US20040052997A1 - Composite pressure container or tubular body and composite intermediate - Google Patents

Composite pressure container or tubular body and composite intermediate Download PDF

Info

Publication number
US20040052997A1
US20040052997A1 US10/244,749 US24474902A US2004052997A1 US 20040052997 A1 US20040052997 A1 US 20040052997A1 US 24474902 A US24474902 A US 24474902A US 2004052997 A1 US2004052997 A1 US 2004052997A1
Authority
US
United States
Prior art keywords
fiber
tubular body
pressure container
resin
composite pressure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US10/244,749
Other languages
English (en)
Inventor
Ietsugu Santo
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Rayon Co Ltd
Original Assignee
Mitsubishi Rayon Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Rayon Co Ltd filed Critical Mitsubishi Rayon Co Ltd
Priority to US10/244,749 priority Critical patent/US20040052997A1/en
Assigned to MITSUBISHI RAYON COMPANY, LTD. reassignment MITSUBISHI RAYON COMPANY, LTD. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: SANTO, IETSUGU
Priority to CA002440806A priority patent/CA2440806C/en
Priority to EP03020502A priority patent/EP1400342A3/de
Priority to CN2006100774826A priority patent/CN1891423B/zh
Priority to JP2003325227A priority patent/JP2004106552A/ja
Priority to CNB031569943A priority patent/CN100548633C/zh
Publication of US20040052997A1 publication Critical patent/US20040052997A1/en
Assigned to MITSUBISHI RAYON COMPANY, LTD. reassignment MITSUBISHI RAYON COMPANY, LTD. RECORD TO CORRECT ASSIGNEE'S ADDRESS ON AN ASSIGNMENT PREVIOUSLY RECORDED ON REEL 014392 FRAME 0069 Assignors: SANTO, IETSUGU
Priority to US11/485,977 priority patent/US7790235B2/en
Priority to JP2006201244A priority patent/JP2007039684A/ja
Priority to JP2006201243A priority patent/JP2007002256A/ja
Abandoned legal-status Critical Current

Links

Images

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B15/00—Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00
    • B29B15/08—Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00 of reinforcements or fillers
    • B29B15/10—Coating or impregnating independently of the moulding or shaping step
    • B29B15/12—Coating or impregnating independently of the moulding or shaping step of reinforcements of indefinite length
    • B29B15/122—Coating or impregnating independently of the moulding or shaping step of reinforcements of indefinite length with a matrix in liquid form, e.g. as melt, solution or latex
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C53/00—Shaping by bending, folding, twisting, straightening or flattening; Apparatus therefor
    • B29C53/56—Winding and joining, e.g. winding spirally
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C53/00—Shaping by bending, folding, twisting, straightening or flattening; Apparatus therefor
    • B29C53/80—Component parts, details or accessories; Auxiliary operations
    • B29C53/8008—Component parts, details or accessories; Auxiliary operations specially adapted for winding and joining
    • B29C53/8066—Impregnating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00—Other particular articles
    • B29L2031/712—Containers; Packaging elements or accessories, Packages
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/32—Hydrogen storage
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
    • Y10T428/1369—Fiber or fibers wound around each other or into a self-sustaining shape [e.g., yarn, braid, fibers shaped around a core, etc.]

