US20130043211A1 - Method of manufacturing a floor board - Google Patents

Method of manufacturing a floor board Download PDF

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Publication number
US20130043211A1
US20130043211A1 US13/581,738 US201113581738A US2013043211A1 US 20130043211 A1 US20130043211 A1 US 20130043211A1 US 201113581738 A US201113581738 A US 201113581738A US 2013043211 A1 US2013043211 A1 US 2013043211A1
Authority
US
United States
Prior art keywords
substance
panel
pattern
curable
onto
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US13/581,738
Other languages
English (en)
Inventor
Bruno Vermeulen
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Spanolux NV SA
Original Assignee
Spanolux NV SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Spanolux NV SA filed Critical Spanolux NV SA
Assigned to SPANOLUX N.V.-DIV. BALTERIO reassignment SPANOLUX N.V.-DIV. BALTERIO ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: VERMEULEN, BRUNO
Publication of US20130043211A1 publication Critical patent/US20130043211A1/en
Priority to US14/678,653 priority Critical patent/US10239346B2/en
Abandoned legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/20—Applying plastic materials and superficially modelling the surface of these materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00—Processes for applying liquids or other fluent materials
    • B05D1/28—Processes for applying liquids or other fluent materials performed by transfer from the surfaces of elements carrying the liquid or other fluent material, e.g. brushes, pads, rollers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/06—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation
    • B05D3/061—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation using U.V.
    • B05D3/065—After-treatment
    • B05D3/067—Curing or cross-linking the coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/12—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by mechanical means
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • B05D5/02—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain a matt or rough surface
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50—Multilayers
    • B05D7/52—Two layers
    • B05D7/54—No clear coat specified
    • B05D7/542—No clear coat specified the two layers being cured or baked together
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41F—PRINTING MACHINES OR PRESSES
    • B41F17/00—Printing apparatus or machines of special types or for particular purposes, not otherwise provided for
    • B41F17/24—Printing apparatus or machines of special types or for particular purposes, not otherwise provided for for printing on flat surfaces of polyhedral articles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/22—Removing surface-material, e.g. by engraving, by etching
    • B44C1/227—Removing surface-material, e.g. by engraving, by etching by etching
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C5/00—Processes for producing special ornamental bodies
    • B44C5/04—Ornamental plaques, e.g. decorative panels, decorative veneers
    • B44C5/0469—Ornamental plaques, e.g. decorative panels, decorative veneers comprising a decorative sheet and a core formed by one or more resin impregnated sheets of paper
    • B44C5/0476—Ornamental plaques, e.g. decorative panels, decorative veneers comprising a decorative sheet and a core formed by one or more resin impregnated sheets of paper with abrasion resistant properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44F—SPECIAL DESIGNS OR PICTURES
    • B44F9/00—Designs imitating natural patterns
    • B44F9/02—Designs imitating natural patterns wood grain effects

