufacturing method of the present invention comprises: The method includes a step of disposing the functional films on a transfer substrate and a step of transferring the plurality of types of functional films to a core substrate.
- the transfer method in this way, it is possible to form a film once on a transfer substrate having excellent heat resistance and transfer it to the core substrate, so that it can be applied to an organic resin substrate that does not have sufficient heat resistance.
- the process of masking the transfer substrate and disposing the functional films on the transfer substrate is performed by repeating the process for each of the multiple types of functional films. Can be done. In the present invention, these plural types of functional films can be simultaneously arranged on the transfer substrate.
- the transferring step includes a step of pressing the surface of the transfer substrate on which the functional film is disposed, while heating and pressing the prepreg, to cure the prepreg, and peeling the transfer substrate. And a step.
- a step of disposing a metal film prior to the step of disposing the plurality of types of functional films and a step of disposing a metal film after the step of disposing the plurality of types of functional films are performed.
- a step of disposing a metal film prior to the step of disposing the plurality of types of functional films and a step of disposing a metal film after the step of disposing the plurality of types of functional films are performed.
- the plurality of types of functional films are formed of a composite material in which various functional powders are mixed and dispersed in a resin material, the functional films are arranged on a support film, and the functional films are transferred to a core substrate. I do.
- a metal film may be provided on the core substrate.
- a process of masking the core substrate and disposing the functional film on the core substrate may be repeated for each of a plurality of types of functional films.
- a plurality of types of functional films can be simultaneously disposed on the core substrate.
- the functional film may be any one of a dielectric film, a magnetic film, a piezoelectric film, a pyroelectric film, and a semiconductor film.
- the method for manufacturing a multilayer substrate according to the present invention at least one core substrate provided with the plurality of types of functional films is laminated and integrated with another core substrate with a bonding material (including a pre-preda) interposed therebetween.
- a bonding material including a pre-preda
- the multilayer substrate according to the present embodiment has a dielectric ceramic thin film 211 formed by a thin film method inside the substrate, and electrode films 211 on both surfaces of the dielectric thin film 211. , 213 are arranged to form a capacitor, which is held by substrate materials (organic insulating materials) 215, 216 mainly composed of resin.
- a dielectric thin film is formed on a transfer substrate having heat resistance, and this is heat-treated to improve its crystallinity. This is performed by transferring a dielectric thin film to a resin substrate. This step will be described in more detail with reference to FIGS. 18 (a) to 18 (n).
- a transfer substrate 31 is prepared (FIG. 18 (a)), and a metal film 212 serving as an electrode is formed on the surface of the transfer substrate 231 by a thin film method such as sputtering (FIG. 18 (a)).
- a thin film method such as sputtering
- the transfer substrate 23 any substrate made of an inorganic base material having heat resistance of 500 ° C. or more can be used.
- substrates of silicon, SUS (stainless), alumina, zirconium, quartz, sapphire, magnesium oxide, zirconium oxide, etc. can be used.
- the metal electrode film if it is a conductive material having conductivity, for example, copper (Cu), titanium (T i), nickel (N i), gold (Au), silver (A g), platinum (P t) , No ,. Radium (Pd), tungsten (W), molybdenum (Mo), and other alloys containing at least one of them can be used, regardless of the type.
- the electrode film to be formed has a two-layer structure, and a Pt film 212 a having excellent heat resistance and reduction resistance during heat treatment is first formed on the surface of the transfer substrate 231. Then, a Ti film 211b having high adhesion to the dielectric ceramic layer is formed thereon.
- the method for forming the electrode film other than the above-mentioned sputtering, it is possible to use vapor deposition, CVD, laser ablation, baking of a sol-gel forming film, plating, and other methods.
- a dry method such as sputtering, vapor deposition, or CVD, which can form a smoother metal film. According to these dry film forming methods, unevenness unlike an electrolytic metal foil does not occur, so that when used as a counter electrode of a capacitor, local electric field concentration can be prevented.
- a dielectric ceramic layer 211 is formed on the electrode film 211 by a thin-film method such as sputter deposition, CVD, laser ablation, or firing of a sol-gel forming film (FIG. 18 (d) )).
- a material for forming the dielectric ceramic layer 211 for example, a barium titanate-based ceramic can be used.
- the thickness of the dielectric ceramic layer 211 is preferably at least 0.1 ⁇ in order to ensure the withstand voltage, and at most 5 / im in order to form a high-capacity capacitor. Further, a ceramic dielectric film having a thickness of more than 5 ⁇ m is not preferable because the flexibility of the film itself is remarkably lost, and a problem that the film itself is easily broken in a manufacturing process such as when transferring a substrate is not preferable.
- the layer 211 is subjected to a heat treatment, Improve crystallinity.
- the temperature of the heat treatment is preferably from 500 ° C to 900 ° C.
- a dielectric ceramic layer having a stable crystal structure and excellent dielectric properties can be formed. It is desirable that the crystal form be improved in crystallinity so as to obtain better dielectric properties, and that the perovskite peaks be clearly separated as shown in FIGS.