Definitions

  • the present invention relates to a composite pressure container, tubular body and/or composite intermediate produced using a prepreg tow process, reinforced fibers and prepreg tows for use in same, and methods of making and using same.
  • composite molded articles have been increasingly used in applications such as CNG (compressed natural gas) tanks, breather oxygen tanks, e.g., for firefighters, hydrogen storage tanks, e.g., for fuel cells, off-shore pipes and flywheel rotors.
  • CNG compressed natural gas
  • breather oxygen tanks e.g., for firefighters
  • hydrogen storage tanks e.g., for fuel cells, off-shore pipes and flywheel rotors.
  • the filament winding method is suitable for the production of cylindrical or spherical molded articles, and it is quite advantageous because it facilitates automated manufacturing processes. This method also allows great reduction in the weight of the article, e.g., by replacing ordinary metals with a composite.
  • a reinforcing fiber is dipped in an impregnation bath containing a low-viscosity resin, and, after removal of the excess resin, is wound on a mandrel or a form to produce a pressure container or a tubular body.
  • a plastic or metal liner is used, and the reinforcing fiber is wound around the liner outer shell to enhance the strength of the liner.
  • a reinforcing fiber that is not impregnated with resin is impregnated with resin formed in situ, to form a reinforcing fiber.
  • the reinforcing fiber is then wound on a mandrel such as the above-mentioned liner.
  • the wet filament winding method is still used as a mainstream process.
  • Epoxy resin is mainly used as the resin in filament winding. To facilitate impregnation, low-viscosity resin is generally used. In the wet filament winding method, the resin composition, curing agent or catalyst are generally selected so that the curing reaction proceeds gradually at room temperature.
  • a latent curing agent or a resin composition having a latent curing property is generally selected, and it is stored at a low temperature or room temperature. Because of the latent curing property, the curing reaction proceeds very slowly, and thickening of the resin does not occur even if the winding is carried out at room temperature.
  • the prepreg tow resin generally has a relatively high viscosity when compared to wet method resins, the prepreg tow resin adheres less to a roll or to a guide. Even if the prepreg tow resin does adhere to the roll or guide, however, resin thickening does not occur, as noted above. Therefore, the requirement for solvents or solvent resin removal is desirably minimized. Thus, large molded articles can easily be produced with great effect.
  • Pressure containers have attracted much interest because they are particularly suitable for storing and/or preserving an energy source that replaces gasoline. These pressure containers have heretofore been produced with metallic materials, which are heavy. When metallic pressure containers are used in automobiles, operating costs are high, and payload must be limited. It has been found that the use of composite pressure containers can realize a high burst pressure with light weight, and thus an all composite or partial composite pressure container has come to be used.
  • One of the problems heretofore associated with the production of composite pressure containers is that the substantial tensile strength (as hoop strength) of a pressure container decreases relative to the reinforcing fiber tensile strength (strand tensile strength).
  • a general performance standard of a composite container is to exhibit a fiber strength (fiber strength translation) from the reinforcing fiber strength to the hoop fiber tensile strength in the composite pressure container.
  • the fiber strength translation directly influences the design weight strength and the material cost of a pressure container. When the fiber strength translation is increased by even several percentages, it is quite advantageous in view of the cost. For this reason, it is extremely important to increase the hoop fiber tensile strength of a composite pressure container.
  • U.S. Pat. No. 5,356,499 reports that the burst pressure of a hoop fiber of a pressure container that is reinforced with a reinforcing fiber or the fiber strength translation of a reinforcing fiber calculated therefrom is improved by adding an appropriate amount of a surface active agent to the resin composition whose viscosity has been chemically adjusted in advance.
  • a surface active agent markedly increases the fiber strength translation in comparison with the absence of the surface active agent, and further its coefficient of variation (CV) of the burst pressure is minimized by the use of an appropriate amount of the surface active agent, especially the use of a prepreg tow.
  • the combination of a room temperature curing agent and a latent curing agent, appropriate adjustment of resin viscosity with a room temperature curing agent, and a surface active agent in an amount of less than approximately 1% contribute toward improving the fiber strength translation of a composite pressure container.
  • the level of the fiber strength translation is at most 90%, and there is room for further improvement.
  • one object of the present invention is to solve the aforementioned problems.
  • Another object of the present invention is to provide a composite pressure container or tubular body using a prepreg tow in which the fiber strength translation of a hoop fiber is improved.
  • Another object of the present invention is to provide a composite pressure container or tubular body using a prepreg tow, which can be produced in an ecologically friendly manner.
  • the first embodiment of which provides a composite pressure container or tubular body, which includes:
  • said uncured thermosetting resin includes at least one surface active oligomer or polymer.
  • Another embodiment of the invention provides a process for producing a prepreg tow and/or a prepreg, which includes:
  • thermosetting resin a thermosetting resin
  • Another embodiment of the invention provides a process for producing a prepreg tow and/or a prepreg, which includes:
  • thermosetting resin a thermosetting resin
  • Another embodiment of the invention provides a prepreg or prepreg tow, which includes at least one fiber, at least one thermosetting resin, and at least one surface active oligomer or polymer.
  • Another embodiment of the invention provides a reinforced fiber, which includes a fiber, at least one thermosetting resin, and at least one surface active oligomer or polymer.
  • Another embodiment of the invention provides a pressure container or tubular body, which includes the above reinforced fiber in contact with an inner shell or liner.
  • FIG. 1 is a schematic view showing a preferred process for producing of a prepreg tow.
  • the present invention relates to a pressure container or a tubular body in which a reinforcing fiber wound on a pressure container or a tubular body in a hoop layer or layers exhibits a tensile strength as a hoop strength at a high achievement rate (high fiber strength translation) relative to a delivered reinforcing fiber tensile strength. More specifically, the invention relates to a resin, a surface active additive, a composite strength, an uncured resin viscosity, a resin content and its composite intermediate which are most appropriate for improving, when producing a composite pressure container or tubular body using a prepreg tow, a strength of the composite container or tubular body, substantially a fiber strength translation inside the composite pressure container or tubular body.
  • prepreg tows have been formed by a method in which the viscosity of a thermosetting resin is decreased using an organic solvent; a reinforcing fiber is impregnated with the thermosetting resin; and the solvent is then volatilized and dried.
  • solventless methods have been used.
  • a surface active polymer or oligomer is used, and water is used as a diluent.
  • a resin solution containing a surface active polymer or oligomer is charged into a resin tank 5 , and fed to a reinforcing fiber bundle with a metering pump. After the fiber is fully impregnated with the resin solution using a resin impregnation roll 3 , water is volatilized with an oven 6 .
  • the water content of the resin aqueous solution or emulsion is preferably 90% or less, based on the weight of the solution or emulsion. It is more preferably 50% or less, more particularly preferably 40% or less, more especially preferably 30% or less, and most preferably, 20% or less, based on the weight of the solution or emulsion. These ranges include all values and subranges there between, including 89, 80, 75, 61, 60, 59, 55, 51, 47, 45, 42, 38, 35, 25, 18, 15, 10, 9, 5 and 2%.
  • the viscosity of the emulsion with which the fiber is contacted or impregnated is preferably 1 to 10,000 cps. More preferably, the viscosity is 10 to 1,000 cps, more particularly preferably, 50 to 100 cps. These ranges include all values and subranges there between, including 2, 15, 25, 75, 200, 500, 750, 1,500, 5,000, 7,500, and 9,000 cps.
  • a metering pump in each weight.
  • the resin may also be distributed in each weight by controlling with a shim or a needle valve. Feedback controlling via a shim or a needle valve with in-line detection of resin content is also preferable.
  • the simplest and preferred method uses a gear pump. Combinations of metering and controlling methods are possible.
  • the resin is excessively adhered, and the excess resin is then squeezed out.
  • the constant feed method makes it easy to control the amount of resin fed to each weight, and it further dispenses with a squeezing-out step, and this can reduce the possibility of damaging the fiber and increase the production rate and is therefore preferred.
  • a device for contacting and impregnating the resin is preferably one in which the resin is continuously fed, and the flowing resin is preferably one in which the resin can be continuously be fed and in which the flowing resin makes efficient contact with the reinforcing fiber bundle and particularly at the start of impregnation.
  • Reinforcing fiber is comprised of many filaments. “Impregnation” preferably means the respective surfaces of all or substantially all the filaments is wet with resin or resin emulsion. Before impregnation, the reinforcing fiber surface is facing the air or surrounded by air. The air is believed to be replaced with uncured resin or resin emulsion by capillary effect or resin flow through the bundle of filaments. The filament surface(s) is in contact with resin after impregnation.