Definitions

  • aspects of the invention relate to a method of manufacturing a floor board.
  • a method of manufacturing a floor panel which comprises supplying a panel, printing a curable substance or surface removing substance onto the panel in a predefined pattern for creating an elevation on the panel at the pattern or removing a portion of the surface of the panel at the pattern, respectively, and curing the curable substance or removing any reaction products of the surface removing substance and the panel, hence forming the floor board.
  • embossed press plates or press rollers Due to the method it is not necessary to use relatively expensive embossed press plates or press rollers to be pressed under high pressure on the panel in order to create an embossed surface of the floor board. Furthermore, the method provides the opportunity to create a high degree of variations in relief patterns of floor boards. A comparable degree of variation in case of using different embossed press plates or press rollers would be more expensive.
  • the step of printing is digitally controlled and/or non-contact printing and/or non-contact printing. Due to the digitally controlled step a quick switch to manufacturing floor boards having alternative relief patterns can be effected. This introduces a great flexibility in relief patterns and avoids the necessity of repetitive embossment such as in case of prior art relief press rollers or relief press plates. This means that a standardized basic product can be efficiently further treated to form a unique product corresponding to individual customer desires. More specifically, it is possible that the substance is printed onto the panel via a digitally controlled printing nozzle.
  • the panel may comprise a substrate of HDF, WPC (Wood Plastic Composite), polymeric composite (engineered polymer), PVC, LVT (Luxury Vinyl Tile) or the like.
  • the panel may be provided with a decorative basic pattern, which is directly printed on the substrate or laminated thereon by means of a known method of laminating.
  • the supplied panel may already comprise an embossment, but may also have a flat surface on which the curable substance or the surface removing substance is printed.
  • the curable substance may be cured by curing means, for example by means of UV radiation or a UV laser.
  • Alternative curing means may comprise electron-beam heating, or normal heating at elevated temperature; for example, the entire panel including the curable substance may be placed in a heated environment so as to cure the substance.
  • the curable substance may comprise wear resistant particles in order to provide good wear performance of the elevated portions of the floor board in use.
  • the predefined pattern substantially corresponds to a decorative basic pattern being present on the panel.
  • the floor board will be provided with embossment in register.
  • the pattern may be a wood grain pattern where the wood grains are depressed portions and the surrounding portions are elevated portions.
  • the depressed portions can be made by printing a surface removing substance at the intended depressed portions or printing a curable substance beside of the intended depressed portions.
  • the curable substance or surface removing substance may be printed onto the panel by first printing a liquid onto the panel in said predefined pattern, and then providing an intermediate substance to the liquid, wherein the intermediate substance or the liquid together with the intermediate substance form the curable substance or surface removing substance.
  • the intermediate substance may comprise a powder. This can be applied onto the liquid and stick to the liquid, whereas abundant powder is removed, for example by a suction device.
  • the intermediate substance contains wear resistant particles since this provides the opportunity to print the liquid without wear resistant particles onto the panel so as to avoid wear of a printing head, whereas the powder including wear resistant particles can be applied less accurate to the printed liquid.
  • the maximal thickness of the curable substance lies between 50 and 250 ⁇ m, but a thinner or thicker layer is conceivable.
  • the maximal thickness lies between 5 and 1000 ⁇ m.
  • the curable substance may contain a varnish, which is lustrous or matte, for example.
  • the panel is a flexible sheet which is laminated to a substrate after printing the curable substance or surface removing substance thereon so as to form the floor board.
  • the sheet is a paper sheet which is already provided with a resin or still has to be provided with a resin.
  • the method comprises the steps of supplying a panel, applying a curable substance or surface removing substance onto the panel in a predefined pattern for creating an elevation on the panel at the pattern or removing a portion of the surface of the panel at the pattern, respectively, wherein the substance is applied onto the panel by first putting a layer of the substance onto the panel and then creating the predefined pattern by a digitally controlled impacting member which is pressed into said substance and movable in a plane extending parallel to the panel so as to form the pattern, curing the curable substance or removing any reaction products of the surface removing substance and the panel, hence forming the floor board.
  • the advantage of the method is that using expensive prior art embossed press plates is not necessary to create embossed floor boards, whereas quick changes to the desired relief pattern can be achieved.
  • the impacting member will be smaller than the dimensions of the panel.
  • the impacting member may be comparable to a conventional dot matrix printer, in which digitally controlled pins impact on a paper via an ink ribbon. This method is applicable in case of partly cured top layers, such as polyurethane (PU) hot coating top layers.
  • the control of the impacting member can be based on image recognition, for example cameras that recognize the pattern of approaching panels.
  • FIG. 1 is a schematic side view of an apparatus for performing an embodiment of the method.
  • FIG. 2 is a similar view as FIG. 1 of an alternative embodiment.
  • FIG. 3 is a similar view as FIG. 1 of another alternative embodiment.
  • FIG. 1 illustrates the main steps of an embodiment of the method.
  • the manufacturing process performed by an apparatus 1 runs from the right to the left in FIG. 1 .
  • a panel 2 is transported first to a digital printing station 3 .
  • a liquid is printed on an upper surface of the panel 2 in a predetermined pattern.