- Table 1 below shows the relative permittivity of the barium titanate thin film formed by sputtering without heat treatment and with heat treatment at various temperatures.
- Figures 21 to 25 show the X-ray It is a diffraction chart.
- the crystallinity is improved, and a clear perovskite structure is exhibited.
- the dielectric constant of the barium titanate film £ from 2 0-3 0 during thin film formation, when having improved crystallinity by 5 0 0 ° C or more heat treatment Increases to more than 200 at a stroke.
- an electrode film 2 13 is formed on the dielectric ceramic layer 2 1 1.
- This electrode film 213 has a two-layer structure, similarly to the electrode film 212 formed in FIGS. 18 (b) and 18 (c), and a Ti film 213b is first formed on the dielectric ceramic layer 211.
- a Cu film 213a is formed.
- Cu has the advantages of lower cost and lower electrical resistance than the Pt electrode film attached earlier, but the electrode film formed directly on the transfer substrate involves a heat treatment step, so it has poor heat resistance and oxidation resistance. A good Pt film is more suitable. Therefore, it is desirable to use different materials for the electrode films formed on both sides of the dielectric.
- the electrode film 212 a directly formed on the transfer substrate should be made of an electrode material having a high melting point, and the electrode film 213 a should be made of an inexpensive electrode material having a low electric resistance. Is desirable.
- the electrode films 213a and 213b are patterned by etching (FIGS. Is ( g ) and 18 (h)). It should be noted that any of etching and dry etching can be applied to the patterning of the electrode film.
- the transfer substrate 231 is turned over, and the resin pre-predeer (organic material in the B-stage state) 215 is subjected to press processing while applying pressure and heating to transfer (FIG. 18 (i)). Then, the transfer substrate 231 is peeled off (FIG. 18 (j)). In this transfer, the dielectric ceramic layer 211 provided with the electrode films 212 and 213 is pressed by pressing the cured resin substrate via an adhesive layer without using the pre-predator 215. It is also possible to transfer to a substrate.
- the organic resin substrate 215 to be transferred has excellent dielectric properties and low water absorption, and both a thermoplastic resin and a thermosetting resin can be used.
- a thermoplastic resin for example, epoxy resin, phenolic resin, butyl benzyl ether conjugate, bismaleidido toeazine resin, polyolefin resin, polyimide, polyester, polyphenylene oxide, polyphenylene sulfide, liquid crystal polymer, fluorine polymer A resin containing one or more of these, such as a base resin, can be used.
- these resins may be mixed with dielectric ceramic powder, magnetic powder, etc. as necessary, and various electric Characteristic can be imparted.
- the pressure during transfer to 1 to 3 MPa, it is easy to embed the capacitor element layer formed as a thin film into the pre-preda at the same time as the transfer.
- the capacitor element is embedded in the pre-predator, no step is formed at the time of laminating the substrate in a later step, so that there is no gap at the outer periphery of the capacitor. For this reason, the reliability of the capacitor element formed in the multilayer substrate with respect to the moisture resistance is improved.
- the first electrode film 212 covering the surface of the dielectric ceramic layer 211 is aligned with the pattern-formed electrode film 213 to form a counter electrode. Patter jung is performed so that it can be formed (Fig. 18 (k), 18 (1)). This makes it possible to form a large-capacity capacitor on an organic substrate, which could not be formed conventionally using a resin or organic substrate, or a substrate using a composite material in which a dielectric ceramic material is dispersed in a resin substrate. .
- the laminating step not only the dielectric ceramic layer (capacitor layer) but also various functional layers including a thin-film magnetic material layer, a resistor layer, and a coil pattern can be laminated.
- the multilayer substrate of the present embodiment shown in FIG. 17 includes, in addition to the capacitor, an inductor 222 in which a predetermined coil pattern is formed adjacent to the thin-film magnetic material layer 221 in the substrate. Further, various types of chip components can be mounted on the surface of the multilayer substrate formed in this manner.
- reference numeral 225 denotes a through hole
- 227 denotes a ground electrode.
- the dielectric ceramic layer 211 described above can be formed on the entire substrate as shown in FIGS. 18 (a) to 18 (n) and FIGS. 19 (a) and 19 (b).
- a dielectric ceramic layer 211 can be formed on a part of the substrate.
- a dielectric ceramic layer is formed on a part of the substrate.
- a dielectric ceramic layer 211 having electrode films 211, 213 on both sides is formed on the transfer substrate, and then these are formed on a resin substrate 215. I just need to transfer it.
- Other functional layers such as a magnetic material layer and an antibody layer can be formed on a portion other than the portion where the dielectric ceramic layer 211 is formed.
- a silicon wafer substrate having a thickness of 0.4 mm was prepared as the transfer substrate 2 31.
- a film was formed in a thickness of 0.1 ⁇ in order of Pt and Ti by sputtering to form an electrode film 212.
- a thin film of barium titanate having a thickness of 0.3 zm was formed on the electrode film 21 12 by RF sputtering under a heating condition of 600 ° C. to obtain a dielectric ceramic layer 211.
- a film was formed on the dielectric ceramic layer 211 by 0.1 ⁇ m each in the order of Ti and Cu.