  • the surface active polymer or oligomer is stirred and more preferably constantly stirred without agglomeration.
  • any method will do, but it is more preferable that the temperature can be fully controlled.
  • a method in which temperature-controlled air, unreactive gas or reactive gas flows countercurrently with the fiber feed direction is preferable as the easiest and surest method.
  • Drying time is not particularly limited.
  • the total exposing time at elevated temperature is preferably controlled such that the volatile content (and most preferably water content) should be less than 2% and more preferably less than 1%.
  • Drying temperatures preferably 100-200° C. (212-392° F.), more preferably 100-120° C. (212-250° F.) are used, which ranges include all values and subranges therebetween, including 105, 110, 115, 125, 130, 140, 150, 160, 170, 180, 190 and 195° C.
  • the reinforcing fiber suited for the composite pressure container or tubular body various fibers are available, and they are not particularly limited.
  • the fibers can selectively be used according to the usage and properties required.
  • a mixture of fibers is also possible.
  • a glass fiber is suitable as it is a general reinforcing fiber, historically.
  • carbon fiber, boron fiber, aramid fiber, polyester, polyethylene, nylon (polyamide), polypropylene, E-glass, S-glass, carbon graphite, and organic polymer fiber called PBO (polyphenylene benzo-bis-oxazole) fiber are also suitable. Combinations of fibers are possible.
  • the resin which exhibits a thermosetting property
  • examples of the resin include epoxy resin, unsaturated polyester, vinyl ester, bismaleimidetriazine, cyanate ester, benzoxazine and bismaleimide. Combinations of resins are possible. Epoxy resin is most preferable in view of the chemical resistance and cost.
  • the epoxy resin is selected from the group including a reaction product of epichlorohydrin and a compound containing at least one hydroxyl group, epoxidized cresol novolak, epoxidized phenol novolak, a reaction product of an aromatic hydroxyl compound and glyoxal, glycidylaniline, glycidylaniline derivative and bisphenol A novolak derivative. Combinations are possible.
  • the epoxy resin is selected from the group including 4,4′-(isopropylidenediphenol), isopropylidenediphenolbis(2,6-dibromophenol), an epoxidized cresol novolak formed by glycidylating a cresol condensate resulting from resination of cresol with an acid catalyst, bisphenol A novolak, a tetraglycidyl ether of a tetrakis(4-hydroxyphenyl)ethane resin, 4,4′-methylenebis(N,N-glycidylaniline) and N,N-diglycidylaniline. Mixtures are possible.
  • an aromatic amine curing agent selected from the group including diaminediphenylsulfone, diaminodiphenylmethane, phenylenediamine and isomers thereof, a curing agent selected from the group including an aliphatic amine curing agent, an aromatic amine curing agent, an acid anhydride curing agent, a phenol curing acid and a Lewis acid or a curing agent selected from the group including dicyandiamide, ethylenediamine, diethylenetriamine, triethylenetetramine and hexamethylenediamine. Diaminodiphenylsulfone and dicyandiamide are especially preferable as a curing agent. Combinations are possible. Other curing agents may optionally and preferably be incorporated as appropriate to adjust the shelf life of the prepreg tow.
  • the catalyst of the epoxy resin is selected from the group including a tertiary amine, a Lewis acid, a urea compound and an imidazole. Combinations are possible. Specifically, it is more preferably selected from the group including benzyldimethylamine, pyridine, triethylamine, tetramethylbutanediamine, 2-methylimidazole, 2-ethylmethylimidazole, BF3MEA, phenyldimethylurea, 3-pheny-1,1-dimethylurea, 1,1′-4-(methyl-m-phenylene)bis(3,3′-dimethyl)urea, 3-(3,4-dichlorophenyl)-1,1-dimethylurea, 4-diamino-6-( 2 ′-dimethylimidazolyl-(1′)), 2,4-diamino-6-( 2 ′-methylimidazolyl-(1′))ethyl-S
  • the resin since the resin, and preferably the epoxy resin, is generally undissolved in water, it is preferably dispersed in water through the surface active oligomer or polymer. An affinity of the surface active oligomer or polymer for the epoxy resin and water is therefore preferably taken into account.
  • the molecular weight of the surface active agent oligomer or polymer is preferably at least 5,000 and at most 30,000. When the molecular weight is less than 5,000, it is difficult to obtain a stable thermosetting resin emulsion. When the molecular weight exceeds 30,000, it is difficult to mix the resin. More preferably, the molecular weight of the surface active agent is from 5,500 to 25,000, more particularly preferably from 7,500 to 20,000, more especially preferably from 10,000 to 17,500, and most preferably from 12,000 to 15,000.
  • molecular weight means number average molecular weight.
  • the surface active oligomer or polymer has one or more hydrophilic atoms or hydrophilic groups in its main chain or side chain.
  • hydrophilic atoms or groups include oxygen, nitrogen, amino group, nitro group, sulfonic acid, sulfonate, hydroxy, sulfonyl, carboxylate, carboxylic acid, phosphonate, phosphate, ester, ether, and the like. Combinations are possible.
  • One or more oxygen atoms in the main chain is most preferred.
  • At least ⁇ fraction (1/10) ⁇ of atoms relative to the other atoms in the main chain are oxygen atoms. More preferably, at least ⁇ fraction (2/10) ⁇ are oxygen atoms, more particularly preferably at least ⁇ fraction (4/1) ⁇ , and most preferably ⁇ fraction (6/10) ⁇ .
  • Homopolymers and copolymers are suitable for the surface active oligomer or polymer.
  • Block copolymers, random or statistical copolymers, and graft copolymers are preferable.
  • the surface active oligomer or polymer has an affinity for the epoxy resin used.
  • an epoxy skeleton for example, a bisphenol-A skeleton into the main chain
  • the compatibility with an epoxy resin other than the surface active oligomer or polymer can be increased.
  • the molecular weight of an epoxy skeleton is 300 or more, more preferably 500 or more, and most preferably 700 or more.
  • the surface active oligomer or polymer is a reaction product of polyethylene glycol or polypropylene glycol and an epoxy resin.
  • a preferred example of the surface active oligomer or polymer may be formed by reacting 2 mols of polyethylene glycol with 1 mol of a bisphenol-A epoxy resin which is 468 g/mol per epoxy equivalent.
  • the content of the surface active oligomer or polymer is preferably at least 1% and at most 10%, more preferably at least 2% and at most 10% based on the resin solid content. These ranges include all values and subranges therebetween, including 1.5, 2.5, 3, 4, 4.5, 5, 5.5, 6, 6.5, 7, 7.5, 8, 8.5, 9, and 9.5% based on the resin solid content.
  • the content of the surface active oligomer or polymer is less than 1%, the surface active effect is low which has an adverse effect on a stability of an emulsion. Further, when it is more than 10%, water is easily absorbed to decrease a heat resistance.
  • the curing agent, catalyst or curing accelerator is a powder at room temperature.
  • the particle diameter of the powder is preferably 20 ⁇ m or less, more preferably 10 ⁇ m or less. When the particle diameter is more than 20 ⁇ m, a stability in an emulsion or a slurry is poor and precipitation tends to occur. These ranges include all values and subranges therebetween, including 18, 16, 14, 12, 8, 6, 4, 2 and 1 ⁇ m or less.
  • the interlaminar shear strength or SBS (short beam shear) in evaluating a unidirectionally oriented laminate according to ASTM D 2344 (incorporated herein by reference) is at least 8 Ksi and at most 18 Ksi
  • the flexural strength in a 90° direction (FS90) evaluated according to ASTM D 790 (incorporated herein by reference) is at least 8 Ksi and at most 22 Ksi.
  • Ksi is a unit for pressure. Ksi is an abbreviation of kilopound (LB) per square inch. 1 Ksi means 6.89 MPa.
  • the adhesion between the reinforcing fiber and the resin is very strong, and the tensile strength is less exhibited.
  • the composite should have optimum adhesion between filament and resin. If composite has a strong adhesion between filament and resin, local filament failure may tend to cause catastrophic failure to transverse (90°) direction at a relatively lower stress level. If the adhesion is optimum, the initial failure may stop locally and also optimum adhesion may help appropriate stress transfer from filament to filament. One the other hand weak adhesion may cause low stress transfer between filaments and the stress imbalance between filaments may be extreme.
  • SBS Short Beam Shear
  • 90° flexure are not direct criteria for adhesion but they are strongly related to adhesion properties and finally to tensile strength translation.
  • “Hoop state” or “hoop layer” means a layer or layers where prepreg tow is wound in the circumferential direction to form a tubular or cylindrical shape.
  • a small winding angle relative to the circumferential direction is needed and it is up to the width of prepreg tow. Accurately winding angle is not perpendicular to circumferential direction. This is called a hoop layer.
  • the second hoop layer may be wound with an opposite winding angle atop the first layer.
  • Several hoop layers may be added as appropriate.
  • “Hoop state” is a generic naming of a hoop layer or some hoop layers. Wound prepreg tow layers are cured or hardened to utilize as a composite article. Cured composite of pressure containers or tubular body may be tested in burst strength by applying inner pressure in pressure containers or tubular body.
  • helical layers may be needed, wherein the prepreg tow is placed with higher angle relative to the hoop tow direction (circumferential direction).
  • the main purpose of helical layer is to wind or wrap prepreg tow to cover the domes or spherical parts of pressure container.
  • Almost all pressure containers have hoop and helical layers, but some types of pressure containers have only hoop layers.
  • a composite pressure container has at least a hoop layer. Failure of pressure container in burst test initiates at hoop layer of container or is designed as the failure initiates at hoop layers or hoop state.
  • the failure feature of hoop strength for pressure container or tubular body can be regarded as a tensile mode in burst test, and the achieving rate of its tensile strength is an important factor to define the capability of pressure container or tubular body.
  • Fiber Strength Translation is defined as a tensile strength achieving rate how the fiber actually exhibits their tensile strength in a hoop state compared to the tensile strength evaluated in a strand tensile test.