  • the liquid may be an ink or varnish, being transparent or colored or any other liquid material.
  • the printed panel 2 is transported to a powder unit 4 , where an intermediate substance or a powder 5 is spread over the panel 2 .
  • the powder 5 will stick to the liquid.
  • the liquid and the powder 5 form a substance which is curable.
  • a part of the powder 5 may fall beside of the printed pattern or on a portion of the printed pattern which is already dry. That part of the powder 5 will be removed from the panel 2 by a suction device 6 , but an alternative powder removing device is conceivable.
  • the formed substance on the panel 2 is cured at a heating station 7 .
  • the panels 2 Before storing the resulting floor boards 2 a at a storage station 9 the panels 2 may be cooled at a cooling station 8 .
  • the powder In the heating station 7 the powder may be melted together into a single mass which is elevated above the initial upper surface of the panel 2 . It is conceivable that the liquid and powder together form a curable substance or the powder itself forms a curable substance adhering to the panel 2 upon curing.
  • the powder forms the curable substance whereas the liquid pattern only functions as a temporary carrier for carrying the powder in the desired pattern.
  • the liquid may partly or fully disappear during the step of heating, for example by evaporation.
  • the powder 5 may be a swelling powder such that upon curing the volume of the substance becomes larger (and the elevations higher) than that of the sum of the liquid and the powder 5 separately.
  • the maximal thickness of the substance after curing lies between 50 and 250 ⁇ m, but a higher or lower thickness is conceivable. In practice, a thickness of 5-1000 ⁇ m is preferred.
  • the powder 5 can also contain wear-resistant particles, for example corundum particles. It is advantageous that in the embodiment as illustrated in FIG. 1 the wear resistant particles are supplied separately from a printing head of the digital printing station, thus avoiding wear of the printing head through the presence of wear resistant particles.
  • the heating station 7 may comprise a UV-laser, for example, but alternative curing means are conceivable.
  • the apparatus of FIG. 1 may comprise a camera (not shown) for recognizing a basic pattern being printed on the panel 2 before arriving at the digital printing station 3 .
  • the pattern to be printed on the panel 2 at the digital printing station 3 may correspond to the basic pattern such that the panel 2 obtains an embossment in register.
  • metallic resin powder which creates a metallic effect after melting
  • lustrous resin powder in which lustrous particle are added to the powder
  • anti-static powder which avoids build-up of electrostatic charge
  • powders which generate pearlescent effect, matt effect, or odour effect.
  • the curable substance is directly printed at the printing station 10 in a predetermined pattern on a panel 2 . This is illustrated in FIG. 2 . In this case, a relatively large amount of substance has to be printed by the printing station 10 .
  • Other features as described in relation to the embodiment as illustrated in FIG. 1 are also applicable to the embodiment as illustrated in FIG. 2 .
  • a layer of the substance is spread onto the panel 2 at a substance spread device 11 and then the predetermined relief pattern is created by a digitally controlled impacting member 12 , see FIG. 3 .
  • the substance may be spread uniformly over the panel 2 .
  • the digitally controlled impacting member 12 is repeatably pressed into the curable substance and movable in a plane extending parallel to the panel 2 so as to form the relief pattern.
  • Other features as described in relation to the embodiment as illustrated in FIG. 1 are also applicable to the embodiment as illustrated in FIG. 3 .
  • a surface removing sub- stance can be applied on the panel (directly or indirectly via powder in a printed liquid as described hereinbefore) such that the local surface of the panel 2 at the intended pattern is removed.
  • the substance can be applied on the panel in a manner as illustrated in FIGS. 1 and 2 .
  • the substance is selected such that it reacts with the surface of the panel 2 so as to remove a portion thereof.
  • the relief pattern of the panel 2 is formed by removing material from the panel 2 instead of adding material. After heating and/or cooling of the substrate on the panel any reaction products may be removed by pressed air, for example. It is also possible that neither heating nor cooling is necessary in this embodiment. After applying the embossment in this way the panel may be covered with a finishing layer containing wear resistant particles.
  • the surface removing substance is selected such that it reacts with the surface of the panel 2 after being activated.
  • the substance can be activated by a heat source, UV radiation, a laser beam or the like.
  • an activation device needs not to be focussed very accurately on specific areas of the panel surface since only those areas will be activated where the substance is present. After activation and reaction of the substance with the panel surface, any reaction products may be removed.
  • Panels having the same decorative basic pattern may be provided with different relief patterns, for example one of the type embossing-in-register and the other one of the type brushed all-over. This enlarges the variation of appearances of floor boards.
  • the panel 2 on which the curable substance or surface removing surface is applied may be made of HDF, WPC, polymer composite or engineered polymer, LVT, PVC or the like. It is noted that the method can also be applied on a flexible sheet which will be laminated to a substrate at a later stage so as to form a floor board.
  • the invention is not limited to the embodiments shown in the figures, which can be varied in several ways within the scope of the invention. It is for example possible that the method is applied on alternative substrates than on a panel or a sheet, for example on the packaging material of floor panels. Furthermore, the digital printing station may be replaced by alternative printing means, for example a conventional printing roller as known from the prior art roller printing process.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Floor Finish (AREA)
  • Finishing Walls (AREA)
  • Printing Methods (AREA)
US13/581,738 2010-03-05 2011-03-07 Method of manufacturing a floor board Abandoned US20130043211A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US14/678,653 US10239346B2 (en) 2010-03-05 2015-04-03 Method of manufacturing a floor board