- a predetermined pattern is formed by etching the electrode film 21 on the surface so that a capacitor can be formed.
- the transfer substrate is inverted with respect to a 100 ⁇ m thick bulbenzil resin pre-preader and pressed while applying pressure and heating. Thereafter, the transfer substrate was peeled off. In this state, the metal electrode film 212 covers the entire surface.
- the metal electrode film 211 is aligned with the pattern etched to form the capacitor, and is subjected to buttering so that a counter electrode can be formed.
- a Cu film is formed on a silicon wafer substrate having a thickness of 0.4 mm, then a Ti film is formed, and then these Cu and Ti films are etched into a coil shape.
- S io 2 in order to secure insulating properties is formed in a thickness of 0. 2 ⁇ , N i on it - it was deposited to the F e film becomes 0. 3 mu m
- a magnetic layer 221 was formed.
- the transfer temperature was about 200 ° C, and the transfer pressure was about 2MPa. Was.
- the base material and the dielectric film were laminated with the resin pre-predeer 216 interposed therebetween, whereby a laminated body as shown in FIG. 17 could be formed.
- the temperature of the heat treatment of the dielectric ceramic layer is preferably from 500 ° C. to 900 ° C., and the thickness of the dielectric ceramic layer is greater than 5 zm.
- the flexibility of the film itself is remarkably lost, and a problem that the film itself is broken in a manufacturing process such as when transferring a substrate is likely to occur. Therefore, it is preferably 5 m or less.
- one or more (one or two or more) capacitor element layers formed by the dielectric ceramic layer and the electrode film are embedded in a resin-based substrate in the same plane.
- a pair of electrode films formed with the dielectric ceramic layer interposed therebetween are formed of different materials on opposite sides.
- the method for producing a multilayer substrate according to the present invention is a method for producing a multilayer substrate having one or more (one or two or more) capacitor element layers inside the substrate.
- the step of transferring includes a step of burying the capacitor element layer in the pre-preda at the same time as the transfer.
- the manufacturing method includes a step of patterning the second electrode film after the step of forming the second electrode film, and the patterning the second electrode film and the first electrode film. Transferring the resulting dielectric ceramic layer onto the resin pre-predader, and after the transferring step, patterning the first electrode film.
- a step of masking the transfer substrate into an electrode pattern and forming a first electrode pattern on the transfer substrate by a thin film method Forming a dielectric ceramic layer, heat-treating the dielectric ceramic layer to improve crystallinity, and, after the heat-treating step, masking the dielectric ceramic layer into an electrode pattern to form a thin-film method.
- the method further includes a step of forming a second electrode pattern and a step of transferring the dielectric ceramic layer provided with the first and second electrode patterns onto a resin prepreg.
- the temperature of the heat treatment of the dielectric ceramic layer is set at 500 ° C. to 900 ° C.
Abstract
Description
Claims
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
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JP2005504202A JPWO2004089049A1 (ja) | 2003-03-28 | 2004-03-26 | 多層基板およびその製造方法 |
US10/544,649 US20060180342A1 (en) | 2003-03-28 | 2004-03-26 | Multilayer substrate and method for producing same |
EP04723746A EP1610599A1 (en) | 2003-03-28 | 2004-03-26 | Multilayer substrate and method for producing same |
Applications Claiming Priority (6)
Application Number | Priority Date | Filing Date | Title |
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JP2003090235 | 2003-03-28 | ||
JP2003-90235 | 2003-03-28 | ||
JP2003095573 | 2003-03-31 | ||
JP2003093352 | 2003-03-31 | ||
JP2003-93352 | 2003-03-31 | ||
JP2003-95573 | 2003-03-31 |
Publications (1)
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WO2004089049A1 true WO2004089049A1 (ja) | 2004-10-14 |
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PCT/JP2004/004277 WO2004089049A1 (ja) | 2003-03-28 | 2004-03-26 | 多層基板およびその製造方法 |
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US (1) | US20060180342A1 (ja) |
EP (1) | EP1610599A1 (ja) |
JP (1) | JPWO2004089049A1 (ja) |
KR (1) | KR100755088B1 (ja) |
WO (1) | WO2004089049A1 (ja) |
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JP2006229214A (ja) * | 2005-01-21 | 2006-08-31 | Ngk Spark Plug Co Ltd | 配線基板の製造方法 |
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KR20210015500A (ko) * | 2019-08-02 | 2021-02-10 | 삼성전기주식회사 | 칩 안테나 |
KR102268383B1 (ko) * | 2019-08-02 | 2021-06-23 | 삼성전기주식회사 | 칩 안테나 |
US11251518B2 (en) | 2019-08-02 | 2022-02-15 | Samsung Electro-Mechanics Co., Ltd. | Chip antenna |
Also Published As
Publication number | Publication date |
---|---|
JPWO2004089049A1 (ja) | 2006-07-06 |
EP1610599A1 (en) | 2005-12-28 |
US20060180342A1 (en) | 2006-08-17 |
KR100755088B1 (ko) | 2007-09-03 |
KR20050095889A (ko) | 2005-10-04 |
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