  • Original fiber has its inherent tensile strength, which can be measured in tensile strand test specifically based on ASTM D2343. It is called “Strand Tensile Strength” or “Delivered Tensile Strength” and is defined as ⁇ st . Its number is provided by fiber supplier or acquired by measurer based on ASTM D2343, the entire contents of which are hereby incorporated by reference.
  • reinforcing fibers which are coated and/or impregnated with resin are wound on the liner and cured. From inside the liner, hydraulic pressure is applied until the liner and composite shell bursts. The pressure at burst is called the burst pressure. The actual pressure applied on inner surface of composite shell is defined as P act .
  • ⁇ is composite tensile stress at burst
  • R is inner radius of composite shell
  • t is the thickness of the composite shell
  • ⁇ f fiber tensile strength at burst
  • Vf Fiber Volume ratio in composite shell
  • Fiber Tensile Strength Translation is defined as
  • a prepreg tow having a strength of 300 Ksi or more in the NOL ring test according to ASTM D 2290 (incorporated herein by reference) is preferable for the composite pressure container or tubular body. Accordingly, a reinforcing fiber having a high strength is preferred.
  • a fiber strength translation is at least 80%.
  • These mechanical properties are preferable for the composite pressure container using the prepreg tow to exhibit the fiber strength translation of at least 80%.
  • the ring burst test used herein is established by Mitsubishi Rayon Co., Ltd. Specifically, the ring burst test is described in JP1 104379 , incorporated herein by reference.
  • the test result of this method can provide a criterion how the prepreg tow can exhibit a tensile strength translation in the actual tubular body or pressure container, which includes hoop part of pressure container by applying hydraulic pressure from inside of the ring.
  • the specimen has a cylindrical shape and the actual size is 500 mm of inner diameter, 510 mm of outer diameter and 25 mm of cylindrical length, which is machined with 0.1 mm of tolerance from longer cylinder part made by filament winding process.
  • the specimen shall be installed in a matched metal die and from inside the specimen hydraulic pressure is applied. More concretely fluid for pressurizing is poured in a rubber-like tube locating inside of the specimen and actually the pressure is applied on the inner surface of specimen till the specimen fails or breaks. Strain gauge is attached on the outer surface of the specimen and the strain can be recorded and also the hydraulic pressure is recorded.
  • the ring burst test exhibits a burst pressure that is close to that of actual pressure container or tubular body, and its failure is considered as tensile mode.
  • NOL ring test also exhibits a tensile failure mode of tubular body. The difference is the way of applying force.
  • the ring burst test is more practical than NOL ring test for hoop strength of pressure container and tubular body, and it is more useful than NOL ring test to assess prepreg tow capability. There is no ASTM standard equivalent to ring burst test.
  • the number of filaments in the tow count of the prepreg tow is between 500 and 300,000. If the tow count is less than 0.5K, manufacturing cost of the towpreg is very high. In addition, too many spools are needed for filament winding process, which is undesirable. If the tow count is more than 300K, tension difference between both sides of prepreg tow may be higher than the prepreg tow with smaller tow count, which may reduce tensile strength translation.
  • the above range includes all values and subranges therebetween, including 750, 1000, 1100, 1500, 2000, 5000, 10,000, 15,000, 20,000, 25,000, 50,000, 75,000, 85,000, 95,000, 99,000, 100,000, 150,000, 200,000, 250,000, 275,000, and 295,000.
  • the resin viscosity of the prepreg tow is 10,000 to 1,000,000 cps at 75° F.
  • the resin viscosity is less than 10,000 cps, the resin is bled out on the surface in winding the prepreg tow on a spool.
  • the resin viscosity is more than 1,000,000 cps, a void is formed between prepreg tows in winding the prepreg tow on a mandrel, and this may decrease the fiber strength translation.
  • the aforementioned resin viscosity range includes all values and subranges therebetween, including 12,000, 15,000, 25,000, 50,000, 100,000, 150,000, 500,000, 750,000, and 900,000 cps at 75° F.
  • the width of the prepreg tow is uniform.
  • a standard deviation is adjusted to, preferably 0.01 inch or less, more preferably 0.005 inch or less. These ranges include all values and subranges therebetween, including 0.009, 0.007, 0.006, 0.004, 0.003, 0.002, and 0.001 inch or less.
  • the standard deviation of the tow width is large, a gap between tows or overlapping thereof may occur to decrease the uniformity of molded articles and have an adverse effect on the fiber strength translation of the hoop fiber.
  • the fiber volume content of the prepreg tow is preferably 40 to 95%, more preferably 65 to 75%. These ranges include all values and subranges therebetween, including 51, 55, 57, 59, 61, 63, 67, 69, 71 and 73%.
  • the fiber volume content is less than 40%, a large amount of the resin is present between layers, which may have an adverse effect on the fiber strength translation. Alternatively, a large amount of the resin is bled out on the surface to deteriorate the appearance.
  • tubular body is generally referred to herein to mean a pipe, such as an offshore, overground, underground, or underwater pipe, a tube, transfer pipe, tank, cylindrical object, circular object, rotor, flywheel rotor and the like.
  • the tubular body may have one or more means of attachment to an axle, turning lathe, or spindle as appropriate, or it may have a flange or connecting or sealing means on one or both ends.
  • pressure container is generally referred to herein to mean a container used to store, preserve, carry, and/or deliver a compressed liquid, gas, other fluid, supercritical fluid, foam, powder, aerosol, and the like.
  • the pressure container may include one or more wound fibers, resins, liners, and shells as appropriate.
  • the pressure container may include one or more plastic, metal, and/or composite shells and/or liners or any combination thereof as appropriate.
  • the reinforcing fiber is wound around the liner outer shell to enhance the strength of the pressure container.
  • the pressure container may also include one or more valves, valve attachment means, content delivery means, flanges, threads, regulators, caps, relief valves, pressure gauges, and/or connectors as appropriate in any combination.
  • the resulting resin mixture was heated at 70° C., and poured into the same amount of deionized water held at 70° C., to form a solution.
  • the solution was stirred at 1,500 rpm.
  • the temperature was then decreased to 35° C. to form an emulsion.
  • the amount of the copolymer added was approximately 8%.
  • a prepreg tow was produced using a prepreg tow production apparatus shown in FIG. 1 using the emulsion formed in Example 1.
  • the emulsion was charged in a resin tank 5 , maintained at 35° C., and always stirred with a stirrer.
  • the resin emulsion was fed to a resin impregnation device through a resin feed pipe 4 with a metering pump.
  • a spool of 12,000 filaments of carbon fiber TR50S manufactured by Mitsubishi Rayon Company Ltd. was installed in a creel.
  • a carbon fiber tow was fed to the resin impregnation device and brought into contact with the resin fed from the resin tank. Subsequently, the fiber was impregnated with the resin through a resin impregnation roll, and water was then dried with an oven 6.
  • the tow was wound with a winder 7 .
  • the production rate was 15 m/min, and the resin content was 30% by weight.
  • the prepreg tows produced in Example 2 were used, and they were arranged unidirectionally to form a unidirectional prepreg. Twelve plies of the prepreg were laminated, and cured in an autoclave at 275° F. for 2 hours to form a unidirectional laminate.
  • test pieces for an interlaminar shear strength (SBS) and a 90° tensile strength (FS90) were prepared, and SBS and FS90 were measured according to ASTM D2344 and ASTM D790 (both incorporated herein by reference).
  • SBS and FS90 at 75° F. were 15 Ksi and 16 Ksi respectively.
  • a NOL ring test piece having an inner diameter of 146 mm, a thickness of 1.50 mm and a width of 6.35 mm was prepared using the prepreg tow formed in Example 2. The curing was conducted at 257° F. for 2 hours.
  • a hoop tensile strength was 645 Ksi, and a fiber strength translation recorded 92.1% and the coefficient of variation was 2.3%.
  • a ring burst test was likewise conducted using the prepreg tow produced in Example 2.
  • a Teflon ring (5 mm thick, 500 mm of outer diameter) was used as a mandrel, and a hoop was wound thereon. The product was then cured under the same curing conditions as in Example 4 to prepare a test piece, which has the same dimension as aforementioned.
  • a hydrostatic pressure was exerted from inside to burst the ring. At this time, a fiber tensile strength calculated was 670 Ksi. A tensile strength translation was 95.7%, and CV (Coefficient of Variation) of the burst pressure was 1.6%.
  • Example 2 An emulsion was produced in the same manner as in Example 2 except that the amount of the surface active copolymer formed in Example 1 was changed to 0.5% and the water content to 50% respectively. However, the emulsion stability was not good.
  • Example 2 a resin mixture was formed as in Example 2 except that the content of the surface active copolymer was changed to 0.5%. A prepreg tow was produced using the resin mixture. The resin content was 30%.
  • Example 2 An emulsion was produced in the same manner as in Example 2 except that the amount of the surface active copolymer formed in Example 1 was changed to 4% and the water content to 50% respectively.
  • a prepreg tow was produced under the same conditions as in Example 2. The resin content was 30%.
  • Example 2 The prepreg tow in Example 2, Comparative Example 1 or Comparative Example 2 was wound on an aluminum pressure container liner having a diameter of 6.4′′ in the same pattern to prepare a test piece. Subsequently, a bottle burst test was performed by a method described in ASTM D2585-65, incorporated herein by reference.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Moulding By Coating Moulds (AREA)
  • Reinforced Plastic Materials (AREA)
  • Filling Or Discharging Of Gas Storage Vessels (AREA)
  • Pressure Vessels And Lids Thereof (AREA)
  • Rigid Pipes And Flexible Pipes (AREA)
US10/244,749 2002-09-17 2002-09-17 Composite pressure container or tubular body and composite intermediate Abandoned US20040052997A1 (en)