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP10155673A EP2363299B1 (fr) 2010-03-05 2010-03-05 Procédé de fabrication d'une lame à parquet
EP10155673.6 2010-03-05
PCT/EP2011/053383 WO2011107610A1 (fr) 2010-03-05 2011-03-07 Procédé de fabrication d'une lame de plancher

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2011/053383 A-371-Of-International WO2011107610A1 (fr) 2010-03-05 2011-03-07 Procédé de fabrication d'une lame de plancher

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US14/678,653 Continuation US10239346B2 (en) 2010-03-05 2015-04-03 Method of manufacturing a floor board

Publications (1)

Publication Number Publication Date
US20130043211A1 true US20130043211A1 (en) 2013-02-21

Family

ID=42395111

Family Applications (5)

Application Number Title Priority Date Filing Date
US13/581,738 Abandoned US20130043211A1 (en) 2010-03-05 2011-03-07 Method of manufacturing a floor board
US14/678,653 Active US10239346B2 (en) 2010-03-05 2015-04-03 Method of manufacturing a floor board
US16/356,750 Active US11292289B2 (en) 2010-03-05 2019-03-18 Method of manufacturing a floor board
US17/678,838 Active 2031-07-28 US11970020B2 (en) 2010-03-05 2022-02-23 Method for manufacturing a floor board
US18/121,276 Active US11938751B2 (en) 2010-03-05 2023-03-14 Method for manufacturing a floor board

Family Applications After (4)

Application Number Title Priority Date Filing Date
US14/678,653 Active US10239346B2 (en) 2010-03-05 2015-04-03 Method of manufacturing a floor board
US16/356,750 Active US11292289B2 (en) 2010-03-05 2019-03-18 Method of manufacturing a floor board
US17/678,838 Active 2031-07-28 US11970020B2 (en) 2010-03-05 2022-02-23 Method for manufacturing a floor board
US18/121,276 Active US11938751B2 (en) 2010-03-05 2023-03-14 Method for manufacturing a floor board

Country Status (10)

Country Link
US (5) US20130043211A1 (fr)
EP (2) EP2363299B1 (fr)
CN (1) CN102834275B (fr)
BR (1) BR112012021883B1 (fr)
CA (2) CA2791216C (fr)
DK (1) DK2363299T3 (fr)
ES (1) ES2564800T3 (fr)
PL (2) PL2363299T3 (fr)
RU (1) RU2561327C2 (fr)
WO (1) WO2011107610A1 (fr)