Priority Applications (9)

Application Number Priority Date Filing Date Title
US10/244,749 US20040052997A1 (en) 2002-09-17 2002-09-17 Composite pressure container or tubular body and composite intermediate
CA002440806A CA2440806C (en) 2002-09-17 2003-09-12 Composite pressure container or tubular body and composite intermediate
EP03020502A EP1400342A3 (de) 2002-09-17 2003-09-15 Verbunddruckbehälter oder Verbundrohrkörper und Zwischenverbundmaterial
CNB031569943A CN100548633C (zh) 2002-09-17 2003-09-17 复合材料压力容器或管状体以及复合材料中间体
JP2003325227A JP2004106552A (ja) 2002-09-17 2003-09-17 複合圧力容器または複合管状体ならびに複合中間物
CN2006100774826A CN1891423B (zh) 2002-09-17 2003-09-17 预浸渍丝束和/或预浸渍物的制造方法
US11/485,977 US7790235B2 (en) 2002-09-17 2006-07-14 Composite pressure container or tubular body and composite intermediate
JP2006201244A JP2007039684A (ja) 2002-09-17 2006-07-24 複合圧力容器または複合管状体ならびに複合中間物
JP2006201243A JP2007002256A (ja) 2002-09-17 2006-07-24 プリプレグトウおよび／またはプリプレグの製造方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US10/244,749 US20040052997A1 (en) 2002-09-17 2002-09-17 Composite pressure container or tubular body and composite intermediate

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US11/485,977 Division US7790235B2 (en) 2002-09-17 2006-07-14 Composite pressure container or tubular body and composite intermediate

Publications (1)

Publication Number Publication Date
US20040052997A1 true US20040052997A1 (en) 2004-03-18

Family

ID=31946396

Family Applications (2)

Application Number Title Priority Date Filing Date
US10/244,749 Abandoned US20040052997A1 (en) 2002-09-17 2002-09-17 Composite pressure container or tubular body and composite intermediate
US11/485,977 Expired - Lifetime US7790235B2 (en) 2002-09-17 2006-07-14 Composite pressure container or tubular body and composite intermediate

Family Applications After (1)

Application Number Title Priority Date Filing Date
US11/485,977 Expired - Lifetime US7790235B2 (en) 2002-09-17 2006-07-14 Composite pressure container or tubular body and composite intermediate

Country Status (5)

Country Link
US (2) US20040052997A1 (de)
EP (1) EP1400342A3 (de)
JP (3) JP2004106552A (de)
CN (2) CN100548633C (de)
CA (1) CA2440806C (de)

Cited By (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050077643A1 (en) * 2003-10-01 2005-04-14 Seiichi Matsuoka Pressure container manufacturing method
US20070296124A1 (en) * 2004-12-29 2007-12-27 Giandomenico Gonella Method for Combining a First Material with a Composite Material so as to Realise a Structural Element and a Container Element and a Structural Element and a Container Element Made According to This Method
US20080006337A1 (en) * 2006-03-22 2008-01-10 Quigley Peter A Dual Containment Systems, Methods and Kits
US20080006338A1 (en) * 2006-03-21 2008-01-10 Wideman Thomas W Reinforcing Matrix for Spoolable Pipe
US20080015305A1 (en) * 2006-07-17 2008-01-17 Gm Global Technology Operations, Inc. Composites having an improved resistance to fatigue
US20080210329A1 (en) * 2007-02-15 2008-09-04 Quigley Peter A Weighted Spoolable Pipe
US20090107558A1 (en) * 2007-10-23 2009-04-30 Quigley Peter A Heated pipe and methods of transporting viscous fluid
US20100101676A1 (en) * 2001-04-27 2010-04-29 Quigley Peter A Composite Tubing
US20100212769A1 (en) * 1995-09-28 2010-08-26 Quigley Peter A Composite spoolable tube
US20110209768A1 (en) * 2008-12-01 2011-09-01 Andreas Dowe Use of a composition for contact with supercritical media
US8678042B2 (en) 1995-09-28 2014-03-25 Fiberspar Corporation Composite spoolable tube
US8678041B2 (en) 2004-02-27 2014-03-25 Fiberspar Corporation Fiber reinforced spoolable pipe
CN103707496A (zh) * 2012-10-08 2014-04-09 合肥杰事杰新材料股份有限公司 一种热塑性纤维缠绕成型的管材及其成型工艺
US8955599B2 (en) 2009-12-15 2015-02-17 Fiberspar Corporation System and methods for removing fluids from a subterranean well
DE102013227142A1 (de) * 2013-12-23 2015-06-25 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Langzeitstabile Prepregs, Verfahren zu deren Herstellung und Verwendungen der Prepregs
US9127546B2 (en) 2009-01-23 2015-09-08 Fiberspar Coproation Downhole fluid separation
US9206676B2 (en) 2009-12-15 2015-12-08 Fiberspar Corporation System and methods for removing fluids from a subterranean well
US9822928B2 (en) 2010-06-17 2017-11-21 3M Innovative Properties Company Composite pressure vessels
US9890880B2 (en) 2012-08-10 2018-02-13 National Oilwell Varco, L.P. Composite coiled tubing connectors
US9926418B2 (en) 2008-12-23 2018-03-27 Cytec Industrial Materials (Derby) Limited Curative fibre components
CN108962423A (zh) * 2018-07-04 2018-12-07 凤凰电力有限公司 用于电缆的碳纤维复合芯及其制造方法
DE102018121012A1 (de) * 2018-08-28 2020-03-05 Alzchem Trostberg Gmbh Verfahren zur Herstellung eines Druckgasbehälters
WO2023098573A1 (zh) * 2021-11-30 2023-06-08 中材科技（苏州）有限公司 一种复合式缠绕成型设备

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7262020B2 (en) 2003-07-03 2007-08-28 The Regents Of The University Of California Methods for comparing relative flux rates of two or more biological molecules in vivo through a single protocol
CN100453882C (zh) * 2005-07-04 2009-01-21 哈尔滨工业大学 大尺寸、超薄金属内衬的复合材料压力容器的制造方法
CN100342172C (zh) * 2005-07-04 2007-10-10 哈尔滨工业大学 大尺寸、超薄金属内衬的复合材料压力容器的制造方法
CN101331176B (zh) * 2005-10-17 2012-07-04 高级复合材料国际有限公司 增强复合材料
FR2909919B1 (fr) * 2006-12-13 2012-12-07 Eads Ccr Procede de fabrication d'une piece complexe en materiau composite a fibres longues et a matrice thermodurcissable
EP2134531B1 (de) 2007-04-18 2013-10-16 DSM IP Assets B.V. Verfahren zur herstellung eines gekrümmten produkts mit verstärkungselementen aus gezogenem polymer und daraus gewonnenes produkt
GB2451136B (en) 2007-07-20 2012-11-28 Umeco Structural Materials Derby Ltd Thermoset resin fibres
JP5104661B2 (ja) * 2008-08-28 2012-12-19 東レ株式会社 炭素繊維織物および繊維強化プラスチックの製造方法
JP2010095159A (ja) * 2008-10-16 2010-04-30 Nsk Ltd 車両ステアリング用伸縮軸の製造方法
JP2011140966A (ja) * 2010-01-05 2011-07-21 Jx Nippon Oil & Energy Corp 複合容器
DE102010008633A1 (de) * 2010-02-16 2011-08-18 Siemens Aktiengesellschaft, 80333 Herstellungsverfahren eines winkelstarren Körpers
JP2011206933A (ja) * 2010-03-29 2011-10-20 Jx Nippon Oil & Energy Corp 複合容器の製造方法、及び、複合容器
CN101905532A (zh) * 2010-06-25 2010-12-08 中材科技（苏州）有限公司 一种使用大丝束碳纤维制造压力容器的方法
CN102135178B (zh) * 2010-12-30 2013-01-23 西安航天复合材料研究所 一种用于压力容器的干纱缠绕成型方法
DE102011010558A1 (de) * 2011-02-07 2012-08-09 Thyssenkrupp Uhde Gmbh Verbundwerkstoff
US9486940B2 (en) * 2012-12-18 2016-11-08 Autoliv Asp, Inc. Radiation curable resin systems for composite materials and methods for use thereof
JP6216509B2 (ja) * 2012-12-26 2017-10-18 東邦テナックス株式会社 サイジング剤付着炭素繊維束及びその製造方法並びにこのサイジング剤付着炭素繊維束を用いる圧力容器の製造方法
CN103407152B (zh) * 2013-07-05 2014-11-05 北京航空航天大学 一种碳纤维缠绕机纤维传导装置
CN104464988B (zh) * 2014-11-03 2017-11-24 安徽蓝翔电器成套设备有限公司 改性玻璃纤维套管及其制备方法和应用
CN105623189A (zh) * 2014-11-03 2016-06-01 中国石油化工股份有限公司 一种碳纤维预浸料用环氧树脂组成物及其制备方法
CN105291410A (zh) * 2015-11-01 2016-02-03 北京工业大学 一种制备呼吸器用复合气瓶的缠绕和固化工艺
JP6724389B2 (ja) * 2016-01-28 2020-07-15 東洋インキＳｃホールディングス株式会社 圧力容器の製造方法
CN105754285B (zh) * 2016-02-29 2018-05-01 山东柏远复合材料科技有限公司 以纤维为增强材料、以热固性树脂为胶结材料制备的具有空间结构的复合材料及其制备方法
DE102017106992A1 (de) * 2017-03-31 2018-10-04 Hauni Maschinenbau Gmbh Verfahren zum Herstellen von wenigstens doppellagigen rohrförmigen Strängen der Tabak verarbeitenden Industrie sowie Vorrichtung zur Herstellung von wenigstens doppellagigen Strängen der Tabak verarbeitenden Industrie
CN107285136B (zh) * 2017-06-22 2023-03-10 兰州蓝星纤维有限公司 一种大丝束碳纤维原丝上丝装置及其使用方法
JP6543309B2 (ja) * 2017-08-11 2019-07-10 帝人株式会社 サイジング剤付着炭素繊維束及びその製造方法並びにこのサイジング剤付着炭素繊維束を用いる圧力容器の製造方法
KR102290264B1 (ko) 2018-06-26 2021-08-18 플라스틱 옴니엄 어드벤스드 이노베이션 앤드 리서치 내부 라이너가 강화된 복합 압력 용기 및 이의 제조하는 방법
CN113736112B (zh) * 2021-08-20 2022-09-23 清华大学 一种聚合物纤维布增强的ZnO压敏微球-环氧树脂复合材料的制备方法

Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4252592A (en) * 1977-07-05 1981-02-24 Ciba-Geigy Corporation Method of making epoxide resin-impregnated composites
US4835975A (en) * 1983-10-18 1989-06-06 Windecker Robert J Cryogenic tank
US4886356A (en) * 1988-04-01 1989-12-12 The Perkin-Elmer Corporation Detector cell for liquid chromatography
US5356499A (en) * 1989-10-25 1994-10-18 Thiokol Corporation Method for increasing fiber strength translation in composite pressure vessels using matrix resin formulations containing surface acting agents
US5459180A (en) * 1993-03-29 1995-10-17 Hoechst Ag Polyol/epoxy adducts for use as emulsifier for liquid epoxy resins
US5545278A (en) * 1989-10-25 1996-08-13 Thiokol Corporation Method for increasing fiber strength translation in composition pressure vessels using matrix resin formulations containing anhydride curing agents and surface-active agents
US5589523A (en) * 1994-03-15 1996-12-31 Toray Industries, Inc. Microcapsule-type curing agent, method for producing the same, thermosetting resin composition, prepreg and fiber reinforced composite material
US5591784A (en) * 1994-06-17 1997-01-07 Three Bond Co., Ltd. Curing of fiber-reinforced composite structures
US20020108699A1 (en) * 1996-08-12 2002-08-15 Cofer Cameron G. Method for forming electrically conductive impregnated fibers and fiber pellets
US6515081B2 (en) * 1997-10-14 2003-02-04 Toray Industries, Inc. Composition of epoxy resin, curing agent and reactive compound
US6670006B1 (en) * 1997-03-27 2003-12-30 Mitsubishi Rayon Co., Ltd. Epoxy resin composition for FRP, prepreg, and tubular molding produced therefrom
US6730729B2 (en) * 2001-05-22 2004-05-04 Basf Aktiengesellschaft Heat curable binders