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WO2014014400A1 (fr) 2012-07-17 2014-01-23 Floor Iptech Ab Feuille supplémentaire
US9079212B2 (en) 2013-01-11 2015-07-14 Floor Iptech Ab Dry ink for digital printing
US20150239230A1 (en) * 2012-09-14 2015-08-27 Spanolux N.V.- Div. Balterio Method and an apparatus for decorating a panel
US9446602B2 (en) 2012-07-26 2016-09-20 Ceraloc Innovation Ab Digital binder printing
US10035358B2 (en) 2012-07-17 2018-07-31 Ceraloc Innovation Ab Panels with digital embossed in register surface
US10041212B2 (en) 2013-02-04 2018-08-07 Ceraloc Innovation Ab Digital overlay
US10239346B2 (en) 2010-03-05 2019-03-26 Unilin Bvba Method of manufacturing a floor board
US10443203B2 (en) 2013-02-28 2019-10-15 Ihc Iqip Uk Ltd. Pile driving guide
US10899166B2 (en) 2010-04-13 2021-01-26 Valinge Innovation Ab Digitally injected designs in powder surfaces
US10968591B2 (en) 2016-09-30 2021-04-06 Ihc Iqip Uk Ltd. Pile guide comprising a base frame and a guide member
US20220009248A1 (en) * 2020-07-09 2022-01-13 Välinge Innovation AB Glossy printing
US11318772B2 (en) * 2020-02-14 2022-05-03 Palo Alto Research Center Incorporated Printing system using vibration-driven particle applicator
US11878324B2 (en) 2013-01-11 2024-01-23 Ceraloc Innovation Ab Digital thermal binder and powder printing

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CN104520018B (zh) 2012-07-26 2017-08-11 塞拉洛克创新股份有限公司 数码结合剂印刷
CN102825968B (zh) * 2012-09-18 2015-05-13 王鸥 装饰板表面图案形成方法
EP3616939A1 (fr) 2013-01-11 2020-03-04 Ceraloc Innovation AB Gaufrage numérique
EP3792065A1 (fr) * 2013-01-11 2021-03-17 Ceraloc Innovation AB Impression numérique avec de l'encre à blanc transparente
CA2896942C (fr) * 2013-01-11 2021-08-24 Floor Iptech Ab Impression numerique a poudre et liant
EA029513B1 (ru) * 2013-01-11 2018-04-30 Сералок Инновейшн Аб Сухие чернила для цифровой печати
WO2014109703A1 (fr) 2013-01-11 2014-07-17 Floor Iptech Ab Liant thermique numérique et impression de poudre
US10486459B2 (en) 2013-01-22 2019-11-26 Unilin, Bvba Method and device for manufacturing products having a surface provided with embossments, and products obtained thereby
EP2913199B1 (fr) * 2014-02-28 2018-03-21 Flooring Technologies Ltd. Procédé et dispositif de fabrication d'un panneau décoratif
KR101674766B1 (ko) * 2014-12-23 2016-11-10 주식회사 포스코 투명 패턴 프린트 강판 제조 방법
KR20210060496A (ko) 2018-08-30 2021-05-26 인터페이스 인크. 바닥재 및 장식용 구조체들을 위한 디지털 인쇄
EP3865308A1 (fr) * 2020-02-12 2021-08-18 Jesús Francisco Barberan Latorre Procédé et machine pour produire des reliefs, ainsi que des panneaux contenant ces reliefs
RU2745545C1 (ru) * 2020-03-13 2021-03-26 Общество с ограниченной ответственностью "3Д-Реплика" (ООО - 3Д-Реплика") Декоративное устройство с нанесенным рельефным изображением и способ получения рельефного изображения
IT202000020143A1 (it) * 2020-08-13 2022-02-13 Giorgio Macor Pannello decorato

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US20150328919A1 (en) 2015-11-19
US11970020B2 (en) 2024-04-30
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US11292289B2 (en) 2022-04-05
CA2984272C (fr) 2022-11-29
CA2791216A1 (fr) 2011-09-09
EP2363299A1 (fr) 2011-09-07
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US10239346B2 (en) 2019-03-26
CN102834275A (zh) 2012-12-19
BR112012021883B1 (pt) 2020-03-31
DK2363299T3 (da) 2013-01-28
US11938751B2 (en) 2024-03-26
US20220176731A1 (en) 2022-06-09
PL2363299T3 (pl) 2013-02-28
ES2564800T3 (es) 2016-03-29
PL2542426T3 (pl) 2016-06-30
BR112012021883A2 (pt) 2018-05-02
US20190210401A1 (en) 2019-07-11
RU2561327C2 (ru) 2015-08-27
US20160068010A9 (en) 2016-03-10
CA2791216C (fr) 2017-12-12
CA2984272A1 (fr) 2011-09-09
EP2542426B1 (fr) 2016-01-06
CN102834275B (zh) 2015-12-16
RU2012140050A (ru) 2014-04-10

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