Family Cites Families (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1544249A (en) * 1975-06-05 1979-04-19 Shell Int Research Process for preparing epoxy resin composite materials
JPH0710288B2 (ja) 1989-11-28 1995-02-08 美津濃株式会社 ゴルフクラブシャフト
JPH04214739A (ja) 1990-12-14 1992-08-05 Dainippon Ink & Chem Inc 成形用プリプレーグ
DE4128487A1 (de) 1991-08-28 1993-03-04 Hoechst Ag Verfahren zur herstellung von waessrigen epoxidharz-dispersionen
JPH06212057A (ja) 1992-01-28 1994-08-02 Kobayashi Kk 塩化ビニル系プラスチゾル組成物
JP3169468B2 (ja) * 1992-03-27 2001-05-28 竹本油脂株式会社 炭素繊維のサイジング方法
JP2711977B2 (ja) 1993-03-30 1998-02-10 三洋化成工業株式会社 エポキシ樹脂硬化物の有機溶剤懸濁液の製法
JPH07137163A (ja) 1993-06-18 1995-05-30 Nippon Oil Co Ltd 管状複合成形体の製造方法
JP2741330B2 (ja) 1993-09-13 1998-04-15 株式会社ペトカ 回転体用金属被覆炭素繊維強化プラスチックパイプ及びその製造方法
JP3406707B2 (ja) 1994-10-06 2003-05-12 新日鐵化学株式会社 粒状エポキシ樹脂の製造方法
JPH093777A (ja) 1995-06-19 1997-01-07 Nitto Boseki Co Ltd 炭素繊維用サイジング剤及び炭素繊維
JPH0985844A (ja) 1995-07-18 1997-03-31 Toray Ind Inc 繊維強化プラスチック製管状体
JPH09194712A (ja) 1996-01-18 1997-07-29 Mitsubishi Eng Plast Kk 芳香族ポリカーボネート樹脂組成物
JPH10114026A (ja) 1996-08-19 1998-05-06 Bridgestone Corp 内装仕上材
JP3623344B2 (ja) 1996-08-19 2005-02-23 株式会社ブリヂストン 木質仕上材
US5792380A (en) 1997-04-30 1998-08-11 Eastman Kodak Company Ink jet printing ink composition with detectable label material
JPH11130882A (ja) 1997-10-28 1999-05-18 Toray Ind Inc ヤーンプリプレグおよびその製造方法
CN100488906C (zh) * 1998-10-13 2009-05-20 Ppg工业俄亥俄公司 玻璃纤维补强的预浸渍片、层压件、电路板以及装配织物的方法
SE9803608D0 (sv) * 1998-10-22 1998-10-22 Borealis As A composition for an electric cable
JP2000214060A (ja) 1999-01-22 2000-08-04 Mitsubishi Rayon Co Ltd 円筒体の引張り試験装置
JP2000220302A (ja) 1999-02-03 2000-08-08 Mitsubishi Rayon Co Ltd 構造物の補修・補強方法
JP2001253952A (ja) 2000-03-09 2001-09-18 Mitsubishi Rayon Co Ltd Ｆｒｐ用マルチフィラメントおよびこれを用いたｆｒｐ
JP4651779B2 (ja) 2000-06-16 2011-03-16 東邦テナックス株式会社 ロービングプリプレグ及びその製造方法
JP2001258430A (ja) 2001-01-29 2001-09-25 Daiwa Seiko Inc 釣 竿
JP2003268137A (ja) 2002-03-15 2003-09-25 Mitsubishi Rayon Co Ltd プリプレグ及びプリプレグの製造方法

Patent Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4252592A (en) * 1977-07-05 1981-02-24 Ciba-Geigy Corporation Method of making epoxide resin-impregnated composites
US4835975A (en) * 1983-10-18 1989-06-06 Windecker Robert J Cryogenic tank
US4886356A (en) * 1988-04-01 1989-12-12 The Perkin-Elmer Corporation Detector cell for liquid chromatography
US5356499A (en) * 1989-10-25 1994-10-18 Thiokol Corporation Method for increasing fiber strength translation in composite pressure vessels using matrix resin formulations containing surface acting agents
US5545278A (en) * 1989-10-25 1996-08-13 Thiokol Corporation Method for increasing fiber strength translation in composition pressure vessels using matrix resin formulations containing anhydride curing agents and surface-active agents
US5459180A (en) * 1993-03-29 1995-10-17 Hoechst Ag Polyol/epoxy adducts for use as emulsifier for liquid epoxy resins
US5589523A (en) * 1994-03-15 1996-12-31 Toray Industries, Inc. Microcapsule-type curing agent, method for producing the same, thermosetting resin composition, prepreg and fiber reinforced composite material
US5591784A (en) * 1994-06-17 1997-01-07 Three Bond Co., Ltd. Curing of fiber-reinforced composite structures
US20020108699A1 (en) * 1996-08-12 2002-08-15 Cofer Cameron G. Method for forming electrically conductive impregnated fibers and fiber pellets
US6670006B1 (en) * 1997-03-27 2003-12-30 Mitsubishi Rayon Co., Ltd. Epoxy resin composition for FRP, prepreg, and tubular molding produced therefrom
US6515081B2 (en) * 1997-10-14 2003-02-04 Toray Industries, Inc. Composition of epoxy resin, curing agent and reactive compound
US6730729B2 (en) * 2001-05-22 2004-05-04 Basf Aktiengesellschaft Heat curable binders

Cited By (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8678042B2 (en) 1995-09-28 2014-03-25 Fiberspar Corporation Composite spoolable tube
US8066033B2 (en) 1995-09-28 2011-11-29 Fiberspar Corporation Composite spoolable tube
US20100212769A1 (en) * 1995-09-28 2010-08-26 Quigley Peter A Composite spoolable tube
US8763647B2 (en) 2001-04-27 2014-07-01 Fiberspar Corporation Composite tubing
US20100101676A1 (en) * 2001-04-27 2010-04-29 Quigley Peter A Composite Tubing
US7566376B2 (en) * 2003-10-01 2009-07-28 Fuji Jukogyo Kabushiki Kaisha Pressure container manufacturing method
US20050077643A1 (en) * 2003-10-01 2005-04-14 Seiichi Matsuoka Pressure container manufacturing method
US8678041B2 (en) 2004-02-27 2014-03-25 Fiberspar Corporation Fiber reinforced spoolable pipe
US20070296124A1 (en) * 2004-12-29 2007-12-27 Giandomenico Gonella Method for Combining a First Material with a Composite Material so as to Realise a Structural Element and a Container Element and a Structural Element and a Container Element Made According to This Method
US8187687B2 (en) * 2006-03-21 2012-05-29 Fiberspar Corporation Reinforcing matrix for spoolable pipe
US20080006338A1 (en) * 2006-03-21 2008-01-10 Wideman Thomas W Reinforcing Matrix for Spoolable Pipe
US20120266996A1 (en) * 2006-03-21 2012-10-25 Fiberspar Corporation Reinforcing Matrix for Spoolable Pipe
US8839822B2 (en) 2006-03-22 2014-09-23 National Oilwell Varco, L.P. Dual containment systems, methods and kits
US20080006337A1 (en) * 2006-03-22 2008-01-10 Quigley Peter A Dual Containment Systems, Methods and Kits
US20080015305A1 (en) * 2006-07-17 2008-01-17 Gm Global Technology Operations, Inc. Composites having an improved resistance to fatigue
US7896190B2 (en) * 2006-07-17 2011-03-01 GM Global Technology Operations LLC Composites having an improved resistance to fatigue
US8746289B2 (en) 2007-02-15 2014-06-10 Fiberspar Corporation Weighted spoolable pipe
US20080210329A1 (en) * 2007-02-15 2008-09-04 Quigley Peter A Weighted Spoolable Pipe
US20090107558A1 (en) * 2007-10-23 2009-04-30 Quigley Peter A Heated pipe and methods of transporting viscous fluid
US8985154B2 (en) 2007-10-23 2015-03-24 Fiberspar Corporation Heated pipe and methods of transporting viscous fluid
US9057466B2 (en) * 2008-12-01 2015-06-16 Evonik Degussa Gmbh Use of a composition for contact with supercritical media
US20110209768A1 (en) * 2008-12-01 2011-09-01 Andreas Dowe Use of a composition for contact with supercritical media
US9926418B2 (en) 2008-12-23 2018-03-27 Cytec Industrial Materials (Derby) Limited Curative fibre components
US9127546B2 (en) 2009-01-23 2015-09-08 Fiberspar Coproation Downhole fluid separation
US9206676B2 (en) 2009-12-15 2015-12-08 Fiberspar Corporation System and methods for removing fluids from a subterranean well
US8955599B2 (en) 2009-12-15 2015-02-17 Fiberspar Corporation System and methods for removing fluids from a subterranean well
US9822928B2 (en) 2010-06-17 2017-11-21 3M Innovative Properties Company Composite pressure vessels
US9890880B2 (en) 2012-08-10 2018-02-13 National Oilwell Varco, L.P. Composite coiled tubing connectors
CN103707496A (zh) * 2012-10-08 2014-04-09 合肥杰事杰新材料股份有限公司 一种热塑性纤维缠绕成型的管材及其成型工艺
DE102013227142A8 (de) * 2013-12-23 2015-09-03 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Langzeitstabile Prepregs, Verfahren zu deren Herstellung und Verwendungen der Prepregs
DE102013227142A1 (de) * 2013-12-23 2015-06-25 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Langzeitstabile Prepregs, Verfahren zu deren Herstellung und Verwendungen der Prepregs
DE102013227142B4 (de) 2013-12-23 2020-06-04 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Langzeitstabile Prepregs, deren Verwendung, Verfahren zu deren Herstellung und Faserverbundwerkstoff
CN108962423A (zh) * 2018-07-04 2018-12-07 凤凰电力有限公司 用于电缆的碳纤维复合芯及其制造方法
DE102018121012A1 (de) * 2018-08-28 2020-03-05 Alzchem Trostberg Gmbh Verfahren zur Herstellung eines Druckgasbehälters
WO2023098573A1 (zh) * 2021-11-30 2023-06-08 中材科技（苏州）有限公司 一种复合式缠绕成型设备

Also Published As

Publication number Publication date
US20060257576A1 (en) 2006-11-16
CN1891423B (zh) 2010-12-22
US7790235B2 (en) 2010-09-07
JP2007002256A (ja) 2007-01-11
EP1400342A3 (de) 2004-11-24
CN100548633C (zh) 2009-10-14
CA2440806A1 (en) 2004-03-17
CN1891423A (zh) 2007-01-10
JP2007039684A (ja) 2007-02-15
JP2004106552A (ja) 2004-04-08
CA2440806C (en) 2009-08-18
CN1490150A (zh) 2004-04-21
EP1400342A2 (de) 2004-03-24

Similar Documents

Publication Publication Date Title
US7790235B2 (en) Composite pressure container or tubular body and composite intermediate
CN101283215B (zh) 气罐及其制造方法
US20040119188A1 (en) Impregnated fiber precursors and methods and systems for producing impregnated fibers and fabricating composite structures
KR102039001B1 (ko) 고압 탱크
EP3077449B1 (de) Verfahren zur herstellung faserverstärkter teile basierend auf cyanatester/-epoxidmischungen und mit diesem verfahren herstellbare faserverstärkte teile
KR101802631B1 (ko) 저점도 에폭시 수지 조성물을 포함하는 토우프레그와 그의 제조방법 및 토우프레그를 이용한 압력용기의 제조방법
JP5395156B2 (ja) ガスタンク及びその製造方法
KR20210121409A (ko) 필라멘트 와인딩용 토우프레그 및 그의 제조방법
US20210316494A1 (en) Method for producing a compressed-gas container
JP2013244344A (ja) ゴルフシャフト及びその製造方法
JP7463816B2 (ja) プリプレグの製造方法及び高圧ガス貯蔵タンクの製造方法
KR20230137633A (ko) 에폭시 수지 조성물과 이로부터 제조되는 탄소섬유 복합재료 및 압력용기
KR102453290B1 (ko) 강도전이율이 향상된 탄소섬유 복합재료와 그의 제조방법 및 이를 포함하는 압력용기
KR102307642B1 (ko) 압력용기용 에폭시 수지 조성물과 테이프 형상의 프리프레그 및 그의 제조방법
US20240166816A1 (en) Thermosetting resin composition, prepreg, fiber reinforced composite material, and high-pressure gas container
JP7279868B1 (ja) エポキシ樹脂組成物及びその硬化物、プリプレグ、繊維強化複合材、高圧ガス容器
US20240116218A1 (en) Molded article manufacturing method, resin impregnating apparatus, and 3d printer
WO2022030135A1 (ja) 圧力容器用ライナー及び高圧ガス貯蔵タンク
KR102317589B1 (ko) 토우 프레그 제조용 수지 결합제 조성물과, 상기 수지 결합제 조성물을 사용하는 방법 및 상기 수지 결합제 조성물을 이용하여 제조된 토우 프리프레그
KR20230140801A (ko) 토우프레그 및 이의 제조방법
JPH04294129A (ja) 複層繊維強化プラスチック管およびその製造方法

Legal Events

Date Code Title Description
AS Assignment

Owner name: MITSUBISHI RAYON COMPANY, LTD., JAPAN

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:SANTO, IETSUGU;REEL/FRAME:014392/0069

Effective date: 20030110

AS Assignment

Owner name: MITSUBISHI RAYON COMPANY, LTD., JAPAN

Free format text: RECORD TO CORRECT ASSIGNEE'S ADDRESS ON AN ASSIGNMENT PREVIOUSLY RECORDED ON REEL 014392 FRAME 0069;ASSIGNOR:SANTO, IETSUGU;REEL/FRAME:015112/0596

Effective date: 20030110

STCB Information on status: application discontinuation

Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION